14-12-2025

1001CJA106216260007 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A laser is placed at the midpoint A of base in an isosceles triangular room having vertical plane
mirrors as walls. The angle opposite to the base of the triangle is θ as shown. The laser beam is
projected at an angle α with the bisector line in such a way that the beam comes back to the initial
point offer N reflections with the inclined walls. Distance AO = d. Choose the correct option(s).

(A)
Value of N is

(B)
Value of N is
(C) The distance of closest approach of the ray from the apex O is dsin α
The distance of closest approach of the ray from the apex O is
(D)

2) Consider a ship of mass M and volume V floating in water with density ρ. Assume that its density
is uniform and its horizontal and vertical cross sections are rectangular. To prevent the ship from
overturning, a thin layer of mass m is placed at the bottom floor of the ship. What is the minimum

value of m ?

(A) ρV – M

(B)

(C)

(D)
3) Two spring, each of unstretched length 20 cm but having different spring constants k1 = 1000N/m
and k2 = 3000 N/m are attached to two opposite faces of a block of mass m = 100g kept on a smooth
horizontal surface as shown in the figure. The outer ends of the two springs are now attached to two
pins P1 and P2 whose locations are shown in the figure, as a result of this, the block acquires a new
equilibrium position. The block has been displaced by small amount from its equilibrium position and

released to perform simple harmonic motion, then:

New equilibrium position is at 35 cm from P1 and time period of simple harmonic motion is
(A)

New equilibrium position is at 20 cm from P1 and time period of simple harmonic motion is
(B)

(C) The potential energy stored in spring of spring constant k2 in equilibrium position is 3.75J.
(D) The potential energy stored in spring of spring constant k1 in equilibrium position is 11.25 J.

4) A particle of mass m is projected up from the bottom of an smooth inclined plane with initial
velocity v0 at angle 45° with an inclined plane of inclination 30° as shown in figure. At the same time
a small block of same mass m is released from rest at a height h, the particle hits the block at some
point on inclined plane. (take g = 10 m/s2) (size of the block is negligible)

(A)
The value of height h is .

(B)
The value of height h is .
If the particle stick to the block after collision, the velocity of block parallel to the
(C)
inclined plane just after collision will be .
If the particle stick to the block after collision, the velocity of block parallel to the inclined plane
(D)
just after collision will be .

5) A soap film of thickness h = 1.0 µm is formed in a circular wire loop of radius R = 5 cm. The soap
film is punctured in the center with a very sharp pin due to which the hole made spreads
symmetrically. Assume no loss in energy during retraction and that thickness of the soap film
remains almost unchanged . Surface tension and density of the soap solution are T = 0.04 N/m and
400 kg/m3 respectively.

(A) Speed of the periphery of the hole is independent of radius of hole.

(B)
Speed of the periphery of the hole when radius hole is 20 m/sec.

(C)
Speed of the periphery of the hole when radius hole is 10 m/sec.
(D) Time taken by film to disappear is approximately 0.5 ms.

6) Consider a situation in which there is a Newtonian fluid between two long coaxial uniformly

moving cylinders of radius R and 2R.

(A) Force per unit length required to keep the inner cylinder moving is 4 πηv0.

(B)
Force per unit length required to keep the inner cylinder moving is .
1/3
(C) Distance of the point from the axis at which speed of fluid is zero is 2 R.
(D) Distance of the point from the axis at which speed of fluid is zero is .

SECTION-I (ii)

1) A square platform of side length 8 m is situated in x-z plane such that it is at 16 m from the x-axis
and 8 m from the z-axis as shown in figure. A particle is projected with velocity
m/s relative to wind from origin and at the same instant the platform starts with acceleration
m/s2. Wind is blowing with velocity . Which one of the following options is correct?

(g = 10 m/s2)

List-I List-II

(I) Possible values of v2 (in m/s) so that particle hits the platform is/are (P) 4

(II) Possible value of v1 (in m/s) so that particle hits the platform is/are (Q) 6

(III) Possible time of flight (in second) of the particle is/are (R) 8

Possible value of displacement(s) (in m) of the particle in y direction

(IV) when v2 has its minimum possible value is/are (till particle hit the (S) 20
platform)

(T) None
(A) I → Q,R;II → P,Q;III → P;IV → S
(B) I → Q;II → Q;III → P;IV → S
(C) I → S;II → P,Q;III → Q,R;IV → P,S
(D) I → Q,R;II → P;III → Q,S;IV → P,Q,R

2) Two guns, situated on the top of a hill of height 10 m, fire one shot each with the same speed
m/s at some interval of time. One gun fires horizontally and other fires upwards at an angle of 60°
with the horizontal. The shots collide in air at a point P. Assume origin on the ground and below the
muzzle and motion of the shots in xy-plane (x-axis along horizontal and y-axis vertically upward)

List-I List-II
The time interval between the
(I) firing of first shot to the instant (P) 5
of collision (in second)
x-coordinate at the instant of
(II) (Q) 2.5
collision (in m)
y-coordinate at the instant of
(III) (R)
collision (in m)
Just before the collision,
magnitude of y- component of (S) 2
(IV) relative velocity of one shots
with respect to other shot (in (T) 7
m/s)
(A) I → S;II → R;III → P;IV → Q
(B) I → R;II → S;III → P;IV → Q
(C) I → P;II → Q;III → R;IV → S
(D) I → S;II → R;III → Q;IV → P

3) List -I represents the different spring mass systems. All springs and pulleys are ideal. List-II
represents their time periods of small oscillations about equilibrium position. Match the systems
mentioned in List-I with the corresponding time periods in List-II.

List-I List-II

(I) (P)
 (II) (Q)

(III) (R)

(IV) (S)

(T) None
(A) I → S;II → P;III → R;IV → Q
(B) I → R;II → P;III → S;IV → Q
(C) I → R;II → S;III → P;IV → Q
(D) I → S;II → P;III → Q;IV → R

4) The position of a mirror and a particle moving along X-axis is given by xm = t3 – 6t2 and xp = 9t2 –

60t. Match the List-I with List-II.

List-I List-II
(I) Velocity of image of particle is zero (P) 2 sec
(II) Acceleration of image of particle is zero (Q) 3 sec
(III) Acceleration of image of particle is negative (R) 3.5 sec
(IV) Velocity of image of particle is towards the origin (S) 4 sec
(T) 5 sec
(A) I → P,T;II → P,T;III → R;IV → Q,R,S
(B) I → P,T;II → R;III → P,Q;IV → Q,R,S
(C) I → P,R;II → R,T;III → P,Q;IV → P,R,S
(D) I → P,T;II → P,Q;III → R;IV → Q,R,S
 SECTION-II

1) A plane mirror of length 1.50 m hangs on a 2.50 m tall wall inside a room. The bottom of mirror is
0.50 m above the floor. A small bulb is situated at the ceiling of room at a distance of 1.0 m from the
wall of plane mirror as shown in the figure. Find the length (in m) of patch of light on the floor due

to reflection from mirror (assume floor size is sufficient)

2) Rod is massless and of length . Find angular frequency ω (in m/s) of small oscillation of the block
of mass m, the hinge is frictionless. k1, k2, k3 are spring constants of the shown springs. Ignore

gravity.

3) In the figure shown a light spring of spring constant 'k' is attached at the ends of two uniform
identical rods of mass 'm' and length 'ℓ' each. The rods can rotate about other ends. They are rotated
by same and small angles in opposite direction in the plane of the figure and released. Neglecting

the effect of gravity, the angular frequency of oscillation of the rods is w. Fill (Take : k = 600

N/m, m = 1kg)

4) A ball is thrown with a speed m/s so that the area enclosed by the balls trajectory with
the horizontal surface is maximum. Taking g = 10 m/s2 and the maximum area (in m2)
enclosed by the balls trajectory with the horizontal surface is closest to the whole number _______

5) A swimmer is crossing the river by path which takes minimum time, His speed is 2u0 in whole
motion. Swimmer start from O. Drift of swimmer on crossing river is :-
Vr → Speed of river at point (x,y) & d = 60 m

6) A very long open cylindrical container of radius R = 5m, has a small hole at the bottom on the
curved surface. Initially the hole is closed and water is filled into the container. Now the container is
slowly rotated about its axis so as to acquire an angular speed of rad/sec as shown in the figure.
As seen from the rotating frame of the container, the initial speed of efflux after opening the hole is

n m/s then n = ? (Take g = 10m/s2 , initial height of water in container is 5m)

7) A thin plate AB of large area A is placed symmetrically in a small gap of height h filled with water
of viscosity η0, and the plate has a constant velocity V by applying a force F as shown in the figure. If
the gap is filled with some other liquid of viscosity 0.75 η0, at what minimum distance (in cm) from
top wall should the plate be placed in the gap, so that the plate can again be puled at the same
constant velocity V, by applying the same force F? (Take h = 20 cm)

8) An artificial satellite falls back to the Earth due to malfunction. During its last stage just before
hitting the ground, its height is much smaller than the Earth's radius (so acceleration of a satellite
can be considered as g). to avoid its hitting the ground, a projectile is launched to destroy it, as
shown in the figure below. The launching speed u is fixed but the launching angle θ is arbitrary.
Ignore air resistance. Find the minimum value of u (in m/s) so that the projectile can hit the satellite
before it hits the ground. (Given : r = 3 km, β = 60°, v = 500 m/s, α = 30°).
 PART-2 : CHEMISTRY

SECTION-I (i)

1) Observe the following potential energy V/S dihedral angle graph. Which compound(s) can have
this graph

(A)
(B)

(C)

(D)

2) (I) (II) (III)

(IV) (V)
Correct statement(s) about given compounds is/are :

(A) Compound IV and V are Diastereomers.

(B) Compound II and III are mirror images of each other.
(C) Compound V is more stable than compound IV due to intramolecular hydrogen bonding.
(D) Compound I have POS so it is optically inactive.

3) Which of the following statement(s) is/are correct?

Bond dissociation enthalpy of hydrogen halide (HX) and dihalogen (X2) show similar trends as
(A)
we move down the group in periodic table
 Extent of dimerization of CH3COOH is generally higher in non-polar solvent like benzene as
(B)
compare to polar solvent like methanol.
(C) In P(CH3)3F2 the methyl groups are in equatorial, rather than axial, positions.
(D) & both have different bond order.

4) Which of the following statement(s) is/are correct?

(A) Among isoelectronic mononuclear species ionization energy increases with atomic number.
(B) All three coinage metals have (n – 1)d10 ns1 electronic configuration in their ground state.
(C) Technetium is smallest synthetic element of f block.
(D) Oxygen has lowest electron affinity in its group.

5) A definite mass of H2O2 is oxidized by excess of acidified KMnO4 and acidified K2Cr2O7 in separate
experiment. Which of the following is/are correct statement ?
[K = 39, Cr = 52, Mn = 55]

(A) Mass of K2Cr2O7 used up will be greater than that of KMnO4

(B) Moles of KMnO4 used up will be greater than that of K2Cr2O7
(C) Equal mass of oxygen gas is evolved in both the experiment.
If equal volumes of both the solutions are used for complete reaction, then the molarities of
(D)
KMnO4 and K2Cr2O7 solution are in 6 : 5 ratio.

6) When photons of energy 4.25 eV strikes the surface of a metal 'A', the ejected photoelectrons have
maximum kinetic energy TA (in eV) and de Broglie wavelength The maximum kinetic energy of
photoelectrons liberated from another metal 'B' by photons of energy 4.20 eV is TB (= TA – 1.50 eV).
If the de Broglie wavelength of these photoelectrons is then

(A) the work function of 'A' is 2.25 eV.

(B) the work function of 'B' is 3.70 eV.
(C) TA = 2.00 eV
(D) TB = 2.75 eV

SECTION-I (ii)

1)

List-I (Compound) List-II (Relation)

(P) (1) Functional group Isomerism

(Q) (2) Structural Isomerism

 (R) (3) Conformational Isomerism

(S) (4) Geometrical Isomerism

(5) Metamer

The CORRECT option is :

(A) P → 3;Q → 2;R → 4;S → 1,2
(B) P → 4;Q → 3;R → 1,2;S → 2
(C) P → 4;Q → 1,3;R → 2;S → 1
(D) P → 1,2;Q → 4;R → 2;S → 3

2)

List-I List-II
(Molecule) (Property)

(P) (1) Meso compound

Compound having even

(Q) (2)
number of chiral centres.

Optically active
(R) (3)
compound
 Compound having odd
(S) (4)
number of chiral centres.

(5) Achiral
(A) P → 2;Q → 3,4;R → 3,4,5;S → 1,2
(B) P → 1;Q → 2,3;R → 3,5;S → 1,2,3
(C) P → 2,3;Q → 3,4;R → 2,3;S → 1,2,5
(D) P → 2,4;Q → 3,4,5;R → 1,2,3;S → 1

3)

List-II
List-I
(Properties which are common in both
(Pair of molecules)
molecules)

(P) SO2 & SO3 (1) Maximum number of atoms in one plane

Number of d-orbitals used by central atom

(Q) PCl5 & XeO3F2 (2)
for bond formation (if any involved)

(R) H2O & NH3 (3) Shape of molecule

(S) SF6 & XeF4 (4) Number of bond angles which are ≥ 90°

Bond order (average) (Between any two

(5)
bonds)
(A) P → 5;Q → 1,4;R → 1,5;S → 1,3
(B) P → 1;Q → 1,3;R → 2,5;S → 1,4
(C) P → 5;Q → 1,3;R → 1,5;S → 1,5
(D) P → 4;Q → 4,3;R → 1,2;S → 1,4

4) Match the lists.

List-I
(Endothermic equilibrium List-II
reactions)

(P) 2NH3(g) N2(g) + 3H2(g) (1) Introduction of catalyst do not affect equilibrium.

(Q) PCl5(g) PCl3(g) + Cl2(g) (2) Addition of more reactant do not affect equilibrium.

On adding inert gas at constant volume, equilibrium

(R) 2HI(g) H2(g) + I2(g) (3)
state does not change.

On adding inert gas at constant pressure,

(S) NH4HS(s) NH3(g) + H2S(g) (4)
equilibrium shift in forward direction.

α is independent of equilibrium pressure.

(5)
(α = degree of dissociation)
(A) P → 1,3,4;Q → 1,3,4;R → 2,4,5;S → 1,2,3
(B) P → 2,3,4;Q → 2,3,5;R → 1,3,4;S → 1,2,3,4
(C) P → 2,3,4;Q → 1,3,5;R → 1,3,4;S → 1,2,3,4
(D) P → 1,3,4;Q → 1,3,4;R → 1,3,5;S → 1,2,3,4

SECTION-II

1) How many enol form is possible for (including stereoisomers)

will be ?

2) How many of the following having pKa greater than phenol ?

(1) (2) (3) (4)

(5) (6) (7) (8)

3) Mixture of two elemental diatomic gases A & B is used as rocket fuel due to their exothermic
reaction. Gas A is most abundant element in the universe and Gas B is second most abundant
element in the earth atmosphere.
If Gas A & B combines in 2 : 1 and 1 : 1 molar ratio they produce two different compounds C & D
respectively. Number of following statements which are correct about A, B, C & D.
(1) Gas B is nitrogen
(2) Gas A is hydrogen
(3) For compound D maximum number of atoms in one plane is equal to its atomicity
(4) For compound C maximum number of atoms in one plane is equal to its atomicity
(5) Compound D have higher boiling point compared to compound C
(6) Compound C form much stronger hydrogen bond compare to compound D

4) Zeolite ZSM-5 with a composition Nax[AlySi96-ZO192].16H2O (where x, y or z < 27) is used as a

catalyst in benzene alkylation, xylene isomerisation and methanol to hydro carbon (for motor fuels)
conversion. It is a type of 3D-silicate where some of the silicon atoms have been replaced by
aluminium atoms. If number of Si atoms are 5 times as compare to Na atoms in a Zeolite. Calculate
ratio of number of Al atoms and silicon atom present in this Zeolite.

5) An element E form amphoteric oxide ExOy. If E+y contain same number of 3d electrons as present
in cation of amphoteric oxide of Manganese.
(a) If maximum possible number of electrons present in orbitals having zero nodal planes in case of
cation of E in amphoteric oxide is 'P'
(b) Atomic number of element E is 'Q'

Calculate value of

6) For a fixed amount of real gas, when a graph of Z v/s P was plotted, then at very high pressure,
slope was observed to be 0.01 atm–1. At the same temperature if a graph is plotted between PV v/s P,
then for 2 moles of the gas, the ‘Y’ intercept is found to be 40 atm-litre. Calculate excluded volume
(in litres) for 20 moles of the real gas.

7) Gas A (Molecular mass 16) and gas B (Molecular mass 4) are confined into a vessel at partial
pressure of 2 atm each at 27°C. The gases are then allowed to effuse out at 27°C through a valve till
the pressure inside the vessel becomes 2 atm, after which valve is closed and the remaining gases
are heated to 177°C and allowed to react as

A(g) + B(g) ⇌ C(g) ; atm–1 at 177°C.

Calculate partial pressure of C (in atm) at equilibrium, assuming C is not formed till effusing process
is completed at 27°C.
(Assume rate of effusion of gases to be constant and equal to their initial rate of effusion)

8) A solution has two solutes, A and B. Molarity of solute A is 0.5 M and of solute B is 1M. What
should be the density of solution (in gm/ml) so as numerical value of molality of both solute is equal
to numerical value of their molarity ?
(Molecular weight of solute A and B are 180 and 60 respectively).

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let maximum and minimum value of expression is M and m respectively then :

(A) m = 0
m=
(B)

(C) M = 1
 M=
(D)

2) A line L is drawn from P(4, 3) to meet the lines L1 ≡ 3x + 4y + 5 = 0 and L2 ≡ 3x + 4y + 15 = 0 at

points A and B respectively. From point A a line perpendicular to L is drawn meeting the line L2 at
A1. Similarly from point B, a line perpendicular to L is drawn meeting the line L1 at B1. Thus a
parallelogram AA1BB1 is formed. The equation of L so that area of parallelogram AA1BB1 is least -

(A) x – 7y + 17 = 0
(B) 7x + y – 31 = 0
(C) x – 7y – 31 = 0
(D) 7x + y + 17 = 0

3) The co-ordinates (2, 3) and (1, 5) are the foci of an ellipse which passes through the origin, then
the equation of

(A)
Tangent at the origin is

(B)
Tangent at the origin is

(C)
Normal at the origin is

(D)
Normal at the origin is

4) If foci of concide with the focii of and eccentricity of the hyperbola is 2,

then

(A) a2 + b2 = 16
(B) there is no director circle to the hyperbola
(C) centre of the director circle of hyperbola is (0, 0)
(D) length of latus ractum of the hyperbola = 12

5)

Pair of tangents drawn from P(–2, 1) to y2 = 4x touching the parabola at A and B then area of ΔPAB
is (in square units) greater than or equal to

(A)

(B)

(C)

(D) 27

6) If the circles x2 + y2 – 9 = 0 and x2 + y2 + 2αx + 2y + 1 = 0 touch each other, then α is

(A)

(B) 0
(C) 1

(D)

SECTION-I (ii)

1)

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II
Distance between the two lines and
(I) (P) 1
is
The variable line x + λy + λ – 5 = 0 (λ ∈ R) passes through
(II) (Q) 2
a fixed point. The x co-ordinate of fixed point is
The x-coordinates of the point of intersection of lines 3x +
(III) 4y = 9 and y = mx + 1 is an integer, if m is also an integer (R) 5
then sum of possible values of m is
The x-coordinate of incentre of triangle, whose vertices are
(IV) (S) –3
and (2,0), is
(T) –1
(A) I → Q;II → R;III → P;IV → S
(B) I → Q;II → R;III → S;IV → P
(C) I → R;II → Q;III → S;IV → P
(D) I → P;II → Q;III → S;IV → R

2) Let ℓx + my + 1 = 0 is common tangent of curves x2 = 4y, 12x2 + 4y2 = 3 and y2 = 4ax, a > 0.
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(I) 4ℓ2 – a (P) neither prime nor composite number

(II) 3m2 + 3a (Q) odd composite number

(III) (R) odd prime number

(IV) 2a2 + 3ℓ2 + 4m (S) even composite number

(T) complex number

(A) I → P;II → Q;III → S;IV → R
(B) I → P;II → T;III → Q;IV → R
(C) I → Q;II → R;III → S;IV → P
(D) I → R;II → S;III → P;IV → Q

3) Let tangent of parabola y2 = 4x at point P(x1, y1) and Q(x2, y2) intersect each other at
R(–15, –2). If S is area of ΔPQR and (x0, y0) is circumcentre of ΔPQR, (where y2 > y1).
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(I) x1x2x0 – 2S (P) 208

(II) (Q) 147

(III) (R) 163

(IV) (S) 182

(T) 190
(A) I → R;II → P;III → S;IV → Q
(B) I → P;II → Q;III → R;IV → S
(C) I → P;II → R;III → T;IV → Q
(D) I → S;II → R;III → Q;IV → T

4) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

Number of solutions of 4(sin6θ + cos6θ) = 10 – 18sinθcosθ

(I) (P) 2
in [0, 3π], is

Number of possible pairs (x, y) satisfying

(II) (Q) 3
x2 – 6x + 10 – sin2y = 0, where y ∈ [0, 2π] and x ∈ R, is

(III) (R) 4
Number of integral values of x in [0, 2π] satisfying , is

(IV) Number of solutions satisfying tanx + secx = 2cosx in [0, 4π], is (S) 5

(T) 6
(A) I → Q;II → P;III → S;IV → R
(B) I → P;II → Q;III → S;IV → R
(C) I → P;II → T;III → R;IV → S
(D) I → Q;II → P;III → R;IV → T

SECTION-II

1) A circle by given x2 + y2 + 4x – y + c = 0 is the director circle of circle S1 and S1 is the

director circle of circle S2 and so on. If the sum of radii of all these circles is 2, then the value of c is
equal to where n ∈ N. Find the value of n.

2) Let L1, L2 and L3 be the length of tangents drawn from a point P to the circles x2 + y2 = 4, x2 + y2 –
4x = 0 and x2 + y2 – 4y = 0 respectively. If L14 = L22L32 + 16, then locus of P are the curves C1(a
straight line) and C2(a circle). Let the circumcentre of the triangle formed by C1 and other two lines
which are inclined at an angle of 45° with C1 and is tangent to C2 is (α, β), then (α + 2β) equals

3) If point (2a, a) lies inside the parallelogram formed by the lines 2x – y + 1 = 0, 2x – y – 20 = 0, x +

y – 1 = 0 and x + y – 8 = 0, then sum of all integral values of 'a' is -

4) Consider the family F of the straight lines passing through the intersection of the lines 2x + y + 3
= 0 and 5x + 4y – 9 = 0. Then number of lines belonging to the family F whose distance from the

point (13, –10) is in the form , where α is a parameter (α ∈ R+) is

5) If e1 is the eccentricity of the ellipse (b < 4) and e2 is the eccentricity of the

hyperbola and e1e2 = 1, then b2 is equal to

6) Let the focus of conic is at (a, b) then is :

7) If the points P, A and B are (1, 0), (t2, 2t) and respectively, then

8) Let P(x) be a cubic polynomial and α, β, γ are roots of equation P(x) = 0. If

, then the value of is equal to

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,C,D C A,C,D A,D A,B B,C

SECTION-I (ii)

Q. 7 8 9 10
A. A A B B

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 3.75 8.00 6.00 195.00 10.00 15.80 to 15.83 5.00 604.00 to 612.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A A,B,C,D B,C,D A,B,D A,B,C,D A,B,C

SECTION-I (ii)

Q. 25 26 27 28
A. B C C D

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 4.00 3.00 4.00 0.20 6.20 4.00 0.80 1.15

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,D A,B A,C A,B,D A,B,C A,D

SECTION-I (ii)

Q. 43 44 45 46
A. B D A A
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 32.00 0.00 3.00 0.00 7.00 3.00 1.00 7.00
 SOLUTIONS

PART-1 : PHYSICS

1)
The path of the light ray can be projected in the same direction by placing identical triangles
one after the other. For example after 1st reflection at point 1, ray would actually go to 2' but
we can place an adjacent triangle and say that ray would go straight to point 2. Similarly the
complete zig-zag actual path can be replaced by just a straight line path from A to B as shown.

By dropping a perpendicular from D upon line AB we can see that the distance of closest
approach

= d sin α =

2)
Correct answer (C)

3)
x & y are extension in the spring
For eq.
k1x = k2y ... (1)
x + y = 0.2m ... (2)

,
= 5 cm = 15 cm
For time period
Displace block by small distance lets say 'z'

Potential energy =

4)

Correct answer A,D

5)

Correct Answer is (A,B)

6)
7) Correct Answer is (A)

8)
As shown in figure, from equation of motion

for first gun,

...(i)

and ...(ii)
While for the second gun
...(iii)

and ...(iv)
For collision, x1 = x2 and y1 = y2

i.e.,

and
i.e., t2 = 2t1 and
which on simplification gives t1 = 1 sec and t2 = 2 sec (as t2 ≠ 0) and substituting t1 = 1 s and g
= 10 m/s2 in equations (i) and (ii) co-ordinates of point P will be
m

9)

Correct Answer is (B)

10)
∴ yimg = (6t2 – 24t) – (18t – 60)
= 6t2 – 42t + 60
(A) 0 = 6(t2 – 7t + 10) = 6(t – 2) (t – 5)
∴ t=2&5
(B) aimg = 12t – 42

11)

⇒ = 4.0 m

⇒ =0
length of patch on floor = = 3.75 m

12)

Correct answer is 8.

13)

Correct answer is 6
14)
Coordinates of the ball at t = t is

and time of flight is

Area under trajectory is

For A to be maximum,

15)
t = 6 sec

⇒ x = 10 m

16)

Correct Answer is 15.80 to 15.83

 17) Case I

As plates have 2 sides, Total force

Case II
This force should be equal as in case I

For minimum distance from top,

18)

Correct Answer is 604.00-612.00

PART-2 : CHEMISTRY

19)

Only (A) shows Gauche effect.

20)

The correct answer is option (A),(B),(C) & (D)

21) • Cl2 > Br2 > F2 > I2 (Bond strength)

H F > HCl > HBr > HI (Bond strength)
• Non polar solvent does not affect hydrogen bonding how ever methanol (solvent) make H-
bonding with solute particles, which reduces intermolecular hydrogen bonding between acetic
acid particles.

22) • Tc is d-block element

• Cu, Ag & Au have ns1(n – 1)d10 electronic configuration
• Zeff = Z – σ
For isoelectronic species σ is same, so I.E. ∝ Z

23) E of H2O2 = E of KMnO4 = E of K2Cr2O7 = E of O2

⇒

or
⇒

or

24)

For and

For and
As and

25)

The correct answer is option (B)

26)

The correct answer option is (C)

27)

Theory based

28)

Correct answer is option (D)

29) (E & Z)

(cis & trans)

30)
Phenol is more acidic than following :

31)

Statements (2), (4), (5) & (6) are correct

32) 3D-Silicate = SiO2 or Si96O192

z Si+4 atoms have been replaced by Al+3 then
y = z and using charge balence (x + 3y = 4z) ; x = z
96 – z = 5x
x = 16 = y
number of silicon atoms = 96 – 16 = 80

Number of Al atom per Si atom =

33) Amphoteric oxide of Mn is MnO2 (Mn+4)

Mn+4 = 1s2 2s2 2p6 3s2 3p6 3d3
Cation of E contain 3, d-electrons, it will belongs to 3d series. Amphoteric oxide of 3d series
are V2O5, Cr2O3, MnO2, ZnO
Only possible answer will be Cr2O3
Cr+3 = 1s2 2s2 2p6 3s2 3p6 3d3
P = 7 Q = 24 (Cr) x = 2 y = 3

34)

⇒ b = 0.2 L mol–1
Now, excluded volume = nb = 20 × 0.2 = 4.00 L.

35) A(g) + B(g) ⇌ C(g) atm–1

Partial 2 atm 2 atm

After effusion atm atm

At 177°C 2 atm 1 atm
At eq. 2–x 1–x x
 10x2 – 33x + 20

x= atm.

36) Let volume be 1L (1000 ml)

For molarity and molality to be equal numerical
Value of volume (in L) is equal to
Mass of solvent (in kg)

d = 1.15 gm/ml

PART-3 : MATHEMATICS

37) Let
⇒ 2E – E cos θ = 1 + sin θ
⇒ 2E – 1 = E cos θ + sin θ
∴
⇒
⇒
⇒

m = 0 and M =

38) The given lines L1 & L2 are parallel and distance between them (BC or AD) is =
units

Let ∠BAC = θ
⇒ AB = BCcosecθ = 2cosecθ
and AA1 = AD secθ = 2secθ
Now area of parallelogram AA1BB1 is

Δ = AB . AA1 = 4secθ cosecθ =

 clearly Δ is least for
Let slope of AB be m

⇒ tan45 = ⇒ 4m + 3 = ± (4 – 3m)

⇒ m = or – 7
∴ equation of 'L' is x – 7y + 17 = 0
or 7x + y – 31 = 0

39) Tangent and normal are bisectors of

Now equation of SP is y = 3x / 2 and that of S'P is y = 5x

Then equations of their bisectors are

or

Lines are

and

Now (2, 3) and (1, 5) lie on the same side of which is equation
of tangent.

Points (2,3) and (1, 5) lie on the different sides of which

equation of normal.

40) For the ellipse : e = =

∴ focii are (–4, 0) and (4, 0)
For the hyperbola
ae = 4, e = 2
∴a=2
b2 = 4 (4 – 1) = 12
b=

41) Area

42) Equation of the radical axis is 2αx + 2y + 10 = 0

i.e. αx + y + 5 = 0 ....(i)
Putting the value of y from Eq. (i) in the circle x2 + y2 = 9,
we get
(1 + α2)x2 + 10αx + 16 = 0
∵ Radical axis is tangent
∴D=0
⇒ 36α2 – 64 = 0
⇒α=±

43) (I)
(II) (x – 5) + λ(y + 1) = 0
⇒ (5, 1) is the fixed point.

(III)
m = –1,–2
sum = –3
(IV) Triangle is equilateral

44) Let y = mx + c is common tangent

∴
⇒ m = –1, a = 1, c = –1
common tangent y = –x – 1
x+y+1=0
ℓ = 1, m = 1

45) P(x1, y1) ≡ (t12, 2t1)

Q(x2,y2) ≡ (t12, 2t2)
R(–15,–2) ≡ (t1t2, t1 + t2)
∴ t1 = –5, t2 = 3
P(25,–10), Q(9, 6)
intersection point of normals at P,Q is T(21,–30)
∴ circumcentre (x0,y0) ≡ (3,–16) is midpoint of TR

46) (I) 4(sin6θ + cos6θ) = 10 – 18sinθcosθ

4 – 3sin22θ = 10 – 9sin2θ
3sin22θ – 9sin2θ + 6 = 0
sin22θ – 3sin2θ + 2 = 0
(sin2θ – 1) (sin2θ – 2) = 0
sin2θ = 1 in [0,3π]

(II) x2 – 6x + 10 = sin2y
or sin2y = (x – 3)2 + 1
sin2y = 1 for x = 3

and
(III)

∴ x = 0,3,4,5,6
(IV) tanx + secx = 2cosx
1 + sinx = 2cos2x
1 + sinx = 2 – 2sin2x
2sin2x + sinx – 1 = 0
2sin2x + 2sinx – 1 = 0
(2sinx –1) (sinx + 1) = 0

(rejected)

in [0,4π] no of solutions is 4.

47) Radius of given circle = = = a (say)

Now radius of circle S1 = , radius of circle S2 = and so on.

Now a + + + .....∞ = 2 (Given) ⇒ =2 ⇒ =2

⇒ a=2– = ⇒ 4+2– = 6 – c. Hence c = Ans.

48)
(h2 + k2 – 4)2 = (h2 + k2 – 4h) (h2 + k2 – 4k) + 16
⇒ (h + k) (h2 + k2 – 2h – 2k) = 0
circle C1 : x2 + y2 – 2x – 2y = 0 and
C2 : x + y = 0
circumcentre will be mid point of
hypotenuse in right angle triangle
(α,β) = (0,0)

49)
here 1 < 3a < 8 ...(i)
and –1 < 3a < 20 ...(ii)
(i) ∩ (ii)

50)
Intersection point of
2x + y + 3 = 0
& 5x + 4y – 9 = 0
is (–7, 11)
hence maximum distance of point (13, –10)
& any member of family is '29' but the given distance

, (a ∈ R+)

is more than or equal to 30 because hence no such lines are possible.

51)

52) Vertex is (2, 2) and

so, focus are

53)
54) Let P(x) = k(x – α)(x – β)(x – γ)

put , &x=0