04-01-2026

1001CJM202033250011 JM

PART-1 : PHYSICS

SECTION-I

1) A coil of inductance 5H is joined to a cell of emf 6V through a resistance 10Ω at time t = 0. The
emf across the coil at time t = ln s is :-

(A) 3V
(B) 1.5 V
(C) 0.75V
(D) 4.5V

2) A circular loop wire of radius r rotates about the z–axis with angular velocity ω. The normal to the
loop is always perpendicular to the z–axis. At time t = 0, the normal is parallel to the y–axis. An
external magnetic field is applied. The EMF ε(t) induced in the loop is

(A)
(B)
(C)
(D)

3) Dimensional formula of magnetic flux is :-

(A) [ML2T–2A–1]
(B) [ML2T–2A–2]
(C) [MLT–2A–1]
(D) [MLT–2A–2]

4) A magnetic field B = (B0y / a) is into the plane of paper in the +z direction. B0 and a are positive
constants. A square loop EFGH of side a, mass m and resistance R, in x-y plane, starts falling under
the influence of gravity. Note the directions of x and y axes in the figure. The induced current in the
loop will be :-

(A)
, In CW direction

(B)
, In ACW direction

(C)
, In ACW direction

(D) , In ACW direction

(where v is the velocity at time t)

5) Power factor of an L-R series circuit is 0.6 and that of a C–R series circuit is 0.5. If the element (L,
C, and R) of the two circuits are joined in series the power factor of this circuit is found to be 1. The
ratio of the resistance in the L-R circuit to the resistance in the C–R circuit is :-

(A) 6/5
(B) 5/6

(C)

(D)

6) A wire bent as a parabola y = 4x2 is located in a uniform magnetic field of 2T, perpendicular to xy
plane. At t = 0, a connecting bar AB starts sliding from origin with constant acceleration of 2
m/s2 along +ve y-axis. Find the emf (in volts) induced in the loop thus formed at y = 2m.

(A) 8 V
(B) 9 V
(C) 10 V
(D)

7) In an oscillation of L-C circuit, the maximum charge on the capacitor is Q0. The charge on the
capacitor, when the energy is stored equally between the electric and magnetic field is :-

(A)

(B)
(C)

(D)

8) In the adjoining ac circuit the voltmeter whose reading will be zero at resonance is :-

(A) V1
(B) V2
(C) V3
(D) V4

9) An alternating supply of 220V is applied across a circuit with resistance 22 Ω and impedance 44Ω.
The power dissipated in the circuit is :-

(A) 1100 Ω
(B) 550 Ω
(C) 2200 Ω
(D) (2200/3)Ω

10) A long solenoid has 1000 turns. When a current of 4A flows through it, the magnetic flux linked
with each turn of the solenoid is 4 × 10–3 Wb. The self inductance of the solenoid is :-

(A) 4H
(B) 3H
(C) 2H
(D) 1H

11) If the work done in blowing a bubble of volume V is W, then the work done in blowing the bubble
of volume 2V from the same soap solution will be :-

(A) W/2
(B)
(C)
(D)

12) A space 2.5 cm wide between two large plane surfaces is filled with oil. Force required to drag a
very thin plate of area 0.5 m2 just midway the surfaces at a speed of 0.5 m/sec is 1 N. The coefficient
of viscosity in kg-s/m2 is :

(A) 5 × 10–2
(B) 2.5 × 10–2
(C) 1 × 10–2
(D) 7.5 × 10–2

13) A tube of length L is filled completely with an incompressible liquid of mass M and closed at both
ends. The tube is then rotated in a horizontal plane about one of its end with a uniform angular
velocity ω. Then the force exerted by the liquid at this other end is :-

(A) Mω2L

(B)
Mω2L

(C)
Mω2L
(D) 2Mω2L

14) A simple pendulum has time period T1. When the point of suspension moves vertically up
according to the equation y = kt2 where k = 1 m/s2 and t is time then the time period of the

pendulum is T2 then is

(A)

(B)

(C)

(D)

15) Oscillators A and B shown in figure are oscillating with same amplitude and energy. Respective

spring constants are mentioned in the figure. Then :-

(A)

(B)

(C)
(D)

16) The electric fields of two plane electromagnetic plane waves in vacuum are given by
and

At t = 0, a particle of charge q is at origin with a velocity (c is the speed of light in

vacuum). The instantaneous force experienced by the particle is :

(A)
(B)
(C)
(D)

17) Consider a water jar of radius R that has water filled up to height H and is kept on a
stand of height h (see figure). Through a hole of radius r(r < < R) at its bottom, the water leaks out
and the stream of water coming down towards the ground has a shape like a funnel as shown in the
figure. If the radius of the cross-section of water stream when it hits the ground is x. Then :

(A)

(B)

(C)

(D)

18) A sonometer wire, 100 cm in length has a fundamental frequency of 330 Hz. The velocity of
propagation of transverse wave along the wire is :-

(A) 330 m/s

(B) 660 m/s
(C) 115 m/s
(D) 990 m/s

19) Dependence of disturbances due to two waves on time is shown in the figure. The ratio of their
intensities I1 / I2 will be-

(A) 1 : 1
(B) 1 : 2
(C) 4 : 1
(D) 16 : 1

20) Two wires are fixed in a sonometer. Their tensions are in the ratio 8:1. The lengths are in the
ratio 36:35. The diameters are in the ratio 4:1. Densities of the materials are in the ratio 1:2. If the
higher frequency in the setting is 360 Hz, the beat frequency when the two wires sounded together
is: (in Hz)

(A) 8
(B) 5
(C) 10
(D) 6

SECTION-II

1) The potential difference between the plates of a parallel plate capacitor is changing at the rate of
106 V/s. If the capacitance is 2µF, the displacement current (in Amp) in the dielectric of the capacitor
will be :-

2) In series RLC circuit, L = 1 mH, C = 0.1 μF,

R = 10Ω and applied voltage is V = 9 sinωt.
At resonance peak voltage across capacitor is:-

3) Two soap bubbles of radii r1 and r2 equal to 4 cm and 5 cm are touching each other over a

common surface S1S2 (shown in figure). Its radius will be :

4) A simple pendulum has a time period T1 when on the earth's surface and T2 when taken to a

height R above the earth's surface where R is the radius of the earth. The value of is :-

5) Velocity of sound in air is 330 m/s. For a particular sound in air, a path difference of 40 cm is
equivalent to a phase difference of 1.6π. The frequency of the wave (in Hz) is :-

PART-2 : CHEMISTRY

SECTION-I

1) The enthalpy of the reaction,

is ΔH1 and that of is ΔH2 then–

(A) ΔH1 < ΔH2

(B) ΔH1 + ΔH2 =0
(C) ΔH1 > ΔH2
(D) ΔH1 = ΔH2

2) If enthalpies of formation for C2H4(g), CO2(g) and H2O (ℓ) at 25°C and 1 atm, pressure are 52,
–394 and –286 KJ/mol respectively, then enthalpy of combustion of C2H4(g) will be

(A) – 141.2KJ/mol
(B) –1412 KJ/mol
(C) 14.2 KJ/mol
(D) +14.12 KJ/mol

3) The difference between heats of reaction at constatnt pressure and constant volume for the
reaction
2C6H6(ℓ) + 1502(g) → 12CO2(g) + 6H2O (ℓ) at 25° in kJ mol–1 is :-

(A) –7.43
(B) +3.72
(C) –3.72
(D) +7.43

4) Given, H2(g) + Br2(g) → 2HBr(g), ΔH°1 and standard enthalpy of condensation of bromine is ΔH°2,
standard enthalpy of formation of HBr at 25°C is :-

(A)

(B)

(C)

(D)

5) Calculate the standard enthalpy of formation of CH3OH(ℓ) from the following data :-
CH3OH (ℓ)+ +2H2O(ℓ) ΔH° –726KJ mol–1
C(s) + O2(g) → CO2(g) ; ΔH° = –393 KJ mol–1

H2(g) + O2(g) → H2O(ℓ) ; ΔH° = –286 KJ mol–1

(A) +310 KJ mol–1

(B) –310 KJ mol–1
(C) –239 KJ mol–1
(D) +239 KJ mol–1

6) Enthalpy of neutralization of H2C2O4 acid is –109 kJ/mol using NaOH. If enthalpy of neutralization
of HCl by NaOH is –57 kJ/mol. Calculate ΔHionization of H2C2O4 into its ions

(A) 50.84 kJ/mol

(B) 5 kJ/mol
(C) 2.5 kJ/mol
(D) 10 kJ/mol

7) When two equal sized pieces of the same metal at different temperatures Th(hot piece) and Tc
(cold piece) are brought into contact into thermal contact and isolated from it's surrounding. The
total change in entropy of system is given by ? [Cv (J/K) = heat capacity of metal]

(A)

(B)

(C)

(D)

8) Molar heat of vapourisation of a liquid is 6 kJ mol–1. If the entropy change is 16 J mol–1 K–1, the
boiling point of the liquid is :-

(A) 375°C
(B) 375 K
(C) 273 K
(D) 102°C

9) Which is correct statement ?

(A) ΔGº must be equal to zero at equilibrium

(B) All exothermic reaction are always spontaneous reaction
(C) PVγ = constant is valid for all adiabatic process
(D) ΔSsurrounding is equal to zero in ir-reversible adiabatic process
10)

One mole of an ideal triatomic gas undergoes expansion process adiabatically from same initial state
up to same final volume by two different processes reversibly and irreversibly. Then correct
option(s) is/are :

(A) Final temperature of gas will be more if process is carried out reversibly
(B) Magnitude of work involved during the process will be more if process is carried out reversibly
(C) Magnitude of change in internal energy of gas will be less if process is carried out reversibly
(D) Magnitude of change in enthalpy of gas will be less if process is carried out reversibly

11) Solubility of AgCl in pure water is 10–5 mol/litre at 25ºC then caluclate solubility of AgCl in 0.1M
aqueous solutions of KCl at 25ºC

(A) 10–9 mol/litre

(B) 10–5 mol/litre
(C) 10–7 mol/litre
(D) 10–4 mol/litre

12) pH when equal volume of 0.1 M HA(Ka = 10–5) & 1 M HB (Ka = 10–6) are mixed:–

(A) 3
(B) 4
(C) 2
(D) 7

13) In 100 ml buffer solution of 0.1M CH3COOH & 0.1M CH3COONa, how many millimoles of NaOH
should be added to increase it's pH by 0.3, if Ka of CH3COOH is 1.8 × 10–5 .
Given (log 2 = 0.3)

(A) 0.333
(B) 33.3
(C) 333
(D) 3.33

14) pH of the resulting solution obtained by mixing equal volumes of two solutions with pH = 3 and
pH = 6 is

(A) 4.5
(B) 3.0
(C) 9.0
(D) 3.3

15) A metal hydroxide of molecular formula M(OH)4 is 50% ionised. Its 0.0025M solution will have
the pH:

(A) 12
(B) 2
(C) 4
(D) 11.7

16)

Out of following how many mixtures are buffers solution

(i) NaCN (0.5 mole)
(ii) NaCN (0.5 moles) + HCN (0.5 moles)
(iii) NH3 (1 mole) + NH4Cl (1 mole)
(iv) CH3COOH (1 mole) + NaOH (0.75 moles)
(v) NH4Cl (1 mole) + NaOH (0.75 moles)
(vi) CH3COONa (0.5 moles) + HCl (0.25 mole)
(vii) H2CO3 (1 mole) + NaOH (1.5 moles)

(A) 4
(B) 6
(C) 3
(D) 5

17) 20 mL of 0.1 M H2SO4 solution is added to 30 mL of 0.2 M NH4OH solution. The pH of the
resultant mixture is : [pkb of NH4OH = 4.7].

(A) 9.4
(B) 5.0
(C) 9.0
(D) 5.2

18) Enthalpy of neutralization of H3PO3 acid is

–106.68 kJ/mol using NaOH. Enthalpy of neutralization of HCl by NaOH is –55.84 kJ/mol. Calculate
ΔHionization of H3PO3 into its ions:

(A) 50.84 kJ/mol

(B) 5 kJ/mol
(C) 2.5 kJ/mol
(D) None of these

19) For the reaction :

5A(g) + 3B(g) + 7C(g) → 5D(g) + 4E(l) ;
ΔH = –56 kcal /mole
Find heat exchanged when 2 moles of A , 1.5 moles of B and 2.1 moles of C reacts in a closed rigid
container at 300K.

(A) –62 kcal

(B) –15kcal
(C) –18.6 kcal
(D) –50 kcal
20) 50 gm of an ideal gas is undergoing a process for which heat capacity is 50 cal/mole-K. If rise in
temperature during the process is 100ºC then calculate work involved in process
(given molar mass of gas = 10 gm/mole, Cp of gas = 5R)

(A) –29 kcal

(B) –21 kcal
(C) 29 kcal
(D) 21 kcal

SECTION-II

1) One mole of He gas changes its state from

(10 atm, 100 K) to (1 atm, 1000 K). Then change in entropy (ΔS) will be 2.303 x cal K–1 (taking R = 2
cal mol–1 K–1). Then x is:

2) 1 mole of CaCO3 is heated in a closed container fitted with a frictionless movable piston at 1atm,
300K. Calculate the work obtained (in cal.)
[Use : R = 2 cal/K-mole] (without sign)
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.

3) One mole of an ideal gas at 27ºC, 8.21 atm absorbs 420 cal. of heat during a reversible isothermal
expansion. Calculate the final volume (in litre) of gas. [Use : R = 0.0821 litre-atm/K-mole]

4) Calculate pH when 100 ml of 0.2 M NaOH is reacted with 100 ml of 0.2 M CH3COOH (Ka = 10–5)

5) Calculate – log [CH3COO–] in 0.1M CH3COOH(aq.) solution when mixed with equal volume of 1M
HCl
(Ka = 10–5)

PART-3 : MATHEMATICS

SECTION-I

1) Let f(x) = ; {.} denotes the fraction part. Then the set of values of a, for
which f(x) can attain its maximum value is

(A) (0, 4/π)

(B) (π/4, ∞)
(C) (0, ∞)
(D) (–∞, ∞)
2) Let ƒ(x) = (sinx)n + nC1(sinx)n–1cosx + nC2(sinx)n–2cos2x + ......+(cosx)n,
where n is an even number, then for x ∈ [0,2π], number of maxima and minima are p and q
respectively, then-

(A) p = 2, q = 2
(B) p = 1, q = 3
(C) p = 3, q = 1
(D) p = 3, q = 3

3) =

(A)
(1 + cot5 x)2/5 + c

(B)
(1 + tan5 x)1/5 + c

(C)
– (1 + tan5 x)2/5 + c

(D)
– (1 + cot5 x)2/5 + c

4) If dx = P (1 + x5/2)7/2
+ Q (1 + x5/2)5/2 + R (1 + x5/2)3/2 + C, then P, Q and R are :

(A)

(B)

(C)

(D)

5) If ƒ(x) is an even differentiable function then value of , where ƒ' is

derivative of ƒ w.r.t. 'x', is-

(A)
(B)

(C)

(D) 0

6)
The value of is -
(where {.} represents fractional part function)

(A)

(B) 333
(C) 0

(D)

7) A function y = f (x) satisfies the differential equation f (x) · sin 2x – cos x + (1 + sin2x) f ' (x) = 0
with initial condition y (0) = 0. The value of y (π/6) is equal to

(A) 1/5
(B) 3/5
(C) 4/5
(D) 2/5

8) A continuous function f : R → R satisfy the differential equation f(x) = (1 + x2) then

the value of f(–2) is :

(A) 0

(B)

(C)

(D)

9)

If f(x) = min. {x + 2, 1, 2 – x} ; then

Area bounded by the curve y = f(x) ; lines x = –2 & x = 2 is

(A) 3
(B) 2
(C) 4
(D) 1

10) The area of the region

A = {(x, y) ; 0 ≤ y ≤ x |x| + 1 and – 1 ≤ x ≤ 1} in sq. units, is

(A) 2
(B)

(C)

(D)

11) A line passing through the point P(a, θ) makes an acute angle α with the positive x-axis. Let this

line be rotated about the point P through an angle in the clock-wise direction. If in the new

position, the slope of the line is 2 – and its distance from the origin is , then the value of
3a2tan2α – 2 is

(A) 4
(B) 6
(C) 5
(D) 8

12) Let the ellipse 3x2 + py2 = 4 pass through the centre C of the circle x2 + y2 – 2x – 4y – 11 = 0 of
radius r. Let f1, f2 be the focal distances of the point C on the ellipse. Then 6f1f2 – r is equal to

(A) 74
(B) 68
(C) 70
(D) 78

13) Let and . Let be a unit vector in the plane of the vectors and and
be perpendicular to . Then such a vector is :

(A)

(B)

(C)

(D)

14) Let a be the length of a side of a square OABC with O being the origin. Its side OA makes an
acute angle α with the positive x-axis and the equations of its diagonals are

x+ y = 0 and

Then a2 is equal to

(A) 48
(B) 32
(C) 16
(D) 24

15) Let the values of λ for which the shortest distance between the lines = = and

= = is be λ1 and λ2. Then the radius of the circle passing through the points (0,
0), (λ1, λ2) and (λ2, λ1) is

(A)

(B) 4

(C)

(D) 3

16) Let the lengths of the transverse and conjugate axes of a hyperbola in standard form be 2a and
2b, respectively, and one focus and the corresponding directrix of this hyperbola be (–5, 0) and 5x +

9 = 0, respectively. If the product of the focal distances of a point on the hyperbola is p,

then 4p is equal to ______.

(A) 238
(B) 189
(C) 143
(D) 172

17) Let e1 and e2 be the eccentricities of the ellipse and the

hyperbola , respectively. If b < 5 and e1e2 =1, then the eccentricity of the ellipse having its axes
along the coordinate axes and passing through all four foci (two of the ellipse and two of the
hyperbola) is :

(A)

(B)

(C)

(D)

18) Let p be the number of all triangles that can be formed by joining the vertices of a regular
polygon P of n sides and q be the number of all quadrilaterals that can be formed by joining the

vertices of P. If p + q = 126, then the eccentricity of the ellipse is :

(A)

(B)

(C)

(D)

19) If the equation of the line passing through the point and perpendicular to the lines

and is , then a + b + c + d is equal to :

(A) 10
(B) 14
(C) 13
(D) 12

20) Let and be the vectors of the same magnitude such that Then

is :

(A)
(B) 1 +
(C) 2 +
4+2
(D)

SECTION-II

1) If the integral dx = x + a
ℓn |sin x – 2 cos x| + k, then a is equal to :

2) If = , where C is constant of integration,

then is equal to

3) Let r be the radius of the circle, which touches x-axis at point (a, 0), a < 0 and the parabola y2 =
9x at the point (4, 6). Then r is equal to ______.
4) Let the area of the triangle formed by the lines x + 2 = y – 1 = z, and

be A. Then A2 is equal
to ____.

5) Consider the lines L1 : x –1 = y–2 = z and L2 : x –2 = y = z – 1. Let the feet of the perpendiculars
from the point P(5,1, –3) on the lines L1 and L2 be Q and R respectively. If the area of the triangle
PQR is A, then 4A2 is equal to :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A A B D A B D B D D B B C A C D B A C

SECTION-II

Q. 21 22 23 24 25
A. 2 90 20 2 660

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A B A D C B D B D B A A D D D B C B B B

SECTION-II

Q. 46 47 48 49 50
A. 7 6 6 9 6

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A D A D B D D A A A C D A A B B D B C

SECTION-II

Q. 71 72 73 74 75
A. 2 0 30 56 147
 SOLUTIONS

PART-1 : PHYSICS

1) εL = L

2) Bz → always remain parallel to surface

ε = πr2ω By sin ωt

3) ϕ = BA

= [ML2T–2A–1]

4) εEH = εFG = 0
ε = ε2 – ε1

= vB2a – vB1a

= va
= vB0a

5)

0.6 =

XL = R1 0.5 =
XC =
∴ XC = XL as cosϕ = 1

⇒
6) ε = VBℓ, 2 = 4x2

ℓ = 2x =
V2 = 2ay = 2 × 2 × 2
V=
ε= = 8V

7)

UL = UC

UL + UC =

8)

The Correct Answer is (D)

9) Here, V = 200 V
Resistance, R = 22Ω
Impedance, Z = 44 Ω

Current in circuit, I =
Power dissipated in the circuit, P = I2R = (5)2 × 22 = 550 W

10) Nϕ = Li

11) Work done to from a soap bubble

W = 8πR2T [As V ∝ R2 \ R ∝ V1/3]
∴ W ∝ V2/3

= (2)2/3 ⇒ W2 = (4)1/3 W

12) F = 2 FV

FV =

∵ FV =

=
⇒ η = 2.5 × 10–2 kg-s/m2
13)
Force on this element

dF = dmω2x

14) y = kt2
vy = 2kt
ay = 2k
ay = 2 m/s2

.....(i)

.....(ii)

ans.

15)

16)
Its corresponding magnetic field will be

Net force on charge particle

17)

The correct answer is (D)

18) For fundamental mode,

= 100 or λ = 200 cm = 2m
∴ v = fλ = 330 × 2 = 660 m/s

19) I ∝ n2a2

20)

= ⇒ n1 = = = 350
beats frequency = n2 – n1 = 10 Hz

21) Displacement current is given by

0
id = ε
Where ϕE is the electric flux given as ϕE = EA where A is area of the capacitor plates and E is
the electric field between the plates.

0 0
So, id = ε =εA
But E = V/d where V is the potential difference between the capacitor plates separated at d
distant apart.

So, id = =C
Where C is the capacity of the capacitor.
∴ id = 2 × 10–6 × 106 = 2A

22)
 = 90 volt

23) r = = = 20 cm

24)

then

25) Δϕ = Δx

1.6π = × ⇒ λ = 1/2 m

∴f= = = 660 Hz

PART-2 : CHEMISTRY

26) Question Explanation: Compare the enthalpy changes for the formation of gaseous and
liquid water from hydrogen and oxygen.

Concept: Enthalpy and Phase Transitions.

Solution: The formation of liquid water from gaseous water releases heat (condensation),
which is an exothermic process.
Therefore, the formation of liquid water releases more heat (more negative enthalpy) than the
formation of gaseous water.

1.

2.
The phase transition is
Since is negative, ΔH2 is more negative than
Final Answer: Option (A)

27) Question Explanation:

Calculate the enthalpy of combustion of ethene from the enthalpies of formation of ethene,
CO2, and water.
Concept:
This question is based on enthalpy of combustion.
Solution:

= 2 × (–394) + 2(–286) – 52 –3 × 0

Final Answer:
The correct option is (B).

28) Question Explanation: Calculate the difference between the heat of reaction at constant
pressure (ΔH) and constant volume (ΔU) for the combustion of liquid benzene. Concept:
Relation between ΔH and ΔU.
Solution: The difference is calculated using the expression ΔH − ΔU = Δng​RT.
Heat of reaction at constant volume = ΔU
Heat of reaction at constant pressure = ΔH
2C6H6(I) + 15O2(g) → 12CO2(g) + 6H2O (l)
Δng = 12-15 = -3
ΔH = ΔU + ΔngRT
ΔH − ΔU = ΔngRT

Final Answer: The correct option is (A)

29) H2(g) + Br2(g) → 2HBr(g) ΔH = ΔH°1 ...(i)

Br2(g) → Br2(ℓ) ΔH = ΔH°2 ...(ii)
[eq1 – eq2]
H2(g) + Br2(l) → 2HBr(g) ΔH = ΔH°1 – ΔH°2

Required equation, H2(g) + Br2(l) → HBr(g)

ΔH =

30) C(s) + 2H2(g) + O2(g) → CH3OH(ℓ)

This required reaction ≡ + (2)nd reaction + 2 × (3)rd reaction –(1)st reaction

= – 393 + 2×(–286) – (–726)
= – 393 – 572 + 726
= – 239 KJ mol–1

31) ΔHionisation + 2 (–57) = –109

32) Question Explanation: Calculate the total change in entropy (ΔSsystem​) when two pieces of
the same metal at different temperatures are mixed in an isolated system.

Concept: Entropy change (ΔS):

Solution:
The net heat absorbed by hot and cold body is equal to zero.
qH + qC = 0
Let CV is the total heat capacity of hot and cold body.
CV(Tf – TC) + CV (Tf – TH) = 0

⇒ Tf =
Entropy change ΔSTotal = ΔShot body + ΔScold body

ΔShot body = [Link]

ΔScold body = [Link]

ΔSTotal = CV = CV

ΔSTotal = CV ln

Final Answer: Option (D)

33) Question Explanation: Calculate the boiling point of a liquid given its molar heat and
entropy of vaporization.

Concept: Boiling point (Tb ) at equilibrium:

Solution: The boiling point is the temperature at which the phase change is at equilibrium.
Given:

Final Answer:
The correct option is (B)

34)

ΔGº = - RT ln keq.
ΔGº = 0 Only when keq - 1
B) ΔG = ΔH - TΔS.
C) PVg = K → T & VALID only for Adiabatic reversivle
D) Adiabatic irreversible

dqsystem = 0
(ΔG) SURR = 0
35)

Wrev < Wirrev

|Wrev| > |Wirrev|

36) AgCl
Ksp = [Ag+] [Cl–]
Ksp = s2
Ksp = (10–5)2 = 10–10

AgCl
10–10 = [Ag+] [0.1]
[Ag+] = 10–9
s' = 10–9

37)

38) CH3COOH + NaOH CH3COONa + H2O

10 b 10
10-b 10+b

pH = pKa + log

ΔpH = 0.3 = log

2=

⇒b=

39) Final [H+] =

–log [H+] = pH = 3.3

40) Question Explanation: Calculate the pH of a diacidic weak base solution

with 50% ionization.
Concept: pH of Weak Base Solution .
Solution:
[OH–] = 4 × cα = 4 × 0.0025 × 0.5 = 5 × 10–3
POH = – log (5 × 10–3) = – log 5 – log 10–3 = 0.7 + 3 = 2.3
pH = 14 – 2.3 = 11.7
Final answer : 11.7
41)

A buffer solution should contain weak acid and its conjugate base or weak base and
its conjugate acid.

42) Question Explanation: Calculate the pH of the solution resulting from mixing a strong
acid and a weak base.
Concept: pH of Basic Buffer (NH4​OH/NH4​Cl)
Solution :
20 ml 0.1 M H2SO4 ⇒
30 ml 0.2 M NH4OH ⇒
NH4OH + H+ ⇌ NH4⊕ + H2O
⇒ 6 4 0 0
⇒ 2 0 4 4
Solution is basic buffer

pOH = pKb + log = 4.7 + log 2 = 4.7 + 0.3 = 5

pH = 14 – 5 = 9
Final answer : 9.0

43) H3PO3 → 2H+ + ; ΔrH = ?

+ –
2H + 2OH → 2H2O ;
ΔrH = –55.84 × 2 = –111.68
–106.68 = ΔionH – 55.84 × 2
ΔionH = 5 kJ/mol

44)

ΔH = ΔU + ΔngRT ⇒ –56 = ΔU +

ΔU = –50

∴ net ΔU = – 50 ×

45) q = nCΔT = 5 × 50 × 100 = 25 kcal

ΔU = nCVΔT = 5 × 8 × 100 = 4 kcal

46)

47) CaCO3(s) → CaO(s) + CO2(s)

 W = – ΔngRT
= –1 × 2 × 300
= – 600 cal

48) V1 = =

∵ W = –q = – 420 = –1 × 2 × 300 ln

0.7 =
V2 = 6 litre.

49) NaOH + CH3COOH → CH3COONa + H2O

100 × 0.2 100 × 0.2
= 20 = 20 0
–20 –20 +20
0 0 20

=9

50)

CH3COOH ⇌ CH3COO– + H+

≃ x

Ka = 10–5 =
x = 10–6

PART-3 : MATHEMATICS

51) f(x) = (sinθ + cosθ) = sin (θ + θ/4) is maximum at θ = π/4.

∴ ⇒ {x} =

⇒ 0< ⇒ 0 < a < 4/π

52) ƒ(x) = (sinx + cosx)n
∴ ƒ'(x) = n(sinx + cosx)n–1 (cosx – sinx)

∴ p = 2, q = 2

53)

= (1 + cot5x)2/5 + C
Here 1 + cot5x = t
–5 cot4x cosec2x dx = dt

dx = dt

54) Let I =

Put 1 + x5/2 = t ⇒ x3/2 dx = dt

⇒I=

= +

–
On comparing with given, we have

55)

Let , then
⇒ I = –I ⇒ I=0

56)

57) y sin 2x – cos x + (1 + sin2x) =0 where y = f (x)

= 1 + sin2x (by putting 1 + sin2x = t)

y(1 + sin2x) =
y(1 + sin2x) = sin x + C ; (y(0) = 0) ⇒ C=0

hence, y=

58) [Note : f(0) = 1]

Differentiate both sides w.r.t. x

Let

Solving the above L.D.E.

59)

60) We have,
A = {(x, y) ; 0 ≤ y ≤ x |x| + 1 and – 1 ≤ x ≤ 1}
when x ≥ 0, then 0 ≤ y ≤ x2 + 1
and when x < 0, then 0 ≤ y ≤ – x2 + 1
Now, the required region is the shaded region.

[∵ y = x2 + 1 ⇒ x2 = (y – 1), parabola with vertex (0, 1) and y = – x2 + 1 ⇒ x2 = – (y – 1).

Parabola with vertex (0, 1) but open downward we need to calculate the shaded area, which is
equal to

61) mPR = 2 – = tan 15°

∴ = 15° ⇒
equation of PR :
y = tan 15° (x – a)
y = (2 – ) (x – a)

⊥ distance from origin =

|a| = =
2
a =2
3a2 tan2 α –

3 × (4 + ).

62)
Centre of circle (1, 2), radius

E pass from centre (1, 2)

∴ vertical ellipse

∴ Focal distance of C (h, k)

= b ek

F1 =

F2 =

∴ F1F2 =
∴ 6F1F2 – r =74 – 4 = 70

63) Let vector in plane of & =

⇒ 6 + l(3) = 0
⇒ l = –2
Unit vector →

64)

Slope of diagonal OB =
= tan105°
∴ α = 60°
∴ A(acos60°, asin60°)

∴
A Lies on other diagonal

∴ . + =0

65)

A ≡ (1, 2, 3) B ≡ (λ, 4, 5)

Shortest Distance =

⇒ λ = 3 ± 1 = 4, 2
Radius of circle passing through points
(0, 0), (4, 2) & (2, 4)
66) PF1.PF2 = (eα - a) (eα + a)

P = e2 a2 – a2 =

67)
∴

⇒
b2 = 9

Focii : -
ellipse passing through all four foci

n
68) Total triangles = C3 = p
Total quadrilaterals =
69) Line is to 2 line ⇒ line will be parallel to

Parallel vector along the required line is

Dr’s of required line a (5a –ab), – (b2 + 5), (a + ab)

Also Dr’s of required line a –2, d, –4

.....(1)

Also point will lie on

⇒ d = 7, c = 2

From (1)

a + b + c + d = 2 + 3 + 2 + 7 = 14

70) = +1
Apply componendo and dividendo

⇒ =

⇒ =

⇒ =

⇒ + =

⇒ =

⇒ = =
Now

=1+ +
=1+1+ =

71)

=
= x + 2ℓn |(sin x – 2 cos x)| + k
⇒a=2

72) =
∴ α = – 9, β = 3
⇒ (α + 3β) = 0

73)
(x – a)2 + (y – r)2 = r2
(4 – a)2 + (6 – r)2 = r2
16 + a2 – 8a + 36 + r2 – 12r = r2
a2 – 8a – 12r + 52 = 0
Tangent to parabola at (4, 6) is

6.4 = i.e. 3x – 4y + 12 = 0
This is also tangent to the circle
∴ CP = r

…..(1)
equation of circle is
(x – a)2 + (y – r)2 = r2
satsty P(4, 6) ⇒ a2– 8a – 12r + 52 = 0 …..(2)
From equation (1)
If a + 4 = 3r then a = +6 (rejected)
If 3a + 12 = –r then a = –14 and r = 30
74) L1 : x + 2 = y – 1 = z = ℓ

L2 : = = =m

L3 : = = =n
Point of intersection of L1 and L2

A(–2, 1, 0)
Point of intersection of L2 and L3

Point of intersection L3 and L4

Ar(ΔABC) =

A=

A=
A2 = 56

75)
Let Q (λ + 1, λ + 2, λ)
⇒ λ –4 + λ + 1, λ + 3 = 0
⇒ 3λ = 0
λ=0

Let R (μ + 2, μ, μ + 1)

μ –3 + μ –1 + μ + 4 = 0
≠μ =0

Area of ΔPQR (A) =

=
4A2 = 49 × 3 = 147