THE H B KAPADIA NEW HIGH SCHOOL

CHAPTER - 1 to 8 STD 11 Date : 06/01/26

//X
Practice Assignment
•
A Write the answer of the following questions. [Each carries 1 Mark] [25]
1. The mass of one atom of C12 = ..........
(A) 1.992648 ´ 1023 gm (B) 6.022 ´ 1023 gm
(C) 1.992648 ´ 10–23 gm (D) None of these
2. If angular momentum quantum number l = 3 then give possible values of magnetic quantum
number m.
(A) 0, 1, 2 (B) 0, ±1, ±2, ±3 (C) 0, 1, 2, 3 (D) ±1, ±2, ±3
3. Which of the following elements has the highest ionisation energy
(A) [Ne]3s2 3p1 (B) [Ne]3s2 3p2 (C) [Ne]3s2 3p3 (D) [Ar]3d10 4s24p2
4. Which one of the following constitutes a group of the isoelectronic species ?
(A) N2, O 2– , NO +, CO (B) C22– , O 2– , CO, NO (C) NO+, C22–, CN– , N2 (D) CN– , N2 , O22–, C22–
5. The standard Gibbs energy change at 300 K for the reaction 2A ƒ B + C is 2494.2 J. At a given time,
1 1
the composition of the reaction mixture is [A] = , [B] = 2 and [C] = . The reaction proceeds in
2 2
the : [R = 8.314 J/K/mol, e = 2.718]
(A) forward direction because Q > Kc (B) reverse direction because Q > Kc
(C) forward direction because Q < Kc (D) reverse direction because Q < Kc
6. If pH of a saturated solution of Ba(OH)2 is 12, the value of its K(Sp) is :
(A) 4.0 ´ 10–6 M3 (B) 4.0 ´ 10–7 M3 (C) 5.0 ´ 10–6 M3 (D) 5.0 ´ 10–7 M3
7. The Ksp of Ag 2CrO 4 , AgCl, AgBr and AgI are respectively, 1.1 ´ 10–12 , 1.8 ´ 10–10 , 5.0 ´
10–13, 8.3 ´ 10–17. Which one of the following salts will precipitate last if AgNO3 solution is added
to the solution containing equal moles of NaCl, NaBr, NaI and Na2CrO4 ?
(A) AgI (B) AgCl (C) AgBr (D) Ag2CrO4
8. Consider the following compounds : KO2, H2O2 and H2SO4
The oxidation states of the underlined elements in them are respectively
(A) +2, –2 and +6 (B) +1, –2 and +4 (C) +4, –4 and +6 (D) +1, –1 and +6
9. The increasing order of stability of the following free radicals is ...... . [AIEEE-2006]
& <(CH ) C& <(C H ) CH
(A) (CH ) CH & < (C H ) C&
3 2 3 3 6 5 2 6 5 3
(B) (C6H5 )3 C& < (C H ) CH
& <(CH ) C & &
6 5 2 3 3 < (CH3 )2 CH
& <(C H ) C
(C) (C6H5 )2 CH & & &
6 5 3 <(CH3 )3 C < (CH3 )2 CH
(D) (CH ) CH & <(CH ) C & < (C H ) C& < (C H ) CH
&
3 2 3 3 6 5 3 6 5 2
10. How would you explain the fact that the first ionization enthalpy of sodium is lower than that of
magnesium but its second ionization enthalpy is higher than that of magnesium ?
11. Calculate the standard enthalpy of formation of CH3OH(l) from the following data :
3 –
○
CH3OH(l) + O2(g) Æ CO2(g) + 2H2O(l) ; DrH = –726 kJ mol–1
2
–
○
C(graphite) + O2(g) Æ CO2(g) ; DrH = –393 kJ mol–1

1 –
○
O(g) Æ H2O(l) ; Df H = –286 kJ mol–1
H2(g) +
2
12. Comment on the thermodynamic stability of NO(g), given :

1 1 –
○
N 2(g) + O2(g) Æ NO(g) ; DrH = 90 kJ mol–1
2 2
1 –
○
NO(g) + O2(g) Æ NO2(g) ; DrH = –74 kJ mol–1
2
 1 1 –
○
N 2(g) + O2(g) Æ NO(g) ; DrH = 90 kJ mol–1
2 2
1 –
○
NO(g) + O2(g) Æ NO2(g) ; DrH = –74 kJ mol–1
2
13. Indicate the s and p bonds in the following molecules :
(i) C6 H6 (ii) C6 H1 2
(iii) CH2 Cl2 (iv) CH2 = C = CH2
(v) CH3 NO2 (vi) HCONHCH3
14. The formula for calculation of percentage of nitrogen in NH3 is ...........

7 ´ 100 7 ´ 100 3 ´ 100 14 ´ 100

(A) (B) (C) (D)
14 17 14 17
15. Normality of 4.9 gm/lit of H2SO4 is ......... .
(A) 0.2 (B) 20 (C) 10 (D) 0.1
16. 1.520 g of the hydroxide of a metal on ignition gave 0.995 g of oxide. The equivalent weight of metal is
(A) 1.520 (B) 0.995 (C) 19.00 (D) 9.00
17. What is the weight of one molecule of CO2 ? ([Link] of CO2 = 44 g / mole)
(A) 3.37 ´ 10–23 g (B) 7.31 ´ 10–23 g (C) 2.1 ´ 10–23 g (D) 3.41 ´ 10–23 g
18. The correct increasing order of energy is.....
(A) ns, np, (n – 1)d, (n – 1)f (B) ns, (n – 1)p, (n – 2)d, (n – 2)f
(C) ns, np, (n – 1)d, (n – 2)f (D) ns, (n – 2)d, np, (n – 1)f
19. Which one is correct for electron in 4f orbital ?
n l m s n l m s
1 1
(A) 4 3 +4 + (B) 4 4 –4 –
2 2
1 1
(C) 4 3 +1 + (D) 3 2 –2 +
2 2
20. The electronic configuration of Gadolinium (atomic number 64) is .....
(A) [xe] 4f 8 5d9 6s2 (B) [xe] 4f 7 5d1 6s2 (C) [xe] 4f 9 5d5 6s2 (D) [xe] 4f 6 5d2 6s2
21. The correct order of atomic radii is.....
(A) Na < Mg < Al < Si (B) Si < Al < Mg < Na (C) Na < Al < Si < Mg (D) Al < Si < Mg < Na
22. In which of the following pairs, the two species are iso-structure ?
(A) SO 2– –
3 and NO3 (B) BF3 and NF3 (C) BrO–3 and XeO3 (D) SF4 and XeF4
23. The angular shape of ozone molecule (O3) consists of :
(A) 1 sigma and 2 pi bonds (B) 2 sigma and 2 pi bonds
(C) 1 sigma and 1 pi bonds (D) 2 sigma and 1 pi bonds
24. The correct order of increasing bond angles in the following triatomic species is :
(A) NO2– < NO2+ < NO2 (B) NO2– < NO2 < NO2+
+
(C) NO2 < NO2 < NO2 – (D) NO2+ < NO2– < NO
25. For the gas phase reaction, PCl5(g) ƒ PCl3(g) + Cl2(g)
Which of the following conditions are correct ?
(A) DH = 0 and DS < 0 (B) DH > 0 and DS > 0
//X (C) DH < 0 and DS < 0 (D) DH > 0 and DS < 0
•
B Write the answer of the following questions. [Each carries 2 Marks] [22]
26. Calculate the amount of carbon dioxide that could be produced when,
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
27. Electrons are emitted with zero velocity from a metal surface when it is exposed to radiation of
wavelength 6800 Å. Calculate threshold frequency (v0) and work function (W0) of the metal.
28.
4.4) Explain the structure of CO2 .
29. Calculate the enthalpy change for the process CCl4(g) + C(g) + 4Cl(g) and calculate bond enthalpy
of C – Cl in CC4(g).
–
○
DvapH (CCl4) = 30.5 kJ mol–1
–
○
Df H (CCl4) = –135.5 kJ mol–1
–
○
DaH (C) = 715.0 kJ mol–1
–
○
DaH (Cl2) = 242 kJ mol–1
–
○
where DaH is enthalpy of atomisation
30. For the reaction 2A(g) + B(g) Æ 2D(g)
–
○ –
○
DU = –10.5 kJ and S = –44.1 JK–1
–
○
Calculate DG for the reaction, and predict whether the reaction may occur spontaneously.
31. Calculate the entropy change in surroundings when 1.00 mol of H2O(l) is formed under standard
–
○
conditions. Df H = –286 kJ mol–1.
32. The equilibrium constant expression for a gas reaction is,
[NH3 ]4 [O2 ]5
Kc =
[NO]4 [H2O]6
Write the balanced chemical equation corres-ponding to this expression.
33. Write formulas for the following compounds :
(a) Mercury(II) chloride (b) Nickel(II) sulphate
(c) Tin(IV) oxide (d) Thallium (I) sulphate
(e) Iron(III) sulphate (f ) Chromium(III) oxide
34. Identify the functional groups in the following compounds.

CHO NH2

(a) (b) (c)

OMe
OH O OCH2CH2N(C2H5)2 CH = CHNO 2
35. 5) A microscope using suitable photons is employed to locate an electron in an atom within a
distance of 0.1 Å. What is the uncertainty involved in the measurement of its velocity ?
2.13) The mass of an electron is 9.1 ´ 10–31 kg. If its K.E. is 3.0 ´ 10–25 J, calculate its wavelength.
36.
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•
C Write the answer of the following questions. [Each carries 3 Marks] [24]
37. In three moles of ethane (C2H6) calculate the following :
(i) Number of moles of carbon atoms.
(ii) Number of moles of hydrogen atoms.
(iii) Number of molecules of ethane.
38. A 25 watt bulb emits monochromatic yellow light of wavelength of 0.57 mm. Calculate the rate of
emission of quanta per second.
4.2)
39. Write Lewis structure of Nitrite ion NO–21
40. Nitric oxide reacts with Br2 and gives nitrosyl bromide as per reaction given below :
2NO(g) + Br2(g)  2NOBr(g)
When 0.087 mol of NO and 0.0437 mol of Br2 are mixed in a closed container at constant
temperature, 0.0518 mol of NOBr is obtained at equilibrium. Calculate equilibrium amount of
NO and Br2.
41. One mole of H2O and one mole of CO are taken in 10 L vessel and heated to 725 K. At equilibrium
40% of water (by mass) reacts with CO according to the equation : H2O(g) + CO(g)  H2(g) + CO2(g)
Calculate the equilibrium constant for the reaction.
42. At 700 K, equilibrium constant for the reaction H2(g) + I2(g)  2HI(g) is 54.8. If 0.5 mol L–1 of HI(g)
is present at equilibrium at 700 K, what are the concentration of H2(g) and I2(g) assuming that we
initially started with HI(g) and allowed it to reach equilibrium at 700 K ?
43. Write a note on s-block elements of periodic table.
13R) Fe+2 in acidic medium converts Cr2O–72 ion into Cr+3 ion by reduction Fe+3 is obtained, balance these
44.
//X redox reaction with equation.
•
D Write the answer of the following questions. [Each carries 4 Marks] [4]
45.
//X Give energy level diagram for NO calculate bond order and state magnetic property.
•
E Write the answer of the following questions. [Each carries 5 Marks] [25]
46. Reaction between N2 and O2– takes place as follows : 2N2(g) + O2(g)  2N2O(g) If a mixture of
0.482 mol N2 and 0.933 mol of O2 is placed in a 10 L reaction vessel and allowed to form N2O
at a temperature for which Kc = 2.0 × 10–37, determine the composition of equilibrium mixture.
47. Balance the following redox reactions by ion – electron method :
(a) MnO–4(aq) + I–(aq) ® MnO2(s) + I2(s) (in basic medium)
(b) MnO–4(aq) + SO2(g) ® Mn2+
(aq)
+ HSO–4(aq) (in acidic solution)
(c) H2O2(aq) + Fe2+(aq) ® Fe3+(aq) + H2O(l) (in acidic solution)

(d) Cr2O72– + SO2(g) ® Cr3+

(aq)
+ SO2–4(aq) (in acidic solution)
48. Balance the following equations in basic medium by ion-electron method and oxidation number
methods and identify the oxidising agent and the reducing agent.
(a) P4(s) + OH–(aq) ® PH3(g) + HPO–2(aq)
(b) N2H4(l) + ClO–3(aq) ® NO(g) + Cl–(g)
(c) Cl2O7(g) + H2O2(aq) ® ClO–2(aq) + O2(g) + H+
49. Give the IUPAC names of the following compounds :

(a) (b) CN

(c) (d)
Cl Br
O
(e) (f ) Cl2 CH CH2 OH
Cl H
50. Write a note on p-block elements of periodic table.
 THE H B KAPADIA NEW HIGH SCHOOL
CHAPTER - 1 to 8 STD 11 Date : 06/01/26
//X
Practice Assignment
•
A Write the answer of the following questions. [Each carries 1 Mark] [25]
1.

2.

3.

4.

5.

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7.

8.

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10.

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B Write the answer of the following questions. [Each carries 2 Marks] [22]
26.

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28.

29.

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31.

32.

33.

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35.

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C Write the answer of the following questions. [Each carries 3 Marks] [24]
37.

38.

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40.

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42.

43.

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D Write the answer of the following questions. [Each carries 4 Marks] [4]
45.
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E Write the answer of the following questions. [Each carries 5 Marks] [25]
46.

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47.

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