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Hydrocarbon Reactions and Properties

The document discusses various chemical reactions and processes related to hydrocarbons, including Kolbe Electrolysis, Soda-Lime Decarboxylation, and Corey’s House Synthesis. It highlights mechanisms for forming symmetrical alkenes and compares reaction rates and chemical properties. Additionally, it touches on photohalogenation and combustion reactions of hydrocarbons.

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iqbaalfaariahtasneem
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3 views80 pages

Hydrocarbon Reactions and Properties

The document discusses various chemical reactions and processes related to hydrocarbons, including Kolbe Electrolysis, Soda-Lime Decarboxylation, and Corey’s House Synthesis. It highlights mechanisms for forming symmetrical alkenes and compares reaction rates and chemical properties. Additionally, it touches on photohalogenation and combustion reactions of hydrocarbons.

Uploaded by

iqbaalfaariahtasneem
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

--

4, -cHs
~
-
e 4

CH, C42
violet

non-selective
selective

reversible
I
A + X
exolhesic
a
Light
plent
&
I
t
/
u
&
a 2.
3

I I'
U
30:20:1
82: (
1600:
0
I strong
RA
to prevent -
d
nNOS
Reversible
OA RX
newne
~
Hydrocarbons R-R

From carboxylic acid ( Kolbe Electrolysis ) CHz-CH3

II
I
CO2 H20
2R
R-R
C OH +
symmetrical
-
- +

alkane
Hydrocarbons

Soda - Lime Decarboxylation


Soda-Lime

⑧
R-H + CO2
D 0

It On- 11
R-c-0H R -c
-

-> -
0
-
Ht

It I was
-

R -c -0 -> R + W2
I
Cabanion
rate a stability
of c-
RV 10
+

>
-
R-H
Hydrocarbons
~ Soda-Lime Decarboxylation)
Compare Rate :
TMT
--

7 >

O -
&I
&- -
↓
Hydrocarbons M, H -I
-

8 - - -

-
I
-
M H
+

a sd> c 2b
Hydrocarbons

Corey’s House Synthesis :


un
It is used for the formation of symmetrical alkene
R
⑳

he h

wa

RzG Li+ RBU


de
R. R
Mechanism
-

Lull
R -X Zi R-Li le di
->
Ra
(Gilman

s
ti [
Reagent)
pX R-R + R-G+ hiX

~ aLi+um
·
Attack I R is RDS
·
ROR C -
Sa o RX
·

If' is same,

R-F < R-U < R- B5 <R-1

useful for
the
o
preparation
uncymmetrical alkanes.
-Rate
Compare B8
Br
I -
7 7

B8
1 20 30
Hydrocarbons
R
Chemical Properties :
I

Ro U
-> sunlight
Photohalogenation =
x
- x

R X
-

R. Y

L R -
X

seenlight
Hydrocarbons

Reed’s Reaction

↑R-C + SO, +UK


-
Hydrocarbons CnHan +2
302 nCO2 +(n+Y D
+

Combustion I complete

--> GO2 420+

- >
>
CO2 + H20
Hydrocarbons

Isomerization

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