26-11-2025

6001CJA10102225005RT JA

PHYSICS

SECTION-I

1) If a simple pendulum has significant amplitude (up to a factor of 1/e of original) only in the period
between t = 0 s to t = τs, then τ may be called the average life of the pendulum. When the spherical
bob of the pendulum suffers a retardation (due to viscous drag) proportional to its velocity, with 'b'
as the constant of proportionality, the average life time of the pendulum is (assuming damping is
small) in seconds :-

(A)

(B)

(C) b

(D)

2) The displacement of a damped harmonic oscillator is given by x(t ) = e–0.1 cos (10πt + ϕ). Here t is
in seconds. The time taken for its amplitude of vibration to drop to half of its initial value is close to :

(A) 13 s
(B) 7 s
(C) 27 s
(D) 4 s

3) Two particles move parallel to the x-axis about the origin with same amplitude 'a' and frequency
At a certain instant they are found at a distance a/3 from the origin on opposite sides but their
velocities are in the same direction. What, is the phase difference between the two?

(A)

(B)

(C)

(D)

4) A man of mass 60 kg standing on a platform executing S.H.M. in the vertical plane. The
displacement from the mean position varies as The value of f, for which the man
will feel weightlessness at the highest point is: (y is in metres)

(A)
(B)

(C)

(D)

5) A pendulum is executing simple harmonic motion and its maximum kinetic energy is If the
length of the pendulum is doubled and it performs simple harmonic motion with the same angular
amplitude as in the first case, its maximum kinetic energy is Then

(A)

(B)

(C)
(D)

6) A solid cylinder of mass M attached to a massless spring of force constant k is placed on a

horizontal surface in such a way that cylinder can roll without slipping. If the system is released
from the stretched position of the spring, then the period will be-

(A)

(B)

(C)

(D)

7) A particle of mass m is executing oscillation about the origin on the x-axis. Its potential energy is
U where k is a positive constant. If the amplitude of oscillation is a, then its time period T
is:

(A)
Proportional to
(B) Independent of a
(C) Proportional to
(D) Proportional to

8) A particle performing S.H.M. about mean position x = . At t = 0, it has displacement from origin

and moving away from the origin. Then which of the following is its possible graph between
position (x) and time (t) ? (A is amplitude)

(A)

(B)

(C)

(D)

9) In list-I, the systems are performing SHM and in list-II, the time period of SHM is shown then
match list-I with list-II.

List-I List-II

(P) (1)

(Q) (2)

(R) (3)
 (S) (4)

(A) P→3, Q→2, R→1, S→4

(B) P→4, Q→3, R→2, S→1
(C) P→4, Q→2, R→3, S→1
(D) P→4, Q→3, R→1, S→2

10) A particle performs SHM in a straight line. In the first second, starting from rest, it travels a
distance a and in the next second it travels a distance b in the same direction. The amplitude of the
SHM is

(A)

(B)

(C)

(D)

11) In series LCR AC circuit, the capacitance is changes from C to 4C. For same resonant frequency,
the inductance should be changed from L to

(A)

(B)

(C) 2L
(D) 4L

12) A resistor and capacitor are connected in series with

a source. The average power dissipated in the circuit is

(A) 0.5 W
(B) 1.0 W
(C) 3 W
(D) 1.5 W

13) Given below are two statements:

Statement-I: When the frequency of an a.c. source in a series LCR circuit increasing gradually, the
RMS current in the circuit first increases, attains a maximum value and then decreases.
Statement-II: In a series LCR circuit, the value of power factor at resonance is one.
In the light of given statements, choose the most appropriate answer from the options given below:

(A) Statement I is incorrect but Statement II is true

(B) Both Statement I and Statement II are false
(C) Statement I is correct but Statement II is false
(D) Both Statement I and Statement II are true.

14) A man weighing 60 kg stands on the horizontal platform of a spring balance. The platform starts

executing simple harmonic motion of amplitude 0.1 m and frequency Hz :-

(A) The spring balance reads the weight of man as 60 kg

(B) The spring balance reading fluctuates between 60 kg and 70 kg
(C) The spring balance reading fluctuates between 50 kg and 60 kg
(D) The spring balance reading fluctuates between 50 kg and 70 kg

15) A block (B) is attached to two unstretched springs S1 and S2 with spring constants k and 4k,
respectively (see figure I). The other ends are attached to identical supports M1 and M2 not attached
to the walls. The springs and supports have negligible mass. There is no friction anywhere. The
block B is displaced towards wall 1 by a small distance x (figure II) and released. The block returns
and moves a maximum distance y towards wall 2. Displacements x and y are measured with respect

to the equilibrium position of the block B. The ratio is

(A) 4
(B) 2

(C)

(D)

16) 200 Ω resistance and 1H inductance are connected in series with an A.C. circuit. The frequency

of the source is Then phase difference in between V and I will be :-

(A) 30°
(B) 60°
(C) 45°
(D) 90°

17) The figure shows a LCR network connected to 300 V a.c. supply. The circuit elements are such
that R = XL = XC = 10Ω. V1, V2 and V3 are three a.c. voltmeters connected as shown in the figure.
Which of the following represents the correct set of readings of the voltmeters ?

(A) V1 = 100 V, V2 = 100 V, V3 = 100 V

(B) V1 = 150 V, V2 = 0 V, V3 = 150 V
(C) V1 = 300 V, V2 = 100 V, V3 = 100 V
(D) V1 = 300 V, V2 = 300 V, V3 = 300 V

18) In an alternating current circuit in which an inductance and capacitance are joined in series,
current is found to be maximum when the value of inductance is 0.5 henry and the value of
capacitance is . The angular frequency of applied alternating voltage will be

(A) 5000 rad/sec

(B) 4000 rad/sec
(C)
(D) 500 rad/sec

19) Which one of the following curves represents the variation of impedance (Z) with frequency f in
series LCR circuit?

(A)

(B)

(C)

(D)
20) In an electrical circuit R, L, C and an a.c. voltage source are all connected in series. When L is
removed from the circuit, the phase difference between the voltage the current in the circuit is .
If instead, C is removed from the circuit, the phase difference is again . The power factor of the
circuit is

(A)

(B)

(C) 1

(D)

SECTION-II

1) A block of mass m is attached to three springs A,B and C having force constants k, k and 2k
respectively as shown in figure. If the block is slightly pushed against spring C. If the angular

frequency of oscillations is then find N. The system is placed on horizontal smooth surface.

2) For given spring mass system, If the time period of small oscillations of block about its mean

position is then find n. Assume ideal conditions. The system is in vertical plane and take

3) The time period of a uniform square plate of side 'a' if it is suspended through a comer is
 Find the value of 10x.

4) The rms readings of voltmeters are 150V, 130V and 120V respectively. If applied ac

rms voltage = x and power factor of the circuit is y. Find

5) When an alternating voltage of 220V is applied across a device X, a current of 0.5 A flows
through the circuit and is in phase with the applied voltage. When the same voltage is applied across
another device Y, the same current again flows through the circuit but it leads the applied voltage
by radians.
Calculate the current (in mA) flowing in the circuit when same voltage is applied across the
series combination of X and Y (in Amp).

CHEMISTRY

SECTION-I

1) The least reactive carboxylic acid derivative towards nucleophilic substitution is

(A) RCONH2
(B) RCOCl
(C) (RCO)2O
(D) RCOOC2H5

2)

'(B)' may be
(A)

(B)

(C)

(D)

3)
What is 'A'

(A)
(B)

(C)

(D)

4)
Product (B) is:

(A)
(B)

(C)

(D)

5) End product of this conversion

is ?

(A)

(B)

(C)

(D)

6) The ease of alkaline hydrolysis is more for:

(A)

(B)

(C)

(D)

7) is the final product obtained when one of the following is reacted with base.
Select the correct one.

(A)

(B)
(C)

(D)

8) A compound (A), C5H10O, forms a phenyl hydrazone and gives negative Tollens' and iodoform
tests. The compound on reduction gives n-pentane. The compound (A) is:

(A) Pentanal
(B) Pentan-2-one
(C) pentan-3-one
(D) Amyl alcohol

9) Arrange the following compounds in increasing order of their reactivity in nucleophilic addition
reactions:
Ethanal (I), Propanal (II), Propanone (III), Butanone (IV)

(A) I < II < III < IV

(B) IV < I < II < III
(C) IV < III < II < I
(D) III < IV < II < I

10) In the reaction,

[A] and [B] respectively be :

Both are

(A)
 Both are

(B)

(C)

(D)

11) The following sequence of reactions on 'A' gives:

(A)

(B)

(C)

(D)

12) Which of the following reactants on reaction with conc. NaOH followed by acidification gives the
following lactone as the only product?
(A)

(B)

(C)

(D)

13)
The product B is

(A)

(B)

(C)

(D)

14) What is product of the following sequence of reactions ?

(A)
(B)

(C)

(D)

15)

In the sequence of following reactions :

The starting compound 'P' is

(A) m-nitrotoluene
(B) p-nitrotoluene
(C) o-nitrotoluene
(D) o-bromotoluene

16) An organic compound A on reduction gives compound B, which on reaction with

trichloromethane and caustic potash forms C. The compound 'C' on catalytic reduction gives N-
methyl benzenamine, the compound 'A' is

(A) Nitrobenzene
(B) Nitromethane
(C) Methanamine
(D) Benzenamine

17) The correct sequential order of the reagents for the given reaction is :

⊕ ⊕
(A) HNO2, Fe/H , HNO2, KI, H2O/H
⊕
(B) HNO2, KI, Fe/H , HNO2, H2O/warm
⊕ Å
(C) HNO2, KI, HNO2, Fe/H , H2O/H
⊕
(D) HNO2, Fe/H , KI, HNO2, H2O/warm

18) Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : Experimental reaction of CH3Cl with aniline and anhydrous AlCl3 does not give o
and p-methylaniline.
Reason (R) : The — NH2 group of aniline becomes deactivating because of salt formation with
anhydrous AlCl3 and hence yields m-methyl aniline as the product. In the light of the above
statements, choose the most appropriate answer from the options given below :

(A) Both (A) and (R) are true and (R) is the correct explanation of (A).
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A).
(C) (A) is true, but (R) is false.
(D) (A) is false, but (R) is true.

19) Which one of the following reactions does not represent correct combination of substrate and
product under the given conditions ?

(A)

(B)

(C)

(D)

20) The order of basicity among the following compounds is

(A) II > I > IV > III

(B) IV > II > III > I
(C) I > IV > III > II
(D) IV > I > II > III

SECTION-II

1) The number of moles of KOH required in carbylamine reaction, to react with one mole R-NH2
2) (major)
The number of carbon atoms and oxygen atoms in the product is x and y respectively. Then value of
x-y is?

3)

The molar mass of product 'A'

(round off to nearest integer)
[atomic mass: C=12, H=1, N=14, O=16]

4) Scheme 1 and 2 describe the conversion of P to Q and R to S, respectively. Scheme 3 describes

the synthesis of T from Q and S. The total number of Br atoms in a molecule of T is ______.
Scheme 1 :

Scheme 2 :

Scheme 3 :

5) How many of the CO2 molecules will be released when a molecule of following compound is
subjected to pyrolysis

MATHEMATICS
 SECTION-I

1) If occurs in the term in the expansion of , then r =

(A) 7
(B) 8
(C) 9
(D) 10

2) If the greatest value of the term independent of 'x' in the expansion of

, then the value of 'a' is equal to:

(A)
(B) 1
(C)
(D) 2

3) The term independent of x in the expansion of is equal to:

(A) 36
(B)
(C)
(D)

4) The value of is equal to:

(A)
(B)
(C)
(D)

5)

The value of r for which

is maximum, is

(A) 20
(B) 15
(C) 11
(D) 10

6) If the coefficients of x-2 and x-4 in the expansion of ; are m and n

respectively, then is equal to

(A) 27
(B) 182
(C) 5/4
(D) 4/5

7) Let (x0, y0) be the solution of the following equations . Then x0 is

(A) 1/6
(B) 1/3
(C) 1/2
(D) 6

8) If the fourth term in the binomial expansion of is equal to 200, and x > 1,
then the value of x is :

(A) 103
(B) 100
(C) 104
(D) 10

9) If the number of integral terms in the expansion of (31/2 + 51/8)n is exactly 33, then the least value
of n is:

(A) 264
(B) 256
(C) 128
(D) 248

10) Coefficient of x11 in the expansion of (1 + x2)4 (1 + x3)7 (1 + x4)12 is

(A) 1051
(B) 1106
(C) 1113
(D) 1120

11) The term independent of x in

(A) 1

(B)

(C)
(D) None of these

12) For x ∈ R, x ≠ –1, if

,
then a17 is equal to :

(A)

(B)

(C)

(D)

13) The coefficient of in the expansion of is.

(A) -1260
(B) -12600
(C) -126000
(D) -126

14) The coefficient of x25 in expansion of expression is

(A)
(B)
(C)
(D) None

15) If

,
then α is equal to

(A) 30
(B) 60
(C) 15
(D) 10
16) The mean of 6 distinct observations is 6.5 and their variance is 10.25. If 4 out of 6 observations
are 2, 4, 5 and 7, then the remaining two observations are:

(A) 10,11
(B) 3, 18
(C) 8, 13
(D) 1, 20

17) The mean and standard deviation of 20 observations were calculated as 10 and 2.5 respectively.
It was found that by mistake one data value was taken as 25 instead of 35. If are the
mean and standard deviation respectively for correct data, then is:

(A) (11, 26)

(B) (10.5, 25)
(C) (11, 25)
(D) (10.5, 26)

18) Let in a series of 2n observations, half of them are equal to a and remaining half are equal to -a.
Also by adding a constant b in each of these observations, the mean and standard deviation of new
set become 5 and 20, respectively. Then the value of a2 + b2 is equal to:

(A) 425
(B) 650
(C) 250
(D) 925

19) If the mean and variance of the following data:

6, 10, 7, 13, a, 12, b, 12 are 9 and respectively, then is equal to:

(A) 24
(B) 12
(C) 32
(D) 16

20) Let the mean and variance of the frequency distribution

be 6 and 6.8 respectively. If x3 is changed from 8 to 7, then the mean for the new data will be:

(A) 4
(B) 5

(C)

(D)

SECTION-II
1) If coefficients of term and term are equal in the expansion of then the
value of will be

2) The term independent of x in the expansion of is

3) The term independent of 'x' in the expansion of where is

equal to ________.

4) The remainder when 599 is divided by 13 is

5) The first of the two samples in a group has 100 items with mean 15 and standard deviation 3. If
the whole group has 250 items with mean 15.6 and standard deviation , then the standard
deviation of the second sample is:
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B A C C B A D D C A C D D C C D D C C

SECTION-II

Q. 21 22 23 24 25
A. 3 12 15 6 350

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A B C C A A A C C C C C B A B A B C D D

SECTION-II

Q. 46 47 48 49 50
A. 3 2 78 4 4

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C D D B A B C D B C D B B B C A D A D C

SECTION-II

Q. 71 72 73 74 75
A. 14 4 210 8 4
 SOLUTIONS

PHYSICS

1)

For damped oscilletion

and A = A0e

if m = 1 kg ⇒

0
2) A = A e–0.1t =
ln2 = 0.1t
t = 10 ln2 = 6.93 ≈ 7 sec

3)
4)

5) Maximum kinetic energy

if length is doubled

6)
Elongation in spring
Restoring torque about point P. is,

7)

8)

Only in option D displacement is negative at t = 0 and moving away from the origin.
9) (A)

(B) = constant

(C)
= constant

(D)

10) When particle starts from mean positon

11)

12)

13) In the series of RLC circuit

At resonance,
Impedance is minimum so the current will be maximum, from the figure if f is increase the
impedance also increase then current decrease, so statement (I) is correct.
In RLC circuit at resonance,
So, the circuit behaves a pure resistive circuit the power factor will be unit so statement II is
also correct.

14) The maximum force acting on the body executing simple harmonic motion is
ω2a = m×(2πf)2a = 60 × × 0.1 N

= 60 × 16 × 0.1 = 96N = ≈ 10kgf and this force is towards mean position.

The reaction of the force on the platform away from the mean position. It reduces the weight
of man on upper extreme,i.e. net weight becomes
= (60 –10)kgf.
This force adds to the weight at lower extreme osition i.e., net weight becomes = (60 + 10)
kgf.
herefore. the reading the weight recorded by spring balance fluctuates between 50 kgf and 70
kgf.

15)

16)

17) VR = iR, VL = iXL = VC = iXC

18) Current is maximum when XL=XC

19) Impedance at resonant frequency is minimum in series LCR circuit.

So,
20)

21) Since the push is slight, the tilt in the orientation of springs A and B can be ignored.
If the block is pushed by distance x, then by resolution of vectors, then component of

displacement along the line of A and B are both

So restoring force exerted by A and B will be both

The resultant restoring force due to A & B is Kx along the diagonal between A and B.
Net restoring force towards the equilibrium is = 3Kx

Angular frequency

22) Time period.

 23)
Time period of a compound pendulum is

Moment of inertia,

24)

25) Since the current in the two devices is the same (0.5A at 220 volt)
When R and C are in series across the same voltage then

CHEMISTRY
26) Stronger is the basic nature, poor is the leaving group, less is the reactivity towards
nucleophilic substituition

27) HYZ followed by elimination.

28)

29) Aniline is protanated to form Anilinium ion

30) NaBH4 reduces reactant to

which forms ester.

31)

32)

33)

Ketones do not give Tollen's [Link] methyl ketones give iodoform test.

34)

Reactivity towards nucleophilic additon

35)

36)

37)

38) 1. Asking About :

Product of the reaction.

2. Concept :
Reaction of carbonyl compound with ammonia derivative and Beekmann Rearrangement

3. Solution / Explanation :
39)

41) Asking About :- Reactant of sequence of reactions.

Concept :- Reduction, Isocyanide test

Solutions / Explanation :-

A = nitrobenzene
A is reduced to aniline which on reaction with CHCl3 + KOH give phenyl isocyanide.
Reduction of phenyl isocyanide given N-methylbenzenamine.
42)

43)
Friedel Craft Alkylation does not occur on this deactivated ring.

44)

45) Basic strength ∝ stability of conjugate acid

∝ +M/+H/+I
IV > I > II > III

46)

47)
 48)

49)

50)

MATHEMATICS

51)

52)

r=5

53) (

=
=

54)
55)

Coefficient of
Coefficient of
in maximum when

56)

57)
Taking log to these base e of both equations
....(i)
.....(ii)
Eliminating y between the two, we have
58)
y=1
x = 10

59)
will be integer for r = 0, 8, 16, 24, ---
& will be integer for
n - r = 0, 2, 4, .......
So, and will have integer
0, 8, 16, 24, ......
Now, an =
= 0 + 8 (33 - 1) = 256.

60) Coefficient of x11 in the expansion of (1 + x2)4 (1 + x3)7 (1 + 44)12 is

Coefficient of xa) (Coefficient of xb) (Coefficient of xc)
Such that a + b + c = 11
Here a = 2m, b = 3n, c = 4p
2m + 3n + 4p = 11
Case I : m = 0, n = 1, p = 2
Case II: m = 1, n = 3, p = 0
Case III: m = 2, n = 1, p = 1
Case IV: m = 4, n = 1 p = 0

Required Coefficient = + ..... +

= 462 + 140 + 504 + 7
= 1113
61)

General term in the expansion is

For constant term,

Which is not an integer. Therefore, there will be no constant term

62)

63)
Coefficient of this implies that

Coefficient of w is

64)

Therefore, coefficient of
65)

66) Let other two numbers be a, (21 - a)

Now,

(Using formula for variance)

So, remaining two observations are 10, 11.

67) Given:

or
or

again given S.D =

or
or
= 2725 (Correct)

or

68) Let observations are denoted by for

and

Now, adding a constant b then

and (No change in S.D.)

69)

70) Given

from (i) and (ii)

So, new mean

71) Coefficient of term in expansion of (1 + x)43 = and coefficient

of term = coefficient of term =
According to question
then or or r = 14.

72)

4th term

73)
Replace 3 by 1

r=4

74)

Here 52 = 25 which is close to . Hence

Now,

Hence, the remainder is 8

75)