13-07-2025

1001CJA106213250007 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A small sphere of mass m is connected by a string to a nail at O and moves in a circle of radius r
on the smooth plane inclined at an angle θ with the horizontal. If the sphere has a velocity u at the

top position A. Mark the correct option(s).

(A)
Minimum velocity at A so that string does not get slack instantaneously is .

(B)
Tension at B if sphere has required velocity to just complete circle A is mg.

(C)
Tension at C if sphere has required velocity to just complete circle is mg

(D)
Centripetal force at point A is mg if it just get slack instantaneously.

2) Block A is released on the circular track of bigger block B from rest from the position as shown in
figure. Friction is absent everywhere. Choose INCORRECT statements :-

(A) Acceleration of center of mass of A & B is zero initially

(B) When A reaches Q acceleration of center of mass of A & B is zero
Normal force of the surface below is greater than combined weight of A & B, when A reaches
(C)
at point Q
(D) Acceleration of B is maximum when A reaches Q

3) A wedge of mass m is kept on a smooth table and its inclined surface is also smooth. A small block
of mass m is projected from the bottom along the incline surface with velocity u. Assume that the
block remains on the incline and take θ = 45°, g = 10 m/s2.
(A) Magnitude of acceleration of block is more than magnitude of acceleration of wedge.
(B) The block strikes the table normally.
(C) Radius of curvature of the path of the block when it is at the highest point is u2/16g.
(D) Radius of curvature of the path of the block when it is at the highest point is 3u2/16g.

4) A particle of mass m = 3 kg is moving on a straight line in a conservative force field in which

the potential energy associated with the particle is given by U(y) = 2y2 – 30y + 450 . At t = 0,
particle is at y = 8 m and moving towards positive y-axis with 1 m/s.

(A)
During the course of its motion the maximum speed of the particle will be m/s.
(B) Particle will never cross the origin.

(C)
Particle will come to its equilibrium position for the first time at second
(D) The amplitude of oscillation for the particle is 1m.

5) A bead is moving on a frictionless fixed circular wire of radius 0.8 m in horizontal plane with
constant speed & there is no interaction force between bead & wire & it is also connected with

string & spring as shown in figure.

(A) Speed of bead is 4 m/sec.

(B) Elongation in spring is 10 cm.
(C) If we cut the string, normal force due to wire on bead is 20√5 N .
(D) If we cut the spring, normal force due to wire is 20√5 N .

6) Six particle are located at the vertices of regular hexagon of side 'a' . At t = 0 they all start
moving simultaneously with constant speed 'v'. The first particle is heading for second, the second
particle is heading for third and so on. Then choose the correct option(s).

At the acceleration of each particle is

(A)

At , the acceleration of each particle is

(B)

(C)
At the radius of curvature of trajectory of each particle is a.

At the radius of curvature of trajectory of each particle is

(D)

SECTION-I (ii)

1) A rough track connects point O (Om, Om) to point A(1m, 1m). External force F always tangential
to path pulls object of mass 2 kg from point O(0m, Om) to point A(1m, 1m) very slowly. Coefficient of

friction between block and track is 0.5.

List–I List–II

Work done by frictional force on block magnitude

(I) (P) 30
wise in Joules

Normal reaction force between block and track at x

(II) (Q)
= in Newton

Work done by external force F on block magnitude

(III) (R) 10
wise in Joules
 Net reaction force between block and track at x =
(IV) (S)
in Newton

(T)
If equation of track is y2 = x then choose the correct combination from List–I & List–II.
(A) I → R;II → Q;III → P;IV → T
(B) I → S;II → Q;III → T;IV → P
(C) I → P;II → Q;III → R;IV → S
(D) I → P;II → Q;III → T;IV → R

2) In List-I, some diagrams are shown and in List-II, related work done by weight or by F in different
cases are given. Match them correctly. Match List–I with List–II and select the correct answer using
the codes given below the lists :

List–I List–II

Chain of weight W is pulled slowly by a variable force F so

Work done by
weight of chain
(I) (P)
=

that complete chain comes to table.

Chain slip from the table due to weight 2W and becomes

Work done by F
(II) (Q)
=

vertical

Chain slips from the table slowly due to weight W of the chain
and variable force F and it becomes vertical

Work done F =
(III) (R)
 Chain of weight W is pulled by constant force Slightly more
than F so that complete chain comes to table. Initially chain is

Work done by F
(IV) (S)
=

in equilibrium due to F.

(T) None of these

(A) I → R;II → P;III → S;IV → Q
(B) I → P;II → S;III → Q;IV → R
(C) I → S;II → P;III → Q;IV → R
(D) I → Q;II → R;III → S;IV → P

3) There are two point masses A and B, situated at origin and point (5m, 0m) respectively, at a
certain time t. and are respectively the velocities of point masses A and B at this instant t.
Match the situations under List–I with their correct option under List–II and select the correct
answer using the codes given below the lists :

List–I List–II

and

The speed of approach between point

(I) (P) masses A and B at the given time t is
5 m/sec.

and

The speed of separation between

(II) (Q) point masses A and B at the given
time t is 5 m/sec.

and

At the given time t = t sec, the

(III) (R) magnitude of angular velocity of point
mass A with respect to B is 3 rad/sec.
 and

At the given time t = t sec, the

(IV) (S) magnitude of angular velocity of point
mass A with respect to B is 1 rad/sec.

(T) None of these

(A) I → Q;II → R;III → P;IV → S
(B) I → P;II → S;III → Q;IV → R
(C) I → S;II → P;III → Q;IV → R
(D) I → Q;II → R;III → S;IV → P

4) Two balls of masses 2m and 3m are connected by a massless rigid rod and allowed to slide on the
smooth inside of a fixed vertical ring of radius R as shown in figure. The dumb bell is released from

rest at θ = 0°. Match the correct answers for List-I in List-II.

List-I List-II

Speed of the balls when the

(I) (P) 0.632
rod is horizontal.

Speed of the balls when

(II) havier ball reaches the (Q) 0.784
bottom of the ring.

(III) Maximum speed of the balls. (R) 0.801

(IV) Maximum value of θ. (S)

(T)

(A) I → P;II → Q;III → R;IV → T

(B) I → Q;II → P;III → R;IV → T
(C) I → R;II → P;III → Q;IV → S
(D) I → R;II → P;III → R;IV → T

SECTION-II
1) A particle is moving under the influence of a force along with many other forces. There
exists a set of infinite circles C1, C2, C3, ... ∞. If the work done by this force in completing the circular
path in each circle is given by W1, W2, W3,... W∞ respectively. Assume that in all circles the particle is
moving in anticlockwise sense. Determine the value of (W1 + W2 + W3 + ...W∞). (Given : k = 1 Nm

and π = 3.14)

2) A man starts running a race with velocity 2.5 π m/s when he starts running he finds the wind is
blowing at an angle 45º with the track. As he progresses on the straight horizontal track. He finds
wind is rotating with uniform angular velocity and by the time he completes the race wind rotates
through an angle 45° if the wind always blows perpendicular to the track and time of race is

find the length of the race (in m).

3) Two particles A and B are seperated from each other by a distance ℓ. At t = 0 particle A starts
moving with uniform acceleration a along line perpendicular to initial line joining A and B at the
same moment, particle B starts moving with acceleration of constant magnitude b such that particle
B always points towards instantaneous position of A (b > a) find the distance (in m) Travelled by B
till the moment B converges with A take b = 3 m/s2 , a = 1 m/s2 and ℓ = 8m.

4) Figure shows a plot of potential energy U versus position x of a 0.200 kg particle that can travel
only along an x axis under the influence of a conservative force. The graph has these values: UA =
9.00 J, UC = 20.00 J, and UD = 24.00 J. The particle is released at the point where U forms a
"potential hill" of "height" UB = 12.00 J, with kinetic energy 4.00 J. The turning point on the right

side is at x = xR and on the left side is x = xL. The value of (in m) is

5) A particle is moving in space such that it’s position vector is given by

Find radius of curvature of the path at t = 2.5s.

6) Figure shows a block placed on a bracket. Bracket is placed on a smooth floor, it is pulled by a
force F = 6N horizontally. Block is projected with velocity v0 relative to bracket as shown in figure.
Find time in second after which it stops relative to bracket. Horizontal surface of bracket is smooth
while vertical surface is rough (Given: m = 1kg, M = 5kg, v0 = 4m / s 0.5), the motion of bracket

is restricted in z-direction.

7) A particle P is moving on a circle under the action of only one force, which always acts towards a

fixed point O lying on the circumference. Find ratio of to at the moment

when (C is centre of circle)

8) The 4 kg box A is resting on the left end of the 3 kg uniform plank B when the 50 N constant force
is applied to A. Determine the distance xA (in cm) traveled by the box when it arrives at the right end
of the plank. Use the kinetic coefficients of friction shown in the figure.

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following set(s) contain only acidic oxides and of p-block only.

(A) NO2 , GeO2 , In2O3 , CO2

(B) CrO3 , Cℓ2O7 , P4O6 , Mn2O7
(C) N2O3 , SeO2 , P4O10 , SO3
(D) Cℓ2O , B2O3 , SO2 , N2O5

2) Which of the following statement is CORRECT regarding electron gain enthalpy (ΔHeg).

All halogens have higher magnitude of ΔHeg compared to other elements of same period in
(A)
periodic table.
(B) For any neutral atom X
Elements like N, Be or Mg require energy to accept electron in their isolated gaseous atom in
(C)
ground state.
(D) Si, P, S & Cl have highest value in their respective groups.
3) Which of the following statements are INCORRECT regarding cyclic silicate .

(A) There is 3 member ring present in silicate structure.

(B) Given cyclic silicate is planar in nature.
(C) All silicon atoms are present in same plane.
(D) It can exist a single chain silicate with exact molecular formula.

4) Which of the following statements is CORRECT :

(A) Ethylene glycol is more viscus as compared to Ethanol

–
(B) HSO5 have intramolecular hydrogen bonding
(C) NH3 has a higher boiling point than SbH3, because of hydrogen bonding between NH3 molecules
Among HCl, HBr and HI, HI is the strongest acid & HCl is the weakest acid, while among HOCl,
(D)
HOBr and HOI, HOCl is the strongest acid & HOI is the weakest acid.

5) Which of the following statement is/are CORRECT?

(A) In noble gases Helium has lowest boiling point

(B) In NaHCO3(s) hydrogen bonding takes place
(C) Boiling point of SiCl4 is greater than the boiling point of CCl4
(D) Boiling point of H2O is greater than the boiling point of HF

6)
CORRECT about above molecules :-

(A)
All use set of orbital by central atom in hybridisation
(B) All have two types of S–F bond length data
(C) Out of given three molecules , has highest number of atoms in one plane
(D) All have same total number of lone pair.

SECTION-I (ii)

1)

List- I List- II
(elements) (Properties)

(P) P (1) has more size than Na

(Q) Cl (2) has stable half/full filled configuration

configuration have maximum principle

(R) Ne (3)
quantum number = 4
 configuration have maximum azimuthal
(S) K (4)
quantum number = 1

(5) d-Block element

(A) P → 1;Q → 2;R → 4;S → 3
(B) P → 2;Q → 4;R → 3;S → 4
(C) P → 1;Q → 2;R → 4;S → 1
(D) P → 2;Q → 4;R → 4;S → 1

2)

List-I List-II
(Order) (Properties)

(P) K < Na < Li (1) Atomic radius

(Q) Ca > Mg > Be (2) First ionisation energy

(R) K > Ca (3) Metallic character

(S) C > Si > Ge (4) Number of electrons in penultimate shell

(5) Second ionisation energy

The correct code is :
(A) P → 2,5;Q → 1,3,5;R → 2,4;S → 1,3
(B) P → 2,5;Q → 1,3;R → 1,3,5;S → 2,4
(C) P → 1,3,5;Q → 2,4;R → 1,3;S → 2,5
(D) P → 1,3;Q → 2,5;R → 1,3,5;S → 1,2

3) Match the oxyacids or their derivatives listed in List-I with properties written in List-II.

List-I List-II

Contain linkage between similar

(P) Hypophosphoric acid (1)
elements

Maximum number of atoms

(Q) Pyrosulphurous acid (2)
present in a ring.

Anhydrous sulphuric acid Contain central atoms (P, S or B) of

(R) (3)
(cyclic allotrope) different oxidation states

Meta boric acid (Trimeric Contain central atoms (P, S or B) in

(S) (4)
form) sp2 hybridisation from List-I

Maximum number of X-O-X

(5)
linkages
The correct option is :
(A) P → 3;Q → 4;R → 2;S → 2
(B) P → 1;Q → 3;R → 2;S → 4
(C) P → 3;Q → 4;R → 5;S → 5
(D) P → 1;Q → 3;R → 3;S → 5
4) Match the molelcules species with their properties :

List-I List-II

The axial bond length is larger than the equatorial

(P) IF7 (1)
bond length

2– The axial bond length is shorter than the equatorial

(Q) [SiF6] (2)
bond length

(R) BrF3 (3) dx -y orbitals are involved in bonding

2 2

+
(S) [PI4] (4) All possible bond angles are not identical

(5) All possible bond angles are identical

(A) P → 1;Q → 3;R → 4;S → 2
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 2;Q → 3;R → 4;S → 5
(D) P → 1;Q → 3;R → 4;S → 1

SECTION-II

1) How many statements is/are correct ?

(i) Van der waal's forces are responsible for the formation of dry ice (molecular crystal).
(ii) Ion-dipole intractions are responsible for hydration of ions.
(iii) In solidified noble gas, the attraction between molecules arises entirely from weakest dispersion
(London)forces.
(iv) Boiling point of ICl is less than boiling point of Br2.
(v) Ionic bonds are directional in nature.

2) Consider y-axis as internuclear axis, how many of the following overlappings result in π-bond
formation:
(i) py – py (ii) px – px (iii) pz – pz
(iv) dxy – dxy (v) dyz – dyz (vi) px – dxy
(vii) dxy – pz (viii) dxz – dxz (ix)
(x)

3) Find the total number of correct orders among the following.

(1) Order of electron affinity : S > O–
(2) Order of ionic radius : Al3+ < Mg2+ < O2–
(3) Order of Electronegativity : Si < P < C < N
(4) Order of atomic radius : O < S < Se
(5) Order of second ionization energy : C < N < F < O
(6) Order of ionic radii : S2– < Cl– < K+ < Ca2+

4) Number of species that have identical structures both according to Lewis theory & according to
maximum covalency among the following.
 , H2SO4 , , COCl2 , C3O2 , , ,

5) Consider the following species :

S1 :
S2 : XQ2R
S3 :
S4 :
S5 :
In the above species W, X, Y and Z are central atom. P exhibit covalency of two in ground state
whereas Q, R, T exhibit covalency of one in ground state. Hybridisation increases from S1 to
S5 uniformely. Element W has 3rd highest IE1 in 2nd period.
a = Number of polar species
b = Total lone pair present on S5
c = Total lone pair present on Y in S4

Find the value of

6)

Consider and
P = Sum of maximum number of atoms in one plane for both the species
Q = Number of such plane containing maximum atoms in
R = Number of such plane containing maximum atoms in .
Find the value of (P + Q + R)

7) Find number of substance in which inter molecular hydrogen boding is responsible for association
of the molecules in their liquid states.
H3PO4, H2O, CHCl3, C6H5Cl, H2SO4, H2O2, CH3OCH3, Ortho-chlorophenol, para-hydroxy benzaldehyde

8) The rare 3T double chain silicate occurs in Xonolite[Ca6SixOy(OH)2]

calculate sum of x and y. (A portion of Silicate part of Xonolite)

PART-3 : MATHEMATICS

SECTION-I (i)

1) If 4sinαcosβ + 2cosβ – = sinα, where α,β ∈ [0, 2π] and L = α – β then

(A)
maximum value of L is

(B)
minimum value of L is

(C)
maximum value of L is

(D)
minimum value of L is

2) The solution/s of the equation 9cos12 x + cos2 2x + 1 = 6cos6 x cos2x + 6cos6 x – 2cos2x is/are

(A)
,n∈I

(B)
,n∈I

(C)
,n∈I
(D) x = nπ, n ∈ I

3) then which of the following may be true ?

(where b, d ∈ N)

(A)

(B)

(C)

(D) bd = 32021

4) Which of the following functions have the maximum value unity ?

(A) sin2x – cos2x

(B)

(C)
(D)

5) Given that x + y + z = 15 when a, x, y, z, b are in A.P. and when a, x, y, z, b are in

H.P. then

(A) G.M. of a and b is 3

(B) one possible value of a + 2b is 11
(C) A.M. of a and b is 6
(D) greatest value of a – b is 8

6) Let a > 0, b > 0, c > 0 and a + b + c = 6 then the value of the expression

may be

(A)

(B) 35
(C) 15
(D) 10

SECTION-I (ii)

1) The graph of y = (x – a)2 + b and y = (x – a)2 + c have y-intercepts of 2021 and 1961 respectively.
Each graph has two positive integral x-intercepts. Then match the following List-I with List-II.

List-I List-II

(I) a is equal to (P) –64

(II) b is equal to (Q) –4

(III) c is equal to (R) 0

(IV) number of integral roots of (x – a)2 + b = 5, is (S) 2

(T) 45
(A) I → T;II → R;III → P;IV → S
(B) I → T;II → Q;III → P;IV → S
(C) I → T;II → Q;III → P;IV → R
(D) I → Q;II → P;III → R;IV → T

2) Match the following List-I with List-II.

List-I List-II

Least value of the expression

(I) (P) 2
2log10x – logx0.01 for x > 1 is

The number of solutions of

(II) (Q) 4
log4(x – 1) = log2 (x – 3) is

Least integral value of x which satisfies

(III) (R) 1
log(x + 1)

Number of solutions of the equation [loge x] =

(IV) |x| is (where [.] denotes the greatest integer (S) 0
function)

(T) 5
(A) I → Q;II → R;III → S;IV → P
(B) I → Q;II → P;III → Q;IV → S
(C) I → Q;II → S;III → R;IV → T
(D) I → Q;II → R;III → P;IV → S

3) Match the following List-I with List-II

List-I List-II

If the expression sin2(θ) + sin2(120° + θ) + sin2 (120° – θ)

(I) (P)
remains constant, ∀ θ ∈ R, then value of the constant is

If the sum of the solutions of the equation 2e2x – 5ex + 4 = 0

(II) (Q) 1
is ln k then k equals

(III) If , find the value of (R)

(wherever defined)

If 3 tan(θ – 30°) = tan(θ + 120°) then the value of cos 2θ

(IV) (S) 2
equals

(T) 0
(A) I → S;II → R;III → Q;IV → P
(B) I → R;II → S;III → P;IV → Q
(C) I → R;II → S;III → Q;IV → T
(D) I → P;II → Q;III → R;IV → S

4) Let & , where an is nth term of an infinite G.P., then match the following
List-I with List-II.

List-I List-II

(I) Common ratio + first term is equal to (P) 45

(II) a5 is equal to (Q)

(III) (R)
is equal to

(IV) (S) 44
is equal to

(T) 0
(A) I → Q;II → T;III → P;IV → R
(B) I → T;II → R;III → Q;IV → S
(C) I → Q;II → R;III → P;IV → S
(D) I → S;II → P;III → T;IV → Q
 SECTION-II

1) A real sequence is define as t1 = 20, t2 = 21 and for all n 3. If 5t13 = (where p

and q are coprime), then |p – q| is

2) If positive numbers x, y, z in order are in A.P., then the minimum value of is equal
to

3) The number of distinct solutions in x ∈ [0, π] which satisfy the equation 8 cos x cos 4x cos 5x = 1

is k then is equal to _____

4) The value of cos x·cos 2x·cos 3x ... cos 999x where x = is p then 21000p is equal to

5) Consider the cubic polynomial P(x) = x3 – ax2 + bx + c. If the equation P(x) = 0 has integral roots
such that P(6) = 3 then sum of all possible values of 'a' is _____

6) If the equations x2 – 3x – ai = 0 has integral roots where ai N and ai < 300 then ______

7) If log245 175 = a, log1715 875 = b , then the value of is

8) (where ℓ , m are relatively coprime), then ℓ + m is equal to

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,D A,B,D A,B,D A,B,C,D A,B,C,D A,B,D

SECTION-I (ii)

Q. 7 8 9 10
A. A A B B

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 6.28 100.00 9.00 4.60 to 4.70 16.66 to 16.67 6.66 to 6.67 2.00 170.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. C,D A,B,C A,B,D A,B,D A,B,D A,B,C

SECTION-I (ii)

Q. 25 26 27 28
A. D B B C

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 3.00 5.00 5.00 5.00 5.00 21.00 5.00 23.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,D A,B A,B,C,D A,B,C,D A,B,D A,B

SECTION-I (ii)

Q. 43 44 45 46
A. B D B C
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 3.00 4.00 5.00 2.00 51.00 1600.00 5.00 71.00
 SOLUTIONS

PART-1 : PHYSICS

1) (A) T + mg sin 37° =

∴v=

(C) mg 2r sin 37° = mv2 – mv2

∴ = 3 mg

T – mg sin 37° = mar

∴T=

2) (A) Since A has acceleration so centre of mass will also accelerating.

(B) at Q acceleration of A is in frame of 'B' so acceleration of centre of mass will not zero.

(C) at Q N – mg =
So net normal force will be greater than combined weight.
(D) When 'A' is at Q acceleration of B is zero.

3)

Correct answer is (A,B,D)

4) (For equilibrium)
Particle is performing simple harmonic motion

5)

Correct answer is (A,B,C,D)

6)
Correct answer is (A,B,D)

7)

wr = µmgℓ
wf = 10 J

, at x =
N = mgcosθ

N = 2 × 10 × = 20 N
wf = µmgℓ + mgh
wf = 0.5 × 20 × 1 + 20 × 1
wf = 30 J
At any point : N = mg cos θ
f = µmgcosθ
R=

R = mgcos
 8) In Case (A)
KEt – KEi = Wall forces
0 – 0 = Wf + Wweight

So, Wf = –Wweight =
In Case (B)

Wgravity= PEi – PEf = =

In case (C)
KEf – KEi = Wall
0 – 0 = Wf + Wweight

⇒ Wf = –Wweight =
In case (D)

WF =

Initially F =

work done by F =

9)

and

(I) (P) Va = 5 m/s, ω = 5 rad/s

and

(II) (Q) VS = 15 m/s, ω = 1 rad/s

and

(III) (R) VS = 5 m/s, ω = 5 rad/s

 and

(IV) (S) VA = 15 m/s, ω = 3 rad/s

10)

This is yet another problem on the conservation of mechanical energy. The potential energy of
the dumbbell-earth system is taken to be zero when the balls in the bottom of the vertical ring.
At any arbitrary value of θ, the potential energy of he system is (see figure b).

U = (3m)gR(1– sinθ) + (2m)gR(1 – cosθ)

= mgR(5 – 3sinθ – 2 cos θ) ............(i)
If the balls posses common speed v, the kinetic energy of the system is

K= .......(ii)
Whichever position the balls may slide to, the sum (U + K) always remains constant
(a) At the time of release, θ = 0 and v = 0, Substituting them in equation (i) and (ii)
Ut + Kt = mgR (5 – 3 sin 0° – 2 cos 0°) + 0 = 3mgR
At the time the rod is horizontal, θ = 45.0° and let the speed of the balls be v. Then

U2 + K2 = mgR(5 – 3 sin 45.0° – 2 cos 45.0°) +

= mgR
Setting U1 + K1 = L1 + K2 ;

3mgR = mgR
or v = 0.784
(b) At the time the heavier ball reaches the bottom of the ring. θ = 90.0° and let speed of the balls be
v', Then :

U3 + K3 = mgR (5 – 3 sin 90.0° – 2 cos 90.0°) +

= 2mgR +
But
U1 + K1 = U3 + K3

3mgR = 2mgR +
or v' = 0.632

(c) When the speed of the balls is the maximum the potential energy of the system the minimum so
that

⇒ mgR (–3cosθ + 2sinθ) = 0 (using equation)

⇒ tanθ =
⇒ θ = 56.3°
Thus, the minimum potential energy is :
Umin = mgR(5 – 3sin 56.3° – 2 cos 56.3°) = mgR (5 – )

The corresponding kinetic energy is Kmax = , where vmax is the maximum speed of the balls.
Applying energy conservation principle :
3mgR = mgR(5 – 3sinθmax – 2cosθmax)
⇒ 3sinθmax + 2cosθmax – 2 = 0
⇒ 13cos2θmax – 8cosθmax – 5 = 0

⇒ cosθmax = 1 or
⇒ θmax = 0° or 113°
The first solution is ignored because it corresponds to the initial position of the balls.
11)
As is evident from the figure the origin lies inside the circle C1 and outside all the remain in
infinite number of of circles, we can write
(for circle C1)

(for remaining circles)

W1 + W2 + W3 + .... W∞ = 2πk

12)

Let velocity of wind = vw

Initially velocity of man = 2.5 π m/s
Velocity of wind with respect to man makes an angle 45° with track initially

θ = 45° when vman = 2.5 π m/s ⇒ vw = 2.5 π m/s

Let when velocity of man is vm the wind appears to make an angle θ with track, so
vm = vwcotθ
vm = 2.5π cot θ

[where x is position of man w.r.t origin at time t]

but
x=
So length of race is 100 m.

13)
Let after time t, the velocity B is directed at angle θ with the horizontal.

∴l=

14)

Correct answer is (4.60 to 4.70)

15)

16)

Correct answer is (6.66 to 6.67)

 17)

18)

Srel = 1.1 m

50 – 16 = 4aA
16 – 7 = 3aB
aB = 3 m/s2
aA = 8.5 m/s2
aAB = 5.5 m/s2

PART-2 : CHEMISTRY

19)

The correct answer is option (C), (D)

20)

* All halogens have higher electron gain enthalpy compare to other elements.
*

ΔHeg = –IE (X–)

|ΔHeg| = |IE(X–)|
* For elements like N , Be , Mg have + ve value of ΔHeg
* Phosphorous does not have maximum magnitude of ΔHeg in its group.
Ans. D is incorrect.

21) is cyclic silicate which involve 3 tetrahedral units.

2 atoms are shared per tetrahedral unit
6 member ring will be formed
Any three atom will be present in same plane.
Single chain silicate cannot have same molecule formula.
option C is incorrect.

22) SbH3 has higher boiling point than NH3 due to vanderwaal forces. In hydra acids, the
acidity increases down the group while for oxyacids, the acidity decreases down the group.

23) The correct answer is option (A), (B), (D)

24)

The correct answer is (A),(B),(C)

25)

The correct answer is option (D)

26)

The correct answer is option (B)

27)

The correct answer is option (B)

28)

The correct answer is option (C)

29) (i), (ii) & (iii) are correct.

30) (i) σ (ii) π (iii) π (iv) π

(v) π (vi) π (vii) no bond (viii) δ

31) (6) correct order is S2– > Cl– > K+ > Ca2+
 32)

The correct answer is 5.00

33)

The correct answer is 5.00

34) The correct answer is 21.00

P = 8, Q = 10, R = 3

35) H3PO4, H2O, H2SO4, H2O2, para-hydroxy benzaldehyde

36)

The correct answer is 23.00

PART-3 : MATHEMATICS

37)

or

or

38) 9cos12 x + cos2 2x + 1 – 6cos6 x cos 2x – 6cos6 x + 2cos2x = 0

⇒ (3cos6 x – 1 – cos2x)2 = 0
⇒ cos2 x (3cos4 x – 2) = 0
⇒ cos x = 0

or
39)

40) (A)

(B)

(C)

(D) cos2x + sin4x = 1 – sin2x. cos2x = 1 – (sin2x)2 ≤ 1

41) a, x, y, z, b are in A.P.

a + b = 10 ..............(1)

are in A.P.

ab = 9 ...........(2)
If a = 1, b = 9
If a = 9, b = 1

42) A.M. ≥ H.M. for , we get ⇒

Now,

43) 2021 = a2 + b
⇒ b = 2021 – a2
⇒ (x – a)2 + b = (x – a)2 + 2021 – a2
Let α be the roots :
2021 = a2 – (α – a)2
⇒ 37 × 43 = (2a – α)(α)
Similarly
(2a – β)β = 1961 = 37 × 53

a = 45

44) (I) y = 2 log10x – logx(10)–2

y = log10x +
let log10x = t > 0

y = 2t +
as AM ≥ GM

y ≥ 4.

(II)

x – 1 = x2 + 9 – 6x
x2 – 7x + 10 = 0
x = 2, 5
But x > 3
∴x=5

(III) logx + 1 x> (x > 0)

2x2 – x – 1 > 0
(x – 1) (2x + 1) > 0

.... (2)
(1) ∩ (2)
Least integral value is x = 2
(IV)
No. solution.

45) (I) LHS = sin2θ +1 – [cos2 (120° + θ) – sin2(120° – θ)]

= sin2θ +1 – [(cos 240°) (cos2θ)] = sin2θ + 1 + cos2θ

= sin2θ + 1 + (1 – 2sin2θ) =
(II) 2e2x – 5ex + 4 = 0
Let roots be x1 and x2, product of the roots be

x1 + x2 = ln 2

(III)

⇒ =

(IV)

or

⇒ 3 cos 2θ – = cos 2θ +
⇒ cos 2θ = 1

46) Let first term & common ratio of G.P. are A & R
Given that AR + AR3 + AR5 + ... ∞ = 6
& A + AR2 + AR4 + ... ∞ = 9
⇒ R(A + AR2 + AR4 + ... ∞) = 6

⇒ & ⇒A=5

(I) A + R = +5=

(II) a5 = A.R4 =

(III)
(IV)

47) t1 = 20 t2 = 21

Let 5tn = un

∴ un + 3 = u n – 2 period of reoccurance is 5

∴ u13 = u3 = 5t3 = 5

48) Since x, y, z are in A.P., x + z = 2y and hence

≥ 1 + 3 [A.M. ≥ G.M.]
⇒ minimum value of the given expression is 4.

49) As no multiple of π nor any odd multiple of satisfies the equation we can multiply both
sides by
sin x cos 2x, which gives
sin 8x cos 5x = 2 sin 4x cos 4x cos 5x = 4 sin 2x cos 2x cos 4x sin 5x
= (sin x sin 2x)(8 cos x cos 4x cos 5x) = sin x cos 2x
⇒ sin 13x + sin 3x = sin 3x – sin x
⇒ sin 13x = sin (–x)
⇒ 13x = nπ + (–1)n (–x)

Which gives 10 solutions

50) Let P = cos x cos 2x ·cos 3x ... cos 999x and Q = sin x sin 2x sin 3x ... sin 999x
PQ · 2999 = sin 2x sin 4x sin 6x ... sin 1998x
= (sin 2x·sin 4x ... sin 998x)(–sin(2π – 1000x)(–sin(2π – 1002x) ... [–sin(2π – 1998x)]
= sin 2x·sin 4x ... sin 998x · sin999x · sin997x ... sin x = Q

P= (Q ≠ 0)

51)

Let α, β, γ are roots then x3 – ax2 + bx + c = (x – α) (x – β) (x – γ)

Put x = 6
(6 – α) (6 – β) (6 – γ) = 3
Case-I : 6 – α = 1, 6 – β = +1, 6 – γ = 3
⇒ α = 5, β = 5, γ = 3
So, a = 5 + 5 + 3 = 13
Case-II : (6 – α) = –1, 6 – β = –1, 6 – γ = 3
α = 7, β = 7, γ = 3
a = 17
Case-III : 6 – α = –1, 6 – β = 1, 6 – γ = –3
α = 7, β = 5, γ = 9
a = 21

52) D = 9 + 4ai = odd number = perfect square

⇒ (2k + 1)2 = 9 + 4ai, k I
⇒ (4k2 + 4k + 1) = 9 + 4ai
⇒ 4(k2 + k) = 4(ai + 2) ⇒ k(k + 1) – 2 = ai
Thus ai = 4, 10, 18, 28, 40, ........
So general term tr = r2 + 3r
T15 = 270, t16 = 304

53) 175 = 52.7, 245 = 5.72, 875 = 53.7, 1715 = 5.73

Let α = log5, β = log7

54)

Let 7θ = π