09-12-2025

1001CJA101021250037 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A ray of light strikes a plane mirror at an angle of incidence 45° as shown in figure. After
reflection, the ray passes through a prism of refractive index 1.50, whose apex angle is 4°. Through
what angle must the mirror be rotated if the total deviation of the ray is to be 90° ?

(A) 1° in counter clockwise direction

(B) 2° in counter clockwise direction
(C) 1° in clockwise direction
(D) 2° in clockwise direction

2) A convex lens of focal length 10 cm is cut along its diameter and two halves are joined together
such that the angle between their planes is 170°. They are placed symmetrically with respect to the
axis OO’ as shown figure. To the left of lens, a point object is placed at a distance of 15 cm from the
lens system. The position and separation between the images formed by the lens system :-

(A) Nearly 30 cm right from the lens and both images do not coincide.
(B) Nearly 30 cm right from the lens and both images coincide.
(C) Nearly 45 cm right from the lens and both images do not coincide.
(D) Nearly 45 cm right from the lens and both images coincide.

3) Four forces P, 2P, 3P & 4P are respectively acting along the four sides of a square ABCD taken in
order. Find magnitude of resultant force.

(A) 2P
(B)
(C)
(D)

4) A heavy cylindrical roller of diameter D and a light cylindrical roller of diameter d rest on a
horizontal plane as shown in figure. The heavy roller has a string wound round it to which a
horizontal force P can be applied as shown in figure. Assuming that the coefficient of friction μ has
the same value for all surfaces of contact, determine the limits of μ so that the larger roller can be
pulled over the smaller one. (Assume that smaller sphere remains stationary during this process).

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) The position vector of a particle of mass m is given by the following equation

, where α = m/s3, β = 5 m/s2 and m = 0.1 kg. At t = 1 s, which of the following statement(s)
is(are) true about the particle?

(A)
The velocity is given by .

(B)
The angular momentum with respect to the origin is given by

(C)
The force is given by .
(D)
The torque with respect to the origin is given by .

2) A man standing on the edge of a swimming pool looks at a stone lying on the bottom. The depth of
the swimming pool is equal to h. If the line of vision makes an angle θ with the normal to the surface
then which of the following is/are correct? If μ is refractive index of water :-

(A) distance from the surface of water to the image of the stone formed is , if angle θ is very
small.
distance from the surface of water to the image of the stone formed is hμ, if angle θ is very
(B)
small.

(C)
distance from the surface of water to the image of the stone formed is , if angle
θ is large.

(D)
distance from the surface of water to the image of the stone formed is , if angle
θ is large.

3) Moment of inertia of an elliptical disc of semi-axes a & b having mass m about :-

(A)
the major axis is .

(B)
the major axis is .

(C)
the minor axis is .

(D)
the minor axis is .

SECTION-I (iii)

1) Select correct answer using the codes given below.

List-I List-II
 Number of images
(P) (1)
formed is one.

Number of images
(Q) (2)
formed is two.

Number of images
(R) (3)
formed is three.

Number of images
(S) (4)
formed is four.

(5) No image is formed.

(A) P → 5;Q → 2;R → 4;S → 3
(B) P → 5;Q → 2;R → 2;S → 3
(C) P → 1;Q → 2;R → 2;S → 4
(D) P → 1;Q → 2;R → 2;S → 1

2) A metal plate containing an illuminator circular aperture is placed at one end of an optical bench
and a screen, at the other end. By means of a convex lens the image of the aperture is formed on the
screen, the diameter of the image-being 4 cm. If the lens is displaced 17.5 cm along the optical
bench, an image of the aperture again appears on the screen, the diameter of the image being 2.25
cm. Then match the following :-

List-I List-II

(P) Focal length of the lens in cm (1) 122.5

(Q) Diameter of the aperture in cm (2) 3.3

(R) Distance between the aperture and the screen in cm (3) 3

(S) Power of lens in Dioptre (4) 30

(5) 40
(A) P → 2;Q → 3;R → 4;S → 1
(B) P → 1;Q → 4;R → 5;S → 2
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 3;Q → 2;R → 1;S → 4

3) A uniform disc of radius r and mass m is mounted on an axle OG of length L and negligible mass.
The axle is pivoted at the fixed point O, and the disc is constrained to roll on a horizontal floor.
Knowing that the disc rotates anticlockwise with the angular velocity ω1 about the axle OG.

List-I List-II

(P) Net angular velocity of disc (magnitude) (1) 52

(Q) Its angular momentum about O nearly (magnitude) (2) 0

(R) Its kinetic energy (3)

(S) Friction force acting on disc (magnitude) (4) 37.5

(5) 110
Given all answer in SI units (m = 3, r = 2, L = 4, ω1 = 2)
(A) P → 4;Q → 3;R → 1;S → 2
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 4;Q → 1;R → 2;S → 3
(D) P → 3;Q → 2;R → 1;S → 5

4) A heavy plank of mass 102.5 kg is placed over two solids cylindrical rollers of radii R = 10 cm, & r
= 5 cm. Mass of roller are 40 kg and 20 kg respectively. Plank is pulled towards right by applying a
horizontal force F = 25 N as shown in figure. During first second of motion the plank gets displaced
by 10 cm. If plank remain horizontal and slipping does not take place, calculate magnitude of force

of friction acting between

 List-I List-II

(P) Plank and bigger roller (1) 0.5

(Q) Plank and smaller roller (2) 3

(R) Bigger sphere and floor (3) 1.5

(S) Smaller sphere and floor (4) 1

(5) 10
(A) P → 1;Q → 2;R → 5;S → 3
(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 2;Q → 3;R → 4;S → 1
(D) P → 1;Q → 3;R → 4;S → 1

SECTION-II

1) Find distance (in cm) of final image from the lens as shown.

2) A narrow beam of light strikes a face of prism just below the midpoint M of edge AB of prism
having regular hexagon cross section as shown. The beam is parallel to AF and CD faces. If minimum
value of refractive index of prism for which the emergent beam will be parallel to incident beam is

, then x is :-

3) Radius of curvature of the silvered face is 20 cm as shown. If final image of object O forms on the
object itself, find radius of curvature of the other surface (in cm).

4) A point mass m is attached at B to a hoop of mass 3m and radius R. System is released from rest

with θ = 90° and roll without friction. If angular acceleration of hoop is then find x.

5) In the figure, if ray does not emerge from side AC then maximum value of θ is π/n radian. Then n

is :-

6) The moment of inertia of the plate in figure (a) about axis shown is I. The moment of inertia of the
hexagonal plate of same material shown in figure (b) about the axis given is αI, find value of α.

Figure (a) Figure (b)

PART-2 : CHEMISTRY

SECTION-I (i)

1) Two containers containing 1 litre each of two buffer solutions having pH 3 (container I) and 4
(container II) respectively are separated by semipermeable membrane, which allows only unionized
weak acid HA to pass through it. If 1 mole of weak acid HA (pKa = 4) is added to Ist container, then
what is the ratio of [A–]I and [A–]II.
(A)

(B) 10

(C)

(D) 0.1

2)

‘X’ , ‘Y’ and Z respectively are:

(A) ‘X’ ⇒ K4[Fe(CN)6] ; ‘Y’ ⇒ K3[Fe(CN)6] ; Z = CrCl3

2–
(B) ‘X’ ⇒ CrCl3 ; ‘Y’ ⇒ CrO4 ; Z = Cr(OH)3
(C) ‘X’ ⇒ MnCl2 ; ‘Y’ ⇒ MnO2.xH2O ; Z = Mn(OH)2
(D) ‘X’ ⇒ Ag ; ‘Y’ ⇒ Ag2O ; Z = AgOH

3) In a container of 0.5 litre, 2 mole of PCl3(g) and 3 mole of Cl2(g) are present at equilibrium.
Calculate number of moles of PCl3(g) that should be added so that new equilibrium moles of moles of
PCl5 (g) increased by 50%. (KC = 12M)

(A) 0.5
(B) 2.1
(C) 1
(D) 1.6

4) An aq. solution is prepared by dissolving 0.1 mole H2CO3 in sufficient water to get 100 ml solution
at 25°C.
(H2CO3) = 4 × 10–6 ;
(H2CO3) = 5 × 10–11.
The only incorrect equilibrium concentration is -

(A) [H+] = 6.32 × 10–4 M

– –3
(B) [HCO3 ] = 2 × 10 M
2– –11
(C) [CO3 ] = 5×10 M
(D) [OH–] = 5 × 10–12 M

SECTION-I (ii)
1) A salt of strong base – weak acid (AB) in a solution buffered at pH = 3, Ka of HB = 10–8 & Ksp of AB
= 2 × 10–10. Select incorrect option(s).

(A) Solubility 4.47 × 10–3

(B) Solubility 1.41 × 10–4 M
(C) Solubility of salt AB decreases on increase in value of pH.

(D)
In given solution

2) Which of the following pairs of ions can be separated by excess of aqueous NH3 ?

(A) Zn2+, Sn2+

(B) Pb2+, Al3+
(C) Ni2+, Cr3+
(D) Cu2+, Fe3+

3) Correct statement(s) about solubility of AgCl(s) is/are ?

KSP of AgCl = 10–10 M2, Kf of [Ag(NH3)2]+(aq) = 108

(A) Solubility in pure water is 10–5 M

(B) Solubility of AgCl is more in aqueous AgNO3 solution than in water.
(C) Solubility of AgCl in 2M NH3(aq) solution is approximately 0.166 M
(D) Solubility of AgCl is lesser in aqueous NaCl solution than in water.

SECTION-I (iii)

1) Match the following List.

List – I List – II

–3 –7
(P) HA (Ka = 10 , C = 10 M) (1)

–4 –5
(Q) HA (Ka = 10 , C = 10 M) (2)

–10 –4
(R) HA (Ka = 10 , C = 10 M) (3)

–5 –1
(S) HA (Ka = 10 , C = 10 M) (4)

(5)
The correct option is:
(A) P → 4;Q → 3;R → 5;S → 4
(B) P → 3;Q → 2;R → 4;S → 1
(C) P → 3;Q → 2;R → 1;S → 5
(D) P → 2;Q → 4;R → 5;S → 3

2) At 250°C and 1 atm pressure, vapour density of following reaction mixture at equilibrium is 20.
A(g) ⇌ B(g) + C(g)
Molar mass of A, B and C are 60, 40, 20 g/mole respectively.
Match the following List for the above reaction.

List–I List–II

(P) Kp for the reaction × 60 (1) 48

(Q) Degree of dissociation × 60 (2) 15

(R) Degree of dissociation at 5 atm pressure × 60 (3) 30

(S) Vapour density of reaction mixture at 5 atm (4) 20

(5) 24
The correct option is:
(A) P → 2;Q → 5;R → 1;S → 4
(B) P → 4;Q → 3;R → 2;S → 5
(C) P → 3;Q → 2;R → 5;S → 1
(D) P → 1;Q → 2;R → 4;S → 3

3) For the reversible reaction at 500 K

Variation of partial pressure of gases with time is shown below. Initially only ‘A’ is

taken at the partial pressure of 1 atm.

Given: = 2 kJ mol–1, = 3 kJ mol–1, = 8 kJ mol–1, (ΔfS°)B = 8 J mol–1 K–1
Match the following List for the above reaction.

List – I List – II

(P) ΔG° for given reaction (kJ/mol–1) (1) 4

(Q) Kp for given reaction (2) 2

(R) ΔS° for given reaction (J/mol–1 K–1) (3) 1

(S) ΔfS° for A (J/mol–1 K–1) (4) 3

(5) 0
The correct option is:
(A) P → 5;Q → 3;R → 1;S → 1
(B) P → 5;Q → 3;R → 1;S → 2
(C) P → 4;Q → 2;R → 5;S → 4
(D) P → 1;Q → 1;R → 5;S → 4

4) Match the following List.

List – I List – II

(P) Herbicides (1) Excess nitrate in drinking water

Increase in nutrient
(Q) Methemoglobinemia (2)
concentration

(R) Tooth decay (3) Carbon monoxide

(S) Eutrophication (4) Fluoride

(5) Sodium chlorate

The correct option is:
(A) P → 2;Q → 3;R → 5;S → 1
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 5;Q → 1;R → 4;S → 2
(D) P → 2;Q → 4;R → 3;S → 1

SECTION-II

1) Give sum of serial number of correct statements.

(1) Addition of a non–volatile solute to a pure solvent at constant T always lowers the vapour
pressure.
(2) The vapour pressure of a solution of A and B at temperature T is always less than the vapour
pressure of pure A at T.
(3) If ΔTf = 1.45°C, then ΔTf = 1.45 K.
(4) The system’s temperature remains constant as pure water freezes at constant pressure.
(5) The system’s temperature remains constant as an aqueous solution of sucrose freezes at constant
pressure.
(6) A substance cannot have multiple triple points.
(7) The critical point marks the highest temperature at which the liquid can exist.
(8) Thermodynamic equilibrium in an isolated system is reached when the system’s entropy is
maximized.
(9) Equilibrium position in a closed system may not always maximize its entropy.

2) How many statement/s is/are correct?

(i) CO which is major pollutant resulting from the combustion of fuels in automobiles plays a major
role in photochemical smog.
(ii) Classical smog has an oxidizing character while the photochemical smog is reducing in
character.
(iii) Photochemical smog occurs in day time whereas the classical smog occurs in early morning
hours.
(iv) During formation of smog the level of ozone in the atmosphere goes down.
(v) Chlorofluorocarbons are responsible for ozone layer depletion.
(vi) Greenhouse effect is responsible for global warming.
(vii) Ozone layer does not permit infrared radiation from the sun to reach the earth.
(viii) Acid rains is mostly because of oxides of nitrogen and sulphur.

3) Find the number of compounds which give coloured gaseous/volatile product(s) on treatment with
conc.H2SO4.
NaHCO3, KNO3, KF, KCl, KBr, KI, K2C2O4, NaCl + K2Cr2O7, Na2CO3

4) How many of the following reactions produce H2 gas as (one of the) product?

(i) (ii) (iii)

(iv) (v) (vi)

(vii) (viii) NaH + H2O → (ix)

(x)

5) Assuming precipitates do not contribute to solution pH, (i) to (viii) are solutions mixings with
observations. All solutions are 100 mL each. Report your answer as total number of incorrect
observations.
A – 0.1 M NaOH P – 0.9 M AlCl3
B – 0.2 M Na2CO3 Q – 0.8 M HNO3 (dil)
C – 0.3 M AgNO3 R – 0.7 M Na2SO4
D – 0.4 M BaCl2 S – 0.6 M Zn(NO3)2
E – 0.5 M NaCl T – 0.5 M Na2S
(i) A + P ⇒ White ppt formed which is soluble in excess NH3
(ii) A + B + Q ⇒ Liberation of colorless gas and pH > 7
(iii) D + E + R ⇒ White ppt formation, pH = 7
(iv) C + P ⇒ White ppt formed which is soluble in excess KCN
(v) C + T ⇒ White ppt formed which is insoluble in excess NH3
(vi) B + E + S ⇒ White ppt formed which is soluble in solution Q
(vii) A + S ⇒ White ppt formed which is soluble in excess NH3
(viii) S + T ⇒ Precipitate of same color as obtained on mixing C & T solutions

6) Non–volatile solute ‘A’ is dissolved in water to produce ideally dilute solution solution. This
solution is divided into two equal parts and collected in two different containers. When one part is
heated to 101.02°C, its 30% by mass water present initially in the solution escaped out as vapour.
The other part at solution is cooled to –2.8°C, then what percentage by mass of water present
initially in this solution will separate as ice. Solute ‘A’ does not dissociate but it dimerises to 20% to
give A2 at temperature lower than 5°C. Kf and Kb of water are 1.8 K-kg mol–1 and 0.51 K-kg
mol–1 respectively.

PART-3 : MATHEMATICS
 SECTION-I (i)

1) If the graph of the function is symmetrical about the y-axis, then n can be
(where a > 0 and a ≠ 1)

(A) 2

(B)

(C)

(D)

2) Let ; be defined as and , then

the domain of the function fog(x) is :

(A)

(B)

(C) R

(D)

3) The co-ordinate of circumcentre of the ΔABC where A ≡ (–2, 3, 6); B ≡ (2, –3, 6) and C ≡ (2, 3, –6)
is

(A)

(B) (1, 1, 1)

(C)

(D) (2, 0, 0)

4) If x2 + y2 + z2 = 1; x, y, z ∈ R then maximum value of (x – 2y)2 + 4(z – x)2 + (2y – z)2 is equal to :

(A) 1
(B) 4
(C) 9
(D) 16

SECTION-I (ii)

1) Let A = {2, 3, 4} and B = {8, 9, 12}. Then the number of element in the relation
 is N then N is
divisible by :

(A) 4
(B) 6
(C) 18
(D) 9

2) Let and be three vectors having magnitude 1, 1 and 2 respectively.

If then

(A)

(B)
acute angle between and is
(C)

(D)

3) be given by then which of the following

option is/are true for f(x) :

(A) f(x) is injective function

(B) f(x) is surjective function
(C) f(x) is odd function
(D) f(x) is an even function

SECTION-I (iii)

1) Let and

List-I List-II

(P) (1) 0

(Q) (2)

(R) (3) 2π

(S) (4) π

(5) 3π
(A) P → 4;Q → 4;R → 1;S → 2
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 4;Q → 4;R → 2;S → 2
(D) P → 1;Q → 2;R → 3;S → 4

2) Consider function f : N → R; satisfying

f(1) + 2f(2) + ….. + xf(x) = x(x + 1) f(x) – 1 and f(1) = 1.
Also x1, x2, x3 are roots of the equation x3 – 6x2 + 3Px – 2P = 0; P ∈ R also 0 < x1 ≤ x2 ≤ x3.

List-I List-II

(P) f(x1) (1)

(Q) f(x1 x2 x3) (2) 1

(R) f(P) (3)

(S) (4)

(5)

(A) P → 5;Q → 4;R → 1;S → 2

(B) P → 5;Q → 4;R → 1;S → 4
(C) P → 5;Q → 4;R → 2;S → 5
(D) P → 5;Q → 4;R → 1;S → 5

3) Match the statement in List-I with given statement in List-II

List-I List-II

If sin–1 |cos x| – cos–1 |sin x| = a has atleast one solution,

(P) (1) {0}
then ‘a’ belongs to

(Q) If equation (2)

has atleast one solution, then ‘a’ belongs to

(R) If has atleast one (3)

solution then ‘a’ belongs to

sin–1 (x2 + y2) + tan–1 (4y2 – 1) + sec–1 x = a, then a belongs

(S) (4) R
to

(5)

(A) P → 1;Q → 2;R → 3;S → 4

(B) P → 1;Q → 2;R → 3;S → 3
(C) P → 1;Q → 2;R → 4;S → 4
(D) P → 1;Q → 2;R → 3;S → 5
4) Let and be two unit vectors which are orthogonal. Two
lines and where λ, μ ∈ R are coplanar, then choose the correct option
from the following List(s) (where [.] represents greatest integer function) :

List-I List-II

(P) λ + μ is equal to (where lines intersect) (1) 1

(Q) | λ – μ | is equal to (where lines intersect) (2) 5

(R) If θ is angle between L1 and L2, then [tan θ] + 3 (3) 6

Distance of point of intersection of L1 and L2 from origin is ‘d’,

(S) (4) 4
then [d] is (where [ . ] represents GIF)

(5) 0
(A) P → 2;Q → 1;R → 4;S → 4
(B) P → 2;Q → 1;R → 4;S → 1
(C) P → 2;Q → 1;R → 4;S → 2
(D) P → 2;Q → 1;R → 4;S → 3

SECTION-II

1) Let D be the domain of the function . If the range of the

function g : D → R defined by g(x) = x – [x],

( where [.] represents greatest integer function) is (α, β) then is equal to ________

2) Let , then number of roots of equation f(x) = 0 is

3) Let x > 0; then be value of f(f(2)) + f(f(3)) is equal to

4) Consider . If α, β and γ be the projection of

along and respectively such that |α| = |β| = |γ| and then number of such ordered triplets
(a, b, c) is :

5) Let are non-zero position vectors of 4 co-planer points and

. If the least value of sin2α + 4sin2β + 9sin2γ is k then
[k] is (where [.] greatest integer function)

6) The value of (given and also

angle between is is and is is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A B D A

SECTION-I (ii)

Q. 5 6 7
A. A,B,D A,D A,D

SECTION-I (iii)

Q. 8 9 10 11
A. D C B C

SECTION-II

Q. 12 13 14 15 16 17
A. 60 2 40 8 4 6

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. D A B A

SECTION-I (ii)

Q. 22 23 24
A. B A,D A,C,D

SECTION-I (iii)

Q. 25 26 27 28
A. D B B C

SECTION-II

Q. 29 30 31 32 33 34
A. 32 4 4 8 4 19

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. D D C C

SECTION-I (ii)

Q. 39 40 41
A. A,B,C,D A,B,C,D B,C

SECTION-I (iii)

Q. 42 43 44 45
A. C D D C

SECTION-II

Q. 46 47 48 49 50 51
A. 135 0 5 8 4 0
 SOLUTIONS

PART-1 : PHYSICS

1)

In mirror :

In prism:

Total deviation = 92° (C.W.)

⇒ mirror should rotate 1°
Acw for ray will rotate 2° Acw
Answer is A

2)

V = 30
hi = 30 sin 5°

3)

4)

Since smaller sphere remains at rest

μN1d = μN2d
N1 = N2
(Net torque about C2 must be zero.)
Net horizontal force on smaller sphere is zero.
5)

At t = 1

(A)
(B)

(C)

(D)

6)
 ....(1)
Similarly from triangle IAA’

....(2)
Equating eqn. (1) and (2)

....(3)

Sin θ = μ sin ϕ ….(4)

cos θ dθ = μ cos ϕ dϕ

….(5)
From eqn. (5) & (1)

….(6)

….(7)
From eqn. (6) & (7)

7)
About x ⇒ dIx = dmy2

= a sin θ; dx = a cos θ dθ

8)

Theoritical

9)

Diameter of the aperture

Magnification,

u1 = –52.5 cm; v1 = 70 cm
Distance between the aperture and screen
= |u1| + |v1| = 122.5 cm

Focal length of the lens = 30 cm

Power =
10)

11)

F0 – f1 – f3 = m3a3 ….(1) for plank

f1 + f2 = m1a1 ….(2) for solid bigger sphere
f1R1 – f2 R2 = Icm1α1 ….(3)
a1 = R1 α1 ….(4)
f3 + f4 = m2a2 ….(5) for smaller sphere
f3R2 – f4R2 = Icm2 α2 ….(6)
a2 = R2 α2 ….(7)
a3 = 2a1 ….(8)
a3 = 2a2 ….(9)

,
f2 = f1 – 20a1 = 10a1
f2 = 10a1
25 – 15a3 – 7.5a3 = 102.5a3
25 = 125a3

a1 = 0.1 a2 = 0.1
f1 = 30 × 0.1 = 3 f3 = 1.5
f2 = 10 × 0.1 = 1 f4 = 0.5

12)

fL = 20 cm
1st refraction from the lens
u = –60 cm ; f = 20 cm

v = 30 cm
As image formed by the lens is at centre of curvature of the mirror. The light will retrace its
path & final image will form at object itself.

13)

For light beam to emerge parallel to the incident direction it must strike the face DE which is
parallel to face AB. It means incident ray at M must go to E (or below it).

Let side length of hexagon be b,

Using Snell’s law

1 · sin 30° = μ · sin θ

14)

This combination should behave as concave mirror of focal length 8 cm so that position of
object coincides with centre of curvature.

Now,

⇒ fL = 80 cm

Here, nL = 3, nS = 2, R1 = –x, R2 = –20

x = 40 cm
 15)

16) r = 75 – C = 75 – 45 = 30

θ = 45°

17)
I' = I + I + I + I + I + I = 6I

PART-2 : CHEMISTRY

18)

So,

19) K4[Fe(CN)6] + H2O2 + H2SO4 → K3[Fe(CN)6] + K2SO4 + H2O

K3[Fe(CN)6] + H2O2 + OH– → K4[Fe(CN)6]

20)
x 2 3
So, x = 1
Now,

1 2 3
1+0.5 (2–0.5+y) (3–0.5)

So, y = 2.1

21)

Ans is (A)

Now,

22)

23)
24)

AgCl(s) ⇌ Ag+ + Cl– Ksp = 10–10 M2

s (s–x) s
Ag + 2NH3(aq) ⇌ [Ag(NH3)2]+(aq)
+
Kf = 108
s–x c=2 x
c – 2x
10–10 = (s – x)s ..... (1)
8
10 = s
(s – x) (c – 2s)2 ..... (2)

10–2 =
s = 0.1
2 – 2s
s = 0.2 – 0.25
1.25 = 0.2

s=

25) Theory based.

26)
1–α α α =1+α

(Q)
So, 60 = 40 + 40α

So,

(P)

(R)

So,

(S)
27) (Q)
(P) ΔG° = –RTℓnKp = 0
(S)

So,
ΔG° = ΔH° – TΔS°
1 = 3 – TΔS°

(R)

28) Theory based.

29) 1 + 3 + 4 + 7 + 8 + 9 = 32

30) (iii), (v), (vi) & (viii).

31)

32) (i), (ii), (iii), (iv), (v), (viii), (ix) & (xi) produce H2 gas.

33) (i) Al(OH)3 ↓ white

(ii) CO2 liberated, net solution acidic due to H+ ions
(iii) BaSO4 ↓ white, no hydrolysis ions so pH = 7
(iv) AgCl ↓ white
(v) AgS ↓ black
(vi) ZnCO3 ↓ white
(vii) Zn(OH)2 ↓ white
(viii) ZnS ↓ white
Correct - iii, iv, vi, vii
Incorrect - i, ii, v, viii

34) ΔTb = Kb × m
1.02 = 0.51 × m
So, m = 2
So, before evaporate
 For 2nd solution

So, mass of solvent =

So, % mass of water solidified =

PART-3 : MATHEMATICS

35)
For graph of y = f(x) to be symmetrical about y-axis
⇒ f(–x) = f(x)

36) g(x) should be defined and also

⇒
⇒ 2x – 2 = 2x + 5 Not possible

37)

All points are equidistant from origin and equation of plane passing through A, B, C is 3x + 2y
+z–6=0
So, circumcentre will be the be the foot of perpendicular from origin to be plane

38) Let

Now

39) Choice
Similarly choice of
So total relation = 6 × 6 = 36

40)
⇒
⇒
⇒ also

⇒ ⇒

41)

Clearly f(–x) = –f(x)

Also
So f(x) is surjective

42)

Take

⇒ = 3θ

= π – 3θ

⇒ ; |x| ≥ 1
= π; |x| < 1

43) (x – 1) f(x – 1) = x f(x) = 1 . f(1) ⇒

H.M. of x1, x2, x3 = A.M. of x1; x2, x3
as x1 = x2 = x3 = 2; P = 4

44) (P)
sin–1 |sin x| – cos–1 |cos x| = a
{sin–1 |sin x|} = {cos–1 |cos x|} ⇒ a = 0
(Q)
0 ≤ x ≤ 1, 0 ≤ x2 – 1 ≤ 1, 1 ≤ x2 ≤ 2

⇒ x=1 ⇒

(R) |sin–1|sin x|| = |tan–1|tanx||

(∵ a ≥ 0)

|sin–1|sinx|| = a ⇒
(S) Clearly x = ±1, y = 0
45)

L1 and L2 are coplanar

So, they are intersecting ⇒ 6 – λ = 1 + μ and –1 + 2λ = –1 + 3μ
⇒ λ = 3 and μ = 2

⇒ so, [tan θ] + 3 = 4
Point of intersection is It is distance from origin is
So, [d] = 5

46)

x > 0 and 6 + 2 log3 x < 0 ⇒ a = 0;

47) f(y) = max{x2, 6 – |x|} – 2

48) f(f(x)) = x

49) |2a + b| = |–2a + b| =

Also a2 + b2 + c2 = 1

b=0

a=0
So total 8 ordered proper possible.

50) sin α + 2sin β + 3sin γ =

Since

⇒ sin2 α + 4sin2 β + 9sin2 γ ≥

So [k] = 4

51)

⇒ are coplanar