HUMIDITY CONVERSION FORMULAS

Calculation formulas for humidity

B210973EN-F
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Table of Contents
1. Relative humidity definitions ............................................................ 3
2. Water vapour saturation pressure .................................................... 4
3. Calculation of dewpoint from RH...................................................... 7
3.1 Calculation of dewpoint at different pressure............................ 7
3.2 Calculation of RH from dewpoint and ambient temperature .... 8
4. Using psychrometers ........................................................................ 9
5. Mixing ratio ........................................................................................10
6. Enthalpy .............................................................................................11
7. Absolute humidity .............................................................................12
8. Parts per million (ppm) .....................................................................13
9. Enhancement factor..........................................................................15

1. Relative humidity definitions

Relative humidity is at all temperatures and pressures defined as the ratio of the water
vapour pressure to the saturation water vapour pressure (over water) at the gas
temperature:

RH = Pw/Pws · 100% (1)

The total pressure does not enter the definition. Above 100°C the same definition is valid.
But as the saturation vapour pressure Pws is greater than 1 013 hPa (normal ambient
pressure) the RH can't reach 100% in an unpressurised system.

Below 0°C the definition is also valid. Here 100%RH is also impossible because
condensation will occur at a lower humidity than 100% (when the vapour is saturated
against ice).

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2. Water vapour saturation pressure

The following formula gives the water vapour saturation pressure to sufficient accuracy
between 0°C and 373°C ( W. Wagner and A. Pruß:" The IAPWS Formulation 1995 for the
Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use ",
Journal of Physical and Chemical Reference Data, June 2002 ,Volume 31, Issue 2, pp.
387535):

T
ϑ = 1− (2)
Tc

 Pws  Tc
In = (
C1ϑ + C 2ϑ 1.5 + C 3ϑ 3 + C 4ϑ 3.5 + C 5ϑ 4 + C6ϑ 7.5 ) (3)
 Pc  T

T = Temperature in K

Pws = Saturation vapor pressure (hPa)

Tc = Critical temperature, 647.096 K

Pc = Critical pressure 220 640 hPa

Ci = Coefficients,

C1 = -7.85951783

C2 = 1.84408259

C3 = -11.7866497

C4 = 22.6807411

C5 = -15.9618719

C6 = 1.80122502

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Correspondingly the saturation water vapour pressure over ice at temperatures between
-100 and 0.01°C can be calculated using:

T
θ= (4)
Tn

 Pwi 
In (
 = a0 1 − θ
−1.5
) (
+ a1 1 − θ −1.25 ) (5)
 Pn 

T = Temperature in K

Pn = Vapor pressure at triple point temperature, 6.11657 hPa

Tn = Triple point temperature 273.16 K

Pwi = Saturation vapor pressure (hPa)

ai = Coefficients,

a0 = -13.928169

a1 = 34.707823

If lower accuracy or a limited temperature range can be tolerated a simpler formula can be
used for the water vapour saturation pressure over water (and over ice):

 m⋅T 
 T +T 
Pws = A ⋅10  n 
(hPa) , where (6)

A, m, Tn = constants see Table 1

T = Temperature (°C)

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max
A m Tn error Temperature range
6.116441 7.591386 240.7263 0.083% -20...+50°C
6.004918 7.337936 229.3975 0.017% +50...+100°C
water

5.856548 7.27731 225.1033 0.003% +100...+150°C

6.002859 7.290361 227.1704 0.007% +150...+200°C
9.980622 7.388931 263.1239 0.395% +200...+350°C
6.089613 7.33502 230.3921 0.368% 0...+200°C

ice 6.114742 9.778707 273.1466 0.052% -70...0°C

Table 1. Constants for formula 6.

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3. Calculation of dewpoint from RH

Calculate Pws using formula (3) or (6)

Calculate Pw = Pws · RH/100 (in hPa!)

Calculate dewpoint using formula (7):

Tn
Td = (7)
 
 m 
 − 1
 10  Pw  
 log A  
 

The constants in formula (7) are the same as for formula (6).

Example:

The ambient temperature is 40°C and the RH is 50%. Calculate Td:

Pw = Pws(40°C) · 50/100 = 36.88 hPa

Td = 240.7263/(7.591386/10log(36.88/6.116441)-1) = 27.6°C

3.1 Calculation of dewpoint at different pressure

1. Calculate Pws using formula (3) or (6)

2. Calculate measured vapor pressure (at measurement pressure)

RH
Pw meas = Pws ⋅ (8)
100

3. Multiply with pressure ratio:

Ppres
Pw pres = ⋅ Pw meas (9)
Pmeas

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4. Calculate dewpoint at process pressure:

Tn
Td pres =
 
 
 m
−1
 10  Pw pres  
 log A  
    (10)

3.2 Calculation of RH from dewpoint and ambient

temperature

Pws(Td)
RH =100% ⋅ (11)
Pws(Tambient)

Pws may be calculated using formulas (3) or (6). If the simplified formula (6) is used the
expression for RH may be further simplified to:

 Td Tambient 
m −
Tambient+Tn 
RH =100% ⋅10  Td+Tn
(12)

Values for the constants M and Tn for the appropriate temperature range can be found in
Table 1.

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4. Using psychrometers
The drybulb-temperature Tdry and the wetbulb-temperature Twet can be converted into Pw
using formula (13):

Pw = Pws (Twet) - Ptot · K · (Tdry - Twet) , where (13)

Pws = Water vapour saturation pressure from formula (6)

Ptot = Total ambient pressure

K = Psychrometer constant 0.000662°C-1

When Pw is known RH can be calculated using (1) or Td can be calculated using (7)

Example:

Twet is 38.5°C, Tdry = 40.0°C and the ambient pressure is 1 013 hPa. Calculate RH and Td:

Pws(38.5°C) = 68.05 hPa

Pws(40.0°C) = 73.75 hPa

Pw = 68.05 - 1013 · 0.000662 · (40.0-38.5) = 67.04 (hPa)

RH = 67.04/73.75 · 100 = 90.9%

Td = 240.7263/(7.591386/10log(67.04/6.116441)-1) = 38.21°C

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5. Mixing ratio
The mixing ratio (mass of water vapour/mass of dry gas) is calculated using (14):

X = B·Pw/(Ptot-Pw) [g/kg] , where (14)

B = 621.9907 g/kg

The value of B depends on the gas. 621.9907 g/kg is valid for air.

In general the constant can be calculated using:

B=M(H2O)/M(gas) · 1000 [g/kg] , where (15)

M(H2O) = Molecular weight of water

M(gas) = Molecular weight of gas

For instance for hydrogen we get

B = 18.015/2.016 · 1000 = 8 936 g/kg

Example:

The dewpoint Td is 40°C and the total ambient pressure Ptot is 998 hPa. Calculate mixing
ratio:

Pw = Pws(40°C) = 73.75 hPa

X = 621.9907 · 73.75/(998-73.75) = 49.63 g/kg

(To obtain the mixing ratio in units of grains/pound use B = 4 354 [grains/pound])

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6. Enthalpy
Enthalpy can be calculated from mixing ratio using (16):

h = T · (1.01 + 0.00189X) + 2.5X (kJ/kg) , where (16)

T = Temperature (°C)

X = Mixing ratio (g/kg)

To convert to Btu/lb divide by 2.324

Note that a different base temperature for zero enthalpy, 0°F is often used together with
the Btu/lb unit.

Example:

The ambient temperature is 20°C and the relative humidity is 50%. Calculate enthalpy:

Pw = Pws(20°C) · 50/100 = 11.69 hPa

X = 621.9907 · 11.69/(1013-11.69) = 7.26 g/kg

h = 20 · (1.01 + 0.00189 · 7.26) + 2.5 · 7.26 = 38.62 kJ/kg

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7. Absolute humidity
Absolute humidity is defined as the mass of water vapour in a certain volume. If ideal gas
behaviour is assumed the absolute humidity can be calculated using (17):

A = C · Pw/T (g/m3) , where (17)

C = Constant 2.16679 gK/J

Pw = Vapour pressure in Pa

T = Temperature in K

Example:

The ambient temperature is 20°C and the relative humidity is 80%. Calculate absolute
humidity:

Pw = Pws(20°C) · 80/100 = 18.7 hPa

A = 2.16679 · 1870/(273.15+20) = 13.82 g/m3

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8. Parts per million (ppm)

Parts per million values are usually given vs. the amount of dry air:

I: Volume/volume PPMv(dry):

Pw
PPM v = 10 6 (18)
Ptot − Pw

Where

Pw = Water vapour pressure

Ptot = Total pressure

II: Mass/mass PPMm(dry)

M w Pw
PPM m = 10 6
M d (Ptot − Pw )

Mw
= 0.62199 (19)
Md

Where

Pw = Water vapour pressure

Ptot = Total pressure

Mw = Molecular mass of water

Md = Molecular mass of dry air

From wet air:

III: Volume/volume PPMv(wet):

Pw 6
PPM v = 10 (20)
Ptot

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IV: Mass/mass PPMm(wet)

M w Pw 6
PPM m = 10
M d Ptot

Mw
= 0.62199 (21)
Md

Example:

The dewpoint is 7°C and the total pressure is 998 hPa. Calculate PPMv(dry).

By using formula (6) with the dewpoint temperature , Pw=Pws(Td), we get Pws(7°C) = 10.02
hPa. Now:

10.02
PPM v = 10 6 = 10142
(998 −10.02)

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9. Enhancement factor
The water vapour saturation pressures described in Paragraph 2 are exactly valid only in
vacuum (water vapour is the only gas present). If other gases are present the real
saturation vapour pressure Pws will increase. For ambient pressure and lower pressures
this effect is typically ignored. But at pressures significantly above ambient it has to be
taken into account. The enhancement factor f has been defined as follows:

Xw ⋅P
f = , where (22)
Pws

Xw = The mole fraction of water vapour in the gas phase

P = Total pressure

Pws = The saturation water vapour pressure (from Paragraph 2)

xw · P is in effect the water vapour pressure at saturation at pressure P

For CO2-free air the following equation for f has been proposed (Greenspan: J. of Research
of the NBS vol 80A, No. 1 p 41-44)

  P   P 
α 1− ws  + β  −1
  P   Pws 
f =e (23)

The parameters α and β depend on the temperature as follows:

4
α = ∑ Ai t (i−1) (24)
i=1

∑ Bi t (i−1)
β = e i=1 (25)

T = Temperature (°C)

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The parameters Ai and Bi are listed below:

water -50 to 0°C water 0 to 100°C ice -100 to 0°C

A1 3.62183 · 10-4 3.53624 · 10-4 3.64449 · 10-4

A2 2.60553 · 10-5 2.93228 · 10-5 2.93631 · 10-5

A3 3.86501 · 10-7 2.61474 · 10-7 4.88635 · 10-7

A4 3.82449 · 10-9 8.57538 · 10-9 4.36543 · 10-9

B1 -10.7604 -10.7588 -10.7271

B2 6.39725 · 10-2 6.32529 · 10-2 7.61989 · 10-2

B3 -2.63416 · 10-4 -2.53591 · 10-4 -1.74771 · 10-4

B4 1.67254 · 10-6 6.33784 · 10-7 2.46721 · 10-6

The formulas above are fitted for the pressure range 1 ... 20 atm.

for instance at 20°C ad 10 bars f = 1.031

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