20-07-2025

9610WJA801815250007 JA

PART 1 : PHYSICS

SECTION-I

1) Pulley is rotating with angular velocity ω. Pulley is sufficiently rough so that string does not slip
on the pulley. Then angular momentum of system (pulley + blocks) about axle of pulley is :-

(A) Iω
(B) (m1 + m2 + I)ωr
2
(C) (m1 + m2)r ω + Iω
2 2 2
(D) (m1r + m2r + I)ω

2) The resultant force on a system of particles is zero.

(A) The centre of mass of the system must be at rest.

(B) Acceleration of each particle may be in the same direction.
(C) Velocity of each particle may be in the same direction at some instant of time.
(D) Acceleration of each particle must be zero.

3) A piece of paper (shown in figure 1) is in the form of a square. Two corners of this square are
folded to make it appear like figure-2. Both corners are put together at centre of square 'O'. If 'O' is
taken to be (0, 0), the centre of mass of new system will be :

(A)

(B)

(C)

(D)
4)

A particle of mass m = 1 kg moves in a circle of radius R = 2m with uniform speed v = 3π m/s. The
magnitude of impulse given by centripetal force to the particle in one second is :-

(A)
(B)
(C)
(D)

5) A particle collides elastically with two moving walls one by one as shown on a horizontal plane.

Find the final speed of the particle after two collisions :

(A) 11 m/s
(B) 19 m/s
(C) 21 m/s
(D) 5 m/s

6) A particle starts S.H.M. from the mean position. Its amplitude is A and time period is T. At the
time when its speed is half of the maximum speed, its displacement y is :

(A)

(B)

(C)

(D)

7) A uniform rod kept vertically on the rough ground falls from rest. Its foot does not slip on the
ground. Then select the incorrect statement.

(A) The maximum tangential acceleration of any point on the rod at any position is 1.5g
(B) No part of the rod can have acceleration greater than 'g' in any position.
(C) At any position of the rod, different points on it have different acceleration.
(D) Any point on the rod has different acceleration at different position of the rod.

8) A bullet of mass 50 g is fired from below into the bob of mass 450 g of a long simple pendulum as
shown in Figure. The bullet stays inside the bob and the bob rises through a vertical height 1.8 m.
What was the speed of bullet when it striked the bob?

(A) 40 m/sec
(B) 50 m/sec
(C) 60 m/sec
(D) 35 m/sec

9) A block of mass m moving with speed v collides with another block of mass 2m at rest. The lighter
block comes to rest after the collision. The coefficient of restitution is :

(A)

(B)

(C)

(D)

10) Four rigid bodies, each with the same mass and radius, are spinning freely with the same
angular momentum. Which object requires the maximum work to stop it?

(A) A solid sphere spinning about a diameter.

(B) A hollow sphere spinning about a diameter.
A disc spinning about an axis perpendicular to the plane of the disc and passing through the
(C)
centre.
(D) A hoop spinning about an axis along a diameter.

11) Which of the following quantities are always positive in a simple harmonic motion :-

(A)
(B)
(C)
(D)

12) The potential energy for a force field is given by U (x, y) = cos (x + y). The force acting on a

particle at position given by coordination is :-

(A)

(B)

(C)

(D)

13) STATEMENT–1 : Work done by a force on a body whose centre of mass does not move may be
non-zero.
STATEMENT–2 : Work done by a force depends on the displacement of the centre of mass.

(A) Statement-1 is True, Statement-2 is True

(B) Statement-1 is True, Statement-2 is False
(C) Statement-1 is False, Statement-2 is True
(D) Statement-1 is False, Statement-2 is False.

14) A disc of mass M and radius R is reshaped in the form of ring of same mass but radius 2R. The
radius of gyration increased by a factor :

(A)
(B) 4
(C)
(D) 2

15) A cube of side a and mass m is to be tilted at point A by applying a force F as shown in figure.
The minimum force required is: (there is sufficient friction to prevent sliping)

(A) mg

(B)
mg

(C)
mg

(D)
mg

16) A particle is moving parallel to x-axis as shown in the figure such that at all instant the y
component of its position vector is constant and is equal to 'b'. The angular velocites of the particle
about origin is :-

(A)

(B)

(C)

(D) vb

17) The solid cylinder shown in figure is in pure translatory motion on smooth horizontal surface. It
enters in a rough region. The angular velocity of the cylinder after long time will be :

(A)

(B)

(C)

(D)

18)

A block of mass 'M' area of cross-section 'A' & length is placed on smooth horizontal floor. A force
'F' is applied on the block as shown. If 'y' is young modulus of material, then total extension in the
block will be :

(A)

(B)

(C)
(D) Cannot extend

19) Two rods A and B of lengths ℓA and ℓB have coefficients of linear expansion αA : αB = 1 : 4. If the
difference between the lengths of the two rods is to be independent of temperature, ℓA : ℓB should be

(A) 1 : 16
(B) 1 : 4
(C) 1 : 2
(D) 4 : 1

20) m grams of ice at 0°C are mixed with 2m grams of water at 100°C in a container of negligible
heat capacity. The resulting temperature of the mixture is :-

(A) 10°C
(B) (100/3)°C
(C) 40°C
(D) none of these

SECTION-II

1) A particle performing linear SHM with time period T is at x = moving towards positive

extreme. The time after which it will first come to rest is . Find N.

2) A steel rod at 25°C is bolted at both ends and then cooled. By how many °C should the rod be
cooled so that it will rupture? Assume that till rupture, Hooke's law is obeyed. If your answer is N fill

value of . (αsteel = 10 × 10–6/°C, Y = 2 × 1011N/m2 and σb (breaking stress of steel rod) = 4 × 108
N/m2)

3) Three rods made of the same material and having the same cross-section have been joined as
shown in the figure. Each rod is of the same length. The left and right ends are kept at 0°C and 90°C
respectively. The temperature of junction of the three rods will be ______ °C.

4) Figure shows a steel rod joined to a brass rod. Each of the rods has length of 31 cm and area of
cross-section 0.20 cm2. The junction is maintained at a constant temperature 50°C and the two ends
are maintained at 100°C. The amount of heat taken out from the cold junction in 10 minutes after
the steady state is reached in n × 102 J. Find ‘n’. The thermal conductivities are Ksteel = 46 W/m–°C

and Kbrass = 109 W/m–°C.

5) The figure shows the face and interface temperature of a composite slab of four layers of two
materials having identical thickness. Under steady state condition, find the value of temperature θ.

PART 2 : CHEMISTRY

SECTION-I

1) A hydrate of magnesium iodide has a formula MgI2.xH2O. If 1.055 g sample is heated to a constant
weight of 0.695 g. What is the value of x ?

(A) 2
(B) 4
(C) 6
(D) 8

2)

Moles of K2Cr2O7 used to oxidise 1 mol Fe0.92O to Fe+3 are

(A)

(B)

(C)

(D)

3) 1 mole of an ideal gas at 300K is allowed to expand reversibly and isothermally from 5 L to 10 L.
The work done is [Given : ln2 = 0.7]

(A) –210 R
(B) 210 R
(C) –300 R
(D) –400 R

4) Molar heat capacity of water in equilibrium with ice at constant pressure is

(A) zero
(B) ∞
(C) 40.45 kJ K–1 mol–1
(D) 75.48 JK–1 mol–1

5) In which of the following reaction product formation is favoured by decrease in temperature and
pressure

(A)
CO2(g) + C(s) 2CO(g); ΔHº=172.5kJ

(B)
CO(g) + 2H2(g) CH3OH(l); ΔHº= – 21.7kJ

(C)
2O3(g) 3O2(g); ΔHº = –285 kJ

(D)
H2(g) + F2(g) 2HF(g) ΔHº = –541 kJ

6)

Assume that the decomposition of HNO3 is

and the reaction approaches equilibrium at 400K & 30 atm pressure. At equilibrium the partial
pressure of HNO3 is 2atm. Find KC at 400 K
(R = 0.08 ℓ – atm/K–mol)

(A) 4
(B) 8
(C) 16
(D) 32

7) 0.1 Mole of CH3NH2(Kb = 5 × 10–4) is mixed with 0.08 mole of HCl and diluted to 10 litre, what will
be the OH– concentration in the solution -

(A) 4.25 × 10–4 M

(B) 1.25 × 10–4 M
(C) 7.9 × 10–5 M
(D) 2.5 × 10–4 M

8) What is the minimum pH necessary to cause a precipitate of Pb(OH)2 (Ksp = 1.2 × 10–5) to form in
a 0.12 M PbCl2 solution?

(A) 12.4
(B) 10.8
(C) 12.0
(D) 11.1

9) Dipole moment of is 1.5 D. The dipole moment of :

(A) 2.35 D
(B) 1 D
(C) 1.5 D
(D) 3 D

10) Given that (at T = 298 K)

Cu(s) | Cu2+ (1.0 M) || Ag+ (1.0 M) | Ag(s) Eºcell = 0.46 V
Zn(s) | Zn2+ (1.0 M) || Cu2+ (1.0 M) | Cu(s) Eºcell = 1.10 V
Then Ecell for
Zn | Zn2+ (0.1 M) || Ag+ (1.0 M) | Ag at 298 K will be

(A) 1.59 V
(B) 1.53 V
(C) 2.53 V
(D) cannot be calculated due to insufficient data

11)

Calculate Ecell (in volts) for given cell :

Cr(s) | Cr3+ (10–2 M) || Fe2+ (10–3 M) | Fe(s)
E°cell = 1.06 V

(A) 1.01 V
(B) 2.01 V
(C) 3.01 V
(D) 0.01 V

12) IUPAC name of following compound is

(A) N-methyl-N-ethyl cyclobutanamide
(B) N-ethyl-N-methyl cyclobutanamide
(C) N-ethyl-N-methyl cyclobutane carboxamide
(D) N-methyl cyclobutyl propanamide

13)

The correct electron affinity order is

(EA = –ΔHEG) :-

(A) N < O < F

(B) N < F < O
(C) F < O < N
(D) O < F < N

14) The first ionization energy of magnesium is smaller as compared to that of elements X and Y, but
higher than that of Z. the elements X, Y and Z, respectively, are :

(A) chlorine, lithium and sodium

(B) argon, lithium and sodium
(C) argon, chlorine and sodium
(D) neon, sodium and chlorine

15) Molecule in which all bond lengths are unaffected due to back bonding :

(A) BF3
(B) B(OMe)3
(C) N(SiH3)3
(D) None of these

16)

[SiF6]–2 is known where as [SiCl6]–2 not because

–2 +4
(A) In [SiCl6] interaction between lone pair of chloride ion and Si is very strong
–2
(B) In [SiCl6] back bonding is not possible
(C) Six large chloride ions cannot be accomodated around Si+4 due to limitation of its size
(D) Si has no vacant orbital for accepting lone pair

17) Which of the following complex is paramagnetic as well as square planar –

2–
(A) [NiCl4]
3–
(B) [Cu(CN)4]
0
(C) [Co(dmg)2]
2–
(D) [PtBr4]
18)

Compare C–O & M–C bond length in the following complexes.

(a) [M(CO)x]2+ (b) [M(CO)x]+
0
(c) [M(CO)x] (d) [M(CO)x]–

(e) [M(CO)x]2–
(A) for C–O a < b < c < d < e ; for M–C a > b > c > d > e
(B) for C–O a > b > c > d > e ; for M–C a > b > c > d > e
(C) for C–O a > b > c < d < e ; for M–C a < b < c > d > e
(D) for C–O a > b > c > d > e ; for M–C a < b < c < d < e

19) Which of the following forms stable +4 oxidation state ?

(A) La(Z = 57)

(B) Eu(Z = 63)
(C) Gd(Z = 64)
(D) Ce(Z = 58)

20) The correct trend of |E.A.| is:

+ +
(A) NO < N2
(B) N+ < O+
+ +
(C) N2 < N
(D) O+ < NO+

SECTION-II

1) 1.0 mole of an ideal gas, initially present in a 2.00 L insulated cylinder at 300 K is allowed to
expand against vaccum to 8.0 L. ΔSuniverse for the process is _____ cal/K-mole.
(Round off answer to nearest integer value).

2) The equilibrium constant Kc at 298 K for the reaction A + B ⇌ C + D is 100. Starting with an
equimolar solution with concentrations of A, B, C and D all equal to 1M, the equilibrium
concentration of D is_____ × 10–2 M. (Nearest integer)

3) A solution is prepared by mixing two aqueous solutions of 50 ml, 0.2 M HA(aq) and 50 ml, 0.2 M
HB(aq) at 25ºC. The POH of the solution will be :
(Given : Ka(HA) = 5 × 10–9, Ka(HB) = 1.25 × 10–9)

4) Calculate the solubility of AgCN in a buffer solution at pH = 3.0

Given : Ksp of AgCN of HCN . If the solubility of AgCN is ,
then x is
5) Which of the following species are planar and polar?
H2O, CO2 , BF3 , BF2Cl , NH3 , CH4 , PCl5 , SF6 , XeF4

PART 3 : MATHEMATICS

SECTION-I

1) A rod of length 12 cm moves with its ends always touching the co-ordinate axes. Then find the
locus of a point P on the rod, which is 3 cm away from the end which is in contact with the x-axis.

(A)

(B)

(C)

(D)

2) If the normals from any point to the parabola cut the line x = 2 in points whose ordinates
are in A.P., then the slopes of tangents at the co-normal points are in

(A) H.P.
(B) GP.
(C) A.P.
(D) None of these

3) If (h, k) is a point on the axis of parabola from where three

distinc normals can be drawn, then

(A) h > 2
(B) h < 4
(C) h > 8
(D) h < 8

4) If eccentricity of ellipse is , then latus rectum of ellipse is -

(A)

(B)
(C)

(D)

5) If the eccentricity of the hyperbola sec2 α = 5 is times the eccentricity of the ellipse
, then a value of α is

(A) π/6
(B) π/4
(C) π/3
(D) π/2

6) If circumference of circle x2 + y2 + 8x + 8y – b = 0 is bisected by circle x2 + y2 – 2x + 4y + a = 0

then (a + b) is equal to

(A) 50
(B) 56
(C) –56
(D) –34

7) If x2 + y2 = 9 and x2 + y2 – 8x – 6y + n2 = 0 have exactly two common tangents then number of

integral values of n is

(A) 2
(B) 8
(C) 9
(D) 10

8) The number of integers in the range of m for which point (m,1) lies in the smaller region enclosed
by x2 + y2 – 3x + 1 = 0 and 2x – y = 2 is

(A) 0
(B) 1
(C) 2
(D) 3

9) Let S = {(x,y)| x2 + 2xy + y2 – 3x – 3y + 2 = 0}, then S

(A) consists of two coincident lines.

(B) consists of two parallel lines which are not coincident.
(C) consists of two intersecting lines.
(D) is a parabola.

10) The straight line ax + by = 1 makes chord with the curve px2 + 2axy + qy2 = r, which subtends a
right angle at the origin. Then
(A)
(B)
(C)
(D)

11) If the lines and y = kx + 6 are inclined at an angle to each other, then
the value of k will be

(A) 1
(B) 2
(C) –1
(D) –2

12) 5 - digit numbers are to be formed using 2, 3, 5, 7, 9 without repeating the digits. If p be the
number of such numbers that exceed 20000 and q be the number of those that lie between 30000
and 90000, then q:p is

(A) 6:5
(B) 4:3
(C) 5:3
(D) 3:5

13) A rack has 5 different pairs of shoes. The number of ways in which 4 shoes can be chosen from
it, so that there will be no complete pair is :

(A) 1920
(B) 200
(C) 110
(D) 80

14) The total number of ways in which six '+' and four '-' signs can be arranged in a line such that no
two '-' signs occur together is

(A) 15
(B) 25
(C) 45
(D) 35

15) Value of (nC0)2 + 3(nC1)2 +...+(2n–1)(nCn–1)2 + (2n + 1) (nCn)2 is

(2n–1)
(A) C(n–1)
(2n–1)
(B) Cn
2 2n
(C) n ( Cn)
2n
(D) (n+1)( Cn)
16) The value of the expression is equal to

47
(A) C5
52
(B) C5
52
(C) C4
49
(D) C4

17) The value of (21C1 – 10C1) + (21C2 – 10C2) + (21C3 – 10C3) + (21C4 – 10C4) + .... + (21C10 – 10C10) is

(A) 220 – 210

(B) 221 – 211
(C) 221 – 210
(D) 220 – 29

18) Let p(x) be the cubic polynomial 7x3 – 4x2 + K. Suppose the three zeroes of p(x) form an
arithmetic progression. Then the value of K, is

(A)

(B)

(C)

(D)

19) The least integral value α of x such that , satisfies

(A) α2 – 7α + 6 = 0
(B) α2 + 3α – 4 = 0
(C) α2 + 5α – 6 = 0
(D) α2 – 5α + 4 = 0

20) For every x ∈ R, the polynomial x8 – x5 + x2 – x + 1 is -

(A) positive
(B) never positive
(C) positive as well as negative
(D) negative

SECTION-II
1) Sum of the series up to infinite terms is equal to

2) If & , then is equal to

3) Let a, b and c be positive real numbers. If the least value of can be expressed as

(where p and q are relatively prime) then (p + q) is :

4) Given that , then the value of is equal to

5) The sum of all values of x satisfying the equation log9log3 = 0 is

 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C C D D B C B C A A A B B C B A C B D C

SECTION-II

Q. 21 22 23 24 25
A. 6 5 60 3 5

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D C A B C D B C C A A C A C D C C A D A

SECTION-II

Q. 46 47 48 49 50
A. 3 182 3 4 2

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B A B B C C A B C C D D D D C A D C A

SECTION-II

Q. 71 72 73 74 75
A. 1 4 9 125 3
 SOLUTIONS

PART 1 : PHYSICS

1)

Sol.
L = m1vr + m2vr + Iω = (m1 + m2)r2ω + Iω

2) acm = 0, vcm may not be zero.

3)

Consider total mass of square = 4m

4)

The angular displacement of the particle in t = 1 sec is

∴ The magnitude of impulse by centripetal force in t = 1 second is

= change in momentum = mv = .

5)

After 1st collision, speed = (2 × 5) + 3 = 13 m/s

After 2nd collision, speed = (2 × 3) + 13 = 19 m/s
Ans. 19 m/s

6) vmax = ωA ⇒ =

⇒ A2 – y2 = ⇒ y2 = ⇒y=

7)

Tagential acceleration is rα.

8) Let the speed of bullet be v. Let the common velocity of the bullet and bob after the bullet is

imbedded into the bob is V. By principle of conservation of momentum

The string becomes loose and bob will go up with a deceleration, g = 10 m/sec2. As it comes to

rest at a height 1.8 m we have v2 = u2 + 2as, or v = 60 m/sec.

9)

10) Work done = Δ K.E.

Maximum work is required which have maximum K.E.

K.E. = ⇒ Minimum I corresponds to maximum K.E. since bodies have same angular
momentum.

11) In any motion, the acceleration vector must be in the direction of resultant force.
So = Facos0° ⇒ (+ve)

12)
Fx = – = sin (x + y) Fy = – = sin (x + y)

Fx = sin(x + y)](0, π/4) = Fy = sin(x + y)](0, π/4) =

∴=

13) Work done depends on displacement of point of application of force and not on
displacement of centre of mass. Hence statement-2 is false.

14)

Moment of inertia of the disc of mass M and radius R

⇒
And for the ring of same mass but radius 2R,
= M(2R)2
⇒ k2 = 2R

Thus,

15)

F – mg

F≥

16)

17) By conservation of angular momentum about point on ground

muR + o =

muR =

18)

Acceleration

then

Extension in 'dx' element

Total extension

19) Question Explanation:

Two rods A and B of length ℓA and ℓB have coefficients of linear expansion αA : αB = 1 : 4. If the
difference between the lengths of the two rods is to be independent of temperature. We need
to find ℓA : ℓB

Concept:
This question is based on Thermal Expansion (linear).

Solution:

ℓA(1 + αAΔT) – ℓB(1 + αBΔT) = ℓA – ℓB

ℓAαAΔT – ℓBαBΔT = 0

ℓA : ℓB = 4 : 1

Final Answer:
The correct option is (4).

20)

Question Explanation:
The problem involves mixing m grams of ice at 0°C with 2m grams of water at 100°C in a
container. The goal is to determine the final temperature of the mixture.
Concept:
This question is based on Calorimetry, Low of mixture.

Solution:
m × 80 + m × 1 × (T – 0)
= 2m × 1 × (100 – T)
80 + T = 200 – 2T
3T = 120
T = 40ºC

Final Answer:
The correct option is (3)

21) Let the particle is at P position particle first comes to rest when it reaches right extreme

position then by phasor diagram angle moved by particle is

Time taken

hence

22)

Δl = αℓΔT

= αΔT

σb = = = yαΔT ⇒ ΔT = = = 200°C]

23)

Conceptual

24)

Let T = 100º C
& T0 = 50ºC
 0
Heat = (T – T ) (KS + KB) × 10 × 60

= (100 – 50) × × (46 + 109) × 10 × 60

= 300 J

25) at steady state

θ = 5°C

PART 2 : CHEMISTRY

26) × x × 18 = (1.055 – 0.695 )

⇒ x = 8 Ans.

27) Fe0.920 → Fe+3

nf = = 0.76
no. of geq K2Cr2O7 = no. of geq Fe0.92O
moles × 6 = 1 × 0.76

28)

W = –nRTln = –1 × R × 300 ln
= – 300 R × 0.7 = –210 R

29) Question Explanation:

Calculate molar heat capacity at constant pressure when water and ice in equilibrium.

Concept:
This question is based on Molar heat capacity at const P.

Solution:
Water in equilibrium with ice at constant pressure (eg. 1 bar) this is exist at specific constant
temperature the normal freezing point which is 0°C (or 273 K).
So ΔT = 0 (temperature remains constant)

Cp,m = ∞
Final Answer:
The correct option is (2)

30) Question Explanation:

Which equilibrium favoured by low temperature and low pressure.
Concept:
This question is based on Le-chatelier's principle.

Solution:
Temp.↓ equilibrium shift forward for exothermic reaction where heat is released
Pressure ↓ equilibrium shift forward when number of gaseous moles increases on product
side

for 2O3(g) 3O2(g); ΔHº = –285 kJ

Low temperature & low pressure is favoured for forward direction.

Final Answer:
The correct option is (3).

31)

32)
Initially 0.1 mole 0.08 mole
At eq. 0.1 – 0.08 – 0.08 mole
= 0.02 mole

(0.02–x) mole (0.08+x) mole x mole

(assuming x << 0.02)

33)

∴ POH = 2

34) = 0; due to symmetry

So for is equal to

35)

...(1)
...(2)
(1) and (2)

36)

2Cr(s) + 3Fe2+ → 2Cr3+ + 3Fe

Ecell = 1.06 –

37) Question Explanation:

To write IUPAC name of the given compound.

Concept:
This question is based on Nomenclature of cyclic compounds.

Solution:

N-ethyl-N-methyl cyclobutane carboxamide.

Final Answer:
The correct option is (3)

38)

N ⇒ 1s2 2s2 2p3

O ⇒ 1s2 2s2 2p4
F ⇒ 1s2 2s2 2p5
N<O<F

39) The 1st IE order of 3rd period is

Na < Al < Mg < Si < S < P < Cl < Ar
X & Y are Ar & Cl
Z is sodium (Na).

40) Bond length decreases due to back- bonding.

41)

[SiCl6]2– not exist due to steric repulsion beween Cl – Cl atom.

42) (A) [NiCl4]2– ⇒ Tetrahedral, paramagnetic

(B) [Cu(CN)4]3– ⇒ Tetrahedral, diamagnetic
0
(C) [Cu(dmg)2] ⇒ Square planar, paramagnetic
(D) [Pt(Br)4]2– ⇒ Square planar, diamagnetic

43)
Negative charge on metal cation ∝ Synergic Bonding
Synergic Bonding ∝ M – C Bond Strength

44) O.S.
0
(1) La57 ⇒ 4f ⇒ +3
7 2
(2) Eu63 ⇒ 4f 6s ⇒ + 2, + 3
7 1 2
(3) Gd64 ⇒ 4f 5d 6s ⇒ + 3
(4) Ce58 ⇒ 4f1 5d1 6s2 ⇒ + 3, + 4

45) E.A. values are:

NO+ = 9.25 eV
N2+ = 15.56 eV
N+ = 14.6 eV
O+ = 13.6 eV

46) This is adiabatic free expansion

w = 0 ; q = 0 so ΔU = 0 i.e. T1 = T2 = 300 K

ΔSsys = nR ln = 1 × R ln = 2.8 cal/K-mole

ΔSsurr. = =0
ΔSuniv. = ΔSsys + ΔSsurr. = 2.8 cal/K-mole.

47)

A + B ⇌ C + D : Keq = 100
1M 1M 1M 1M
First check direction of reversible reaction.

Since QC = ⇒ reaction will move in forward direction to attain equilibrium

state.
⇒ A + B ⇌ C + D : Keq = 100
to 1 1 1 1
teq. 1–x 1–x 1+x 1+x

Now : Keq = 100 =

(i)
⇒ 10 – 10x = 1+x
 ⇒ 11 x = 9

(ii)
⇒ –10 + 10x = 1 + x
⇒ –9x = –11

→ 'x' cannot be more than one, therefore not valid.

therefore equation concretion of (D) = 1 + x

= 1.8181 = 181.81 × 10–2

= 182 × 10–2

48)
[OH–] = 10–3
pOH = 3

49)

50) H2O and BF2Cl are planar and polar

PART 3 : MATHEMATICS

51)
PB = 9, AP = 3

52) Equation of the normal to the parabola is

Given by ...(i)
Since it intersects x = 2 we get
let the three ordinates be in A.P.
..(ii)
From equation (i) we have

Hence equation (ii) reduces to

are in G.P.

Hence slopes of tangents are in G.P.

53) In the given equation of parabola the focus is (1,1) and equation of directrix is
axis of parabola is y = x
Vertex of the parabola is (0,0). Let a is the distance between vertex and focus .
The distance of the point on the axis from, which three normal may be drawn will be at least
2a from the vertex which is equal to . So coordinates of the point nearest to the vertex
from which three normals may be drawn can be given as (2,2)
h > 2.

54) compare with

∴ a12 = (a2 + 1) & b12 = (a2 + 2)

∴
∴ a12 = b12 (1 – e2)
⇒ a2 + 1 = (a2 + 2) (1 – e2)

⇒ a2 + 1 = (a2 + 2)
⇒ 6a2 + 6 = 5a2 + 10
⇒ a2 = 4 ⇒ a = ±2

∴ Latus rectum =

55)

=1+ = 1 + cos2α
Similarly eccentricity of the ellipse
 is = sin2α; put
⇒ 1 + cos α = 3sin α ⇒ 2 = 4 sin2α
2 2

⇒ sin α =

56)

Circumference of circle is bisected by circle

, then radical axis passed through centre of C1
pass through (–4, –4)
⇒

57)

Ans is (C)

9 values

58) S1 < 0 ⇒ m2 – 3m + 2 < 0 ⇒ m ∈ (1,2)

hence,

59) Δ = 0, It represent pair of Straight Lines

let x2+2xy+y2–3x–3y+2 = (x+y+k1) (x+y+k2)
On comparing coefficient, k1 + k2 = –3
k 1 + k2 = 2
solving k1 = –1 ; k2 = –2
or k1 = –2 ; k2 = –1
Hence, lines are parallel.

60) px2 + 2axy + qy2 – r(ax + by)2 = 0

coefficient of x2 + coefficient of y2 = 0
(p – ra2) + (q – rb2) = 0
61)

tan60º =

2 k + 3k + =2+ –k
2 k + 4k = 2

k=
or
–2 k– 3k– =2+ –k
–2 k–2k = 2+2
–2(1+ )k = 2(1+ )
k = –1

62) p = 5! = 120
q = 3C1 x 4! =72 (digit 3, 5 or 7)

63) Select any 4 pairs and one shoe from each pair
= 5C4.2C1.2C1 2C1 2C1 = 80

64)

No. of ways of arrangement of 6 (+) signs =1

no. of ways of arrangement of 4(-) signs

in gaps
= 35
total no. of ways
= 35

65) S = (1)(nC0)2 + 3(nC1)2 +....+(2n–1)(nCn–1)2 + (2n + 1) (nCn)2 .... (1)

S = (2n + 1)(nC0)2 + ...... +(1)(nCn)2 .... (2)
(1) + (2)
2S = (2n + 2) (nC02 + nC12 + .... + nCn2)
S = (n + 1) (2nCn)

66) 47C4 + 51C3 + 50C3 + 49C3 + 48C3 + 47C3 = 52C4

67) ⇒ (21C1 + 21C2 +21C3 + ------+ 21C10) – (10C1 +10C2 + -----10C10) ....(1)
we know that
(21C0 + 21C1 + ----- + 21C10) + 21C11 +----+ 21C21 = 221
⇒ 21C1 + 21C2 + ------ + 21C10 = 220 – 1
So from (1)
⇒ (220 – 1) – (210 – 1)
⇒ 210(210 – 1)

68)

Let zeroes of p(x) are (a – d), a and (a + d)

So, a–d+a+a+d

⇒
(a – d) (a + d) + (a – d)a + (a + d)a = 0
a2 – d2 + a2 – da + a2 + da = 0
3a2 = d2

(a – d) (a + d)a = K
(a2 – d2)a = K

69)
x ∈ (–7, 2) ∪ (5,∞)
least integral value is –6
which is satisfied α2 + 5α – 6 = 0

70) x8 – x5 + x2 – x + 1
Case 1 x < 0, x5 (x3 – 1) + x(x – 1) + 1 = +ve
Case 2 0 < x < 1, x8 + x2 (1 – x3) + (1 – x) = positive
Case 3 x > 1, positive
So polynomial is positive

71)

T1 + T2 + T3 ... + Tn
then sum of ∞ terms = 1

72)

a=b+ ⇒

73)

Apply A.M. > G.M. on , we get

∴
Hence, p + q = 5 + 4 = 9

74)

= 125

75)

3x –5 = 9 + (x – 2) –
2x = 12 –
x=
x–6=–
x2 + 36 – 12x = 9(x–2)
x2 – 21x + 54 = 0
sum = 3