12-12-2025

2302CJA101021250075 JM

PART-1 : PHYSICS

SECTION-I

1) Which of the following relationships between the acceleration a and displacement x of the particle
involve simple harmonic motion :-

(A) a = 0.7 x
(B) a = –200 x2
(C) a = –10 x
(D) a = 100 x2

2) The equation of motion of a particle executing SHM is + kx = 0. The time period of the
particle will be :–

(A)

(B)

(C) 2πk
2π
(D)

3) The variation of acceleration (a) and displacement (x) of the particle executing SHM is indicated
by the following curve :–

(A)

(B)
(C)

(D)

4) Which of the following equation represents damped oscillation :-

(A)

(B)

(C)

(D)

5) A particle is executing S.H.M. between x = ±A. The time taken to go from 0 to is T1 and to go

from to A is T2; then

(A) T1 < T2
(B) T1 > T2
(C) T1 = T2
(D) T1 = 2T2

6) The maximum velocity of a simple harmonic motion represented by is given

by :-

(A) 300

(B)

(C) 100

(D)

7) Out of the following functions representing motion of a particle which represents SHM
(A) y = sin ωt – cos ωt
(B) y = sin3 ωt
(C) y = 5cos
(D) y = 1 + ωt + ω2t2

(A) Only (A) and (B)

(B) Only (A)
(C) Only (D) does not represent SHM
(D) Only (A) and (C)

8) Part of a simple harmonic motion is graphed in the figure, where y is the displacement from the

mean position. The correct equation describing this S.H.M is

(A) y = 4 cos (0.6t)

y = 2 sin
(B)

y = 4 sin
(C)

(D)
y = 2 cos

9) Two sound waves are respectively;

y = a sin(wt-kx) and y = b cos(wt–kx)
The phase difference between the two waves is :-

(A) π/2
(B) π/4
(C) π
(D) 3π/2

10) A plane progressive wave is shown in the adjoining phase diagram. The wave equation of this
wave, if its position is shown at t = 0 is :

(A) y = 0.05 sin 2π (300 t – x)

(B) y = 0.05 sin 2π (300 t + x)
(C) y = 0.05 sin 8π (300 t + x)
(D) y = 0.05 sin 8π (300 t – x)

11)

A transvers harmonic wave on a string is described by y = 3 sin[36t + 0.018 x + ] where x and y

are in cm and t in s. The least distance between two sucessive crests in the wave is :

(A) 2.5 m
(B) 3.5 m
(C) 1.5 m
(D) 4.5 m

12)

A transverse wave is travelling along a stretched string from right to left. The figure shown
represents the shape of the string (snap short) at a given instant. At this instant.

(A) The particles at A, B and H have dowanward velocity

(B) The particles at D, E and F have dowanward velocity
(C) The particles at C, E and G have zero velocity
(D) The particles at A and F have maximum velocity

13) A travelling harmonic wave is represented by the equation y (x, t) = 10–3 sin (50 t + 2x), where x
and y are in meter and t is in seconds. Which of the following is a correct statement about the wave?
The wave is propagating along the

(A) negative x-axis with speed 25 ms–1

(B) The wave is propagating along the positive x-axis with speed 25 ms–1
(C) The wave is propagating along the positive x-axis with speed 100 ms–1
(D) The wave is propagating along the negative x-axis with speed 100 ms–1

14) A closed organ pipe of length L and an open organ pipe contain gases of densities ρ1 and ρ2
respectively. The compressibility of gases are equal in both the pipes. Both the pipes are vibrating in
their first overtone with same frequency. The length of the open organ pipe is :

(A)

(B)
(C)

(D)

15) The frequency of first overtone of a closed organ pipe of length L is f1. A hole is made at a

distance from the closed end so that it becomes an open pipe. Now the frequency of first overtone

of open pipe is f2. Then is :-

(A)

(B)

(C)

(D)

16)

An engine is moving on a circular track with a constant speed. It is blowing a whistle of frequency
500 Hz. The frequency received by an observer standing stationary at the centre of the track is

(A) 500 Hz
(B) More than 500 Hz
(C) Less than 500 Hz
(D) More or less than 500 Hz depending on the actual speed of the engine

17)

In the 5th overtone of an open organ pipe, there are (N-stands for nodes and A-for antinodes)

(A) 2 N, 3 A
(B) 3 N, 4 A
(C) 4 N, 5 A
(D) 5 N, 4 A

18) The length of a metal wire is ℓ1 when the tension in it is T1 and is ℓ2 when the tension is T2. The
natural length of the wire is :-

(A)

(B)
(C)

(D)

19) The breaking stress for a wire of radius r of given material is F N/m2. The breaking stress for the
wire of same material of radius 2r is:

(A) F/4
(B) F/2
(C) F
(D) 2F

20) A metal rod of Young's modulus Y and coefficient of thermal expansion a is held at its two ends
such that its length remains invariant. If its temperature is raised by t°C, the linear stress
development in it is :-

(A)

(B) Yαt

(C)

(D)

SECTION-II

1) A particle vibrates in SHM along a straight line. Its greatest acceleration is 5π2 cm/s2 and the
velocity of the particle is 3π cm/s, when its distance from the equilibrium position is 4 cm. The
product of amplitude and the period of oscillation of the vibrating particle is :

2) A simple pendulum of length 0.4 m oscillates with an angular amplitude of 0.04 rad. Find speed of
bob when the string make angle of 0.02 rad with the vertical. [Take g = 10 m/s2]

3) A simple harmonic motion is represented by,

y = 5(sin 3πt + cos3πt)cm. The amplitude and time period of the motion are :- (in cm)

4) A mass of 2 kg is put on a flat pan attached to a vertical spring fixed on ground as shown in the
figure. The mass of the spring and pan is negligible. When pressed slightly and released the mass
execute a simple harmonic motion. The spring constant is 200 N/m. What should be minimum
amplitude (in cm) so that mass get detached from the pan. Take (g = 10 m/s2).

5) A block of mass 0.9 kg attached to a spring of force constant k is lying on a frictionless floor. The
spring is compressed to cm and the block is at a distance cm from the wall as shown in the
figure. When the block is released, it makes elastic collision with the wall and its period of motion is

0.2 sec. Find the approximate value of k. (in N/m)

PART-2 : CHEMISTRY

SECTION-I

1) Choose the correct statements of the following

(a) Copper can displace iron from FeSO4 solution
(b) Iron can displace copper from CuSO4 solution
(c) Silver can displace copper from CuSO4 solution
(d) Iron can displace silver from AgNO3 solution

(A) a and b
(B) b and c
(C) b and d
(D) a and d

2)

The e.m.f. of following cell at 300K, when

[Cl–] = [Br2] = [Br–] = 0.01M and Cl2(g) at 1 atm.

Cl2(g) + 2Br–(aq.) —→ 2Cl–(aq) + Br2(aq.) E° = 0.29V

(A) +0.29V
(B) 0.23V
(C) –0.35V
(D) 0.35V

3)

Calculate the equilibrium constant for

Hg22+ —→ Hg + Hg2+
Given :

(log2 = 0.3, log3 = 0.4)

(A) 5 × 10–3
(B) 6 × 10–3
(C) 7 × 10–3
(D) None of these

4) A conductance cell was filled with a 0.02 M KCl solution which has a specific conductance of
2.768 × 10–3 ohm–1 cm–1. If its resistance is 82.4 ohm at 25°C, the cell constant is :-

(A) 0.382 cm–1

(B) 0.2281 cm–1
(C) 0.581 cm–1
(D) 0.928 cm–1

5) The standard reduction potential of Cu2+/Cu and Cu2+/Cu+ are 0.339 V and 0.153 V respectively.
The standard electrode potential of Cu+/Cu half cell is-

(A) 0.525 V
(B) 8.27 V
(C) 0.184
(D) 0.490 V

6) A cell is constituted as follows

Pt|H2 (1 atm) |HA1| |HA2| H2 (1 atm) | Pt
The pH of two acids solutions HA1 and HA2 are 5 and 3 respectively. The emf of the cell is -

(A) 0.059 V
(B) 0.0295 V
(C) 0.118 V
(D) – 0.118 V

7) Given are E° values for some half reactions

I2 + 2e– → 2I– ; E° = 0.54 V
MnO4– + 8H+ + 5e–→ Mn2+ + 4H2O ; E° = 1.52 V Fe3+ + e– → Fe2+ ; E° = 0.77 V
Sn4+ + 2e– → Sn2+ ; E° = 0.1 V
The strongest reducant and oxidant respectively are :

2+ –
(A) Sn , MnO4
– 4+
(B) MnO4 , Sn
 3+
(C) I2, Fe
2+
(D) I2, Sn

8) In acidic medium, MnO2 is an oxidant as, . If the pH of the

solution is decreased by one unit, the electrode potential of the half cell Pt MnO2, Mn2+ will change
by

(A) –0.118 V
(B) 0.118 V
(C) 0.236 V
(D) –0.236 V

9) In the given figure, the electrolytic cell contains 1 L of an aqueous 1 M Copper (II) sulphate
solution. If 0.4 mole of electrons are passed through cell, the concentration of copper ion after

passage of the charge will be :

(A) 0.4 M
(B) 0.8 M
(C) 1.0 M
(D) 1.2 M

10) Calculate the standard cell potential in(V) of the cell in which following reaction takes place :
Fe2+(aq) + Ag+(aq) → Fe3+(aq) + Ag(s)
Given that

(A) x + 2y – 3z
(B) x – z
(C) x – y
(D) x + y – z

11) If the standard reduction potential for four divalent elements X, Y, Z, W are – 1.46 V, – 0.36V,
0.15 V and – 1.24 V respectively, then :-

(A) X will displace Z+2 from aqueous solution

(B) Y will displace Z+2 from aqueous solution
(C) W will displace Z+2 from aqueous solution
(D) All the above statements are correct

12) The position of some metals in the electrochemical series in decreasing electropositive character
is Mg > Al > Zn > Cu > Ag. What will happened if copper spoon is used to stirred a solution of
aluminium nitrate ?

(A) The spoon gets coated with aluminium

(B) An alloy of aluminium and copper is formed
(C) No reaction occurs
(D) The solution starts turning blue

13) What is the hybridization of the central atom of .

(A) sp
(B) sp2
(C) sp3
(D) sp3d

14)

The stability of dihalides of group 14 elements follow which of the order ?

(A) SiCl2 < GeCl2 < PbCl2 < SnCl2

(B) GeCl2 < PbCl2 < SnCl2 < SiCl2
(C) SiCl2 < GeCl2 < SnCl2 < PbCl2
(D) GeCl2 < SiCl2 < PbCl2 < SnCl2

15) Boric acid in water :-

(A) triprotic strong acid

(B) triprotic weak acid
(C) monoprotic weak acid
(D) it is not a protic acid

16)

Solid CO2 is

(A) Ionic solid

(B) Covalent solid
(C) Molecular solid
(D) Metallic solid

17) Select wrong statement about diborane (B2H6) :-

(A) 2C-2e bond formed by terminal Hydrogen

(B) 3C-2e bond formed by bridge Hydrogen
(C) 3C-2e bond, called banana bond
(D) All hydrogen are present in same plan

18) Ionisation enthalpy (ΔtH1kJ mol–1) for the elements of Group 13 follows the order. :-

(A) B > Al > Ga > ln > Tl

(B) B < Al < Ga < ln < Tl
(C) B < Al > Ga < ln < Tl
(D) B > Al < Ga > ln < Tl

19)

Metal hydrides are ionic, covalent or molecular in nature. Among LiH, NaH, KH, RbH, CsH, the
correct order of increasing ionic character is :-

(A) LiH > NaH > CsH > KH > RbH

(B) LiH < NaH < KH < RbH < CsH
(C) RbH > CsH > NaH > KH > LiH
(D) NaH > CsH > RbH > LiH > KH

20)

The correct lewis acid for boron halides is:

(A) BF3 > BCl3 > BBr3 > BI3

(B) BCl3 > BF3 > BBr3 > BI3
(C) BI3 >BBr3 > BCl3 >BF3
(D) BBr3 > BCl3 > BI3 >BF3

SECTION-II

1) How many type of oxides do carbon family form ?

2) For a cell, Cu(s) |Cu2+(0.001M| |Ag+(0.01M)| Ag(s) the cell potential is found to be 0.43 V at 298 K.
The magnitude of standard electrode potential for Cu2+/Cu is ___× 10–2 V.

3) Ionic conductance at infinite dilution of Al3+ and SO42– ions are 189 ohm–1 cm2 eq–1 and 160
ohm–1 cm2 eq–1 respectively. Limiting conductance of Al2 (SO4)3 in ohm–1 cm2 eq–1 will be :-

4) The cell Pt\H2(g) (1 atm) \ H+ ; pH = x \\ Normal calomal electrode has EMF of 0.64 volt at 25ºC.
The standard reduction potential of normal calomal electrode is 0.28 V. What is the pH of solution in
anodic compartment.
Take

5)
Cell potential at 25°C will be [multiple your answer by 1000]

PART-3 : MATHEMATICS

SECTION-I

1) The value of

is:

(A) 1
(B) 2
(C) 0
(D) 1/2

2) The value of where [·] denotes the greatest integer function, is equal to

(A) 0
(B) 1
(C) –1
(D) does not exist

3) If f(n + 1) = and f(n) > 0 for all n ∈ N then is equal to

(A) 3
(B) –3

(C)

(D) 0

4) is equal to

(A) e–5
(B) e5
(C) e10
(D) e1/5

5)

(A)

(B)

(C)

(D)

6) If
is continuous in the interval [–1, 1] then p equals

(A) –1
(B) 1
(C) 1/2
(D) –1/2

7) Let .
If ƒ(x) is differentiable at x = 0, (pr ≠ 0), then-

(A) (p – r)2 + (q + 5)2 = 0

(B) (p + r)2 + (q + 5)2 = 0
(C) (p – r)2 + (q – 5)2 = 0
(D) (p + r)2 + (q – 5)2 = 0

8) Let ƒ (x) = a|x|3 + b|x|2 + c|x| + d, where a, b, c and d are constants, then :-

(A) ƒ(x) is differentiable at x = 0, whatever be a, b, c and d

(B) ƒ(x) is not differentiable at x = 0, whatever be a, b, c and d
(C) If ƒ(x) is differentiable at x = 0, then c = 0
(D) If ƒ(x) is differentiable at x = 0, then a = 0, c = 0

9) If ƒ(x) ƒ(y) + 2 = ƒ(x) + ƒ(y) + ƒ(xy) and ƒ(1) = 2, ƒ'(1) = 2 then sgn ƒ(x) is equal to
(where sgn denotes signum function) -

(A) 0
(B) 1
(C) –1
(D) 4

10) Let R be the set of real numbers and ƒ : R → R, be a differentiable function such that
|ƒ(x) – ƒ(y)| < |x – y|3 ∀ x,y ∈ R. If ƒ(10) = 100, then the value of ƒ(20) is equal to -

(A) 0
(B) 10
(C) 20
(D) 100

11) If , then =?

(A)

(B)

(C)

(D)

12) , (p is constant), then at x = 0 is-

(A) p
(B) p + p2
(C) p + p3
(D) independent of p

13) If x = 2 cos t – cos 2t, y = 2 sin t – sin 2t, then at t = is :-

(A) –5/2
(B) –3/2
(C) 3/2
(D) 5/2

14) An apache helicopter of enemy is flying along the curve given by y = x2 + 7. A soldier, placed at
(3, 7), wants to shoot down the helicopter when it is nearest to him. then the nearest distance is
(A)
(B)
(C)
(D)

15) Let f(x) = ,

find the set of values of "a" such that x = 2 is a local minima:

(A) (–∞, –1] ∪ [10, ∞)

(B) (–1, 10)
(C) (–∞, –10]
(D) (–∞, ∞)

16)

Let g(x) = f(log x) + f(2 – log x)and f "(x) < 0 ∀ x ∈ (0, 3).
Then find the interval in which g(x) increases : –

(A) (0, 1)
(B) (1, 2)
(C) (2, 3)
(D) (0, e)

17) The equation sin x + x cos x = 0 has at least one root in

(A)

(B)

(C)

(D)

18) The tangent to curve y1 = ax2 + bx + at (1, 2) is parallel to normal at point (–2, 2) on curve
y2 = x2 + 6x + 10, then value of (a – 2b) is :

(A) 4
(B) –4
(C) 2
(D) 6

19) Water is dripping out at a steady rate of 1 cu cm/sec through a tiny hole at the vertex of the
conical vessel, whose axis is vertical. When the slant height of water in the vessel is 4 cm, find the

rate of decrease of slant height, where the vertical angle of the conical vessel is
(A)
cm/sec

(B)
cm/sec

(C)
cm/sec

(D)
cm/sec

20)

If , then =

(A)

(B)

(C)

(D)

SECTION-II

1) The maximum value of the function

f(x) = 3x3 – 18x2 + 27x – 40 on the set is :

2) Let y = x3 – 6x2 + 9x + 1 be an equation of a curve, then the x-intercept of the tangent to this
curve whose slope is least, is

3) A differentiable function f satisfying a relation f(x + y) = f(x) + f(y) + 2xy(x + y) –

and . Then the value of [f(2)] is (where [x] represents greatest integer function)

4) The value of equals where [.] denotes greatest integer function

5) If f(1) = 1, f' (1) = 3, then the derivative of f(f(f(x))) + (f(x))2 at x = 1 is :

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A A D A A D B A D B B A C D A C C C B

SECTION-II

Q. 21 22 23 24 25
A. 10 68 10 10 100

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D B B A C A B A A D C C C D C D D B C

SECTION-II

Q. 46 47 48 49 50
A. 2 34 349 6 41

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A A B A D A C B D B D B B A D B D A A

SECTION-II

Q. 71 72 73 74 75
A. 122 3 8 399 33
 SOLUTIONS

PART-1 : PHYSICS

1)

a = –ω2x
a = –( )2x
(3) is S.H.M.

2)

ω2 = K ⇒

3) a = –ω2x
Straight line

4) Damped oscillation → F = – Kx – bv

5) v = ω

6) vmax = Aω = 3 × 100 = 300

7) For SHM, ∝–y

8) y = asin(ωt + ϕ)
y = 2 sin (ωt + ϕ)
at t = 0, y = – 2

– 2 = 2 sin ϕ ⇒ ϕ = –

∴ y = 2 sin

9) y1 = asin (ωt – kx)

y2 = bcos (ωt – kx)
y2 = bsin (ωt – kx + π/2)

∴ Phase difference is

10) Amplitude A = 0.05 m

2λ = 0.5
or λ = 0.25 m

Frequency f = = 1200 Hz
Angular frequency ω = 2πf = 2400 π rad/s

Propagation constant k = = 8π/m

From the phase diagram, it is clear that
at t = 0, x = 0
Hence, the given wave is a sine wave travelling in +x direction. The standard equation for
such a wave is written as
y = A sin (ωt – kx)
∴ y = 0.05 sin (2400πt – 8πx)
y = 0.05 sin 8π (300 t – x)

11)

12)

DEF will have dowanward velocity.

13) y= a sin(ωt + kx)

⇒ wave is moving along –ve x-axis with speed

14) Velocity of sound, υ ∝

= .........(i)
∵ First over tone of closed organ pipe
= First overtone of open organ pipe

⇒ L2 =

L1 = [∵L1= L(given)]

15) f1 =

f2 =
16)

Since there is no relative motion between the source and listener, So apparent frequency
equals original frequency.

17)

In open organ pipe 5th overtone corresponds to 4th harmonic mode.

Also in open pipe, Number of nodes = Order of mode of vibration and number of antinodes =
(Number of nodes + 1). Here number of nodes = 4, Number of antinodes = 4 + 1 =5.

18) Let the natural length of wire = ℓ

Change in length (ℓ1 – ℓ) when tension T1.
and cange in length (ℓ2 – ℓ) when tension T2.

∴ (ℓ1 – ℓ) = ...(i)

ℓ2 – ℓ = ...(ii)

⇒ ℓ1T2 – ℓT2 = ℓ2T1 – ℓT

19) Breaking stress depend on material of body.

20)

⇒ Stress =

21)

22) =

angular speed,

= = 0.17 rad/s
V = θ (ℓ) = 0.17 (0.4) = 68 × 10–3 m/s
 = 68 mm/s

23) y = 5 × 2

= 10

y = 10
A = 10 cm

24) mg = KA
A = 10 cm

25)

⇒ R = 100 N/m

PART-2 : CHEMISTRY

26)

A. Question Explanation:

The question asks you to identify which of the given metal displacement reactions are
spontaneous, based on the reactivity series of metals.

B. Concept: Electrochemical series

C. Solution -

A. Reactivity Series of Metals: A list of metals arranged in order of their reactivity. A more
reactive metal can displace a less reactive metal from its salt solution.
B. Displacement Reaction: A reaction in which a more reactive metal displaces a less reactive
metal from its salt solution.
C. Electrochemical Series: The electrochemical series is a more precise list, but for this
question, a general understanding of metal reactivity is sufficient.
D. General reactivity order from most to least reactive. K, Na, Ca, Mg, Al, Zn, Fe, Pb, H, Cu, Ag,
Au.

D. Final Answer:

Let's analyze each statement:

A. (a) Copper can displace iron from FeSO4 solution: Copper is less reactive than iron, so
 this is incorrect.
B. (b) Iron can displace copper from CuSO4 solution: Iron is more reactive than copper, so
this is correct.
C. (c) Silver can displace copper from CuSO4 solution: Silver is less reactive than copper, so
this is incorrect.
D. (d) Iron can displace silver from AgNO3 solution: Iron is more reactive than silver, so this
is correct.

Therefore, the correct statements are (b) and (d).

The correct answer is 3. b and d.

E. Question Level - Medium

27)

At 300 K

E = E° –

E = 0.29 –

0.29 + 0.06 ⇒ 0.35 V

28) + 2e– —→ 2Hg ...(1)

+2 + –
Hg 2e —→ Hg ...(2)
(1) + (2)
—→ Hg + Hg+2 E° = 0.78 – 0.85
⇒ – 0.07 V

– 0.07 = 0.03 log K

–2.3 = log K
K = 10–2.3
⇒ 10–3 × 10+0.7 = 6 × 10–3

29) K=

2.768 × 10–3 =
30) ΔG° = –nFE°
(1) Cu+2 → : Cu E° 0.339
ΔG°1 = –2.F.(0.339)
(2) Cu → Cu+2 : –0.153
+

ΔG°2 = –1.F.(–0.153)
+
(3) Cu → Cu : E° ΔG°3 = –[Link]°
ΔG°3 = ΔG°1 + ΔG°2
–FE° = –2.F. 0.339 + F.(0.153)
E° = 0.678 – 0.153
E° = 0.525

31) Anode :

Cathode :
________________________________

________________________________

= 0.118 volt

32) Larger the value of larger is tendency for reduction and consequently stronger will be
the oxidant. Similarly, smaller the value of larger the tendency for oxidation and
consequently stronger will be the reductant.

33)

34) No. of Cu2 ions deposited at cathode = No. of Cu+2 ions released from anode so conc. of
cu+2 ions remains same (1M)

35) Fe2+(aq) + Ag+(aq) → Fe3+(aq) + Ag(s)

Cell reaction
anode : Fe+2(aq) → Fe+3(aq) + ;
cathode : Ag+ (aq) + → Ag(s) ;
⇒ cell standard potential = (m + x)V
∴ to find 'm';
Fe+2 + 2 → Fe ;
+3
Fe +3 → Fe ;
Fe (aq) → Fe+3(aq) +
+2
;
= (–2Fy + 3Fz) = –Fm
⇒ m = (2y – 3z)
⇒ = (x + 2y – 3z)V

36)

X, Y, W will displace Z+2

37)
SRP : Cu > Al
↓
Show reduction but Cu is already in lowest oxidation state so no reaction take place.

38) SiO2 is a giant molecule it means one Si atom with four oxygen atom and one oxygen atom
combine with two Si atom

hybridisation of Si = sp3

39) SiX2 < GeX2 < SnX2 < PbX2

Stability of +2 oxidation state.

40)

H3BO3 + H2O [B(OH)4]– + H+

41) solid CO2 : London force / disperion force

42) Terminal hydrogen in same plane, bridge hydrogen below and above plane.

43) On moving down the group from B to Tl, a regular decreasing trend in the ionisation
energy values is not observed.

44) Ionic char. ∝ ΔEN

45)

Lewis acid order is explained in terms of back bonding.

More efficient back bonding in BF3 and least efficient in BI3.

46) MO2 + MO

47) At anode
Cu → Cu2+ + 2e–
At cathode
2Ag+ + 2e– → 2Ag
Cell reaction → Cu + 2Ag+ → Cu2+ + 2Ag

48)
= 189 + 160
= 349 ohm–1 cm2eq–1

49)
 50)

PART-3 : MATHEMATICS

51)

Let P =

Put

P=

52)

Hence, the given limit is 0.

53) As n → ∞. f(n) = f(n + 1) = k say

We have f(n + 1) =
⇒ f(n + 1) =

⇒k= ⇒ k2= 9 or k = 3
⇒

54) =

=
= e5

55) = 3/5

56)

57) ƒ(0–) = ƒ(0+) ⇒ p = r ...(1)

ƒ'(0–) = ƒ'(0+) ⇒ 3+2 = –q ⇒ q = –5 ...(2)
⇒ (p – r)2 + (q + 5)2 = 0

58) ƒ (x) =
⇒ if ƒ (x) is differentiable at x = 0, then

ƒ '(x) =
⇒ ƒ '(0+) = ƒ '(0–) = 0 when c = 0

59) Put y =

f(x)

⇒ f(x) =
⇒ f(x) = 1 ± xn
f(1) = 2, f'(1) = 2
⇒ f(x) = 1 + x2
sgn(f(x)) = sgn(1 + x2) = 1

60)

⇒
⇒
⇒ f'(x) = 0
⇒ f(x) = constant
f(20) = f(10) = 100

61) Substitute x = sinα, y = sinB

62)

63) ∵

∴
64) let any point on the curve be P(t, t2 + 7) and Q(3, 7)

|PQ| =
Let ƒ(t) = (t – 3)2 + 4t3
ƒ'(t) = 2(t – 3) + 4t3
= 4t3 + 2t – 6
= 2(2t3 + t – 3)
= 2(t – 1)(2t2 + 2t + 3)
ƒ'(t) = 0
⇒t=1

fmin = f(1) = 4 + 1 = 5
|PQ|min =

65)
⇒ a2 – 9a – 9 ≥ 1
⇒ a2 – 9a – 10 ≥ 0
⇒ (a – 10) (a + 1) ≥ 0

66)

g'(x) =
∵ x>0
∴ f '(log x) – f '(2 – log x) > 0
⇒ f '(log x) > f '(2 – log x)
⇒ log x < (2 – log x)
⇒ 2 log x < 2
⇒ log x < 1
⇒0<x<e

67) let f(x) = x sin x

f(0) = 0
f(π) = 0
f(0) = f(π)
∴f'(x) = sin x + x cos x = 0
have at least one root in (0, π)

68) (1, 2) lies on y1

2=a+b+ ⇒a+b= ....(1)

2a + b =

From (1) & (2) a = 1 & b =

a – 2b = 6

69) Given that cm3/s, where v is the volume of water in the conical vessel.

From the Figure = 4 cm, h = and .

Therefore,

Therefore,

Therefore, the rate of decrease of slant height .

70)

71) S = {x ∈ R, x2 + 30 – 11x ≤ 0}
= {x ∈ R, 5 ≤ x ≤ 6}
Now f(x) = 3x3 – 18x2 + 27x – 40
⇒ f'(x) = 9(x – 1)(x – 3),
which is positive in [5, 6]
⇒ f(x) increasing in [5, 6]
Hence maximum value = f(6) = 122

72)

So, minimum value is –3 when x = 2

at x = 2, y = 3
Hence, equation of tangent is 3x + y = 9
So, x-intercept = 3

73)

74)

= 399

75) y = f(f(f(x))) + (f(x))2 = f' (f(f(x)))f' (f(x))f' (x) + 2f(x)f' (x)

= f' (1)f' (1)f' (1) + 2f(1)f' (1)
=3×3×3+2×1×3
= 27 + 6
= 33