18-12-2025

2302CJA101031250041 JM

PART-1 : PHYSICS

SECTION-I

1) The resultant of two forces, one double the other in magnitude, is perpendicular to the smaller of
the two forces. The angle between the two forces is :-

(A) 120°
(B) 60°
(C) 90°
(D) 150°

2) In the figure, both bodies A & B are in pure translation. Ratio of acceleration of body B to that of

body A will be :

(A)

(B)

(C)

(D)

3) Figure shows a hemisphere and a supported rod. Hemisphere is translating in right direction with
a uniform velocity v2 and the lower end of the rod has velocity v1 towards left. The rate at which the

angle θ is decreasing will be

(A)

(B)

(C)

(D)

4)

In the given figure pullies and strings are ideal and system (man + plank) is in equilibrium. If man
applies a force F on string then choose the necessary condition for system to be in equilibrium. Mass
of man is m and mass of plank is M :-

(A)

(B)

m≥
(C)

m<
(D)

5) What is the tension in the rope at a distance x from the end where the force is applied ? Given

that the surface is smooth.

(A)

(B)

(C)

(D)

6) A block of mass m lying on a rough horizontal plane is acted upon by a horizontal force P and
another force Q inclined at an angle θ to the vertical. The block will remain in equilibrium if
minimum coefficient of friction between it and the surface is :-

(A)

(B)

(C)

(D)

7) The initial velocity of a particle moving along x-axis is u (at t = 0 and x = 0) and its acceleration a
is given by a = kx. Which of the following equation is correct between its velocity (v) and position (x)
?

(A) v2 – u2 = 2kx
(B) v2 = u2 + 2kx2
(C) v2 = u2 + kx2
(D) v2 + u2 = 2kx

8) The equation of trajectory of a projectile is y = 16 x – . The horizontal range is :-

(A) 16 m
(B) 8 m
(C) 3.2 m
(D) 12.8 m

9) A river is flowing due east with a speed 3m/s. A swimmer can swim in still water at a speed of 4
m/s. If he wants to start from south bank and reach just opposite point on north bank then what will

be his resultant speed :-

(A) 70 m/s
(B) 5 m/s
(C) m/s
(D) 1 m/s

10) A body with weight 60 N is resting on rough surface coefficient of friction between body and
surface is 0.5. What may be maximum value of weight W so that body does no slip on surface-
(A) 60 N

(B)

(C) 30 N

(D)

11) The ratio of angular speed of minute hand and second hand of a clock is :-

(A) 60
(B) 1/60
(C) 30
(D) 1/30

12) A particle is moving on a circular path of radius m in such a way that magnitude of its
velocity varies with time as v = 2t2 + t, where v is velocity in m/s and t is time in s. The acceleration
of the particle at t = 2 s is :

(A) 21 m/s2
(B) 9 m/s2
(C) 10 m/s2
(D) 13.5 m/s2

13) A road is banked at an angle of 30° to the horizontal for negotiating a curve of radius .
At what velocity will a car experience no friction while negotiating the curve? (g = 10 m/s2)

(A) 54 km/hr
(B) 72 km/hr
(C) 36 km/hr
(D) 18 km/hr

14) A conical pendulum is moving in a circle with angular velocity ω as shown. If tension in the
string is T, which of following equations are correct ?

(A) T = mω2ℓ
(B) T sinθ= mω2ℓ
(C) T = mg cosθ
(D) T = mω2ℓ sinθ

15) A ball of mass m is attached to the end of a thread fastened to the top of a vertical rod which is
fitted to a horizontally revolving round table as shown. If the thread forms an angle α with the

vertical, the angular velocity ω of table is

(A)

(B)

(C)

(D)

16) A body of mass m accelerates uniformly to a speed v0 in time t0. The work done on the body till
anytime t < t0 is :-

(A)

(B)

(C)

(D)

17) A vertical spring with force constant K is fixed on a table. A ball of mass m at a height h above
the free upper end of the spring falls vertically on the spring so that the spring is compressed by a
distance d. The net work done on the particle by the gravity force and the spring force in the process

is :-

(A)
mg(h + d) + Kd2

(B)
mg(h + d) – Kd2

(C)
mg(h – d) – Kd2

(D)
mg(h – d) + Kd2

18) A uniform cable of mass 'M' and length 'L' is placed on a horizontal surface such that its
part is hanging below the edge of the surface. To lift the hanging part of the cable upto the surface,
the external work done should be :

(A)

(B)

(C)

(D) nMgL

19) In the given figure, spring, string and pulley are massless. System released from rest when
spring in its natural length. Find maximum elongation in the spring.

(A) mg/K
(B) 2mg/K
(C) mg/2K
(D) None of these

20) Which one of the following forces cannot be expressed in terms of potential energy?

(A) Coulomb's force

(B) Gravitational force
(C) Frictional force
(D) Restoring force

SECTION-II

1) The block has mass 20 kg and rests on a surface for which the coefficient of friction 0.4. If a force
F = 40t2 (in S.I units) is applied to the cable (see figure), the power developed by the force at t = 1

s is nearly ______ kilowatt.

2) From an automatic gun a man fires 360 bullet per minute with a speed of 360 km/hour. If each
weighs 20 g, then find the power supplied by the gun to the bullets in watts.
3) Find out tension (in N) in the string connecting blocks of masses 80 kg and 20 kg. The surface is

smooth.

4) A coin placed on a rotating turn table just slips if it is at a distance of 40 cm from the centre. If the
angular velocity of the turntable is doubled, it will just slip at a distance of _______ cm.

5) A small body of mass m is allowed to slide on an inclined frictionless track from rest position as
shown in the figure.

If minimum height h is nr, so that body may successfully complete the loop of radius ‘r’ Value of 2n
is :

PART-2 : CHEMISTRY

SECTION-I

1) The chief ore of Zn is the sulphide, ZnS. The ore is concentrated by froth floatation process and
then heated in air to convert ZnS to ZnO.

The number of moles of Zn formed by 3.125 moles of ZnS will be :

(A) 2
(B) 3.125
(C) 2.125
(D) 4

2) A solution of two liquids, A (Molar mass = 50 gm/mol) and B (Molar mass = 100 gm/mol) contains
equal moles of both liquids. How many gram of liquid B should be added in 75 gm of above solution,
in order to make the molality of A equal to ‘2 m’ in the final solution ?

(A) 250 gm
(B) 200 gm
(C) 50 gm
(D) 300 gm

3)
The moles of H+ from H2O alone in a solution at 25°C is

(A) 10–7
(B) 6.85 × 10–8
(C) 3.85 × 10–8
(D) 10–8

4) The wave function for an orbital is H-atom is given as

The orbital is :

(A) 2s
(B) 3p
(C) 2p
(D) 3d

5) In H-atom, if ‘x’ is the radius of the first Bohr orbit, de Broglie wavelength of an electron in 3rd
orbit is :

(A) 3 π x
(B) 6 π x

(C)

(D)

6) Which of the following statement is true referred to the above paragraph :

I. Higher is the mass of the particle, error in measurement of velocity reduces.
II. For an electron if uncertainly in position tends to zero then uncertainly in momentum is
extremely small.
III. If λ1 > λ2 are the two different wavelength used to detect the position of electron and uncertainty
in velocity be v1 and v2 respectively then v2 > v1

(A) only I
(B) I and II
(C) I,II & III
(D) I and III

7) For reaction
2P(g) + Q(g) R(g) + S(g) ; KC = 1012
If initial moles of P, Q, R, S are 2, 1, 7 and 3 moles respectively in a one litre vessel. Find equilibrium
concentration of P

(A) 8 × 10–4 M
(B) 4 × 10–4 M
(C) 10–4 M
(D) 2 × 10–4 M

8) 20 ml, 0.1M HA [(Kb)A– = 10–10] is titrated against 0.2M, NaOH. Select the correct statement :-
[Given : log2 = 0.3, log3 = 0.48]

(A) Initially pH of HA solution is 11.5

(B) At half equivalence point pH of solution is 4 and at equivalence point pH is 9.09
(C) Phenolphthalein is suitable indicator for this titration but methyl orange is not suitable
(D) Phenolphthalein & methyl orange both are suitable indicator for end point determination.

9) 4.0 moles of argon and 5.0 moles of PCl5 are introduced into an evacuated flask of 100 litre
capacity at 610 K. The system is allowed to equilibrate. At equilibrium, the total pressure of mixture
was found to be 6.0 atm. The Kp for the reaction is [Given : R = 0.082L atm K–1 mol–1]

(A) 2.25
(B) 6.24
(C) 12.13
(D) 15.24

10) Which of the following statements are correct about HCN and HCP.
(I) HCN is linear with triple bond between carbon and nitrogen
(II) HCP does not exist because P does not form triple bond due to large size
(III) In HCP molecule two -bond and two bonds are present
(IV) Carbon atom is sp hybridised in HCN

(A) Only I
(B) I and IV
(C) I, II, IV
(D) I, III and IV

11) Consider the given Gibb’s energy diagram for the equilibrium reaction

2A (g) B2(g) The reaction is carried out in a 1 L flask taking

3 mol of A. At point R, the mole fraction of B2 is 0.7. Select the appropriate option(s) from amongst
the following.
(1) G is negative at all points from P to R and is zero at R.
(2) KC for the reaction is greater than 1.
(3) The reaction is not feasible from point R towards T as G is positive.
(4) <0

(A) 1, 2
(B) 1, 2, 3
(C) 1, 3, 4
(D) 1, 2, 3, 4

12) An aqueous solution containing 10–2M Na2SO4 and 10–2M NaI. Now pure Pb(NO3)2 is added
gradually, then calculate concentration of SO42– when PbI2 just start precipatating in
solution [Consider volume of solution to be remain constant]
[(Ksp (PbI2)) = 10–9 & Ksp(PbSO4) = 10–8]

(A) 10–2M
(B) 10–3M
(C) 10–6M
(D) 10–5M

13) Calculate the solubility of Ag CN in a buffer of pH = 3. Ksp of AgCN = 10-16 and equilibrium
constant for HCN dissociation = 10-10.

(A) 10-4.5 M,
(B) 10-6.5 M,
(C) 10-5.5 M,
(D) 10-3.5 M

14) Which of the following property is NOT related to the hydrogen bonding

(A) Boric acid is solid at room temperature

(B) Viscous nature of glycerol
Boiling point of hydrocarbon is greater than that of respective fluorocarbon (for higher carbon
(C)
members)
(D) Solubility of C2H5OH in water

15) Choose the correct option in which all compounds are non planar and sp3d hybridized
(I) XeO2F2 (II) BrF3 (III) SiF2Cl2 (IV) XeO3F2

(A) I and IV only

(B) II and III only
(C) I, II and III only
(D) I, II and IV only

16) Given the correct order of initials 'T' or 'F' for the following statements. Use 'T' if statement is
true and 'F' if it is false
(I) In NH3, the orbital in which lone pair is present is pure orbital
(II) In F2O2, polar as well as non polar both bonds are present
(III) In , one of the π-bond can be formed by orbital of central atom
(IV) In , all C–O bonds are not same

(A) T T T T
(B) F T F T
(C) F T T T
(D) T F T F

17) Assuming all non–hydrogenic atoms undergo hybridization & following are various
categories of orbital overlapping.
sp3–sp3 axial ovelap (σ) → Type – A
sp2–sp2 axial overlap (σ) → Type – B
sp3–sp2 axial overlap (σ) → Type – C
p – p lateral ovelap (π) → Type – D
p – d lateral overlap (π) → Type – E
Identify the species which contain only 2 of these types (from A to E) of overlapping of orbitals.

(A) H2CO3
(B) B3N3H3F3
(C) SNF3
(D) H2S4O6

18) Which order is wrong :-

(A) Electronegativity – P < N < O < F

(B) Ist ionisation potential – B < Be < O < N
(C) Basic property – MgO > CaO > FeO > Fe2O3
(D) Atomic radius – Li < Na < K

19) In which of the following arrangements, the sequence is not strictly according to the property
written against it ?

(A) CO2 < SiO2 < SnO < PbO2 : increasing oxidising power
2

(B) B < C < O < N : increasing first ionisation enthalpy

(C) NH3 < PH3 < AsH3 < SbH3 : increasing basic strength
(D) HF < HCl < HBr < HI : increasing acid strength

20) B has a smaller first ionization enthalpy than Be. Consider the following statements :

It is easier to remove 2p electron than 2s

(I)
electron

2p electron of B is more shielded from the

(II) nucleus by the inner core of electrons than
the 2s electrons of Be.
 2s electron has more penetration power
(III)
than 2p electron.

atomic radius of B is more than Be

(IV)
(Atomic number B = 5, Be = 4)
The correct statements are :
(A) (I), (II) and (III)
(B) (II), (III) and (IV)
(C) (I), (III) and (IV)
(D) (I), (II) and (IV)

SECTION-II

1) Calculate value of here

x is value of O – N – O bond angle in
y is value of O– N – O bond angle in
z is value of F – Xe – F bond angle (between adjacent F) in XeF4

2) The NaNO3 weighed out to make 50 mL of an aqueous solution containing 70.0 mg Na+ per mL is
______g. (Rounded off to the nearest integer)
[Given : Atomic weight in g mol–1 – Na : 23 ; N : 14 ; O : 16]

3) What is the atomic number of an element if the quantum numbers of the highest energy electron
of the element in the ground state are n = 4, l = 1, m = –1, s = +1/2 ?

4) Which of the following hypothetical reactions is/are favoured in the forward direction by both with
the increase of temperature as well as increase of pressure?
(A)
(B)
(C)
(D)
(E)
(F)
(G)

5) The following titration curve was obtained as part of a general chemistry laboratory experiment
for an unknown that weighed 0.8 g. The titrant was either a 0.2 M strong base or 0.2 M strong acid.

If the molar mass of the unknown is M, the value of is

 PART-3 : MATHEMATICS

SECTION-I

1) The greatest value of the term independent of x in the expansion of ; where(α

∈ R) is-

(A) 25

(B)

(C)

(D) 1

2) If (1 + x + x2)5 = a0 + a1x + a2x2 + .....+a10x10,then (a0 – a2 + a4 – a6 + a8 – a10)2 + (a1 – a3 + a5 – a7 +

a9)2 is equal to

(A) 0
(B) 210
(C) 1
(D) – 1

3) The sum of

+ ......... 50 terms is equal to :-

(A)

(B)
(C)

(D) None of these

4) The sum of first 10 terms of the series

is :-

(A)

(B)

(C)

(D) None of these

5) Observe the numerical triangle as shown below.

The first term in 15th row will be

(A) 2–100
(B) 2–105
(C) 2–110
(D) 2–115

6) Find the coefficient of x49 in the expansion of (2x + 1) (2x + 3) (2x + 5) ....... (2x + 99) :–

(A) 250 × 2500

(B) 249 × 2500
(C) –250 × 2500
(D) –249 × 2500

7) A vertical pole consists of two parts, the lower part being one third of the whole. At a point in the
horizontal plane through the base of the pole and distance 20 meters from it, the upper part of the

pole subtends an angle whose tangent is . The possible heights of the pole are :

(A) 20 m and m
(B) 20 m and 60 m
(C) 16 m and 48 m
(D) None of these

8) It α, β, γ are roots of equation x3 + qx – r = 0 then the equation. Whose roots are

(A) (r + 1) x3 – q(r + 1) x2 – r3 = 0
(B) rx3 – q(r + 1) x2 – (r + 1)3 = 0
(C) x3 + qx – r = 0
(D) None of these

9) The number of real solution of equation = –x2 + 5x–10 is equal to

(A) 1
(B) 2
(C) 4
(D) No solution

10) The value of the expression is equal to

(A) cos 2x
(B) cos2x
(C) 2cosx
(D) 1 + cosx

11) If α is a common positive root of the equations

x2 – ax + 12 = 0,
x2 – bx + 15 = 0
and x2 – (a + b)x + 36 = 0 and
cosx + cos2x + cos3x = α, then
sinx + sin2x + sin3x equals

(A) 1
(B) 0
(C) –1
(D) 3

12)

If sin x + sin2 x + sin3 x = 1, then cos6 x – 4 cos4 x + 8 cos2 x = :-

(A) 3
(B) 4
(C) 2
(D) 1

13) Let and , then is equal

to

(A) 32
(B) 8
(C) 64
(D) 16

14) Consider a sequence of 101 term as

, , , .....
th
If n term is greatest term of sequence, then n is equal to :-

(A) 48
(B) 49
(C) 50
(D) 51

15)

The number of distinct terms in the expansion of (x + y2)13 + (x2 + y)14 is :

(A) 27
(B) 28
(C) 29
(D) 25

16) If x = log2 and y = log3, then a + bx + cy = [log1 + log(1 + 3) + log(1 + 3 + 5) + ....... + log(1 +
3 + 5 + ..... +19)] – 2[log1 + log2 + log3 + ..... + log7], where a, b and c are positive integers. The
value of 2a + 3b + 5c is equal to (where log a = log10a)

(A) 72
(B) 42
(C) 52
(D) 32

17) If x = 1 + 31/3 + 91/3 then value of x3 – 3x2 – 6x is equal to

(A) 6
(B) 4
(C) 13
(D) 15

18) If the sum of is equal to then

find n? (n ∈ N)

(A) 2010
(B) 2011
(C) 2012
(D) 2013

19) The value of is :

(A)

(B)

(C)

(D) None of these

20) If n is the number of irrational terms in the expansion of (31/4 + 51/8)60, then(n – 1) is divisible by :

(A) 26
(B) 30
(C) 8
(D) 7

SECTION-II

1) The number of values of α in [0, 2π] for which 2 sin3α – 7 sin2 α + 7 sin α = 2, is:

2) Let m,n ∈ N and gcd (2,n) = 1. If

then n + m is equal to (Here )

3) 3 natural numbers x, y, z are in G.P. & x, y2, z are in A.P., then the minimum value of x + 2y + z is
equal to

4) If real values of x satisfying the given modulus equation ||x2 – 6x + 5| – |2x2 – 3x + 1|| = |3x2 – 9x +
6| are [a, b], then 2a + b is equal to

5) Number of solutions of in [–π,π] are

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A A C D A C D C C B C C A C A B B A C

SECTION-II

Q. 21 22 23 24 25
A. 0 600 160 10 5

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A B C B B D B C A D D B A C A B C C C A

SECTION-II

Q. 46 47 48 49 50
A. 39 13 31 2 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C A A B B B B D C B B A B B B B C B A

SECTION-II

Q. 71 72 73 74 75
A. 3 45 4 6 3
 SOLUTIONS

PART-1 : PHYSICS

1)

⇒ θ = 120°

2) Along common normal acceleration is same.

3) Method-I:

Rate of change of θ is nothing but angular velocity of B wrt. A

Method-II:
From the figure,

Also,

– sign as θ in decreasing wrt here.

4)
For equilibrium
Mg + mg = 6T

For man
N≥0
T + N = mg

m ≥ M/5

5)

L —→ M

1 —→

L – x —→ (L–x) = m1

T = Ma =

6) Applied force
fa = P + Qsinθ
Normal reaction
N = mg + Qcotθ
fℓ = µN = µ(mg + Qcosθ)
Now, condition for no slipping
 fa ≤ fℓ
P + Qsinθ ≤ µ(mg + Qcosθ)

µ≥

7)

a=v

8) y = 16x –

y = (tan θ) x –

tan θ = 16
u2cos2θ = 4

u2cosθ =

R=

=
= 12.8 m

9) Resultant speed
= velocity of swimmer w.r.t river
vr = velocity of river w.r.t ground

10) f = µN = 0.5 × 60 = 30N

T = cos 45 = w ..(i)
T sin 45 = f = 30 ..(ii)
T=
so w = 30

11)

12) Question Explanation: Find acceleration at t = 2s or a particle moving in a circle of

radius 19 m with velocity v =2t2+t
Concept: Total acceleration has tangential (at) and centripetal (ac​) components.

Formula Used:

Solution:

= =
Final Answer: Option (3)

13) tanθ = ⇒ v = 36 km/hr

14) Tcosθ = mg ⇒ T = mg/cosθ

Tsinθ = mω2r
⇒ Tsinθ = mω2ℓ sinθ
⇒ T = mω2ℓ

15)
16) v = u + at
v0 = 0 + at0

a=

v= u + at = 0 + t

17) Gravitational potential energy of ball gets converted into elastic potential energy of the
spring.

mg(h + d) = Kd2

Net work done = mg(h + d) – Kd2 = 0.

18)
Uf = 0

∴ w=

19)

When mass goes down

spring elongate by x
by energy conservation

20) Potential energy is defined for conservative force only. It is not defined for non-
conservative force i.e. frictional force.

21) For motion

power = F(2v) = 2Fv = 19200 W

22) Power of gun

23) Explaining the Question :- Three blocks are connected with two strings and a force F is
acting as shown in figure. it is asked to find Tension in the string connecting blocks of masses
80 kg and 20 kg.
Concept:- This question is based on Newton's second laws of motion

Solution :-

asystem = =
FBD of 80 kg block

T = ma
T = 80 2 = 160 N
Final Answer :- 160

24) f = mw2r
⇒ w2r = constant

25) To complete the circle minimum speed at lowest point =

PART-2 : CHEMISTRY

26)

(A) 2 ZnS + 3O2 2 ZnO + 2SO2

2 mol
ZnO + H2SO4 ZnSO4 + H2O
1.6 mol 1.6 mol
2ZnSO4 + 2H2O 2Zn + 2H2SO4 + O2

1.6 mol
2 mol of ZnS 1.28 moles of Zn

then 3.125 mol of ZnS

27) Let x moles of each A and B are present in 75 gm of solution

x × 50 + x × 100 = 75 ⇒ x = 0.5

Now, for final solution, 2 =

∴ Mass of B added = 250 – 100 x = 200 gm

28)

Given, HCl =
Total :

Contribution from water :

Closest option

29) Question Explanation:

Identify orbital from given wave function.

Concept:
This question is based on Schrodinger wave equation.

Solution:

• from angular part sinθsinϕ and from radial part it is p orbital.

• from radial part, it has only one radial node, when

∵ radial node = n – ℓ – 1
∴1=n–1–1
∴ n=3
Orbital is 3p.

Final Answer:
The correct option is (2).

30)

Radius of first orbit = x

Radius of 3rd orbit =

= 9x
Now,
According to de-broglie equation

mvr

m.v (9x)

Ans. (B)

31) Question Explanation:

Select true statements for Heisenberg's uncertainty principle.

Concept:
This question is based on Heisenberg's uncertainty principle.

Solution:

Δx⋅Δp ≥

(1) Δx⋅Δv ≥
If m↑ then Δv↓ (correct)

(2) If Δx → 0 then
Δp → ∞
(3) ∵ Δx = ±λ If λ↓ then Δx↓

∵ Δx⋅Δv =
If λ↓ then Δx↓ and Δv↑
∴ If λ1 > λ2 then v2 > v1 (correct)

Final Answer:
The correct option is (4).
32) 2P + Q R + S
2 1 7 3
2x x 8 –x 4 –x

x = 2 × 10–4
[P] = 2x = 4 × 10–4

33) pH = (pKa – logc) = (4 – (–1)) = 2.5

pH = pKa + log

pH = 7 + (pKa + logc) = 7 + (4 + log )

= 8.41

34) Question Explanation:

Question is asking about the calculate Kp

Concept:
This question is based on calculation of KP

Solution:
PCl5 = 5 mole
Ar = 4 mole

2.5 - P P P

P = 1.5

Final Answer:
The correct option is (1)

35) H ––C ≡ N H ––C ≡ P

36)

2A (g) B2(g)
At R, XB2 = 0.7 XA2 = 0.3
37) [Pb2+] [I–]2 = 10–9
[Pb2+] [10–2]2 = 10–9
2+ –5
[Pb ] = 10
[Pb ] [SO4 ] = 10–8
2+ –2

[10–5] [SO4–2] = 10–8

[SO4–2] = 10–3

38)

Let

……(1)
……(2)
(1) (2)

39) Boiling point of hydrocarbon is greater than that of respective fluorocarbon due to more
polarisability factor which is not associated to hydrogen bonding while rest properties are
associated to the hydrogen bonding.
40) Molecule hybridisation Shape
XeO2F2 sp3d sea-saw
3
BrF3 sp d T-shape
3
SiF2Cl2 sp tetrahedral
3
XeO3F2 sp d trigonal bipyramidal

41) (I) NH3 sp3-ideally it should be 25% S for lone pair and 75% P.
But according to bent rule %S character increases for lone pair.
* due to more near the nucleus nature of s-orbital leading to more stability.

(II) F2O2 Open book like structure.

Non-planar molecule.
(III) IO2F2– will not form p-bond.

sp3d orbital is used in hybridisation

s + px + py + pz +

(IV) HCO3–
Only two resonating (identical), relatively stable resonating structure.
Option (B) is correct.
42)

43)

Ans is (C)
Basic property
CaO is m are basic than MgO

44)

Theory based.

45)

Be ⇒ 1s2 2s2
B ⇒ 1s2 2s2 2p1
B has a smaller size than Be
it is easier to remove 2p electron than 2s electron due to less pentration effect of 2p than 2s.
2p electron of Boron is more shielded from the nucleus by the inner core of electron than the
2s electron of Be
B has a smaller size than Be

46)

sp2 B.A = 120°

sp B.A = 180°
 XeF4 sp3d2 BA = 90°

47)

Na+ present in 50 ml

= = 3500 mg = 3.5 gm

moles of Na+ = = moles of NaNO3

weight of NaNO3 =

48) 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p1 ∴ Z = 31

49) (C) & (F).

Increase in temperature favours endothermic direction and increase in the pressure favours
the direction of decreases in volume (moles of gases).

50) As the pH keeps on decreasing, the titrant must be an acid and the unknown, a base. The
shape of the curve reveals that it is a monoacidic base. The end point is reached at a volume of
50 mL.

PART-3 : MATHEMATICS

51) r = = 5 ⇒ T6 = 10C5 (x sin α)5

⇒ T6 = 10C5 (sin α cos α)5 = 10C5

T6 is maximum when sin 2α = 1 so maximum value is

52) Put ⇒ (1 + i + i2)5 = a0 + a1i – a2 – a3i + a4 + a5i.....

5
So i = (a0 – a2 + a4....) + i(a1 – a3 + a5....)
∴ a0 – a2 + a4.....= 0 and a1 – a3 + a5.....= 1
∴ (a0 – a2 + a4.....)2 + (a1 – a3 + a5......)2 = 1
53) Add and subtract

S=

S=

= =

54) x2 + x4 + x6 + ..... 10 terms}

0
55) 2 , 2–1, 2–3, 2–6, 2–10 .....15 term
0
2 , 2–(0+1), 2–(0+1+2), 2–(0+1+2+3), 2–(0+1+2+3+4), .....

= 2–105

56) (2n + 1) (2n + 3) (2n + 5) .... (2x + 99)

⇒ 250
Coefficient of x49 is equal to –(sum of roots)

57) and H cot β = d

or and

⇒
 ⇒
⇒
⇒

58) x3 + qx – r = 0 → α,β,γ
α,β,γ = r

⇒ yx3 – q (g + 1)x2 – (g + 1)3 = 0

59) Let f(x) = –x2 + 5x –10 and g(x) =

f(x)max = and g(x) > 0

so f(x) = g(x) has no Real solutions

60)

= 2cosx

61) ∵ α is common root,

α2 – aα + 12 = 0 ...(1)
α2 – bα + 15 = 0 ...(2)
2
α – (a + b)α + 36 = 0 ...(3)
Now, (1) + (2), then subtracting equation (3)
α2 – 9 = 0 ⇒ α = 3 (∵ a > 0)
Given, cosx + cos2x + cos3x = α = 3
This is possible only, if
cosx = 1, cos2x = 1, cos3x = 1
∴ sinx = 0, sin2x = 0, sin3x = 0
∴ Reqd. = 0
 62)

Given, 1 = sin x + sin2 x + sin3 x

⇒ cos2 x = sin x (1 + sin2 x)
= sin x (2 – cos2 x)
⇒ cos x = (1 – cos2 x) (4 + cos4 x – 4 cos2 x)
4

= 4 – 4 cos2 x + cos4 x – cos6 x

– 4 cos2 x + 4 cos4 x
⇒ cos6 x – 4 cos4 x + 8 cos2 x = 4

63) Let

64) Let T1 + 1 is max.

T1 + 1 =

= is max, when
r + 4 = 52
r = 48
so term is 49th

65)

To get common terms in both expansion

∴ r1 = 2r2 and 26 – 2r1 = 14 – r2

∴ r1 = 8 and r2 = 4 ⇒ only one term is common

66) [log1 + log4 + log9 + ..... + log100] – 2log7!

= 2log(1·2·3· ..... ·10) –2log7!

= = 2log720 = 2log(10 × 9 × 8)
= 2[1 + 3log2 + 2log3]
= 2(1 + 3x + 2y) = 2 + 6x + 4y
 ∴ a = 2, b = 6, c = 4
2a + 3b + 5c = 4 + 18 + 20 = 42

67) Use a3 + b3 + 3ab(a+b) = (a+b)3

x = 1 + 31/3 + 91/3 ⇒ x –1 = 31/3 + 91/3
Take cube in both side
(x – 1)3 = (31/3 + 91/3)3 ⇒ x3 – 1 – 3x(x –1) = 3 + 9 + 3.31/3 . 91/3(31/3 + 91/3)
31/3 . 91/3 = 271/3 = 3and 31/3 + 91/3 = x –1
⇒ x3 – 3x2 – 6x = 4

68)

=
∴ n = 2012

69)

= sin = sin =

= =
=

70)

Correct option is (A)

71) 2 sin3α–2 = 7 sin2α – 7 sinα

2 (sinα – 1) (sin2α + 1 + sinα) = 7 sinα (sinα –1)
⇒ sin α = 1 or
2 sin2α + 2 + 2 sinα = 7 sinα (sinα – t) (sinα– 2)

⇒ sin α = 1 or sinα = sin α ≠ – 2

⇒ 3 solutions

72)

30(30C0) + 29(30C1) + ... + 2(30C28) + 1(30C29)

= 30(30C30) + 29(30C29)+...... + 2(30C2) + 1(30C1)

∴ n = 15, m = 30
n + m = 45

73) xz = y2 &

⇒
A.M. ≥ G.M.
⇒ ⇒
∵ xz ≠ 0 ⇒ xz ≥ 1
⇒ y2 ≥ 1 ⇒ y ≥ 1
Now, x + 2y + z = 2y2 + 2y
∴ (2y2 + 2y)min = 2 + 2 = 4

74) (x2 – 6x + 5) (2x2 – 3x + 1) ≤ 0

(x2 – 5x – x + 5) (2x2 – 2x – x + 1) ≤ 0
(x(x – 5) – 1 (x – 5)] [2x(x – 1) – 1 (x – 1)] ≤ 0
(x – 1) (x – 5) (2x – 1) (x – 1) ≤ 0
(x – 5) (2x – 1) (x – 1)2 ≤ 0

75) Let t = 2sin2x + sinx

⇒
t + 15 = 25 + t –
⇒t=1
2sin2x + sinx – 1 = 0