27-12-2025

6001CJA10102225020GRIP JA

PHYSICS

SECTION-I

1) A transverse sinusoidal wave moves along a string in the positive x–direction at a speed of 10
cm/s. The wavelength of the wave is 0.5 m and its amplitude is 10 cm. At a particular time t, the
snap–shot of the wave is shown in figure. The velocity of point P when its displacement is 5 cm is :–

(A)

(B)

(C)

(D)

2) Speed of a transverse wave on a straight wire (mass 6.0 g, length 60 cm and area of cross-section
1.0 mm2) is 90 ms–1. If the Young's modulus of wire is 16 × 1011 Nm–2, the extension of wire over its
natural length is :

(A) 0.02 mm
(B) 0.04 mm
(C) 0.03 mm
(D) 0.01 mm

3) A uniform string of length 20m is suspended from a rigid support. A short wave pulse is
introduced at its lowest end. It starts moving up the string. The time taken to reach the support is :
(take g = 10 ms–2)

(A)
(B)
(C) 2s
(D)
4) In a string the speed of wave is 10 m/s and its frequency is 100 Hz . The value of the
phase difference between the points separated by 2.5 cm on the string will be :

(A) π/2
(B) π/8
(C) 3π/2
(D) 2π

5) A transverse wave is propagating along +x direction. At t = 2 sec, the particle at x = 4m is at y =

3 [Link] the passage of time its y coordinate increases and reaches to a maximum of 6 mm. The
wave equation may be (using ω and k with their usual meanings)

(A)

(B)

(C)

(D)

6) A sonometer wire, with a suspended mass of M = 1 kg., is in resonance with a given tuning fork.
The apparatus is taken to moon where the acceleration due to gravity is 1/6 that of earth. To obtain
resonance on the moon, the value of M should be

(A) 1 kg
(B) kg
(C) 6 kg
(D) 36 kg

7) A string is stretched between two fixed points separated by 75.0 cm. It is observed to have
resonant frequencies of 420 Hz and 315 Hz. There are no other resonant frequencies between these
two. The lowest resonant frequencies for this string is :-

(A) 105 Hz
(B) 155 Hz
(C) 205 Hz
(D) 10.5 Hz

8) When a wave travels in a medium, the particle displacement is given by the equation y = a sin
2π(bt – cx) where a, b and c are constants. The maximum particle velocity will be twice the wave
velocity if :-

c=
(A)

(B) c = πa
(C) b = ac
(D)
b=

9) A stretched wire of length 114 cm is divided into three segment whose frequencies are in the ratio
1: 3 : 4, the length of the segments must be in the ratio :

(A) 18 : 24 : 72
(B) 24 : 72 : 18
(C) 24 : 18 : 72
(D) 72 : 24 : 18

10) Following are expressions for four plane simple harmonic waves :

(a) y1 = Acos 2π

(b) y2 = Acos

(c) y3 = Acos 2π

(d) y4 = Acos 2π
The pairs of waves which will produce destructive interference and stationary waves respectively in
a medium, are :

(A) (c, d), (a, b)

(B) (a, d), (b, c)
(C) (a, c), (b, d)
(D) (a, b), (c, d)

11) Dependence of disturbances due to two waves on time is shown in the figure. The ratio of their

intensities I1 / I2 will be-

(A) 1 : 1
(B) 1 : 2
(C) 4 : 1
(D) 16 : 1

12) The path difference between the two waves

y1 = a1 sin (ωt – kx)
and y2 = a2 cos (ωt – kx + ϕ), is :

(A)
(B)
λ

(C)

(D)

13) Velocity of sound waves in air is 330 m/sec. For a particular sound in air, a path difference of 40
cm is equivalent to a phase difference of 1.6π. The frequency of this wave is :-

(A) 165 Hz
(B) 150 Hz
(C) 660 Hz
(D) 330 Hz

14) The transverse displacement y(x, t) of a wave on a string is given by

This represents a :-

(A) standing wave of frequency

(B)
standing wave of frequency

(C)
wave moving in +x direction with speed
wave moving in –x direction with speed
(D)

15) Find the number of possible natural oscillations of air column in a pipe closed at one end of
length 85 cm whose frequencies lie below 1250 Hz. (velocity of sound = 340 ms–1)

(A) 4
(B) 5
(C) 7
(D) 6

16) A sound wave of wavelength 40 cm enters the tube from one end. What must be the smallest
radius r such that minimum sound will be heard at the detector for the given figure :-

(A) 35 cm
(B) 17.5 cm
(C) 52.5 cm
(D) 70.5 cm
17) Air column of 20 cm length in a resonance tube resonates with a certain tunning fork when
sounded at its upper open end. The lower end of the tube is closed and adjustable by changing the
quantity of mercury filled inside the tube. The temperature of the air is 27°C. What should be the
change in length of the air column required, if the temperature falls to 7°C and the same tuning fork
is again sounded at the upper open end :-

(A) 1 mm
(B) 5 mm
(C) 7 mm
(D) 13 mm

18) It is found that an increase in pressure of 100 kPa causes a certain volume of water to decrease
by 5 × 10–3 percent of its original volume. Then the speed of sound in the water is about (density of
water 103 kg/m3)

(A) 330 m/s

(B) 1414 m/s
(C) 1732 m/s
(D) 2500 m/s

19) Two loudspeakers are emitting sound waves of wavelength with an initial phase difference of
/2 . At what minimum distance from O on line AB will one hear a maxima?

(A) 25 λ

(B)

(C)

(D) 50 λ

20) For a certain organ pipe three successive resonable frequencies are observed at 425, 595 and
765 Hz respectively. Taking the speed of sound in air to be 340 m/sec
(i) whether the pipe is closed end or open end
(ii) determine the length of pipe.

(A) closed end, 1 m

(B) open end, 1 m
(C) closed end, 2m
(D) open end, 2 m

SECTION-II

1) An open pipe 40 cm long, and a closed pipe 31 cm long, both are having same diameter. Both are
in unison in their first overtone. Determine end correction of closed pipe in cm.

2) A one metre long (both ends open) organ pipe is kept in a gas that has double the density of air at
STP. Assuming the speed of sound in air at STP is 300 m/s, the frequency difference between the
fundamental and second harmonic of this pipe is ________ Hz.

3) Three waves of equal frequency having amplitudes 10 µm, 4 µm and 7 µm arrive at a given point
with a successive phase difference of π/2. The amplitude of the resulting wave in µm is :

4) Sinusoidal waves 5.00 cm in amplitude are to be transmitted along a string having a linear mass
density equal to 4.00 × 10–2 kg/m. If the source can deliver a maximum power of 90 W and the string
2
is under a tension of 100 N, then the highest frequency at which the source can operate is (take π =
10) :

5) A stretched uniform wire of a sonometer between two fixed knife edges, when vibrates in its
second harmonic gives 1 beat per second with a vibrating tuning fork of frequency 200 Hz. Find the
percentage change in the tension of the wire to be in unison with the tuning fork.

CHEMISTRY

SECTION-I

1) The below species has how many hyperconjugating structure (involving C–H bond)

(A) 12
(B) 8
(C) 5
(D) 3

2) In which of the following more basic compound :-

(A)

(B)

(C)

(D)

3) Amongst the amines C6H5NH2 (I), CH3NH2 (II), (CH3)2NH (III) and (CH3)3N (IV) the order of
basicity (in aqueous medium) is–

(A) I < IV < II < III

(B) IV < III < II < I
(C) I < II < III < IV
(D) II < III < IV < I

4) Which resonating structure is least stable

(A)

(B)

(C)
(D)

5) Amongst the amines C6H5NH2 (I), CH3NH2 (II), (CH3)2NH (III) and (CH3)3N (IV) the order of
basicity (in aqueous medium) is–

(A) I < IV < II < III

(B) IV < III < II < I
(C) I < II < III < IV
(D) II < III < IV < I

6) Which of the following carbocation does not undergo rearrangement :

(A)

(B)

(C)

(D)

7) In which of the following more acidic compounds:-

(A)

(B)
(C)

(D)

8) Most stable carbanion is :-

(A)

(B)

(C)

(D)

9) Which of the following is most stable carbocation?

(A)

(B)

(C)

(D)

10) The least acidic compound, among the following is:

(A) D
(B) A
(C) B
(D) C

11) Which of the following is false order of – I effect ?

(A) –F > –Cl > –Br > –I

(B)

(C) –F > –OH > –NH2

(D)
> –C ≡ CH > –H

12)
The product (A) will be :

(A)

(B)

(C)
(D)

13) Which one of the following compounds possesses the most acidic hydrogen ?

(A)

(B) H3C–C C–H

(C)

(D)

14) The product of the following reaction is :–

CH3
|

CH3 – C–CH=CH2
|
CH3

CH3
|
(A) CH3 – C – CH – CH3
| |
CH3 OH
CH3
|
(B) CH3 – C – CH2 – CH2OH
|
CH3
CH3 – C –– CH – CH3
(C) | |
CH3 CH3
CH3
|
(D) HO – CH2 – C – CH2 – CH3
|
CH3
15)
Compound X is :-

(A)
(B)
(C)

(D)

16) CH3 — C C — CH3 X

X is :-

(A) Cis-2-butene
(B) Trans-2-butene
(C) Butane
(D) 2-butyne

17)
'X' is :-

(A) Aromatic
(B) Anti-Aromatic
(C) Non-Aromatic
(D) Non-Cyclic compound

18) In the given compounds

(A)

(B)

(C)
The order of rate of reaction is :-

(A) rA > rB > rC

(B) rA > rC > rB
(C) rC > rB > rA
(D) rB > rA > rC

19) Lassaigne’s test for the detection of nitrogen will fail in the case of

(A)

(B)

(C) NH2–[Link]

(D)

20) Which of the following compounds will be suitable for Kjeldahl's method for nitrogen estimation
?

(A)

(B)

(C)

(D)

SECTION-II

1) Identify total number of species which are more stable than .

(i) (ii) (iii) (iv)

(v) (vi)
(vii) (viii)

2)

Write the sum of locant in the following compound is:

3)
Total number of carbon in principal carbon chain ?

4) A sample of 0.2 g of an organic compound when analysed by Duma’s method yields 22.4
mL of N2 gas which is collected over KOH solution at 17°C and at a pressure of 749 mm Hg.
The percentage of nitrogen in the given organic compound is ____(Nearest integer)
a) Aqueous tension of water at 290 k is 13 mm Hg
b) R = 0.0821 L atm/ [Link].

5) On a thin layer chromatographic plate, an organic compound moved by 3.5 cm, while the solvent
moved by 5 cm. The retardation factor of the organic compound is _____ × 10–1.

MATHEMATICS

SECTION-I

1) The area of the region is equal to

(A) 7
(B) 24/5
(C) 20/3
(D) 5

2) The area (in square units) of the region enclosed by the ellipse in the first quadrant
below the line is
(A)

(B)
(C)

(D)

3) The area (in sq. units) of the region

A = {(x, y) : x2 ≤ y ≤ x + 2} is

(A)

(B)

(C)

(D)

4) Area bounded by the curve y = log x, x-axis and the ordinates x = 1, x = 2 is-

(A) log 4 sq. units

(B) log 4 + 1 sq. units
(C) log 4 – 1 sq. units
(D) None of these

5) The area bounded between the curve , x = –2, x = 3 and x–axis is-

(A) 45/4
(B) 45/2
(C) 15
(D) 25/2

6) The area between the curve y = sin3 x, x-axis and the ordinates x = 0 to x = π/2 is-

(A) 1
(B) 1/3
(C) 2/3
(D) 3/2

7)

The area enclosed between the curves y = sin2x and y = cos2x in the interval 0 ≤ x ≤ π is

(A) 2 sq. unit

(B)
(C) 1 sq. unit
(D) 4 sq. unit

8) Area (in sq. units) of the region outside and inside the ellipse is :

(A) 3(4 – π)
(B) 6(π – 2)
(C) 3(π – 2)
(D) 6(4 – π)

9) Given : ƒ(x) = and

g(x) = , x ∈ R. Then the area (in sq. units) of the region bounded by the curves, y =
ƒ(x) and y = g(x) between the lines, 2x = 1 and 2x = , is :

(A)

(B)

(C)

(D)

10) The area bounded by the curve y = , coordinates axes and x = π/4 is-

(A) 1
(B) 2
(C) π/4
(D) ∞

11) Area lying in the first quadrant and bounded by the circle x2 + y2 = 4, the line x = y and x-
axis is-

(A) π

(B)

(C)

(D) None of these

12)
The area between the curve y = tan x, y = cot x and x-axis in the interval is

(A) log 2
(B) log 3
(C)
(D) None of these

13) The area between the parabola x2 = 4y and line x = 4y –2 is

(A)

(B)

(C)

(D) 9

14) If the area (in sq. units) of the region {(x, y) : y2 ≤ 4x, x + y ≤ l, x ≥ 0, y ≥ O} is , then a
– b is equal to :

(A)

(B)

(C) 6

(D)

15) The area (in sq. units) of the region A = {(x, y) ∈ R × R|0 < x < 3, 0 < y < 4, y < x2 + 3x} is :

(A)

(B)

(C) 8

(D)

16)

Let the straight line x = b divide the area enclosed by y = (1 – x)2, y = 0 and x = 0 into two parts

and such that . Then b equals

(A)

(B)
(C)

(D)

17) The area of the region between the curves y = and y = bounded by the

lines x = 0 and x = is-

(A)

(B)

(C)

(D)

18) The area bounded by the curves y = logex and y = (logex)2 is-

(A) 3 – e
(B) e – 3

(C)

(D)

19) The area enclosed by the curve y = sinx + cosx and y = |cosx – sinx| over the interval is

(A)
(B)
(C)
(D)

20) The area of the region bounded by the curves y = |x-2|, x = 1, x = 3 and the X-axis is

(A) 4
(B) 2
(C) 3
(D) 1
 SECTION-II

1) The area enclosed by |x – 2| + |y – 3| = 1 is (in square units) -

2) The area of the region enclosed between the curves and .

3) Let the area of the region {(x, y) : x – 2y + 4 ≥ 0, x + 2y2 > 0, x + 4y2 ≤ 8, y ≥ 0} be , where m
and n are coprime numbers. Then m + n is equal to _____.

4) If the area bounded by x = 0, y = 0, x = 2, y = 2, and is (a - b ln2) sq. unit, where

then value of is

5) The area bounded by the curve x2 = 32y and line x – 2y + 5 = 0 is-

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C D A D C A A D D A B C D D B C B C A

SECTION-II

Q. 21 22 23 24 25
A. 2 106 5 30 1

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A A D A D A B C A D C D A C A A B C D

SECTION-II

Q. 46 47 48 49 50
A. 2 6 17 13 7

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C B C A C C B B A C A B C B B B A B D

SECTION-II

Q. 71 72 73 74 75
A. 2 8 119 5 72
 SOLUTIONS

PHYSICS

1)

2)

3) Velocity at point

4) V = nλ
λ= = 0.1

Δϕ = . Δx =

Δx =

5)

at t = 2 sec and x = 4m, y is 2 mm & is

6) At earth ⇒
(T = Mg M=1 Kg)

At moon
n' = n When M' = 6 Kg

7) Two consecutive resonant frequencies for a string fixed at both ends will be

= 105 Hz
Which is the minimum resonant frequency

8) Equation of the harmonic progressive wave given y = a sin 2π(bt – cx)

Here 2πν = ω = 2πb ⇒ ν = b

k= = 2πc ⇒ =c

(Here c is the symbol given for and not the velocity)

∴ Velocity of the wave = νλ =

= a2πb cos2π(bt – cx) = aω cos(ωt – kx)

Maximum particle velocity = aω = a2πb = 2πab given this is 2 ×

i.e., 2πab = or c = .

9) n1 : n2 : n3 :: 1 : 3 : 4

n∝
 ℓ1 : ℓ2 : ℓ3 :: 1 : : = [12 : 4 : 3]
[72 : 24 : 18] Ans.

10) For interference, two waves must have same frequency, same wavelength, same velocity in
same direction.
For stationary waves, two waves must have same frequency, same wavelength and same
velocity in opposite direction.

11) I ∝ n2a2

12) y1 = a1 sin (wt – kx)

y2 = a2 sin (wt – kx + ϕ + )

Δϕ = ϕ +

Δx =

13) Phase difference = × path difference

⇒ 1.6π = × 40 ⇒ λ = 50 cm = 0.5m
⇒ ν = nλ ⇒ 330 = 0.5 × n ⇒ n = 660 Hz

14)

–x direction

15)

Frequency COP, nN = (2N + 1)

for N = 0, n0 = 100 Hz
N = 1, n1 = 300 Hz
N = 2, n2 = 500 Hz
N = 3, n3 = 700 Hz
N = 4, n4 = 900 Hz
N = 5, n5 = 1100 Hz

Which are less than 1250 Hz.

 16)

Δx = πr – 2r =

3.14 r – 2r =

r= = 17.5 cm

17) f = =

L = 20

L = 20

L = 20

L = 200 × mm
change in length

= mm

= mm
= 6.67 mm ≈ 7 mm

18) Bulk modulus β =

speed v =
19)

20) 425 : 595 : 765

5 : 7 : 9
ratio of frequency is odd
pipe → closed end.
425 is frequency of 2nd overtone

⇒ , ℓ = 1m

21)

⇒
⇒ 120 + 6e = 124 + 4e
2e = 4
e = 2 cm

22)

Now
⇒ Δn = 106.06 Hz

23)
Resultant amplitude
 24) using

25) Solution:
f=k
f2 = kT
ℓnf2 = ℓnk + ℓnT

Final Answer: 1.

CHEMISTRY

26)

27) More basic because ℓ.p. is localised.

28)
Also as per N.C.E.R.T result if R = –CH3
Basic strength 2° > 1° > 3°
Hence order of basic strength in aqueous solution
(I) < (IV) < (II) < (III)
29)
is less stable due to positive charges near.

30)
Also as per N.C.E.R.T result if R = –CH3
Basic strength 2° > 1° > 3°
Hence order of basic strength in aqueous solution
(I) < (IV) < (II) < (III)

31) 4th has maximum number of hyperconjugative forms

32)

33) EWG or –I occuring group stabilize carbanion.

34)

35)
C.B. of terminal alkyne will be sp hybridisation and loculised. In other C.B. will be resonance
stablised.

36) From theory (order of –I-effect)

37) (3) Order of acidic strength of groups present in given compound is carboxylic acid > m-
nitrophenol > Phenol > Terminal alkyne so, acid base reaction with 2 mole NaNH2 will be
preferred with the most acidic group that carboxylic gr. & 2nd acidic group m-nitrophenol in
the given compound.
38)
Due to presence of 3 (-R) groups

39)
Addition of OH & H, No rearrangment Acc Markownicoff.

40) Br2 + H2O [Bayer's reagent] test for unsaturation

Na metal, only terminal alkyne can react in the given option.

41) CH3 – C ≡ C – CH3

Syn - Addition Cis-2-butene

42)

43) Stability order of product.

> >
Rate of reaction α stability of product.

44) For lassaigne’s test organic, compound must contain N in addition to carbon to form NaCN
in sodium extract.

45)

Question Explanation:

Determine which chemical form of nitrogen in an organic compound is accurately quantifiable

 using Kjeldahl's method.

Concept:

This question is based on Kjeldahl's Method.

Solution:
Kjeldahl's method estimates nitrogen by digesting the organic compound with concentrated H2SO4 to
convert nitrogen into ammonium sulfate.

This method is valid for amines like aniline but is not applicable to compounds containing nitrogen in
nitro (-NO2) or diazo (-N=N-) groups, or nitrogen present in a ring (like pyridine), as they do not
yield ammonium sulfate quantitatively.

Final Answer: Option (4)

46)

1,3,4,5,6,7,8

47)

Numbering will start from Cl and then clockwise it will reach to Br at position 5.

48) Question Explanation:

Identify the sum of carbon atoms in the principal carbon chain for two different unsaturated
hydrocarbons.

Concept:

This is based on IUPAC nomenclature of hydrocarbons and principal carbon chain selection.

Solution:
Compound (a): The principal chain must include the double bond (C=C). Starting numbering from
the double bond end to the longest continuous path yields a chain of 8 carbons.

Compound (b): The principal chain must include the maximum number of double bonds. The longest
chain containing both double bonds consists of 9 carbons.
Total carbons = 8 (from a) + 9 (from b) = 17.

Final Answer: 17

49)

= 12.76
= 13

50) Retardation factor =

MATHEMATICS

51)

52)
Jee Main 2024

Required area

53)
x2 = x + z
⇒ x = 2, –1

Area

54) Curve y = log x, x-axis and x = 1, x = 2

Req. Area =
= (2 log2 –2) – (log 1 – 1)
= log 4– 1 sq. unit
55)

Given curve is

⇒ (∵ intercept form)

Desired area in given by

56) Curve y = sin3x, x-axis and x = 0 to x = π/2

Req. Area

sq unit (by Walli's formula)

57)

Area
58)

Area of Ellipse = πab = 6π

Required area,
= π × 2 × 3 – (Area of quadrilateral)

=
= 6π – 12
= 6(π – 2)

59)

Required area = Area of trepezium ABCD – Area of parabola between x = &

A= –

60) The area bounded by the curve ,

coordinates axes and x = is

We have
Required Area is given by
1 unit, Hence result

61) x2 + y2 = 4 {in the first quadrant}

y2 + 3y2 = 4
4y2 = 4
y2 = 1
y=±1

62) In first quadrant tan x and cot x meet at x = . Also as shown in the diagram, desired area

is bisected at x = . So

reqd. area =

63)

Solving the equation of the given curves for x, we get

x2 = x + 2
⇒ (x – 2) (x +1) = 0
⇒ x = –1, 2
So reqd. area =

64) {(x, y) : y2 ≤ 4x, x + y ≤ 1, x ≥ 0, y ≥ 0}

a= ,b=
a–b=6

65)

Required Area
66)

∵ R1 – R2 =

⇒ (1 – b)3 =

⇒1–b=

67) and
Bounded Region

dx

= dx

dx = dx

Put ;
68) Curves y = log x .....(1)
2
and y = (log x) .....(2)
by (1) and (2) (log x)2 = log x ⇒ logx [logx–1]=0
⇒ logx = 0, log x = 1 ⇒ x = 1, x = e

Req. Area =

= –

= 1 – e + 2 [x log x – x]1e = 1 – e + 2(1)

=3–e

69) Question Explanation:

Finding the area enclosed by two trigonometric curves over an interval.

Concept:
This question is based on area between two curves.

Solution:

Final Answer:
The correct option is (2)

70)

and x-axis

Area of ABC

Area of CDE

Total area

71)
Put x – 1 = x
y–1=y
|x| + |y| = 1

=2

72)

From

Area

Area = 8.
73)

∴ m + n = 119

74)

Area = 4-
= 6 - 4 n2
a = 6, b = 4

75)

⇒ x2 – 16x – 80 = 0
⇒ x = –4 & x = 20.
Required area