08-01-2025

6051CJA8011642410A3 JA

PHYSICS

SECTION-I (i)

1) A horizontal plank has a rectangular block placed on it. The plank starts oscillating vertically and
simple harmonically with an amplitude of 40 cm. The block just loses contact with the plank when
the latter is at momentary rest. Then :

(A)
the period of oscillation is
the block weighs double of its true weight, when the plank is at one of the positions of
(B)
momentary rest
(C) the block weighs 0.5 times its true weight on the plank halfway up.
(D) the block weighs 1.5 times its true weight on the plank halfway down.

2) A solid sphere of radius R and density ρ is attached to one end of a mass-less spring of force
constant k. The other end of the spring is connected to another solid sphere of radius R and density
3ρ. The complete arrangement is placed in a liquid of density 2ρ and is allowed to reach equilibrium.
The correct statement(s) is (are) :

the net elongation of the spring is

(A)

(B)
the net elongation of the spring is
(C) the light sphere is partially submerged
(D) the light sphere is completely submerged

3) A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in
equilibrium at temperature T. Assuming the gases are ideal, the correct statement(s) is (are) :-

(A) The average energy per mole of the gas mixture is 2RT.
(B) The average energy per mole of the gas mixture is 3RT
(C) The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2.
(D) The ratio of the rms speed of helium atoms to that of hydrogen molecules is .

4) A uniform rod of mass m, length ℓ, area of cross-section A and Youngs modulus Y is pulled by a
force F = mg on a rough table (µ = 0.5). Choose the INCORRECT option(s).

(A)
Strain at mid point of rod is .
(B)
Elastic potential energy density at mid point is .
(C) Acceleration of rod is g/2.

(D)
Stress at distance ℓ/4 from end, where force is applied, is .

5) n drops of a liquid, each with surface energy E, joining to form a single drop

(A) some energy will be released in the process

(B) some energy will be absorbed in the process
(C) the energy released or absorbed will be E(n – n2/3)
(D) the energy released or absorbed will be nE(n2/3 – 1)

6) When m gm of water at 10°C is mixed with m gm of ice at 0°C, which of the following statements
are false?

The temperature of the system will be given by the equation m × 80 + m × 1 × (T – 0) = m × 1

(A)
× (10 – T)
(B) Whole of ice will melt and temperature will be more than 0°C but lesser than 10°C
(C) Whole of ice will melt and temperature will be 0°C
(D) Whole of ice will not melt and temperature will be 0°C

7) Select the correct statement (s) :

(A) r.m.s. speed of 8 gm oxygen gas in container at 27°C is approximately 484 m/s
(B) r.m.s. speed of 8 gm oxygen in container at 27°C is approximately 968 m/s
(C) For number of molecules greater than one, r.m.s. speed is greater than average speed
(D) A gas behaves more closely as an ideal gas at low pressures and at high temperatures

SECTION-I (ii)

Common Content for Question No. 1 to 2

Answer appropriately matching the information given in the three columns of the
following table.
The Doppler effect (or the Doppler shift) is the change in frequency or wavelength of a wave for an
observer who is moving relative to the wave source. The total Doppler effect may result from motion
of the source, motion of the observer and the motion of the medium
Now consider the situation of a moving source , moving observer and moving medium ( ).

Speed of sound is 330 m/s relative to medium.

Column–1 Column-2 Column-3

(I) (i) (P)

 (II) (ii) (Q)

(III) (iii) (R)

(IV) (iv) (S)

1) In which case, will the ratio of frequency received by observer and frequency emitted by source

is greater than 1.

(A) (IV)-(iii)-(R)
(B) (IV)-(i)-(S)
(C) (III)-(iii)-(R)
(D) (II)-(ii)-(S)

2) In which case, will the ratio of frequency received by observer and frequency emitted by source

(A) (I)-(i)-(P)
(B) (I)-(iii)-(P)
(C) (III)-(i)-(Q)
(D) (III)-(iii)-(Q)

3) In which case the ratio of wavelength received by observer and wavelength emitted by source
equal to one?

(A) (II)-(iv)-(R)
(B) (III)-(ii)-(Q)
(C) (II)-(i)-(P)
(D) None of these

Common Content for Question No. 4 to 5

Answer questions by appropriately matching the information given in the three columns of
the following table.
In a container of negligible mass equivalent column-1 has mixture of contents and in Column-2 the
value of equilibrium temperature of mixture and in column-3 the amount of water at equilibrium
temperature (Take standard values of specific & latent heats)
(Take specific heat of steam to be 0.5 cal/g°C)
Column-1 Column-2 Column-3
(in °C) (in gram)
(I) 20g steam at 100°C passes (i) 100 (P) 113
into 103 g of water at
47.5° C initially.
(II) 10 g steam at 110°C passes with (ii) 80 (Q) 123
113 g water at 30°C
(III) 100 g ice at –20°C mix with 100 g (iii) 0 (R) 190
of water at 82°C
(IV) 38 g steam at 120° C pass into (iv) 50 (S) 198
 160 g ice at –25°C

4) In container 38g steam at 120°C pass into 160g ice at –25°C then :

(A) (IV) (i) (R)

(B) (IV) (ii) (S)
(C) (IV) (iv) (S)
(D) (IV) (i) (Q)

5) If the amount of water at equilibrium temperature will be 113gm (approx), then :

(A) (I) (i) (P)

(B) (II) (i) (P)
(C) (IV) (iii) (P)
(D) (III) (iii) (P)

6) If the final temperature becomes 100°C then :

(A) (IV) (i) (Q)

(B) (I) (i) (P)
(C) (I) (i) (R)
(D) (II) (i) (Q)

SECTION-II

1) If the average power of wave-1 and wave-2 is P1 and P2 respectively. Then find the value of .
Assume that the strings carrying the waves are identical.
y1 = 3.0 sin (3.2t – 200x) cm
y2 = 6.0 sin(0.4t – 25 x) cm

2) A thin ring of volume mass density ρ, cross-sectional area A, radius R and young's modulus of
elasticity E, is rotated about an axis passing through its centre with angular velocity ω. If increase in

cirumference (assumed small) is Find a.

3) A particle performing linear SHM with time period T is at x = moving towards positive

extreme. The time after which it will first come to rest is . Find N.

4) A U tube filled with a liquid is accelerating horizontally with an acceleration a. The acceleration of
the tube in m/s2 is _______

(Take : g = 10 m/s2) :-

5) Three uniform rods of lengths ℓ, 2ℓ and 3ℓ, masses m, 2m and 3m and coefficient of linear
expansion α, 2α and 3α are placed in contact on a smooth horizontal surface as shown in figure. The
temperature of the system is increased by T. By what distance (in mm) the point B will move ? (Take

ℓαT = mm, ℓ = 1m)

CHEMISTRY

SECTION-I (i)

1) A buffer solution can be prepared from a mixture of

(A) NH4Cl and NaOH in 2 : 1 mole ratio.

(B) CH3COONa and HCl in 1 : 1 mole ratio.
(C) CH3COONa and HCl in 2 : 1 mole ratio.
(D) CH3COONa and HCl in 1 : 2 mole ratio

2) Which is/are correct statement(s) about the solubility of Given: Ksp(AgC ) = 10–10,
Kf[Ag(NH3)2+] = 108.

(A) Solubility of in 2M NH3 is 0.166 M

(B) Solubility of in 2M AgNO3 is 5 × 10–11 M
(C) Solubility of in 2M KBr is 10–5 mol/L
(D) Solubility of in pure water is 10–5 g/L

3) Consider the following four compounds I, II, III, and IV.

Choose the correct statement(s).

(A) The order of basicity is II > I > III > IV.

(B) The magnitude of pKb difference between I and II is more than that between III and IV.
(C) Resonance effect is more in III than in IV.
(D) Steric effect makes compound IV more basic than III.

4) With respect to the compounds I-V, choose the correct statement(s).

(A) The acidity of compound I is due to delocalization in the conjugate base.

(B) The conjugate base of compound IV is aromatic.
(C) Compound II becomes more acidic, when it has a -NO2 substituent.
(D) The acidity of compounds follows the order I > IV > V > II > III.

5) Which of the following compound has wrong IUPAC name?

CH3 – CH2 – CH2 – COOCH2CH3

(A)
Ethyl butanoate

(B)

(C)

(D)

6) Which of the following statement(s) is/are correct for given compound :

(A) It is a optically active compound
(B) It can show geometrical isomerism
(C) It posses centre of symmetry but not plane of symmetry
(D) It is a optically inactive compound

7) Which of the following compounds are optically active ?

(A) [Link].CH2.CH3
(B) H2C=[Link]=CH2

(C)

(D)

SECTION-I (ii)

Common Content for Question No. 1 to 2

Match List-I, II, III with each other :

List - I List - II List - III

(A) (1) (i) (2R, 3R)

 (B) (2) (ii) (2S,3S)

(C) (3) (iii) (2S,3R)

(D) (4) (iv) (2R,3S)

1) Which of the following is the correct match?

(A) A-(4); B-(ii); C-(3); D-(iv)

(B) A-(4); B-(iv); C-(3); D-(i)
(C) A-(4); B-(i); C-(3); D-(ii)
(D) A-(4); B-(ii); C-(3); D-(iii)

2) What is the relation between A and B?

(A) Enantiomers
(B) Meso
(C) Identical
(D) Diasstereomers

3) Correct configuration for Chiral carbons of compound D?

(A) 1R, 2R
(B) 2R, 3S
(C) 2R, 3R
(D) 2S, 3S

Common Content for Question No. 4 to 5

Match the column I with column II.

Column-I Column-II Column-III

(A) (P) Aromatic (i) Diamagnetic

 (B) (Q) Non-aromatic (ii) Paramagnetic

All electrons are

(C) (R) Anti-aromatic (iii)
paired

Unpaired electron
(D) (S) Cyclic structure (iv)
are present

4) Find the correct match

(A) A - P, S
(B) B - P, S
(C) C - Q, S
(D) D - Q, S

5) Which of the following is correct match for compound C is

(A) R, (i)
(B) Q, (ii)
(C) P, (i)
(D) S, (iv)

6) The compound which is unstable at room temperature

(A) A
(B) B
(C) C
(D) D

SECTION-II

1) 10 mL of H2A (weak diprotic acid) solution is titrated against 0.1 M NaOH. pH of the solution is
plotted against volume of strong base added and following observation is made.

If pH of the solution at first equivalence point is pH1 and at second

equivalence point is pH2.

Calculate the value of at 25°C

Given : For H2A, and , log 25 = 1.4
(Answer upto nearest integer)

2) The acid ionization (hydrolysis) constant of Zn2⊕ is 1.0 × 10–9 then the pH of a 0.001 M solution of
ZnCl2 is

3) Observe the following compound and write the number of hydrogen atom involved in
hyperconjugation?

4) How many geometrical isomers are possible with following structure :

CH3–CH=CH–CH=CH–CH=CH–CH3

5)
X = Total number of resonating structure of organic product M
Y = Molecular weight of N
then find (X - Y)

MATHEMATICS

SECTION-I (i)

1) For the hyperbola , the normal at P meets the transverse axis AA' in G & the conjugate
BB' in g and CF be perpendicular to normal from the centre then

(A) [Link] = CB2

(B) Locus of middle point of G & g is a hyperbola
(C) [Link] = CA2

(D)
Eccentricity of the locus of middle point of G & g is

2) A rectangular hyperbola whose centre is C is cut by any circle of radius r in four points P, Q, R
and S. Then CP2 + CQ2 + CR2 + CS2 =
 16 if r =
(A)

(B) 16 if r = 2
(C) 2 if r = 1
(D) 4 if r = 1

3) A normal is drawn to the ellipse If maximum radius of circle

centred at origin and touching the normal is 5. The possible value/values of a is/are

(A) 2
(B) 4
(C) –3
(D) –2

4) For the parabola y2 = 4(x – 4) -

(A)
product of slopes of the tangents drawn from origin is –

(B)
product of slopes of the tangents drawn from origin is

(C)
angle between tangents drawn from origin is

(D)
angle between tangents drawn from origin is

5) The equation ||z + i| – |z – i|| = k represents

(A) a hyperbola if 0 < k < 2

(B) a pair of ray if k > 2
(C) a straight line if k = 0
(D) a pair of ray if k = 2

6) For two data sets, each of size 5, the variances are given to be 4 and 5 the corresponding means
are given to be 2 and 4 respectively, then which of the following are correct :

(A) mean of combined data set is 3

(B) mean of combined data set is 5
(C) variance of combined data set is 5.5
(D) variance of combined data set is 4.5

7) The median and standard deviation of a distribution are 20 and 4 respectively. If each item is
increased by 2 then :

(A) median will be same

(B) median will increase by 2
(C) standard deviation will remain same
(D) variance will be same

SECTION-I (ii)

Common Content for Question No. 1 to 2

Column-1 Column-2 Column-3

(I) (i)
(P)

(II) (ii)
(Q)

(R)
(iii)
(III)

(S)
(IV) (iv)

1) The tangent to a suitable conic (Column 1) at is found to be , then which of

the following options is the only correct combination?

(A) (II) (iii) (R)

(B) (IV) (iv) (S)
(C) (IV) (iii) (S)
(D) (II) (iv) (R)

2) If a tangent to a suitable conic (Column 1) is found to be y = x + 8 and its point of contact is (8,
16), then which of the following options is the only correct combination?

(A) (III) (i) (P)

(B) (III) (ii) (Q)
(C) (II) (iv) (R)
(D) (I) (ii) (Q)

3) For , if a tangent is drawn to a suitable (Column 1) at the point of contact (-1,1), then
which of the following options is the only correct combination for obtaining its equation?

(A) (II) (ii) (Q)

(B) (III) (i) (Q)
(C) (III) (i) (P)
(D) (I) (ii) (Q)
Common Content for Question No. 4 to 5

Column-I Column-II Column-III

(I) (i) Circle

(P) radius =

(ii) Hyperbola
(II) (Q) eccentricity =

(III) (iii) Straight line

(R) eccentricity =

(S) square root of absolute

value of sum of intercepts on
(iv) Ellipse
(IV)
axes =

4) Find the correct match

(A) (I) (i) (P)

(B) (I) (iv) (Q)
(C) (I) (iii) (S)
(D) (II) (iv) (R)

5) Find the correct match

(A) (II) (iii) (S)

(B) (II) (ii) (Q)
(C) (II) (iv) (Q)
(D) (II) (i) (P)

6) Find the correct match

(A) (III) (ii) (Q)

(B) (III) (ii) (S)
(C) (III) (ii) (R)
(D) (IV) (i) (S)

SECTION-II

1) An ellipse and a hyperbola have the same centre origin, the same foci and the minor-axis of the
one is the same as the conjugate axis of the other. If e1, e2 be their eccentricities respectively, then

2) Radius of largest circle that can be inscribed in the parabola x2 = 4y and passing through its focus
is
3) Tangents are drawn from any point on the hyperbola to the circle x2 + y2 = 9. If the
locus of the mid-point of the chord of contact is 4(x4 + y4 + 2x2y2) = βx2 – γy2 then the value of (γ –
2β) is equal to

4) Let a conic is having the foci as (6, 8) & (5, 12). If this conic is passing through (0, 0) & its

possible eccentricities are e1, e2, then is equal to

5) Let α be a complex number satisfying the equations |z – 2| = 2 and . Then the area

of triangle formed by and 2 is

 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7
A. A,B,C,D A,D A,D A,B A,C A,B,C A,C,D

SECTION-I (ii)

Q. 8 9 10 11 12 13
A. A B C C A B

SECTION-II

Q. 14 15 16 17 18
A. 4.00 9.00 6.00 5.00 2.00

CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24 25
A. A,C A,B,C C,D A,B,C B,C B,C,D A,C,D

SECTION-I (ii)

Q. 26 27 28 29 30 31
A. A A C B C D

SECTION-II

Q. 32 33 34 35 36
A. 2.00 6.00 9.00 6.00 8.00

MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42 43
A. A,B,C,D B,D A,C A,C A,C,D A,C B,C,D

SECTION-I (ii)

Q. 44 45 46 47 48 49
A. D A D B A C
 SECTION-II

Q. 50 51 52 53 54
A. 2.00 4.00 9.00 2.00 2.00
 SOLUTIONS

PHYSICS

1) The position of momentary

rest in S.H.M. is extreme position where velocity of particle is zero.
As the block loses contact with the plank at this position i.e. normal force becomes zero, it has
to be the upper extreme where acceleration of the block will be g downwards.

∴ ω2A = g ⇒ ω2 = = 25 ⇒ ω = 5 rad/s

Therefore period T = = s
Acceleration in S.H.M. is given by a = ω2x
From the figure we can see that,At lower extreme, acceleration is g upwards
∴ N – mg = ma ⇒ N = m (a +g) = 2mg
At halfway up, acceleration is g/2 downwards

∴ mg – N = ma ⇒ N = m (g – ) = mg
At halfway down acceleration is g/2 upwards

∴ N – mg = ma ⇒ N = m (g + )= mg

2)
FB = mg

FB = 2ρ × πR3 =

mg = ρ × πR3 + 3ρ × πR3
3)

Total energy = = 4RT

average energy /mole = 2RT

4)
F – f = ma

At mid point

Stress

Strain =

Energy density = Stress × strain =

At

Stress =

5)
R = n1/3 r …(i)
Ei = 4πr2 × T
Ei = n4πr2 T
Ef = 4πR2 T

=
Hence n2/3 E < nE
Energy released = nE – n2/3 E
= E(n – n2/3).

6)

Heat required to melt ice = m × 80

Heat given by the water = m × 10 × 1 = 10m
Heat required to melt ice > Heat given by water so complete ice will not melt.

8) Frequency received observer (f0) is related to frequency emitted by source (f) as

& wavelength received by observer is

9) Frequency received observer (f0) is related to frequency emitted by source (f) as

& wavelength received by observer is

10) Frequency received observer (f0) is related to frequency emitted by source (f) as
& wavelength received by observer is

11)

Let the final temperature of mixture = 100°C

Heat required for water = 103 × 1 × (100 –47.5) = 5407.5
Let – m gram steam required for this
m × 540 = 5407.5
∴ m = 10 gm
So total amount of water = 103 +10=113 gm
For 100°, the required heat for water
= 113 × 1 × (100 – 30) = 7910 cal

Heat available by conversing steam into water = 10 × × 10 + 10 × 540

= 5450 cal (which is less then required)
So the final temperature will be not 100°C. Let it would be 'T'
Heat gain = heat loss
∴ 113 × 1 × (T – 30) = 5450 + 10 × 1 × (100 – T)
113T + 10T = 5450 + 1000 + 113 × 30

= 80°C
Let the temperature at equilibrium be 0°C
Heat required for ice

= 100 × × 20 + 100 × 80 = 9000 cal

Heat available from the
conversion of water from 82°C to 0°C
= 100 × 1 × 82 = 8200 cal
i.e. whole ice doe not convert into water
So final temperature will be = 0°C

Now the amount of water of ice converts into water will be = 90gm
So the total amount of water is a containes will be = 100 + 90 = 190 gm
Let the final temperature will be = 100°C
So heat required for ice upto 100°C water formation will be

= 160 × × 25 + 160 × 80 + 160 × 1 × 100

= 2000 + 12800 + 16000 = 30800 cal
Heat can be available from steam conversion will be

38 × × 20
= 38 × 540
Which is less than required
∴ Temperature can't be 100°C, so the final temperature would be = T

160 × × 25 + 160 × 80 + 160 × 1 × T

= 38 × 540 + 38 × 1 ×(100 –T)
14800 + 160 T = 20900 + 3800 – 38 T
198T = 9900
 ∴ T = 50°C

12) Let the final temperature of mixture = 100°C

Heat required for water = 103 × 1 × (100 –47.5) = 5407.5
Let – m gram steam required for this
m × 540 = 5407.5
∴ m = 10 gm
So total amount of water = 103 +10=113 gm
For 100°, the required heat for water
= 113 × 1 × (100 – 30) = 7910 cal

Heat available by conversing steam into water = 10 × × 10 + 10 × 540

= 5450 cal (which is less then required)
So the final temperature will be not 100°C. Let it would be 'T'
Heat gain = heat loss
∴ 113 × 1 × (T – 30) = 5450 + 10 × 1 × (100 – T)
113T + 10T = 5450 + 1000 + 113 × 30

= 80°C
Let the temperature at equilibrium be 0°C
Heat required for ice

= 100 × × 20 + 100 × 80 = 9000 cal

Heat available from the
conversion of water from 82°C to 0°C
= 100 × 1 × 82 = 8200 cal
i.e. whole ice doe not convert into water
So final temperature will be = 0°C

Now the amount of water of ice converts into water will be = 90gm
So the total amount of water is a containes will be = 100 + 90 = 190 gm
Let the final temperature will be = 100°C
So heat required for ice upto 100°C water formation will be

= 160 × × 25 + 160 × 80 + 160 × 1 × 100

= 2000 + 12800 + 16000 = 30800 cal
Heat can be available from steam conversion will be

38 × × 20
= 38 × 540
Which is less than required
∴ Temperature can't be 100°C, so the final temperature would be = T

160 × × 25 + 160 × 80 + 160 × 1 × T

= 38 × 540 + 38 × 1 ×(100 –T)
14800 + 160 T = 20900 + 3800 – 38 T
198T = 9900
∴ T = 50°C

13) Let the final temperature of mixture = 100°C

Heat required for water = 103 × 1 × (100 –47.5) = 5407.5
Let – m gram steam required for this
m × 540 = 5407.5
∴ m = 10 gm
So total amount of water = 103 +10=113 gm
For 100°, the required heat for water
= 113 × 1 × (100 – 30) = 7910 cal

Heat available by conversing steam into water = 10 × × 10 + 10 × 540

= 5450 cal (which is less then required)
So the final temperature will be not 100°C. Let it would be 'T'
Heat gain = heat loss
∴ 113 × 1 × (T – 30) = 5450 + 10 × 1 × (100 – T)
113T + 10T = 5450 + 1000 + 113 × 30

= 80°C
Let the temperature at equilibrium be 0°C
Heat required for ice

= 100 × × 20 + 100 × 80 = 9000 cal

Heat available from the
conversion of water from 82°C to 0°C
= 100 × 1 × 82 = 8200 cal
i.e. whole ice doe not convert into water
So final temperature will be = 0°C

Now the amount of water of ice converts into water will be = 90gm
So the total amount of water is a containes will be = 100 + 90 = 190 gm
Let the final temperature will be = 100°C
So heat required for ice upto 100°C water formation will be

= 160 × × 25 + 160 × 80 + 160 × 1 × 100

= 2000 + 12800 + 16000 = 30800 cal
Heat can be available from steam conversion will be

38 × × 20
= 38 × 540
Which is less than required
∴ Temperature can't be 100°C, so the final temperature would be = T

160 × × 25 + 160 × 80 + 160 × 1 × T

= 38 × 540 + 38 × 1 ×(100 –T)
14800 + 160 T = 20900 + 3800 – 38 T
198T = 9900
∴ T = 50°C

14) P ∝ A2w2
 15)

By Hook's law

a=9

16) x =

θ=

t=

17)
⇒ a = 5 m/s2

18)
∴ Displacement of COM of composite system in zero

∵
⇒ xA + 3xB + 5xC + 3xD = 0
⇒ xA + 3(xA + e) + 5(xA + 5e) + 3(xA + 14e) = 0

⇒ 12xA + 70e = 0 ⇒ Also,

xB = xA + e

CHEMISTRY
19)

20)

21)

pKb different between I and II is 0.53 and that of III and IV is 4.6.
So option (B) is incorrect
Correct Statement (C), (D)
The most basic compound in the given option is (II) and least basic compound is (III)
In 2,4,6-trinitro aniline (III) due to strong –R effect of –NO2 groups, the l.p. of –NH2 is more
involved with benzene ring hence it has least basic strength.
Whereas (IV) N,N-Dimethyl 2,4,6-trinitro aniline, due to steric inhibition to resonance (SIR)
effect; the lone pair of nitrogen is not in the plane of benzene, hence make it (l.p.) more free to
protonate
22)

(C) –NO2 is –I group (electron withdrawing group). It increases acid strength.

(D) Acid strength order : IV > V > I > II > III

23)
24)

COS present, POS absent, optically inactive

25)

A, C and D have no plane of symmetry as well as centre of symmetry. So they are optically
active.

32) H2CO3 + NaOH→NaHCO3 + H2O

pH1 =
N1V1 = N2V2
N1 × 10 = 0.1 × 20
N1 = 0.2
NaHCO3 + NaOH → Na2CO3 + H2O

= M

⇒ pH =

33) Kh = ⇒ x = [H⊕] =

[H⊕] = = 10–6 M
pH = 6

34)

35) symmetrical n = 3 (odd)

 ∴

36)

MATHEMATICS

37)
Equation of normal at P(a secθ, b tanθ) : ax cosθ + bycotθ = a2 + b2

So, and
equation of CF : bx cotθ – ay cosθ = 0

&
∴ [Link] = b2 = CB2 ...(A)

Now,
∴ [Link] = CA2 ...(B)
Mid point of G & g is : (h,k) =

∴ sec2θ – tan2θ = 1

Locus of (h,k) ...(C)

eccentricity ...(D)

38)

On solving
xy = c2 with
circle
x2 + y2 + 2gx + 2fy + λ = 0

and again by eliminating from equation of circle and hyperbola we have

Now CP2 + CQ2 + CR2 + CS2

39) Equation of normal at any point an ellipse is

Since,

40) y2 = 4(x – 4) shift origin to (4, 0)

y2 = 4X. Old origin now becomes (– 4,0)

Let equation of tangent be y =

pass through (–4, 0)

41) ||z + i| – |z – i|| = k

for 0 < k < 2 its hyperbola having foci as i & – i.
for k = 0 |z + i| = |z – i| which is perpendicular bisector of line joining i, – i
for k = 2 a pair of ray.

42)

n1 = 5, n2 = 5, ,
,
Combined mean =

=3
Combined variance

= 4.5 + 1
= 5.5

43)

Mediam = 20, SD = 4
if each observation is increased by 2, then mediam will also be increased by ‘2’. Now, if we talk
about Var & S.D. then we know it very will any constant added or subpact to last observations
then S.D. & & Var will never change.

50) ellipse

Hyperbola,

∴
and
Also, b = B

So,

51)
Equation of circle : x2 + (y – r – 1)2 = r2
solve with x2 = 4y : 4y + (y – r – 1)2 = r2
D=0⇒r=4

52) Let point an hyperbola (3sec t, 2tan t)

equation of chord of contact x(3sec t) + y(2tan t) = 9
compare with xh + yk – h2 – k2 = 0

4(h2 + k2)2 = 36h2 – 81k2

x – 2β = 81 – 72 = 9

53)

foci (6, 8) & (5, 12)

for an ellipse or hyperbola

distance between foci = 2ae =

=
2ae = …(1)

for ellipse →
PF1 + PF2 = 2a
10 + 13 = 2a

a= …(2)
For hyperbola →
|PF1 – PF2| = 2a
|10 – 13| = 2a

a = …(3)
For ellipse take a1 & e1
From Eq. (1) & (2)
2a1e1 =

a1 =

2×

e1 = …(4)
For hyperbola take a2 & e2
From Eq. (1) & (3)
2a2e2 =

a2 =

e2 = …(5)
According to question

From Eq. (4) & (5)

=2

54) |α – 2| = 2 and

⇒ arg

area