26-11-2025

7101CJA101001250025 JM

PHYSICS

SECTION-I

1) A particle performing S.H.M. about mean position x = and at t = 0, it has displacement

and moving away from the origin. Then which of the following is its possible graph between position
(x) and time (t)

(A)

(B)

(C)

(D)

2) A mass M is suspended from a spring of negligible mass. The spring is pulled a little and then
released so that the mass executes SHM of time period T. If the mass is increased by m, the time

period becomes , then the ratio of is :-

(A)

(B)

(C)

(D)

3) Two light identical springs of spring constant k are attached horizontally at the two ends of a
uniform horizontal rod AB of length ℓ and mass m. The rod is pivoted at its centre 'O' and can rotate
freely in horizontal plane. The other ends of the two springs are fixed to rigid supports as shown in
figure. The rod is gently pushed through a small angle and released. The frequency of resulting

oscillation is:

(A)

(B)

(C)

(D)

4) If the distance x of a particle on a straight line measured from a fixed origin on it and its velocity v
are connected by the relation 4v2 = 25 – x2 (where v, x are in S.I. units), then the amplitude of
harmonic motion is

(A) 3m
(B) 4m
(C) 5m
(D) None of these

5) The x-t graph of a particle undergoing simple harmonic is shown below. The acceleration of the

particle at t = 4/3s is-

(A)

(B)

(C)

(D)

6) Two uniform rods AB and CD, each of length ℓ and mass m are fixed to two gears (Which are
disc's of radius 2r and r pivoted to fixed points A and C respectively at same horizontal level) as
shown in figure. The system is in vertical plane. When rod AB is slightly rotated clockwise by a small
angle, rod CD rotates in the opposite sense (anticlockwise) by another small angle such that there is
no slipping and no dissipation of energy at the point of contact of the gears due to their teeth in
contact. Neglecting the mass of gears, find the time period of small oscillations of the system. [g is

acceleration due to gravity] [Consider cos θ = 1 – ..... neglecting higher terms]

(A)

(B)

(C)

(D)

7) A solid sphere of mass M is attached to two massless springs each of spring constant k. It can roll
without slipping along a horizontal surface. If the system is released after a small stretch in left

spring, then the time period of oscillations will be :

(A)

(B)

(C)

(D)

8) If a spring has time period T, and is cut into n equal parts, then the time period of each part will
be -
 T
(A)

(B)

(C) nT
(D) T

9) A block of mass 1 kg kept over a smooth surface is given velocity 2 m/s towards an ideal spring of
spring constant 1 N/m at a distance of 10m. Find after what time block will be passing through P

again

(A)
(B) 10 sec
(C)
(D)

10) Two identical rods each of mass M length fixed together are suspended as shown in figure. The

time period of system when oscillating about point O is:

(A)

(B)

(C)

(D)

11) A particle is making simple harmonic motion along the X-axis. If at a distances x1 and x2 from the
mean position, the velocities of the particle are v1 and v2 respectively, then the time period of its
oscillation is given as :
(A)

(B)

(C)

(D)

12) A particle is subjected two simple harmonic motions as :

and
where x is displacement and t is time in seconds.
The maximum acceleration of the particle is
x × 10–2 ms–2. The value of x is :

(A) 175
(B)
(C)
(D)

13) For a particle under going linear SHM about x = 0, choose the correct possible combinations.
Symbols have their usual meanings :-

List–I List–II

(P) (1) Extreme position

(Q) Velocity is negative (2) Mean position.

(R) Acceleration is negative (3) 0 < x < A.

(S) (4) –A < x < 0

(5) None
(A) (P) - (1,3) ; (Q) - (2,4) ; (R) - (2,3) ; (S) - (1,2,3)
(B) (P) - (1,3) ; (Q) - (2,3) ; (R) - (1,2,4) ; (S) - (3,4)
(C) (P) - (3,4) ; (Q) - (2,3,4) ; (R) - (1,3) ; (S) - (1,2,3,4)
(D) (P) - (3,4) ; (Q) - (2,3,4) ; (R) - (2,3) ; (S) - (5)

14) In the shown arrangement, the coefficient of friction between the blocks is µ and no friction
between ground surface and block 2m. The blocks are displaced slightly and released. They move
together without slipping on each other. The time period will be :-

(A)

(B)

(C)

(D)

15) Two particles P and Q describe SHM of same amplitude a and frequency v along the same
straight line. The maximum distance between the two particles is The initial phase difference
between them is

(A) zero
(B)
(C)
(D)

16) A body is executing Simple Harmonic Motion. At a displacement x its potential energy is E1 and
at a displacement y its potential energy is E2. The potential energy E at displacement [x + y] is –

(A)
(B)
(C)
(D)

17) What is the period of small oscillations of the block of mass m if the springs are ideal and pulleys

are massless ?

(A)

(B)
(C)

(D)

18) Three masses 700g, 500g, and 400 g are suspended at the end of a spring as shown and are in
equilibrium. When the 700 g mass is removed, the system oscillates with a period of 3 seconds, when

the 500 g mass is also removed, it will oscillate with a period of :-

(A) 1 s
(B) 2 s
(C) 3 s

(D)

19) A block of mass M, at rest on a horizontal frictionless table, is attached to a rigid support by a
spring of constant K. A bullet of mass m with velocity v strikes the block as shown in figure. The
bullet remains embedded in the block. Then the amplitude of the resulting simple harmonic motion

is :-

(A)

(B)

(C)

(D)

20) A simple pendulum of length 1m is allowed to oscillate with amplitude 2°. It collides elastically

with a wall inclined at 1° to the vertical. Its time period will be : (use g = π2)

(A) 2/3 sec

(B) 4/3 sec
(C) 2 sec
(D) None of these

SECTION-II

1) A block of mass 5 kg is placed between two springs just touching them and not connected to any
of the springs. If the block is displaced slightly and released, then the time period of resulting

oscillation is (in sec). Fill the value of (q–p) in the OMR.

2) The amplitude of a particle executing SHM is 3 cm. The displacement at which its kinetic energy
will be 25% more than the potential energy is: ________ cm.

3) A uniform stick of length l is mounted so as to rotate about a horizontal axis perpendicular to the
stick and at a distance d from the centre of mass. The time period of small oscillations has a

minimum value when d/l is . Where n is an integer. Find n

4) If the time period of oscillation of block of mass m, is Find x. Spring, string and pulley

are ideal. Spring constant is k.

5) Figure shows two masses m1 = 2 kg and m2 = 3 kg connected by a spring of force constant k = 48

N/m and the system is placed on a smooth horizontal surface. If the blocks are compressed slightly
and released, then find the time period of small oscillations. (take )

CHEMISTRY

SECTION-I
1) IUPAC name of following compound is

(A) N-methyl-N-ethyl cyclobutanamide

(B) N-ethyl-N-methyl cyclobutanamide
(C) N-ethyl-N-methyl cyclobutane carboxamide
(D) N-methyl cyclobutyl propanamide

2) IUPAC Name of following compound is :-

(A) 5-Ethyl-3-methylcyclohexene
(B) 4-Ethyl-6-methylcyclohexene
(C) 3-Methyl-5-ethylcyclohexene
(D) 5-Ethyl-1-methylcyclohex-2-ene

3) The correct IUPAC name of is

(A) Methyl ethanoate

(B) Acetato ethanoate
(C) Ethanoic anhydride
(D) Ethanoyl ethanoate

4) is named as :

(A) 2, 3-Dimethylenebutanal
(B) 3-Methyl-2-methylidene but-3-enone
(C) 3-Methyl-2--methylidene but-3-enal
(D) 2, 3-Dimethylenebutanone

5) The correct IUPAC name of compound is.

(A) 2–Cyano–3–oxopentanal
(B) 2–Formyl–3–oxopentanenitrile
(C) 2–Cyano–1, 3–pentanedione
(D) 1, 3–Dioxo–2–cyanopentane
6) Which of following is the strongest base :

(A)

(B)

(C)

(D)

7) (I) (II)

(III)
Correct order of stability of is:

(A) III > I > II

(B) II > I > III
(C) I > II > III
(D) I > III > II

8) Which of the following will not tautomerise to enol:-

(A)

(B)

(C)
(D)

9)

Identify the strongest base from the given compounds :-

(A)

(B)

(C)

(D) All have same basic strength

10) Which of the following compounds are antiaromatic :-

(I) (II)

(III) (IV)

(V) (VI)

(A) (III) and (VI)

(B) (II) and (V)
(C) (I) and (V)
(D) (V) and (VI)

11) Bond length is defined as the internuclear distance between the two atoms. When bond order is
greater, then the bond length is lesser. When double bond character increase, then bond length
decreases and vice versa.
Correct order of the (C–N) bond lengths for the given compound is-
(A) a > b > c > d
(B) d > a > b > c
(C) c > b > a > d
(D) b > c > a > d

12) Consider the following reaction:

(A)

(B)

(C)

(D)

13)
These are three canonical structures of naphthalene. Examine them and find correct statement
among the following :

(A) All C – C bonds are of same length

(B) C1 – C2 bond is shorter than C2 – C3 bond.
(C) C1 – C2 bond is longer than C2 – C3 bond
(D) None

14) Which of the following has longest C – O bond :

(A)

(B)

(C)

(D)

15) The increasing order of boiling points of the following compounds is :

(A) II > III > I

(B) II > I > III
(C) III > I > II
(D) I > II > III

16) Identify the correct order of boiling point of the following compounds ?
(1) CH3CH2CH2CH2OH
(2) CH3CH2CH2CHO
(3) CH3CH2CH2COOH

(A) 1>2>3
(B) 3>1>2
(C) 1>3>2
(D) 3>2>1

17)
Which of the following has the most negative heat of hydrogenation ?

(A)

(B)

(C)

(D)

18) Statement-I : The potential energy barrier for rotation about C = C bond in 2-butene is much
higher than that in ethylene.
Because
Statement-II : Hyperconjugation effect decreases the double bond character.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation
(B)
for statement-1
(C) Statement-1 is true, statement-2 is false
(D) Statement-1 is false, statement-2 is true.

19) Which of the following carbocation is most stable:

(A)

(B)

(C)

(D)
20) Decreasing order of – Ι effect of the following:-

– NO2, , – CN, – COOH

(A) > – CN > – NO2 > – COOH

(B) > – NO2 > – CN > – COOH

(C) > – COOH > – CN > – NO2

(D) – NO > > – CN > –COOH

2

SECTION-II

1)

Total number of groups which can show –I effect when attached to benzene ring :
(a) –OH (b) –NH2

(c) (d) –Cl

(e) (f) –O–

(g) –CH3 (h)

(i) (j) –C≡N

(k)

2) Total number of structures which are most stable resonating structures among all their respective

resonating structures : (i) CH2=CH–CH=CH2 (ii)

(iii) (iv)

(v)

(vi) (vii)

(viii)

3) Calculate resonance energy (in kcal) of the CH2=CH–CH=CH2 if its heat of hydrogenation is 57
kcal while heat of hydrogenation of CH2=CH–CH2–CH3 is 30 kcal.

4) Number of acidic protons that are present in given molecule is ?

5) How many resonating structures of carbocation 'M' as shown below are possible (excluding given

resonating structure) :

MATHS

SECTION-I

1) Let + 10x + 3y + 1 = 0 represents a circle, then the

number of values of θ in [0,4π] is -

(A) 0
(B) 1
(C) 2
(D) 3

2) The locus of the mid point of the chord of circle x2 + y2 – 2x – 2y – 2 = 0 which subtends an angle
of 120° at the centre, is

(A) x2 + y2 – 2x – 2y + 1 = 0
(B) x2 + y2 + x + y + 1 = 0
(C) x2 + y2 – 2x – 2y – 1 = 0
(D) x2 + y2 = 1

3) Distance between the chord of contact with respect to point (0, 0) and (g, f) of circle
is

(A)

(B)

(C)
(D)

4) If a variable line, 3x + 4y – λ = 0 is such that the two circles x2 + y2 – 2x – 2y + 1 = 0 and x2 + y2 –

18x – 2y + 78 = 0 are on its opposite sides, then the set of all values of λ is the interval :-

(A) [12, 21]

(B) (2, 17)
(C) (23, 31)
(D) [13, 23]

5) If the circles and intersect in two distinct

points P and Q then the line passes through P and Q for (where a ∈ )

(A) Exactly one value of a

(B) No value of a
(C) Infinitely many values of a
(D) Exactly two values of a

6) If the line x cosθ + y sinθ = 2 is the equation of a transverse common tangent to the circles x2 + y2
= 4 and , then the value of θ is :-

(A)

(B)

(C)

(D)

7) The equation of the circle which passes through the intersection of circles x2 + y2 + 13x – 3y = 0
and 2x2 + 2y2 + 4x – 7y – 25 = 0 and whose centre lies on 13x + 30y = 0, is -

(A) x2 + y2 + 30x – 13y – 25 = 0

(B) 4x2 + 4y2 + 30x – 13y – 25 = 0
(C) 2x2 + 2y2 + 30x – 13y – 25 = 0
(D) x2 + y2 + 30x – 13y + 25 = 0

8)

A light ray gets reflected from the line x = – 2. If the reflected ray touches the circle x2 + y2 = 4 and
point of incident is (–2, –4), then equation of incident ray is

(A) 3x + 4y + 22 = 0
(B) 4x + 3y + 20 = 0
(C) x + 2y + 10 = 0
(D) x + y + 6 = 0

9) Two tangents are drawn from a point P to the circle x2 + y2 – 2x – 4y + 4 = 0, such that the angle

between these tangents is , where ∈ (0, p). If the centre of the circle is
denoted by C and these tangents touch the circle at points A and B, then the ratio of the areas of
ΔPAB and ΔCAB is :

(A) 11 : 4
(B) 9 : 4
(C) 3 :1
(D) 2 : 1

10) The set of all real values of l for which exactly two common tangents can be drawn to the circles
x2 + y2 – 4x – 4y + 6 = 0 and x2 + y2 – 10x – 10y + λ = 0 is the interval :

(A) (18, 48)

(B) (12, 24)
(C) (18, 42)
(D) (12, 32)

11) If the circle C1 : x2 + y2 = 16 intersects another circle C2 of radius 5 in such a manner that the
common chord is of maximum length and has a slope equal to 3/4, then the coordinates of the centre
of C2 can be

(A) (–9/5, –12/5)

(B) (9/5, 12/5)

(C)

(D) None of these

12) Length of the common chord of two circles with radii 3, 4 units which intersect orthogonally, is :-

(A) 24

(B)

(C)

(D) 12

13) The angle between the tangents drawn from the origin to the circle (x – 7)2 + (y + 1)2 = 25 is-

(A) π/3
(B) π/6
(C) π/2
(D) π/8
14) Consider a circle intersecting x-axis at (2, 0) and (8, 0), tangent to y-axis at (0,-4) with centre
below x-axis. The equation of common chord between this circle and the circle
x2 + y2 – 4x – 4y – 2 = 0.

(A) x – 2y + 3 = 0
(B) 2x + y – 3 = 0
(C) x – 2y = 3
(D) None of these

15) A line segment through a point P cuts a given circle in 2 points A & B, such that PA = 16 & PB =
9, find the length of tangent from points to the circle

(A) 7
(B) 25
(C) 12
(D) 8

16) The locus of the mid-points of the chords of the circle , which subtends a

right angle at is :

(A) ax + by = 0
(B)

(C)

(D)

17) Locus of midpoint of chords of the circle x2 + y2 = 25, which are tangents to the circle x2 + y2 –
20x – 20y + 175 = 0 will be:

(A) (10x + 10y + x2 + y2)2 = (x2 + y2)

(B) (10x + 10y – x2 + y2)2 = 100(x2 + y2)
(C) (10x + 10y + x2 – y2) = 25(x2 + y2)
(D) (10x + 10y – x2 – y2) = 25(x2 + y2)

18) If the circle x2 + y2 + 2x + 2ky + 6 = 0 and x2 + y2 + 2ky + k = 0 intersect orthogonally, then k

is

(A) 2 or – 3/2
(B) – 2 or – 3/2
(C) 2 or 3/2
(D) – 2 or 3/2

19) Let A be the centre of the circle x2 + y2 – 2x – 4y – 20 = 0, and B(1, 7) and D(4, –2) are points on
the circle then, if tangents be drawn at B and D, which meet at C, then area of quadrilateral ABCD
is:

(A) 150
(B) 75
(C) 75/2
(D) None

20) The equation of the circle passing through the point of intersection of the circle x2 + y2 = 11 and
the line 2x + y = 1 and having minimum possible radius is

(A) 5x2 + 5y2 + 18x + 6y – 5 = 0

(B) 5x2 + 5y2 + 9x + 8y – 15 = 0
(C) 5x2 + 5y2 + 4x + 9y – 5 = 0
(D) 5x2 + 5y2 – 4x – 2y – 18 = 0

SECTION-II

1) Let R is the radius of the circle passing through the origin and cutting orthogonally each of the

circles x2 + y2 – 8y + 12 = 0 and x2 + y2 – 4x – 6y – 3 = 0, then is equal to

2) A circle with center in the first quadrant is tangent to y = x + 10, y = x – 6, and the y-axis. Let (h,
k) be the center of the circle. If the value of (h + k) = a + where is a surd, find the value of
a + b.

3) The smallest radius of the circle which touches 3x + 4y – 5 = 0 and x2 + y2 + 2x + 6y + 6 = 0 is

___.

4) Length of common chord of two circles of radii 3 and 4 which intersect orthogonally is ℓ, then
is

5) Let AB be a chord of length 12 of the circle If tangents drawn to the

circle at point A and B intersect at the point P, then five times the distance of point P from chord AB
is equal to ___.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D C A C D B C B D C D A C A B B A B C B

SECTION-II

Q. 21 22 23 24 25
A. 7 2 12 4 18

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A C C B C C D A D C B B B A B A D D B

SECTION-II

Q. 46 47 48 49 50
A. 8 4 3 5 5

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A D A B D B A B C C B C C C D D A B D

SECTION-II

Q. 71 72 73 74 75
A. 3 10 1 5 72
 SOLUTIONS

PHYSICS

1) x = &x= at t = 0

⇒ sin ϕ =
⇒ –π < ϕ < 0 ...... (i)
& particle is moving away from origin

⇒ v=
at t=0 v>0
⇒ cosϕ < 0

⇒ or ........(2)
from (1) & (2)

2) ...(1)

...(2)
Dividing eq. (1) and (2), we have

∴ or
or 9M + 9m = 25 M

or 16 M = 9m or

3)
4)

4v2 = 25 – x2

Differentiating,

a=5

5)

6) mg cos θ – mg cos2θ +

= constant

= constant
 = constant

= constant

= constant

(angular SHM equation)

(angular frequency)2 =

T=

7) Use energy method

8) Time period of a mass loaded spring

So ...(i)
Spring constant (k) is inversely proportional to the length of the spring, i.e.

9)

10)

11) Velocity of particle performing simple harmonic motion,

12)

x1 =

x2 =
From phasor,

∴ Amplitude of resultant SHM = 7

ϕ=
∴ XR = 7 sin (5t + ϕ)
aR = –7 × 25 sin (5t + f)
∴ amax = 175 cm/sec = 175 × 10–2 m/sec

13) possible for all 'x' other than mean position & extreme position Velocity is
negative possible at all 'x' except extreme positions Acceleration is negative for 0 < x ≤ A
for all points.

14) Explanation: In this question two blocks connected with spray are placed one oves others,
both blocks moving without slipping it is asked to find time period of oscillation.
Concept: Time period of SHM
Solutoin:
Both springs are is
Parallel keq = k + 2k = 3k
Total mass = 2m+m = 3m

Final Answer: Time period of oscillation is option (1)

15)

16) Question Explanation: Finding the potential energy at a displacement (x + y) from the
given potential energies at displacements x and y.
Concept: Potential energy in SHM.
Solution: The potential energy of a particle in SHM is proportional to the square of its
displacement from the mean position. We can use this relationship to find the required
potential energy.

Final Answer: option (2)

17) Question Explanation: Finding the period of small oscillations for a block attached to
springs and pulleys.
Concept: Time period of a spring-mass system.
Calculation:

T=
Fnet = – (4k) (4x) = – 16kx
⇒ keq = 16K
Final Answer: option (1)
18) Question Explanation: Finding the new period of oscillation when mass is removed from
a spring-mass system.

Concept: Time period of a spring-mass system.

Solution:
Time period of a spring-mass system is given by

T=
When mass 700 g is removed, the left out mass (500 + 400)g oscillates with a period of 3 s

∴ 3 = 2π …(i)
When 500 g mass is also removed, the left out mass is 400g.

∴ t´ = 2π …(ii)

⇒
⇒ t´= 2s

Final Answer

The correct option is (2)

19)

20) Question Explanation: Finding the time period of a simple pendulum that collides with a
wall.
Concept: Time period of a simple pendulum.
Solution: The pendulum's motion is restricted by a wall. The time period is the time for a full
cycle, which consists of swings of different lengths.
Calculation:

Time period for half part :

So 2° part will be covered in a time t = = 1 sec.

0
For the left 1° part : θ = θ sin (ωt) ⇒ 1° = 2°

⇒ = π × t ⇒ t = 1/6 sec.

Total time = + 2t ⇒ 1 + 2 × sec.

21) T =
T= =

T=
Answer (q – p) = 7

22) KE = PE +

KE =

mω2 (A2 – x2) = mω2x2

A2 – x2 =

= A2

∴x=
x = 2cm

23) Use to minimize the time period

24)
When the block is displaced by the spring gets elongated by Since pulley is massless,
tension,
As block is in equilibrium,

If the whole set-up is replaced by a single spring-block, then the equivalent spring constant of
that spring will be

Time period,
 25)

CHEMISTRY

26) Question Explanation:

To write IUPAC name of the given compound.

Concept:
This question is based on Nomenclature of cyclic compounds.

Solution:

N-ethyl-N-methylcyclobutanecarboxamide.

Final Answer:
The correct option is (3)

27)

28)
Ethanoic anhydride

29)

30) Here the main functional group is – CN, which has nitrile suffix and CHO and CO are taken
as substituents.
2–Formyl–3–oxopentanenitrile

31) Question Explanation:

To compare base nature and select the strongest base.
Concept:
Comparison of base strength on the basis of different effects.
Solution:
Base strength ∝ e– donor tendency

l.p is localised so e– density is higher, makes it strongest base.

In (1), (2) and (4) l.p. of N is delocalised so less available for donation makes them less basic
than (3)
Final Answer:
The correct option is (3)

32)

I pull strength stabilises carbanions.

33) Bridgehead carbon has no planar geometry.

34)
Sp3 hybridised

Sp2 hybridised
EN ↑
B.S ↓

35)
36) In the compound

In (c) minimum double bond character due to (SIR)

In (b) Double bond character due to resonance
In (a) Pure double bond
In (d) Pure triple bond
Bond Length = c > b > a > d

37) 3°carbon free radical is most stable.

Therefore, X among the following is :

38) Explanation: Asking about the carbon-carbon bond length in naphthalene.

Concept: This question is based on bond length.
Solution: Naphthalene is an aromatic hydrocarbon.
It has 3-resonance structures.

Stability order is : a > b = c

In structure (a) both fused rings are benzenoid rings (Fries rule), so it is more stable than (b)
and (c).
According to the more stable structure C1 – C2 bond has more double bond character
compared to the C2 – C3 bond. Hence C1 – C2 bond is shorter than C2 – C3 bond.

Final Answer: The correct option is (2).

39) Question Explanation: Identifying the compound with the longest C−O bond.

Concept: Bond Length and Double Bond Character

Solution:
 Extended resonance (better resonance, more double bond converted into single, b.l.
↑)

40)
BP ∝ dipolemoment (m)

Alter
Increasing order of boiling point is :

Shows hydrogen bonding from –O–H group only

Shows strongest hydrogen bonding from both sides of –OH group as well as –NO2
group.

Shows stronger hydrogen bonding from one side –OH–group and another side of –

OCH3 group shows only dipole-dipole interaction.

⇒ Hence correct order of boiling point is:
II > III > I

41)

Strength of H–bonding order –COOH > –OH > –CHO

 Boiling point ∝ Strength of H–bonding
So boiling point order will be 3>1>2

42)

H.O.H.

43) Question Explanation: Evaluating statements about the rotational energy barrier in 2-
butene vs ethene.

Concept: This question is based on rotational barrier and π-Bond strength.

Solution:

Statement I: The rotational energy barrier about the C = C bond is high (due to the presence
of the π-bond). The barrier is similar in 2-butene and ethene (both are C = C bonds). The
statement says 2-butene is much higher, which is False.

Statement II: The Hyperconjugation effect decreases the double bond character. True.

α–H → 0 αH → 6
Always D.B. Decreases Double Bond
Character character due to Hyperconjugation

Final Answer: Option (4)

44)

45) Information based

46)

(a), (b), (c), (d), (e), (i), (j), (k)

 47) (i), (vi), (vii), (viii)

48)
=3

49)

50)

MATHS

51) Question Explanation: In this question, we have to find number of values of θ in [0, 4π].

Concept: This question is based on general equation of circle.

Solution: Circle be
For the circle, there must be
coefficient of x2 = coefficient of y2

and coefficient of xy = 0

n = 0,
n = 1,

n = 2,

To satisfy both conditions,

Number of values of θ = 2

Final answer: The correct option is (3).

52) ⇒ CP2 = 4cos260°

2
⇒ CP = 1
(h – 1)2 + (k – 1)2 = 1
⇒ x2 + y2 – 2x – 2y + 1 = 0

53) Solution: : x2 + y2 + 2gx + 2fy + c = 0

C.O. C of (0, 0)

x. 0 + y.0 + 2g + 2f +c=0
gx + fy + c = 0 ........ (1)

C.O.C. of (g, f)

x. g. + y. f + 2g + 2f +c=0
2 2
2gx + 2fy + g + f + c = 0 (1)

gx + fy + ....... (2)
Distance between parallel lines
(1) & (2)

=
Final Answer: Option (4)

54) Solution:
Centre of circles are opposite side of line
(3+4-λ) (27 + 4 - λ) < 0
(λ -7) (λ-31) < 0
λ (7, 31) .............(1)
distance from S1

.... (2)
distance from S2
 ..... (3)
From (1) ∩ (2) ∩ (3).
so λ ∈ [12, 21]

Final Answer: option (1).

55)
and must represent the same line

and
a is imaginary only
so no value of a

56)
C1C2 = r1 + r2

C1(0,0)
r1 = 2 r2 = 4
∵ Circle touches each other externally
∴ Equation of transverse common tangent is S1 – S2 = 0
where S1 ≡ x2 + y2 – 4 = 0

i.e. ...(1)
So, compare the equation (1) with
xcosθ + ysinθ = 2

57) Equation of circle passing through point of intersection of two given circles will be
(x2 + y2 + 2x –7y/2 – 25/2) + λ (x2 + y2 + 13x – 3y) =0

⇒ x2 (1 + λ) + y2(1 + λ) + x (2 + 13λ) – y – =0

centre =
∵ centre lies on 13x + 30y = 0

⇒ –13 + 30 =0
⇒ –26 – 169λ + 105 + 90λ = 0
=λ=1
∴ Required circle
2x2 + 2y2 + 15x – y– =0
2 2
⇒ 4x + 4y + 30x – 13y – 25 = 0.

58) Equation of any tangent of x2 + y2 – 4 = 0 is

y = mx ± 2
its passes through (–2, – 4)
(2m – 4)2 = 4 (1 + m2)
4m2 – 16m + 16 = 4 + 4m2

one tangent is vertical and slope of other tangent is 3/4

Hence equation of incident ray is y + 4 = (x + 2)

3x + 4y + 22 = 0

59)

∴ area of ΔPAB =

= =

area of ΔCAB =

60) C1 (2, 2) C2 (5, 5)

r1 = r2 =
|r1 – r2| < c1 c2 < r1 + r2

61) Let (h, k) be the coordinates of the centre of circle

C2. Then its equation is (x – h)2 + (y – k)2 = 52
The equation of C1 is x2 + y2 = 42 and so the equation of the common chord of C1 and C2 is
2hx + 2ky = h2 + k2 – 9 ..... (i)
Let p be the length of the perpendicular from the centre (0, 0) of C1 to (i). Then p =

But the length fo the common chord is 2

which will be of maximum length if p = 0
⇒ h2 + k2 – 9 = 0 ..... (ii)

The slope of (i) is (given)

∴ – = ⇒k=– ..... (iii)

Putting the value of k in (ii), we get

h=± ⇒k= [from (iii)]

Hence the centres of circle C2 are and

62)

l = 2rsinθ =

63) Let y = mx be a tangent drawn from the origin to the circle

(x – 7)2 + (y + 1)2 = 52. Then,

= ±5 ⇒ 12m2 + 7m – 12 = 0
Let m1 and m2 be the slopes of the two tangents. Then,

m1m2 = – = –1
Hence, then angle between two tangents is π/2
64)
(x – 5)2 + (y + 4)2 = 52
⇒ x2 + y2 – 10x + 8y + 16 = 0
x2 + y2 – 4x – 4y – 2 = 0
(common chord)
–6x + 12y + 18 = 0
x – 2y = 3

65) As we know
[Link] = PT2 = (Length of tangent)2

Length of tangent

66)

67)
Equation of chord of the circle x2 + y2 = 25, whose midpoint is P(h, k)
T = S1
xh + yk – 25 = h2 + k2 – 25
⇒ xh + yk – h2 – k2 = 0 ....(1)
This chord is tangent to the circle
x2 + y2 – 20x – 20y + 175 = 0
Length of perpendicular from centre = Radius

⇒ (10h + 10k – h2 – k2)2 = 25(h2 + k2)

(10x + 10y – x2 – y2) = 25(x2 + y2)

68) Since, the given circles intersect orthogonally.

2(1) (0) + 2(k) (k) = 6 + k
[∵ 2g1g2 + 2f1 f2 = c1 + c2]
⇒ 2k2 – k – 6 = 0

69) Here centre A(1, 2), and Tangent at (1, 7) is

x.1 + y.7 – 1(x + 1) – 2(y + 7) – 20 = 0
or y = 7 ...(1)
Tangent at D(4, –2) is 3x – 4y – 20 = 0 ...(2)
Solving (1) and (2), C is (16, 7)
Area ABCD = AB × BC

= 5 × 15 = 75 units.

70)

71) Let x2 + y2 + 2gx + 2ƒy = 0 is the circle

2g(0) + 2ƒ(–4) = 12 ⇒
2g(–2) + 2ƒ(–3) = –3 ⇒ g = 3
⇒ x2 + y2 + 6x – 3y = 0
72) Distance between line L1 & L2
[Since it touch y-axis; diameter is 2h = distance between parallel line]

⇒
[radius]
Also radius = ⊥r distance from centre of circle to tangent an it

radius ⇒ =
⇒
⇒

∴a=2
b=8
a + b = 10

73) (Reference to Allen Module)

74)

ℓ = 2(4sinθ)
75) (Reference to Allen Module)

Here, AM = BM = 6

In ΔPAO :

Therefore, 5 PM = 72.