Understanding Atomic Nucleus and Its Properties
Understanding Atomic Nucleus and Its Properties
Nucleus:
The nucleus of an atom is at the centre. Most of the mass of an atom is at the centre. The
entire positive charge of an atom lies in the nucleus.
All atomic nuclei are made up of elementary particles called protons and neutrons. Proton
i s
the nucleus of the hydrogen atom. It has a
positive charge of 1.6 × 10–19 C having a mass of 1.6726 × 10-27 kg. This is nearly equal
to 1836 times the electron mass. Neutron is electrically neutral (i.e. neutron carries no
charge). Mass of neutron is slightly greater than that of the proton (1.6750 × 10-27 kg).
Both the proton and neutron together constitute the nucleus. They are called nucleons.
Generally, atomic number is denoted by Z and mass number is denoted by A and (A-Z)
gives
number of neutrons (N) in the nucleus.
N A Z ; A = Z + N
Nucleus is positively charged and its shape is
considered as spherical.
Types of Nuclei:
Isotopes: Atomic nuclei having same atomic number but different mass numbers are
known as isotopes. They occupy same position in the periodic table and possess identical
chemical properties. They have same proton number.
Ex: 1) 3Li6, 3Li7 2) 1H1,1 H2,1 H3
Isotones : Atomic nuclei having same number of neutrons are called isotones.
Ex.: 1) 17Cl37,19 K39 , 2) 7 N17 ,8 O18 ,9 F19
Isobars: Atomic nuclei having same mass number but different atomic numbers are
called Isobars. They have same number of nucleons.
Ex.:1) 18Ar40,20 Ca40 , 2) 32 G e 7 6 ,3 4 S e 7 6
Isomers: Atomic nuclei having same mass
number and same atomic number but different nulear properties are called isomers.
Ex:- m 35 Br 80 metastable Bromine and g35 Br 80 ground state Bromine are two isomers
with different half lives
Isodiaphers : Nuclei having different Atomic number (Z) and mass number (A) but with
same excess number of neutrons over protons (A-2Z) are called isodiaphers.
23 27
Ex:- 11 Na , 13 Al
Size of the Nucleus:
Nuclear sizes are very small and are measured in fermi (or) femtometer. 1
fermi=10-15m
1
3
Radius of the nucleus depends on number of nucleons. R R0 A
above equation does not apply to heavy nucleides
Value of Ro = 1.4 x 10-15m
Radius of the nucleus is in the order of 10-15 m.
Size of an atom is in the order of 10-10m.
If an -particle with an initial kinetic energy E
approaches a target of atomic number Z, if the distance of closest approach is “d” then
1 2 e 2
E (Where ‘e’ is charge of an electron) If “v” represents the initial velocity of
4 d
1 2 e 2 1 2
particle, (m is mass of “ ” particle) then 4 mv
d 2
Note : If a particle of charge q, mass m is projected towards a nucleus of charge Q with
1 qQ 1 2
velocity v from infinity then the distance of closest approach d is give by 4 d 2 mv
Note : If R, S and V be the Radius, surface area and volume of a nucleus with mass
number A then
1 2
1 2
R 1 A 1 3 A 3
; S R A 3 1 1
2 S
R A3
R2 A2 S 2 A 2
V1 A
V R3 A 1
V2 A 2
Note : If a stationary nucleus splits in to two lighter nuclei with mass numbers A1 and A2
then according to law of conservation of linear momentum, the two lighter nuclei move in
opposite directions with equal momenta hence m1v1 = m2v2
Ratio of velocities of the two nuclei
v1 m 2 A 2 R 2
3
v 2 m1 A1 R 1
Q m A R 3
Ratio of kinetic energy of the two nuclei
KE1 m 2 A 2 R 2
3
KE 2 m1 A1 R 1
2
Q KE p & KE 1 when p is constant
2m m
Density of the Nucleus:
Density of nucleus is independent of mass number of the atom.
Density of the nucleus is 1.45 x 1017 Kgm-3.
The density is maximum at the centre and gradually falls to zero as we move radially out
wards.
Radius of the nucleus is taken as the distance
between the centre and the point where the density falls to half of its value at the centre.
Density of nucleus is of the order of 1014 gm / cc 1017 kg / m3
EX. 1: Compare the radii of the nuclei of mass numbers 27 and 64.
[Link] ratio of the radii of the nuclei is
1 1
R1 A1 3 27 3 3
= (Q R = R0A1/3) =
R2 A2 64 4
16
EX. 2: The radius of the oxygen nucleus 8 O is 2.8 x 10-15m. Find the radius of lead
nucleus 205
82 Pb .
40 Fe 56 Region of
8.79ONeCa Greater stability
C
He 40 A 180
NF
7.6
Li
2
1 H
1
0 50 100 150 200 210
Mass number (A)
The main features of binding energy curve shown in figure are :
1) The minimum value of binding energy per nucleon is in the case of deuteron (1.11MeV).
BE
2) The maximum value of is 8.7MeV for the nucleus 28Fe56 (iron) which is the most
A
stable.
3) Binding energy is high in the range 28<A<138. The binding energy of these nuclei is very
close to 8.7 MeV.
4) Further increase in the mass number, binding energy per nucleon decreases and
consequently for the heavy nuclei like uranium it is 7.6 MeV.
5) In the region of smaller mass numbers, the binding energy per nucleon curve shows the
characteristic minima and maxima. Minima are associated with nuclei containing an odd
number of protons and neutrons such as 36 Li,10 14
5 B,7 N and the maxima are associated
with nuclei having an even number of protons and neutrons such as 42 He,12 16
6 C,8 O .
6) Nuclei with A > 220 are distinctly unstable. That means from A > 220 single heavy nucleus
breaks into two nearly equal nuclei with mass number A < 150 and so which are most
stable. This process takes at right of the BE curve as shown in figure . This process
explains the nuclear fission.
7) Light nuclei such as hydrogen combine to form heavy nucleus to form helium for greater
stability. This process takes at left of the BE curve as shown in figure. This process
explains the nuclear fusion.
Binding energy per nucleon (Mev)
Ene
rgy+
ergy +
En
+
Note : Iron 28 Fe56 whose binding energy per nucleon stands maximum at 8.7 MeV is most
stable and will undergo neither fission nor fusion.
Exo-ergic Reaction : The reaction in which energy will be released is
called exo-ergic Reaction. A+B C+D+Q
Here A and B are called Reactants
C and D are called Products
Q is the amount of energy released
In an Exo - ergic Reaction
Mass of reactants > Mass of products
m MR MP MA MB MC MD
Energy Released Q m C2 joule [ m is in kg]
m931.5 MeV ( m is in amu)
If Binding energies are given then for Exo-ergic reactions.
(B.E) Products > (B.E) Reactants.
Energy released Q = (B.E)P – (B.E)R
= [(B.E)C + (B.E)D] – [(B.E)A + (B.E)B]
Endo-ergic Reaction : The reaction in which energy will be absorbed is called Endo-
ergic Reaction. A + B C + D – Q
Here A and B are called Reactants
C and D are called Products
Q is the amount of energy absorbed
In an Endo - ergic Reaction
mass of reactants < Mass of products
m MP MR MC MD MA MB
m = Zm p A Z mn M n
= { (20 x 1.007825+(20x1.008665)} - 39.962589
= 40.329800 - 39.962589 ; m = 0.3672111
Binding energy per nucleon =
m 931 0.367211 931
= 8.547 MeV .
A 40
EX. 6 : The binding energies per nucleon for deuterium and helium are 1.1 MeV and 7.0 MeV
respectively. What energy in joules will be liberated when 2 deuterons take part in the reaction.
Sol. 12 H 12 H 24 He Q
Binding energy per nucleon of helium ( 24 He ) =7 MeV
Binding energy = 4 x7 = 28 MeV
Binding energy per nucleon of deuterium ( 12 H )=1.1MeV
Binding energy = 2 x 1.1 = 2.2 MeV
Energy liberated (Q) = (28 -(2.2)2] = 23.6 Mev.
i.e. Q=23.6x106x1.6x10-19; Q 37.76 1013 J
EX. 7: The kinetic energy of -particles emitted in the decay of 88Ra226 into 86Rn222 is measured
to be 4.78 MeV. What is the total disintegration energy or the ‘Q-value of this process’ ?
Sol. The standard relation between the kinetic energy of the -particle (KEa) and the Q-value (or total
disintegration energy) is
A- 4 A
KEa = .Q Q= .KEa
A A- 4
226 226
4.78MeV 4.78MeV
226 4 222
Q 4.865 MeV 4.87MeV
EX. 8: A nucleus X-initially at rest, undergoes alpha-decay, according to the equation.
A
92 X 228
z Y
The α -particle in the above process is found to move in a circular track of radius 1.1102 m
in a uniform magnetic field of 3.0 103 T .
The energy (in MeV ) released during the process and binding energy of the parent nucleus
X, respectively.
Given: m y 228.03 amu ; m 4.003amu , m 10 n 1.009 amu ; m 10 H 1.008 amu ,
1 amu 1.66 1027 ; kg 931.5 MeV / c 2
A
Sol: The given equation is 92 X 228
z Y 42 He
A 228 4 232 ; 92 z 2 z 90
m v2 rqB
qv B ; v
r m
1.1 102 2 1.6 1019 3 103
4.003 1.66 1027
4.0 106 m / s
From conservation of linear momentum, m v my v y
m v 4.003 4.0 10
6
vy 7.0 104 m / s
my 228.03
1 1.66 1027
There fore, energy released during the process m v my v y
2 2
2 2 1.6 1013
4.003 4.0 106 2 228.03 7.0 104 2 MeV
0.34
0.34 MeV amu 0.000365amu
931.5
232
Therefore, mass of 92 X m y m 0.000365
232.033365 u
Mass defect m 92 1.008 232 92
1.009 232.033365 .
Binding energy 1.962635 931.5 MeV
1828.2 MeV
Natural radio activity :
Spontaneous decay of naturally occurring unstable nuclei by emission of certain
sub particles (like , , and radiation) is called natural radio activity..
The emission of these rays takes place because of the instability of the nucleus. In the
process of emitting these rays a nucleus tries to attain the stability.
In general natural radioactivity takes place in heavy nuclei beyond lead in the periodic
table. There are also naturally radioactive light nuclei, such as potassium isotope 19 K40 ,
the carbon isotope 6C14 and the rubidium isotope 37 Rb87 .
Regarding radioactivity.
i) It is completely uneffected by the physical and chemical conditions to which the nucleus
is subjected i.e we cannot change the radio activity by applying high temperature, high pressure
and strong electric field etc.
ii) The nucleus can disintegrate immediately (or) it may take infinite time.
iii) The energy liberated during the radioactive decay comes from individual nuclei.
Modes of Decay:
The radioactive nucleus before decay is called a parent nucleus, the nucleus resulting from
its decay by particles (Radiation) emission is called daughter nuclei.
This daughter nuclei may be stable (or) unstable.
X
Y R Q
Parent Daughter Radiation Energy
Here R may be either particle (or) particle (or) radiation. Q is the energy of the emitted
particles (or radiation).
-decay : When a nucleus disintegrates by radiating -rays, it is said to undergo -decay.. An
- particle is a helium nucleus. Thus a nucleus emitting an particle losses two protons and two
neutrons, as a result its atomic number Z decreases by 2, the mass number A decreases by 4 and the
neutron number N decreases by 2.
A
zX z 2 Y A 4 2 He 4 Q
226
Ex: 88 Ra 86 Rn 222 2 He 4 4.87MeV
Both electric charge and nucleon number are conserved in the process of decay..
Application : When a stationary Radio active nucleus x decays into another nucleus y by emitting
an -particle. x y particle Q
Applying LCLM if particle moves forward with a momentum ‘P’ then daughter nucleus y
recoils with same momentum ‘P’ so that total momentum of the system is zero. Hence Py P
The energy released ‘Q’ is in the form of K.E of daughter nucleus ‘y’ and ‘ ’ particle.
Q KE y KE
KE y M
Ratio of kinetic energies KE M
y
P2 1
( KE and KE when ‘P’ is same)
2m m
KE y M KE KE y M y M
1 1
KE My ; KE My
M y
KE Q M
M M y KE y Q
; M M y
Z X A Z1 Y A 1 e 0 .
Ex: 90 Th 234 91 Pa 234 1 e 0
Both electric charge and nucleon number are conserved in decay also.
-Decay: When a nucleus disintegrates by radiating rays, it is said to undergo decay..
Gamma rays are nothing but electromagnetic radiations of short wavelengths (not exceeding
10–10m.)
The emission of rays from the nucleus does not alter either atomic number Z or mass number
A. It just results in the change of the energy state of a nucleus.
When a parent nucleus emits an or a particle, the daughter nucleus may be formed in one of
excited states. Such a nucleus will eventually comes to the ground state. In this process radiation
will be emitted.
Z X A Z X A Photon( s)
87
Example: 38 *Sr 38 Sr 87 .
38 Sr is isomer of 38 Sr .
Note :When a Radio active nucleus emits an - particle followed by two - particles, its isotope is
formed.
A 2
Z 2Y A4
Z X Z X A4
Note :When a Radio active nucleus emits a - particle its isobar is formed.
A
Z 1Y A
Z X
Note: When a Radio active nucleus emits a - particle its isomer is formed
A A
Z X
Z X
Deflection of Radioactive radiations in electric and magnetic fields :
E
B
Ra
Ra
Lead block
B
X X X X
X X X X
X X X X
Ra
Lead block
EX. 9: The nucleus 2310Ne decays by emission. Write down the -decay equation and determine
the maximum kinetic energy of the electrons emitted. Given that :
m (2310Ne) = 22.994466u; m(2311Na)=22.989770 u
_ _
Sol. 23
10 Ne 2311 Na e v Q
For - decay, Q = [M(x) - M(y)]C2 = [22.994466-22.989770]931.5
= 0.004696 x 931.5 = 4.37 MeV
EX. 10: Calculate the binding energy of an -particle. Given that mass of proton = 1.0073u,
mass of neutron = 1.0087u. and mass of -particle = 4.0015u.
Sol. mP = 1.0073u, mN = 1.0087u, M = 4.0015u
N = A -Z =4 -2 =2 Q 2 He 4 Z X A
B.E = m x 931.5 MeV
= Zm p ( A Z ) mn M 931.5
82 Pb214 ?
Sol. Let n be the number of - particles and m be the number of - particles emitted.
238 214 4 0
U 82 Pb n2 He m 1e
92
N 0 0 0
This shows that the number of radioactive nuclei decreases exponentially with time.
Above equation is known as the decay law (or) the law of radio-active decay. It is an
exponential law.
N0
taking logarithm on both sides for the above equation. loge N = loge No - t ; t loge
N
1 N 0
t ln
N
Nx Ny
N0 N0
O time O t
(a) (b)
In(N0)
In(N)
time(t)
(C)
Activity (R) :
The number of decays per unit time (or) decay rate is called activity (R)
dN d
| R |
dt
dt
N0 e t (or) R N N0 et (or)
If a nucleus can decay simultaneously by n processes, which have activities R1, R2, ........... and Rn.
Then the resultant activity R = R1 + R2 +............... + Rn. If nucleus decays simultaneously more
than one process is called parallel decay.
The S.I unit of activity is Becquerel (Bq) and other units are curie (Ci) and Rutherford (Rd).
1 Bq = 1 decay per second,
1 Rd = 106 decays per second.
1 Ci = 3.7 × 1010 decays per second.
Note : Curie is approximately equal to the activity of one gram of pure radium.
Decay Constant ( ) : It gives the ability of a nucleus to decay. The decay constant for a given
radio active sample is defined as the reciprocal of the time during which the number of nuclei
1
decreases to times their original value.
e
N
N0
N0
e
0 1 t
N0 1
when N = , t T eT or 2 eT
2 2
taking logirthms on both sides ln 2 T
2.303log10 2 0.693
(or) loge 2 T T
ln 2 2.303log 2 0.693
T=
The above relation establishes that the half - life (T) depends upon the decay constant of the
radioactive substance. The value of is different for different radioactive substances.
Note :
i) Half life is the characteristic property of the sample and T cannot be changed by any known method.
ii) At any given instant whatever be the amount of the undecayed sample, it will be reduced to
exactly half its value after a time equal to the half life of the sample.
1 1 1 1
iii) In parallel decay 1 2 ........ n hence ........ , where T is the equivalent
T T1 T2 Tn
half-life and T1, T2 ...........Tn are the half-lives in individual decay.
Application :
In a radioactive sample the number of nuclides undecayed after n-half lives (i.e., t = nT) is
N n ln 2 1 N 0
t = nT
1
l n 0 or ln
N N
N0 1 n
or 2
n
; or N N
0
N 2
Note: The number of nuclei remain in the sample after half of half life period (t=1/2T) is given
1
1 n
N N here n 1 then N N 1 2
0
by 2 0 2
2
N0
N taking N0 = 100, N = 50 2 = 70.7
2
70.7% of nuclei remain and 29.3% of nuclei decayed.
(N/ N0)
1
T Half life
0.5
0.25
0.125
0.0625
0 time
T 2T 3T 4T
Average life (or) Mean life :
The phenomenon of radioactivity is random because we just can’t predict which of the atoms in a
given sample will decay first and when. Hence radioactivity process totally depends on chance. In
decay process some of the atoms of the given sample may have very short life span, and others
may not decay even after a very large span of time. So to determine the ability of the nucleus to
decay it would be useful to calculate the average life. Hence average life is defined as the total
life time of all the nuclei divided by the total number of original nuclei.
i.e
life span of individual nucleus t
Total number of original nuclei N0
Let N0 be the radio active nuclei that are present at t = 0 in the radioactive sample.
The number of nuclei which decay between t and (t + dt) is dN i.e the life time of these nuclei is ‘t’.
The total life time of these dN nuclei is (t dN)
t
The total life time of all the nuclei present initially in the sample = tdN [Q N = 0 at infinity]
t 0
R0
2 R0
e
0 T t
Determination of decay constant and half life period (T) of a radioactive sample graphically
If N0 and N be the number of atoms present undecayed initially and after a time t, then
We know that N=N0 e t taking log on both sides
t
log e N loge N 0 t log N log N 0
2.303
log N t log N 0
2.303
Slope of the graph m tan
2.303
2.303 tan
2.303 log 2
Half life period T
2.303 log 2
T T log 2 cot
2.303 tan
Note : In radioactive sample decay
N
1) The probability survival of nucleus after time Ps e t .
N0
N N0
log e 0 2.303log10 N
t N
In this problem, the initial number of active nuclei,
18
N = 6.0 1018 ; N 1.0 10 , T 40 s,
0
0.693 0.693
1.733 102 s 1.
T 40
6.0 1018
2.303log10
1.0 1018
t
2
1.733 10
1 1 1 TT
;T 1 2 .
T T1 T2 T1 T2
EX. 15: Plutonium decays with a half life of 24,000 years. If plutonium is stored for 72,000 years,
what fraction of it remains?
Sol. T1/2 = 24,000 years
Duration of time (t) = 72,000 years
t 72000
Number of half lifes (n) = T 3
1/2 24000
1 1 2 1 3 1
1g g g g
2 4 8
1
Fraction of plutonium remains = g
8
EX. 16: A certain substance decays to 1/32 of its initial activity in 25 days. Calculate its half -life.
1 1 1 1 1
Sol. 1g
1
g
2
g
3
g
4
g
5
g n 5
2 4 8 16 32
t t 25
n t1/2
t1/ 2 n 5 ; t1/2 5 days
EX. 17: The half -life period of a radioactive substance is 20 days. What is the time taken for 7/
8th of its original mass to disintegrate?
Sol. Let the initial mass be one unit.
7 1
Mass reamaining = 1
8 8
1
A mass of 1 unit becomes unit in 1 half life
2
1 1
unit becomes unit in 2nd half life
2 4
1 1
unit becomes unit in 3rd half life
4 8
Time taken = 3 half lifes = 3 x 20 = 60 days
238
EX. 18: How many disintegrations per second will Occur in one gram of 92 U , if its half-life
against -decay is 1.42 x 1017s?
0.693
Sol. Given Half -life period (T) =
1.42 1017 s
0.693
4.88 1018
1.42 1017
Avagadro number (N) = 6.023 1023 atoms
238 N
n = Number of atoms present in 1 g of 92 U
A
0.623 10 23
25.30 1020
238
dN
Number of disintegrations = n
dt
= 4.88 x10-18 x 25.30 x 1020 = 1.2346 x 104 disintegrates/sec
EX. 19: One gram of radium is reduced by 2 milligram in 5 years by -decay. Calculate the half-
life of radium.
Sol: Initial mass = 1 g, t = 5 years
2
Reduced mass = 2mg = 2 x 10-3 g = g
1000
2 998
Remaining mass = 1 -
1000 1000
N 998
(Q Mass Number of atoms)
N0 1000
N
e t ; 998 e t
N0 1000
1000 1000
et e5 log e 5
998 998
2.303 (3.0000 -2.9991) = 5
2.303 1 0.0009
5
0.693 0.693 5
(T1/2) = = 1671.7 years
2.303 0.0009
EX. 20: The half-life of a radioactive substance is 5000 years . In how many years, its activity will
decay to 0.2 times of its initial value? Given log105 = 0.6990.
Sol. T = 5000 years,
N 2 1
N 0 = 0.2 = 10 5
0.693 0.693
T 5000
N
e t
N0
1 1 t
= t 5 e
5 e
loge5 = t
2.303 0.6990 = t
2.303 0.6990 5000
t
0.693
t = 11614.6years 1.1615 104 years
60
EX. 21: Obtain the amount of 27 Co necessary to provide a radioactive source of 8.0 mCi strength.
60
The half -life of 27 Co is 5.3 years.
Sol. Half - life of 60 27 Co = 5.3 years
= 5.3x365x24 x 60 x 60 S = 5.3 x 3.15 x 107 s
103 x x 103
Now `x` gm of 60
27 Co contains
k - mole = 6.025 1026
60 60
N = 0.1004x x 1023 = 1.004 x x 1022 atoms
Required strength of 60 27 Co = 8 m Ci
= 8 x 10-3 x 3.7 x1010 dis/s
We know that, decay rate (R) = N
R 8 3.7 107
N
0.693 / T1/ 2
29.6 107
x5.3x3.15x107 = 713.0909 x 1014
0.693
1.004x x 1022 = 713.0909 x 1014
x = 710.2499 x 10-8 kg = 7.1 x 10-6 g
Artificial Transmutation of Elements
The conversion of one element into another by artificial means is called artificial
transmutation of the element. Rutherford performed number of experiments in which
the atoms of different stable elements, such as nitrogen, aluminium, phosphorus, etc,
were bombarded by high speed particles from natural radioactive substances. Finally
in 1919, he discovered the phenomenon of artificial transmutation.
B A B
S
R F M
Fig.
The apparatus used by Rutherford is as shown in Fig.
i. It consists of a chamber A provided with an adjustable rod, carrying a radio - active
substance R (Radium C).
ii. The side of the glass tube facing ‘R’ is covered by metal plate with a central hole which is
closed by a thin silver foil ‘F’.
iii. A screen ‘S’, coated with a fluorescent material like zinc sulphide is arranged infront of
the silver foil and the scintillations produced on it can be observed through the microscope
‘M’.
iv. The side tubes B, B were used to fill various gases in the chamber.
v. The source of - particles, Ra was placed on a small disc at R. Its distance from F was
adjustable.
vi. The radio-active substance emits -particles whose range in air was found to be about
7cm.
vii. When the glass tube is filled with nitrogen gas, scintillations are observed, even when ‘R’
is at a distance of 40cm from the foil.
viii. These particles producing scintillations can not be -particles as they can not have such
a long range.
ix. Rutherford concluded that nitrogen nucleus hit by an (2He4)-particle transmutes into
oxygen nucleus along with a proton (1H1).
x. The nuclear reaction causing artificial transmutation can be represented as 7N14+ 2He4
8O17 + 1H1
Thus an atom of nitrogen is transformed into an isotope of oxygen. This process is called
transmutation of elements.
* High energy - particles were used in the discovery of artificial transmutation and
neutron because - particles produce intense ionisation of the medium through which
they pass and can be stopped after travelling a few mm in air.
Significance :
i) It leads to the discovery of proton and neutron.
ii) It helps to produce radio isotopes.
iii) It helps to produce transuranic elements.
Radio isotopes and their uses:
Radio isotopes have very short half lives and hence used for various purposes.
1) Medical applications :
27
a) 13 Al 0 n1 11 Na 24* 2 He4
Radio – sodium is used to find out how a given medicine is circulated in the body. It is also
used to find out circulatory disorders in blood vessels.
31
b) 15 P 1 H2 15 P32* 1 H1
Radio – phosphorus is used in the treatment of skin diseases. It is also used for the
treatment of blood disorders.
127
c) 53 I 0 n1 53 I128* rays
Radio – iodine is used in the treatment of thyroid glands. Radio - iodine ( I131) is used for
diagnosis and treatment of brain tumor and for the study of pumping condition of heart.
59 1 60*
d) 27 Co 0 n 27 Co rays Radio – cobalt is used in the detection and
treatment of cancer
e) Radio-iron is used to detect anemia and treat anemia.
2) In Geology:
a) Radio carbon(C14) is used to determine the age of fossils by radio - carbon dating
b) Radio isotopes are used to determine the age of rocks by the ratio of U 238 to Pb 206
3) In industry :
a) Radio – isotopes are used to find the wear and tear of machine parts
b) Radio isotopes are used to detect flaws in metal structures
c) Radio isotopes are used for treatment of alloys such as quenching , annealing and
hardening.
d) Radio isotopes are used in the selection of appropriate lubricants.
4) In research: Radio - isotopes are used in the study of nuclear disintegrations of elements.
5) In food preservation: By exposing vegetables and other food stuffs to radiations from
radio - active isotopes, their shelf life can be increased.
6) In agriculture:
a) Radio phosphorus (P32) is used to study the uptake of phosphorus by plants using.
b) Radio sulphur (S34) is used to study the transport ofminerals in plants .
c) Radio zinc is used to develop new species of plants by causing genetic mutation.
d) Irradiation by - radiations of seeds to improve yields.
7) In Chemistry :
a) Radio oxygen (O18) is used to study the mechanisms of photosynthesis and hydrolysis of
ester
b) Radio isotopes are used in the chemical analysis of solubility of sparingly soluble salts
such as PbSO4 and AgCl and determination of trace amounts of elements in industrial
raw materials and products.
Neutron
It is electrically neutral and its mass is slightly greater than that of proton. It was discovered
by chadwick
Bothe – Becker equation:
9 4 13
4 Be 2 He 6 C 6 C12 0 n1
Note : If only x% of energy released in fission is converted into electrical energy then out
x nE
put power of reactor is P
100 t
Note: If ‘x’gm of fuel with mass number ‘A’ completely undergo nuclear fission in time t
sec in a reactor then its power is given by
x
Number of moles in x gm of fuel =
A
x
Number of atoms (nuclei) present in x gm of fuel n N A . Where NA is Avogadro
A
number
nE xN A E
power P P
t At
Uses of Nuclear Reactors:
1) To generate electric power.
2) To produce nuclear fuel plutonium -239 and other radioactive materials which have a
wide variety of applications in the fields of medicine, industry and research.
Uses of atomic energy :
1. Generation of electric power : The coolant in a nuclear reactor absorbs the heat
generated as a result of the chain reaction and it releases the heat to the water which is
converted into high pressure steam. This steam is used to drive turbine and operate the
electric generator.
2. Production of radio isotopes : A small amount of the pure element is placed in an
aluminium container and the container is placed in the reactor for a few days. The element
absorbs neutrons and the element becomes radioactive isotope.
127
53 I 0 n1 53 I128* .
Radioiodine obtained in this way can be used to treat the thyroid gland. These radio
isotopes have a number of applications in the field of medicine , agriculture, industry and
basic research.
3. Source of neutrons : A large number of neutrons are produced in a reactor. They are
used in research . The effect of neutrons on biological tissues is studied. A new branch of
physics called Neutron Physics has come up.
4. Atomic energy is used to create artificial lakes, to divert the course of a river , to make
tunnels for laying new railway tracks etc.
5. Atomic energy is used for driving automobiles, submarines and war - planes.
6. Atomic energy is used in war - fare for creating destructive atom bombs and hydrogen
bombs.
Nuclear Fusion:
The phenomenon in which two lighter nuclei combine to form a heavier nucleus of mass
less than the total mass of the combining nuclei is called nuclear fusion. This mass
defect appears as energy.
At temperatures of about 107K, light nuclei combine to give heavier nuclei. Hence, fusion
reactions are called thermo nuclear reactions.
Nuclear fusion takes place in the sun and other stars.
Energy produced in a single fission of 92U235 is larger than that in a single fusion of
Hydrogen into Helium.
But fusion produces more energy than fission per nucleon.
In fission, 0.09% of mass is converted into energy. In fusion 0.66% of mass is converted
into energy.
Hydrogen bomb is a fission – fusion bomb.
Stellar and solar energy:
Stellar and solar energy is due to fusion.
The cycles that occur are. Proton - Proton Cycle & Carbon - Nitrogen Cycle
Proton - Proton Cycle:
The Thermonuclear reactions involved are:
1 1 2 0
2( H )+2( H ) 2( H ) + 2( e ) + Q1
1 1 1 +1
21H 2
2 1 H 1
2 2 He Q2
3
3 3 4 2
He + He ( He ) + 2( H ) + Q3
2 2 2 1
On adding up these reactions, we obtain.
1 4 0
4( H ) He + 2 e + Q
1 2 +1
Where Q Q1Q2 Q3 is the total energy evolved in the fusion of 4 hydrogen nuclei (protons)
to form Helium nucleus. The value of Q as calculated from mass defect comes out to be
26.7MeV
Carbon - Nitrogen Cycle:
Proposed by bethe. It consists of following reactions.
13 13 0
6 C 12 1 H 1 7 N 13 Q1 ; N C +( e )+ Q2
7 6 1
13 1 14
6 C 1 H 7 N Q3 ; 7 N 1 H 8 O15 Q4
14 1
15 15 0
O N +( e )+ Q5 ;
8 7 +1
15
7N 1 H 1 6 C 12 2 He 4 Q6
On adding all these 6 equations, we get
1 4 0
4 H He + 2( e )+ Q
1 2 +1
Where Q Q1Q2 Q3Q4Q5Q6 The value of Q as calculated from mass defect is 26.7
Mev.
In the sun both proton - proton cycle and
carbon- nitrogen cycles occur with equal
probabilities. In stars, whose interior temperatures are less than that of the sun, proton -proton
cycle dominates the energy generation. Again in stars, whose interior temperatures are more
than that of the sun, the energy generation is mainly due to carbon- nitrogen cycle.
The core temperature of heavier stars may be larger than that of the sun and much larger
nuclei may be formed.
NOTE: Due to enormous energy released in Sun and Stars the atmosphere of them will
be in ionised state which is called Plasma (Which contains fast moving neutrons and
electrons). Nuclear fusion can not be controlled.
Nuclear Fission Nuclear Fusion
1) Neutrons are required 1) Protons are required
for it for it
2) It is possible at normal 2) It is possible at high
pressure and temperature pressure and temperature
3) Energy released per 3) Energy released per
nucleon 0.9Mev nucleon 6Mev
4) % of mass getting 4) % of m ass getting
converted into energy converted into energy
=0.1% =0.7%
5) Fissionable materials 5) Fusion materials
are expensive are cheap
6) Harmful reactions 6) Harmful reactions
are produced are not produced
EX. 22: An explosion of atomic bomb releases an energy of 7.6 x 1013 J. If 200 MeV energy is released
on fission of one 235 U atom calculate (i) the number of uranium atoms undergoing fission. (ii) the
mass of uranium used in the atom bomb
Sol:E=7.6x103J;Energy released per fission = 200 MeV
= 200 106 1.6 x 10-19 = 3.2 x 10-111 J
Total energy
Number of uranium atoms (n) =
Energy per fission
7.6 1013
n 11
= 2.375 1024 atoms
3.2 10
Avagadro number (N) = 6.023×1023atoms
Mass of uranium =
n × 235 2.375 × 1024 × 235
= = 92.66g
N 6.023 × 1023
EX. 23: Calculate the energy released by fission from 2 g of 23592U in kWh. Given that the energy
released per fission is 200 MeV.
Sol. Mass of uranium = 2g
Energy released per fission = 200 MeV
= 200 x 106 x 1.6 x 10-19 = 3.2 x 10-11 J
Number of atoms in 2 gram of uranium is
2 6.023 1023
n = 5.125 1021 atoms
235
Total energy released = No. of atoms x energ released per fission
= 5.125 x 1021 x 3.2 x 10-11 = 16.4 1010J
Energy in Kwh =
16.4 1010
Kwh
36 105
= 0.455 105 Kwh = 4.55 104 Kwh
EX. 24: 200 Mev energy is released when one nucleus of 235U undergoes fission. Find the number
of fissions per second required for producing a power of 1 megawatt.
Sol. Energy released = 200MeV
= 200 x 106 x 1.6 x 10-19 = 3.2 x 10-11J
P = 1 mega watt = 106 watts.
Total energy
[Link] fissions per second (n)= Energy per fission
106
n= 11
3.125 1016 Fissions
3.2 10
EX. 25: How much 235U is consumed in a day in an atomic power house operating at 400 MW,
provided the whole of mass235U is converted into energy?
Sol. Power = 400 MW = 400 x 106 W;
time = 1 day = 86, 400 s.
Energy produced , E = power time = 400 106 86,400 = 3.456 1013 J.
As the whole of mass is converted into energy , by Einstein's mass -energy relation.
E = Mc2
E 3.456 1013
2
8 2
3.84 104 kg 0.384 g.
c (3 10 )
EX. 26: How long can an electric lamp of 100W be kept glowing by fusion of 2.0 kg of deuterium
? Take the fusion reaction as 21H+21H 32He+n+3.27 MeV
Sol. 1 H 2 1 H 2 32 He n 3.27 MeV
No. of atoms in 2 kg of 1H2 = 2/2 x 6.023 x 1026
= 6.023 x 1026 atoms
In the above reaction two deuterium nuclei are combined
Power (p) = w x rate of fusion.
Number of atoms
= 3.27 MeV x Time exp ended
6.023 1026
100 = 3.27 x 106 x 1.6 x 10-19 x
2x
3.27 1.6 6.023 1011
x = 15.756 x 10111S
2
15.756 1011 15.756 1011
= = =5x104 years
365 24 60 60 3.15 107
EX. 27: Suppose India had a target of producing by 2020 AD, 200,000 MW of electric power, ten
percent of which was to be obtained from nuclear power plants. Suppose we are given that,
on an avedrage, the efficiency of utilization ( i.e conversion to electric energy) of thermal
energy produced in a reactor was 25%. How much amount of fissionable uranium would our
country need per year by 2020 ? Take the heat energy per fission of 235U to be about 200 MeV.
Sol. Required power from nuclear plants
= 10% of 2,00,000 Mw = 2 x 1010w
Required electric energy from nuclear plants in one year = 2 x 1010 x 365 x24 x 60 x 60
= 2 x 1010 x 3.15 x 107 = 6.30 x107 J
Available electric energy per fission = 25% of 200 MeV = 50 MeV = 8 x 10-12J
6.30 1017
Req. no. of fissions per year = =0.7875x1029
8 10 12
0.7875 1029
Req. no. of moles of U238 = 23 =0.1307 x10
6
6.023 10
Required mass of U238 = 0.1307 x 235 x106 g
= 30.71 x106 gm = 30.71 x106 x 10-3 kg
= 0.03071 x 106 kg = 3.071 x 104 kg
EX. 28: Calculate the energy released by the fission 1 g of 235U in joule, given that the energy
released per fission is 200 MeV.
( Avogadro’s number = 6.023 1023 )
Sol. The number of atoms in 1 g of 235U
Avogadro ' s number 6.023 1023
= = 2.563 10 21
Mass number 235
Energy released per fission = 200 MeV
= 200 106 1.6 10 19 3.2 10 11 J .
Energy released by 1 g of 235U
= Number of atoms energy released per fission
= 2.563 1021 3.2 10 11 J 8.202 1010 J
EX. 29: In the process of nuclear fission of 1 gram uranium, the mass lost is 0.92 milligram. The
efficiency of power house run by it is 10%. To obtain 400 megawatt power from the power
house, how much uranium will be required per hour? (c = 3 x 108 ms–1)
Sol. Power to be obtained from power house = 400 mega watt\ Energy obtained per hour = 400 meagwatt
x 1hour = (400 x 106 watt) x 3600 second = 144 x 1010 joule
Here only 10% of input is utilised. In order to obtain 144 x 1010 joule of useful energy, the output
10 E
energy from the power house = 144 x 1010 J
100
E = 144 x 1011 joule
Let, this energy is obtained from a mass–loss of m kg.
Then m c 2 144 1011 joule
144 1011
m 16 105 kg = 0.16 g
8 2
3 10
Since 0.92 milli gram (= 0.92 x 10–3 g) mass is lost in 1 g uranium, hence for a mass loss of 0.16g,
1 0.16
the uranium required is 174 g
0.92 103
Thus to run the power house, 174 gm uranium is required per hour.
PAIR AND PRODUCTION AND PAIR ANNIHILATION : When an energetic - photon
falls on a heavy nucleus, it is absorbed by the nucleus and a pair of electron and positon
is produced. This phenomenon is called as pair production and can be represented by
the following equation:
hv 1 β0 1 β0
γ photon Positron electron
0
+1
photon
Heavy nucleus 10
The rest mass energy of electron or positron is:
2
E0 m0c 2 9.1 10 3 10
31 8
1 β0 1 β0 2hf
Positron γ photon
electron
+10
2 ( photon )
0
1
Additional information
Elementary particles :
We have realized, so far that there are only four fundamental constituents of matter. We
can describe various physical processes involving atoms, molecules and nuclei in terms
of electrons, protons, neutrons and photons. The first three are the building blocks of
atoms and hence matter. The fourth one (i.e photon) is the quantized energy which is
exchanged whenever electronic or nucleonic transition is involved.
Subsequently many more elementary particles and antiparticles have been discovered,
using giant and modern accelerating machines.
The particles which are not constituted by any other particles are called Elementary
particles. A brief discussion of important fundamental particles is as follows.
i) Electron : It was discovered in 1897 by Thomson. Its charge is –e and mass is 9.1 X 10–
31kg. Its symbol is e– (or 1 0 ). It is a stable particle having spin = 1/2
ii) Proton : It was discovered in 1919 by Rutherford in artificial nuclear disintegration. It has
a positive charge +e and its mass is 1836 times (1.673 X 10–27kg) the mass of electron.
In free state, the proton is a stable particle. Its symbol is P+. It is also written as 1 H 1 . It is
a stable particle having spin = 1/2.
iii) Neutron : It was discovered in 1932 by Chadwick. Electrically it is a neutral particle. Its
mass is 1839 times (1.675 X 10–27 kg) the mass of electron. In free state the neutron is
unstable. Inside the nucleus the neutron is stable. Its symbol is n (or) 0 n1 .
iv) Positron : It was discovered by Anderson in 1932. It is the antiparticle of electron, i.e., its
charge is +e and its mass is equal to that of electron. Its symbol is e+ (or 1 0 )
v) Antiproton : It is the antiparticle of proton. It was discovered in 1955. Its charge is –e and
its mass is equal to that of proton. Its symbol is P–.
vi) Antineutron : It was discovered in 1956. It has no charge and its mass is equal to the
mass of neutron. The only difference between neutron and antineutron is that their
magnetic momenta will be equal in magnitude and opposite in direction. The symbol
for antineutron is n .
vii) Neutrino and antineutrino : The existence of these particles was predicted in 1930 by
Pauli while explaining the emission of - particles from radioactive nuclei, but these
particles were actually observed experimentally in 1956. Their rest mass and charge are
both zero but they have energy and momentum. These are mutually antiparticles of each
other. They have the symbol and
viii) Pi - Mesons : The existence of pi - mesons was predicted by Yukawa in 1935, but they
were actually discovered in 1947 in cosmic rays. Nuclear forces are explained by the
exchange of pi-mesons between the nucleons. pi - mesons are of three types, positive
- mesons , negative pi-mesons and neutral - mesons . Charge on is
0
e. Whereas mass of is 274 times the mass of electron. 0 has mass nearly 264
times the electronic mass. These are unstable having half life 10–8 sec and spin = 0
ix) Mu-Mesons : These were discovered in 1936 by Anderson and Neddermeyer. These are
found in abundance in the cosmic rays at the ground level. There are two types of mu-
mesons. Positive mu-meson and negative mu-meason . There is no neutral
mu-meson. Both the mu-mesons have the same rest mass 207 times the rest mass of
the electron. These are unstable having half life 10–6 sec and spin = 1/2.
x) Photon : These are bundles of electromagnetic energy and travel with the speed of light.
h
Energy and momentum of a photon of frequency are h and respectively. They
c
posses no charge. no mass and spin = 1 and are stable.
xi) Gravitons : Hypothetical particles that carry gravitational energy are called Gravitons.
They possess no mass, no charge and spin = 2 as proposed by Dirac.
Antiparticles :An antiparticle is a form of matter that has the same mass as the particle
but carries an opposite charge and / or a magnetic moment that is oriented in an opposite
direction relative to the spin.
Name of the particle Antiparticle
Electron (e-1) Positron (e+1)
Proton(P )+ Anti proton (P-)
Neutron (n) Anti Neutron ( n )
Neutrino (v) Anti Neutrino ( v )
Positive Pi-Meson ( ) Negative Pi-Meson( )
Positive Mu-Meson( ) Negative Mu-Meson( )
Note: A few electrically neutral particles, like the photon and neutral meson are their
own antiparticles. A collision between a particle and an antiparticle results in annihilation
of matter.
Classification of particles based on spin
1) Bosons : These particles have spin in the integral multiples of unity
2) Fermions : These particles have spin in the integral multiples of 1/2.
Classification of particles based on rest mass
1) Photons : Particles with zero rest mass
2) Leptons : Lighter particles
3) Mesons : Particles with intermediate mass
4) Baryons : Heavier particles
Classification of particles based on interaction
1) Photons: representing electromagnetic interactions.
2) Leptons: representing weak interactions.
3) Hadrons: representing strong interactions.
4) Gravitons: representing gravitational interactions.
EX. 30: An electron-positron pair is produced when a -ray photon of energy 2.36MeV passes
close to a heavy nucleus. Find the kinetic energy carried by each particle produced, as well
as the total energy with each.
Sol. The reaction is represented by
( 1 e0 ) ( 1 e0 ), sothat
2
E m0C 2 K .E electron + m0C K .E positron 2.36MeV = 2m0.C2 K.E (electron) + K.E (positron)
= 1.02 MeV + K .E(e) K .E(e )
1
K.E. of (e ) K .E(e ) (2.36 1.02) MeV ,
2
(K.E. carried each) = 0.67 MeV (motional energy)
Total energy shared by each particle is obviously m0C 2 K.E 0.51MeV 0.67MeV = 1.18MeV..
EX. 31: A gamma ray photon of energy 1896 MeV annihilates to produce a proton-antiproton
pair. If the rest mass of each of the particles involved be 1.007276 a.m.u approximately, find
how much K.E these will carry?
Sol. Working on the same lines as an electron-positron pair production, we notice that the reaction.
proton + antiproton, has the energy balance
E = m0 (proton) C2 + K.E (proton) +
m0 (antiproton)C2 + K.E (antiproton)
But m0C2 = energy equivalent of 1.007276 a.m.u 938 MeV. [Q 1.007276 x 931 938 MeV]
Thus K.E of each particle
1
= [1896 MeV - 2 × 938 MeV] = 10MeV..
2
EX. 32: Obtain the maximum kinetic energy of -particles, and the radiation frequencies of
decays in the decay scheme shown in Fig. 14.6. You are given that
m(198Au) = 197.968233 u; m(198Hg) = 197.966760 u
198
79 Au
1 Page 24 Table 2
2 1.088Mev
1 3
0.412Mev
2
0
198
80 Hg
E
Sol. -rays are electro magnetic radiations having energy E = h = where h = plank`s
h
constant = 6.625 x 10-34 J.S
1) Frequencies of 1 , 2 and 3 are calculated as follows
EX. 34 The probability of survival of a radioactive nucleus for one mean life is
1 1 ln 2 ln 2
1) 2) 1 3) 4) 1
e e e e
Sol. key(1) Probability of survival for any nucleus at time t is
N N 0e λt
P e λt
N0 N0
1
λ
λ
1
So, in one mean life, required probability is e ;
e
EX. 35 The fraction f of radioactive element decayed change with respect to time (t). The curve
representing the correct variation is
1) f 2) f
O t O t
f f
3) 4)
O t O t
Sol. key(3)
EX. 36 The rate of decay (R) of nuclei in a radiocative sample is plotted against time (t). Which
of the following best represents the resulting curve?
1) R 2) R
O t O t
R R
3) 4)
O t O t
Sol. key(1)
EX. 37 A sample of uranium is a mixture of three isotopes 92 U 234 , 92U 235 and 92U 238 present in
the ratio 0.006%, 0.71% and 99.284% respectively. The half lives of then isotopes are 2.5 x
105 years, 7.1 x 108 years and 4.5 x 109 years respectively. The contribution to activity (in %)
of each isotope in the sample respectively
1) 51.41%, 2.13%, 46.46%
2) 51.41%, 46.46%, 2.13%
3) 2.13%,51.41%, 46.46%
4) 46.46%, 2.13%, 51.41%
Sol. key(1) Let m is the total mass of the uranium mixture. The masses of the isotopes 92 U 234 ,
0.006
92U
235
and 92U 238 in the mixture are m1 m ;
100
0.71 99.284
m2 m , and m3 m.
100 100
m1 N A
If N A is the Avogadro number, then number of atoms of threeisotopes are; N1 ,
M1
m2 N A m3 N A
N2 , and N 3
M2 M3
Activity of radioactive sample A λN .
0.693 0.693
As λ A N
t1/ 2 , t1/ 2
If t1 , t2 and t3 be the half lives, then
N1 N 2 N 3
A1 : A2 : A3 : :
t1 t2 t3
m m m
or A1 : A2 : A3 1 : 2 : 3
M 1t1 M 2t2 M 3t3
0.006 0.71 99.284
: :
234 2.5 10 5 235 7.5 10 8 238 4.5 10 9
EX. 38 Binding energy per nucleon versas mass number curve for nuclei is shown in the fig.
W,X,Y and Z are four nuclei indicated on the curve. The process that would release energy is
Binding energy per nucleon Mev
8.5 Y
8.0 X
7.5
W
5.0
Z
0 30 60 90 120
Mass Number of nuclei
1) Y 2Z 2) W X Z
3) X Y Z 4) W 2Y
Sol. .key(4) Energy of products must be more then the reactants to release energy.
EX. 39 A small quantity of a solution containing N24 radio - nuclide of half - life T and activity R0
is injected into blood of a person. 1cm3 of sample of blood taken from the blood of the person
shows activity R1. If the total volume of the blood in the body of the person is V, find the
timer after which sample is taken.
T R0 T VR0
1) 1 n 2) 1 n
ln(2) VR1 ln(2) R1
T VR1 T R1
3) 1 n 4) 1 n
ln(2) R0 ln(2) VR0
Sol. . key(1) Total volume of blood,
Total activity R
V
Activity per cm3 R1
R0e t VR1
, (or) e t
R1 R0
VR ln(2)t T R
ln 1 t ;t ln 0
R0 T ln(2) VR1
EX. 40 A nucleus with mass number 220 initially at rest emits an - particle. If the Q value of
the reaction is 5.5 MeV, calculate the kinetic energy of -particle.
1) 4.4 MeV2) 5.4 MeV 3) 5.6MeV 4) 6.5 MeV
Sol. .key(2) K1 K 2 5.5 MeV
From conservation of linear momentum
2 K1 (216m)1/ 2 2 K 2 (4m)1/ 2 ; K 2 54 K1
From the above K 2 5.4 MeV
EX. 41 Some amount of radioactive substance (half-life=10 days) is spread inside a room and
consequently the level of radiation becomes 50times the permissible level for normal occupancy
of the room. The room be safe for occupation after
1) 20days 2) 34.8 days 3) 56.4 days 4) 62.9 days
Sol. .key(3) Since the intial activity is 50 times the activity for safe occupancy, therefore,
R0 50 R where R N since,
RN n t /T
R N 1 1
R0 N 0 2 2 or
t /10
1 1
2 50
EX. 42 The fraction of a radiactive sample will decay during half of its half-life period is
1 1 2 1 1
1) 2) 3) 4)
2 2 1 2 2
t
n
N 1 1 T T t 1
Sol. .key(3) Here, t or
N0 2 2 2 T 2
1
N 1 2 1 N0 N 1 1 2 1
;
N0 2 2 N0 2 2
EX. 43 In moon rock sample the ratio of the number of stable argon-40 atoms present to the
number of radioactive potassium-40 atoms is 7:1. Assume that all the argon atoms were
produced by the decay of potassium atoms, with a half-life of 2.5 109 yr. The age of the rock
is
1) 2.5 109 yr 2) 5.0 109 yr
3) 7.5 109 yr 4) 1010 yr
Sol. .key(3) Let the number of radioactive Potassium atoms present initially (t=0) is N 0 and the
number of stable argon atoms at t=0 is zero. After time t the number of stable argon atoms is m and
the radioactive potassium atoms is N 0 m given that
N0 m 1 7 1
, m N 0 and N 0 m N 0
m 7 8 8
since after one half-life N 0 reduces to N0/2 after 2 half-lives N0/4 and after 3 half-lives it reduces to N0/8
N1 N 2 R1 R2 T ; t2 t1 R1 R2 T
EX. 45 The half life of a radioactive substance is 20 [Link] approximate time interval
t2 t1 between the time t2 , when 2/3 of it has decayed and time t1 and 1/3 of it had decayed
is
1) 14 minutes 2) 20 minutes
3) 28 minutes 4) 7 minutes
Sol. . key(2) 2 1 1 1
A t t1 t1 / 20 ; At t2 t2 / 20
3 2 3 2
t2-t1= 20 mins.
EX. 46 A charged capactor of capacitance C is discharged through a resistance R. A radio active
sample decays with an average life t. Find R interms of C and t in order that the ratio of the
electrostatic energy stored in the capacitor to the activity of the radio active sample remains
constant with time
2t C
1) 2) 3) 2t C 4) t C
C 2t
1 2 1
Uc CVo CV 2
Sol. key(1) constant; 2 2
A No N
1
Where V Voe t / CR , N N o e t and
t
EX. 47 A radioactive sample can decay by two differentprocesses. The half-life for the first
process is T1 and that for the second process is T2 . The effective half-life T of the radioactive
sample is
1 1 1
1) T T1 T2 2) T T T
1 2
T1 T2 T1 T2
3) T T T 4) T T T
1 2 1 2
1 2
dN
Sol. . key(2) N ; 1
dt
T
EX. 48 In nuclear fusion,One gram hydrogen is converted into [Link] the efficiency of the
generator be 5%,then the energy obtained in KWH is
1) 8.75 103 2) 4.75 103 3) 5.75 103 4) 3.73 103
output
Sol. key(1). Efficency =
mc 2
EX. 49 A photon of energy 1.12 Mev splits into electron positron pair. The velocity of electron
is (Neglect relativistic correction)
1) 3 x 108 ms-1 2) 1.33 x 108 ms-1
3) 6 x 108ms-1 4) 9 x 108ms-1
1
.Sol. key(2) E mv 2 2 2 E0
2
EX. 50. A sample of radioactive material has mass m, decay constant and molecular weight M.
Avagadr o constant = N A . The activity of the sample after time t will be
mN A t mN A t
1) e 2) e
M M
mN A t m
3)
M
e 4)
1 e
t
N Am
Sol. key(2). activity = N o e t where No
M
EX. 51 Samples of two radioactive nuclides A and B are taken. A and B are the
disintegration the following cases, the two samples can simultaneously have the same decay
rate at any time?
1) Initial rate of decay of A is twice the initial rate of decay of B and A B
2) Initial rate of decay of A is twice the initial rate of decay of B and A B
3) Initial rate of decay of B is twice the initial rate of decay of A and A B
4) Initial rate of decay of B is same as the rate of decay of A at t = 2h and B A
dN
Sol. key(2). rate of decay N
dt
(1) t 0
N0 A 2 N0B N0 A 2 N0B
A B
dN
A N A AA N 0 Ae At 2 A N 0 Ae At
dt A
dN
B N B B N 0 B e At
dt B
Q A B
dN dN
dt A dt B
(2) A N 0 A 2 B N 0 B A B
at t t
dN
N 0 e t
dt
If equal : A N 0 Ae t B N 0 B e t
A B
2 e
A B t
A B t
can have real solution.
(3) Proceed similar to (2) twill have no real soltion.
(4) B N 0 B A N 0 Ae 2 A
N 0 B N 0 Ae 2 A
at some t t , if equal rates occur
B N 0 Be t A N 0 Ae At
B
e 2 A 1 not possible.
EX. 52. The variation of decay rate of two radioactive samples A and B with time is shown
in figure. Which of the following statements are true?
dN
dt
t
1) Decay constant of A is greater than that of B, hence A always decays faster than B.
2) Decay constant of B is greater than that of A but its decay rate is always smaller than that of A.
3) Decay constant of A is greater than that of B but it does not always decay faster than B.
4) Decay constant of B is smaller than that of A, but still its decay rate becomes equal to that of A
at a later instant.
dN d 2N
Sol. key (3, 4). N 0 e t 2
2 N 0e t
dt dt
at instant when
dN dN
, slope A slope B
dt A dt B
A B.
EX. 53. Which sample A or B shown in figure has shorter mean-life?
dN
dt
A
t
1) B A 2) B A
3) B A 4) Nothing can be concluded
dN dN
Sol. key(1). at t 0 ; dt
A dt B
d 2N d 2N
but dt 2 B A A A
B
dt 2 A
Q m X m
A
Z
A 4
Z 2
Y m 2 He 4 c 2
A
b) For 1 -decay; Z X ZA1Y 01e v
Q m Z
X A m Z 1
Y A c 2
A
c) For -decay; Z X ZA1Y 01e v
Q m Z
XA m Z 1
Y A 2me C 2
A
d) For K-capture; Z X 01e ZA1Y v
Q m Z
XA m Z 1
Y A c 2
the target nucleus. The threshold energy is some what greater than Q because the
outgoing particles must have some kinetic energy to conserve momentum.
Radioactivity law for different types of disintegration.
dN
a. Only disintegration:- N N N 0 e t
dt
b. Disintegration with continuous production:-
B stable
formation rate decay
q
A
dN 1
N q N q N 0 q e t
dt
Successive Disintegration
A parent nucleus may decays into a daughter nucleus, which may decay into another daughter
nucleus and so on. Such decay is called successive disintegration or series decay. The
chain stops only when the end product is stable.
c. For successive disintegration of the products:
decay decay
A 1
B
2
C stable
dN A
For A 1 N A N A N 0e 1t
dt
dN B
For B 1N A 2 N B
dt
N 01
NB e 1t e 2t
2 1
dN C
For C 2 N B .
dt
2e 1t 1e 2t
N c N 0 1
2 1 2 1
If ‘C’ is the final stable product, then the decay and recovery curves for the substances A,
B and C are as shown
N
N0
no. of atoms
A
B C
time
O
At peak of B, the rate of formation of B = rate of disintegration of B. Hence 1 N A 2 N B .
If ‘C’ is also an unstable product, then the decay and recovery curves for the substances
A,B and C are as shown
N
N0
A
no. of atoms
B C
time
O
Also, N0 = NA + NB + NC; at t = 0, NB =0 ;
at 0 t ; N B increases
1 2
at t ln ; N B = maximum
2 1 1
at t ; N B decreases to zero
1 0 and so 2 1 2
1 0 N 2t
then N B 1 e
2
For 2 be large e 2t 0
hence N B 2 N 01
i.e Thus B is in permanent of secular equlibrium with A (parent)
N
N0
B
A
O t
Transient Equlibrium
If the parent is long-lifed compared to daughter but half-life of the parent not very large i.e
TA TB Then 1 2 , but 1 0.
NB 1 e 2t
For N 1 e 1t
A 2 1
1
N0
2 1
B
t
O
Note : It is to be noted that if the parent has shorter half-life than that of the daughter
1 2 , no state of equilibrium is attained
d. Simultaneous disintegration of parent nuclei:-
B
1
2
C
eff 1 2 or
1 1 1 TT
Teff 1 2
Teff T1 T2 T1 T2
Where T1 and T2 are the respective half lifes
e. Radioactive equilibrium:
After a period of time, successive daughter nucleus decays at the same rate as it is
formed. The situation is called radioactive equilibrium.
A N A B N B C N C ......
Nuclei
(Jee main previous year questions)
(𝟏. 𝟑 × 𝟏𝟎−𝟏𝟓 )𝑨𝟏/𝟑 𝐦. It follows that the mass density of a nucleus is of the order of:
Mass mA
SOL. (d) Density of nucleus,
Volume 4
R3
3
mA
p (𝑅 = 𝑅0 𝐴1/3 )
R0 A1/3
4 3
3 1.67 1027
(Given, 𝑅0 = 1.3 × 10−15 )
4 3.14 1.3 10
15 3
3. An unstable heavy nucleus at rest breaks into two nuclei which move away with velocities in
the ratio of 8:27. The ratio of the radii of the nuclei (assumed to be spherical) is:
[Online Apri1 15, 2018]
SOL. (c) Let heavy nucleus breaks into two nuclei of mass 𝑚1 and 𝑚2 and move away with velocities
𝑉1 and 𝑉2 respectively.
V1 8
According to question,
V2 27
4
p R13
3 mass
(⋅.⋅ density p = volume)
4
p R23
3
1 1
3
R 27 3 3 3 R1 3
⇒ 1
R2 8 2 R2 2
[2007]
SOL. (b)
5. If radius of the Al1327 nucleus is estimated to be 𝟑. 𝟔 fermi then the radius of Te52
125
nucleus
be nearly
[2005]
𝑅 = 𝑅0 (𝐴)1/3
Here, 𝑅0 is a constant
5
⇒ 𝑅2 = 3 × 3.6 = 6 fermi
6. You are given that mass of Li37 = 𝟕. 𝟎𝟏𝟔𝟎𝐮, Mass of He24 = 𝟒. 𝟎𝟎𝟐𝟔𝐮 and Mass of H11
= 𝟏. 𝟎𝟎𝟕𝟗𝐮. When 20 𝐠 of Li37 is converted into He24 by proton capture, the energy
SOL. (d) 7
3 Li H11 2 He42
𝛥𝑚 → [𝑚Li + 𝑚H ] − 2[𝑀He ]
𝟎. 𝟎𝟎𝟎𝟓𝟒𝟖𝐮, 𝐦−
𝐯 = 𝟎, 𝐦𝐝 = 𝟐. 𝟎𝟏𝟒𝟏𝐮, where 𝐩 ≡ proton, 𝐧 ≡ neutron, 𝐞 ≡ electron,
(b) 𝐩 → 𝐧 + 𝐞+ + 𝐯
(c) 𝐧 + 𝐩 → 𝐝 + 𝜸
(d) 𝐞+ + 𝐞 → 𝜸
SOL. (c) For the momentum and energy conservation, mass defect (𝛥𝑚) should be positive. Since
(𝑚𝑝 + 𝑚𝑛 ) > 𝑚𝑑
8. 120
Find the Binding energy per nucleon for Sn50 . Mass of proton 𝒎𝒑 = 𝟏. 𝟎𝟎𝟕𝟖𝟑𝐔, mass of
neutron 𝒎𝒏 = 𝟏. 𝟎𝟎𝟖𝟔𝟕 U and mass of tin nucleus 𝒎𝐒𝐧 = 𝟏𝟏𝟗. 𝟗𝟎𝟐𝟏𝟗𝟗 U. (take
𝟏𝐔 = 𝟗𝟑𝟏𝐌𝐞𝐕)
= 1.096
is 200 𝐌𝐞𝐕. Given that the Avogadro number, 𝐍 = 𝟔. 𝟎𝟐𝟑 × 𝟏𝟎𝟐𝟔 per kilo mole and 1
𝐍𝐞𝟐𝟎 → 𝟐𝐇𝐞𝟒 + 𝐂 𝟏𝟐
Given that the binding energy/nucleon of Ne20 , 𝐇𝐞𝟒 and 𝐂 𝟏𝟐 are, respectively, 𝟖. 𝟎𝟑𝐌𝐞𝐕,
SOL. (d)
11. Imagine that a reactor converts all given mass into energy and that it operates at a power
level of 109 watt. The mass of the fuel consumed per hour in the reactor will be : (velocity of
12. Two deuterons undergo nuclear fusion to form a Helium nucleus. Energy released in this
process is : (given binding energy per nucleon for deuteron = 𝟏. 𝟏𝐌𝐞𝐕 and for helium=
𝟕. 𝟎𝐌𝐞𝐕)
(a) 𝟑𝟎. 𝟐𝐌𝐞𝐕 (b) 𝟑𝟐. 𝟒𝐌𝐞𝐕 (c) 𝟐𝟑. 𝟔𝐌𝐞𝐕 (d) 𝟐𝟓. 𝟖𝐌𝐞𝐕
SOL. (c) H 2 + H 2 → He4
13. When Uranium is bombarded with neutrons, it undergoes fission. The fission reaction can be
written as:
where three particles named 𝒙 are produced and energy 𝐐 is released. What is the name of
the particle 𝒙 ?
14. Assume that a neutron breaks into a proton and an electron. The energy released during this
process is: (mass of neutron = 𝟏. 𝟔𝟕𝟐𝟓 × 𝟏𝟎−𝟐𝟕 𝐤𝐠, mass of proton = 𝟏. 𝟔𝟕𝟐𝟓 × 𝟏𝟎−𝟐𝟕 kg,
[2012]
𝛥𝑚 = 𝑚𝑛 − 𝑚𝐻 − 𝑚𝑒 = 1.6725 × 10−27
= −9 × 10−31 kg
8.1 × 10−15
𝐸= = 0.511MeV
16 × 10−19
15. Ionisation energy of Li (Lithium) atom in ground state is 𝟓. 𝟒𝐞𝐕. Binding energy of an
electron in 𝐋𝐢+ ion in ground state is 𝟕𝟓. 𝟔 𝐞𝐕. Energy required to remove all three
(a) 𝟖𝟏. 𝟎𝐞𝐕 (b) 𝟏𝟑𝟓. 𝟒𝐞𝐕 (c) 𝟐𝟎𝟑. 𝟒𝐞𝐕 (d) 𝟏𝟓𝟔. 𝟔𝐞𝐕
SOL. (d)
16. After absorbing a slowly moving neutron of mass 𝒎𝐍 (momentum ≈ 𝟎) a nucleus of mass
𝐌 breaks into two nuclei of masses 𝒎𝟏 and 𝟓𝒎𝟏 (𝟔𝒎𝟏 = 𝐌 + 𝒎𝐍 ) respectively. If the de
Broglie wavelength of the nucleus with mass 𝒎𝟏 is 𝝀, the de Broglie wavelength of the
Let 𝑝1 and 𝑝2 be the momentum ofbroken nuclei ofmasses 𝑚1 and 5𝑚1 respectively.
𝑝𝑓 = 𝑝1 + 𝑝2
𝑝𝑖 = 𝑝𝑓
0 = 𝑝1 + 𝑝2
𝑝1 = −𝑝2
|𝜆1 | = |𝜆2 |
𝜆1 = 𝜆2 = 𝜆.
[2010]
17. The binding energy per nucleon for the parent nucleus is 𝑬𝟏 and that for the daughter
nuclei is 𝑬𝟐 . Then
SOL. (c) In nuclear fission, the binding energy per nucleon of daughter nuclei is always greater than the
parent nucleus.
m 2m m m
(a) c (b) c (c) c (d) c
M m M M M m
M M
SOL. (b) Mass defect, M M m
2 2
= [𝑀 + 𝛥𝑚 − 𝑀] = 𝛥𝑚
Now,
1M 2 1M 2 1
Q v1 v2 M m 0
2
2 2 2 2 2
M 2
v1 . v1 v2 -------(ii)
2
From equation (i) and (ii), we get
M 2
v1 mc
2
2
2mc 2 2m
v
2
1 V1 c
M M
19. Statement‐l: Energy is released when heavy nuclei undergo fission or light nuclei undergo
fusion and
Statement‐2 : For heavy nuclei, binding energy per nucleon increases with increasing 𝒁
[2008]
Statement‐ 1
(c) Statement‐l is true, Statement‐2 is true; Statement‐2 is not a correct explanation for
Statement‐l
SOL. (d) We know that energy is released when heavy nuclei undergo fission or light nuclei undergo
The second statement is false because for heavy nuclei the binding energy per nucleon decreases
with increasing 𝑍 and for light nuclei, B. E/nucleon increases with increasing 𝑍.
𝟏𝟕 ,
20. 𝐈𝐟 𝑴𝑶 is the mass of an oxygen isotope 𝟖𝐎 𝑴
𝑷 and 𝑴𝑵 are the masses of a proton and a
[2007]
(a) (𝑴𝑶 − 𝟏𝟕𝑴𝑵 )𝒄𝟐 (b) (𝑴𝑶 − 𝟖𝑴𝑷 )𝒄𝟐 (c) (𝑴𝑶 − 𝟖𝑴𝑷 − 𝟗𝑴𝑵 )𝒄𝟐 (d) 𝑴𝑶 𝒄𝟐
Number of neutrons = 17 − 8 = 9
Binding energy
= [8MP + 9MN − Mo ]c 2
21. When Li37 nuclei are bombarded by protons, and the resultant nuclei are Be48 , the emitted
particles will be
[2006]
(a) alpha particles (b) beta particles (c) gamma photons (d) neutrons
We see that both proton number and mass number are equal in both sides, so emitted particle
22. If the binding energy per nucleon in Li37 and He24 nuclei are 𝟓. 𝟔𝟎 𝐌𝐞𝐕 and 𝟕. 𝟎𝟔 𝐌𝐞𝐕
[2006]
(a) 𝟐𝟖. 𝟐𝟒𝐌𝐞𝐕 (b) 𝟏𝟕. 𝟐𝟖𝐌𝐞𝐕 (c) 𝟏. 𝟒𝟔𝐌𝐞𝐕 (d) 𝟑𝟗. 𝟐𝐌𝐞𝐕
𝐸 + 7 × 5.6 = 2 × [4 × 7.06]
23. A nuclear transformation is denoted by 𝑿(𝒏, 𝜶) Li37 Which of the following is the nucleus of
element 𝑿 ?
[2005]
A 7
SOL. (a) z X + n1 → 3Li + 2He4
𝐴+1 =4+7
⇒ 𝐴 = 10
Using conservation of charge number
𝑍+0=2+3 ⇒𝑍 =5
10
It is boron 5B
24. A nucleus disintegrated into two nuclear parts which have their velocities in the ratio of 2: 1.
[2004]
1 1
(a) 3 2 :1 (b) 𝟏: 𝟐𝟏/𝟑 (c) 𝟐𝟏/𝟑 : 𝟏 (d) 1: 3 2
m v 1
1 2
m2 v1 2
25. The binding energy per nucleon of deuteron H12 and helium nucleus He24 is 𝟏. 𝟏𝐌𝐞𝐕 and
7 MeV respectively. If two deuteron nuclei react to form a single helium nucleus, then the
energy released is
[2004]
(a) 𝟐𝟑. 𝟔𝐌𝐞𝐕 (b) 𝟐𝟔. 𝟗𝐌𝐞𝐕 (c) 𝟏𝟑. 𝟗𝐌𝐞𝐕 (d) 𝟏𝟗. 𝟐𝐌𝐞𝐕
4 × 1.1 = 4.4MeV
26. When a 𝐔𝟐𝟑𝟖 nucleus originally at rest, decays byemitting an alpha particle having a speed
238 × 0 = 4𝑢 + 234𝑣
4
𝑣=− 𝑢
234
4
Speed | v | u
234
given that the repulsive potential energy between the two nuclei 𝐢𝐬 ∼ 𝟕. 𝟕 × 𝟏𝟎−𝟏𝟒 𝐉 , the
temperature at which the gases must be heated to initiate the reaction is nearly [Boltzmann’s
[2003]
This kinetic energy should be able to provide the repulsive potential energy
3
𝑘𝑇 = 7.7 × 10−14
2
2 × 7.7 × 10−14
⇒𝑇= = 3.7 × 109 𝐾
3 × 1.38 × 10−23
Topic 3: Radioactivity
28. Activities of three radioactive substances 𝐀, 𝐁 and 𝐂 are represented by the curves 𝐀, 𝐁
ln 𝑅 = ln 𝑅0 + (−𝜆 ln 𝑡)
ln 2
Slope
t1/2
6 10
A TA ln 2
10 6
6 5 ln 2
𝜆𝐵 = ⇒ 𝑇𝐵 =
5 6
2 5 ln 2
𝜆𝑐 = ⇒ 𝑇𝐶 =
5 6
10 5 15
T1 A : T1 B : T1 C : : 2 :1: 3
2 2 2 6 6 6
29. A radioactive nucleus decays by two different processes. The half life for the first process is
10 𝐬 and that for the second is 100 𝐬. The effective halflife of the nucleus is close to:
SOL. (a) Let 𝜆1 and 𝜆2 be the decay constants of two process. 𝑁 be the number of nuclei left
undecayed after two process. From the law of radioactive decay we have
dN 𝑑𝑁
1 N 2 N [⋅.⋅ − 𝑑𝑡 = 𝜆𝑁]
dt
𝑑𝑁
⇒− = (𝜆1 + 𝜆2 )𝑁
𝑑𝑡
⇒ 𝜆eq . = (𝜆1 + 𝜆2 )
ln 2 ln 2 ln 2 ln 2
(⋅.⋅ 𝜆 = 𝑇
)
T T1 T2
1 1 1
⇒ = +
𝑇 𝑇1 𝑇2
1 1 1 11
⇒ 𝑇 = 10 + 100 = 100 [Given: 𝑇1 = 10 s & T2=100 s]
100
⇒𝑇= = 9 sec.
11
30. In a radioactive material, fraction of active material remaining after time 𝒕 is 9/16. The
According to question,
𝑁(𝑡) 9
= = 𝑒 −𝜆𝑡
𝑁0 16
After time, t/2;
𝑁(𝑡/2) = 𝑁0 𝑒 −𝜆(𝑡/2)
𝑁(𝑡/2) 9
= √𝑒 −𝜆𝑡 = √
𝑁0 16
3
𝑁(𝑡𝑙2) = 𝑁0
4
31. The activity of a radioactive sample falls from 700 𝐬 −𝟏 to 500 𝐬−𝟏 in 30 minutes. Its
Activity, 𝐴 = 𝐴0 𝑒 −𝜆t
In
A A0et ln 2/T1/2 2
T1/2
𝐼𝑛2
⇒ 𝑇1/2 = 30 𝐼𝑛1.4 = 61.8 minute
⇒ 𝑇1/2 ≈ 62 minute
32. Two radioactive materials A and B have decay constants 10 𝝀 and 𝝀, respectively. If initially
they have the same number of nuclei, then the ratio of the number of nuclei of A to that 𝐨𝐟 𝐁
⇒ (𝜆A − 𝜆B ). 𝑡 = 1
1 1 1
⇒t= t= =
(𝜆B − 𝜆A ) 10𝜆 − 𝜆 9𝜆
33. Two radioactive substances A and 𝐁 have decay constants 𝟓𝝀 and 𝝀 respectively. At 𝒕 = 𝟎,
a sample has the same number of the two nuclei. The time taken for the ratio of the number
2
1
of nuclei to become will be:
e
SOL. (a) Let N1 and N2 be the number ofradioactive nuclei of substance at anytime t.
𝑁1 (at 𝑡) = 𝑁0 𝑒 −5𝜆𝑡 (i)
At the end there are 6 𝜶‐particles and 4 𝜷‐particles which are emitted. If the end nucleus is
SOL. (c) When one 𝛼‐ particle emitted then daughter nuclei has 4 unit less mass number (A) and 2 unit
232
Th90 Y78208 6 He24
35. Using a nuclear counter the count rate of emitted particles from a radioactive source is
measured. At 𝐭 = 𝟎 it was 1600 counts per second and 𝐭 = 𝟖 seconds it was 100 counts per
second. The count rate observed, as counts per second, at 𝐭 = 𝟔 seconds is close to:
1 3
Activity at t = 6s = 1600 (2) = 200C/s
= 𝟑. 𝟕 × 𝟏𝟎𝟏𝟎 𝐝𝐞𝐜𝐚𝐲𝐬/𝐬), has twice the number of nuclei as another sample of a different
radioactive material 𝐁 which has an activity of 20 𝐦𝐂𝐢. The coniect choices for half-lives of
37. At a given instant, say 𝐭 = 𝟎, two radioactive substances A and 𝐁 have equal activities. The
RB
ratio of their activities after time 𝐭 itself decays with time 𝐭 as e 3t . If the half‐life
RA
at t = 0 RA = RB
NA e−𝜆AT = NB e−𝜆BT
NA = NB at t = 0
RB N 0 e Bt
At t t,
RA N 0 e At
⇒ 𝜆B − 𝜆A = 3
𝜆B = 3 + 𝜆 A = 4
ℓn2 ℓn2
(t1/2 ) = =
B 𝜆𝐵 4
38. At some instant, a radioactive sample S1 having an activity 𝟓𝝁𝐂𝐢 has twice the number of
nuclei as another sample 𝐒𝟐 which has an activity of l𝟎𝝁𝐂𝐢. The half-lives 𝐨𝐟 𝐒𝟏 and 𝐒𝟐 are
ln 2 ln 2
Half life period t = or, 𝜆 =
𝜆 T
ln 2
𝜆1 N1 = × N1 = 5𝜇Ci ..... (i)
t1
ln 2
𝜆2 N2 = × N2 = 10𝜇Ci ..... (ii)
t2
39. 60
A solution containing active cobalt Co27 having activity 𝐨𝐟 𝟎. 𝟖 𝝁𝐂𝐢 and decay constant 𝝀
is injected in an animal’s body. If 𝟏𝐜𝐦𝟑 of blood is drawn from the animal’s body after 10
hrs of injection, the activity found was 300 decays per minute. What is the volume of blood
that is flowing in the body? (1Ci = 𝟑. 𝟕 × 𝟏𝟎𝟏𝟎 decay per second and at 𝐭 = 𝟏𝟎 hrs,
given by
[2017]
T
(a) 𝒕 = 𝑻 𝐥𝐨𝐠 (𝟏. 𝟑) (b) t
log 1.3
log 2 log1.3
(c) t T (d) t
log1.3 log 2
SOL. (d) Let initially there are total N0 number of nuclei
At time t
NB
0.3( given)
NA
⇒ 𝑁𝐵 = 0.3𝑁𝐴
N0 = 𝑁𝐴 + 𝑁𝐵 = 𝑁𝐴 + 0.3𝑁𝐴
N0
𝑁𝐴 =
1.3
As we know Nt N0e t
N0
or, N 0 e t
1.3
1
e t ⇒ 𝑙𝑛(1.3) = 𝜆𝑡
1.3
ln 1.3 ln 1.3 ln 1.3
or, t t T
ln 2 ln 2
T
41. Half‐lives of two radioactive elements A and 𝐁 are 20 minutes and 40 minutes, respectively.
Initially, the samples have equal number of nuclei. After 80 minutes, the ratio of decayed
[2016]
N 1 16 3 4
N 0 20 1
2 4
42. Let 𝐍𝜷 be the number of 𝜷 particles emitted by 1 gram 𝐨𝐟 𝐍𝐚𝟐𝟒 radioactive nuclei (half
life = 𝟏𝟓 𝐡𝐫𝐬) in 𝟕. 𝟓 hours, 𝐍𝜷 is close to (Avogadro number = 𝟔. 𝟎𝟐𝟑 × 𝟏𝟎𝟐𝟑 /𝐠. mole):
N𝛽 = 7.4 × 1021
43. A piece of wood from a recently cut tree shows 20 decays per minute. A wooden piece of same
size placed in a museum (obtained from a tree cut many years back) shows 2 decays per
minute. If half life 𝐨𝐟 𝐂 𝟏𝟒 is 5730 years, then age of the wooden piece placed in the museum
is approximately:
(a) 10439 years (b) 13094 years (c) 19039 years (d) 39049 years
dN0
SOL. (c) Given: 20decays / min
dt
dN
= 2decays/ min
dt
T1/2 = 5730 years
As we know,
N N 0 e t
N0
Log = 𝜆t
N
1 N0
t= Log
𝜆 N
2.303 × T1/2 N0
= × Log10
0.693 N
dN 0
N 20
But dt 0 10
dN N 2
dt
2.303 × 5730
t= ×1
0.693
= 19039 years
44. A piece of bone of an animal 𝐟𝐫𝐨𝐦 a ruin is found to have C14 activity of 12 disintegrations
per minute per gm of its carbon content. The C14 activity of a living animal is 16
disintegrations per minute per gm. How long ago nearly did the animal die? (Given half life
o𝐟 𝟏𝟒 𝐂 is 𝐭 𝟏/𝟐 = 𝟓𝟕𝟔𝟎
years)
(a) 1672 years (b) 2391 years (c) 3291 years (d) 4453 years
𝐧𝐮𝐜𝐥𝐞𝐢/𝐬. If at 𝐭 = 𝟎 there were no nuclei, the time when there are 50 nuclei is:
N t
dN dN
dt
100 N or 0 100 N 0dt
1
log 100 N 0 t
N
log (100 − 𝜆𝑁) − log 100 = −𝜆𝑡
100 − 𝜆𝑁
log = −𝜆𝑡
100
100 N N
e t 1 e t
100 100
100
𝑁= (1 − 𝑒 −𝜆 𝑡)
𝜆
As, 𝑁 = 50and𝜆 = 0.5/ sec
100
50 = (1 − 𝑒 −0.5𝑡 )
0.5
Solving we get,
4
𝑡 = 2 ln ( ) sec
3
46. The half‐life of a radioactive element A is the same as the mean‐life of another radioactive
element B. Initially both substances have the same number of atoms, then :
0.693 1
⇒ = ⇒ 𝜆A = 0.693𝜆B
𝜆A 𝜆B
or 𝜆A < 𝜆B
Initially number of atoms (N) of both are equal but since 𝜆B > 𝜆A ,
47. The counting rate observed from a radioactive source at 𝒕 = 𝟎 was 1600 counts 𝐬−𝟏 , and
𝒕 = 𝟖𝐬, it was 100 counts 𝐬−𝟏 . The counting rate observed as counts 𝐬−𝟏 at 𝒕 = 𝟔𝐬 will be
--(i)
N0 2
𝑑𝑁
= 𝑘𝑁 k‐ disintegration constant
𝑑t
dN
dt N ---(ii)
dN 0 N 0
dt
therefore 𝑛 = 4,
Therefore, in 8 seconds 4 half life had occurred in which counting rate reduces to 100 counts s −1 .
T1
Half life, 2 sec
2
In 6 sec, 3 half life will occur
dN
dt 1 3 dN
200 counts s −1
1600 2 dt
48. The decay constants of a radioactive substance for 𝜶 and 𝜷 emission are 𝝀𝜶 and 𝝀𝜷
respectively. If the substance emits 𝜶 and 𝜷 simultaneously, then the average halflife of
T T
SOL. (c) Tav
T T
(a) The rate of radioactive decay cannot be controlled but that of nuclear fission can be
controlled.
(b) Nuclear forces are short range, attractive and charge dependent.
(c) Nuclei of atoms having same number of neutrons are known as isobars.
(d) Wavelength of matter waves is given by de Broglie formula but that of photons is not
SOL. (a) Radioactive decay is a continuous process. Rate of radioactive decay cannot be controlled.
50. A sample originally contained 𝟏𝟎𝟐𝟎 radioactive atoms, which emit 𝜶‐particles. The ratio
𝐨𝐟𝜶‐particles emitted in the third year to that emitted during the second year is 𝟎. 𝟑. How
SOL. (b)
51. The half life of a radioactive substance is 20 minutes. The approximate time interval
2 1
(𝒕𝟐 − 𝒕𝟏 ) between the time 𝒕𝟐 when of it had decayed and time 𝒕𝟏 when of it had
3 3
decayed is:
[2011]
2 = 𝑒 𝜆(𝑡2 −𝑡1 )
⇒ In2 = 𝜆(𝑡2 − 𝑡1 )
⇒ 𝑡2 − 𝑡1 = In2/𝜆
having energy 𝑬𝟐 , but the 𝜷− rays are emitted with a continuous energy spectrum having
Statement‐2 : To conserve energy and momentum in 𝜷− decay at least three particles must
[2011 𝐑𝐒]
(b) Statement‐l and statement‐2 both are correct and statement‐2 is the correct explanation
of statement‐l.
(c) Statement‐l is correct, statement‐2 is correct and statement‐2 is not the correct
explanation of Statement‐l
SOL. (b) Statement‐l: A nucleus having energy 𝐸1 decays by 𝛽‐ emission to daughter nucleus having
energy 𝐸2 then 𝛽‐ rays are emitted with continuous energy spectrum with energy 𝐸1 − 𝐸2 .
Statement‐2: For energy conservation and momentum conservation at least three particles,
53. A radioactive nucleus (initial mass number 𝑨 and atomic number 𝒁 emits 3𝜶‐ particles
and 2 positrons. The ratio of number of neutrons to that of protons in the final nucleus will
be
[2010]
A Z 8 A Z 4 A Z 12 A Z 4
(a) (b) (c) (d)
Z 4 Z 8 Z 4 Z 2
SOL. (b) When a radioactive nucleus emits 1 𝛼‐particle, the mass number decreases by 4 units and
atomic number decreases by 2 units. When a radioactive nucleus emits 1 positron the atomic
Number of protons, 𝑁𝑝 = 𝑍 − 8
Nn A Z 4
Required ratio
Np Z 8
54. The half‐life period of a radio‐active element X is same as the mean life time of another
radio‐active element 𝒀. Initially they have the same number of atoms. Then
[2007]
𝑇1/2 = 𝑇𝑎𝑣
0.693 1
⇒ =
𝜆𝑋 𝜆𝑌
⇒ 𝜆𝑋 = (0.693). 𝜆𝑌
𝜆X < 𝜆 Y .
As the rate of decay is directly proportional to decay constant, Y will decay faster than 𝑋.
55. The energy spectrum of 𝜷‐particles [number 𝐍(𝐄) as a function 𝐨𝐟 𝜷‐energy 𝐄 emitted
[2006]
SOL. (c) The range of energy of 𝛽‐particles is from zero to some maximum value.
7
56. Starting with a sample of pure 66Cu , of it decays into Zn in 15 minutes. The
8
corresponding halflife is
[2005]
𝟏
(a) 15 minutes (b) 10 minutes (c) 𝟕 𝟐 minutes (d) 5 minutes
7 1 1 3
𝑁 =1− = =( )
8 8 2
No. of half-lives = 3
𝑡 15
𝑛= ⇒3=
𝑇 𝑇
15
⇒ 𝑇 = halflife period 5 minutes
3
57. The intensity of gamma radiation 𝐟𝐫𝐨𝐦 a given source is I. On passing through 36 mm of
1 I
lead, it is reduced to . The thickness of lead which will reduce the intensityto will be
8 2
[2005]
Intensity I I 0 .e d
I
d log
I0
I
For 𝑑 = 36 mm, intensity
8
I/8
−𝜇 × 36 = log ( ) -----(i)
I
𝐼/2
−𝜇 × 𝑑 = log ( ) -----(𝑖𝑖)
𝐼
1 1
log 3 log
36
8 2 3 or 𝑑 =
36
= 12mm
d 1 1 3
log log
2 2
58. Which of the following cannot be emitted by radioactive substances during their decay?
[2003]
SOL. (a) The radioactive substances emit 𝛼 ‐particles (Helium nucleus), 𝛽‐particles (electrons) and
[2003]
Also the number of 𝛽 + particles released is 2, which should decrease the atomic number by 2.
= 𝑍 − 16 + 4 − 2 = 𝑍 − 14
= 92 − 14 = 78
60. A radioactive sample at any instant has its disintegration rate 5000 disintegrations per
minute. After 5 minutes, the rate is 1250 disintegrations per minute. Then, the decay constant
(per minute) is
[2003]
𝐴 = 𝐴𝑜 𝑒 −𝜆𝑡
𝐴𝑜
⇒ 𝑒 −𝜆𝑡 =
𝐴
1 𝐴𝑜 1 5000
⇒ 𝜆 = log 𝑒 = log 𝑒
𝑡 𝐴 5 1250
2
= log 𝑒 2 = 0.4log 𝑒 2
5
61. At a specific instant emission of radioactive compound is deflected in a magnetic field. The
[2002]
SOL. (a) Charged particles are deflected in magnetic field. Electrons, protons and He2+ all are charged
62. 𝐈𝐟 𝑵𝟎 is the original mass of the substance of half‐life period 𝒕𝟏/𝟐 = 𝟓 years, then the
[2002]
SOL. (a) After every half‐life, the mass of the substance reduces to half its initial value.