Series : WYXZ5 SET ~ 3
प्रश्न-पत्र कोड
रोल नं. Q.P. Code 56/5/3
Roll No.
परीक्षार्थी प्रश्न-पत्र कोड को उत्तर-पस्ु तिका के
मख
ु -पृष्ठ पर अवश्य स्िखें ।
Candidates must write the Q.P. Code
on the title page of the answer-book.
(I) कृ पया जााँच कर िें स्क इस प्रश्न-पत्र में मस्ु िि पृष्ठ 23 हैं ।
Please check that this question paper contains 23 printed pages.
*5120EAB*
(II) प्रश्न-पत्र में दास्हने हार्थ की ओर स्दए गए प्रश्न-पत्र कोड को परीक्षार्थी उत्तर-पस्ु तिका के मख
ु -पृष्ठ पर
स्िखें ।
Q.P. Code given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
(III) कृ पया जााँच कर िें स्क इस प्रश्न-पत्र में 33 प्रश्न हैं ।
Please check that this question paper contains 33 questions.
(IV) कृपया प्रश्न का उत्तर ललखना शुरू करने से पहले, उत्तर-पुलतिका में यथा तथान पर प्रश्न का
क्रमांक अवश्य ललखें ।
Please write down the Serial Number of the question in the
answer-book at the given place before attempting it.
(V) इस प्रश्न-पत्र को पढ़ने के स्िए 15 स्मनट का समय स्दया गया है । प्रश्न-पत्र का स्विरण पवू ााह्न में
10.15 बजे स्कया जाएगा । 10.15 बजे से 10.30 बजे िक परीक्षार्थी के वि प्रश्न-पत्र को पढ़ेंगे और
इस अवस्ि के दौरान वे उत्तर-पस्ु तिका पर कोई उत्तर नहीं स्िखेंगे ।
15 minute time has been allotted to read this question paper. The
question paper will be distributed at 10.15 a.m. From 10.15 a.m. to
10.30 a.m., the candidates will read the question paper only and will not
# write any answer on the answer-book during this period.
agm`Z {dkmZ (g¡ÕmpÝVH$)
CHEMISTRY (Theory)
निर्धारित समय : 3 घण्टे अनर्कतम अंक : 70
Time allowed : 3 hours Maximum Marks : 70
56/5/3 #1# P.T.O.
General Instructions :
Read the following instructions carefully and follow them :
(i) This question paper contains 33 questions. All questions are compulsory.
(ii) This question paper is divided into five sections – Section A, B, C, D and E.
(iii) Section A – questions number 1 to 16 are multiple choice type questions. Each
question carries 1 mark.
(iv) Section B – questions number 17 to 21 are very short answer type questions.
Each question carries 2 marks.
(v) Section C – questions number 22 to 28 are short answer type questions. Each
question carries 3 marks.
(vi) Section D – questions number 29 and 30 are case-based questions. Each
question carries 4 marks.
(vii) Section E – questions number 31 to 33 are long answer type questions. Each
question carries 5 marks.
(viii) There is no overall choice given in the question paper. However, an internal
choice has been provided in few questions in all the sections except Section A.
(ix) Kindly note that there is a separate question paper for Visually Impaired
candidates.
(x) Use of calculator is not allowed.
SECTION A
Questions no. 1 to 16 are Multiple Choice type Questions, carrying 1 mark
each. 161=16
1. CH3CH2CHO and CH3CH2COOH can be distinguished by :
(A) Sodium bicarbonate test
(B) Hinsberg test
(C) Iodoform test
(D) Lucas test
2. While doing qualitative analysis in chemistry lab, Abhishek added yellow
coloured potassium chromate solution into a test tube. He was surprised
to see the colour of the solution changing immediately to orange. He
realised that the test tube was not clean and contained a few drops of
some liquid. Which of the following substances will be the most likely
liquid to be present in the test tube before adding potassium chromate
solution ?
(A) Sodium hydrogen carbonate solution
(B) Methyl orange solution
(C) Sodium hydroxide solution
(D) HCl solution
56/5/3 #3# P.T.O.
3. The role of a catalyst is to change :
(A) equilibrium constant
(B) enthalpy of reaction
(C) Gibbs energy of reaction
(D) activation energy of reaction
4. Which of the following molecules is chiral in nature ?
(A) 1-chloropropane (B) 2-chloropropane
(C) 1-chlorobutane (D) 2-chlorobutane
5. CH3CH2OH can be converted to CH3CHO by :
(A) catalytic hydrogenation
(B) treatment with LiAlH4
(C) treatment with PCC
(D) treatment with KMnO4
6. The IUPAC name for CH3 – CH2 – N(CH3) – CH2 – CH2 – CH3 is :
(A) N-methylpentan-2-amine
(B) N-ethyl-N-methylpropan-1-amine
(C) N,N-diethylpropan-1-amine
(D) N,N-dimethylpropan-1-amine
7. A plot between concentration of reactant [R] and time ‘t’ is shown below.
Which of the given order of reaction is indicated by the graph ?
(A) Third order (B) Second order
(C) First order (D) Zero order
56/5/3 #5# P.T.O.
8. The treatment of ethyl bromide with alcoholic silver nitrite gives :
(A) ethyl nitrite
(B) nitroethane
(C) nitromethane
(D) ethene
9. Which of the following aqueous solutions will have the highest freezing
point ?
(A) 1·0 M KCl
(B) 1·0 M Na2SO4
(C) 1·0 M Glucose
(D) 1·0 M AlCl3
10. Which of the following aldehydes will undergo Cannizzaro reaction ?
(A) CH3 – CH – CHO
|
CH3
(B) (CH3)3C CHO
(C) CH3 – CH2 – CHO
(D) CH3 – CH – CH – CHO
| |
CH3 CH3
11. In which of the following groups are both ions coloured in aqueous
solution ?
I. Cu+ II. Ti4+ III. Co2+ IV. Fe2+
[Atomic number : Cu = 29, Ti = 22, Co = 27, Fe = 26]
(A) I and II (B) II and III
(C) III and IV (D) I and IV
56/5/3 #7# P.T.O.
12. Match the type of cell given in Column I with their use given in Column II.
Column I Column II
i. Lead storage cell a. Wall clock
ii. Mercury cell b. Apollo Space Programme
iii. Dry cell c. Wrist watch
iv. Fuel cell d. Inverter
(A) i-a, ii-b, iii-c, iv-d (B) i-d, ii-c, iii-a, iv-b
(C) i-c, ii-d, iii-b, iv-a (D) i-b, ii-a, iii-d, iv-c
For Questions number 13 to 16, two statements are given — one labelled
as Assertion (A) and the other labelled as Reason (R). Select the correct
answer to these questions from the codes (A), (B), (C) and (D) as given
below.
(A) Both Assertion (A) and Reason (R) are true and Reason (R) is the
correct explanation of the Assertion (A).
(B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not
the correct explanation of the Assertion (A).
(C) Assertion (A) is true, but Reason (R) is false.
(D) Assertion (A) is false, but Reason (R) is true.
13. Assertion (A) : The solubility of aldehydes and ketones in water
decreases with increase in size of the alkyl group.
Reason (R) : Aldehydes and ketones have dipole-dipole interaction.
14. Assertion (A) : The boiling points of alkyl halides decrease in the order
RI > RBr > RCl > RF.
Reason (R) : The van der Waals forces of attraction decrease in the
order RI > RBr > RCl > RF.
15. Assertion (A) : For measuring resistance of an ionic solution an AC
source is used.
Reason (R) : Concentration of ionic solution will change if DC source is
used.
16. Assertion (A) : Henry’s law constant (KH) decreases with increase in
temperature.
Reason (R) : As the temperature increases, solubility of gases in
liquids decreases.
56/5/3 #9# P.T.O.
SECTION B
17. (a) Calculate the elevation of boiling point of a solution when 3 g of
CaCl2 (Molar mass = 111 g mol–1) was dissolved in 260 g of water,
assuming that CaCl2 undergoes complete dissociation. (Kb for
water = 0·52 K kg mol–1) 2
OR
(b) Liquids ‘X’ and ‘Y’ form an ideal solution. The vapour pressure of
pure ‘X’ and pure ‘Y’ are 120 mm Hg and 160 mm Hg respectively.
Calculate the vapour pressure of the solution containing equal
moles of ‘X’ and ‘Y’. 2
18. Concentration of KCl Conductivity at Molar Conductivity at
solution in mol/L 298·15 K in S cm–1 298·15 K in S cm2 mol–1
1·000 0·1113 111·3
0·100 0·0129 129·0
0·010 0·00141 141·0
Based on the data given above, give plausible reason for the variation of
conductivity and molar conductivity with concentration. 2
19. (a) Give any two differences between order and molecularity of a
reaction. 1
(b) For a reaction X + Y → Z, in which both X and Y follow first order
kinetics; if the concentration of X is increased 2 times and
concentration of Y is increased 3 times, how does it affect the rate
of reaction ? 1
20. Write the mechanism of dehydration of ethyl alcohol with conc. H2SO4 at
443 K. 2
21. (a) Carboxylic acid is more acidic than phenol. Give reason. 1
(b) Give a chemical test to distinguish between benzaldehyde and
acetophenone. 1
56/5/3 # 11 # P.T.O.
SECTION C
22. (a) Shweta mixed two liquids A and B of 10 mL each. After mixing, the
volume of the solution was found to be 20·2 mL.
(i) Why was there a volume change after mixing the liquids ? 1
(ii) Will there be an increase or decrease of temperature after
mixing ? 1
(iii) Give one example for this type of solution. 1
OR
(b) (i) How does sprinkling of salt help in clearing the snow covered
roads in hilly areas ? 1
(ii) What happens when red blood cells are kept in
0·5% (mass/vol) NaCl solution ? Justify your answer. 1
(iii) Write an application of reverse osmosis. 1
23. For the reaction A + B → Products, the following initial rates were
obtained at various initial concentrations of reactants :
Sl. No. [A]/mol L–1 [B]/mol L–1 Initial rate/mol L–1 s–1
1 0·1 0·1 0·05
2 0·2 0·1 0·10
3 0·1 0·2 0·05
Determine the order of the reaction with respect to A and B and overall
order of the reaction. 3
56/5/3 # 13 # P.T.O.
24. (a) Write the name and structure of a hexadentate ligand. 1
(b) Why is [Ni(CN)4]2– square planar while [Ni(CO)4] is tetrahedral ? 2
[Atomic number : Ni = 28]
25. Account for the following :
(a) Haloarenes are less reactive towards nucleophilic substitution
reactions. 1
(b) p-dichlorobenzene has higher melting point than ortho and meta
isomers. 1
(c) Tertiary alkyl halides are least reactive towards SN2 reaction. 1
26. (a) Write the chemical equation for the following : 2
(i) Preparation of phenol from cumene
(ii) Nitration of anisole
(b) Complete the following : 1
(CH3)3 C – O – CH3 + HI →
27. Write the products formed in the following reactions :
(a) CH3CHO + NH2CONHNH2 → 1
dil. NaOH
(b) CH3CHO ⎯⎯⎯⎯⎯⎯
→ 1
2 Cl / red P
(c) CH3COOH ⎯⎯⎯⎯⎯→ 1
H2 O
28. (a) Name the vitamin which is responsible for coagulation of blood. 1
(b) What is meant by denaturation of protein ? Give an example. 2
56/5/3 # 15 # P.T.O.
SECTION D
The following questions are case-based questions. Read the case carefully and
answer the questions that follow.
29. Carbohydrates are polyhydroxy aldehydes or ketones that represent
enormous structural diversity in terms of the arrangement of atoms in
space, resulting in hundreds of stereoisomers. Although the chemical
properties of most stereoisomers may not be very different, their
metabolic rate and utilization in biological systems is significantly
different and known to influence the overall carbohydrate metabolism.
Structural variants, which arise due to a different arrangement of atoms
in three-dimensional space are known as stereoisomers. The number of
stereoisomers can be theoretically estimated by using the formula 2n,
where ‘n’ is the number of stereocenters or asymmetric (chiral) carbon
atoms in a molecule. Out of these stereoisomers, there are some
structures, which are mirror images of each other, and they are referred
to as enantiomers.
Answer the following questions :
(a) Give chemical reactions to show the presence of an aldehydic group
and straight chain in glucose. 2
(b) (i) Define anomers. 1
OR
(b) (ii) Draw the structure of -D-Glucopyranose. 1
(c) Sucrose is known as invert sugar. Explain. 1
30. Werner’s coordination theory in 1893 was the first attempt to explain the
bonding in coordination complexes. It must be remembered that this
theory was put forward before the electron had been discovered by
J.J. Thomson in 1897, and before the electronic theory of valency. Werner
did not have any of the modern instrumental techniques and all his
studies were made using simple experimental techniques. Werner was
able to explain the nature of bonding in complexes and he concluded that
in complexes, the metal shows two different sorts of valency : primary
and secondary. Primary valences are normally ionisable whereas
secondary valences are non ionisable.
56/5/3 # 17 # P.T.O.
Answer the following questions :
(a) One mole of CrCl3 . 4H2O precipitates one mole of AgCl when
treated with excess of AgNO3 solution. Write (i) the structural
formula of the complex, and (ii) the secondary valency of Cr. 2
(b) What is the difference between a complex and a double salt ? 1
(c) (i) Arrange the following complexes in the increasing order of
conductivity of their solution : 1
[Cr(NH3)3Cl3], [Cr(NH3)6]Cl3, [Cr(NH3)5Cl]Cl2
OR
(c) (ii) Write two differences between primary and secondary
valences in coordination compounds. 1
SECTION E
31. (a) (i) When pyrolusite ore is fused with KOH, in presence of air, a
dark green coloured product ‘A’ is obtained which changes to
purple coloured compound ‘B’ in acidic medium.
(I) Write the formulae of ‘A’ and ‘B’.
(II) Write the ionic equation for the reaction when
compound ‘B’ reacts with Fe2+ in acidic medium. 2
(ii) Give reasons : 3
(I) Ce4+ in aqueous solution is a good oxidising agent.
(II) The actinoid contraction is greater from element to
element than lanthanoid contraction.
(III) E value is more negative than expected,
Zn 2+ / Zn
whereas ECu 2+ / Cu is positive.
OR
56/5/3 # 19 # P.T.O.
(b) (i) While studying the periodic properties, Arti came across an
abnormal behaviour in the atomic size of Hf. She found that,
even though Hf is placed below Zr in the same group, both
have almost similar atomic sizes.
(I) Which phenomenon is responsible for the above
behaviour ? Define it.
(II) Mention any other consequence of the above
phenomenon. 2
(ii) Give reasons for the following : 3
(I) Transition metals exhibit catalytic properties.
(II) Transition metals have high enthalpy of atomisation.
(III) Sc is a transition element, while Zn is not.
32. (a) (i) For a galvanic cell, the following half reactions are given.
Decide, which will remain as reduction reaction and which
will be reversed to become an oxidation reaction. Give
reason for your answer. 2
(I) Cr3+ + 3e– → Cr(s); E = – 0·74 V
(II) Fe2+ + 2e– → Fe(s); E = – 0·44 V
(ii) Represent the cell in which the following reaction takes
place : 3
+ 2+
Mg(s) + 2Ag (0·001 M) → Mg (0·100 M) + 2Ag(s)
Calculate Ecell if Ecell = 3·17 V. (log 10 = 1)
OR
(b) (i) State Kohlrausch’s law. Give any two applications of it. 2
(ii) NH Cl, NaOH and NaCl are 129·8, 217·4,
m 4 m m
2 –1
and 108·9 S cm mol respectively. Molar conductivity
of 1 10–2 M solution of NH4OH is 9·33 S cm2 mol–1.
Calculate the degree of dissociation () of NH4OH solution
at this concentration. 3
56/5/3 # 21 # P.T.O.
33. (a) (i) In a chemistry practical class, the teacher gave his students
an amine ‘X’ having molecular formula C2H7N, and asked
the students to identify the type of amine. One of the
students, Neeta, observed that it reacts with C6H5SO2Cl, to
give a compound which dissolves in NaOH solution. Can you
help Neeta to identify the compound ‘X’ ? 1
(ii) Arrange the following in the increasing order of their pKb
value in aqueous phase : 1
C6H5NH2, (CH3)2NH, NH3, CH3NH2, (CH3)3N
(iii) Aniline on nitration gives considerable amount of meta
product along with ortho and para products. Why ? 1
(iv) Convert aniline to : 2
(I) p-bromoaniline
(II) phenol
OR
(b) (i) Arun heated a mixture of ethylamine and CHCl3 with
ethanolic KOH, which forms a foul smelling gas. Write the
chemical equation involved. 1
(ii) Identify A and B in the following reactions : 2
(iii) Convert aniline to : 2
(I) benzene
(II) sulphanilic acid
56/5/3 # 23 # P.T.O.