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Chemistry Solutions Test XII

The document is a chemistry test consisting of multiple-choice questions, very short answers, short answers, and brief answers related to solutions, boiling points, and vapor pressures. It includes calculations for molar mass, definitions of key terms, and derivations of important equations. The test is structured to assess knowledge on various concepts in physical chemistry.

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2 views3 pages

Chemistry Solutions Test XII

The document is a chemistry test consisting of multiple-choice questions, very short answers, short answers, and brief answers related to solutions, boiling points, and vapor pressures. It includes calculations for molar mass, definitions of key terms, and derivations of important equations. The test is structured to assess knowledge on various concepts in physical chemistry.

Uploaded by

khadehuaajbhiiwahi
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Solutions Test

XII Chemistry [20 Marks]

Q.1 MCQs [3 Marks]

1. Henry’s law constant is 0.159 mol dm⁻³ atm⁻¹. What is the solubility of gas at a partial
pressure of 0.164 atm?

(A) 0.0159 mol L⁻¹

(B) 0.164 mol L⁻¹

(C) 0.026 M

(D) 0.042 M

2. Which solution shows positive deviation from Raoult’s law?

(A) Phenol & Aniline

(B) Chloroform & Acetone

(C) Ethanol & Acetone

(D) Chloroform & Ethanol

3. The temperature at which vapour pressure of a liquid becomes equal to atmospheric


pressure is:

(A) Melting point

(B) Boiling point

(C) 273 K

(D) 373 K

Q.2 Very Short Answers [3 Marks]


1. How is van’t Hoff factor related to degree of dissociation?

2. Define: Osmosis

3. What is cryoscopic constant?

Q.3 Short Answers (Any Two) [4 Marks]

1. Normal boiling point of ethyl acetate is 77.06°C. A solution of 50 g of solute in 150 g ethyl
acetate boils at 84.27°C.

Evaluate molar mass of ethyl acetate.

Kb = 2.77 °C kg mol⁻¹

2. Derive the relation between molar mass of non-volatile solute and elevation of boiling
point.

3. How is vapour pressure lowering related to rise in boiling point of solution?

Q.4 Brief Answers (Any Two) [6 Marks]

1. (a) What is boiling point?

(b) Derive the relation between relative lowering of vapour pressure and molar mass of
solute.

2. The vapour pressures of pure liquids A and B are 450 mm Hg and 700 mm Hg
respectively.

Find the compositions of liquid and vapour if total vapour pressure is 800 mm Hg.

3. (a) Calculate mole fraction of solute if vapour pressure of pure benzene is 640 mm Hg and
vapour pressure of solution is 600 mm Hg.

(b) State the characteristics of non-ideal solutions.

Q.5 Attempt (Any One) [4 Marks]


1. (a) Define van’t Hoff factor.

(b) Define isotonic solution.

(c) Define semipermeable membrane.

(d) Define freezing point.

OR

2. (a) Derive the equation:

M2 = (1000 Kb W2) / (W1 M2)

(b) Define ebullioscopic constant with its unit.

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