Biomass Energy Engineering Notes
Biomass Energy Engineering Notes
Biomass Energy
Biomass is biological material derived from living, or recently living organisms. Refers to
plants or plant-derived materials which are specifically called lignocellulose biomass.
As a renewable energy source, biomass can either be used directly via combustion to
produceheat, or indirectly after converting it to various forms of biofuel.
Benefits of Using Biomass
1) Biomass used as a fuel reduces need for fossil fuels for the production of heat, steam, and
electricity for residential, industrial and agricultural use.
2) Biomass is always available and can be produced as a renewable resource.
3) Biomass fuel from agriculture wastes maybe a secondary product that adds value to
agricultural crop.
4) Growing Biomass crops produce oxygen and use up carbon dioxide.
5) The use of waste materials reduce landfill disposal and makes more space for everything
else.
6) Carbon Dioxide which is released when Biomass fuel is burned, is taken in by plants.
7) Less money spent on foreign oil.
Photosynthesis Process
The process by which plants and other photoautotrophs generate carbohydrates and oxygen
from carbon dioxide, water, and light energy in chloroplasts, the "fuel" used by all living things.
The conversion of unusable sunlight energy into usable chemical energy, is associated with the
actions of the green pigment chlorophyll.
Most of the time, the photosynthetic process uses water and releases the oxygen that we
absolutely must have to stay alive.
6H O + 6CO ----------> C H O + 6O
2 2 6 12 6 2
Six molecules of water plus six molecules of carbon dioxide produce one molecule of sugar
plus six molecules of oxygen
Energy Plantation
It is a means of extracting maximum solar energy by growing plants. The plants are grown,
especially for their fuel value and acts as solar collectors. They are economical, free from
pollution and require no maintenance. Energy fauns are the best alternatives for present fuel
crisis and to replace fossil and nuclear energy sources. In plant farm, the natural photosynthesis
process stores ten times more energy annually than consumed by the world. In India, the total
forest area is around 25%. Jojaba, Acacia, Tortilla, Albizzia, Lebbak, Prasois. Juliflora are
some of the tree species which have been identified for energy farm in our country. Indian
Institute of Science, Bangalore running a program to grow monoculture plantations of fast
growing species and monitor the biomass productivity. They also studied the economics of
monoculture plantations and developed an alternative forestry strategy to meet various village
needs.
Energy farm is a locally available energy source with highest versatility among renewable
energies. No other energy source can open such new opportunities for agricultural and forest
development. A number of projects have been taken up to full fill the needs of fuel and power
generation. A number of projects, worth about 5MW capacity, have been taken under DNES
(Development of Non conventional Energy Sources) at various places in the country. Gasifiers
and sterling engines are used for generation of energy from various types of biomass.
Biogas generation
The decomposition of animal, plant and human wastes generates biogas and is a mixture of
methane (50 to 70%), carbon dioxide (30 to 40%), hydrogen, hydrogen sulphide and nitrogen.
The biogas is a clean, slow burning gas with its calorific value ranging from 21000kJ/kg to
23028 kJ/kg (38 l 31 kJ/m3 ).Biogas is mainly used for cooking applications. The materials
used for biogas generation retains its fertilizer properties and return to the soil.
The biogas is generated from cow dug , piggery waste, poultry droppings, algae, crop residues,
garbage kitchen wastes etc. The cellulosic organic material of animal or plant origin forms raw
material with high potential for biogas generation.
There are three methods by which biogas could be generated. They are digestion, pyrolysis or
hydro gasification.
Digestion is a biological process which occurs in a chamber called digester .The process occurs
in the presence of anaerobic organisms at atmospheric pressure and temperatures of 35 – 70 C
and in the absence of oxygen.
Anaerobic digestion
It is the method of generating biogas through fermentation or bio digestion of different types
of wastes by a number of anaerobic and facultative organisms. Facultative organisms are
bacteria which grow with or without oxygen. Bacteria are classified in to two groups, aerobic
- which grow in presence of oxygen and anaerobic-does not require oxygen to grow. The
biodegradation or decomposition of the organic matter by fermentation process through
anaerobic digestion, results in the formation of biome.
The anaerobic digestion produces sugar. Alcohols, pesticides and amino acids by breaking
organic matter. This results in the formation of methane by another type of bacteria.
The phases of anaerobic digestion are:
1) Enzymatic hydrolysis: In this phase, the fats, starches and proteins present in the cellulose
cellulose biomass are converted in to simple compounds.
2) Acid formation: In this phase, the complex organic compounds converted in to simple
organic acids. The acids and volatile solids are formed by hydrolysis and fermentation from
micro organism of facultative and anaerobic group and together called acid formers. This stage
may last about two weeks and this phase results in the formation of large amount of carbon
dioxide.
3) Methane formation: In this phase, the acids produced from previous phase converted in to
methane (CH4) and CO2 by anaerobic bacteria which are also known as methane fomenters.
For digestion process to be efficient, these acid formers and methane fomenters must be in a
state of dynamic equilibrium. The variation in pH value, will affect the methane formers as
they are sensitive to pH variations. For fermentation and biogas generation, a pH value of 6.5
to 8 is suitable
The anaerobic digestion is represented by the general equation
It is also to be noted that, the digestion at high temperature is faster than that at lower
temperature. For every 5°C raise in temperature, the gas yield rate increases twice. The
temperature ranges that influence the bacteria are
- Psicrophilic, about 20 C
-Mesophilic, about 35 C
- Thermophilic, about 55°C
In tropical countries, the digesters are operating in psichrophilic range. The digesters are heated
in cold climates by using a part of biogas output and temperature ranges up to 35°C. Some
digesters work at 55°C, to digest material.
Advantages of Anaerobic digestion
1) The anaerobic digestion produces biogas which has a calorific value. Hence this gas could
be successfully used to produce steam or hot water.
2) A smaller quantity of excess sludge is produced during anaerobic digestion of organic
matter.
3) The running cost is very less when compared to equivalent aerobic system
4) The odor is less
5) The use of biogas in industries reduces the consumption of coal and also reduces air
pollution.
Biomass Resources
•Animal dung
• Poultry wastes
• Plant wastes ( Husk, grass, weeds etc.)
•Human excreta •Industrial wastes(Saw dust, wastes from food processing industries)
•Domestic wastes (Vegetable peels, waste food materials)
•Dedicated Energy Crops (switch grass, miscanthus, bamboo, sweet sorghum, tall fescue,
kochia, wheatgrass etc)
•Agricultural Crop Residue (Examples include corn stover (stalks, leaves, husks, and cobs),
wheat straw, oat straw, barley straw, sorghum stubble, and rice straw.)
• Forestry Residues
•Algae
Biomass conversion Technologies
A wide variety of conversion technologies is available for manufacturing premium fuels from
biomass. Biomass conversion or simply bioconversion can take many forms
• Gasification takes place by heating the biomass with limited oxygen to produce low
heating value gas or by reacting it with steam and oxygen at high pressure and
temperature to produce medium heating value gas.
• The latter may be used as fuel directly or used in liquefaction by converting it into
methanol alcohol or ethanol or it may be converted to high heating value gas
Biochemical conversion
• Biochemical conversion takes two forms .anaerobic digestion and fermentation.
• Anaerobic digestion involves the microbial digestion of biomass(an anaerobe is a
micro organism that can live and grow without air or oxygen, it gets its oxygen by
the decomposition of matter containing it).
• The process takes place at low temperature upto 65 C and requires a moisture
content of atleast 80 percent .
• It generates a gas containing mostly of CO2 and methane (CH4) with minimum
impurities such as hygrogen sulphide
• The gas can be burned directly or upgrades to synthetic natural gas by removing
CO2 and the impurities.
• The residue may consists pf protein rich sludge that can be used as animal feed and
liquid effluents that are biologically treated by standard techniques and returned to
soil
Fermentation
• It is the breakdown of complex molecules in organic compound under the influence
of ferment such as yeast, bacteria, enzymes etc
• Fermentation is a well established and widely used technology for the conversion
of grains and sugar crops into ethanol
• It is intended for mixing with gasoline to produce gasohol(90% gasoline, 10%
ethanol)
• This process requires high cost and high energy required
Different variations in the drum type: Floating design is either provided with water seal or
without water seal. The plant works as anaerobic digester with water seal and this design
reduces corrosion of the gas holder drum. The materials of gas holder and digester are also
varied. Usually bricks and stones are used. In latest designs of gas holder, fibre glass reinforced
plastic is used.
Construction
The biogas plant is a brick and cement structure having the following five sections:
Mixing tank present above the ground level.
Inlet chamber: The mixing tank opens underground into a sloping inlet chamber
Digester: The inlet chamber opens from below into the digester which is a huge tank with
a dome like ceiling. The ceiling of the digester has an outlet with a valve for the supply of
biogas
Outlet chamber: The digester opens from below into an outlet chamber.
Overflow tank: The outlet chamber opens from the top into a small over flow tank
Working
The various forms of biomass are mixed with an equal quantity of water in the mixing tank.
This forms the slurry.
The slurry is fed into the digester through the inlet chamber
When the digester is partially filled with the slurry, the introduction of slurry is stopped
and the plant is left unused for about two months.
During these two months, anaerobic bacteria present in the slurry decomposes or ferments
the biomass in the presence of water
As a result of anaerobic decomposition, biogas is formed, which starts collecting in the
dome of the digester.
As more and more biogas starts collecting, the pressure exerted by the biogas forces the
spent slurry into the outlet chamber.
From the outlet chamber, the spent slurry overflows into the overflow tank.
The spent slurry is manually removed from the overflow tank and used as manure for plants.
The gas valve connected to a system of pipelines is opened when a supply of biogas is
required
Advantages:
This is a plant where no steel is used, there is no moving part in it and maintenance cost is
[Link] plant can be constructed by village mason taking some pre-explained precautions
and using all the indigenously available building [Link] quality of bricks and
cement should be used to avoid the afterward structural problems like cracking of the
dome and leakage of gas. This model have a higher capacity when compared with KVIC
model, hence it can be used as a community biogas [Link] design has longer life than
KVIC models.
Substrates other than cattle dung such as municipal waste and plant residues can also be
used in janata type [Link] plant consists of an underground well sort of digester made
of bricks and cement having a dome shaped roof which remains below the ground level is
shown in [Link] almost middle of the digester, there are two rectangular openings facing
each other and coming up to a little above the ground level, act as an inlet and outlet of the
[Link] shaped roof is fitted with a pipe at its top which is the gas outlet of the [Link]
principle of gas production is same as that of KVIC model. The biogas is collected in the
restricted space of the fixed dome, hence the pressure of gas is much higher, which is
around 90 cm of water column.
2. Floating gas holder type of biogas plant(KVIC)
The raw materials used and the principle involved are common to both the types of biogas
plants.
Construction
Mixing Tank - present above the ground level.
Digester tank - Deep underground well-like structure. It is divided into two chambers by
a partition wall in between
It has two long cement pipes:
1. Inlet pipe opening into the inlet chamber for introduction of slurry.
2. Outlet pipe opening into the overflow tank for removal of spent slurry
Gas holder - an inverted steel drum restingabove the digester. The drum can move up and
down i.e., float over the digester. The gas holder has an outlet at the top which could be
connected to gas stoves.
Over flow tank - Present above the ground level.
Working
Slurry (mixture of equal quantities of biomass and water) is prepared in the mixing tank
The prepared slurry is fed into the inlet chamber of the digester through the inlet [Link]
plant is left unused for about two months and introduction of more slurry is stopped. During
this period, anaerobic fermentation of biomass takes place in the presence of water and
produces biogas in the digester. Biogas being lighter rises up and starts collecting in the gas
holder. The gas holder now starts moving up.
The gas holder cannot rise up beyond a certain level. As more and more gas starts
collecting, more pressure begins to be exerted on the [Link] spent slurry is now forced
into the outlet chamber from the top of the inlet [Link] the outlet chamber gets
filled with the spent slurry, the excess is forced out through the outlet pipe into the overflow
tank. This is later used as manure for [Link] gas valve of the gas outlet is opened to get
a supply of [Link] the production of biogas begins, a continuous supply of gas can be
ensured by regular removal of spent slurry
Advantages
Floating-drum plants are easy to understand and operate.
They provide gas at a constant pressure, and the stored gas-volume is immediately
recognizable by the position of the drum.
Gas-tightness is no problem, provided the gasholder is de-rusted and painted
regularly.
Disadvantages
3. Due to lack of knowledge about Biogas generation, some persons add urea fertilizer which
results in toxicity of ammonia nitrogen and decreases gas production.
4. When cattle dung and water is not properly mixed, volatile fatty acids will be accumulated
and results in failure of digester
5. .It is necessary to maintain an optimum range of PH and volatile fatty acids, otherwise
digester will not work properly.
6. There is chance of leakage of gas from gas holder in case of Janata Model
Disadvantages
1. The plant uses larger land area.
2. The efficiency of biological energy conversion is very less (0.1%).
3. In centralized power generation system, the cost of energy production is higher.
4. Collection and transportation of biomass is expensive.
5. When compared to LPG cylinders, it is difficult to store the gas, as it cannot be liquified
ordinarily
Comparison between floating drum plant and fixed dome type plant
12. Pressure: The fermentation process is also influenced by the pressure acting on the slurry
surface. Lower pressure gives better fermentation process.
13. Acid accumulation inside the digester: When fresh raw material is supplied in excess,
the PH value decreases due to the formation of acids. The addition of neem cake produces
methane from these acids.
Thermo chemical conversion of biomass: In bio chemical energy conversion, the action of
bacteria results in the formation of biogas. In thereto chemical conversion of biomass, its
temperature is raised and processes like pyrolysis, combustion and gasification occurs
depending on amount of oxygen supplied. The example for combustion is burning of biomass
in open fire and stoves. In this case, oxygen is supplied in excess of theoretically required.
When less 02 is supplied, pyrolysis and gasification occurs. The conversion of wood and
incineration of solid waste is an example of pyrolysis. A gas mixture consisting of carbon
monoxide and hydrogen [producer gas] is generated at some temperature and O2 supply. The
formation of gaseous mixture of carbon monoxide and hydrogen is called thermal gasification
The conversion of solid fuel in to producer gas by undergoing a series of thermo chemical
processes like drying, pyrolysis, oxidation and reduction is known as thermal gasification.
Carbon monoxide, hydrogen and oxygen are the main constituents when air is used as
gasification agent. A typical gas composition is as follows,
The dual fuel engines and diesel engines uses this gas as working fluid with some design
changes.
Classification of Biomass gasifiers :
A chamber through which oxygen or air required for combustion is passed, known as gasifier.
The gasifier converts solid fuel into producer gas by undergoing a series of thermo chemical
processes.
Gasifiers are classified into
1. According to direction of gas flow: down draught, up draught and cross draught generator.
2. According to generation capacity: small size up to 10 kW, medium size for outputs from
10kW to 50kW, large size from 50 to 300 kW and very large above 300 kW output.
3. According to type of bed: fixed bed and fluidized bed.
1. Fixed bed gasifiers
They are three main designs of fixed bed type:
i) Up draught type: In this type, air entry is below combustion zone and producer gas
escapes from top of gasifier. It is suitable for char-coal, in stationary engines.
ii) Down draught gasifier: In this type, air entry is at combustion zone and gas escapes
through bottom of gasifer. These are suitable for wood and agricultural wastes.
iii) Cross draught. gasifiers: The gasifier contains charcoal which acts as insulator and
dust filter. The gas flows around the gasifier in the annular space.
The major advantages of fluidized bed gasifiers, stem from their feedstock flexibility resulting
from easy control of temperature, which can be kept below the melting or fusion point of the
ash (rice husks), and their ability to deal with fluffy and fine grained materials (sawdust etc.)
without the need of pre-processing. Problems with feeding, instability of the bed and fly-ash
sintering in the gas channels can occur with some biomass fuels.
Other drawbacks of the fluidized bed gasifier lie in the rather high tar content of the product
gas (up to 500 mg/m³ gas), the incomplete carbon burn-out, and poor response to load changes.
Particularly because of the control equipment needed to cater for the latter difficulty, very small
fluidized bed gasifiers are not foreseen and the application range must be tentatively set at
above 500 kW (shaft power)
Up draught type
The oldest and simplest type of gasifier is the counter current or updraught gasifier shown
schematically in Fig The air intake is at the bottom and the gas leaves at the top. Near the grate
at the bottom the combustion reactions occur, which are followed by reduction reactions
somewhat higher up in the gasifier. In the upper part of the gasifier, heating and pyrolysis of
the feedstock occur as a result of heat transfer by forced convection and radiation from the
lower zones. The tars and volatiles produced during this process will be carried in the gas
stream. Ashes are removed from the bottom of the gasifier.
The major advantages of this type of gasifier are its simplicity, high charcoal burn-out and
internal heat exchange leading to low gas exit temperatures and high equipment efficiency, as
well as the possibility of operation with many types of feedstock (sawdust, cereal hulls, etc.) .
Major drawbacks result from the possibility of "channelling" in the equipment, which can lead
to oxygen break-through and dangerous, explosive situations and the necessity to install
automatic moving grates, as well as from the problems associated with disposal of the tar-
containing condensates that result from the gas cleaning operations. The latter is of minor
importance if the gas is used for direct heat applications, in which case the tars are simply
burnt.
A solution to the problem of tar entrainment in the gas stream has been found by designing co-
current or downdraught gasifiers, in which primary gasification air is introduced at or above
the oxidation zone in the gasifier. The producer gas is removed at the bottom of the apparatus,
so that fuel and gas move in the same direction, as schematically shown in Fig.
On their way down the acid and tarry distillation products from the fuel must pass through a
glowing bed of charcoal and therefore are converted into permanent gases hydrogen, carbon
dioxide, carbon monoxide and methane
Depending on the temperature of the hot zone and the residence time of the tarry vapours, a
more or less complete breakdown of the tars is achieved. The main advantage of downdraught
gasifiers lies in the possibility of producing a tar-free gas suitable for engine applications.
In practice, however, a tar-free gas is seldom if ever achieved over the whole operating range
of the equipment: tar-free operating turn-down ratios of a factor 3 are considered standard; a
factor 5-6 is considered excellent.
Because of the lower level of organic components in the condensate, downdraught gasifiers
suffer less from environmental objections than updraught gasifiers.
A major drawback of downdraught equipment lies in its inability to operate on a number of
unprocessed fuels. In particular, fluffy, low density materials give rise to flow problems and
excessive pressure drop, and the solid fuel must be pelletized or briquetted before use.
Downdraught gasifiers also suffer from the problems associated with high ash content fuels
(slagging) to a larger extent than updraught gasifiers.
Minor drawbacks of the downdraught system, as compared to updraught, are somewhat lower
efficiency resulting from the lack of internal heat exchange as well as the lower heating value
of the gas. Besides this, the necessity to maintain uniform high temperatures over a given cross-
sectional area makes impractical the use of downdraught gasifiers in a power range above about
350 kW (shaft power)
Advantages and disadvantages of Biomass
Advantages
1. The initial investment is low and costlier equipments are not used.
2. The use of Biomass as fuel reduces environmental hazards.
3. The technology is best suited for rural areas of developing countries like India.
4. The byproducts can be fully recycled.
5. Less polluting, suitable for domestic purposes.
6. Easy transportable to consumers
Disadvantages
1. The plant uses larger land area.
2. The efficiency of biological energy conversion is very less (0.1%).
3. In centralized power generation system, the cost of energy production is higher.
4. Collection and transportation of biomass is expensive.
5. When compared to LPG cylinders, it is difficult to store the gas, as it cannot be liquified
ordinarily