21-12-2025

9610ZJA802263250019 JA

PART 1 : PHYSICS

SECTION-I (i)

1) A bomb of 50 kg is fired from a cannon placed on smooth horizontal surface with a velocity of 600
m/s horizontally (with respect to ground). If the mass of the cannon is 103 kg, then its recoil velocity
will be :-

(A) 30 m/s
(B) –30 m/s
(C) 0.30 m/s
(D) –0.30 m/s

2) A ball P of mass m moving with velocity u collides head on with another identical ball Q at rest. If
the coefficient of restitution is e, then the ratio of velocities of P and Q after the collision is :-

(A)

(B)

(C)

(D)

3) A moving particle of mass m makes a head on collision with a particle of mass 2m initially at rest.
If the collision is perfectly elastic, the percentage loss of energy of the colliding particle of mass m is
:-

(A) 50%
(B) 66.7%
(C) 88.9%
(D) 100%

4) A bullet of mass m moving with velocity v strikes a suspended wooden block of mass M. If the
block rises to height h, then the initial velocity v of the bullet must have been :-

(A)

(B)

(C)

(D)

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 SECTION-II (i)

Common Content for Question No. 1 to 2

When electric current in a material is proportional to the voltage across it, the material is said to be
“ohmic”, or to obey Ohm’s law. A microscopic view suggests that how application of an electric field
to a conducting material leads to an electric current, The current density (electric current per unit
area, J = I/A) can be expressed as: J = σE
In the above equation, sigma σ is a constant called the conductivity of a material, E is the applied
electric field.
In complicated materials where the conductivity changes over the length of the conductor, the
analysis is done by treating an infinitesimal quantity and integrating. Suppose we have a cylindrical
conductor of radius r and length L. If it’s resistivity is non uniform and varying as the position X from

left end of the cylinder as given by the equation .

1) Find the ratio of electric field at x = ℓ & x = .

2) Find the ratio of total resistance with resistance of left half.

Common Content for Question No. 3 to 4

The reading on the ammeter is 500 mA and the reading on the voltmeter is 10V. Ammeter, voltmeter

and battery are ideal.

3) Find the resistance R1 (in Ω).

4) The potential difference across R2 is ______ (in V)

Common Content for Question No. 5 to 6

A tank of base area 4 m2 is initially filled with water up to height 2m. An object of uniform cross-

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 section 2m2 and height 1m is now suspended by wire into the tank, keeping distance between base
of tank and that of object 1m. Density of the object is 2000 kg/m3. Take atmospheric pressure 1 ×

105 N/m2; g = 10 m/s2.

5) The tension in the wire is a×105 N. Calculate a :

6) The downward force exerted by the water on the top surface of the object is λ×105 N. Calculate λ
:

SECTION-I (ii)

1) A plano-convex lens is made of a material of refractive index n. When a small object is placed 30
cm away in front of the curved surface of the lens, an image of double the size of the object is
produced. Due to reflection from the convex surface of the lens, another faint image is observed at a
distance of 10 cm away from the lens. Which of the following statement(s) is(are) true?

(A) The refractive index of the lens is 2.5

(B) The radius of curvature of the convex surface is 45 cm
(C) The faint image is erect and real
(D) The focal length of the lens is 20 cm.

2)

A ray of light from a denser medium strikes the plane boundary of a rarer medium at an angle of
incidence I. The angle of refraction is r. If the reflected and the refracted rays are mutually
perpendicular, the critical angle of the medium is

(A) sin–1(cot I)
(B) sin–1(tan I)
(C) sin–1(cot r)
(D) sin–1 (tan r)

3) A point source of light S is placed on the axis of a lens of focal length 20 cm as shown. A screen is
placed normal to the axis of lens at a distance x from it. Treat all rays as paraxial.

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 (A) As x is increased from zero intensity continuously decreases
(B) As x is increased from zero intensity first increases then decreases
(C) Intensity at centre of screen for x = 90 cm and x = 110 cm is same
(D) Radius of bright circle obtained on screen is equal to 1 cm for x = 200 cm

4) A lens forms 3 times magnified image of an object on screen. When the distance between the
screen and the lens is increased by 10 cm and object is also moved to get 5 times magnified image
again on the screen. Then :-

(A) Focal length of the lens is 5 cm

(B) Focal length of the lens is –5 cm
(C) The displacement of the object is 2/3 cm towards the lens w.r.t lens
(D) The displacement of the object is 2/3 cm away the lens w.r.t lens

5) A plano-convex lens (µ = 1.5) of focal length 20 cm has its plane side silvered. :-

The radius of curvature of its curved surface is half that of a surface of equiconvex lens of focal
(A)
length 20 cm made of same material
An object placed at 15 cm on the axis infront of convex side gives an image at a distance of 30
(B)
cm from it
An object placed at a distance of 20 cm on the axis infront of convex side gives an image at 40
(C)
cm from it
(D) It acts as a convex mirror

6) A real object is kept in front of a lens in air. The object is a linear extended object with its length
perpendicular to the optical axis of lens. With reference to different cases of image formation by
lens, choose the correct options :

(A) If the image has a magnification – 2.5 then Image is real and power of lens is positive.
(B) If the magnification of the image is +0.5 then Image is virtual and power of lens is negative
(C) If length of image is the same as that of object then Image is real and power of lens is positive.
If length of image is the same as that of object then Image is virtual and power of lens is
(D)
negative.

SECTION-II (ii)

1) The first member of the Balmer series of hydrogen atom has a wavelength of 6561 Å. The
wavelength of the second member of the Balmer series (in nm) is :-

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 2) Electron in hydrogen atom first jumps from third excited state to second excited state and then
from second excited to the first excited state. The ratio of the wavelengths emitted in the

two cases is . What is x.

3) Nucleus 3A7 has binding energy per nucleon of 10 MeV. It captures a proton and its mass is

increased by times mass of proton. If binding energy of the new nucleus formed is α MeV then
find the value of 10α. [Mass energy of proton is 930 MeV]

PART 2 : CHEMISTRY

SECTION-I (i)

1) A definite mass of a monoatomic ideal gas at 1 bar and 27°C expands against vacuum from 1.2
dm3 to 2.4 dm3. The change in free energy of the gas ΔG, is (R = 0.80 bar – L/K-mol, ln 2 = 0.7)

(A) 0
(B) –64 [Link]
(C) +84 J
(D) –84 J

2) In the system, LaCl3(s) + H2O(g) + Heat ⇋ LaClO(s) + 2HCl(g), equilibrium is established. More
water vapour is added to disturb the equilibrium. If the pressure of water vapour at new equilibrium
is double of that at initial equilibrium, the factor by which pressure of HCl is changed is:

(A) 2 times
(B) times

(C)
times
(D) 4 times

3)
Hydrogenation of the above compound in the presence of poisoned palladium catalyst gives

(A) An optically active compound

(B) An optically inactive compound
(C) A racemic mixture
(D) A diastereomeric mixture

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 4) 'A' 'B', 'A' and 'B' respectively are :

(A)

Both are

(B)

Both are

(C)

(D)

SECTION-II (i)

Common Content for Question No. 1 to 2

Read the following passage carefully and answer the questions given after the passage :
Dinitrogen pentroxide decomposed on heating to nitrogen dioxide and oxygen following first order
kinetics
2N2O5(g) → 4NO2(g) + O2(g)
0.2 mole of N2O5 was taken in a vessel of capacity 1 L and heating to a certain temperature of T
Kelvin at which the reaction begins. The concentration of N2O5 is measured at different intervals of
time by withdrawing samples of reaction mixture. A plot of In[N2O5] v/s time is shown is figure-1. The
value of rate constant (k) of the reaction is determined from the slope of the linear plot. The same
experment is repeated at five different temperature and the value of the rate constants are
calculated at each temperature. A plot of In k v/s (temperature)–1 is shown in figure-2 :

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 1) Slope of straight line in figure-2 is –1.2 × 104 K. What is the activation energy of the reaction?
(kJ/mole)
[R = 8.31 J/mole-K]

2) Slope of straight line in figure-1 is –1 × 10–1sec–1. What is the half-life of the reaction?

Common Content for Question No. 3 to 4

Consider the given reaction sequence

3) Sum of number of Geometrical isomers of Complex - P and Complex-R is:

4) Number of N-Co-N linkages in complex Q are:

Common Content for Question No. 5 to 6

Consider the given structures and answer the following questions

, , , ,

, , ,

5) Total number of aromatic compound(s)?

6) Total number of anti-aromatic compound(s)?

SECTION-I (ii)

1) Which of the following information(s) is/are incorrect regarding the voids formed in three

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 dimensional HCP of identical spheres?

A tetrahedral void is formed when a sphere of the second layer is present above the triangular
(A)
void of the first layer.
(B) All the triangular voids are not covered by the spheres of the second layer.
Tetrahedral voids are formed when the triangular voids in the second layer lie above the
(C)
triangular voids in the first layer and the triangular shapes of these voids do not overlap.
Octahedral voids are formed when the triangular voids in the second layer exactly overlap with
(D)
similar voids in the first layer.

2) Consider 0.1 m aqueous solutions of two solutes X and Y. The solute X behaves as a univalent
electrolyte, while the solute Y dimerizes in solution. Which of the following statement(s) is/are
correct regarding these solutions ?

(A) The boiling point of the solution of X will be higher than that of Y.
(B) The osmotic pressure of the solution of X will be higher than that of Y.
(C) The freezing point of the solution of X will be higher than that of Y.
(D) The relative lowering of vapour pressure of both the solution will be the same.

3) Select the correct statement:

(A) Chelation effect is maximum for five and six membered rings
(B) Greater the charge on the central metal cation, greater the value of Δ (CFSE)

(C) In complex ion is a weak field ligand, so that Δoct < P (Pairing energy) and it is low
spin complex.
(D) complex ion will have four different isomers

4) Select the incorrect statement(s):

(A) Cs+ is more hydrated than the other alkali metal ions
(B) Among the alkali metals Li, Na, K and Rb, lithium has the highest melting point
(C) Ionic mobility of Li+ is maximum among alkali metal cations
(D) Ionisation potential of Li is lower than that of Na.

5) Which of the following compound will not give foul smell when reacted with CHCl3 + NaOH

(A)

(B)

(C)

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 (D)

6) Choose the correct option(s) for the following set of reactions

(A)

(B)

(C)

(D)

SECTION-II (ii)

1) An optically active substance 'A' decomposes into optically active substances ‘B’ and ‘C’ as
follows:

The specific rotations of A, B and C are +40°, +10° and –30° per mole, respectively. If initially A and
C were present in 4 :3 mole ratio, the time (in min), after which the sample becomes optically
inactive, is (ln 2=0.7, ln 5=1.6, ln 7=2.0, ln 13=2.5)

2) If x and y are total number of electrons which are present in non-axial and axial set of d-orbitals

respectively in Ni cation of [Ni(DMG)2], then calculate value of .

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 3)
Number of compounds which shows Br2/H2O test

PART 3 : MATHEMATICS

SECTION-I (i)

1) Let and Then, for

the least value of is:

(A) 0

(B)

(C)

(D)

2) Consider the following statements for a continuous function on [a, b] and differentiable function
in (a, b). Then which of the following is INCORRECT?

(A) There exists such that

(B)
There exists such that where .
(C) There exists such that

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 There exists such that Rolle's theorem is applicable in [a, b] if
(D)
where

3) Let f : (0, 1) → be the functions defined as f(x) = if where .

Let g : (0, 1) → be a function such that for all x∈(0, 1). Then

(A) does NOT exist

(B) is equal to 1
(C) is equal to 2
(D) is equal to 3

4) Let the focal chord of the parabola P : y2 = 4x along the line L : y = mx + c, m > 0 meet the
parabola at the points M and N. Let the line L be a tangent to the hyperbola H : x2 – y2 = 4. If O is
the vertex of P and F is the focus of H on the positive x-axis, then the area of the quadrilateral
OMFN is

(A)
(B)
(C)
(D)

SECTION-II (i)

Common Content for Question No. 1 to 2

A plane p contains the line and is parallel to the line

1) Distance of image of A(a, 0, 0) in the plane p from . where a = b = c = 1 is equal

to

2) If the shortest distance between L1 and L2 is then the value of equals

Common Content for Question No. 3 to 4

If loge(I + A) is defined as loge(I + A) =

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 where A is a square matrix and & 0 < x < 1, I is an identity matrix of order 2.

3) If , then (2L + M) is

4) The number of solutions ƒ(x) = g(x) is

Common Content for Question No. 5 to 6

Let , i = 1, 2 and g1(x) = 1, g2(x) = |4x – p| and f(x) = sin2x, for

all
Define

5) The value of is

6) The value of is

SECTION-I (ii)

1) Let xi (i = 1, 2 ..... n) be the roots of the equation xn + 3xn–1 + 5xn–2 + ..... + 2n+1 = 0 and
f(x) = ax2 + bx + c = 0 (a, b, c R & a 0) possess α + iβ as a root (α, β R and β 0), then

is

(A) always negative if n is odd

(B) always positive if n is even
(C) may be positive or negative if n is odd
(D) may be negative or positive if n is even

2) In a = 11 and sin A where ‘a’ is the side opposite to If the side

length of are 11, b, c where ‘b’ is the largest possible side of then

(A)
Circumradius R of is equal to

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 (B)
Inradius r of is equal to

(C)
Area of is equal to

(D)
The value of sin 2A + sin 2B + sin 2C is equal to

3) Let . Now which of the following holds good ?

(A) |P10| is harmonic mean of |P9| & |P11|

(B)

(C) |P10| is arithmetic mean of |P9| & |P11|

(D)

4) Let ƒ : → and g : → be functions satisfying ƒ(x + y) = ƒ(x) + ƒ(y) + ƒ(x)ƒ(y) and ƒ(x) = xg(x)

for all x, y ∈ . If , then which of the following statements is/are TRUE?

(A) ƒ is differentiable at every x ∈

(B) If g(0) = 1, then g is differentiable at every x ∈
(C) The derivative ƒ'(1) is equal to 1
(D) The derivative ƒ'(0) is equal to 1

5) Let (x1, y1) and (x2, y2) where x1 > 0, x2 < 0 be two points lying on the curve x(y – x) = 1 and (x3, y3)
be a point from where two tangents drawn to the curve are perpendicular to each other. Which of
the following option(s) is/are correct ?

(A) The minimum possible value of (x1 – x2)2 + (y1 – y2)2 is

2 2
(B) The minimum possible value of (x1 – x2) + (y1 – y2) is 20
2 2
(C) x3 + y3 = 4
(D)

6) Let f : (0, ∞) → [3, ∞) be a function satisfying the differentiable equation xy' + (x + 1)y = (3x2 +

3x3)e2x. If f (1) = e2 + then which of the following is/are correct ?

(A) y = f (x) is an onto function

(B)
f (x) = has two distinct real roots

(C)
f (x) = has one real roots

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 (D) f (x) = x2 e2x + 1 has one real roots

SECTION-II (ii)

1) Consider a function ƒ : {1, 2, 3, ......15} → {1, 2, 3 ...... 10} given that function is onto and non

decreasing. If the probability that ƒ(5) = 3 and ƒ(10) = 6 is , (p & q are coprime numbers), then
value of |q – 6p| is

2) Let ƒ : I+ → R be a function such that ∀ n >1, and ƒ(1) = 1. If the value of

ƒ(1007) will be , find k.

3) Let and be two unit vectors such that . For some x, y ∈ , let . If
= 2 and the vector is inclined at the same angle α to both and , then the value of is

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 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B B C B

SECTION-II (i)

Q. 5 6 7 8 9 10
A. 1.33 2.40 20.00 5.00 0.20 2.10

SECTION-I (ii)

Q. 11 12 13 14 15 16
A. A,D B,C B,C,D A,C A,B A,B,C

SECTION-II (ii)

Q. 17 18 19
A. 486 20 793

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 20 21 22 23
A. D B B C

SECTION-II (i)

Q. 24 25 26 27 28 29
A. 99.72 6.93 4.00 15.00 5.00 1.00

SECTION-I (ii)

Q. 30 31 32 33 34 35
A. C,D A,B A,B,D A,C,D A,B,C B,D

SECTION-II (ii)

Q. 36 37 38
A. 500 36 4

PART 3 : MATHEMATICS

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 SECTION-I (i)

Q. 39 40 41 42
A. C A C B

SECTION-II (i)

Q. 43 44 45 46 47 48
A. 3.00 64.00 0.00 1.00 2.00 1.50

SECTION-I (ii)

Q. 49 50 51 52 53 54
A. B,C A,B,C A,D A,B,D A,C A,C,D

SECTION-II (ii)

Q. 55 56 57
A. 101 814 3

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 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: Find recoil velocity

Concept: Conservation of momentum
Solution:
0 = 50 × 600 + 103 V0
V0 = –30 m/s
Final Answer: (B)

2) Explain Question: Find ratio of velocities of P and Q.

Concept: Conservation of momentum
Solution:
Momentum of the system remains conserved during the head on collision.
If v1 and v2 are the velocities of balls P2 and Q, respectively, after the collision then from the
momentum conservation principle,
mu = mv1 + mv2
u = v1 + v2 ...(i)

or e =

= (∴ u2 = 0 and u1 = u)
∴ v2 – v1 = eu

From eqs. (i) and (ii), we get v1 = u

and v2 = u ∴ =
Final Answer: (B)

3) Explain Question: Find percentage of energy of colliding particle

Concept: Collision
Solution:
mu + 2m × 0 = mv1 + 2mv2
or +v1 + 2v2 = u ...(i)

mu2 + × 2m × 0 = mv12 × 2mv22

v12 + 2v22 = u2 ...(ii)
From eq. (i), v1 = u – 2v2
On substituting the value of v1 in eq. (ii), we get
(u – 2v2)2 + 2v22 = u2
u2 + 4v22 – 4uv2 + 2v22 = u2
6v22 = 4uv2

v2 = u= u

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 and v1 = u – 2v2 = u – 2 × u=–

Ki = mu2

Kf = mv12 = m = Ki
∴ Percentage loss of energy of the colliding particle

= × 100

= × 100 = = 88.9%
Final Answer: (C)

4) Explain Question: Find initial velocity of the bullet

Concept: Momentum conservation
Solution:
mV = (M + m)V'

⇒ V' = ,h=

h= ⇒V=
Final Answer: (B)

5) Explain Question: Find ratio of electric field at &

Concept: E = ρJ
Solution:

Ratio:
Final Answer: (1.33)

6) Explain Question: Find ratio of total resistance with resistance.

Concept: Series combination
Solution:

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 Ratio
Final Answer: (2.40)

7) Explain Question: Find R1

Concept: Instruments
Solution:

v = 10 v
i = 500 ma
v across R1 = 10

∴
Final Answer: (20.00)

8) Explain Question: Find potential difference across R2

Concept: v = iR
Solution:

V = iR2
V = 500 × 10–3 × 10
V = 5V
Final Answer: (5.00)

9) Question Explanation:
An object of uniform cross section is suspended into tank keeping distance between base of
tank and that of object. Taking atmospheric pressure 1 × 105, it is asked to find the tension in
the wire.

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 Concept:
This question is based on Archimedes principle.

Solution:
(i) By conservation of volume
4 × h = 4 × 2 + 2 × 1 = 10
h = 2.5 m
Pressure at top of the object.

= P0 + 0.5 × 1000 × 10
= 1.05 × 105 N/m2
F = P1A
= 1.05 × 105 × 2 = 2.1 × 105 N
By F.B.D. T + P2A = mg + P1A
T = mg + (P1 – P2)A
= mg – (P2 – P1)A
= 2 × 1 × 2000 × 10 – (1000 × 10 × 1) × 2
= 0.4 × 105 – 0.2 × 105 = 0.2 × 105 N

Final Answer:
The correct answer is 0.2

10) Explain Question: An object of uniform cross section is suspended into tank, keeping
distance between base of tank and that of object. Taking atmospheric pressure 1 × 105, it is
asked to find the downward force exerted by water on surface.
Concept:
This question is based on Archimedes principle.
Solution:

4×2 = 4 (λ + 1)
+2×1
8-2 = 4λ +4

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 6 - 4 = 4λ
h = 2/4
h = 0.5 m
F = (p0 + ρgh).2
F = (105 + 103 × 10 ×0.5) ×2
F = (10×104+0.5×104)2
F = 10.5×2×104
F = 21×104
F= 2.1 × 105 N
λ = 2.1

Final Answer: (2.10)

11)

Explain Question: Calculate focal length and refractive index

Concept: Refraction through curved surface
Solution:

....(i)

Also, ....(ii)
For reflection from convex mirror (curved surface)

...(iii)
R = 30 cm
From (i), (ii) and (iii)
n = 2.5,
Faint image is erect and virtual.
Final Answer: (A,D)

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 12) Explain Question: Find critical angle of the radian
Concept: Total internal reflection
Solution:

r = 90 – I
µ sin I = 1 sin r = cos I
µ = cot I
µ sin QC = 1 sin 90°
µ sin QC = 1

sin QC = = tan I
QC = sin–1 (tan I) = sin–1 (cot r)
Final Answer: (B,C)

13) Explain Question: Choose the correct options

Concept: Lens formula
Solution:

⇒ = ⇒ V = 100 cm

from O to I intensity increases and then decreases

at x = 90 cm & 110 cm intensity is same
(D) Radius at x =200 cm is equal to radius of lens.
Final Answer: (B,C,D)

14) Explain Question: Choose correct options

Concept: Lens formula
Solution:
For first case,
Image distance = 3 times object distance

∴ ... (1)
When distance between screen & lens is increased by 10 cm
v = 3u + 10

|u'| =

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 ∴

⇒ ... (2)

∴u= cm
∴ f = 5 cm

Final Answer: (A,C)

15) Explain Question: Choose correct options

Concept: Lens formula
Solution:
feq = – 10 cm (concave mirror)
Final Answer: (A,B)

16) Explain Question: Choose correct options

Concept: Lens formula
Solution:
Positive power lens (convex lens in rare medium) can form enlarged (or of same size) real,
inverted image.
Positive power lens (convex lens in rare medium) can form virtual, erect, diminished image.
Positive power lens (convex lens in rare medium) can form enlarged, virtual, erect image.
Final Answer: (A,B,C)

17) Explain Question: Find wavelength of the second member of balmer series
Concept: Atomic structure
Solution:
For Balmer series,

λ2 =
λ2 = 4860 Å = 486 nm
Final Answer: (486)

18) Explain Question: Find ratio of wavelengths

Concept: Atomic structure
Solution:

Wevelength observed from transition of ni to nf is

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 For λ1, ni = 4, nf = 3
For λ2, ni = 3, nf = 2
We get λ1 : λ2 = 20 : 7
Final Answer: (20)

19) Explain Question: Find binding energy of new nucleus

Concept: Mass defect
Solution:

BE = 70 + (930) = 79.3
Final Answer: (793)

PART 2 : CHEMISTRY

20)

Explain Question: Calculate the ΔG of the gas.

Concept: ΔG = ΔH – TΔS
Solution:

=
= –84 J
Final Answer: (D)

21)

Explain Question: Calculate the final pressure of HCl.

Concept: Le-Chatelier's principle
Solution:

Final Answer: (B)

22)

Explain Question: Identify the optical nature of final product.

Concept: Optical Isomerism.
Solution:
Addition on triple bond takes place by the addition of hydrogen

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 Will have a plane of symmetry and hence optically inactive. So option (2) is correct.
Final Answer: (B)

23)

Explain Question: Identify product A and B.

Concept: Bromination of phenol in different solvents.
Solution:
In H2O (polar solvent) dibromophenol derivative and in CS2 (non-polar) solvent monobromo
phenol derivative is obtained.
Final Answer: (C)

24)

Explain Question: Calculate activation energy of the reaction.

Concept: Arrhenius theory.
Solution:

lnk =

slope =
Ea = 1.2 × 104 × 8.31
= 9.972 × 104 Joule/mole
= 99.72 kJ/mole
Final Answer: (99.72)

25)

Explain Question: Calculate half-life.

Concept: First order kinetics.
Solution:
Kt = lnA0 – lnAt
lnAt = lnA0 – Kt
slope = –K = –(1 × 10–1), K = 10–1

sec
Final Answer: (6.93)

26)

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 Explain Question: Calculate total number of geometrical isomers of given complex.
Concept: Geometrical isomerism.
Solution:

Final Answer: (4.00)

27)

Explain Question: How many N-Co-N linkages in complex Q.

Concept: Different possible orientation of groups.
Solution:

Final Answer: (15.00)

(6)NH3 — Co — (1)NH3
(6)NH3 — Co — (2)N
(6)NH3 — Co — (5)N
(6)NH3 — Co — (3)NH2
(6)NH3 — Co — (4)NH2
(1)NH3 — Co — (2)N
(1)NH3 — Co — (3)NH2
(1)NH3 — Co — (4)NH2
(2)N — Co — (3)NH2
(2)N — Co — (4)NH2

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 (1)NH3 — Co — (5)N
(2)N — Co — (5)N
(3)NH2 — Co — (4)NH2
(3)NH2 — Co — (5)N
(4)NH2 — Co — (5)N

28)

Explain Question: Identify total number of aromatic compound(s).

Concept: Aromaticity.
Solution:

, , , ,
Final Answer: (5.00)

29)

Explain Question: Identify total number of anti-aromatic compound(s).

Concept: Aromaticity.
Solution:

Final Answer: (1.00)

30)

Explain Question: Identify incorrect statement regarding the voids formed in three
dimensional HCP of identical spheres.
Concept: Concept of Td and Oh voids
Solution:
Incorrect statements are :
(C) Tetrahedral voids are formed when the triangular void in the second layer lies exactly
above the triangular voids in the first layer and the triangular shape of these voids oppositely
overlap.

(D) Octahedral voids are formed when triangular void of the second layer is not exactly

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 overlapped with a similar void in the first layer

Final Answer: (CD)

31)

Explain Question: Which of the following statement(s) is/are correct regarding these
solutions ?
Concept: Colligative properties.
Solution:
Solute X will dissociate into the solution so i >1.
So solution containing solute X having high boiling point & high osmotic pressure, high
relative lowering of V.P. & lower freezing point.
Final Answer: (AB)

32) Explain Question: Identify the correct statement.

Concept: CFSE
Solution:
(A) Five and six membered ring is more stable
(B) Greater the charge on CMA, greater the splitting energy & CFSE.
(C) [CoF6]3– is a high spin complex with sp3d2 hybridisation

(D)
Final Answer: (ABD)

33) Explain Question: Identify the incorrect statement.

Concept: Physical properties of s-block elements.
Solution:
(A) Cs+ is least hydrated than the other alkali metal ions
(B) Among the alkali metals Li, Na, K and Rb, lithium has the highest melting point
+
(C) Ionic mobility of Li is minimum among alkali metal cations, due to hydration energy and
hydration.
(D) Ionisation potential of Li is greater than that of Na.
Final Answer: (ACD)

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 34)

Explaining question : Question is asking about the amines that will not give carbyl amine
test.

Concept : This question is based on carbyl amine test.

Solution : Primary amines give carbyl amine test on reaction with CHCl3 + NaOH. Other
nitrogeneous compounds like 2° amines, 3° amines, amides, nitro etc do not give carbyl amine
test.

* (amide), Ph–NH–CH3(2° amine) and (3° amine) do not give

carbyl amine test.

*
Final answer : 1, 2, 3

35) Explain Question: Identify the product Q, R, S, T and U.

Concept: Grignard reagent and dehydration by H3PO4.
Solution:

Final Answer: (BD)

36) Explain Question: Calculate the time after which sample becomes optically inactive.
Concept: First order kinetics.
Solution:

t = t 4-x 2x 3+x
Total angle of rotation at t min = 0
(4 - x) 40 + 2x × 10 + (3 + x) (–30) = 0
160 - 40x + 20x - 90 - 30x = 0
70 = 50 x

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 x=

t=

t=

= 103 (3 – 2.5) = 500 min

Final Answer: (500)

37) Explain Question: Calculate the non-axial and axial set of d-orbitals in given complexes.
Concept: Concept of inner and outer orbital complex.
Solution:
0 0
Ni2+ → [Ar] 3d8, 45 , 4P
Ni [DMG]2 → dsp2

x=6
y=2

Final Answer: (36)

38) Explain Question: Find number of compounds which shows Br2/H2O test.
Concept: Bromine-water test.
Solution:
Compounds which shows Br2/H2O test

Final Answer: (4)

PART 3 : MATHEMATICS

39) Explain Question : Given two complex numbers satisfying certain conditions we have to
find least value of modulus of their difference
Concept : Algebra of modulus of complex numbers
Solution :

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 ⇒
⇒
⇒
⇒
∴ or
z2 lie on imaginary axis. Or on real axis with in [–1,1]
Final Answer : (C)

40) Explain Question : Given a continuous and differentiable function we have to find which
all statements are incorrect
Concept : IVT, RT
Solution :
(A) Using IVT,
here

but
Thus invalid.
(B) Use RT on g(x) = f2(x)
(C) Valid using IVT
(D) RT applicable.
Final Answer : (A)

41) Explain Question : Given two functions we have to find limit of product of the functions
as x tends to zero.
Concept : Newton Leibnitz rule
Solution :

Final Answer : (C)

42) Explain Question : Given focal chord of a parabola and a hyperbola and some conditions
we have to find area of a resulting quadrilateral
Concept : Common tangent to parabola and hyperbola
Solution :

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 H:
Focus (ae, 0)

Line L : y = mx + c pass (1, 0)

........(1)

Line L is tangent to Hyperbola.

From (1)

Squaring
m2 = 4m2 – 4
4 = 3m2

(as m > 0)
C = –m

y2 = 4x

⇒ x2 +1 – 2x = 3x

Area

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 Final Answer : (B)

43) Explain Question : Given a plane and a line we have to find image of a point in the plane
Concept : Shortest distance
Solution :
Equating of line L1 and L2 can be obtained in symmetric form

L1 :

L2 :

Equation of plane p :

⇒
Lines L1 and L2 in vector form
L1 :
L2 :

Shortest Distance =

Image of A(1, 0, 0) in the plane is its distance from M is 3.

Final Answer : (3.00)

44) Explain Question : Given a plane and a line we have to find image of a point in the plane
Concept : Shortest distance
Solution :
Equating of line L1 and L2 can be obtained in symmetric form

L1 :

L2 :

Equation of plane p :

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 Lines L1 and L2 in vector form
L1 :
L2 :

Shortest Distance =

Image of A(1, 0, 0) in the plane is its distance from M is 3.

Final Answer : (64.00)

45) Explain Question : Given a matrix which is sum of many different matrices we have to
find value of a related integral
Concept : Expansion of logarithm
Solution :

⇒ ƒ(x) = ℓn(1 + x) & g(x) =

⇒
⇒ 2L + M = 0
Final Answer : (0.00)

46) Explain Question : Given a matrix which is sum of many different matrices we have to
find number of solutions of f(x) = g(x)
Concept : Expansion of logarithm, differentiation
Solution :

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 ⇒ ƒ(x) = ℓn(1 + x) & g(x) =

ℓn(1 + x) =

Consider F(x) = ℓn(x + 1) –

F'(x) =

F(0) = –1 & F(1) = ℓn2 –

⇒ There is one root in (0, 1).
Final Answer : (1.00)

47) Explain Question : Given a series of functions and a standalone function we have to find
value of a resulting integral
Concept : Definite integration
Solution :

g1(x) = 1; g2(x) = |4x – p| & f(x) = sin2x ∀

.... (i)
P-5 :

... (ii)
(i) + (ii)

⇒ ⇒

# =

... (iii)
p-5 :

.... (iv)
(iii) + (iv) :

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 ⇒

⇒
Final Answer : (2.00)

48) Explain Question : Given a series of functions and a standalone function we have to find
value of a resulting integral
Concept : Definite integration
Solution :

g1(x) = 1; g2(x) = |4x – p| & f(x) = sin2x ∀

.... (i)
P-5 :

... (ii)
(i) + (ii)

⇒ ⇒

# =

... (iii)
p-5 :

.... (iv)
(iii) + (iv) :

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 ⇒

⇒
Final Answer : (1.50)

49) Explain Question : Given a n-degree polynomial we have to find a related product
Concept : Condition for imaginary roots
Solution :
Given roots of f (x) are imaginary and hence possible graph of f(x) can be

Final Answer : (B,C)

50) Explain Question : Given a side length and an angle we have to find various parameters
Concept : Sine rule
Solution :
(A) a = 11
2R sinA = 11

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 b > c & b > 11

(A) is true.
Final Answer : (A,B,C)

51) Explain Question : Given sum of a binomial series we have to find what all statements
are true
Concept : Simplification of a binomial series
Solution :

P(n) =

P(n) = ... (1)

Now ... (2)

n+1 n+1 1 n+1 n+1
Now C0 – C1 + n + C2 ....+ (–1) Cn+1 = 0
n+1 n+1 n n+1 n+1
C1 – C2 .... + (–1) · Cn + 1 = C0 = 1

Hence ...(3)
put (2) and (3) in (1)

∴ P(n) = 0 –

Thus |P10| is HM of |P9| and |P11|

Hence (A)

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 =
= Hence (D)
Final Answer : (A,D)

52) Explain Question : Given a functional equation we have to find statements which are true
Concept : Continuity, differentiability, partial derivative
Solution :
since ƒ(x) = xg(x)

...(1)
ƒ (x + y) = ƒ(x) + ƒ(x) + ƒ(x) ƒ(y)
Now we check continuity of ƒ(x)
at x = a

∴ ƒ(x) is continuous ∀ x ∈ R

∴ ƒ(0) = 0

and
∴ ƒ'(0) = 1
Now
ƒ(x + y) = ƒ(x) + ƒ(y) + ƒ(x) ƒ(y)
using partial derivative (w.r.t. y)
ƒ'(x + y) + ƒ'(y) + ƒ(x) + ƒ'(y)
put y = 0
ƒ'(x) = ƒ'(0) + ƒ(x) ƒ'(0)
ƒ'(x) = 1 + ƒ(x)

ƒ(0) = 0 ; c = 0
1 + ƒ(x) = ±ex or ƒ(x) = ± ex – 1
Now ƒ(0) = 0 \ ƒ(x) = ex – 1
∴ ƒ(x) = ex – 1
option (A) is correct
and ƒ'(x) = ex
ƒ'(0) = 1 option(D) is correct

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 option B is correct
Final Answer : (A,B,D)

53) Explain Question : Given a curve and its directrix we have to find correct options
Concept : Transverse axis, director circle of a hyperbola
Solution :
x(y – x) = 1 is a hyperbola with asymptotes x = 0, y = x

The transverse axis will be i.e., the line

solving with the hyperbola ;

⇒
For (A), the square of the distance between vertices

For (C), the equation of director circle :

x2 + y2 = a2 – b2 = a2 (2 – e2)

Final Answer : (A,C)

54) Explain Question : Given a function which satisfies an equation we have to find correct
options
Concept : Integrating factor
Solution :
xy' + (x + 1) y = 3x2 e2x (x+1)

y' + y = 3xe2x (x+1)

I.F. = ex+lnx = xex

y · (xex) = = x3 e3x + c

y = x2 e2x +

e2 + = e2 + ⇒c=2

f (x) = x2 e2x + = x2 e2x + ≥ 3 (Using A.M. ≥ G.M.)

Final Answer : (A,C,D)

55) Explain Question : Given an onto and non decreasing function we have to find a certain
probability
Concept : Basic P & C
Solution :
ƒ(1) ≤ ƒ(2) ≤ ƒ(3) ≤ ƒ(4) ≤ ƒ(5) ≤ ƒ(6) ≤ ƒ(7) ≤ ƒ(8) ≤ ƒ(9) ≤ ƒ(10) ≤ ƒ(11) ≤ ƒ(12) ≤ ƒ(13) ≤ ƒ(14)

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 ≤ ƒ(15)
equality needed = 5
total number of ways of selecting 5 equality from 14 inequality = 14C5
Now, ƒ(5) = 3 and ƒ(10) = 6

Final Answer : (101)

56) Explain Question : Given a function which is summation of a series of functions we have
to find specific value
Concept : Functional rule
Solution :
ƒ(1) + 2.ƒ(2) + 3.ƒ(3) + .......+n(ƒ(n))
= n(n+1)ƒ(n) ........(i)
Replace n → n + 1
ƒ(1) + 2.ƒ(2) + 3.ƒ(3)+.....+nƒ(n) + (n+1)ƒ(n+1)
= (n + 1) (n + 2) ƒ(n+1) .......(ii)
(ii) – (i)
(n + 1) ƒ(n+1) = (n+1) (n+2)ƒ(n+1)
– n(n+1)ƒ(n)
n(n+1) ƒ(n) = (n+1)2ƒ(n+1)
⇒ nƒ(n) = (n+1)ƒ(n+1)
∴ 2ƒ(2) = 3ƒ(3) = ........= n(ƒ(n))
Put in (1) :
ƒ(1) + (n–1)n.ƒ(n) = n(n+1)ƒ(n)
⇒ ƒ(1) = 2nƒ(n)

∴
Final Answer : (814)

57) Explain Question : Given a vector in three dimension we have to find a related value
Concept : Dot product
Solution :

and x = 2cosα
and y = 2cosα
Also, =1
∴
+ 2cosα .
2
4 = 8cos α + 1
8cos2α = 3
Final Answer : (3)

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