07-12-2025

9610ZJA801912250010 JA

PART 1 : PHYSICS

SECTION-II

1) A uniform disc of radius R having charge Q distributed uniformly all over its surface is placed on a
smooth horizontal surface. A magnetic field B = Kxt2, where K = constant, x is the distance (in
metre) from the centre of the disc and t is the time (in second) is switched on perpendicular to the
plane of the disc. The torque (in N-m) acting on the disc after 15 sec. (Take 2KQ = 1 S.I. unit and R
= 1 metre).

2) A hollow sphere of mass 1 kg is kept on a rough horizontal surface. A force of N is applied

as shown in the figure. If the minimum value of coefficient of friction for pure rolling is x. Find the

value of 10x.

3) A rectangular loop with a sliding conductor of length = 0.5 meter is located in a uniform
magnetic field B = 0.5 T perpendicular to the plane of loop. The part ad and bc has electrical
resistance R1 = 50Ω and R2 = 50Ω respectively. The conductor of mass m = 1 kg starts moving with

constant acceleration . Neglecting the self inductance of the loop and resistance of
conductor, the external force required to move the conductor with given acceleration after n sec. of

start is 1.01N. n is

4) The potential energy of a particle varies as U(x) = E0 for 0 < x < 1 and U(x) = 0 for x > 1 For 0 ≤
x ≤ 1. de–Broglie wavelengths is λ1 and for x > 1 the de–Broglie wavelength is λ2.

0
Total energy of the particle is 2E . Find .
5) A ray of light incident on a sphere of refractive index as shown in figure. Find the total

angle of deviation in degrees.

6) A satellite describes an elliptic orbit about a planet. Denoting by r0 and r1, the distances
corresponding to the perigee and apogee of the orbit . The radius of curvature of the orbit at point A

and B in terms of r and r1 is . The value of α is.

7) A 12 kg bar is pressed between two blocks the coefficient of friction between the blocks and the
bar is µ = 0.3. If force F pressing the blocks is 50 N. Minimum force required to keep the block at

rest is F1 and force required to move block with constant velocity is F2. Fill value of . (g =

10 m/s2)

8) One end of light inelastic string is tied to a helium filled balloon and its other end is tied to bottom
of a water filled container at point O. The container lies on a fixed horizontal surface and is pulled
horizontally towards right with constant horizontal acceleration of magnitude a. Assuming no
relative motion of balloon and water with respect to container, the string will be inclined with
vertical line passing through O by an angle and string will be on right of vertical line passing
through O. (g is acceleration due to gravity and a=4g) then n is

SECTION-I (i)
1) Mass density of a planet varies as ; where R is radius of planet and r is distance
from center of planet :-

A particle of mass m is to be projected from surface so as to escape the planet, its velocity of
(A)
projection relative to surface is
A particle of mass m is to be projected from surface so as to escape the planet, its velocity of
(B)
projection relative to surface is
(C) Gravitational intensity on surface of planet is πGp0R.

(D)
Time period of a satellite in circular orbit very close to planet is

2) In a kundt's tube experiment metallic rod of length 1m is clamped from the distance of 25 cm
from one end. If distance between heap of powder 50 cm and speed of sound in air is 330 m/s select

correct statement(s) :-

(A) Frequency in which tube is oscillating is 1320 Hz

(B) Frequency in which tube is oscillating is 330 Hz
(C) Velocity of wave in metallic rod is 330 m/s
(D) Velocity of wave in metallic rod is 1320 m/s

3) The balloon of mass M, the light rope and the man of mass m shown in the figure is at rest and in
equilibrium in the air. If the man starts climbing and reaches the top of the rope, then choose the

correct statement/s

(A) Distance by which balloon descend is L

Distance by which man ascend is
(B)

(C) Potential energy of man increases

(D) Change in gravitational potential energy of (man + balloon) will depend on their mass ratio.

4) Which of the following options is/are CORRECT regarding the below diagram.
(A) I1 = 8 Amp.
(B) I2 = 4 Amp.
(C) I1 = 0
(D) I3 = 8 Amp.

5) A beam of light parallel to main optical axis falls on a converging lens of focal length f1 = 20 cm.
Behind the lens, coaxially at some distance L, is diverging lens of focal length f2 = – 20 cm. After
passing through the diverging lens, the light focuses at a point 'A' 5 cm behind the lens. The position
of lens is then interchanged :-

(A) The value of L is 16 cm.

(B) The value of L is 80/3 cm.
(C) Point A is shifts by 40 cm after the lenses are interchanged.
(D) Point A is shifts by 125/3 cm after the lenses are interchanged.

6)

Choose the correct option(s) :-

(A) r.m.s. current drawn from the source is 30A

(B) r.m.s. current drawn from the source is
(C) average power loss in the circuit is 6kW
(D) average power loss in the circuit is zero.

SECTION-I (ii)

1) A uniform ring of mass m = 10 kg and radius R = 5 cm is kept at rest on a smooth horizontal

surface in vertical plane as shown in the figure. The ring carries a current i = 7 A. A constant
horizontal magnetic field B = 100 mT is switched on at t = 0. List-I describe the
statement regarding ring and and List-II gives their respective values.

List-I List-II

(I) The magnetic moment of loop in SI unit (P) 0.0880

Torque acting on loop due to magnetic field in SI

(II) (Q) 0.044
unit at t = 0

(III) Angular acceleration of loop in SI unit at t = 0 (R) 0.0055

Kinetic energy of ring when it has rotated through

(IV) (S) 0.4400
90°

(T) 0.0550
(A) I → T;II → R;III → S;IV → R
(B) I → P;II → Q;III → R;IV → S
(C) I → S;II → T;III → P;IV → Q
(D) I → T;II → S;III → P;IV → R

2) In the potentiometer arrangement shown in figure, null point is obtained at length .

List-I List-II

ℓ should increase for new null

(P) If E1 is increased (1)
point

ℓ should decrease for new null

(Q) If R is increased (2)
point

ℓ should remain same for new

(R) If E2 is increased (3)
null point

E1 must be increased to get null

(S) If E2 is decreased (4)
point at same length ℓ

E1 must be decreased to get null

(5)
point at same length ℓ
(A) P → 2;Q → 1;R → 4;S → 3
(B) P → 1;Q → 2;R → 2;S → 1
(C) P → 2;Q → 1;R → 1;S → 2
(D) P → 3;Q → 5;R → 4;S → 1

3) Consider the situation shown in diagram. Both capacitors are having same capacitance C.
Capacitors are initially uncharged. Switch K is closed at time = 0 & after a long time capacitors are
fully charged. Column-I represents value of r and Column-II represents charge passing through r

during complete charging process. Now match the followings :

(A) A → S;B → Q;C → R;D → P

(B) A → P;B → Q;C → R;D → S
(C) A → R;B → S;C → P;D → Q
(D) A → Q;B → P;C → R;D → S

4) Four identical metal plates with large surface areas are kept parallel to each other as shown in
the figure. Plate-1 has charge Q. Plate-3 has charge –2Q. Let the electric field is denoted
by List–I gives the four plates while list–II gives the magnitude of some quantity. The magnitude of

charge appearing on left surface in unit of Q is :-

List–I List–II
 (I) Plate–1 (P)

(II) Plate-2 (Q)

(III) Plate-3 (R) 3

(IV) Plate-4 (S) 1

(T) 2

(U)

(A) I → P;II → Q;III → Q;IV → P

(B) I → R;II → S;III → P;IV → T
(C) I → U;II → P;III → S;IV → Q
(D) I → T;II → U;III → P;IV → Q

PART 2 : CHEMISTRY

SECTION-II

1) The enthalpies of neutralization of a weak acid HA & a weak acid HB by NaOH are - 6900
Cal/equivalent & - 2900 Cal/equivalent respectively. When one equivalent of NaOH is added to a
solution containing one equivalent of HA & one equivalent of HB, the enthalpy change was - 3900
Calories. If base distributed between HA & HB in X : Y then find value of X+Y.

2) 50 mL of 0.1M CuSO4 solution is electrolyzed with a current of 0.965 A for a period of 200 sec.
The reactions at electrodes are: Cathode :
Cu2+ + 2e– → Cu(s) Anode : 2H2O → O2 + 4H+ + 4e.
Assuming no change in volume during electrolysis, calculate the decimolar concentration of SO42– at
the end of electrolysis.

3) If number of nearest neighbours, next nearest (2nd nearest) neighbour and next to next nearest
(3rd nearest) neigbhours are x,y and z respectively for body centered cubic unit cell, then calculate
value of xy/z

4) How many of the following compounds do not show any reaction with Br2, Na metal and H2CrO4.
5) The number of chiral centres in penicillin is ______.

6) In how many of the following direction of inductive effect is correctly shown.

(I) (II)

(III) (IV)

7)

Number of compounds which are optically inactive & can show optical isomerism.
8) The pKa values for the three acidic group P,Q,R are 4.3, 9.7 and 2.2 respectively

Calculate the isoelectric point of the amino acid ?

SECTION-I (i)

1) Correct statement among the following is/are :

(A) The rate of hydrolysis of tertiary butyl bromide increases by addition of Ag2O
–
(B) Aqueous Ag2O produces nucleophilic OH
(C) CH3CH2Cl is less reactive than PhCH2Cl for bimolecular nucleophilic substitution reaction

(D)
Rate of SN2 is

2) Possible options for A ?

(A)
(B)

(C)

(D)

3)

Which of the following statements is/are false

In [PtCl2(NH3)4]2+ complex ion, the cis-form is optically active, while trans-form is optically
(A)
inactive
3–
(B) In [Fe(C2O4)3] , geometrical isomerism does not exist, while optical isomerism exists
[Mabcd]n± square planar complexes exhibit both optical as well as geometrical isomerism (given
(C)
a,b,c,d ligands are optically inactive groups)
In [Mabcd]n± tetrahedral complexes, optical isomerism cannot be observed (given a,b,c,d
(D)
ligands are optically inactive groups)

4) Which is/are true about

(A) Hybridization of N is same

(B) Number of lone pair of electron on N are same
(C) Molecular geometry i.e. shape is different
(D) Bond angle order

5) Which of the following statements is/are correct?

First dissociation constant of maleic acid is higher than that of first dissociation constant of
(A)
fumaric acid
Second dissociation constant of fumaric acid is higher than that of second dissociation constant
(B)
of maleic acid
(C) pKa value of salicylic acid is higher than that of benzoic acid
(D) pKb of aniline is lower than that of o - toluidine

6) Colloidal Gold can be prepared by

(A) Bredig’s are method

(B) Reduction of AuCl3
(C) Hydrolysis
(D) Peptization

SECTION-I (ii)

1)

Match the following:

List–I List–II

Same number of unpaired electrons are

(P) (1) Na+, Mg2+, F¯
present in (excluding zero)

Same number of electrons in s & p

(Q) (2) F¯, Mg, O2–
subshells.

(R) Same number of electrons with the ℓ = 1 (3) Mg, Ne, O2–

(S) Same number of total electrons (4) Li, Na, K

(5) F, Cl , Br
(A) P → 1, 2,5;Q → 3, 4;R → 1;S → 4
(B) P → 4, 2;Q → 1, 3;R → 2, 3;S → 1, 4, 5
(C) P → 4,5;Q → 1;R → 1, 2, 3;S → 1
(D) P → 3,5;Q → 1, 2;R → 3, 4;S → 1, 3, 4

2)

List-I List-II
(Complex) (Related Isomerism)
3–
(P) [Co(SCN)4(NO2)2] (1) Ionisation Isomerism

(Q) [Pt(NH3)4] [CuCl4] (2) Coordination Isomerism

(R) [Co(NH3)4(NO3)Cl]Br (3) Hydrated Isomerim

(S) [Cr(H2O)6]Cl3 (4) Linkage Isomerism

(5) Coordination position isomerism

Which option is correct?
(A) P → 4;Q → 2;R → 1;S → 3
(B) P → 4;Q → 2;R → 1;S → 4
(C) P → 2;Q → 2;R → 1;S → 3
(D) P → 4;Q → 2;R → 4;S → 3
3) Alcohol
which is true about alcohol and Reagent?

List - (I) List - (II)

(Alcohol) (Reagent)

(A) (P) B2H6, H2O2/NaOH

Hg(OAc)2, H2O / NaBH4

(B) (Q)
followed by P.C.C.

(C) (R) Hg(OAc)2, H2O/NaBH4

(D) (S) dil. H2SO4

(T) Na/C2H5OH
(A) A → P;B → R;C → S;D → Q
(B) A → P;B → R;C → Q;D → T
(C) A → R;B → S;C → P;D → Q
(D) A → Q;B → S;C → T;D → R

4) Consider the following lists:

List - I List - II

(P) CH2 = CH–CHO (1) Acetal

(Q) C6H5CHO +Ph –NH2 (2) Schiff’s base

C6H5COCH3 + CH3–CH2–NH –CH3

(R) (3) Alcohol

(S) RCHO + 2RCH2OH (4) Enamine

(5) Oxime
(A) P → 3;Q → 2;R → 4;S → 1
(B) P → 5;Q → 2;R → 4;S → 1
(C) P → 3;Q → 5;R → 4;S → 1
(D) P → 3;Q → 2;R → 5;S → 1

PART 3 : MATHEMATICS

SECTION-II

1) Let . Area of region bounded by y = 0, x

= 0, x = 1 and y = (2x –1) f(x) is , then ‘a’ is

2) Let be differentiable in and f(1) =

1. Then the value of ea, such that f(a) = 0, is equal to

3) Let g1,g2,g3 : (0,∞) → R be defined by ,x>0

50 49
and g2(x) = 98(x – 1) – 100(x – 1) + 2450, x > 0
and g3(x) = (x – 1)2020(x – 2)2021(x – 3)2022, x > 0
Let αi and βi respectively denote the number of points of local minima and the number of points of
local maxima of the function gi, i = 1,2,3 in (0,∞) and if the value of α1β1 + α2β2 + α3β3 is λ then λ – 20

equal to (where )

4) Let T (t > 0) is a point on the curve C : y = . A circle S touches the curve C and the x-

axis. The centre of circle S is denoted by (x(t), y(t)). If then a is equal

to

5) Let Sk be the area bounded by the curve y = x2 (1 – x)k and the lines x = 0, y = 0 and x = 1 and

equals , (where p, q are co prime). Also . Then the value of

is equal to
6)
where m, n N and 'C' is constant of integration (g(x) > 0). Then the value of (m2 + n2) is

7) Let Then is

8) If x2 + ax + b = 0 has two distinct negative integral roots and

has no real solution. Then find the

minimum value of a.

SECTION-I (i)

1) If C1 and C2 are two concentric circles of radii 4 and 5 respectively with centre at origin. A
tangent is drawn to circle C2 at a given point 'P'. This tangent is the diameter of a variable circle C3,
which touches C1 externally. Also this tangent meet C3 in Q & R. If the diameter QR subtends a
constant non - zero angle at a fixed point T on line joining O & P. Then the locus of the point 'T' for
various positions of P on C2 is (where O is origin)

(A) x2 + y2 = 2
(B) x2 + y2 = 4
(C) x2 + y2 = 64
(D) x2 + y2 = 36

2) Consider a matrix if then

number of such 3-triples of (x, y, z) is(are) (where x ≠ y , y ≠ z, z ≠ x )

59
(A) C2 – 88 when x, y, z Natural number
59
(B) C2–85 when x, y, z Natural number
62
(C) C2 – 94 when x, y, z Whole number
62
(D) C2–91 when x, y, z whole number

3) Let S1 and S2 be two circles touching each other externally at R. Let ℓ1 be a line which is tangent
to S2 at P and passing through centre C1 of circle S1. Similarly let ℓ2 be a line which is tangent to S1
at Q and passing through centre C2 of circle S2. ℓ1 and ℓ2 are not parallel and intersect at K. If KP =
KQ, then
(A) P and Q lie on opposite sides of the line joining C1 and C2
(B) P and Q lie an same side of the line joining C1 and C2
(C) Triangle PQR is an equilateral triangle
(D) Triangle PQR is not necessarily an equilateral triangle

4) Let then which of the

following statement(s) is (are) correct?

(A) The number of points where y = f(x) is discontinuous is 1

(B) The number of points where y = |f(x)| is discontinuous is 1

(C)

(D) Number of solutions of f(x) = sgn(x) is infinite. (Where sgn(x) is the signum function of x)

5) Which of the following statement(s) is True?

(A) P(n): n2 – n + 41 is prime for every n ∈ N.

(B)
is rational.

(C)
simplifies to an integer.
5 –6 10
(D) Coefficient of x in (1 – x) is C6

6) Which of the following options are correct?

(A)

If a and b are two positive numbers such that then the maximum value of
(B)
is equal to 4

(C)
Constant term in is equal to 2
The coefficient of in

(D)

is equal to 2925

SECTION-I (ii)

1) Let P(x) be a non-constant polynomial function such that (x – 2010)P(x + 67) = xP(x) ∀ x∈R. A
represents the set of all real roots of P(x) = 0
A = {α1, α2, α3, … , αn}, where α1< α2< … < αn.
(α1 being the smallest root & αn being the largest root)

B= ,C=
([·] denotes the greatest integer function)

List-I List-II

(P) is greater than (1) 1

(Where n is the total number of real roots)

(Q) (2) 2
is less than

(R) (3) 3
is less than or equal to
(S) [C] is greater than or equal to (4) 5
(5) 15
(A) P → 1,2,3;Q → 4,5;R → 2;S → 1,2
(B) P → 1,2;Q → 5;R → 3,4,5;S → 1,2
(C) P → 1,2,3;Q → 4,5;R → 3,4;S → 1,2
(D) P → 1,2,4;Q → 3;R → 4,5;S → 2,3

2)

List-I List-II

(P) (1) 2
, equals (where [ ] denotes greatest
integer function)

(Q) If (where [ ] denotes greatest integer (2) 9

function), then the value of f(α), where α is the number of value of x
satisfying the equation 2x + 3x + 4x + 5x – 7x = 0,

(R) (3) 0
If m = then [m] + 5 is equal to
(where [ ] denotes greatest integer function)

If then
(S) (4) 7

equals
(where [ ] denotes greatest integer function)

(5) 1
(A) P → 2;Q → 3;R → 5;S → 4
(B) P → 3;Q → 5;R → 2;S → 1
(C) P → 3;Q → 1;R → 2;S → 4
(D) P → 2;Q → 5;R → 3;S → 4

3) Let S1 ≡ [f(x)]1/3 – [f(y)]2/3 = 0 and S2 ≡ [f(x)]2/3 + [f(y)]2/3 = 12 be two curves, satisfying the relation
[f(x + y) – f(x – y)]x – [f(x – y) + f(x + y)]y = 4xy(x2 – y2)

List-I List-II

(P) (1)
is equal to

(Q) Area bounded by S1 and S2 is (2)

Area bounded by S2
(R) (3) 12π – 24
|x| + |y| = is

(S) Area bounded by S1 and y = x is (4)

(5)
(A) P → 4;Q → 3;R → 1;S → 4
(B) P → 4;Q → 1;R → 3;S → 2
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 2;Q → 3;R → 1;S → 4

4) Let ƒ : and g : be functions defined by and

Let a, b, c, d ∈ . Define the function h : by

h(x) = a f (x) +
Match each entry in List-I to the correct entry in List-II.

List-I List-II

(P) If a = 0, b = 1, c = 0 and d = 0, then (1) h is one-one.

(Q) If a = 1, b = 0, c = 0 and d = 0, then (2) h is onto.

(R) If a = 0, b = 0, c = 1 and d = 0, then (3) h is differentiable on

(S) If a = 0, b = 0, c = 0 and d = 1, then (4) the range of h is [0, 1].

(5) the range of h is {0, 1}.

The correct options is
(A) P → 4;Q → 3;R → 1;S → 2
(B) P → 5;Q → 2;R → 4;S → 3
(C) P → 5;Q → 3;R → 2;S → 4
(D) P → 4;Q → 2;R → 1;S → 3
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-II

Q. 1 2 3 4 5 6 7 8
A. 2.00 2.00 4.00 1.41 32.00 6.00 6.00 4.00

SECTION-I (i)

Q. 9 10 11 12 13 14
A. A,C B,C C A,B,D A,C A,C

SECTION-I (ii)

Q. 15 16 17 18
A. A C A A

PART 2 : CHEMISTRY

SECTION-II

Q. 19 20 21 22 23 24 25 26
A. 4.00 1.00 4.00 5.00 3.00 3.00 4.00 3.25

SECTION-I (i)

Q. 27 28 29 30 31 32
A. A,B,C A,C,D A,C,D A,C,D A,B,D A,B

SECTION-I (ii)

Q. 33 34 35 36
A. C A A A

PART 3 : MATHEMATICS

SECTION-II

Q. 37 38 39 40 41 42 43 44
A. 4.00 2.00 9.00 5.00 11.00 8.00 1.00 5.00

SECTION-I (i)

Q. 45 46 47 48 49 50
A. B,C B,D B,C C,D B,C A,B,D
 SECTION-I (ii)

Q. 51 52 53 54
A. B B C C
 SOLUTIONS

PART 1 : PHYSICS

1)

Explain Question: We have to find torque acting on this disc.

Concept: Torque due to magnetic field.
Solution:

E × 2πx =

= Final Answer: 2

2)

Explain Question: We have to find minimum value of coefficient of friction for pure rolling.
Concept: Dynamics of CRTM
Solution:

10 – f = 1 a f = μN

fR = N = 20

f=4 μ=
Final Answer: 2

3)

Explain Question: We have to find time for which external force required to move the
conductor with given acceleration.
Concept: Motional EMF
Solution:
So

Final Answer: 4

4)

Explain Question: We have to find ratio of wavelength

Concept: D-Broglie wavelength
Solution:

KE = TE - PE

KE =

Final Answer: 1.41

5)

Explain Question: We have to find total angle of deviation in degree.

Concept: Refraction.
Solution:

θ = 37°
δ = 2(53 – 37) = 32°
Final Answer: 32

6)

Explain Question: We have to find radius of curvature of the orbit at point A & B.
Concept: Radius of curvature & properties of ellipse.
Solution:

From property of ellipse

a – ae = r0
a + ae = r1

a=

e=

Radius of curvature = = =
α=6
Final Answer: 6

7)

Explain Question: We have to find value of where = minimum force required

to keep the block at rest & is force required to move block with constant velocity.
Concept: Friction
Solution:

⇒ F1 = 12g – (µF + µF) = 90

⇒ F2 = 12g + (µF + µF) = 150
Require value

⇒ = =6
Final Answer: 6

8)

Explain Question: We have to find angle of inclination of string from vertical, when
acceleration is a
Concept: Buoyant force & acceleration of fluid
Solution:

Let the density of gas and water by ρg and ρw.

The volume enclosed by balloon is V.
Then the FBD of balloon is as shown
In equilibrium

Final Answer: 4

9)
 Explain Question: We have to find velocity of projection relative to surface to escape the
planet.
Concept: Escape velocity
Solution:

Mass of planet is

M= × 4πr2dr
M = πp0R3

(A)

0
(C) = πGP R

(D)

Final Answer: Option (A, C) is Correct.

10)

Explain Question: We have to find frequency of oscillating & velocity of wave

Concept: Kundt's tube expreiment.
Solution:

Distance between heaps = (inside tube)

from vair = fair λair , f = 330 Hz

in rod, open end is antinode, ∴

Final Answer: Option (B, C) is Correct.

11)

Explaining the Question :-We are given balloon and man is at rest and in equilibrium. If the
man starts climbing and reaches at the top of rope, Choose the correct statement(s)
Concept:
This question is based on Motion of COM.
Solution:
(Δx)centre of mass = 0

mL – mx = Mx

mL = x(M + m) ⇒

x = descend of balloon
ascend o man = L – x

= =
∵ man ascends by L – x
∴ his potential energy increases by mg(L – x)

and (ΔPE)balloon = mg(–x)

ΔPETotal = 0

Final Answer:
The correct option is (3)

12)

Explain Question: We have to find electric current I1 & I2 in given circuit.

Concept: Electric Circuit
Solution:

Req = 2Ω [All 3 resistances are in parallel]

So total current = = 12 Amp.
Final Answer: Option (A, B, D) is Correct.

13)

Explain Question: We have to find distance between lenses for given conditions.
Concept: Image friction & combination of lenses.
Solution:

E2 :
∴ u2 = +4 cm
∴ L = 16 cm
Final Answer: Option (A, C) is Correct.

14)

Explain Question: We have to find r.m.s. current drawn & average power loss in the circuit.
Concept: Current in ac circuit, power in ac circuit.
Solution:

Phase of 1st circuit =

Similarly phase of 2nd circuit is also zero.
∴ Equation of current is i = i1 + i2

∴ irms = 30 A
Pavg = 30 × 200 = 6000 = 6 kW.
Final Answer: Option (A, C) is Correct.

15) Explain Question: We have to find magnetic moment, torque, angular acceleration and
kinetic energy of ring.
Concept: Torque acting on loop due to magnetic field.
Solution:
(P) Magnetic moment = iA = i (πR2)

(Q) τ = M × B
(R) = Iα

(S) KE = MB = 0.0055 J

Final Answer: (A)

16) Explain Question: We have to find variation of length with change in E1, E2 and
resistance R
Concept: Potentiometer
Solution:

Potential gradient
E2 = (X)

(P) If E1 , X , ↓
(Q) If R , X ¯,
(R) If E2 ,

Final Answer: (C)

17) Explain Question: We have to find charge passing through the resistance r in various
conditions
Concept: R-C circuit
Solution:

= 2 CV Now Let = q and

Now applying loop rule 2I1 R = rx + R ( I–I1)

3I1 = x+I
 3 q1 = q + 2CV (i)

Also (I1+x) dt = CV
∴ q1 + q = CV (ii)

Final Answer: (A)

18) Explain Question: 4 conducting plates are given

Concept: Basics of conductors
Solution:

Charge on outer plates =

Charge on facing plates are equal and opposite

Final Answer: (A)

PART 2 : CHEMISTRY

19) Question Explanation: Calculate the amount of base distributed between HA & HB
Concept: Apply concept of neutralization
Solution:
HA + NaOH → NaA + H2O ; ΔH = – 6900 cal / eg
HB + NaOH → NaB + H2O ; ΔH = – 2900 cal / eg
Let x eq of NaOH react with HA and y eq NaOH react with HB
x+y=1
(– 6900 x) + (–2900 y) = –3900
∴ x = 1/ 4
y = 3/4
x : y = 1: 3
X+Y=1+3=4
Final Answer: (4.00)

20) Question Explanation: calculate the decimolar concentration of SO42– at the end of
electrolysis
Concept: Concept of electrochemical series
Solution:
ion is present in solution; no electrolysis of

Decimolar concentration of
Final Answer: (1.00)

21) Question Explanation: Calculate the value of xy/z for BCC

Concept: Chracterstics of BCC crystals
Solution:
In BCC

Nearest Neighbour ( at distance) x = 8

Next nearest Neighbour (at a distance) y = 6
Next to next nearest Neighbour (at distance) z = 12

Answer :
Final Answer: (4.00)

22) Question Explanation: Identify compounds which do not show any reaction with Br2, Na
& H2CrO4
Concept: Alkene reacts with bromine.
compounds having acidic hydrogen react with sodium metal.
primary and secondary alcohol can be oxidized with chromic acid.
Solution:
Alkene reacts with bromine.
compounds having acidic hydrogen react with sodium metal.
primary and secondary alcohol can be oxidized with chromic acid.
(a) ,(c), (e), (f), (k)
(005)
Final Answer: (5.00)

23) Question Explanation: Find total chiral centres in penicillin

Concept: Structure of penicillin
Solution:

Final Answer: (3.00)

24)

Explain Question :
The number of compound having correct direction of inductive effect

Concept :
This question is based on Inductive effect.

Solution :
There are two type of inductive effect
(1) Electron-Withdrawing Inductive Effect (–I Effect):
Electrons are pulled away from the rest of the molecule.
Direction: Toward the electronegative atom/group.
(2) Electron-Donating Inductive Effect (+I Effect):
Electrons are pushed toward the rest of the molecule.
Direction: Away from the donating group (i.e., into the chain).
1. In structure (i):
─CH₃ (+I), ─Ph (─I)
→ Direction of inductive effect is correct.
2. In structure (ii):
─COOH (─I)
→ Direction of inductive effect is correct.
3. In structure (iii):
─COO⁻ (+I)
→ Direction of inductive effect is correct.
4. In structure (iv):
Ketone is a ─I group
→ Direction of inductive effect is incorrect.

Final Answer:
The correct option is (3).

25)

Explaining the Question :-

Question is asking about the optical inactive molecules can show optical isomerism
Concept:-
This question is based on definition of optical isomers and meso compounds.
Solution :-
Meso compound is optically inactive but one of its stereoisomer is chiral. Therefore select the
meso compounds to answer this question.
Total meso compounds are = 4 [i, iv, vii, viii]
* Compounds i, iv and vii have plane of symmetry and viii has center of symmetry.
Final Answer :- (4)

26) Question Explanation:

Calculate the isoelectric point (pI) of Glutamic acid given its three pKa values (P = 4.3,Q =
9.7,R = 2.2).

Concept:
pI calculation for an acidic amino acid.

Solution:

I.P. = = = 3.25
Final Answer: (3.25)

27) Question Explanation: Identify correct statement

Concept: Mechanism of hydrolysis, nucleophilic addition and nucleophilic substitution
reaction
Solution:
(A) due to easier removal of Br– in presence of Ag2O
(B) Aq. Ag2O → H2O + Ag2O → 2AgOH
Final Answer: (ABC)

28) Question Explanation: Identify reactant 'A' on the basis of properties of B & C
Concept: 'B' is carbonyl compound
Solution:

Final Answer: (ACD)

29) Question Explanation: Identify true & false statements.

Concept: Apply concept of stereoisomerism for co-ordination compounds.
Solution:
Final Answer: (ACD)

30)

Question Explanation: Identify true statements about given ions.

Concept: Concept of hybridisation & VBT
Solution:

Final Answer: (ACD)

31)

Question Explanation: Identify the correct statements

Concept: Compare the Ka of maleic & fumaric acid
Solution:
of maleic acid > of fumaric acid (After loosing 1 H+, anion of maleic acid become more
stable due to intramolecular H-bonding
 of fumeric acid > of maleic acid
Salicylic acid is more acidic than benzoic acid due to o-effect.
o-toluidine is less basic than aniline due to SIP.
Final Answer: (ABD)

32) Question Explanation: A colloidal gold prepared by which methods.

Concept: Colloidal gold can be prepared by Bredig's Arc method and reduction of AuCl3 by
formaldehyde solution.
Solution:
Colloidal gold can be prepared by Bredig's Arc method and reduction of AuCl3 by
formaldehyde solution.
2AuCl3 + 3HCHO + 3H2O → 2Au + 3HCOOH + 6HCl
(sol)
Final Answer: (AB)

33) Question Explanation: Identify correct match with given properties.

Concept: Apply concept of quantum no. and filling of electrons.
Solution:
no. of electrons having ℓ = 1 in Mg ⇒ 6
no. of electrons having ℓ = 1 in Mg2+ → 6
no. of electrons having ℓ = 1 in Na⊕ → 6
no. of electrons having ℓ = 1 in F ⇒ 6
no. of electrons having ℓ = 1 in O–2 ⇒ 6
no. of electrons having ℓ = 1 in Ne ⇒ 6
no. of electrons having ℓ = 1 in K ⇒ 12
Final Answer: (C)

34) Question Explanation: Find the correct match of complex with type of isomerism.
Concept: Apply concept of type of isomerism for co-ordination compounds.
Solution:
(P) [Co(SCN)4(NO2)2]3– show linkage isomerism because it have SCN– & are ambidentate
ligands.
(Q) [Pt(NH3)4] [CuCl4] → shows co-ordination isomerism
(R) [Co(NH3)4 (NO3)Cl]Br → shows ionisation isomerism because it can give different ions in the
solution
(S) [Cr(H2O)6]Cl3 → shows hydrated isomerism
Final Answer: (A)

35) Question Explanation: Identify the correct reagent which brings out the following
change in given compound.
Concept: Preparation of alkene by using alcohol as substrate.
Solution:
(A) → P Syn addition, Antimarkanikav (HBO)
(B) → R Anti addition, markonikav rule (OMDM)
 (C) → S

(D) → Q
Final Answer: (A)

36) Question Explanation: Identify the correct match of product with its common name
Concept: Preparation of alcohol, Enamine, and acetal.
Solution:

(I)

(II) C6H5CH = O + H2N – Ph

(III)

(IV)
Final Answer: (A)

PART 3 : MATHEMATICS

37) Explain Question : Area of region bounded by y = x, x = 0, x = 1 and y = (2x - 1) f(x).

Concept : Area under curve.
Solution :
Required area =

Final Answer : (4.00)

38) Explain Question : To solve homogenous differential equation.

Concept : Homogenous differential equation.
Solution :
f(1)=1, f(a) = 0

Put

Integrating both side

ev (x + c) + 1 + v = 0

x = a, y = 0 ⇒
ae = 2
Final Answer : (2.00)

39) Explain Question : To find maxima and minima.

Concept : Maxima - minima.
Solution :

g′1(x) = (x – 1)1 (x – 2)2 (x – 3)3 ... (x – 19)19

α1 = {19, 15, 11, 7, 3} = 5
β1 = {17, 13, 9, 5, 1} = 5
g′2(x) = 98 × 50(x – 1)49 – 100 × 49(x – 1)48
= 4900 (x – 1)48 (x – 1 – 1)
= 4900 (x – 1)48 (x – 2)
α2 = 1
β2 = 0

g3(x) = (x – 1)2020 (x – 2)2021 (x – 3)2022

[2020(x – 2) (x – 3) + 2021(x – 1) (x – 3) + 2022(x – 1) (x – 2)]

2019 2020
= (x – 1) × (x – 2) × (x – 3)2021 × 60633x2 – 24250x + 22227]

α3 = 2
β3 = 2
∴ λ – 20 = α1β1 + α2β2 + α3β3 – 20
= 25 + 0 + 4 – 20 = 9
Final Answer : (9.00)

40) Explain Question : To find for given.

Concept : Integration, circle and parabola.
Solution :
 Final Answer : (5.00)

41) Explain Question : Definite integration.

Concept : Definite integration.
Solution :
Now,

⇒ (p + q) = 7. Ans.

; Put, x – 1 = t2 ⇒ dx = 2t dt

Hence, = 4. Ans.
Final Answer : (11.00)

42) Explain Question : Indefinite integration.

Concept : Indefinite integration.
Solution :
Hence m = 2 , n = 2
m2 + n2 = 8 Ans.]
Final Answer : (8.00)

43)

44) Explain Question : To find minimum value of 'a' for given.

Concept : Quadratic, logarithmic and ITF.
Solution :

Let

So p2 + ap + b = 0, where
Now it given that equation p2 + ap + b = 0 has no real solution so the roots of x2 + ax + b
= 0 should no lie in range of p.
So if x1, x2 are roots of x2 + ax + b = 0 then these should not lie in the range of p.
 x1, x2 ∉ range of

As x1, x2 both are (negative) integral roots and

, so x1, x2 ∈ (–∞, –2]

now, a = –(x + x2)
amin = –(max of (x1 + x2))
∴ max of x1 + x2 = –2 – 3 = –5
amin = –(–5) = 5
Final Answer : (5.00)

45) Explain Question : Circles

Concept : Circles

Solution : tanθ =
Now, a2 + 25 = (r + 4)2
a2 = r2 – 9 + 8r
(b – 5)2 = 9
Final Answer : (B,C)

46) Explain Question : To find adjoint of matrix.

Concept : Adjoint of matrix.
Solution :

Given matrix Applying R3 → R3 + R1

x + y + z = 22.3.5
x + y + z = 60
Case-I When
then (x – 1) + (y – 1) + (z – 1) = 60
x + y + z = 57
Number of all triples = 59C2
When and distinct

Case-II When
x + y + z = 60
Number of all such triples = 62C2
When and distinct

Final Answer : (B,D)

47) Explain Question : Line and circle.

Concept : Line and circle.
Solution :

Let us suppose that P and Q lie on opposite sides of line joing C1 and C2
then KP > KC1 > KQ which is contradiction
⇒ P and Q lie on same side of line joining C1 and C2. Since KP = KQ ⇒ K lies on radical axis.

Since KR = KP = KQ ⇒ K is circum centre of ΔPQR also KP ⊥ QR and KQ ⊥ PR ⇒ K is

orthocentre
⇒ ΔPQR is equilateral Δ.
Final Answer : (B,C)

48) Explain Question : Discontinuity of function.

Concept : Discontinuity of function.
Solution :

Let

(A) f(x) is discontinuous at

(B) |f(x)| is continuous function
Final Answer : (C,D)

49) Explain Question : Binomial and special sequences.

Concept : Binomial and special sequences.
Solution :
(A) For n = 41, P(n) is not prime.

(B) We have
= (eln 2 – 1) + (eln 4 – 1) = 1 + 3 = 4
⇒ (B) is correct

(C) We have ∞

∴ Tn = = = =
5 –6 10
(D) Coefficient of x in (1 – x) = C5.
⇒ (D) is not correct
Final Answer : (B,C)

50) Explain Question : Summation of binomial series.

Concept : Summation of binomial series.
Solution :
 Final Answer :
(A,B,D)

51) Explain Question : Roots of a polynomial function.

Concept : Roots of a polynomial function.
Solution :
(x – 2010)P(x + 67) = xP(x) ∨ x∈R
(x – 30·67)P (x + 67) = xP(x)
at x = 0 → P(67) = 0 → ∴ x = 67 is a root
at x = 67 → P(2·67) = 0 → ∴ x = 2·67 is a root
similarly
at x = 30·67 → P(30·67) = 0 → ∴ x = 30·67 is a root
∴ P(x) = (x – 67)(x – 2·67) … (x – 30·67) Q(x)
Where Q(x) is an unknown polynomial
P(x + 67) = x(x – 67) … (x – 29·67) Q(x + 67)
x(x – 67) … (x – 30.67)Q(x + 67) = x(x – 67) … (x – 30·67)Q(x)
∨ x∈R
∴ Q(x) = Q(x+67) ∨ x∈R
∴ Q(x) = K (some non-zero arbitrary constant)
∴ P(x) = K(x – 67) (x – 2·67) … (x – 30·67)
∴ α1 = 67, α2 = 2·67, … αn = 30·67

∴ n = 30, B = =

= 7.75, C = = 2, =3
Final Answer : (B)

52) Explain Question : Different parts of match the column related to definite integration.
Concept : Definite integration.
Solution :

(P)

(Q)

= [x]
Now no. of values of real 'x' satisfying 2x + 3x + 4x + 5x = 7x divide by 7x

we get
Clearly only one value of 'x' satisfies the given equation.

(R)
(S)
Since –1 < x < 0 we can see that [x] = [x3] = [x5] = –1 and [x2] = [x4] = [x6] ...... = 0

So

So

Also .............(1)

applying king property

............(2)
Adding equation (1) and (2)

[I] = –2
So 0 – (–2) = 2
Final Answer : (B)

53) Explain Question : Given two curve to find area bounded by curve in different condition.
Concept : Area bounded by curve.
Solution :
Final Answer : (C)

54) Explain Question : Given two function for match the column, to find nature of h(x) for
different conditions.
Concept : Functions, differentiability.
Solution :

(P) Now a = 0, b = 1, c = 0, d = 0
∵

Hence Range of h(x) is {0, 1}

(Q) a = 1, b = 0, c = 0, d = 0

h(x) =

RHD =

LHD =
Hence h(x) is differentiable on R
(R) a = 0, b = 0, c = 1, d = 0

h(x) = x – g(x)

∴ h(x) is ONTO
(S) a = 0, b = 0, c = 0, d = 1

h(x) = g(x)

Range of h(x) is [0, 1]

Final Answer : (C)