14-12-2025

6001CJA10102225008RT JA

PHYSICS

SECTION-I

1) The percentage error in measurement of a physical quantity m given by m = π tan θ, is minimum

when :- (Assume that error in θ remain constant)

(A) θ = 45°
(B) θ = 90°
(C) θ = 60°
(D) θ = 30°

2) In the figure shown P1 and P2 are two conducting plates having charges of equal magnitude and
opposite sign. Two dielectrics of dielectric constant K1 and K2 fill the space between the plates as
shown in the figure. The ratio of electrical energy in 1st dielectric to that in the 2nd dielectric is

(A) 1 : 1
(B) K1 : K2
(C) K2 : K1
2 2
(D) K2 : K1

3) Two conducting spheres of radius r and 2r at very large separation. Each sphere is having charge
Q. These sphere are connected with a conducting wire of resistance R. Then, the current flowing in

the wire at t = 2 ms. (where r = 30 cm, and Q = 10 mC)

(A)

(B)

(C)

(D)
4) A capacitor is made of two square plates each of side 'a' making a very small angle α between

them, as shown in figure. The capacitance will be close to :

(A)

(B)

(C)

(D)

5) A parallel plate capacitor with plate area ‘A’ and distance of separation ‘d’ is filled with a
dielectric. What is the capacity of the capacitor when permittivity of the dielectric varies as :

(A)

(B)

(C) 0

(D)

6) A parallel plate capacitor has plate of length 'ℓ', width 'w' and separation of plates is 'd'. It is
connected to a battery of emf V. A dielectric slab of the same thickness 'd' and of dielectric constant
k = 4 is being inserted between the plates of the capacitor. At what length of the slab inside plates,
will be energy stored in the capacitor be two times the initial energy stored?

(A) ℓ / 4
(B) ℓ / 2
(C) ℓ / 3
(D) 2ℓ / 3

7) The rectangular box is a non ohmic resistance following where I is current through it (in
A) & V voltage across it (in V). At the balanced condition of wheatstone bridge, find the value of i.
(A) 10 A
(B) 5 A
(C) 20 A
(D) 25 A

8) A battery of internal resistance 4Ω is connected to the network of resistances as shown below. In

order to deliver the maximum power to network, the value of R in ohms should be :

(A)

(B) 2

(C)

(D) 18

9) An infinite line charge of uniform electric charge density λ lies along the axis of an electrically
conducting infinite cylindrical shell of radius R. At time t = 0, the space inside the cylinder is filled
with a material of permittivity ε and electrical conductivity σ. The electrical conduction in the
material follows Ohm's law. Which one of the following graphs best describes the subsequent
variation of the magnitude of current density j(t) at any point in the material?

(A)
(B)

(C)

(D)

10) A capacitor C is connected to two equal resistances as shwon in the figure. Consider the

following statements (i) At the time of charging of capacitor time

constant of the circuit is 2CR
(ii) At the time of discharging of the capacitor the time constant of the circuit is CR
(iii) At the time of discharging of the capacitor the time constant of the circuit is 2CR
(iv) At the time of charging of capacitor the time constant of the circuit is CR

(A) Statement (i) and (ii) only are correct

(B) Statements (ii) and (iii) only are correct
(C) Statement (iii) and (iv) only are correct
(D) Statements (i) and (iii) only are correct

11) The plates of a parallel plate capacitor are charged up to 100 V. Now, after removing the
battery, a 2mm thick plate is inserted between the plates. Then to maintain the same potential
difference, the distance between the capacitor plates in increased by 1.6 mm. The dielectric constant
of the plate is
(A) 5
(B) 1.25
(C) 4
(D) 2.5

12) A tank with base area height of the tank large enough so liquid cannot overflow if filled with a
liquid to height H. The tank is accelerated horizontally with acceleration a as shown in he figure. If a
small hole is made at point A, then it is observed that the liquid does not come out of the tank. The
magnitude of acceleration should be:

(A)

(B)

(C)

(D) None of these

13) The velocity of the liquid coming out of a small hole of a vessel containing two different liquids of
densities and as shown in the figure is:

(A)
(B)
(C)
(D)

14) A sphere of solid material of specific gravity 8 has a concentric spherical cavity and jut sinks in
water. The ratio of radius of cavity to that of outer radius of the sphere must be:

(A)

(B)
(C)

(D)

15) When a large bubble rises from the bottom of a lake to the surface, its radius doubles. If
atmospheric pressure is equal to that of column of water height H, then the depth of lake is [neglect
surface tension] :-

(A) H
(B) 2H
(C) 7H
(D) 8H

16) There is a circular tube in a vertical plane. Two liquids which do not mix and of densities d1 and
d2 are filled in the tube. Each liquid subtends 90° angle at centre. Radius joining their interface

makes an angle with vertical. Ratio is :

(A)

(B)

(C)

(D)

17) Consider a water jar of radius R that has water filled up to height H and is kept on a stand of
height h (see figure). Through a hole of radius r(r < < R) at its bottom, the water leaks out and the
stream of water coming down towards the ground has a shape like a funnel as shown in the figure. If
the radius of the cross-section of water stream when it hits the ground is x. Then:
(A)

(B)

(C)

(D)

18) In an experiment to determine the acceleration due to gravity (g) using a simple pendulum, the
length of the pendulum string is measured to be 64.0 cm using a tape measure with least count 1
mm, and the time taken for 20 oscillations is measured to be 8.0 seconds using a watch with least
count 0.1 second. The percentage error in the measurement of g is close to :

(A) 0.6%
(B) 1.3%
(C) 2.0%
(D) 2.7%

19) A uniform rod OB of length 1 m, cross-sectional area 0.012 m2 and relative density 2.0 is free to
rotate about O in vertical plane. The rod is held with a horizontal string AB which can withstand
maximum tension of 45 N. The rod and string system is kept in water as shown in figure. The
maximum value of angle which the rod can make with vertical without breaking the string is (take

g = 10 m/s2)

(A) 45°
(B) 37°
(C) 53°
(D) 60°

20) The circuit diagram given in the figure shown is the experimental setup for the measurement of
unknown resistance by using a metre bridge. The wire connected between the points P and Q(PQ =
100 cm) has uniform cross-sectional area and its resistivity is directly proportional to the distance
from point P. Null point is obtained with the jockey J with R1 and R2 in the gaps. If R1 and R2 are
interchanged, the jockey has to be displaced through a distance from the previous position along

the wire to stablish the null point. If the ratio of , the value of (in cm) is: [Ignore any end
corrections]

(A) 50

(B)

(C)

(D)

SECTION-II

1) A non uniform cube of side length a is kept inside a container as shown in the figure. The average
density of the material of the cube is is the density of water. Water is gradually filled in
the container. It is observed that the cube begins to topple, about its edge (into the plane of the

figure) passing through point A, when the height of the water in the container becomes The

distance of the centre of mass of the cube from the face AB of the cube is Find K.
Assume that water seeps under the cube.

2) The value of the resistance Rx in the circuit shown in figure so that the total resistance between
points A and B is independent of the number of loops is where x & y are coprime integers.
Find

3) The given RC circuit has two switches S1 and S2. Switch S2 is closed and S1 is open till the
capacitor is fully charged to q0. Then S2 is opened and S1 is closed simultaneously till the charge on

capacitor becomes . for which it takes time t1. Now S1 is again opened and S2 is closed

simultaneously. It takes further time t2 to reach the charge . Then the ratio is
4) Space between plates of a parallel plate capacitor is filled with three dielectric slab as shown in
figure. Find equivalent dielectric constant for the arrangement shown. Area of each plate is A.

5) If you squeeze the handle of a spray bottle (figure), you cause air to flow horizontally across the
opening of a tube that extends down into the liquid almost to the bottom of the bottle. If the air is
moving at 50.0 m/s, what is the pressure difference between the top of the tube and the
atmosphere? Assume that the density of air is ρ = 1.20 kg/m3. If your answer is 250X (in Pa) fill value
of X.

CHEMISTRY

SECTION-I

1) The process that is NOT endothermic in nature is:-

(A)
(B)
(C)

(D)

2) Which order is wrong:-

(A) Electronegativity P<N<O<F

(B) Ist ionisation potential B < Be < O < N
(C) Basic property MgO > CaO > FeO > Fe2O3
(D) Atomic radius Li < Na < K

3) Which of following option is correct?

(A) Atomic size B < Al < Ga

(B) Ionigation energy Li > Na > K
(C) Electronegativity N > O > F
(D) Metalic character Li < Be < B

4) Major product

(A)

(B)

(C)

(D)

5) The major product of the following reaction is

(A)

(B)

(C)

(D)

6) Which of the following compounds will produce a precipitate with AgNO3 ?

(A)

(B)

(C)

(D)

7)

Which of the following compounds will show retention in configuration on nucleophilic substitution
by ion ?

(A)

(B)

(C)
(D)

8) Which of the following ions undergoes disproportionation in aqueous medium-

(A) Fe+2
(B) Cr+3
(C) Cu+
(D) Zn+2

9) Carbonyl compound (X) + Grignard reagent (Y)

What are X and Y?

(A)

(B)

(C)

(D)

10) Alkyl halides can be obtained by all methods except

(A)

(B)
(C)
(D)

11) Which of the following is not an expected intermediate of the following reaction?

an alcohol
(A)

(B)

(C)

(D)

12) The number of isomeric monochlorides (structural isomers) obtained on photochemical

chlorination of n-pentane is

(A) 2
(B) 3
(C) 4
(D) 5

13) When KMnO4 is added dropwise in faintly alkaline solution of iodide, then it gets oxidized to

(A) I2
(B)
(C)
(D)

14) Which elements of lanthanoids exhibit oxidation sate of +4'.in MO2? (M = Lanthanide)

(A) Ce, Dy, Tb

(B) Yb, Eu, Sm
(C) Nd, Ce, Sm
(D) Ho, Tm, Yb
15) . Then product (P) is

(A)

(B)

(C)

(D)

16) ? (Major product)

(A)

(B)

(C)

(D)
17)
A and B respectively are

(A)

(B)

(C)

(D)

18) The number of 4f electrons in the ground state electronic configuration of Gd2+ is ———. [Atomic
number of Gd = 64]

(A) 8
(B) 9
(C) 7
(D) 6

19) FeCr2O4 + Na2CO3 + O2

Which of the following statement is true for the compounds [X], [Y], [Z]?

(A) In all three compounds, the chromium is in +6 oxidation state

[Z] is a deep blue coloured compound which decomposes rapidly in aqueous solution into Cr3+
(B)
and dioxygen
Saturated solution of [Y] gives bright orange compound, chromic anhydride, with concentrated
(C)
H2SO4.
(D) All of these

20) Mark the correct order of decreasing acid strength of the following compounds.
(A) e > d > b > a > c
(B) b > d > c > a > e
(C) d > e > c > b > a
(D) e > d > c > b > a

SECTION-II

1) Identify total number of true statements.

(i) Al2O3 is an amphoteric oxide.
(ii) Third group of periodic table accommodates maximum number of elements.
(iii) First ionisation potential of Mg is higher than that of Al.
(iv) The electronic configuration of an element is 1s2 2s2 2p6 3s2 3p6 3d5 4s1. This represents its
ground state configuration.
(v) Successive ionisation potentials are lower.
(vi) The alkali metals show increasing electronegativities from Li to Cs.
(vii) In group I of alkali metals, the ionization potential decreases down the group. Therefore lithium
is a poor reducing agent in gaseous state.
(viii) The decreasing order of electron affinity of F, Cl, Br is F > Cl > Br

2)
Give total number of elimination products including stereoisomers.

3)
The number of chiral centres in Q is ________

4) When salt-X is mixed with equal amount of K2Cr2O7 in a test tube and conc. H2SO4 is
added followed by heating the test tube, red fumes of compound-Y is obtained which is passed
into NaOH solution. Solution becomes yellow due to formation of compound-Z. The sum of total
atoms present in, Y and Z is

5) How many of the following elements are lanthanides ?

Ce, Nd, Pr, Cu, Ag, Zn, Cd

MATHEMATICS

SECTION-I

1) If ƒ(x) ƒ(y) + 2 = ƒ(x) + ƒ(y) + ƒ(xy) and ƒ(1) = 2, ƒ'(1) = 2 then sgn ƒ(x) is equal to
(where sgn denotes signum function) -

(A) 0
(B) 1
(C) –1
(D) 4

2) If , then the values of A and B so that f(x) become differentiable at x =

1.

(A) 2, 3
(B) –2, 3
(C) 3, 2
(D) –2, –3

3) Let f(x) = , then f(x) is continuous at :-

(A) x = 0
x=±
(B)

x=±
(C)

x=
(D)
4) If f(x) is continuous and then is equal to

(A)

(B)

(C) 0
(D) None of these

5) Let then at , f(x) is:-

(A) Continuous but not differentiable

(B) Not continuous
(C) Continuous and differentiable
(D) None of these

6) If , then

(A) 3f(1) + f(2) = f(3)

(B) f(3) – f(2) = f(1)
(C) 2f(0) – f(1) + f(3) = f(2)
(D) f(1) + f(2) + f(3) = f(0)

7) Let xk + yk = ak, (a, k > 0) and , then k is:

(A)

(B)

(C)

(D)

8) is equal to

(A)

(B)

(C) 1
(D) Does not Exist
9) is equal to

(A) 1
(B) e

(C)

(D) e2

10) If the function and , then the value of g'(1) is

(A) 1
(B) 2
(C) 3
(D) 4

11) If y = y(x) is an implicit function of x such that , then at x = 0 is equal to.

(A) 40
(B) 45
(C) 35
(D) 50

12) If , then f is:

(A) Continuous and differentiable for all x

(B)
Continuous for all x but not differentiable for all

(C)
Neither continuous nor differentiable for
(D) Neither continuous nor differentiable for

13) Let where [x] denotes the greatest integer function. Then:

(A)
f(x) is continuous and differentiable in for all real a, provided b = 2

(B)
f(x) is continuous and differentiable in if f(a) = 4, b = 2

(C)
f(x) is continuous and differentiable in if a = 4 and b = 0

(D)
for no choice of a and b, f(x) is differentiable in
14) Let f be a polynomial function such that
f(3x) = f ' (x) · f '' (x), for all x ∈ R. Then :

(A) f ''(2) – f '(2) = 0

(B) f(2) + f '(2) = 28
(C) f(2) – f '(2) + f ''(2) = 10
(D) f ''(2) – f(2) = 4

15) If f(x) = cosx.cos2x.cos4x.cos8x.cos16x, then is equal to:

(A)

(B)

(C) 1

(D)

16) If the function is twice differentiable, then the ordered pair (k1, k2)
is equal to :

(A)

(B) (1,1)

(C)

(D) (1,0)

17) The functions defined by f(x) = max

(A) Is differentiable for all x

(B) Is differentiable for all x except at one point
(C) Is differentiable for all x except at two points
(D) Is not differentiable at more than two points.

18) If has local maximum and minimum at x = a and x = b respectively,

then ordered pair (a, b) is

(A)
(B)
(C)
(D)

19) A spherical iron ball of 10 cm radius is coated with a layer of ice of uniform thickness that melts
at a rate of 50 cm3/min. When the thickness of ice is 5 cm, then the rate (in cm/min.) at which the
thickness of ice decreases, is

(A)

(B)

(C)

(D)

20) Let
Then the set of all values of b, for which f(x) has maximum value at x = 1, is

(A) (– 6, – 2)
(B) (2, 6)
(C)

(D)

SECTION-II

1) then value of m is equal to _______.

2) then the value of is equal to _______

3) Let be defined as

The value of for which f "(0) exists, is ________ .

4) If y = y(x) is an implicit function of x such that loge(x + y) = 4xy, then at x = 0 is equal to

_______.

5) then find the value of

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C B D B C A B A C A C B A C C D D B D

SECTION-II

Q. 21 22 23 24 25
A. 8 4 5 6 6

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C B B C D A C D C D B B A A A B C D B

SECTION-II

Q. 46 47 48 49 50
A. 5 3 2 12 3

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A C B A C C B D B A B A A A A C C B C

SECTION-II

Q. 71 72 73 74 75
A. 1 100 5 40 1
 SOLUTIONS

PHYSICS

1) Question Explanation: Find the angle at which the percentage error in a physical quantity
is minimum.
Concept: Error propagation in trigonometric functions
Solution: The physical quantity is given by m = tan(θ). The fractional error in m is found by
differentiating this expression. The percentage error in m is minimized when the denominator
of the error expression is maximized.

Final Answer: The percentage error is minimum when θ=45∘.

2) Let σ be the charge density of conducting plate and V be the volume of either dielectric

3)
Differentiating w.r.t time

4)

Assume small element dx at a distance x from left end

Capacitance for small element dx is

dC =

C=
=

5) Taking an element of width dx at a distance

x (x < d/2) from left plate

dc =
Capacitance of half of the capacitor

Capacitance of second half will be same

6)
Before inserting After inserting

slab dielectric slab C f = C1 + C 2

Cf =

Cf =

Cf = 2Ci ⇒
4x + –x=2
7)
V = iR = I

I=5A

8) Given circuit is a blanced wheat stone bridge, so no current flows through 6R registor and
equivalent circuit is

So, external resistance

= Reg
For maximum power output, when

9) Combination behave like discharging of capacitor.

So (A).

10)

Ans: (C).
Sol: During Charging

During Discharging :
Req = 2R, across capacitor

Concept: R – c circuits charging/ discharging.

11) Battery is removed, so charge will remain the same.

It is given that final potential is the same. So final capacitance should be equal to initial
capacitance,
i.e.

of K = 5
Hence, the correct option is (1)

12)
The liquid will not come out of the tank at the point A if the free surface passes through the
point itself.

or
Note that volume of water in the tank remains constant.

13)
Pressure at (1)
Applying Bernoulli's theorem between points (1) and (2),
14) Let be the density of material, be the density of water. When the sphere has just
started sinking.
weight of sphere = weight of water displaced (approx.)

15) p1v1 = p2v2 As volume bobble in decreases 8 time, So depth of lake is 7H

16) h1 = R – R sin
P1 = P3 = P0
h2 = R – R cos
h3 = R + R sin
P2 = P1 + d1g(h1 – h2) ...(1)
P2 = P3 + d2g(h3 – h2) ... (2)
d1(h1 – h2) = d2(h3 – h2)

17)

By equation of continuity
A1v1 = A2v2
18) We know that
If the measured time taken for 20 oscillations is t, then the time period,

Therefore, it is clear that

Therefore,

19) Weight of rod is

Buoyancy force on rod is

. Torque about O (for equilibrium)
from FBD of rod is.

20) From the given circuit diagram

Also ;

21) The cube will topple when torque of buoyancy exceeds the torque ue to gravity about the
side passing through point A.
 Since the cube just beings to topple when water reaches height hence

22) Req for one loop = Req for 2 loops

23) and
q0 = CV0 is the maximum charge. Now S2 is
opened and S1 is closed then

Now again S1 is opened and S2 is closed

24) The given setup is equivalent to 4 capacitors

25)

CHEMISTRY
26)
It is exothermic process.

27)

Basic property CaO > MgO

in group basic property increases.
so option C is wrong option.

28)

In group gonization energy decreases.

29)

SN2 Reaction give inversion product.

30)

31)

Alkyl halide which forms stable carbocation, readily undergo reaction with AgNO3

32) under goes SN2 Rxh but the configuration of C* does not change
which is responsible for chirality.

33)
34)

35) C2H5OH and NaCl cannot react to give alkyl halide.

36)
This rearrangement would not be possible.

37)

38)

39)

40)

41)
42)

43) Atomic number of Gd is 64

Electronic configuration of Gd is

44) FeCr2O4 + Na2CO3 + O2 Na2CrO4

Deep blue colour solution

Cro(O2)2 decomposes rapidly in aqueous solution into Cr3+ and oxygen saturated solution
dichromate ion gives bright orange compound with conc. H2SO4.

45)

46)

True statement is I, II, III, IV, VI.

47)

48)
No. of chiral centres = 2.
 49)

50)

MATHEMATICS

51) Put y =

f(x)

⇒ f(x) =
⇒ f(x) = 1 ± xn
f(1) = 2, f'(1) = 2
⇒ f(x) = 1 + x2
sgn(f(x)) = sgn(1 + x2) = 1

52) Continuity at x = 1
LHL = RHL = f(1)
⇒ A + B = 3A – B + 2
⇒ 2A – 2B + 2 = 0
⇒A–B+1=0 ...(1)
Differentiability at x = 1

f′((1–) = f′(1+)
⇒ 2B = 3A ...(2)
Solving (1) and (2)
A=2
B=3

53) x2 = 1 – x2
⇒ 2x2 = 1

⇒ x=±

54)
55)

LHD ≠ RHD
but both are finite
∴ f(x) is continuous but not differentiable at x = 0

56)
Let
f(x) = x3 – ax2 + bx – c

,
c = 6, a = 3, b = 6
f(x) = x3 – 3x2 + 6x – 6
f(1) = –2, f(2) = 2, f(3) = 12, f(0) = –6
2f(0) – f(1) + f(3) = 2 = f(2)

57) xk + yk = ak, (a, K > 0)

⇒k–1=– ⇒k= .

58)

⇒ using (1 + x)n = 1 + nx + ....

⇒

⇒
Final Answer The correct option is (2)

59)

60) Given that

Let then we should have

Differentiating both sides with respect to we get

For we get

61) ln(x + y) = 4xy (At x = 0, y = 1)

x + y = e4xy

At x = 0

0 0
2
At x = 0, = e (4) + e (24)
62)

Sharp turn at .

Hence, not differentiable at

63)

since [x] = -1 when

Now , at x = 0, for differentiability of f(x)

64)

Let f(x) be a polynomial of degree 'x'.

f(3x) = f '(x) · f ''(x)
⇒n=n–1+n–2 ⇒ n=3
Let f(x) = ax3 + bx2 + cx + d.

put in (1) to get

f ''(2) – f '(2) = 0

65) f(x) =

66) f(x) is continuous and differentiable

f(π–) = f(π) = f(π+)
–1 = –k2
f′(x) =
ƒ′(π–) = ƒ′(π+)
0=0
so, differentiable at x = 0

f''(x) =
f"(π–) = f"(π+)
2k1 = k2

67) Is differentiable for all x except at two point

68)
and

Now

f"(– 2) = – 30
is a point of local maximum
f"(3) = 30
is a point of local minimum
Hence, (– 2, 3) is the required ordered pair.

69)
When

70) If f(x) has maximum value at x = 1 then

(i)
(ii)
Intersection of above two sets

71)

=1

72)
73)

if f ’’ (0) exists then

74) ln(x + y) = 4xy (At x = 0, y = 1)

x + y = e4xy

At x = 0

0 0
2
At x = 0, = e (4) + e (24)

= 40

75)