Chemistry
IMPORTANT TOPIC
CHAPTER-1
1. Explain Henry’s law with its limitations and uses.
2. Derive Raoult’s law for non-volatile solute and volatile convent
3. Explain Raoult’s law for volatile solute and volatile solvent.
4. Distinguished between ideal and non-ideal solution
5. Give types of non ideal solution.
6. Write a note on abnormal molar mass and van’t Hoff factor.
7. Factors affecting solubility of gas in liquid.
8. Numericals (Example-5,9,12,13) (Exe.4,6,21,27,29,32,40)
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CHAPTER-2
1. Explain Faraday’s laws of electrolysis.
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2. What information do you obtained from emf series?
3. Give difference between Electrochemical cell and Electrolysis cell.
4. Ionic conductivity depends on which factors?
5. Explain kohlransch’s law of independent migration of ions.
6. Explain dry cell (with reactions)
7. Explain lead storage cell. (with reactions)
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8. Explain Hydrogen fuel cell (with reactions)
9. Explain corrosion phenomenon with reactions
10. Numericals(Example-1,3,4,5,7,8,9,10) (Exe.2,12,13,15,16)
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CHAPTER- 3
1. Explain : Molecularity
2. Derive formula of rate constant and half life period for zero order and first order
reaction.
3. Explain pseudo first order reaction.
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4. Explain effect of temperature on rate constant.
5. Explain collosion theory.
6. Distinguish between molecularity and order of reaction.
7. Exercise-3,6,9,11,14,17,18,20,21,25,30
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8. Numericals(Example-2,3,4,5,6,8,10,11
CHAPTER -4
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1. Explain catalytic properties of transition elements.
2. Zn,Cd and Hg is not work as a transition metal.
3. Write short note on ‘‘Alloys’
4. Write a note on interstitial compounds.
5. Atomic radius decreases from Sc to V while atomic radii of Cr to Cu is almost similar
and instead of decreasing atomic radius of Zn is found to be increasing. Explain.
6. Explain preparation, properties and uses of KMnO4 and K 2Cr2O7
7. Give comparison of Actinoils with Lanthanoils
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8. Give applications of d and f-block elements.
9. Calculate magnetic moments : Fe2+
CHAPTER 5
1. Explain crystal field theory of octahedral complexes
2. Give postulates of Werner’s theory.
3. Explain Geometrical isomerism of co-ordination compounds.
4. Distinguish between double salt and complex salt.
5. Explain optical isomerism in complex compounds.
6. Give IUPAC of the following:
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i) Na2 [ Fe( NO)(CN )5 ] or sodium nitro preside.
ii) [Cr ( NH 3 )6 ][Cr ( SCN )6 ]
iii) Fe3[ Fe(CN3)6 ]3
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iv) [Cr (OX )3 ]
7. Explain geometrical structures and magnetic properties of [Fe (CN)6]4– ,
[k3[fe(CN)6],[Ni (CN)4]2–
8. Explain different types of structural isomerism with one example of each.
9. Give importance and applications of complex compounds.
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1. Give classification of halogen attached to carbon possessing sp3 hybridisation & sp 2
hybridisation.
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2. Write a note on sandmeyer reaction.
3. Write a note on i) Finkelstein reaction
ii) Swartz reaction
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4. Explain SN reaction
5. Explain SN 2 reaction
6. Write a note on i) Saytzeff rule(B-Elimination reaction).ii) Grignard reaction
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iii) Wurtz reaction
7. Explain : i) Wurtz – Fitting reaction
ii) Fitting reaction
8. Give preparation, properties & uses of CHCl3, DDT,CFC, CH2Cl2,CCl4.
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CHAPTER-7
1. Explain hydroboration – oxidation reaction.(With mechanism)
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2. Explain Acid catalysed reaction.
3. How to prepare alcohols by Grignard reagents?
4. Explain Oxidation of Alcohols.
5. Write a note on Lucas test.
6. Why aqueous solution of phenol is more acidic then alcohol?
7. Explain: (i) Dow process (ii) Cumene process
8. Write a note on: i) Williamson synthesis.
ii) Kolbe reaction iii) Reimer – Tiemann reaction
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9. Explain preparation of Ethers.
CHAPTER 8
1. Explain Aldol and cross aldol condensation.
2. Explain: i) Wolff – kishner reduction ii) Clemmensen reduction
iii) Tollens test iv) Iodoform test v) Cannizarro reaction
3. Give mechanism of nucleophilic addition reaction.
4. Explain relative reactivities of aldehyles and ketones
5. Explain nuclelphilic addition of alcohols .
6. Explain: (i) Popoff’s rule (ii) HVZ reaction (ii) Fehling test
7. How to prepare benzoic acid from isopropyl benzene, benzamide and phenyl
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magnesium bromide (only reactions)
8. Why carboxylic acids are stronger acids than alcohols and phenols.
9. Give reactions of carboxylic acids involving cleavage of O – H bond (give one
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example of each)
10. Give reactions of carboxylic acid involving cleavage of C – OH bond (give one
example of each)
CHAPTER 9
1. Give industrial production of aniline
2. Explain (i) Gabriel – phthalimide synthesis
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3. Write reactions to prepare benzene, cyano benzene iodobenzene and flouro benezene
from benzene diazonium chloride.
4. Write a note on: i) Azo coupling reaction
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ii) Gattarmann reaction
iii) Sandmeyer reaction
5. How can you prepare the following from aniline?
i) Iodo benzene ii) Fluoro benzene
iii) Nitro benzene iv) Phenol
v) Benzene vi) Benzonitrite
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6. Why boiling point of amines are less than that of alcohols?
7. Why boiling point and solubility of 1° are more compared to 2’ and 3’ amines.
8. Write a note on Carbyl amine reaction
CHAPTER 10
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1. Explain classification of carbohydrates.
2. Preparation and Chemical reaction of glucose.
3. Draw the cyclic structures of (i) D glucose (ii) D Fructose
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4. Why sucrose is a non-reducing sugar?
5. What is vitamins ? Explain with examples and classification.
6. Explain structure of Nucleic acid.
7. On what basis you can say that glucose should have a cyclic structure?
8. Give importance of carbohydrates.
9. Give reasons for denaturation of proteins.
10. Describe the double helix structure of DNA.
11. Explain the primary, secondary, tertiary and quaternary structure of protein.
12. What is Mutarotation ? Explain.
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