28-11-2025

1001CJA101021250035 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A large number of pendulum with identical bobs (mass m) but varying lengths are suspended from
a thick thread. Another pendulum of a heavier bob (mass M) is also suspended from the same thread
as shown. This pendulum with the heavier bob is used as a driver and the other pendulum called as
'driven' pendulums. Assume that the amplitude of the driver is maintained constant (by some
suitable mechanism). Let the frequency of the driver to be f0. Which is incorrect option? (β =

damping constant)

(A) One of the driven pendulums oscillates with maximum amplitude.

(B) All the driven pendulum except one are at rest.
(C) The frequency of the driven pendulum having maximum amplitude be f0
Graph between amplitude and frequency will be for the driven pendulum which have
maximum frequency in steady state in under damping (β << f0)

(D)

A = Amplitude of driver pendulum

f1 is slightly smaller than f0.

2) Consider a spring-mass system of mass m and spring constant k on a frictionless, horizontal table.
If the initial Amplitude is A and another mass m is dropped vertically onto the oscillating mass and

sticks with it when its displacement is , then which is incorrect statement ?

(A)
Amplitude after collision is A.

(B)
Total mechanical energy after collision is
(C) Time period after collision is times of initial time period
(D) Equilibrium position of S.H.M will change
3) A small spherical ball of Radius rolls back and forth without slipping on a vertical circular track
of Radius R. For a very small displacement from its equilibrium position, find angular frequency of
oscillation

(A)

(B)

(C)

(D)

4) A conducting rod of mass m and resistance R is placed on a pair of parallel, smooth conducting
rails of negligible resistances separated by a distance L. The rails are inclined at an angle θ to the
horizontal. A uniform magnetic field of strength B is directed vertically upwards. The rod is released
from rest and slides down the rails. Find terminal velocity (vt) of the rod.

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Which of the following statements is/are correct?

A lightly damped system oscillates with an amplitude that is exponentially decaying, it's angular
(A)
frequency is slightly smaller then the natural frequency.
(B) A critically damped system returns to the equilibrium position in the least possible time.
Resonance is a phenomenon where among oscillatory system, a given system responds with the
(C) greatest amplitude for a given external driving force. The angular frequency of the driving force
is known as the driving frequency.

The resonant angular frequency (ωr) of a damped system give by ; here ω0 = Natural
(D)
frequency,

2) Figure shows a LCR circuit, in which capacitor is charged, and at t = 0 switch is closed. Initially
there is no energy stored in inductor. We draw graph VC(t) VS time for different value of resistance,
which graph is/are nearly correct?

(A)

(B)

(C)

(D)

3) A time varying magnetic field is present in a cylindrical region centered at origin and
having Radius R. A particle of mass m and charge q is at rest at the origin (0,0,0) at t = 0. Which of
the following statement(s) is/are correct?

(A) The trajectory of the particle is a circle in the x-y plane for t > 0.
(B) The magnitude of net electromagnetic force on the particle is variable for t > 0.
(C) The speed of particle at any time is constant.
(D) Induced Electric field in region gives tangential acceleration to the given particle.

SECTION-II (i)

Common Content for Question No. 1 to 2

 0

XL = R = 4 ; XC = 8 ;V =

1) Net current will be at an angle θ with I1, find θ (in degree) :-

2) Find reading of A2 (in Ampere).

Common Content for Question No. 3 to 4

A pendulum of mass m & charge q is hanging by a string of length ℓ = 2 m from centre of
magnetic field created by long solenoid as shown in figure, having n turns / length (n = 500) &
current i = αt then (Neglect magnetic field due to motion of charge of bob) (Given α = πA/sec, m =
0.4 gm, g = 10 m/sec2, π2 = 10, μ0 = 4π × 10–7 S.I. unit, q = 1 C, 31/4 = 1.32 & π2 = 10)

3) Find equilibrium angle in degree of pendulum with vertical.

4) If pendulum is slightly displaced from this equilibrium than find its time period of oscillation (in
sec).

SECTION-II (ii)

1) A particle of mass m and charge q is currently located on the interior of a square room of side
length ℓ as shown in the figure below (top view). A uniform magnetic field B is directed into the page

in the figure. Suppose that particle is now propelled at an initial velocity perpendicular to
a wall of the room, as depicted in the figure. If time it requires to return to its initial position is

, find value of k, assuming that its collisions with the walls are perfectly elastic.
2) In circuit (i), Inductance and resistance of the inductor are L and R respectively.

In circuit (ii), capacitance of the capacitor and resistance of resistor are C and

RC respectively. In circuit (iii),Inductance and resistance of the inductor are L and

R, capacitance of the capacitor is C, RC is resistance of the resistor which is connected in parallel
with the capacitor as shown in figure. R1 and R2 are resistors of resistance of 2 : 3 ratio. If reading of
the voltmeter connected across the terminals A and B as shown in figure is zero, find ratio of time

constants of circuit (i) and circuit (ii).

3) The circuit shows a resistance R = 0.01Ω and inductance L = 3mH connected to a conducting rod
PQ of length ℓ = 2m which can slide on a perfectly conducting circular arc of radius ℓ with its centre
at P. Assume that friction & gravity are absent and a constant uniform magnetic field B = 0.1
T exists as shown in the figure. At t = 0, the circuit is switched on and simultaneously an external
torque is applied on the rod so that it rotates about P with a constant angular velocity ω = 2 rad/sec.
Find the magnitude of this torque (in N–m) at t = (0.3 ℓn2) second.
4) Consider the following AC circuit. The voltage difference between D and E has amplitude VDE =
7V. Similarly VDF = 15 V and VEF = 20 V. What is magnitude of V0 (in V)? (V0 is amplitude of source)

5) In the given diagram initially spring of force constant k is compressed by & B has a velocity of

towards right. Time after which the spring attains max extension equal to , then find

the value of (α + β).

6) A cube of mass m & side length a is placed as shown in a region of magnetic field .
A square conducting loop PQRS is attached to the top face of the cube. 'r' is the resistance of the
loop. Then the time at which cube topples is . Then k = :-

PART-2 : CHEMISTRY

SECTION-I (i)

1) In fcc arrangement, if edge length of unit cell = a, select the correct statements

(P) Distance between nearest neighbours =

(Q) Distance between 2nd neighbours = a

(R) Distance between 3rd neighbours =

(S) Distance between 3rd neighbours =

(A) P, Q, S only
(B) P, Q, R only
(C) Q, R only
(D) All correct

2) Consider the given reaction :

PhNO2 Product
Which is incorrect regarding product

(A) It can show hoffmann mustard oil test

(B) A foul smelling compound is produced with CHCl3 / KOH
When react with NaNO2/ HCl followed by phenol, an orange compound is formed in alkaline
(C)
medium.
(D) It form yellow oily liquid with sodium nitrite in hydrochloric acid.

3)
Choose the correct option
(A) Molecular mass of gas (x) is 44.
(B) Gas (y) is neutral in nature
(C) Gas (y) with HCl form white fumes

(D)

Gas (x) + PhOH (major product)

4) Which of the following statements are true about the major product (P) in the given reaction.

(A) (P) is racemic mixture

(B) (P) is optically active compound
(C) (P) is more basic than Me2NH
(D) (P) has no chiral atom

SECTION-I (ii)

1) For a reaction 2N2O5 (g) 4NO2 (g) + O2(g) and t90% = 10 sec then select the correct options.

(Use log (2) = 0.3010)

(A) Reaction is of 1st order

(B) Time to complete 50% reaction is 3.01 sec
(C) Time to complete definite fraction of reaction is independent of initial concentration of reactant
(D) t15/16 = 2t3/4

2) Select the correct statements

(A) In non-stoichiometric cuprous oxide Cu1.8O, conduction is due to presence of holes

2+ 3+
(B) In non-stoichiometric ferrous oxide Fe0.94O, 18% Fe ions are replaced by Fe
Metal deficiency defect is common in compounds of transition metals because they can show
(C)
variable oxidation states.
(D) In Schottky defect density of solid increases

3) Which of the following can lead to formation of final product with carboxylic acid group?

(A)

(B)

(C)

(D)

SECTION-II (i)

Common Content for Question No. 1 to 2

Radius ratio : The arrangement of the ions in the crystal determined the relative size of cations and

anions. One can calculate the limiting value of known as radius ratio, from the packing of the
ions. The critical ratio are,

Cubic (8) octahedral (6) Tetrahedral (4) Triangular

(3) Linear (2)
These ratios are approximate in number since in actual calculations, we must also consider the
mutual repulsion and attrraction of like and unlike charges respectively, as well as polarization of
one ion by another.
It is impossible for both anions and cations to have closest packed structures but if one of the ions is
much larger than the other, it is common for the larger ions alone to approach a closest packed
strcuture and smaller ions to fit into voids in this structure.
Answer the following questions :

1) For an ionic compound Then what is the coordination no. of X–

2) For an ionic compound where A+ present in tetrahedral void and having radius 22.5 pm

then maximum possible radius of (in pm) will be :

Common Content for Question No. 3 to 4

During hydrolysis of ester is acidic medium
ester + H2O acid + alcohol
rate law is given as r = k [ester] [H ] and volume of base used at different time intervals is given as
+

at pH = 3

Answer the following questions :

3) Half life of the reaction at pH = 3 will be : (in sec.)

4) Value of rate constant at 'k' will be:

(in units of ) where n = order of the reaction)

SECTION-II (ii)

1) The electrons in a sample of gaseous Li2+ ions which are initially present in a particular excited
state makes a transition to a lower level. The emitted photons are absorbed by a sample of H-atoms
which are present in their ground state. This sample of H-atoms on de excitation gives maximum 6
different types of spectral lines. Find the quantum number of initial excited state of Li2+ ions.

2) In the given reaction for formation of major product, the molecular mass of product (P) is :

Product (P)

3) Number of compounds which on heating produces diastereomers as product mixture.

(a) (b)

(c) (d)
(e) (f)

(g) (h)

(i) (j)

4) Identify number of reactions, in which primary amines (aliphatic / aromatic) will be formed.

(a) (b)

(c) (d) CH3CH2CN

(e) (f)

(g) (h)

(i) Ph - CN (j)
5) In the given reaction sequence for compound (x)

find sum of double bond equivalent in (x), (y) & (z)

6) For the given reaction sequence Product If 1 mole of

compound is taken initially and the yield of complete reaction is 100% each every step. Then
calculate the mass (in gm) of CO2 liberated during the reaction

PART-3 : MATHEMATICS

SECTION-I (i)

1) 3 women and 15 men are to be arranged in a row such that there should be atleast 2 men
between any two women. Then number of such arrangements is :

14
(A) C4 3!
(B)
14
(C) C12
(D) 14C3

2) The coefficients of x20 in

31
(A) C20
31
(B) C21
31
(C) C19
(D) None of these

3) If solution of the equation in is (where m & n are

coprime numbers), then (m + n) can be
(A) 23
(B) 39
(C) 47
(D) 12

4) The mean of 5 observation is 5 and their variance is 12.4. If three of the observations are 1, 2 & 6;
then the mean deviation from the mean of the data is one tenth of _________.

(A) 27
(B) 28
(C) 29
(D) 30

SECTION-I (ii)

1) If 3 numbers are chosen randomly from the set {1, 2, 22, ......., 2n} without replacement then the
probability they are in increasing geometric progression is :

(A)

(B)

(C)

(D)
(n even)

2) Letters of the word SUDESH can be arranged in :

(A) 120 ways when two vowels are together.

(B) 180 ways when vowels occur in alphabetical order.
(C) 24 ways when vowels and consonants occupy their respective place.
(D) 240 ways when vowels do not occur together.

3) Consider all the permutations of the word ASSASSIN, then the probability that

(A)
No two alike letters are together is

(B)
Exactly one pair of S are together is

(C)
First A occurs before second S is

(D)
Second A occur after third S is

SECTION-II (i)
Common Content for Question No. 1 to 2
Let f(x) = cos x + sin x – 1 and g(x) = sin 2x – 2

1) Number of solutions of the equation f(x) = g(x) in is

2) If the equation f(x) = k has atleast one real solution then the number of possible integral values of
k is equal to

Common Content for Question No. 3 to 4

Let f(θ) = then :

3) Maximum value of f(θ) ∀ θ ∈ R is

4) Number of principle solutions of f(θ) = 0 is

SECTION-II (ii)

1) 4 identical dice, are rolled simultaneously. Probability that product of first two outcomes is more

than the product of last two outcomes is (m, n coprime) then value of n – 2m – 78 is equal to

2) An urn contains 4 green balls and 6 blue balls. A second urn contains 16 green balls and n blue
balls. A single ball is drawn at random from each urn and probability that both balls are of same

colour is . If first two drawn balls (one from each urn) are both green and probability of further
two drawn balls (one from each urn and without replacing first two balls) are of same colour is p,
then the value of 159p

3) If sum of the values of x satisfying the equation

in [0, 2π] is , where p and q are co-prime, then is equal to

4) The sum of all the integral value(s) of x for which

is :

5) The number of elements in the set S = {(x, y, z) : x,y,z ∈ Z, x + 2y + 3z = 42, x, y, z ≥ 0} equals

__________.

6) A, B, C in order roll a fair die indefinitely until a winner is obtained. A wins if he rolls a prime
number B wins if he rolls a composite number whereras C wins if he rolls neither prime nor
composite. Let P(A), P(B), P(C) denotes their respective chances of winning then the value
of is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B D B A

SECTION-I (ii)

Q. 5 6 7
A. A,B,C A,B,C C

SECTION-II (i)

Q. 8 9 10 11
A. 45.00 2.50 30.00 3.00 to 3.10

SECTION-II (ii)

Q. 12 13 14 15 16 17
A. 14 1 4 25 17 4

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. B D C B

SECTION-I (ii)

Q. 22 23 24
A. A,B,C,D A,B,C A,B,C

SECTION-II (i)

Q. 25 26 27 28
A. 8.00 100.00 10.00 69.30

SECTION-II (ii)

Q. 29 30 31 32 33 34
A. 3 225 5 8 19 132

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. D B C B

SECTION-I (ii)

Q. 39 40 41
A. A,C A,B,C,D C,D

SECTION-II (i)

Q. 42 43 44 45
A. 6.00 3.00 0.12 or 0.13 8.00

SECTION-II (ii)

Q. 46 47 48 49 50 51
A. 8 101 25 5 169 9
 SOLUTIONS

PART-1 : PHYSICS

1)

At resonance for forced oscillation amplitude will be maximum when natural frequency of
system = frequency of driven source.
and in case of forced oscillation graph between amplitude and frequency given by

2) Total energy (initially) = kA2, Time period

when mass is at A/2

U = P.E. = KA2 & KA2

&
Final speed of two masses after the collision is given by the conservation of momentum to be

Thus the final K.v is

The total machenical energy afterwords is

E' = U + k'

Now the amplitude be A'

after collision
= T

3)

KE = mv2 + Iω2

Total Energy
4)
Fm = mgsinθ
ILB = mgsinθ

5) when
x = A0e–ytcos(ωdt+dv)
Option (A) correct
In case of critical damping x = (c1+c2t)e–yt

for
∴ Option (B) correct
In case of resonance with low damping

6) as we know that v = v0e–4t cos(ωdt + θ0)

Here ;

for oscillatory motion ωd should be real for under damping

∴ ⇒ ⇒
R< 100

7)

Since, induced Electric Field is depending on radius of loop.

∴ at centre E = 0
No force act on charge
∴ it remains at rest.

8)

∴ tan θ = 1
θ = 45°

9)

∴ Reading of i2 = = 2.5A

10)
For equilibrium
mgsinθ= Eq

∴
θ = 30º

11) τ = –{Eq–mgsin(θ-α)}
where α is small angle displacement of pendulum from equilibrium position
12) = =
∴ when the particle undergoes a perfectly elastic head-on collision with the walls its velocity

reversed and the centre of rotation shifts by 2r = . Furthermore, observer that near the edge
of the square the particle still rotates with its centre of rotation being a vertex of the square-
causing its subsequent collision with other edge of the square to also be head-on collision
∴ total number of rotation = 7

t = 7T =
∴ k = 14

13)

14) The half of the maximum current is equal to

at

The torque at this instant

15)
AE → Voltage phasor across Ro
EB → Voltage phasor across L1
AD → Voltage phasor across 'C'
DB → Voltage phasor across R2
AF → Voltage phasor across L0
FB → Voltage phasor across R1
AB → Voltage phasor across AB whose magnitude is V0
ForΔEDF, DE = 7V = a , DF = 15V = b, EF = 20V = C

∴ by Heron's formula
∴ Area of ΔEDF
=
= 42 unit

Now diameter of circle = = = 25 Volt

∴ VA – VB = V0 = 25 volt

16) (a) , max compression would have been A as per the data.

(b) 2 body oscillation.

∴
t = t1 + t2

17)
 clockwise
limiting case :

PART-2 : CHEMISTRY

18)

FCC

19) PhNO2 PhNH2. It is 1° Amine

(a)
(b) PhNH2 + CHCl3 + KOH PhNC (Isocyanide, foul/pungent smelling compound)

(c) PhNH2 + NaNO2 / HCl

+ PhOH
(d) PhNH2 + NaNO2 + HCl →
with NaNO2 / HCl yellow oily liquid is produced by 2°- Amine

20)
NH3 + HCl NH4Cl (white dense fumes)

PhOH + (major)

21)

22)

For 1st order

= 10 × 0.3010 = 3.01 sec

23)
3x + 2 (0.94 - x) = 2
x = 2 - 1.88 = 0.12
3+
Fe 0.12 and Fe2+ 0.82

24)
(a) Me–C≡C–COOH

(b)

(c) + Ph - CH = CH2

(d) +

25) suggest BCC void having C.M. equals to 8

26)

For maximum possible radius of

will be minimum for T. V.

27)

The given rate law is = [ester][H+]. Since the concentration of H+ is kept constant at pH=3p ,
the reaction is pseudo-first order with respect to the ester.
The half-life of the reaction at pH = 3 is 10 sec.

28)

K= 69.3 M-1 sec-1

29) For H-atom :

For Li+2 ion

equating them :

30)

31)

[a, b, c, g, i ]

(a)

(b) +

(c)

(d)

(e) no Reaction

(f)
(g)

(h)

(i) CH3–CH=CH–Me

(j)

32) [a, b, c, e, f, g, i, j]

(a)

(b)

(c) Ph - CH = NH PhCH2NH2
(d) CH3CH2CN CH3CH2CHO

(e) CH3CH2NH2

(f)

(g)

(h)
 (i) Ph - CN PhCH2NH2

(j) CH3–NH2

33)

34)

CH3–COOH CH4 + CO2↑

3 mole of CO2 liberated from one mole of given compound.

PART-3 : MATHEMATICS

35) x1 W x2 W x3 W x4
x2, x3 ≥ 2, x1, x4 ≥ 0
x1 + x2 + x3 + x4 = 15
Total integral solutions of (x1, x2, x3, x4)
= 14C3
Total arrangements = 14C3

36) (x+1)18 + (x+1)19 + (x+1)20 + ........+(x+1)30

= 20C0 + 21C1+ 22C2 + ......+30C10
= 21C0 + 21C1 ......+ 29C10 + 30C10 = 31C20

37)
38)
a + b + 1 + 2 + 6 = 5 × 5 ⇒ a + b = 16 ....(1)

12.4 =
⇒ 62 = a2 + b2 + 41 – 125
⇒ a2 + b2 = 146 ....(2)
So, 2ab = (a + b)2 – a2 – b2
= 256 – 146
= 110
⇒ ab = 55 ....(3)
(a – b)2 = (a + b)2 – 4ab
= 256 – 4 × 55
= 256 – 220
⇒ (a – b)2 = 36
⇒ a – b = 6 ....(4) (Take a > b)
from (1) & (4) ; a = 11; b = 5

M.D. =

So, 10 M.D. = 28

39) Case- I . n is even n = 2k

Required probability = =
Case-II. n : odd, n = 2k + 1

Required probability =

40) vowels together =

total ways =

vowels and consonants occur in respective place =

41) ASSASSIN
Permutation when no 2S are together minus permuation when no 2S are together but 2A's are
together.

Consider A and S to be alike so no. o f arrangement =

If A comes at first place

If S comes at first place

Hence first A comes before second S is

42) f(x) = g(x)

cos x + sin x – 1 = sin 2x – 2
cos x + sin x – 1 = sin 2x + 1 – 3
Let cos x + sin x = t
(cos x + sin x)2 = t2
cos2 x + sin 2 x + 2 sin x cos x = t2
1 + sin 2x = t2
∴ Equation becomes
2
t–1=t –3
t2 – t – 2 = 0
t = 01 or t = 2
cos x + sin x = –1 or cos x + sin x = 2 (Not possible)

No. of solution in
are 6.

43) f(x) = k
cos x + sin x - 1 = k
will have solution when

-1.414 ≤ k + 1 ≤ 1.414
-2.414 ≤ k ≤ 0.414
So integral values of k ∈ {-2, -1, 0}
Total integral values of k = 3
44) f(θ) = = cos4θ –

cos2θ +

45) f(θ) = = cos4θ –

cos2θ +

46) (i) For M = N, M = 1, 9, 16, 25, 36

(ii) For M = 2, 3, 5, 8, 10, 15, 18, 20, 24, 30

(iii) For M = 6, 12

(iv) For M = 4

⇒
⇒ n – 2m –78 = 8

47)

and

48)
Case I :
sinx + cosx ≥ 0 & Let tanx = t

⇒ t = – 1, 1,

⇒
Case II :
sinx + cosx < 0

⇒ t = –1 No solution

⇒ sum of solutions is

49)

If :

⇒ or
⇒ x = 1 or x = 4
If :

⇒0=0
⇒ true for all x < 1
⇒0≤x<1
⇒ common solution [0, 1] ∪ {4}

50) x + 2y + 3z = 42, x, y, z ≥ 0
z=0 x + 2y = 42 ⇒ 22
z=1 x + 2y = 39 ⇒ 20
z=2 x + 2y = 36 ⇒ 19
z=3 x + 2y = 33 ⇒17
z=4 x + 2y = 30 ⇒16
z=5 x + 2y = 27 ⇒14
z=6 x + 2y = 24 ⇒ 13
z=7 x + 2y = 21 ⇒ 11
z=8 x + 2y = 18 ⇒ 10
z=9 x + 2y = 15 ⇒ 8
z = 10 x + 2y = 12 ⇒7
z = 11 x + 2y = 9 ⇒ 5
z = 12 x + 2y = 6 ⇒ 4
z = 13 x + 2y = 3 ⇒ 2
z = 14 x + 2y = 0 ⇒1
Total : 169

51) Let S : prime number

C : composite number
 N: Neither
Let

⇒
parallarly

&