Calculators/Sakrekenaars: Yes/Ja

Requirements for this paper/Benodigdhede vir hierdie vraestel: Other resources/Ander hulpmiddels:
Answer scripts/ Multi-choice cards (A5)/
Antwoordskrifte: Multikeusekaarte (A5):

Attendance slips (Fill-in paper)/ Multi-choice cards (A4)/

x
Presensiestrokies (Invulvraestel): Multikeusekaarte (A4):

Scrap paper/ Graph paper/

Rofwerkpapier: Grafiekpapier:

Type of assessment/ Semester test Qualification/ [Link].; [Link];

Tipe assessering: Kwalifikasie: [Link]
Module code/ NCHE111 Duration/ 1½ hour
Modulekode: Tydsduur: 1½ uur
Module description/ Introductory Inorganic and Physical Chemistry Max/ 47
Modulebeskrywing: Maks:
Examiner(s)/ Dr CE Read Date/ 23/4/2024
Eksaminator(e): Datum:
Internal/Interne Dr J Röscher Time/ 10:00
moderator(s): Tyd:

Details of student / Besonderhede van student:

Title/ Initials/ Surname/
Titel: Voorletters: Van:
University number/ Contact number/
Universiteitsnommer: Kontaknommer:
Signature/
Handtekening:

Examination instructions / Eksamenvoorskrifte

1. Students are allowed into the venue in the first half hour of a session, but no 1. Studente mag in die eerste halfuur van 'n sessie tot die lokaal toegelaat word,
extra time is granted. maar geen ekstra tyd word toegestaan nie.
2. No student is allowed to leave the venue before half an hour of the 2. Geen student word toegelaat om die lokaal te verlaat binne die eerste halfuur
examination session has elapsed. van 'n eksamensessie nie.
3. Students bring bags to the venue at own risk, and must put them in front of 3. Studente bring sakke na lokaal op eie risiko, en moet dit voor in die lokaal
the room. neersit.
4. Students may not have cell phones/electronic devices with them and/or 4. Studente mag nie selfone/elektroniese toestelle by hulle hê en/of hanteer nie.
handle them. 5. Geen verversings word in 'n eksamenlokaal toegelaat nie.
5. No refreshments are allowed in the examination venue. 6. Studente mag nie die lokaal verlaat om te gaan rook nie.
6. Students may not leave the room for a smoke break. 7. Skryf op beide kante van die bladsye.
7. Write on both sides of each page. 8. Skryf slegs in swart of blou ink.
8. Write in black or blue ink only. 9. Geen bladsye mag uit die antwoordskrif verwyder word nie.
9. No pages may be removed from the answer scripts.
10. Studente mag nie ontoelaatbare materiaal by hulle hê tydens 'n sessie nie,
10. Students may not have unauthorised material with them during a session, e.g. bv. notas en/of objekte wat notas bevat nie.
notes and/or objects that contain notes. 11. Geen items mag tydens die sessie geleen word nie.
11. No items may be borrowed during the session. 12. Studente mag nie 'n ander student probeer help of probeer om hulp te kry nie.
12. Students may not attempt to assist another student, or attempt to obtain 13. Studente moet hul antwoordskrifte aan toesighouers oorhandig voordat hulle
assistance. die lokaal verlaat.
13. Students must hand in their answer scrips to invigilators before they leave the 14. Die presensiestrokie op die agterblad, wat ook as onderneming geld, moet
venue. voltooi en ingegee word.
14. The attendance slip on the back cover that also serves as an undertaking,
must be completed and handed in.

Semestertest for NCHE111_2024 1/8

A Periodic Table, Solubility Table and Specific Heat Capacity Table can be found on the last pages of this paper.

Vraag 1. / Question 1.
Skryf ʼn gebalanseerde reaksievergelyking vir die volledige verbranding van heksaan, C6H14, neer. / Write down a
balanced reaction equation for the full combustion of hexane, C6H14. [2]

Vraag 2. / Question 2.
Watter verbinding sal presipiteer wanneer waterige oplossings van Fe2(SO4)3 en LiOH gemeng word? Skryf ʼn
gebalanseerde vergelyking vir die reaksie neer wat al die fisiese toestande van elke reagens en produk aandui. / What
compound will precipitate when aqueous solutions of Fe2(SO4)3 and LiOH are mixed? Write a balanced equation for the
reaction indicating the physical states of all the reagents and products. [4]

Gebalanseerde vergelyking: / Balanced equation:

Formule van die verbinding wat presipiteer: / Formula of the compound that precipitates:

Vraag 3. / Question 3.
Voltooi die volgende tabel met betrekking tot wateroplosbaarheid. Die oplosbaarheidstabel is agter aan die vraestel
vasgeheg. / Complete the following table with regards to water solubility. The solubility table is attached at the back of
the paper. [4 x ½ = 2]

Verbinding. Wateroplosbaar. Dui die ione wat in die oplossing teenwoordig mag wees aan.
Compound. Water soluble. Indicate the ions that may be present in the solution.
Ja. / Yes. Nee. / No.

CaF2

Na2CrO4

Semestertest for NCHE111_2024 2/8

Vraag 4. / Question 4.
Balanseer die volgende redoksreaksie in 'n suuroplossing. Jy hoef nie die fisiesetoestande in die
gebalanseerdereaksievergelyking aan te dui nie. Dui die stoigiometriese koëffisiënte van die finale gebalanseerde
vergelyking in die kleinste heelgetalveelvoude aan. / Balance the following redox reaction in an acidic solution. You do
not have to Indicate the physical states in the balanced reaction equation. Indicate the stoichiometric coefficients of the
final equation in the smallest integer multiples. [10 x ½ = 5]

Br2 (aq) → BrO3- (aq) + Br- (aq)

Vraag 5. / Question 5.
ʼn Mengsel van CuCl2 en CuCl2∙2H2O het ʼn massa van 1.565 g. Nadat die mengsel genoegsaam verhit is om al die water
af te dryf, was die massa slegs 1.391 g. Bereken die massapersentasie CuCl2∙2H2O in die mengsel. / A mixture of CuCl2
and CuCl2∙2H2O has a mass of 1.565 g. After suffiencient heating to drive off all the water, the mass is only 1.391 g. What
is the mass percent of CuCl2∙2H2O in the mixture? [4]
(Gegee: / Given: MH2O = 18.02 [Link]-1; MCuCl2 = 134.45 [Link]-1; MCuCl2.2H2O = 170.49 [Link]-1)

Semestertest for NCHE111_2024 3/8

Vraag 6. / Question 6.
Beskou die volgende reaksie: / Consider the following reaction:

Na2SO4 (aq) + 4C (s) → Na2S (aq) + 4CO (g)

(Gegee: / Given: MNa2SO4 = 142.1 [Link]-1; MC = 12 [Link]-1; MNa2S = 78.1 [Link]-1; MCO = 28 [Link]-1)

6.1 Bereken die beperkende reagens en die teoretiese opbrengs van Na2S indien 25 g Na2SO4 en 12.5 g koolstof
gemeng word. / Calculate the limiting reactant and the theoretical yield of Na2S when 25 g of Na2SO4 and 12.5
g of carbon are mixed. [4]

6.2 Bereken die massa van die oormaat reagens wat oorbly nadat die reaksie voltooi is. / Calculate the mass of the
excess reagent that is left over after completion of the reaction. [3]

Vraag 7. / Question 7.
Bereken die molêre konsentrasie van ʼn 250 mL natriumkarbonaatoplossing indien jy 3.65 g natriumkarbonaat opgelos
het. / Calculate the molar concentration of a 250 mL sodium carbonate solution if you dissolved 3.65 g of sodium
carbonate. [3]

Semestertest for NCHE111_2024 4/8

Vraag 8. / Question 8.
Spesifiseer die konsentrasie van elke ioon in ʼn waterige oplossing van 0.500 M K2Cr2O7. / Specify the concentration of
each ion in an aqueous solution of 0.500 M K2Cr2O7. [2]

Vraag 9. / Question 9.
Tafelwyn het ʼn pH van 3.40. Wat is die hidroniumioonkonsentrasie van die wyn? / Table wine ha sa pH of 3.40. What is
the hydronium ion concentration of the wine? [2]

Vraag 10. / Question 10.

Bereken die molaliteit van die volgende oplossing: / Calculate the molality of the following solution:
0.0167 g Na3PO4 is opgelos in 100 mL water. Die digtheid van water is 0.98 [Link]-1 en die molêre massa van
natriumfosfaat is 164 [Link]-1. / 0.0167 g of Na3PO4 is dissolved in 100 mL of water. The density of water is 0.98 [Link]-1
and the molar mass of sodium phosphate is 164 [Link]-1. [3]

Semestertest for NCHE111_2024 5/8

Vraag 11. / Question 11.
ʼn Stukkie chroom (15.5 g) word verhit tot 100.0 oC (373.15 K) en dan in 55.5 g water by 16.5 oC (289.65 K) laat val. Die
finale temperatuur van die metaal en water is 18.9 oC. Bereken die spesifieke hittekapasiteit van chroom. (Aanvaar dat
geen energie verlore gegaan het na die houer of die omringende lug nie). / A 15.5 g piece of chromium is heated to
100.0 oC (373.15 K) and is then dropped into 55.5 g of water at 16.5 oC (289.65 K). The final temp. of the metal and
water is 18.9 oC. Calculate the specific heat capacity of chromium. (Assume no energy is lost to the container or to the
surrounding air). [4]

(Let wel: Sien Tabel 6.1 met Spesifieke Hittekapasiteit waardes vir sommige elemente, verbindings en algemene
vastestowwe agterin die vraestel). / (Take note: See Table 6.1 with Specific Heat Capacity values for some elements,
compounds and common solids at the back of this paper).

Vraag 12. / Question 12.

Noem drie dinge waarvan die hittekapasiteit van ʼn voorwerp/element afhanklik is. / Name three things that the heat
capacity of a substance/element are dependend of. [3]

Semestertest for NCHE111_2024 6/8

Vraag 13. / Question 13.
Entalpieveranderinge kan eksperimenteel verkry word vir die volgende reaksies: / Enthalpy changes for the following
reactions can be determined experimentally: [12 x ½ = 6]

Vergelyking 1: / Equation 1: N2(g) + 3H2(g) → 2NH3(g) ∆rHo = -91.8 kJ/mol-rxn

Vergelyking 2: / Equation 2: 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g) ∆rHo = -906.2 kJ/mol-rxn
Vergelyking 3: / Exuation 3: H2(g) + ½O2(g) → H2O(g) ∆rHo = -241.8 kJ/mol-rxn

Gebruik hierdie vergelykings en waardes om die verandering in entalpie vir die vorming van 1 mol NO(g) vanuit
bogenoemde elemente te bepaal vir die volgende reaksie: (Wenk: manipileer die gegewe vergelykings.) / Use these
equations and values to determine the enthalpy change for the formation of 1 mol of NO(g) from the elements for the
following reaction: (Hint: manipulate the given reactions.)

Vergelyking 4: / Equation 4: ½N2(g) + ½O2(g) → NO(g) ∆rHo = ?

Semestertest for NCHE111_2024 7/8

 IA
PERIODIC TABLE OF THE ELEMENTS 0
(1) PERIODIEKE INDELING VAN DIE ELEMENTE (18)
1 2
H IIA IIIA IVA VA VIA VIIA He
1,01 (2) (13) (14) (15) (16) (17) 4,00
3 4 13 atomic number / atoomgetal 5 6 7 8 9 10
Li Be Al symbol / simbool B C N O F Ne
6,94 9,01 27,0 atomic mass / atoommassa 10,8 12,0 14,0 16,0 19,0 20,2
11 12 13 14 15 16 17 18
Na Mg IIIB IVB VB VIB VIIB VIII IB IIB Al Si P S Cl Ar
23,0 24,3 (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) 27,0 28,1 31,0 32,1 35,45 39,9
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39,1 40,1 45,0 47,9 50,9 52,0 54,9 55,9 58,9 58,7 63,4 65,4 69,7 72,6 74,9 79,0 79,9 83,8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85,5 87,6 88,9 91,2 92,9 95,9 (98) 101,1 102,9 106,4 107,9 112,4 114,8 118,7 121,6 127,6 127,9 131,3
55 56 57 * 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132,9 137,3 138,9 178,5 180,9 183,9 186,2 190,2 192,2 195,1 197,0 200,6 204,4 207,2 209,0 (209) (210) (222)
87 88 89 # 104 105 106 107 108 109
Fr Ra Ac Rf Db Sg Bh Hs Mt
(223) 226,0 227,0 (261) (262) (263) (262) (265) (266)
58 59 60 61 62 63 64 65 66 67 68 69 70 71
* / lantaniede
lanthanides Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140,1 140,9 144,2 (145) 150,4 152,0 157,3 158,9 162,5 164,9 167,3 168,9 173,0 175,0
90 91 92 93 94 95 96 97 98 99 100 101 102 103
#
actinides / aktiniede Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232,0 231,0 238,0 237,0 (244) (234) (247) (247) (251) (252) (257) (258) (258) (260)

Semestertest for NCHE111_2024 8/8

GUIDELINES TO PREDICT THE SOLUBILITY OF IONIC COMPOUNDS

SOLUBLE COMPOUNDS
Almost all salts of Na+, K+, NH4+

Salts of:

nitrate, NO3-

chlorate, ClO3-

perchlorate, ClO4-

acetate, CH3CO2-

EXCEPTIONS

Almost all salts of Cl-, Br-, I- Halides of Ag+, Hg22+, Pb2+

Salts containing F- Fluorides of Mg2+, Ca2+, Sr2+, Ba2+, Pb2+

Salts of sulfate, SO42- Sulfates of Ca2+, Sr2+, Ba2+, Pb2+, Ag+

INSOLUBLE COMPOUNDS

EXCEPTIONS
Most salts of:

Carbonate, CO32-

Phosphate, PO43-
Salts of NH4+ and the alkali metal cations
2-
Oxalate, C2O4

Chromate, CrO42-

Sulfide, S2-

Most metal hydroxides and oxides Alkali metal hydroxides and Ba(OH)2 and Sr(OH)2

TOTAL/TOTAAL: 47

Semestertest for NCHE111_2024 9/8