CVD Tungsten
Tungsten
PSG W PSG
STI STI
P-well
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 111
CMP Tantalum Pentaoxide
Silicon Nitride Tungsten Gate
PSG W PSG
STI n+ n+ STI
P-well Ta2O5 Gate Dielectric
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 112
Metal and High-κ Gate MOSFET
Dummy Gate Process
• For < 0.1 µm IC device
• PSG CMP, polysilicon and oxide stripping,
and high-κ dielectric deposition.
• Ta2O5, κ ~ 25, TiO2 κ up to 80, and HfO2
• CVD plus RTA process
• It may never be used due to complexity
• Advantage: can used Ta2O5 hard hard to etch.
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 113
Metal and High-κ Gate MOSFET
Traditional Process
• Traditional MOSFET making process in R&D
– Dielectric deposition and annealing
– Metal deposition
– Photolithography
– Metal etch
– Ion implantation
– Rapid thermal annealing.
• Too early to predict which method will win
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 114
Interconnection
• Making transistor: front-end
• Interconnection: back-end
– Multi metal layers with dielectric in between
– Local interconnection: silicide
– PMD: doped oxide, PSG or BPSG
– W and Al alloy metallization
– IMD: USG and FSG
– Transition to copper and low-κ interconnection
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 115
Local Interconnection
• Connection between neighboring transistors
• Usually polysilicon or polycide stack
• WSi2, TiSi2, and CoSi2 are commonly used
– WSix: CVD process with WF6 and SiH4
• TiSi2: PVD Ti on Si then thermal anneal
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 116
Tungsten Silicide Process
• Wafer clean Tungsten silicide
(a) Amorphous silicon
• Grow gate oxide STI STI
P-well
• Deposited amorphous silicon
• Deposited tungsten silicide (a) Photoresist
Tungsten silicide
• Gate and local interconnection mask (b) Amorphous silicon
STI STI
• Etch tungsten silicide (fluorine chemistry) (b) P-well Gate oxide
• Etch amorphous silicon (chlorine chemistry)
Tungsten Silicide
• Strip photoresist Polysilicon
(c) STI STI
• Polysilicon and silicide annealing (c) P-well Gate oxide
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 117
Self-aligned Silicide (Salicide)
• TiSi2 and CoSi2
• Lower resistivity than WSi2
• TiSi2 when gate size > 0.2 µm
• CoSi2 when gate size < 0.2 µm
• Metal (Ti or Co) PVD
• Thermal anneal to form silicide
• Strip unreacted metal
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 118
Cobalt Self-aligned Silicide Process
Cobalt Deposition Sidewall Spacer
STI Silicon
Cobalt
RTP Silicide Alloying
Silicon
Strip Unreact Cobalt
Cobalt Silicide
Polysilicon
Silicon
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 119
Gate Oxide
Tungsten Local Interconnection
• Lower resistance, higher speed, less power
• Damascene: similar to W plug formation
– Etched trenches are in silicate glass layer
– Deposit Ti and TiN barrier/adhesion layers
– CVD W fill trenches
– CMP to remove bulk W from wafer surface
– W left in trenches to form local interconnection
Hong Xiao, Ph. D. [Link]/HongXiao/[Link] 120