12-05-2025

2302CJA101021250003 JM

PART-1 : PHYSICS

SECTION-I

1) A ball of mass 1g and charge 10–8 C moves from a point A (VA = 600 V) to the point B whose
potential is zero. Velocity of the ball at the point B is 20 cm s–1. The velocity of the ball at the point A
is :–

(A) 16.7 ms–1

(B) 16.7 cm s–1
(C) 2.8 ms–1
(D) 2.8 cm s–1

2) Point charge q moves from point to point along the path PQRS (figure shown) in a uniform
electric field pointing to words positive direction of the X-axis. The coordinates of the points
P,Q,R and S are (a,b,0), (2a, 0,0),
(a,–b,0) and (0,0,0) respectively. The work done by the field in the above process is given by the

expression

(A)
(B)
(C)

(D)

3) A point charge +q of mass m is located at the centre of a ring having radius R and charge +Q.
When it is displaced slightly, the point charge accelerates along the x-axis to infinity, the ultimate
speed of the point charge ?

(A)

(B)

(C)

(D) zero
4) In figure shown value of x so that electric field at P is zero, is

(A)

(B)

(C)

(D)

5) Self energy of a charged spherical shell having charge Q and radius R is

(A)

(B)

(C)

(D)

6)

Three concentric conducting spherical shells carry charges as follows +4Q on the inner shell, –2Q on
the middle shell and –5Q on the outer shell. The charge on the inner surface of the outer shell is :-

(A) 0
(B) 4 Q
(C) –Q
(D) –2Q

7)

There are four concentric conducting shells A, B, C and D of radii a , 2a, 3a and 4a respectively.
Shells B and D are given charges +q and –q respectively. Shell C is now earthed. The potential
difference
VA – VC is :-

(A)

(B)

(C)
(D)

8)

Shown below is a distribution of charges. The flux of electric field due to these charges through the
surface S is :-

(A) 3q/ε0
(B) zero
(C) q/ε0
(D) 2q/ε0

9) Two point charges of same magnitude and opposite sign are fixed at point A and B. A third small
point charge is to be balanced at point P by the electrostatic force due to these two charges. The

point P :-

(A) lies on the perpendicular bisector of line AB

(B) is at the mid point of line AB
(C) lies to the left of A
(D) none of these

10) A particle A has charge +q and particle B has charge + 4q with each of them having the same
mass m. When allowed to fall from rest through same electrical potential difference, the ratio of
their speed VA : VB will be :-

(A) 2 : 1
(B) 1 : 2
(C) 4 : 1
(D) 1 : 4

11) A charged particle 'q' is shot from a large distance with speed v towards a fixed charged particle
Q. It apporaches Q upto a closet distance r and then returns. If q were given a speed '2v', the closest

distance of approach would be :-

(A) r
(B) 2r
(C) r/2
(D) r/4
12) A charged oil drop is suspended in uniform field of 3 × 104 V/m so that it neither falls nor rises.
The charge on the drop will be :-
(take the mass of the charge = 9.9 × 10–15 kg)

(A) 3.3 × 10–18 C

(B) 3.2 × 10–18 C
(C) 1.6 × 10–18 C
(D) 4.8 × 10–18 C

13) Charges are placed on the vertices of a square as shown. Let be the electric field and V the
potential at the centre. If the charges on A and B are interchanged with those on D and C

respectivcely, then

(A) remains unchanged, V changes

(B) Both and V change
(C) and V remain unchanged
(D) changes, V remains unchanged

14) Variation of electrostatic potential along x-direction is shown in the graph. The correct statement

about electric field is :-

(A) x component at point B is maximum

(B) x component at point A is towards positive x-axis
(C) x component at point C is along negative x-axis
(D) x component at point C is along positive x-axis

15) A hemisphere (radius R) is placed in electric field as shown in fig. Total outgoing flux is :-

(A) πR2E
(B) 2πR2E
(C) 4πR2E
(D) (πR2E )/2

16) The electric field at a point due to an electric dipole, on an axis inclined at an angle to
the dipole axis, is perpendicular to the dipole axis, if the angle is :

(A)

(B)

(C)

(D)

17) In a Neon discharge tube 2.9 × 1018 Ne+ ions move to the right each second, while 1.2 × 1018
electrons move to the left per sec., electron charge is 1.6 × 10–19 C. The current in the discharge
tube :–

(A) 1 A towards right

(B) 0.66 A towards right
(C) 0.66 A towards left
(D) zero

18) The current in a metallic conductor is plotted against voltage at two different temperatures T1
and T2. Which is correct :-

(A) T1 > T2
(B) T1 < T2
(C) T1 = T2
(D) None

19)

The resistance of a wire is 5 ohm at 50°C and 6 ohm at 100°C. The resistance of the wire at 0°C will
be :–

(A) 2 ohm
(B) 1 ohm
(C) 4 ohm
(D) 3 ohm

20) The resistance of a wire is 10Ω. Its length is increased by 10% by stretching. The new resistance
will now be :-
(A) 12Ω
(B) 1.2Ω
(C) 13Ω
(D) 11Ω

SECTION-II

1) Two particals (each of charge +Q) are placed a distance of d. Their electrostatic energy is U.

Now, a third partical of charge is placed at the mid–point of above charges. The new
electrostatic energy of the system is U', such that |U'|= xU. The value of x is

2) Two electric dipoles of dipole moments cm and cm are placed in two

difference uniform electric fields of strengths NC–1 and NC–1 respectively. The

ratio of maximum torque experienced by the electric dipoles will be . The value of x is _______

3) Electric potential in a particular region of space is V = 12x – 3x2y + 2yz2. The magnitude of
electric field at point P(1m, 0, –2m) in (N/C) is:

4) A charge q is located at the centre of an imaginary cube. The electric flux through any face is .
Then value of a is

5) A regular hexagon of 10 cm side has charges of 5 µC at each of its vertices. The potential at its
centre will be............kV.

PART-2 : CHEMISTRY

SECTION-I

1) For the zero order reaction : A → P , k = 10–2 (mol/litre) sec–1 If initial concentration of A is 0.3M
, then find concentration of A left at 10 sec.

(A) 0 M
(B) 0.2 M
(C) 0.1 M
(D) 0.15 M

2) For a gaseous reaction

CH3CHO(g) CO(g) + CH4(g)
initial pressure is 80 mm of Hg and total pressure at the end of 20 minutes is 120 mm of Hg. The
rate constant of the reaction assuming first order kinetics is -

(A) 3.465 × 10–2 min–1

(B) 34.65 min–1
(C) 3.465 min–1
(D) 0.3465 min–1

3) 99% of a first order reaction was completed in 32 min. Time required for completion of 99.9%
reaction will be :-

(A) 48 min
(B) 46 min
(C) 50 min
(D) 45 min

4) A catalyst lowers the activation energy of a reaction from 20 kJ mole–1 to 10 kJ mol–1. The
temperature at which the uncatalysed reaction will have the same rate as that of the catalysed at
27° C is:-

(A) –123°C
(B) 327°C
(C) 150°C
(D) +23°C

5) Which of the following statement is correct regarding enthalpy of reaction -

(A) It does not depend on physical state of reactant or products

(B) It always increases with increase in temperature
It is equal to ratio of activation energy of forward reaction to activation energy of backward
(C)
reaction.
(D) It does not depend on presence of catalyst

6)

For the reaction:

2H2 + 2NO N2 + 2H2O
the following mechanism has been suggested :
2NO N2O2 [equilibrium Constant = K1 (fast)]
N2O2 + H2 N2O + H2O (Slow)

N2O + H2 N2 + H2O (fast)

According to following mechanism is correctly matched:

(A)
= K[NO] [H2] Where K = K2 × K3
(B)
= K[NO] [H2] Where K = K2 × K1

(C)
= K[NO] [H2] Where K = K2 × K1

(D)
= K[NO]2 [H2] Where K = K2 × K1

7) For the equilibrium, A(g) ⇌ B(g), ΔH is –40 kJ/mol. If the ratio of the activation energies of the

forward (Ef) and reverse (Eb) reactions is then :-

(A) Ef = 60 kJ/mol; Eb = 100 kJ/mol

(B) Ef = 30 kJ/mol; Eb = 70 kJ/mol
(C) Ef = 80 kJ/mol; Eb = 120 kJ/mol
(D) Ef = 70kJ/mol; Eb = 30 kJ/mol

8)

Consider the reaction A → B, graph between half life (t1/2) and initial concentration (a) of the
reactant is

Hence graph between and time will be

(A)

(B)
(C)

(D)

9) For which of the following aqueous solutions freezing point is maximum ?

(A) 0.1 M urea

(B) 0.1M NaCl
(C) 0.05 M AlCl3
(D) 0.15 M glucose

10) Which of the following is isotonic with 15 % glucose solution (sp. gr = 1.2) :

(A) 1 M CaCl2
(B) 1 N CaCl2
(C) 0.5 M NaCl
(D) 0.5 M urea

11)

Boiling point of an ideal liquid solution containing non-volatile solute depends on :

(I) Concentration of non volatile solute in the solution
(II) Boiling point of pure solvent
(III) Enthalpy of vapourisation of pure solvent
(IV) Molar mass of solvent

(A) I, II, III

(B) II, III, IV
(C) I, IV
(D) I, II, III, IV

12) Dry air was drawn through bulbs containing pure water ,then through bulbs containing a
solution of 600 grams of a non electrolyte in 360 grams of water at the same temperature and
finally through a tube in which dried CaCl2 was placed. The solution bulbs gained 1.5 gram and the
dried CaCl2 gained 2 [Link] Molecular mass of the solute is :-
(A) 40
(B) 9
(C) 90
(D) 50

13) Vapour pressure of pure liquids 'A' and 'B' are 300 torr and 800 torr respectively at 25°C. When
these two liquids are mixed at this temperature to form a solution in which mole percentage of 'B' is
92, then the total vapour pressure is observed to be 0.95 atm. Which of the following is true for this
solution?

(A) ΔVmix > 0

(B) ΔHmix < 0
(C) ΔVmix = 0
(D) ΔHmix = 0

14) One mole of non volatile solute is dissolved in two moles of water. The vapour pressure of the
solution relative to that of water is

(A)

(B)

(C)

(D)

15) At a given temperature, total vapour pressure in torr of a mixture of volatile components A and B
is given by p =120 -75 XB hence, vapour pressure of pure A and B respectively (in torr) are:

(A) 120, 75
(B) 120, 195
(C) 120, 45
(D) 75, 45

16) henry's law constant for CO2 in water is 1.6 × 108 Pa at 298K. The quantity of CO2 is 500g of
soda water when packed under 3.2 bar pressure at 298K.

(A) 2.44g
(B) 24.4g
(C) 0.244g
(D) 0.61g

17) The value of Henry’s law constant for some gases at 293 K is given below. Arrange the gases in
the increasing order of their solubility.
He : 144.97 kbar, H2 : 69.16 kbar,
N2 : 76.48 kbar, O2 : 34.86 kbar

(A) He < N2 < H2 < O2

(B) O2 < H2 < N2 < He
(C) H2 < N2 < O2 < He
(D) He < O2 < N2 < H2

18) The radioactive sources A and B with half lives of 't' hr and '2t' hr respectively, initially contain
the same number of radioactive atoms. At the end of 't' hours, their rates of disintegration are in the
ratio :

(A) :1
(B) 1 : 8
(C) :1
(D)

19) A radioactive isotope is being produced at a constant rate = in an experiment. The

isotope has half life, t1/2. After a time t >> t1/2, the number of active nuclei will become constant. The
value of this constant is -

(A) R
(B) 1
(C) R/λ
(D) λ/R

20) For an exothermic chemical process occurring in two steps as follows

(i) A + B X (slow) (ii) X AB (fast)
The progress of reaction can be best described by:

(A)
(B)

(C)

(D)

SECTION-II

1) Air is in contact with water causing dissolution of gases in water. Air contains 80% by volume
nitrogen and 3 × 10–3 moles of nitrogen gas dissolve in 100 moles of water. If Henry's constant for
solubility of nitrogen in water is (y × 10x atm) find value of 'x'. Given that air pressure is 5 atm.

2) The total vapour pressure observed by mixing two liquid A and B is 350 mm Hg when their mole
fractions in solution are 0.7 and 0.3 respectively. The total vapour pressure becomes 410 mm Hg if
the mole fractions are changed to 0.2 and 0.8 respectively for A and B in solution. The vapour
pressure of pure A is ______ mm Hg. Consider the solutions to behave ideally.

3) 1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to –4°C before freezing. The
amount of ice (in g) that will be separated out is ________ . (Nearest integer)
[Given : Kf(H2O) = 1.86 K kg mol–1]

4) The number of given statement/s which is/are correct is____

(A) The stronger the temperature dependence of the rate constant, the higher is the activation
energy.
(B) If a reaction has zero activation energy, its rate is independent of temperature.
(C) The stronger the temperature dependence of the rate constant, the smaller is the activation
energy.
(D) If there is no correlation between the temperature and the rate constant then it means that the
reaction has negative activation energy.

5) The rate constants for decomposition of acetaldehyde have been measured over the temperature

range 700 –1000 K. The data has been analysed by plotting In k vs [Link] value of
activation energy for the reaction is___ kJ mol . (Nearest integer) (Given : R = 8.31 J K–1 mol–1)
–1

PART-3 : MATHEMATICS

SECTION-I

1) If A = sin–1 , then

(A)
A = tan–1

(B)
A > tan–1

(C)
A < tan–1

(D)
A = sin–1

2) Let R = {(1, 3), (4, 2), (2, 4), (2, 3), (3, 1)} be a relation on the set A = {1, 2, 3, 4}. The relation R
is-

(A) transitive
(B) not symmetric
(C) reflexive
(D) a function

3) The relation R defined in N as aRb ⇔ b is divisible by a is

(A) Reflexive but not symmetric

(B) Symmetric but not transitive
(C) Symmetric and transitive
(D) Equivalence relation

4) The solution of the inequallity (cot–1x)2 – 5cot–1x + 6 > 0 is :-

(A) (cot 3, cot 2)

(B) (– ∞, cot 3) ∪ (cot 2, ∞)
(C) (cot 2, ∞)
(D) None

5) is

(A)

(B)

(C)

(D)

6) If then

(A)
(B)

(C)

(D)

7) The domain of (where {.} is denotes fractional part of x) is

(A)
(B)

(C)

(D) (0,1)

8) Let f : ℝ – ℝ be real valued function defined as Then rage of f is

(A)

(B)
(C)

(D)

9) f : [–1, 1] → [–1, 2] f(x) = x + |x| is

(A) One-one onto

(B) One-one into
(C) Many one onto
(D) Many one into

10) The equation can have four distinct real solutions for x if k belongs to the
interval

(A)
(B)
(C)
(D)

11) The domain of , is :

(A)
(B)
(C)
(D)

12) Which of the following function is periodic with fundamental period π ?

(A)
where [.] denotes greatest integer function

(B)

(C) where {.} denotes fractional part function

(D)

13) Range of the function is

(A)

(B)

(C)
(D)

14) Let be a function such that . Then

(A) f(x) is many-one in (–∞, –1)

(B) f(x) is many-one in (1, ∞)
(C) f(x) is one-one in [1, ∞) but not in (–∞, ∞)
(D) f(x) is one-one in (–∞, ∞)

15) The domain of the function

is (where [x] denotes the greatest integer less than or equal to x)

(A)
(B)
(C)
(D)

16) If , then range of (fog(x)) is

(A) (0, 1]
(B) [0, 3)
(C) [0, 1]
(D) [0, 1)

17) The range of the function f(x) = is

(A)

(B)

(C)

(D) [1, e]

18) Let f : [–10, 10] → R, where f(x) = sinx + be an odd function. The set of values of parameter
P is/are (where [.] is G.I.F.) :-

(A) (–10, 10) – {0}

(B) [100, ∞)
(C) (100, ∞)
(D) (0, 10)
19) The period of the function f(x) = logcos2x + sin4x is :-

(A) π
(B) 2π

(C)

(D) Not defined

20) , then tan S is

equal to :

(A)

(B)

(C)

(D)

SECTION-II

1) Number of integers lying in range of ƒ(x) = cot–1(loge(1 – x2)) is

2) If y = 3[x] + 1 = 4[x – 1] – 10, then [x + 2y] is equal to (where [.] is G.I.F.)

3) Let f be a real valued invertible function such that . Find .

4) if then the value of is

5) Find the number of roots of the equation

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B A A B D D D D B D A D D A C B B C A

SECTION-II

Q. 21 22 23 24 25
A. 1 6 13 6 27

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A A B D D C C A C D A B A C A A C C C

SECTION-II

Q. 46 47 48 49 50
A. 5 314 518 2 154

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B A B B A D A D A C B B C C C A C A C

SECTION-II

Q. 71 72 73 74 75
A. 2 107 3 90 1
 SOLUTIONS

PART-1 : PHYSICS

16) Here,

19)

Let R = R0 at 0ºC, R = R0, 0ºC

5 = R0(1 + α × 50) …(i)
6 = R0(1 + α× 100) …(ii)
Solving (i) and (ii) ⇒ R0 = 4Ω

20) Since ⇒ If length is increased by 10%, resistance is increases by almost 20%

Hence new resistance R' = 10 + 20% of 10

21)

23) V = 12x – 3x2y + 2yz2

∴ Ex = = 12 – 6xy

Ey = = –3x2 + 2z2

Ez = = 4xy
∴ (1, 0, –2)
Ex = 12 – 0 = 12 ;
 Ey = –3 + 8 = 5 ; Ez = 0
∴ (at 1, 0, –2) =
∴ = 13 N/C

PART-2 : CHEMISTRY

26)

[A]t = [A]0 – Kt
= 0.3 – 10–2 × 10
= 0.2 M

27) CH3CHO(g) → CH4(g) + CO(g)

t=0 80 0 0
t = 20min 80 – x x x
(80 –x) + x + x = 120 ⇒ x = 40
t1/2 = 20min

K= = 3.465 × 10–2 min–1

28)

29)

A catalyst lower the activation energy of a reaction from 20 KJ mol–1 to 10 KJ mol–1.

k = k'
A e–E /RT = A e–E '/RT'
a a

ℓn A –
T = 600 k
T = 327°C

30)

(A) Enthalpy of reaction always depends on physical state of reactants.

(B) It is not necessory that it always increases with increase in temperature.
(C) ΔH is different between [Ea]f – [Ea]b not ratio.
(D) Catalyst decreases activation energy but do not change ΔH.

ΔH = [Ea]f – [Ea]b

31)

according to slow step

r(t) = K2 [N2O2] [H2]

Where K1 =
[N2O2] = K1 [NO]2
So, r(t) = K2 K1 [NO]2 [H2]
So, r(t) = K2 K1 [NO]2 [H2] K.

= K [NO]2 [H2]
Where K = K1 K2

32)

ΔH = Ef – Eb = – 40 kJ

= kJ

= kJ
Eb = 120 kJ/mol Ef = 80 kJ/mol
34) Urea NaCl AlCl3 glucose
[C] 0.1M 0.1M 0.05 M 0.15 M
i = assuming 100% ionisation
i 1 2 4 1
[C]net = i × C
Urea NaCl AlCl3 glucose
[C]net 0.1 0.2 0.2 0.15
ΔTf ∝ [C]net
([C]net = minimum, ΔTf = minimum, freezing point = Maximum)

35) [Glucose] = = 1M

36) Boiling point of an ideal liquid solution containing non-volatile solute depends on all the
given factors. hence all options are correct.

37)

M = 40

38) Ptotal = 0.92 × 800 + 0.08 × 300

= 760 or 1 atm > Pobs.

39) According to Raoult's law:

PS = Po. Xsolvent =
where Ps = vapour pressure of solvent above solution;
Po = vapour pressure of pure solvent & Xsolvent = mole fraction of solvent; Substituting values
given in the question;

42) Solubility

45)
 47)

Let V.P. of pure A be

Let V.P of pure B be
When

… (i)

When

Solving (i) and (ii)

= (314)

48) ⇒ Let mass of water initially present = x gm

⇒ Mass of sucrose = (1000 - x) gm

⇒ moles of sucrose =

⇒ 0.75 =
⇒ 256.5 x = 106 – 1000x
⇒ x = 795.86 gm
⇒ moles of sucrose = 0.5969
New mass of H2O = a kg

⇒ ⇒ a = 0.2775 kg
⇒ ice separated = (795.86 – 277.5) = 518.3 gm

49) k = A.e–Ea/RT

Higher is Ea, stronger is the temperature dependence of k (i.e. steeper the slope)

(B)
 50)
Fromk the graph

Ea = 153.735 kJ/mol
~ 154

PART-3 : MATHEMATICS

52) R : {1, 2, 3, 4} → {1, 2, 3, 4}

R = {(1, 3), (4, 2), (2, 4), (2, 3), (3, 1)}
Hence, (2, 3) ∈ R but
So, R is not symmetric.

53) For any a ∈ N, we find that a is divisible by a, therefore R is reflexive but R is not
symmetric, because aRb does not imply that bRa.

54) (cot–1x)2 – 5cot–1x + 6 > 0

(cot–1x – 3)(cot–1x – 2) > 0
cot–1x < 2 & cot–1x > 3
x > cot 2 & x < cot 3
x ∈ (–∞, cot 3) ∪ (cot 2, ∞)

55)

57) is true for all ,

Case (i) , and not possible

60)

for 4 real roots, and

61)
Put

or
or
or
so

63)

64)

65) ⇒

66)
By (1)
And by (2)
Range of is [0, 1]

68) f : [–10, 10] →R ; f(x) = sinx + be an odd function if =0

∵ –10 ≤ x ≤ 10 ⇒ 0 ≤ x2 ≤ 100

∴ = 0 if P ∈ (100, ∞)

74)

75) Inverse of is
⇒ The roots of the given equation are also roots of

i.e., x = 1