COLIGATIVE PROPERTIES

Which is not a colligative property??

35.
(1)Osmotic pressure
2 Relative lowering in vapour pressure
(3) Depression in freezing point
(4} Refractive index
LS0036
26. The lowering of vapour pressure of a solvent by
addition of anon-volatile solute to it, is directly
proportional to :
(1 Mole fraction of solute
(2) The nature of the solute in the solution
(3) The atmospheric pressure
(4) All
LSO037
37. The relative lowering of vapour pressure is equal
to the mole fraction of the nonolatile solute.
This statement was given by :
lRaoult (2) Henry (3) Joule (4) Dalton
LSO038
38. The vapour pressure of a solution having solid as
solute and liquid as solvent is :
H Directly proportional to mole fraction of the
solvent
(2) Inversely proportional to mole fraction of the
solvent
(3) Directly proportional to mole fraction of the
solute
(4) Inversely proportional to mole fraction of the
solute
LSO040
 Pre-Medical
39. If P, and P. are the vapour
pressure of solveint
and its solution respectively. N, and N, are the
mole fraction of solvent and solute respectively
then

(1) P, =o
N,
(2)P,-P, = P,N,
(3) P, = P,N,
(4) P -P.) N,
P (N, +N,)
LS0041
40. One mole of non volatile solute is dissolved in
two mole of water.. The vapour pressure of the
solution relative to that of water is
3
(W
3 3 3); (4) 2
LS0042
41. The vapour pressure of a dilute aqueous solution
of GlucOse is 750 mm Hg at 373 K. The mole
fraction of solute is :
1 1 1
(1) (3)
10 35
LS0043

42. The vapOur pressure of water at rOom

temperature is 23.8 mm of Hg. The vapour
pressure of an aqueous solution of sucrose with
mole fraction 0.1 is equal to:
(1) 23.9 mm Hg (2) 24.2 mm Hg
13) 21.42 mm Hg (4) 31.44 mm Hg
LS0044

43. ThevapOur pressure of pure A is 10 torr. At the

same temperature, when 3g of Bis dissolved in
20 gm of A, its vapour pressure is reduced to
9.0 torr. If the molecular mass of A is 200 amu,
then the molecular mass of B is :
(1)200 amu 2270amu
(3) 310 amu (4)220 amu
LS0268
44. The boling point of CH, CH,OH, CH,NH,
and C,H,NO, are 80°C, 65°C, 184°Cand 212°C
respectively. Which will show highest vapour
pressure at room temperature :
(1) CH, 2} CH,OH
(3) CH,NH, (4) C,H,NO,
LS0046
ALLEN

Li

44 TI

54.

4
LSM57
4
55.

3 4-L

LSHHt
58.

315nu
 ALLEN freezes at 0186 C
of 52. An aqueOus solution
Pre-Medical
obeyed, the
vapour pressure (K, = 1.86 Kkg mol: K, = 0.512 Kkg mol ')
45. If Raoult's law is proportional
What is the elevation in boiling point ?
in a solution is directly
the solvent (2) 0.512
(1) 0. 186
of the solvent 0.512
M)Mole fraction (3) 4LO0512
of the solute 1.86
(2) Mole fraction solute
the solvent and LSO054
(3) Mole fraction of solution
(4) The olume of
the
LS0047 53. In the depressionof freezing point experiment. it
is found that :
pressureof a pure liquid
A' is 70 torr (1) The vapour pressureof solution is more than
46. The vapour another
ideal solution with of pure H,0.
at 27'C. It forms an total
fraction of Bis 0.2 and (2) The vapour pressure ot solution is less than
liquid B. The mole torr at
vapour pressure of
the solution is 84 that of pure solute
pure liquid B at (3) Only solute molecules solidify at of freezing
The vapour pressure of
27 C.
27'C is - point
(1)14 (2) 56 3 140 (4) 70 (4)Only solvent molecules solidify at freezing
LS0048 point
solution of a non LS0056
47. The boiling point of an aqueous
freezing 54. Molal depression constant of water is 1.86 KKa
volatile solute is 100.15 C. What is the
diluting mol.0.02 mole of urea dissolved in 100g of
point of an aqueous solution obtained by water willproduce a depression in freezing point
volume of
the above solution with an equal of :
water? The values of K, and K, for water are (1) 0.186 C 0.372C
0.512 and 1.86 K molality: (4) 3.72 C
(3) 1.86 C
(1)-0.544 C (2) -0.512°C LS0057
3)-0.272C (4) -1.86 C
LSO049
55. What would be the freezing point of aqueous
solution containing 18 g of CH,,0, in 1000 gof
18. The molal elevation constant is the ratio of the water? (K,= 1.86 K molality')
elevation in B.P. to: y-0.186°C (2) -0.372° C
(1) Molarity (3) -0.54°C (4) -0.72° C
(2)Molality LS0058
(3) Mole fraction of solute 56. A solution of 1.25 g of a non-electrolyte in 20 g
(4) Mole fraction of solvent of water fteezes at 271.94 K. If K, = 186K
LS0050 molality and [Link]. of water is 273.15 Kthen
Elevation in boiling point was 0.52 °C when 6 g the molar mass of solute is:
of a compound X was dissolved in 100 g of (1) 207.8g mol (2) 179.79 g mol
water. Molecular weight of X is : (Kb for water = (3) 209.6g mol 496:01l g mot'
LSO059
0.52 Kmol)
(1) 120 (3) 100 (4) 342 57. If a thin slice of sugar beet is placed in
LSO051 concentrated solution of NaCl then
0. An aqueous solution containing lg of urea boils ).Sugar beet will lose water from its cells
(2) Sugar beet will absorb water from solution
at 100.25 °C. The aqueous solution containing (3) Sugar beet willneither absorb nor lose water
3g of glucOse in the same volume will boil at - (4) Sugar beet will dissolve in solution
(1)100.75 C (2) 100.5 C LS0060
(3) 100 °C 4100.25 C 58. In osmosis phenomenon net fow of
LS0052 (1) Solvent molecules occurs from higher
1. Pure benzene freezes at 5.45 °C at a certain concentration to lower concentration
place but 0.374 m solution of 2) Solvent molecules OCCurs from lower
tetrachloroethane in benzene freezes at 3.55 °C. concentration to higher concentration
TheK, for benzene is (3) Solute molecules OCcurs from higher
t5.08 KKg mol (2) 508 K Kg mol' concentratioin to lower concentration
(4) Solute molecules OCcurs from lower
(3) 0.508 K Kg mol (4) 50.8C Kg mol
LSO053 concentration to higher concentration
LS0061

70
 At constant temmperature, the oSmotic
59.
a solution is pressure of 65. If density of 2 Pre-Medical
1) Directly proportional to molal sucrose solution is
the 1.4a mL at 25°C, find
(2) Inversely proportional to concentration (1) 4.06 atm
osmotic pressure.
the
(3) Directly proportional to concentration
(2) 2 atm
the square of (3) 40:7atm (4) 3.4 atm
concentration
(4) Directly proportional LS0069
to the square root of 66. If total concentration of dissolved
particles
concentration red blood cells is 0.3 M (approximate) inside
and the
membrane surrounding the cell
inorganic compOunds can LSO062
is
60. Which semipermeable. Find osmotic pressure inside the
act as cell
semipemeable membrane ?
(1)Calcium sulphate 1) 7.34 atm (2) 1.78 atm
(2) Barium oxalate (3) 2.34 atm (4)0.74 atm
(3) Nickel phosphate LSO070
(4) Copper ferrocyanide 67. Equal volume of 0.1 M urea and 0.1 M glucose
are mixed. The mixture will have:
61. If 0.1 M solution of LS0063 (1) Lower osmotic pressure
glucose and 0.1 M urea 21Same osmotic pressure
solution are placed on to sides (3) Higher osmotic pressure
semipermeable membrane to equal heights,ofthena (4) None of these
it will be correct to say that: LSO071
(UY There will be no net 68. Osmotic pressure of a solution (density is
movenment across the
membrane lg ml) containing 3 g of glucose (molecular
(2) Glucose will flow towards urea weight = 180) in 60g of water at 15°C is :
solution
(3) Urea will flow towards glucose solution (1) 0.34 atm (2) 0.65 atm
(4). Water will flow from urea solution towards 36:25 atm (4) 5.57 atm
glucose solution. LSO072
LS0064 69. Osmotic pressure of a sugar solution at 24°C is
2.5 atm. The concentration of the solution in
62. If mole fraction of the solvent in solution
mole per litre is
decreases then: (1) 10.25 (2) 1.025
(1)Vapour pressure of solution increases (3) 1025 JA)0-1025
(2) B. P. decreases LSO073
3Osmotic pressure increases 70. A solution containing 8.6 g urea in one litre was
(4) Allare correct found to be isotonic with 0.5% (wt./vol) solution
LSO066
of an organic non volatile solute. The molecular
63. The osmotic pressure of a solution increases if weight of organic solute is :
(1) Temperature is lowered (1)348.9 334.89 (3) 3489 (4) 861.2
(2) Volume is increased LSO075
3} Number of solute molecules is increased 71. If 6.84% (w/) solution of cane-sugar
(4) None (mol. wt. 342) is isotonic with 1.52% (w/V)
LS0067 solution of thiocarbamide, then the molecular
same weight of thiocarbamide is :
64. Which of the following solutions at the (1) 152 eT6
temperature will be isotonic : (3) 60
litre water and
(4) 180
(1) 3.42 gof cane sugar in one LSO076
0.18g of glucose in one litre water.
342 g of cane sugar in one litre
water and 72. Asolution containing 500g of a protein per litre
0.18g of gucose in 0.1litre water. is isotonic with a solution containing 3.42 g of
water and sucrose per litre. The molecular mass of protein
3.42 g of cane SUgar in one litre is
0.585g of NaCl in one litre water. (1) 5 (2) 146
(4) 3.4Z g of cane sugar in one litre water and (3) 34200 4)50000
1.17 g of NaCl in one litre water.
LSO068 LS0250
 ALLEN ChemistrY: Sdutions
Pre-Medical
are dissolved
iniection n water 81. The ratlo of the value of any collgative
(A)
73.
contaning
salts at particular (B) tor KCI solutlon to that for
sugar olut property
CONceNtrations that matches (C) neariy time
concentration. Here A, B and C refer to : (1) 1 (2) 0.5
(3)2 (4) 2.5
(1}ntraenous, ionic, blood plasma
(2) Intravenous, bkod plasma, ionic
82. The lowering of vapour pressure LSO086
(3) Biood plasma, intravenous, ionic of 0 IM
aqueous solutlons of NaCl, CuSO,
(4) Blood plasma, ionic, intrauenous
are
and KS0,
LS0077
(1) Allequal
ABNORMAL COLLIGATIVE PROPERTIES 2YIn the ratio of 1: 1:15
(3) In the ratio of 3: 2:1
74. Equimolal solutions of A and B show depression (4) In the ratio of 1.5 : 1:25
in freezing point in the ratio of 2: 1. If a remains
in nomal state in solution, B will be in LSO087
state in solution 83. The freezing point of 1molal NaCl solution
(1) Nomal (2) Associated assuming NaCl to be 100% dissociated in water
is:
(3) Hydrolysed (4) Dissociated
LS0079 (K, = 1.86 KMolality)
75. Vant Hoff factor is : (1) -1.86 C 21-3.72°C
(1) Less than one in case of dissociation (3) +1.86 C (4) + 3.72 C
(2) More than one in case of association LSO088
(3) Always less than one 84. The molal elevation constant of water is
(4) Léss than one in case of association 0.51
The boiling point of 0.1 molal aqueous NaCI
LS0080 solution is nearly:
76. The vant Hoff factor (i) for a dilute solution of (1) 100.05 C 2) 100.1C
KJFe(CN)J is: (3) 100.2° C (4) 101.0° C
(1)10 24 (3) 5 (4) 0.25 LSO089
LS0081 85. Phenol associates in benzerne as
77. The experimental molecular weight of an
electrolyte will always be less than its calculated CH,OH 2; (CH,OH),
value because the value of vant Hoff factor, 'T is :
If degree of association of phenol is 40%,
(1) Less than 1 2rGreater than 1 Van't Hoff factor i is :
(3) One (4) Zero
(1)1
LSO082 (3) 1.4
78. The vant Hoff factor () for a dilute (4) 0.6
aqueous LSO092
solution of Glucose is:
86. The values of observed and calculated molecular
(1) Zero1.0 (3) 1.5 (4) 2.0 weight of calcium nitrate are respectively 65.6
LS0083
79. Osmotic pressure of 0.585% w/y NaCl and 164. The degree of dissociation of calcium
solution nitrate will be:
at 27C is
(1) 2.49 atm (1) 25% (2) 50%
(2) 4.92 atm 375%
(3) 1.2 atm (4) 60%
488 atm LS0093
LSO084 87. A 0.004M solution of [Link], is isotonic with à
80 The substance A when dissolved
in solvent B
shows the molecular mass 0.010M solution of glucose at the 25
The vant Hoff's factor will becorresponding to A, temperature. The degree of dissociation of
(1) 1 (2) 2
Na,S,is
(3) 3 (1)25% (2) 50%
375% (4) 85%
LS0085 LS0094

72