08-12-2024

5301CJA101001240008 JM

PHYSICS

SECTION-I

1) Block A is placed on block B whose mass is greater than that of A. There is friction between
blocks while the ground is smooth. A horizontal force P increasing linearly with time begins to act on
A. The accelerations a1 and a2 of A and B respectively are plotted in a graph against time. Which of
the following graphs represents the real situation?

(A)

(B)

(C)

(D)

2) What force must the man exert on the rope to keep the platform in equilibrium?

(A) 100 N
(B) 200 N
(C) 300 N
(D) 500 N

3) What is the maximum value of the force F such that the block shown in the arrangement, does not

move?

(A) 20 N
(B) 10 N
(C) 12 N
(D) 15 N

4) A string of negligible mass going over a clamped pulley of mass m supports a block of mass M as

shown in the figure. The force of the pulley by the clamp is given by

(A)
(B)

(C)

(D)

5) Two weights W1 & W2 in equilibrium and at rest, are suspended as shown in figure. Then the ratio

is (all strings and pulley are ideal)

(A)

(B)
(C)

(D) None of these

6) The block shown in the figure in equilibrium. Find the acceleration of the block justafter the

string burns:

(A)

(B)

(C)

(D)

7) Two masses of 10 kg and 20 kg respectively are connected by a massless spring as shown in

figure. A force of 200 N acts on the 20 kg mass at the instant when the 10 kg mass has an
acceleration of 12 ms–2 towards right, the acceleration of the 20 kg mass is :

(A) 2 ms–2
(B) 4 ms–2
(C) 10 ms–2
(D) 20 ms–2

8) The pulleys and strings shown in figure are smooth and of negligible mass. For the system to

remain in equilibrium, the angle θ should be

(A) 0°
(B) 30°
(C) 45°
(D) 60°

9) A block of mass 4 kg is suspended through two light spring balances A and B as shown in the

figure. Then balances A and B will respectively read

(A) 4 kg and 0 kg
(B) 0 kg and 4 kg
(C) 4 kg and 4 kg
(D) 2 kg and 2 kg

10) Two blocks of masses M = 5 kg and m = 3 kg are placed on a horizontal surface as shown in
figure. The coefficient of friction between the blocks is 0.5 and that between the block M and the
horizontal surface is 0.7. What is the maximum horizontal force F that can be applied to block so

that the two blocks move without slipping? (Take: g = 10 m/s2)

(A) 4 N
(B) 16 N
(C) 24 N
(D) 96 N

11) Two blocks of masses m1 = 5 kg and m2 = 6 kg are connected by a light string passing over a
light frictionless pulley as shown in figure. The mass m1 is at rest on the inclined plane and mass m2
hangs vertically. If the angle of incline θ = 30°, what is the magnitude and direction of the force of
friction on the 5 kg block? (Take: g = 10 m/s2)

(A) 35 N up the plane

(B) 35 N down the plane
(C) 85 N up the plane
(D) 85 N down the plane

12) A uniform sphere of weight W and radius 5 cm is being held by a string as shown in figure. The

tension in the string will be :

(A)

(B)

(C)

(D)

13) A cylinder of mass M and radius R is resting on two corner edges A and B as shown in the figure.

The normal reaction at the edges A and B are: (Neglect friction)

(A)
(B)

(C)

(D)

14) A block of mass m is in contact with the cart C as shown in the figure. The coefficient of
static friction between the block and the cart is μ. The acceleration α of the cart that will prevent

the block from falling is -

(A)

(B)

(C)

(D)

15) If pulleys shown in the diagram are smooth and massless and a1 and a2 are acceleration of blocks

of mass 4 kg and 8 kg respectively, then.

(A) a1 = a2
(B) a1 = 2a2
(C) 3a1 = a2
(D) a1 = 3a2

16) Two blocks of mass 4 kg and 6 kg are placed one over the other. If a force of 10 N is applied on
the block of mass 4 kg, then the acceleration of the two blocks at the instant shown is (g = 10 m/s2)

(A) a(4 kg) = a(6 kg) = 0

(B) a(4 kg) = 0.5 m/s2,​​ a(6kg) = 0
(C) a(4 kg) = 2 m/s2 , a(6 kg) = 0.5 m/s2
(D) a(4 kg) = 1 m/s2,​​ a(6 kg) = 1 m/s2

17) If velocity of block B in the given arrangement is 300 mm/sec towards right. Then velocity of A
will be
(A) 200 mm/sec
(B) 100 mm/sec
(C) 450 mm/sec
(D) 150 mm/sec

18) If block m remains at rest in the frame of wedge find value of m1. Given that all the surfaces are

smooth and pulley and strings are ideal.

(A)

(B)

(C)

(D) any value of m1

19) Two blocks are connected by a cord passing over a small frictionless pulley and resting
on frictionless planes as shown in the figure. The acceleration of the blocks is-

(A) 0.33 m/s2

(B) 0.66 m/s2
(C) 1 m/s2
(D) 1.32 m/s2

20) Three bodies are lying on a frictionless horizontal table and these are connected as shown in the
figure. They are pulled towards right with a force T3 = 60N. If m1, m2 and m3 are equal to 10 kg, 20
kg and 30 kg respectively, then the values of T1 and T2 will be
(A) 10 N, 10N
(B) 30N, 10N
(C) 10N, 30N
(D) 30N,30N

SECTION-II

1) Force F is applied on upper pulley. If F = 30t(N) where t is time in second. Find the time then m1

loses contact with the floor. (in seconds)

2) Assuming all the surfaces to be frictionless, find the acceleration of the block C shown in figure.

3) If the string is pulled down with a force of 120 N as shown in the figure, then the acceleration of
8kg block will be_____m/s2. (g = 10m/s2)
4) A particle of mass 2kg is initially at rest. A force acts on it whose magnitude changes with time.

The force time graph is shown below. The velocity of the particle after
10s is. (In m/s)

5) Two blocks of masses m1 = 5 kg and m2 = 2 kg are connected by threads which pass over the
pulleys as shown in the figure. The threads are massless and the pulleys are massless and smooth.
The blocks can move only along the vertical direction. If the magnitude acceleration of m1, if

expressed in simplest from, is equal to m/sec2, calculate 'n'. (Take g = 10 m/s2).

CHEMISTRY

SECTION-I

1)

The decreasing order of bond angle is :-

+ –
(A) NO2 > NO2 > NO2
 – +
(B) NO2 > NO2 > NO2
+ –
(C) NO2 > NO2 > NO2
+ –
(D) NO2 > NO2 > NO2

2)

A molecule of blue vitrol (CuSO4.5H2O) contains:-

(A) Ionic, covalent bonds

(B) Ionic, covalent, coordinate bond
(C) Ionic, covalent, coordinate, hydrogen bonds
(D) Ionic bond only

3) Which has maximum dipole moment ?

(A)

(B)

(C)

(D)

4) The hybridisation used by P in PCl5 and S in SF6 respectively are :

(A) dsp3 and d2sp3

(B) d2sp3 and d2sp2
(C) sp3d2 and sp3d3
(D) sp3d and sp3d2

5) Which of the following oxide is neutral ?

(A) CO
(B) SnO2
(C) ZnO
(D) SiO2

6) Choose the s‑block element from the following:

(A) 1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 4s1

(B) 1s2, 2s2, 2p6, 3s2, 3p6, 3d10, 4s1
(C) 1s2, 2s2, 2p6, 3s2, 3p6, 4s1
(D) all of the above

7) Moving from right to left in a periodic table, the atomic size is:

(A) Increased
(B) Decreased
(C) Remains constant
(D) None of these

8) Statement-1 : F atom has a less negative electron gain enthalpy than Cl atom.
Statement-2 : Additional electron is repelled more efficiently by 3p electron in Cl atom than by 2p
electron in F atom.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement‑1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

9) The increasing order of atomic radii of the following group 13 elements is

(A) Al < Ga < In < Tl

(B) Ga < Al < In < Tl
(C) Al < In < Ga < Tl
(D) Al < Ga < Tl < In

10) The isoelectronic set of ions is :

(A) N3⊝, Li⊕, Mg2⊕ and O2⊝

(B) Li⊕, Na⊕, O2⊝ and F⊝
(C) F⊝, Li⊕, Na⊕ and Mg2⊕
(D) N3⊝, O2⊝, F⊝ and Na⊕

11) The pair that has similar atomic radii is :

(A) Sc and Ni
(B) Ti and Hf
(C) Mo and W
(D) Mn and Re

12) The electronegativity of aluminium is similar to : [JEE(Main)-2019]

(A) Boron
(B) Carbon
(C) Lithium
(D) Beryllium

13) The acidic, basic and amphoteric oxides, respectively, are : [JEE (Main)-2020]

(A) MgO, Cl2O, Al2 O3

(B) Cl2O, CaO, P4 O10
(C) Na2 O, SO3, Al2 O3
(D) N2 O3, Li2 O, Al2 O3

14) Amongst the following elements, the highest I.E. is :-

(A) [Ne] 3s2 3p1

(B) [Ne] 3s2 3p3
(C) [Ne] 3s2 3p2
(D) [Ar] 3d10 4s2 4p3

15) Which of the following is neutral oxide :-

(A) NO2
(B) N2O3
(C) N2O5
(D) NO

16) The compound has 3d2 4s2 configuration is related to which block :-

(A) s-block
(B) p-block
(C) d-block
(D) f-block

17) Most favourable conditions for electrovalent bonding are :-

(A) Low ionisation potential of one atom and high electron affinity of the other atom
(B) High electron affinity and high ionisation potential of both the atoms
(C) Low electron affinity and low ionisation potential of both the atoms
(D) High ionisation potential of one atom and low electron affinity of the other atom
18) The structure of PCl5 in the solid state is

(A) square pyramidal

+ –
(B) tetrahedral [PCl4] and octahedral [PCl6]
+ –
(C) square planar [PCl4] and octahedral [PCl6]
(D) trigonal bipyramidal

19) Which among the following species has unequal bond lengths ?

(A)
(B)
(C)
(D)

20) The shape of XeO2F2 molecule is :

(A) Trigonal bipyramidal

(B) Square planar
(C) tetrahedral
(D) see-saw

SECTION-II

1) What is the total number of pπ-pπ bonds present in ?

2) Find the number of molecule having dipole moment less than the dipole moment of

3) Based on VSEPR theory, the number of 90 degree F–Br–F angles in BrF5 is :

4)

For an element the successive ionisation energy values (in eV/atom), are given below.
14.534, 29.601, 47.448, 77.472, 97.888, 552.057, 667.029
Find the number of valence shell electrons in that element.
5) How many of the following oxides are amphoteric
BeO, Al2O3, SnO2, N2O, NO, CO2, PbO2, Sb2 O3

MATHEMATICS

SECTION-I

1) Set of all values of 'x' satisfying inequality ≥ 0 is :-

(A) (–∞, –2) ∪ [1, 3] ∪ (5, ∞)

(B) (–∞, –2) ∪ [0, 1] ∪ (2, 3] ∪ [5, ∞)
(C) (–∞, –2) ∪ [1, 3] ∪ (5, ∞) ∪ {0}
(D) (–∞, –2) ∪ [1, 2) ∪ (2, 3] ∪ (5, ∞) ∪ {0}

2) Number of solutions of equation ||x – 1| – 2| = 1 :-

(A) 0
(B) 2
(C) 4
(D) 1

3)

If (where a, b, c are non-zero real number) then value of is

(A) 8
(B) 4
(C) 6
(D) 2

4)

The numerical value of

is (a, b, c are distinct real numbers)

(A) 1
(B) 8
(C) 0
(D) None
5) Which of the following reduces to an integer?

(A)

(B)

(C)

(D) log48

6)

Solution set of inequality is

(A)
(B)
(C)
(D) None of these

7)

If log27 = a and log32 = b, then the value of log14 84 is :

(A)

(B)

(C)

(D)

8) Given log10 2 = a and log10 3 = b. If 3x + 2 = 45. Then value of x in terms of a and b is

(A)

(B)

(C)

(D)

9) If A + B = 45o, then is equal to

(A) 3

(B)
(C) -1
(D) 2

10) The value of is

(A)

(B)

(C)

(D)

11) If ϵ R and satisfy , then the minimum value of is :

(A) 2
(B) 1
(C)
(D)

12) If , then the value of expression is equal to :

(A) 11
(B) -11
(C) 12
(D) 4

13) The value of is:

(A)

(B)

(C)

(D)

14) If 15 sin4 α + 10 cos4 α = 6, for some α ∈ R, then the value of 27 sec6 α + 8 cosec6 α is equal to :

(A) 350
(B) 500
(C) 400
(D) 250

15) If sinα + sinβ = a and cosα – cosβ = b, then identify the incorrect option-

(A)

(B)

(C)

(D)

16) Find the value of the expression

+ + + ..... +

(A) sin89°
(B) cos91°
(C) sec89°
(D) sin88°

17)

If , then the value of the expression is

(A)
–cot
cot
(B)

tan
(C)

– tan
(D)

18) If , then value of |tan α tan 2α + tan 2α tan 4α + tan 4α tan α| is

(A) 7
(B) 8
(C) 9
(D) 6

19) If is an identity then the value k is equal to :

(A) 2
(B) 3
(C) 4
(D) 6

20) The exact value of is equal to

(A) 12
(B) 24
(C) -12
(D) 48

SECTION-II

1) If log8a + log8b = (log8a )(log8b) and logab = 3, the the value of ‘a’ is

2) If cos(α + β)+sin(α–β) = 0 and 2010 tan β+1=0, then |tanα| is equal to

then tan2 .
3) If cosα= cot2 has the value equal to {where α, β ∈ (0, π)}

4) Value of at is

5) The value of is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C C A D A C B C C D B B C C B D A B B C

SECTION-II

Q. 21 22 23 24 25
A. 2.00 5.00 5.00 50.00 20.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C B D A C A C B D C D D B D C A B C D

SECTION-II

Q. 46 47 48 49 50
A. 0.00 3.00 0.00 5.00 5.00

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C D A C C B B D C B A C D A C D A B B

SECTION-II

Q. 71 72 73 74 75
A. 16 1.00 3.00 1.00 2
 SOLUTIONS

PHYSICS

8) T = mg .... (i)
.... (ii)
Dividing (ii) by (i)

9) If the springs A and B are massless or their mass is negligible compared to the mass with
which they are loaded, the tension is the same everywhere on the spring. Hence each spring
balance will read 4 kg.

10) .... (i)

.... (ii)
Using (ii) in (i), we get

= (0.5 + 0.7) × (5 + 3) × 10 = 96 N

11)
T – m1gsin30° – f = 0
or f = T - m1gsin30°
= 60 – 5 × 10 × sin30°
= 60 – 25 = 35 N

12)
Tcosθ = W
 21) Block m1
m1g – 2T = 0
m1g = 2T

F = 20 × 3 = 60
30t = 60
t = 20

23)
FBD of 8kg clock.

CHEMISTRY

30) CO → Neutral oxide

SiO2 → Acidic Oxide

31)

(1) 1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 4s1 ⇒ Cr24 d- block element
(2) 1s2, 2s2, 2p6, 3s2, 3p6, 3d10, 4s1 ⇒ Cu29 d-block element
(3) 1s2, 2s2, 2p6, 3s2, 3p6, 4s1 ⇒ K19 s-block element

32)

Generally, in periodic table, when we move across the period, atomic radius decreases due to
increase in Zeff.
Hence, according to question Moving from right to left in a period, the atomic size is
increased.

33) Statement (1) is true.

F atom has a less negative electron gain enthalpy than Cl atom.
Reason: Addition of electron is repelled more efficiently by 2p electron in 'F' atom than by
3p electron in Cl atom because size of F < Cl and charge density is greater in F.
Statement (2) is False.

34) Correct order of atomic radii for 13th group elements:

Ga < Al < In < Tl
In general top to bottom in a group, 'n' increases so atomic radius increases.
Ga < Al (d contraction or Scandide contraction).

35) The ions having same number of electrons are isoelectronic.

(1) N3⊝, Li⊕, Mg2⊕ and O2⊝
10 2 10 10
⊕ ⊕ 2⊝ ⊝
(2) Li , Na , O and F
2 10 10 10
⊝ ⊕ ⊕
(3) F , Li , Na and Mg2⊕
10 2 10 10
3⊝ 2⊝ ⊝ ⊕
(4) N , O , F and Na
10 10 10 10

36) Pair having similar atomic radii:

1. Sc and Ni as Sc > Ni
2. Ti and Hf as Hf > Ti
3. Mo and W Mo ≃ W (Due to lanthanide contraction)
4. Mn and Re as Re > Mn

37) Electronegativity of aluminium is similar to beryllium due to diagonal relationship.

38) Acidic, basic and amphoteric, respectively are:

(1) ⨉

(2) ⨉

(3) ⨉

(4) correct order

39)
40) NCERT XIIth Pg # 172, Table 7.3

41) 3d2 4s2

(n – 1) 'd' is incomplete

43)

PCl5(s) exist as [PCl4]+ and [PCl6]–

44)

45)

sp3d with 4 b.p. and 1 ℓ.p.

46) pπ – pπ = 0
pπ – dπ = 2.

47)
 48)
According to VSEPR theory all bond angle are < 90°

49)

Successive I.E. (eV / Atom)

14.534, 29.601, 47.448, 77.472,

Very large jump for the removal of sixth electron.
It means after removal of 5 electrons, noble gas configuration is achieved. Hence, valence e⊝ =
[5]

50) Amphoteric oxide ⇒ BeO, Al2 O3, SnO2, PbO2, Sb2 O3

MATHEMATICS
53)

54)

55)

Check option wise :

(A) (not integer)

(B)

(C)

(D)

56) …..(i)

For logarithm to be defined,

or
or
i.e., or
Now from (i),
i.e.,

57)

log1484 =

58)

63) Let θ =
⇒ cos3θ.cos(3θ) + sin3θ sin cos
⇒ cos3θ.[4cos3θ – 3cosθ] + sin3θ[3sinθ – 4sin3θ]
⇒ cos(2θ)[1 – sin3(2θ)]
⇒ cos3(2θ)

64) 15sin4α + 10cos4α = 6

15sin4α + 10cos4α = 6(sin2α + cos2α)2
(3sin2α – 2cos2α)2 = 0

⇒ 27sec6α + 8cosec6α
⇒ 27(sec2α)3 + 8(cosec2α)3
⇒ 27(1 + tan2α)3 + 8(1 + cot2α)3
= 250

65) square and add

2 – 2 cos(α + β) = a2 + b2

also

from option 4
= – (a2 + b2)

66) =

= = cosec1° = sec89°

67) On rationalizing ; we get

69)

72) cosαcosβ – sinαsinβ + sinαcosβ – cosαsinβ = 0

(cosβ)(cosα + sinα) – (sinβ)(sinα + cosα) = 0
(cosα + sinα)(cosβ – sinβ) = 0
⇒ cosα + sinα = 0 or cosβ = sinβ
⇒ tanα = –1 (Ans.)
or tanβ = 1

(reject tanβ = (given))

73) (Applying componendo & dividendo rule)

74)
= tan 5x

at , tan 5x = 1
75) Use