Hydrogen Energy: Production & Properties
Hydrogen Energy: Production & Properties
Hydrogen Energy
• Hydrogen energy is a form of clean energy derived from hydrogen, the most existing element
in the universe. It is primarily used as a fuel in two main ways: through combustion or in fuel
cells. When hydrogen reacts with oxygen, it produces electricity, with water as the only by
product, making it an environmentally friendly alternative to traditional fossil fuels.
• Hydrogen can be produced through various methods, including electrolysis (splitting water
into hydrogen and oxygen using electricity), steam reforming of natural gas, or from renewable
sources like biomass.
➢ Properties of Hydrogen:
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1. Abundance (Available in very large quantity)
• Hydrogen is the most abundant element in the universe, primarily found in water (H2O) and
various organic compounds.
3. Clean Emissions
• When hydrogen is used in fuel cells or combusted, the only byproduct is water vapor (H2O).
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• Hydrogen is a very light gas with a low volumetric energy density, requiring high-pressure
tanks or liquefaction for storage and transportation.
• Hydrogen can be stored as a gas, liquid, or in chemical forms (such as ammonia or metal
hydrides).
• Hydrogen can be produced through renewable processes like electrolysis (splitting water using
electricity from renewable sources such as wind or solar).
• Hydrogen fuel cells are highly efficient, with energy conversion efficiencies of around 40-
60%, and up to 85% when used in combined heat and power systems.
• Hydrogen is non-toxic, non-polluting, and safe for humans to handle in appropriate conditions.
• Hydrogen can be used in a variety of applications, including power generation (through fuel
cells), transportation (fuel cell vehicles), and even industrial processes (like refining and
ammonia production).
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➢ Sources of Hydrogen:
• Hydrogen can be produced from a variety of sources using different methods. These sources
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can be classified into two main categories: renewable (green) sources and non-renewable
(Gray and blue) sources.
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❖ Renewable Hydrogen (Green Hydrogen)
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• Electrolysis involves using electricity to split water (H2O) into hydrogen (H2) and oxygen
(O2). When the electricity comes from renewable sources like wind, solar, or hydroelectric
power, this process is considered carbon-free and is known as green hydrogen.
▪ Biomass Gasification
• Biomass (organic material such as wood, agricultural waste, and other plant-based materials)
can be heated in a low-oxygen environment to produce hydrogen, carbon monoxide, and
carbon dioxide. The hydrogen is then separated from the other gases.
• These are emerging methods where certain microorganisms (algae and bacteria) or materials
absorb sunlight and convert water into hydrogen.
• Non-renewable hydrogen is produced from fossil fuels, typically natural gas, and involves higher
carbon emissions unless coupled with carbon capture technology.
▪ This is the most common method of hydrogen production, where natural gas (primarily methane,
CH4) is reacted with steam to produce hydrogen and carbon dioxide (CO2).
▪ Coal Gasification
• In this method, coal is heated with steam and oxygen at high temperatures to produce a synthetic
gas composed of hydrogen, carbon monoxide, and CO2. Hydrogen is then separated from the
synthetic gas.
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▪ Autothermal Reforming (ATR)
• ATR is similar to steam methane reforming, but it uses both steam and oxygen to convert natural
gas into hydrogen and carbon monoxide. C
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▪ Partial Oxidation (POX)
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• This method involves partially oxidizing hydrocarbons (like methane) with oxygen to produce
hydrogen and carbon monoxide, which can later be processed to extract more hydrogen.
• Several newer methods and technologies are being explored for hydrogen production:
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• This involves using high temperatures (from nuclear reactors or concentrated solar power) to
split water molecules into hydrogen and oxygen.
• Hydrogen can be produced by converting various types of waste (such as municipal solid waste
or plastic waste) into hydrogen through gasification, pyrolysis, or other chemical processes.
❖ Electrolysis of Water:
• The process of splitting water into hydrogen and oxygen by means of a direct electric
current is known as electrolysis.
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• In principle, an electrolysis cell consists of two electrodes, commonly flat metal or carbon
plates, immersed in an aqueous conducting solution called the electrolyte.
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• A source of direct current voltage is connected to the electrodes so that an electric current
flows through the electrolyte from the positive electrode (or anode) to the negative
electrode (or cathode).
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• As a result, the electrolyte (water) solution is decomposed into hydrogen gas (H2) which
is released at the cathode, and oxygen gas (O2); released at the anode
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• An oxidation reaction occurs when water molecules give electrons to the anode and
liberate oxygen gas at the anode.
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• When water is subjected to extremely high temperatures, the molecular bonds between
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hydrogen and oxygen atoms break. The required energy to decompose water increases as the
temperature rises. Generally, the reaction requires temperatures of around 2000°C or higher
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to be thermodynamically efficient.
• The reaction that occurs during thermal decomposition of water is:
2H2O→2H2+O2
• At high temperatures, water molecules split into hydrogen and oxygen gases.
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• Heating Water: The water is heated using an external heat source such as a nuclear reactor,
concentrated solar power, or other high-temperature sources.
• Thermal Decomposition: At high temperatures (above 2000°C), the heat provides enough
energy to overcome the bond energy between hydrogen and oxygen atoms in the water
molecules, leading to the breaking of the H-O bonds.
• Hydrogen and Oxygen Formation: The decomposition reaction results in the formation of
hydrogen gas (H₂) and oxygen gas (O₂).
• Water (H₂O) is introduced into the system and heated to a very high temperature,
typically between 500°C to 1000°C.
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• The heat source can be nuclear reactors, concentrated solar power, or industrial waste
heat.
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• Water undergoes chemical reactions with specific compounds (like sulphur, iodine, or
copper-chlorine) in a closed cycle.
• These reactions help break the bonds in water molecules (H₂O) at lower energy levels
than direct water splitting.
• The reactions produce hydrogen gas (H₂) and oxygen gas (O₂) in different stages.
• Hydrogen is collected for storage and use, while oxygen is released or used in industrial
applications.
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• Microorganisms such as bacteria or algae are selected based on their ability to produce hydrogen.
• Organic materials like food waste, agricultural waste, or water are prepared as input for the process.
• A bioreactor is set up to provide suitable conditions such as temperature, pH, and light availability
for microbial activity.
• The microorganisms break down the organic material or water to produce hydrogen gas.
• In dark fermentation, bacteria break down organic waste without oxygen, releasing hydrogen and
byproducts like carbon dioxide and organic acids.
• In photo fermentation, photosynthetic bacteria use sunlight to convert organic acids into hydrogen
gas.
• In bio photolysis, algae or cyanobacteria use sunlight to split water molecules into hydrogen and
oxygen.
• The produced hydrogen gas is collected from the bioreactor using a gas collection system.
• Byproducts such as carbon dioxide, organic acids, or oxygen are separated and removed.
• The collected hydrogen gas is stored, compressed, or directly used for applications like fuel cells,
electricity generation, or hydrogen-powered vehicles.
➢ Compressed Gas
• In this method, hydrogen is stored in its gaseous form by compressing it to high pressures, typically
in the range of 200–700 bar, inside specially designed strong cylinders or tanks.
• These tanks are often made of steel or lightweight composite materials with safety valves and
pressure regulators to prevent accidents.
• This method is relatively simple and widely used because it does not require extremely low
temperatures like cryogenic storage. However, the main limitation is that hydrogen has low energy
density per unit volume, even at high pressures, which means large and heavy tanks are needed
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to store sufficient fuel.
➢ Cryogenic Liquid Storage
• In the cryogenic liquid storage method, hydrogen is stored in its liquid state at extremely low
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temperatures. Hydrogen becomes liquid at –253 °C (20 K) under atmospheric pressure. To
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maintain it in this state, special double-walled, vacuum-insulated cryogenic tanks are used to
minimize heat transfer and evaporation.
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creating metal hydrides. When hydrogen gas is passed over these metals under suitable pressure
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and temperature, the metal absorbs the hydrogen atoms into its crystal lattice, forming a stable
compound. Later, when heat is supplied, the hydrogen is released back in gaseous form.
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➢ Hydrogen Pipelines
• Hydrogen can be delivered through dedicated underground pipelines similar to natural gas.
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Best suited for continuous, large-scale industrial supply over long distances.
Requires leak-proof systems and materials resistant to hydrogen embrittlement.
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➢ Metal Hydrides
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• Hydrogen is absorbed into special metal alloys and later released by heating.
• Safe and compact method but adds weight and cost.
• Useful for portable applications and military use.
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• Hydrogen can be used in fuel cells to generate electricity, or power and heat.
• Petroleum refining
• Glass purification
• Semiconductor manufacturing
• Aerospace applications
• Fertilizer production
• Welding, annealing and heat-treating metals
• Pharmaceuticals
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❖ Problem associated with Hydrogen Energy
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➢ Hydrogen Storage - Storage and transportation of hydrogen is more complex than that required
for fossil fuels. This implies additional costs to consider for hydrogen fuel cells as a source of
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energy.
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➢ Hydrogen Extraction- Despite being the most abundant element in the Universe, hydrogen does
not exist on its own so needs to be extracted from water via electrolysis or separated from carbon
fossil fuels. Both of these processes require a significant amount of energy to achieve. This energy
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can be more than that gained from the hydrogen itself as well as being expensive.
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➢ Overall Cost - The cost for a unit of power from hydrogen fuel cells is currently greater than other
energy sources.
➢ Introduction:
• The energy obtained from organic matter, derived from biological organisms like
Plants and animals is known as Biomass energy.
• Animals feed on plants, and plants grow through the photosynthesis process using solar
energy Thus, photosynthesis process is primarily responsible for the generation of
biomass energy.
• A small portion of the solar radiation is captured and stored in the plants during
photosynthesis process. Therefore, it is an indirect form of solar energy.
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➢ Photosynthesis
• Photosynthesis in the plant is an example of biological conversion of solar energy into
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sugars and starches which are energy rich compounds.
Radiant energy of sun is absorbed by the green pigment chlorophyll in the plant and
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stored with in the plant in the form of chemical bund energy.
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• In green plants, both photosynthesis and respiration occur during the day and only
respiration at night.
• The energy produced in the plants by respiration is used in several processes such as
to draw moisture and nutrients through its roots.
• The process of photosynthesis and respiration can be represented in the following
diagram.
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• The uptake of CO2 by a plant leaf is a function of many factors, especially temperature,
CO2 concentration and the intensity of solar light.
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• Solar radiation incident on a leaf is reflected, transmitted and absorbed. Part of the
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absorbed radiation provides the energy, it’s stored during the photosynthesis and
produces oxygen and carbohydrate.
• Anaerobic Digestion is a biochemical degradation process that converts complex organic material, such as biomass
& animal manure, into methane and other by products in the absence of oxygen.
• It is widely used for waste management, renewable energy production, and environmental protection. The process
converts biodegradable materials such as food waste, animal manure, sewage sludge, and agricultural residues into
biogas and digestate.
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1. Hydrolysis:
• Biomass is normally comprised of very large organic polymers, which are unusable.
• Through hydrolysis, these large polymers, namely proteins, fats and carbohydrates, are broken down
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into smaller molecules such as amino acids, fatty acids, and simple sugar.
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2. Fermentation (Acidogenesis):
• It is the next step of anaerobic digestion process in which acid forming bacteria further break down
the Biomass products and produce an acidic environment in the digestive tank while creating ammonia,
H2, CO2, shorter volatile fatty acids, carbonic acids, alcohols, as well as trace amounts of other by
products.
• While organic product, it is still too large and unusable so the biomass must next undergo the process
of acetogenesis for the ultimate goal of methane production.
3. Acetogenesis
• Acetogens break down the Biomass further to a point to which Methanogens can utilize much of the
remaining material to create Methane as a Biofuel.
4. Methanogenesis:
• Methanogenesis constitutes the final stage of anaerobic digestion process in which methanogens create
methane from the final products of acetogenesis as well as from some of the intermediate products
from hydrolysis and acidogenesis.
• It is used in India is known as KVIC plant - This mainly consists of a digester or pit for
fermentation and a floating drum for the collection of gas.
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➢ Construction:
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• The digester is a deep circular pit or a well, built of bricks of 3.5-6.5 m in depth and 1.2 to 1.6
m in diameter and there is a partition wall in the centre, which divides the digester vertically
and submerges in the slurry when it is full.
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• In the inlet slurry mixing tank dung mixed with water (4:5) and loaded into the digester
through inlet pipe.
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The digester is connected to the outlet tank through outlet pipe for removal of spent slurry.
• Gas holder dome is an inverted steel drum resting above the digester, the drum can move up
and down i.e., float over the digester and it has an outlet at the top which could be connected to
the storage tank.
➢ Working:
• Initially slurry is prepared in the mixing tank and it’s fed into the inlet chamber of the digester
through the inlet pipe.
• The plant is left unused for about two months and introduction of more slurry is also stopped.
• During this period, anaerobic fermentation of biomass takes place in the presence of water and
produces biogas in the digester.
• Biogas being lighter rises up and starts collecting in the gas holder dome and this dome now
starts moving up and starts floats freely on the surface of the slurry.
• Gas holder dome after reaching a certain level it cannot rises up as more & more gas starts
collecting, more pressure begins to be exerted on the slurry.
➢ Construction:
• Figure represents the schematic diagram of a fixed dome type biogas plant called as Janta model or Chinese
model of biogas plant.
• It is similar to KVIC model except that both the digester and gas holder are constructed in a fixed dome
usually below the ground surface.
• In the slurry mixing tank dung mixed with water (4:5) and loaded into the digester through inlet pipe.
• Digester is a huge tank with a dome like ceiling which has an outlet with a valve for the supply of biogas.
• The digester is connected to the outlet tank through outlet pipe for removal of spent slurry or sludge.
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➢ Working:
• Initially slurry is prepared in the mixing tank and it’s fed into the inlet chamber of the digester through the inlet
pipe.
• When digester is partially filled with the slurry, the introduction of slurry stopped and plant is left unused for about
two months.
• During this period, anaerobic fermentation of biomass takes place in the presence of water and produces biogas
which starts collecting in the dome of the digester.
• As more and more biogas starts collecting, the pressure exerted by the biogas forces the spent slurry into the
outlet chamber.
• From the outlet chamber, the spent slurry overflows into the overflow tank which is manually removed and used
as manure for plants.
• The gas valve connected to a system of pipelines is opened when a supply of gas is required.
• Biogas, mainly composed of methane (CH₄) and carbon dioxide (CO₂), can be transported from the production
site (like a biogas plant) to the point of use using the following methods:
➢ Pipeline Transportation
• Biogas can be transported through pipelines for short distances, usually within a radius of 5 to 10 km. After
purification to remove moisture, hydrogen sulphide, and carbon dioxide, the gas is slightly pressurized and
distributed through underground or above-ground pipelines.
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vehicles, generators, or rural households.
• Availability of raw materials like dung or organic waste can be seasonal or insufficient.
➢ Lack of Technical Knowledge:
• Many users lack proper training to operate and maintain biogas plants efficiently.
➢ Gas Impurities:
• Biogas often contains hydrogen sulphide and moisture, which can corrode equipment and reduce gas quality.
➢ High Initial Cost:
• Setting up a biogas plant requires significant investment, which may not be affordable for small users.
➢ Maintenance Issues:
• Poor construction and lack of regular maintenance can lead to leakages and reduced gas output.
➢ Low Public Awareness:
• Social acceptance and awareness about the benefits of biogas are still limited in many areas
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➢ Industrial Use:
• Industries use biogas for steam generation, drying, or as a replacement for furnace oil in boilers.
➢ Agricultural Use:
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The digestate (slurry left after biogas production) is a nutrient-rich organic fertilizer for crops.
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➢ Waste Management:
• Biogas plants help manage organic waste from households, farms, and industries, reducing pollution and odors.
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• Power Generation: Biogas is used in internal combustion engines to generate electricity in biogas power plants.
• Pumping Water: Biogas-powered engines are used in agriculture for running water pumps in rural areas.
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• Vehicle Fuel: Upgraded and compressed biogas (CBG) can be used as an alternative fuel in vehicles (similar to
CNG).
• Industrial Engines: Biogas is used to run engines that drive equipment and machinery in small industries.
• Backup Power Systems: Biogas engines serve as a reliable backup power source during grid failures or in off-
grid locations.
❖ Advantages of Biogas
• Renewable Energy Source: Biogas is produced from organic waste, making it a sustainable and eco-friendly fuel.
• Reduces Waste: It helps in managing agricultural, animal, and kitchen waste by converting it into useful energy.
• Produces Organic Fertilizer: The by-product (slurry) from biogas plants is a nutrient-rich organic manure.
• Reduces Greenhouse Gases: Biogas reduces methane emissions from waste and lowers dependence on fossil
fuels.
• Low Operational Cost: Once installed, biogas plants have minimal running costs and require low maintenance.
• Improves Rural Energy Access: Biogas provides clean fuel for cooking, lighting, and power in rural areas.
• Geothermal comes from the Greek word, where ‘Geo’ refers to Earth, and ‘Thermo’ refers to Heat. The heat
procures from inside the earth’s crust. Generally, it is found distantly far below the earth’s burning molten rock
‘Magma’ and stored in the rocks and vapour in the earth's centre.
➢ Principle of Working:
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• Geothermal energy is heating energy that comes from inside the Earth's surface. The Earth's internal heat is stored
in the form of hot water and steam, which can be harnessed for generating electricity or for direct heating purposes.
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❖ Working Principle:
• Heat Extraction: Geothermal power plants use the Earth's natural heat from inside the surface. The heat is
contained in hot water or steam reservoirs deep underground. Wells (deep hole) are drilled into these reservoirs to
access the hot water or steam.
• Conversion to Mechanical Energy: The extracted steam is directed to a turbine. The high-pressure steam rotates
the turbine blades, converting thermal energy into mechanical energy.
• Electricity Generation: The turbine is connected to a generator. As the turbine rotates, the generator converts the
mechanical energy into electrical energy.
• Cooling: After the steam has passed through the turbine, it is condensed back into water using a cooling tower or
heat exchanger. The cooled water is then reinjected back into the ground to be reheated, ensuring sustainability.
• Distribution: The generated electricity is sent through power lines to homes and industries.
• A geothermal power plant uses steam obtained from these geothermal reservoirs to generate electricity. Wells are
drilled at the appropriate locations to bring this geothermal energy up to the surface. A mixture of steam and water
is collected from the production well. Steam separators are employed to separate the steam and use it to operate tur
steam turbines run the generators and, hence, electricity is generated. The condensed steam and the water collected
from the production well are injected back into the reservoir through the injection well.
• In this type of geothermal system, water is vaporised into steam at the lower level in the earth's crust. The steam
rises to the earth’s surface in a dry state (about 200°C and more than 2 MPa pressure). This dry steam can be used
conveniently and directly to run steam turbines and generate electric power. The schematic of such a system is
illustrated in Fig.
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• This is a major geothermal energy source, which is liquid dominated (hot water), and steam is obtained by the use
of a flash separator. The schematic arrangement of a flash steam open geothermal system is illustrated in fig
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a two-phase mixture of low quality (i.e., water dominated) steam. This low-quality mixture is then throttled in a
flash separator, further reducing the pressure but with a improved quality. Here the mixture gets separated into dry
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saturated steam and saturated brine. The dry steam from the separator is used to run turbines and generate electricity,
while the brine is pumped back into the ground.
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• Hot dry rocks are also termed Petro thermal systems. These are very hot solid rocks available in the earth's crust at
medium depths (2 to 5 km). The temperature of the dry rocks is of the order of 300°C, which is quite sufficient to
produce steam. These dry rocks in real hot condition, as there is no water contact. To exploit this hot energy source,
cold water is pumped into the hot rocks, which becomes hot and get evaporated. The hot water or steam so produced
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is passed through a suitable heat exchanger, to produce steam and run a steam turbine, for power generation. The
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(both thermal and chemical). This may make the water toxic and becomes hazardous to the animals and users.
3. Noise Pollution:
• In geothermal systems noise pollution is also a major problem. Exhausts, blow down and centrifugal separators
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work always with high noise, which is hazardous to the working people. The noise can be minimized by using
silencers and its effect on working people can be reduced by using noise protective devices.
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4. Atmospheric Pollution:
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• The harmful gases in the geothermal water after use will escape, (from the cooling tower, separator, etc.) and cause
atmospheric pollution. Hydrogen Sulphide (H2S} is highly toxic and harmful to the living beings.
5. Subsidence:
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• The removal of huge quantities of underground water causes land subsidence (collapse of ground layers and fall in
the ground level). Subsidence causes stressing of pipelines and damage to the structures/foundations. This problem
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