09-12-2025

1001CJA101021250036 JA

PART-1 : PHYSICS

SECTION-I

1) Find out angular velocity of disk, if disk is confined to roll without slipping at points of contact.

Radius of disk is 5m :-

(A)

(B) 3 rad/sec
(C) 1 rad/sec
(D) 4 rad/sec

2) A circular ring of mass M and radius R lies on a smooth horizontal surface. An insect of mass m

starts moving round the ring with uniform speed v relative to the ring. Find angular velocity of

ring.

(A)

(B)

(C)

(D)

3) Assertion (A) : For a simple microscope, the angular size of the object equals the angular size of
the image.
Reason (R) : Magnification is achieved as the small object can be kept much closer to the eye than
25cm and hence it subtends a large angle.
In the light of the above statements, choose the most appropriate answer from the options given
below :

(A) Both (A) and (R) are true and (R) is the correct explanation of (A).
(B) Both (A) and (R) are true but (R) is NOT the correct explanation of (A).
(C) (A) is True but (R) is False.
(D) (A) is False but (R) is True.

4) Let I be the moment of inertia of a uniform square plate about an axis AB that passes through its
centre and is parallel to two of its sides. CD is a line in the plane of the plate that passes through the
centre of the plate and makes an angle θ with AB. The moment of inertia of the plate about the axis

CD is then equal to :-

(A) I
(B) I sin2 θ
(C) I cos2 θ
(D) I cos2 (θ/2)

5) A glass cube has a refractive index of 1.5. A light beam enters the top face obliquely and then

strikes the side of the cube. Choose the correct option.

–1
(A) if i1 < sin (2/3) then only TIR occurs on the side of the cube.
–1
(B) if i1 > sin (2/3) then only TIR occurs on the side of the cube.
(C) no TIR occurs on the side of the cube for any angle of incidence i1.
(D) sure TIR occurs on the side of the cube for every angle of incidence i1.
6) A linear object 5 mm long is located 50 cm in front of a camera lens. The image is focused on the
film plate and is 1 mm long. If the film plate is moved back 1 cm the width of the image blurs to

1mm wide. What is the F-number of the lens? (F-number = )

(A)

(B)

(C)

(D)

7) A plano-convex lens of refractive index 1.5 and radius of curvature 30 cm is silvered at curved
surface. Then minimum distance between real object & its virtual image is :-

(A) 20 cm
(B) 30 cm
(C) zero
(D) 60 cm

8) A rod of length L is hinged from one end. It is brought to a horizontal position and released. The
angular velocity of the rod when it is in vertical position is :-

(A)

(B)

(C)

(D)

9) A rigid body is rotating such that angular displacement at any instant t is given by θ = 2t2 + 3t +
4.

List-I List-II

(P) Angular velocity at t = 2 units (1) 4 units

(Q) Angular acceleration at t = 3 units (2) 0 units

(R) Average angular velocity between t = 0 and t = 2 units (3) 7 units

(S) Average angular acceleration between t = 0 and t = 2 units (4) 11 units

(A) P→4; Q→1; R→3; S→1
(B) P→3; Q→1; R→4; S→1
(C) P→1; Q→2; R→3; S→4
(D) P→4; Q→3; R→2; S→1

10) Same number of books are placed in four book cases as shown. Which bookcase is most likely to
topple forward if pulled a little at the top towards right?

(A)

(B)

(C)

(D)

11) Consider a fixed wheel of radius R. A small wheel (in the form of a uniform solid disc) of radius r
is performing pure rolling on periphery of bigger wheel. Centers of bigger wheel and smaller wheel
are joined by rigid rod such that smaller wheel can rotate freely w.r.t its centre. Rod joining the
centers is rotating with constant angular velocity ω0. Whole situation is shown in figure. Choose the
correct option: (Use R = 4r)

(A) Angular velocity of smaller wheel is ω0

(B) Angular velocity of smaller wheel is 2ω0
(C) Angular velocity of smaller wheel is 4ω0
(D) Angular velocity of smaller wheel is 5ω0

12) Plane surface of a thin plano–convex lens is silvered. If a point object is placed on principal axis
at a distance 60 cm from the lens and final image is formed at a distance 30 cm from the lens on
same side. What will be the distance of final image from the lens if the plane surface is not silvered ?

(A) 120 cm
(B) 180 cm
(C) 30 cm
(D) 90 cm

13) A solid cylinder is placed in ends on position on an inclined plane. It is found that at an angle θ
the cylinder starts to slide. When the cylinder turns on its sides and allowed to roll, it is found that

the steepest angle at which cylinder performs pure rolling is ϕ. The ratio , is :-

(A) 1/3
(B) 1
(C) 3
(D) 1/2

14) A uniform thin rod AB of mass M and length ℓ attached to a string OA of length ℓ/2 is placed on
a smooth horizontal plane and rotates with angular velocity ω around a vertical axis through O. A
peg P is inserted in the plane in order that on striking it the bar will come exactly to rest

(A)
Location of peg for rod coming to rest is r =

(B)
Location of peg for rod coming to rest is r =

(C)
Location of peg for rod coming to rest is r =

(D)
Location of peg for rod coming to rest is r =

15) Statement-I : A convex mirror always forms a virtual image.

Statement-II : A diverging beam incident on a convex mirror is reflected as a diverging beam.

(A) Statement I is true but Statement II is false.

(B) Statement I is false but Statement II is true.
(C) Both Statement I and Statement II are true.
(D) Both Statement I and Statement II are false.

16) A ray of light incident at an angle θ = 45° from air on a glass plate of refractive index is
partly reflected and partly refracted at the two surfaces of the glass as shown in figure. The

displacement y in the figure is

(A)

(B)

(C) d
(D) None of these

17) A thin lens of material having refractive index µ = 1.5 and focal length of 20 cm in air has two
mediums of different refractive indices µ1 = 4/3 and µ2 = 2.5 cover upper and lower halves of the
lens, respectively as shown in figure. If an object is placed on the principal axis, then its two images
will form one after refraction from upper part and other after refraction from lower part. Consider
the object to be at ∞, the separation between two images formed would be :-

(A) 45 cm
(B) 55 cm
(C) 85 cm
(D) 105 cm

18) In a compound microscope the focal length of the objective is 0.5 cm and that of the eyepiece is
2 cm. If the distance between lenses is 22 cm, what should the distance from the object to the
objective be if the observer focuses for image at ∞?

(A)

(B)

(C) 0.6 cm
(D) 0.8 cm

19) An astronomical telescope consists of an objective lens of focal length 90 cm and a single lens
eyepiece of focal length 7.5 cm. It is focused at a distant object in such a way that parallel rays
emerge from the eyepiece. If the object subtends an angle of 0.1° at the objective, then find the
angle subtended by the image.

(A) 0.6°
(B) 1.2°
(C) 1.8°
(D) 3.2°

20) A man wishes to break a uniform long rod (of length ℓ) by hitting it on a rock. The end of the rod
which is in his hand rotates without displacement as shown in figure. The man wishes to avoid
having a large force act on his hand at the time the rod hits the rock. At what distance from end ‘O’
on the rod should hit the rock ? (Ignore gravity).

(A)

(B)

(C)

(D)

SECTION-II

1) A parallel beam of light falls normally on the first face of a prism of small angle α. At the second
face it is partly transmitted and partly reflected, the reflected beam striking the first face again and
emerging from it in a direction making an angle of 6°30’ with the reversed direction of the incident
beam. The refracted beam is found to have undergone a deviation of 1°15’ from the original
direction. Calculate the angle (in degree) of the prism.

2) An object is hanging from a ceiling and the distance of the object from the floor is 10 m. In
between the object & the floor, we hold a convex lens such that image of object is formed on the
floor. The lens is dropped and image is formed on the floor again after 1 sec. The focal length of lens

(in m) is . Find N.

3) Observe the ray diagram for image formation of a point object O on the principal-axis of lenses. If
rectangular box is a lens then magnitude of the focal length (in cm) of this lens is 4η then value of η

is :- (Consider the rays given as paraxial).

4) A disc of mass 1 kg and radius R is free of rotate about a horizontal axis passing through its
centre and perpendicular to the plane of disc. A body of same mass as that of disc is fixed at the
highest point of the disc. Now the system is released, when the body comes to the lowest position,

its angular speed will be where x = ______. (g = 10 ms–2)

5) Find the speed (in cm/s) of the image of object.

PART-2 : CHEMISTRY

SECTION-I

1) A dilute solution having one mole of solute 'S' in 1 Kg solvent with molal elevation constant kb is
taken. Solute dimerises in the solvent. The degree of association 'α' is given as. (ΔT = Elevation in
B.P.)

(A)

(B)

(C)

(D)

2) Which of the following radical(s) can give precipitate with Hg22+ ion in form of mercurous salt?

(A) Cl–
(B) CN–
(C) S2–
(D) All of these

3) Assertion: Conversion of liquid water to vapour at pressure below it’s boiling point pressure is a
spontaneous process. (Assume T = Boiling point temperature)
Reason: All spontaneous process proceeds in a direction of increase in entropy of the system.

(A) Assertion is true, Reason is true and Reason is correct explanation for Assertion.
(B) Assertion is true, Reason is true and Reason is NOT the correct explanation for Assertion.
(C) Assertion is true, Reason is false.
(D) Assertion is false, Reason is true.
4) Which of the following solutions is a buffer with solution pH > 7 at 25°C?
[Given : Ka(CH3COOH) = 2 × 10–5, Kb(NH4OH) = 2 × 10–5]

(A) A solution made by mixing 100 mL of 0.100 M CH3COOH and 50 mL of 0.100 M NaOH
(B) A solution made by mixing 100 mL of 0.100 M CH3COOH and 500 mL of 0.100 M NaOH
(C) A solution made by mixing 100 mL of 0.100 M NH4OH and 50 mL of 0.100 M HCl.
(D) A solution made by mixing 100 mL of 0.100 M CH3COOK and 50 mL of 0.100 M CH3COOH.

5) HNO3 is more volatile than water. If an aqueous solution of HNO3 is taken then which of the
following graph correctly represent variation of vapour pressure/boiling point with composition.

(A)

(B)

(C)

(D)

6) Identify the incorrect statement from the following reactions:

(i) SnCl2 + HgCl2 → Salt X + R
(ii)
(iii) (Elemental form)
(iv) SnCl2 + Salt X → R + Q

(A) X shows yellow turbidity and is basic in nature

(B) Y is yellow ppt. and Z is soluble in water
(C) R is having metal in its highest oxidation state
(D) Q is not liquid at room temperature.

7) Match the following List.

List–I (Salts) List–II (Colour in Borax Bead Test in cold condition)

(P) Cu (1) Blue in oxidising flame

(Q) Fe (2) Green in reducing flame

(R) Cr (3) Red in reducing flame

(S) Co (4) Green in oxidising flame

(A) P-3, Q-2, R-1, S-4
(B) P-3, Q-2, R-4, S-1
(C) P-2, Q-3, R-4, S-1
(D) P-3, Q-4, R-1, S-2

8) For a pure substance A the phase diagram is represented as shown. Identify the option which is

incorrect.

(A) Triple point of the substance is (200 K and 3.8 mm of Hg)

(B) Standard boiling point of the substance should be slightly less than 400 K.
(C) Above 500 K, gas cannot be liquefied.
(D) Melting point of the substance will increase with increase in pressure.

9) 40 ml, 0.35 M NaOH solution is added to 50 ml 0.6 N H3PO4 solution. The pH of the mixture will
be: (Ka1, Ka2 and Ka3 are 10–3, 10–8, 10–12 respectively).
(A) 7.82
(B) 5.76
(C) 8.84
(D) 9.32

10) Which of the following option regarding Henry’s constant of a gas (KH) (unit = Kbar) is incorrect.

(A) KH of O2(g) at 303 K is higher as compared to KH of O2(g) at 293 K.

(B) KH of O2(g) < KH of N2(g), at same temperature.
(C) KH of H2(g) > KH of HCl at same temperature.
(D) KH of H2(g) < KH of CO2(g) at same temperature.

11) For element ‘X’ two allotropes AL1 & AL2 occurs and the conversion attains
9
equilibrium at 1.5 × 10 Pa at 300 K then comment at what pressure equilibria can be attained at
500 K. [ = 3.5 gm/ml, = 2.3 gm/ml]
Assume ΔS for the above conversion is independent of temperature and is positive.

(A) P > 1.5 × 109 Pa

(B) P < 1.5 × 109 Pa
(C) P = 1.5 × 109 Pa
(D) At any pressure

12)
Gas I and Gas II reacts to give white fume. A1 and B1 are respectively:

(A)
(B) S2–, Ba2+
(C) I–, Ag+
(D)

13) The average person can see the red colour imparted by the complex [Fe(SCN)]2+ to an aqueous
solution if the concentration of the complex is 6 × 10–6 M or greater. What minimum concentration of
KSCN would be required to make it possible to detect if 0.56 PPM (by mass) of Fe3+ is present in a
natural water sample? Given the instability constant for reaction :
; Kinstability = 10–2

(A) 0.006 M
(B) 0.015 M
(C) 0.014994 M
(D) 0.015012 M

14) 0.1 moles of a non-volatile, non-electrolyte solute in dilute dissolved in same mass of CCl4
 & CS2 solvent to form two
different dilute solutions. Identify the correct statement.

(A) Both the solutions will have same osmotic pressure at same temperature.
(B) Both the solutions will have same boiling point.
(C) Both the solutions will have same elevation of boiling point.
(D) Solution with CCl4 as solvent will have higher boiling point.

15) The samples of nitric and acetic acids shown here are both titrated with a 0.100 M solution of

NaOH(aq). Statement-I: A more volume

of equimolar NaOH (aq) is needed to reach the equivalence point in the titration of HNO3.
Statement-II: The pH at the equivalence point in the HNO3 titration will be lower than the pH at
the equivalence point in the CH3COOH titration.

(A) Statement-I is correct

(B) Statement-II is correct
(C) Statement-I is incorrect & Statement-II is correct
(D) Statement-I & Statement-II are incorrect

16) An equimolar mixture of PCl3 and Cl2 is taken (mass given = 208.5 grams). Calculate the
equilibrium pressure, if 75% of PCl3 is converted into PCl5?
PCl5(g) PCl3(g) + Cl2(g) KP = 5 atm

(A) 60 atm
(B) 75 atm
(C) 45 atm
(D) 120 atm

17) Which is incorrect order for following aq. solution assume 100% ionisation of electrolyte and (m
M).

(A) Osmotic pressure 1M urea < 1M NaCl < 1M Na3PO4 < 1M K4[Fe(CN)6]
(B) Boiling point 1M urea < 1M NaCl < 1M Na3PO4 < 1M K4[Fe(CN)6]
(C) Freezing point 1M urea > 1M NaCl > 1M Na3PO4 > 1M K4[Fe(CN)6]
(D) Depression in Freezing point 1M urea > 1M NaCl > 1M Na3PO4 > 1M K4(Fe(CN)6)

18) A metal M and its compound can give the following observable changes in sequence of reactions.
Metal is:

(A) Mg
(B) Pb
(C) Zn
(D) Sn

19) SrCO3 (Ksp = 10–10) and ZnCO3 (Ksp = 1.5 × 10–11) are dissolved together in a solution. The ratio

of in the solution is:

(A)

(B)

(C)

(D)

20) Which of the following is not correct for an ideal solution?

(A) Raoult's law is obeyed for entire concentration range and temperatures
(B) ΔHmix = 0
(C) ΔVmix = 0
(D) ΔSmix = 0

SECTION-II

1) If the number of moles of NH3 must be added to one litre of a 0.1 M AgNO3 to reduce
Ag+ concentration to 2 × 10–7 M is expressed as 3.84 × 10–x, then ‘x’ is?
(Given: Kdiss. of [Ag(NH3)2]+ is 6.8 × 10–8, = 0.184)

2) Find the number of sulphides which give H2S gas with dilute HCl.
FeS, K2S, ZnS, MnS, PbS, CdS, NiS, CoS, Sb2S3, HgS
3) The following equilibria are established on mixing two gases A2 and C.
3A2(g) A6(g); KP = 1.6 atm–2
A2(g) + C(g) A2C(g); KP = 'x' atm–1
When A2(g) and C(g) are mixed in 2 : 1 molar ratio, the total pressure of gases at equilibrium is
found to be 1.4 atm and partial pressure of A6(g), 0.2 atm. The value of '4x' is:

4) If the mole fraction of a solute in a solution is changed from , then the ratio of original
molality to the new molality of the solution will be 1 : x. What is the value of x?

5) Find the number of oxidants, which can oxidise Mn2+(aq.).

H2O2/OH–, KMnO4, PbO2/HNO3, NaBiO3/HNO3, S2O82–, I2

PART-3 : MATHEMATICS

SECTION-I

1) Let If the vector can be expressed as

where x, y, z are scalar, then which of the following is incorrect :

(A) x + 2z = 0
(B) x = 2y = 2z = 1
(C) y + z = 0
(D) x = 2y

2) Let P denotes the plane consisting of all points that are equidistant from the points A(–4, 2, 1) and
B(2, –4, 3) and Q be the plane x – y + cz = 1 where c ∈ R then which of the following option is false :

The plane P is the parallel to plane Q if c =

(A)

(B) The plane P is the parallel to plane Q if c = 3

(C) If angle between the planes P & Q is 45°, then product of all possible values of ‘c’ is –2
If angle between the planes P and Q is 45°, then sum of all possible values of ‘c’ is
(D)

3) Assertion: Let function f : R → R is such that f(x) f(y) – f(xy) = x + y for all x, y ∈ R, then f(x) is a
Bijective function.
Reason : f(x) is a linear function

(A) Assertion is True, Reason is True ; Reason is a correct explanation for Assertion
(B) Assertion is True, Reason is True ; Reason is not a correct explanation for Assertion
(C) Assertion is True, Reason is False.
(D) Assertion is False, Reason is True.

4) An even periodic function f : R → R with period 4 is such that .

The value of {f(5.12)} is (where {.} denotes fractional part function) is :

(A) {f(3.26)}
(B) {f(7.88)}
(C) {f(2.12)}
(D) {f(5.88)}

5) Let function , then the solution of the equation

is

(A) 0
(B) –2
(C) 5
(D) None of these

6) If , then the value of g(g(100)) is equal to :

(A) –1
(B) 0
(C) 1
(D) 100

7) Let be defined as , then the least value of ‘a’ for which f(x) is
an injective function is :

(A)

(B)

(C)

(D) 1

8) Let f : R → R defined by then which of the following hold(s) good

(A) Range of f is (–∞, 1]

(B) f is even function
(C)
has 5 solutions
(D) f(x) is bijective function

9) Match the statement in List-I with given value in List-II

List-I List-II

If and are any two unit vectors, then possible integer in

(A) (I) 0
the range of can be

If and are non coplanar vectors then the vectors

(B) and wh (II) 1
ere λ is a scalar, can be coplanar, for λ equal to

The distance of the z-axis from the image of the point A(2,
(C) (III) 2
–3, 3) in the plane x – 2y – z + 1=0 is

The figure shows a pyramid OABCD (where O is the origin)

the base OABC is a square of side 1 unit. The point D is a
distance of 1 unit from the square base. D lies on the normal
passing through the centroid of the base. If the angle
between and is , then K is equal to

(D) (IV) 4

(A) (A) – IV, (B) – II, (C) – I, (D) – III

(B) (A) – IV, (B) – I, (C) – II, (D) – III
(C) (A) – III, (B) – II, (C) – IV, (D) – I
(D) (A) – II, (B) – III, (C) – IV, (D) – I

10) The least integral value of k for which

is :

(A) –7
(B) –5
(C) –3
(D) 5

11) Let (where [.] denotes greatest integer function), if A

and B denote the domain and range of f(x) respectively then the number of integers in A ∪ B is :
(A) 1
(B) 2
(C) 3
(D) 4

12) If , (a, b, c, d ∈ R) then the value of

(A)

(B)

(C) 0

(D)

13) Consider planes

P1 : x + 2y – z = 3
P2 : 2x – y + λz = 3
P3 : x – 3y – 4 = 0
P4 : 4y – z + 5 = 0
Planes P1 and P2 intersect to form line L1. Planes P3, P4 intersect form line L2 Value of λ for which
lines L1 and L2 are coplanar is :

(A)

(B)

(C) –1

(D)

14) and non-zero vector are such

that Identify the incorrect statement :

(A) can be
(B)
(C)
(D)

15) Consider three planes

P1 : x – y + z = 1
P2 : x + y – z = –1
P3 : x – 3y + 3z = 2
Let L1, L2, L3 be the lines of intersection of the planes P2 and P3, P3 and P1 & P1 and P2 respectively.
Statement-1 : At least two of the lines L1, L2 and L3 are non-parallel.
because
Statement-2 : The three planes do not have a common point.

(A) Statement-1 is True, Statement-2 is True

(B) Statement-1 is False, Statement-2 is False
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

16) A ray of light is coming along the line L = 0 and strikes the plane mirror kept along the plane P
= 0 at B. A(2, 1, 6) is a point on the line L = 0 whose image about P = 0 is A′. It is given that L = 0 is

and P = 0 is x + y – 2z = 3 then distance between A′ and B is then λ

is :

(A) 10
(B) 20
(C) 30
(D) Data insufficient

17) Consider two lines as shown , then

equation of line of shortest distance can be :

(A)

(B)

(C)

(D) No unique line exist

18) OABC is a tetrahedron in which O is the origin and position vector of points A, B, C are
and respectively. An integral value of α for which

shortest distance between OA and BC is , will be :

(A) 3
(B) 5

(C)

(D)

19) Consider two lines and If a line

L whose direction ratios are < 2, 2, 1> intersect the line L1 and L2 at points A and B, then the
distance AB is

(A) 20
(B) 19
(C) 18
(D) 17

20) A vector given moves such that it is always parallel to the vector
then magnitude of is :

(A) constant
(B) a quadratic function of time
(C) a linear function of time
(D) a cubic function of time

SECTION-II

1) Let where [y] and {y} denote greatest integer and fractional part function
respectively and . If then find the number
of integral value of k :

2) If , where A, B, C are non-zero real constants and

, then find the value of

3) Let be defined as be an onto function where

λ is a real parameter belonging to (0, 10), then the possible integral value of λ is

4) Let a function f defined from as If the function is surjective,

then the sum of all possible integral values of p in [–100, 100] is . The value of (k – 2) is

5) Let the equation be satisfied by three distinct values of x, where .

If and where g(x) is a linear function then
the value of g(2) is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B B A D A C B A C D A C C B A D A B A

SECTION-II

Q. 21 22 23 24 25
A. 2 15 2 5 8

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A C C A C B D A D B D A D C B D C C D

SECTION-II

Q. 46 47 48 49 50
A. 1 4 6 2 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B A B B D A B B D D C D C D B C A C A

SECTION-II

Q. 71 72 73 74 75
A. 1 8 4 8 2
 SOLUTIONS

PART-1 : PHYSICS

1)
ωR – V = 10
V + Rω = 20

ω= =3

2)

On conserving angular momentum

3)

is same for both object and image

u0 < D
Hence m > 1

4)

According to the perpendicular axes theorem

lz = lx + ly
Since the plate is quite symmetrical about AB and CD we can use again perpendicular axes
theorem
IAB = ICD = I

5)
sin i1 = 1.5 sin i1’
i1’ + i2 = 90°
i1 max = 90°

Hence sure TIR at the side.

6)

u = 50 cm and

f= cm

or D = 0.1 v = 1 cm. Therefore, F = f/D = 8.33

7)

The given arrangement behaves as a concave mirror of focal length 10 cm.

u → –ve
v → +ve (for virtual image)
If object is very close to the silvered lens then distance between them is zero.
8)

Correct answer is B.

9) Angular velocity ω = = 4t + 3
⇒ (w)t = 2 = 4(2) + 3 = 11 units

Angular acceleration
⇒ (α)t = 3 = 4 unit
At t = 0, θ = 2(0) + 3(0) + 4 = 4
At t = 2, θ = 2(2)2 + 3(2) + 4
= 8 + 6 + 4 = 14

<ω> = units
At t = 0, ω = 4(0) + 3 = 3 units
At t = 2, ω = 4(2) + 3 = 11 units

<α> units

10)
In C, mg will also help in toppling

11)
ω,r = ω0 (R+r) ⇒ ω1 = 5ω0

12) Focal length of silvered mirror

f = –20 cm
Focal length of unsilvered lens will be 40 cm

So,

⇒ v = 120 cm.

13)

f = mg sin θ
or no sliding, f < fL
⇒ mg sin θ < μs mg cos θ
⇒ tan θ = μs
mg sin ϕ – f = ma,

and a =

For pure rolling, f < f2

⇒ tan ϕ < 3μs so =3

14) COAM about peg

15)

Correct answer is (B).

16) θ = θ
17)

Focal length for upper half is,

Focal length for lower half is,

If the object is at infinity, two will form at corresponding focuses.

So, the required separation is,
x = |f1| + |f2| = 80 + 25 = 105 cm

18)

For eyepiece object distance = 2 cm

For objective image distance = 22 – 2 = 20 cm

19) Magnification =

20)
Distance from end ‘O’

21)

δ1 = (μ – 1) α = 1.25°
μ 2α = 6.5°
Solving μ = 1.625, α = 2°

22)

23)

Optical reversibility

x=L
its diverging lens of f = –8 cm.
 24)
using conservation of mechanical energy

Given

x=5

25)

Mirror formula
Now, velocity of image after differentiating mirror formula

and

So,

PART-2 : CHEMISTRY

26)
1–α α/2

ΔTb = kb × i × m ⇒
27)

28) Le–Chatelier’s principle, For spontaneous proper ΔGreaction must be (–)ve.

29) (A) nACOH = 10 mmol; = 5 mmol ⇒ [AcO–] = [AcOH] ⇒ pH = pKa < 7.

(B) > nAcOH (not a buffer solution)
(C) = 10 mmol; = 5 mmol ⇒ [NH4+] = [NH4OH] ⇒ pH (14 – pKb) > 7.
(D) = 10 mmol; nAcOH = 5 mmol ⇒ Acidic buffer solution ⇒ pH < 7.

30)
Solution shows –ve deviation in P vs composition.

31)

X → Hg2Cl2 (White precipitate)

Y → Sn(OH)2↓ White precipitate
Z → [Sn(OH)4]2–
P → Au,
R → SnCl4
Q → Hg

32) Oxidising flame Reducing flame

(P) Cu ⇒ Green and Blue Red Brown
(Q) Fe ⇒ Yellow–Brown and Yellow Green
(R) Cr ⇒ Green Green
(S) Co ⇒ Blue Blue

33) Triple point is (200 K, 5 × 10–3 atm)

(200 K, 5 × 10–3 × 760 mm of Hg)
(200 K, 3.8 mm of Hg)
Boiling point slightly less than 400 K
Above 500 K, gas – liquid transition cannot occur without change in temperature as 500 K is
critical point.
34) nNaOH = 14 m mole ;
Final solution will have 6 mmole NaH2PO4 + 4 mmole Na2HPO4

35) As temperature increase; KH increase.

Also if solubility increase; KH decrease.
And solubility for non-polar substances depends on induced polarity, CO2 & HCl are highly
soluble in H2O.

36) ΔG = Negative value as temperature increases to 500 K.

Reaction is forward favouring at lower pressure as product is more dense than reactant.

37) NH4+ is only cation to liberate gas on reaction with group reagent.

38) 0.56 gm of Fe present in 106 gm of H2O

mole present in 106 ml of H2O

= 103 ×
Fe3+ = [10–5] M
Fe3+ + SCN– Fe(SCN)2+
10–5 M a 0
–5
10 – x a – x x = 6 × 10–6

a = 0.015006 M

39) Kb of CCl4 > Kb of CS2 both non polar.

∴ Kb ∝ TBP ∝ Mole mass

40) Equivalents of both acids are same = 0.025.

Hence volume of equimolar NaOH consumed will be same for both acid solutions.
Statement-2: At end point WA, SB titration salt will show basic salt hydrolysis;
pH > 7 & SA + SB → pH = 7

41) PCl5(g) PCl3(g) + Cl2(g) KP = 5 atm

For PCl3(g) + Cl2(g) PCl5 (g) KP =

1 1
1–x 1–x x x = 0.75 Total moles = 1.25 moles

Let PT total pressure at equilibrium.

PT = 75 atm

42) Colligative properties of solution is directly proportional to number of particles of solute.

43) MgS not ppt;

PbS → Black ppt.
SnS → Brown ppt;
Zns → White ppt.

44) 10–10 = [Sr2+] [CO32–]

1.5 × 10–11 = [Zn2+] [CO32–]

45) For a ideal solution ΔSmix = +ve.

46)

⇒ [NH3] = 0.184 M
[NH3]total added for complexion = 0.184 + 2 × 0.1 = 0.384 mole/litre
= 3.84 × 10–1 mole/L

47) FeS, K2S, ZnS and MnS give H2S gas with dilute HCl, whereas PbS, CdS, NiS, CoS, Sb2S3
& HgS do not give H2S gas with [Link].

48) 3A2(g) A6(g); KP = 1.6 atm–2

Initial partial pressure 2P0 0
Equilibrium partial pressure 2P0 - 3a - b a
A2(g) + C(g) A2C(g); KP = 'x' atm–1
Initial partial pressure 2P0 P0 0
Equilibrium partial pressure 2P0 - b - 3a P0 - b b
From question, a = 0.2,

⇒ and (2P0 - 3a - b) + a + (P0 - b) + b = 1.4

⇒ P0 = 0.7 and b = 0.3
 Now, = 1.5 atm–1

49)
XB = mole fraction of solute
MA = molar mass solvent

50)

PART-3 : MATHEMATICS

51)
Taking dot product with

x + 2z = 0, x = 2y

52) P :

P:

53)

As f(x) f(y) – f(xy) = x + y

Put x = y = 0 ⇒ f(0) = 0 or 1
Now putting y = 0
f(x) f(0) – f(0) = x
f(0) [f(x) – 1] = x
⇒ f(0) ≠ 0
⇒ f(x) = x + 1
54)

55) Rg(x – 2013) =

x – 2013 = 2014x + 2013 x – 2013 = 4026 – x

x = –2
reject

56)

g(g(x)) = x

57)

For the function to be one-one, it must be monotonic.

f ′ (x) = x2 + x + a > 0
D<0
1 – 4a < 0

58)

59) (A) Let

(B) for
(C) Image of R in plane is (0, 1, 5) so distance from z-axis = 1

(D) A(1, 0, 0) B(1, 1, 0) C(0, 1, 0)

60) ,
So for x ∈ R if k > 2 and D < 0
⇒ k ∈ (4, ∞)

61) Domain Range = {0, 1, 2}, Integers in A ∪ B = {–1, 0, 1, 2}

62) Given equation will hold only when and

63)

L1 and L2 are coplanar if

64)

65) The direction ratios of L1 L2 L3 are proportional to (0, 1, 1)

66)

67) Let points P(3r + 8, –16r – 9, 7r + 10) and Q(3λ + 15, 8λ + 29, –5λ+5)
and
So on solving r = –1 and λ = –2
,
68) Equation of
Equation of

Shortest Distance =

69)

λ = 2, μ = 0

AB = 18

70)
Multiply both side by

An integration

So,

71)

f(x) = 1 for x ∈ R
g(1) < 0

72)

73) Let
∵ f(x) is ONTO so
⇒ α ≥ 0 for x ∈ R
So, D = 0 ⇒ λ = 4
74)
f(2) ≥ f(2 + h)
2 + p2 ≥ 4p + 5
or
(Reject) (∵ Range is R)

75) a = 1, ,
f(g(x)) = 2g(x)+1
= 6x – 7
So, g(x) = 3x – 4