21-12-2025

0999DJA161115250006 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Three rods A, B and C, having identical shape and size, are hinged together at ends to form an
equilateral triangle. Rods A and B are made of same material having coefficient of linear thermal
expansion α1 while that of material of rod C is α2. By how many kelvin must the system of rods be
heated to increase the angle opposite to rod C by small angle Δθ.

(A)

(B)

(C)

(D)

2) A person lives in a high-rise building on the bank of a river 50m wide. Across the river is a well lit
tower of height 40 m. When the person, who is at a height of 10m, looks through a polarizer at an
appropriate angle at light of the tower reflecting from the river surface, he notes that intensity of
light coming from distance X from his building is the least and this corresponds to the light coming
from light bulbs at height 'Y' on the tower. The values of X and Y are respectively close to (refractive

index of water 4/3)

(A) 13 m, 27 m
(B) 22 m, 13 m
(C) 25 m, 10 m
(D) 17 m, 29 m

3) Consider three concentric soap bubbles of radius ; R and nR as shown. Surface tension for each
bubble is T and atmospheric pressure is P0. Value of n for which pressure (P) of gas inside smallest
bubble is minimum (n is integer greater than 1) :-

(A) 2
(B) 3
(C) n → ∞
(D) for every value of n, value of P remain same

4) A metal plate is exposed to light with wavelength λ. It is observed that electrons are ejected from
the surface of the plate. When a retarding uniform electric field E is imposed, no electron can move
away from the plate farther than a certain distance d. Then the threshold wavelength λ0 for the
material of plate is (e is the electronic charge, h is Planck's constant and c is the speed of light) :-

(A)

(B)

(C)

(D)

5) A radio-active element is produced at a rate proportional to 't3' and decays with decay constant of
λ = 3 S–1. At t = t1, no. of atoms of given element is minimum and t = t2, activity of sample is

minimum. If N(t) represents no. of atoms of element at any time 't', then

(A)

(B)

(C)

(D)

6) A stationary singly ionised helium atom emits a photon corresponding to the first line of Lyman
series. The emitted photon is then absorbed by a stationary hydrogen atom in the ground state. Point
correct statements/s from the following :-
(A) The emitted photon from He+ ion excites the hydrogen atom to sixth excited state.
The kinetic energy of recoiling of He+ of mass m when it emits a photon of frequency v is given
(B)
by .
The emitted photon from He+ ion ionises the hydrogen atom with liberated electron carrying
(C)
kinetic energy of about 20 eV.
(D) The transition energy during the emission of photon from He+ ion is about 54.4 eV.

7) Let where ℓ = 2.0 ± 0.1, z = 1.0 ± 0.1 then the value of y is given by :

(A) + 2 ± 0.8
(B) – 4 ± 1.6
(C) – 4 ± 0.8
(D) none of these

8) The smallest division on the main scale of a Vernier calipers is 0.1 cm. Ten divisions of the Vernier
scale correspond to nine divisions of the main scale. The figure below on the left shows the reading
of this calipers with no gap between its two jaws. The figure on the right shows the reading with a
solid sphere held between the jaws. The correct diameter of the sphere is

(A) 3.07 cm
(B) 3.11 cm
(C) 3.15 cm
(D) 3.17 cm

SECTION-I (ii)

1) Figure below shows four lines OA, OB, OC, OD (representing various processes such as
isothermal, adiabatic, isobaric for a monoatomic and a diatomic ideal gas) on a work done by the gas
(W) versus heat supplied (Q) graph. The initial states of both the gases are the same and so also the

scales for the two axes.

(A) OA represents isobaric process for diatomic gas
(B) OB represents isobaric process for diatomic gas
(C) OC represents isothermal process for diatomic gas
(D) OD represents adiabatic process for diatomic gas

2) For a certain transverse standing wave on a long string, an antinode is formed at x = 0 and next
to it, a node is formed at x = 0.10 m. The displacement y(t) of the string particle at x = 0 is shown in

figure.

(A) Transverse displacement of the particle at x = 0.05m and t = 0.05 s is – 2 cm.

(B) Transverse displacement of the particle at x = 0.04 m and t = 0.025 s is – 2 cm.
(C) Speed of the travelling waves that interfere to produce this standing wave is 2 m/s.

(D)
The transverse velocity of the string particle at x = m and t = 0.1 s is 20 π cm/s

3) Figure shows a closed pipe (closed at both ends) of length 10m. MN is a membrane (thin sheet)
capable of doing simple harmonic motion of amplitude 1mm along left and right from shown
situation. On two sides of membrane are two gases G1 and G2 in which sound can travel at 300 m/s

and 100 m/s respectively.

(A) If resonance is obtained in right side (G2), side (G1) might not resonate.
(B) Resonance in both gases will be possible for some specific frequencies only.

(C) For angular frequency 75 π rad/sec., a particle, right of AA' would be oscillating with
maximum displacement 0.5 mm.

For angular frequency 75 π rad/sec., a particle, right of AA' would be oscillating with
(D)

maximum displacement mm.

4) A slit is cut along the left bottom edge of a rectangular tank. The slit is closed by a wooden wedge
mass 'M' and apex angle 'α' as shown in diagram. The vertical plane surface of the wedge is in the
contact with the left vertical wall of the tank. Coefficient of static friction between these surfaces in
contact is 'μ'. To what maximum height, can water be filled in tank, without any leakage through the
slit ? The width of tank is 'b' and density of water is 'ρ'.

(A)

(B)

(C)

(D)

5) A cylindrical capillary tube of 0.2 mm radius is made by joining two capillaries T1 and T2 of
different materials having water contact angles of 0° and 60°, respectively. The capillary tube is
dipped vertically in water in two different configurations, case I and II as shown in figure. Which of
the following option(s) is(are) correct ?
(Surface tension of water = 0.075 N/m, density of water = 1000 kg/m3, take g = 10 m/s2)

The correction in the height of water column raised in the tube, due to weight of water
(A)
contained in the meniscus, will be different for both cases.
For case I, if the capillary joint is 5 cm above the water surface, the height of water column
(B)
raised in the tube will be more than 8.75 cm. (Neglect the weight of the water in the meniscus)
For case I, if the joint is kept at 8 cm above the water surface, the height of water column in the
(C)
tube will be 7.5 cm. (Neglect the weight of the water in the meniscus)
For case II, if the capillary joint is 5 cm above the water surface, the height of water column
(D)
raised in the tube will be 3.75 cm. (Neglect the weight of the water in the meniscus)

6) He measures depth by vernier callipers as 5.250 cm and diameter as 2.500cm. The thickness of
sheet used is measured by screw gauge as 0.250 mm. Then choose the CORRECT option(s) :

(A) Area of sheet used to make calorimeter with correct significatnt figures is 46.12 cm2
(B) Area of sheet used to make calorimeter with correct significant figures is 27.500cm2
(C) Volume of cylinder with percentage error is 25.76cc ± 0.2%
(D) Volume of cylinder with percentage error is 25.8cc ± 2.0%
 SECTION-III

1) A cylindrical rod of length 50 cm and cross-sectional area 1 cm2. is fitted between a large ice
chamber at 0°C and an evacuated chamber maintained at 27°C as shown in figure. Only small
portions of the rod are inside the chambers and the rest is thermally insulated from the surrounding.
The cross-section going into the evacuated chamber is blackened so that it completely absorbs any
radiation falling on it. The temperature of the blackened end is 17°C when steady state is reached.
Stefan constant σ = 6 × 10–8 W/m2-K4. Find the thermal conductivity of the material of the rod

(in W/m–K) in nearest integer.

2) A cylindrical vessel is divided in two parts by a fixed partition which is perfectly heat conducting.
The wall and piston are thermally insulated from surroundings. The left side contains 0.5 moles of
gas with Cv = 2R at temperature of 300 K. The right side contains 4 moles of mixture of gas with Cv
= 1.75 R at same temperature of 300 K. The piston compresses slowly the right side from volume of

0
V to . Find the total change in internal energy of gases. If ΔU = n × 104 J, find n. (Take : R =

S.I. unit)

3) In young's double slit experiment relative intensity at a point on the screen may be defined as
ratio of intensity at that point to the maximum intensity on the screen. Light of
wavelength passing through a double slit, produces interference pattern of relative intensity
variation as shown in figure. on horizontal axis represents the angular position of a point on the
screen, then the ratio of amplitudes of the two waves producing interference pattern on the screen

is:

4) Two identical speakers 10 m apart are driven by the same source with a frequency f = 21.5 Hz as
shown in the figure. If the receiver is moved in the plane of the speakers, the path that should it take
so that the intensity remains at a minimum that is the relationship between x and y (the coordinates
of the receiver) that causes the receiver to record a minimum in sound intensity is

. Find . Take the speed of sound to be 343 m/s.

5) A neutron strikes a hydrogen atom which is initially at rest and free to move. The initial speed of
the neutron is u. After the collision both neutron and the H atom move making 30º angle with the
initial velocity of the neutron. Also the H atom is found to get excited to first excited state. If the
initial KE = p times first excitation energy of the H atom, find the value of p (assume mass of
neutron = mass of H atom)

6) In a complete rotation, spindle of a screw gauge advances by . There are 50 divisions on

circular scale. The main scale has marks → (is graduated to or has least count = )
If a wire is put between the jaws, 3 main scale divisions are clearly visible, and 20 division of
circular scale coincide with the reference line. Find diameter (in mm) of wire in nearest integer.

PART-2 : CHEMISTRY

SECTION-I (i)

1) Decomposition of N2O4(g) takes place as follows : ‘D’ is the vapour density

at initial stage and ‘d’ is the vapour density at equilibrium. We get following graph when the degree

of dissociation ‘α’ is plotted against

What is the value of at A ? What is the value of of A?

(A) 0
(B) 0.5
(C) 1
(D) 1.5
2) In the following reactions products(A) and (B), respectively , are :
NaOH + Cl2 → (A) + side products
(hot and conc.)
Ca(OH)2 + Cl2 → (B) + side products
(dry)

(A) NaClO3 and Ca(OCl)2

(B) NaOCl and Ca(ClO3)2
(C) NaClO3 and Ca(ClO3)2
(D) NaOCl and Ca(OCl)2

3) Match the catalysts to the correct processes :

Catalyst Process
(A)
TiCl3 Wacker process

(B) Catalyst Process

TiCl3 Ziegler - Natta polymerization

(C) Catalyst Process

CuCl2 Contact process

(D) Catalyst Process

V2O5 Deacon's process

4) The smog is essentially caused by the presence of :

(A) O2 and O3
(B) O3 and N2
(C) Oxides of sulphur and nitrogen
(D) O2 and N2

5) shows

(A) Only geometrical isomerism

(B) Only optical isomerism
(C) Both optical isomerism and geometrical isomerism
(D) No isomerism

6) Which one of following given compound do not gives acetanilide on treatment with aniline.
(A)

(B)

(C)

(D)

7) The number of chiral centres in the open chain structure of glucose is :

(A) 3
(B) 4
(C) 5
(D) 6

8) 0.4 g of organic compound gave 0.188g of AgBr in carius method. The percentage of Br in the
organic compound is

(A) 39.8
(B) 46.0
(C) 20.0
(D) 40.0

SECTION-I (ii)

1) In which of the following reactions, products are favoured over reactants ?

(A)

(B)
(C)

(D)

2) The correct major product is/are for the given reactions :

(A)

(B)

(C)

(D)

3)

Which of the following is/are incorrect statements for following reaction -

CaCO3(s) CaO(s) + CO2(g) ; ΔrH = +ve.

(A) Equilibrium shift in forward direction on addition of CaCO3(s)
(B) Equilibrium shift in backward direction on addition of CaO(s)
(C) The Equilibrium pressure of CO2 increase when temperature increase
(D) The Equilibrium pressure of CO2 increase when CaCO3(s) added under constant temperature.

4) Which are correct against property metioned ?

(A) CH3COCl > (CH3CO)2O > CH3COOEt > CH3CONH2 (Rate of hydrolysis)

(B)

CH3–CH2–COOH > (Rate of esterification)

(C)
(Rate of esterification)

(D)
> Ph–CH2–COOH (Rate of decarboxylation)
5) Tautomerism is exhibited by :-

(A)

(B)

(C)

(D)

6) Which of the following statements is/are not correct?

(A) Metamerism belongs to the category of structural isomerism

(B) Tautomeric structures are the resonating structures of a molecule
(C) Keto form is always more stable than the enol form
(D) Tautomers are not resonating structures of each other

SECTION-III

1) A(g) ⇌ B(g) + C(g) KC = 10–8 C(g) ⇌ D(g) KC = 10–5 1 mole of A(g) is taken in a
closed container of volume 1 litre at temperature T, If concentration of D at equilibrium is 10–x then
calculate value of x.

2) Calculate the concentration (in mole litre–1) of CO2 which will be in equilibrium with 1.2 mole
litre–1 of CO at 100°C for the reaction : FeO(s) + CO(g) Fe(s) + CO2 (g) ; Kp = 5.0.

3)

CH3 – CH = CH – CH = N – CH = CH – CH3
Total number of G.I. possible by given compound.

4) How many of the following shows positive tollen's test

(a) HCOOH (b) HCHO
(c) CH3COOH (d) CH3CHO

(e) (f) Ph – CHO

(g) (h)

5) Total number of methods which can remove permanent hardness of water.

(1) Clark's method (2) Ion-exchange method
(3) Synthetic resin method (4) Calgon method
(5) Treatment with sodium carbonate

6) How many of the following are paramagnetic in nature.

Fe2O3, MnO, La2O3, ZnO, AgCl, SO3, PCl5, CO, NO, PmO, Eu2O3, U2O3, MnO2

PART-3 : MATHEMATICS

SECTION-I (i)

1) The value of amp (iω) + amp (iω2), where i = and ω = = non–real, is

(A) 0

(B)

(C) π

(D)

2)

The modulus of the complex number z such that |z + 3 – i| = 1 and arg(z) = π is equal to

(A) 1
(B) 2
(C) 3
(D) 4

3) The foot of perpendicular from A(1,1,1) to the line joining B(–8,5,6) and C(12,1,0) lies on the plane
-

(A) 2x + y + z = 10
(B) x – y + z = 1
(C) x + y – z = 5
(D) x + y + z = 2

4) The distance of point P (2, 3, 2) from the line – x + y + 2z – 4 = x + 2y – z – 2 = 0, measured

along the line , is
(A)
(B)
(C)
(D)

5) Let A and B be two events such that , , , then

(A)

(B)

(C) A and B are independent events

(D) P(A) < P(B)

6) Let in a binomial distribution, consisting of 5 independent trials, probabilities of exactly 1 and 2

successes be 0.4 and 0.6 respectively. Then the probability of getting exactly 3 successes is equal to

(A)

(B)

(C)

(D)

7) The standard deviation of the numbers p and q is

(A)

(B)

(C) |p – q|

(D)

8) Let n be a fixed positive integer. Define a relation R in the set Z of integers by aRb if and only if a
– b is divided by n. The relation R is

(A) reflexive
(B) symmetric
(C) transitive
(D) an equivalence relation

SECTION-I (ii)
1) Let and , then

(A) The shortest distance between L1 and L2 is 1 unit

(B) Equation of plane containing L1 and parallel to line L2 is 2x + y + 2z – 1 = 0

(C)
Equation of line of shortest distance of L1 and L2 is
(D) The shortest distance between L1 and L2 is 2 units

2) Let A ≡ (1,2,3), B ≡ (α,4,6) and C ≡ (1,2,β) are three vertices of ΔABC. If median AD is equally
inclined with positive x,y and z axis, then which of the following is/are true

(A) ordered pair (α,β) is (3,2)

(B) coordiantes of D are (2,3,5)
equation of median through B is
(C)

equation of median through B is

(D)

3) There are three bags B1, B2 and B3. The bag B1 contains 5 red and 5 green balls, B2 contains 3 red

and 5 green balls, and B3 contains 5 red and 3 green balls, Bags B1, B2 and B3 have probabilities ,

and respectively of being chosen. A bag is selected at random and a ball is chosen at random
from the bag. Then which of the following options is/are correct ?

Probability that the selected bag is B3 and the chosen ball is green equals
(A)

(B)
Probability that the chosen ball is green equals
Probability that the chosen ball is green, given that the selected bag is B3, equals
(C)

Probability that the selected bag is B3, given that the chosen balls is green, equals
(D)

4) The plane passing through the point (–2, –2, 2) and containing the line joining the points (1, 1, 1)
and (1, –1, 2) makes intercepts of lengths a, b, c respectively on the axes of x, y and z respectively,
then

(A) a = 3b
(B) b = 2c
(C) a + b + c = 12
(D) a + 2b + 2c = 0
5) If |z1 + z2|2 = |z1|2 + |z2|2 (where z1 and z2 are non-zero complex numbers), then

(A)
is purely real

(B)
is purely imaginary
(C)

(D)
amp may be equal to

6) A card is randomly selected from a pack of 52 playing cards, such that

P(A) : Probability of that card being an Ace.
P(B) : Probability of that card being a red card.
P(C) : Probability of that card being a face card.
Then which of the following is(are) correct :

(A)

(B)

(C)

(D)

SECTION-III

1) If z1 and z2 are two non-zero complex number such that |z1z2| = 2 and arg(z1) – arg(z2) , then
the value of

2) A line having direction ratio 1,2,2 cut two planes 3x – 2y + 6z + 12 = 0 and 3x – 2y + 6z – 2 = 0 at

the points P and Q respectively. If the length PQ is λ then [2λ] is ([.] denotes greatest integer
function)

3) For two events A and B, the probability of their simultaneous occurance is , whereas

the probability that atleast one of A or B occurs is . If the value of is , (where a, b are
coprime numbers), then value of |a – b| is

4) The minimum number of elements that must be added to the relation R = {(1, 2), (2, 3)} on the
set {1, 2, 3}, so that R is an equivalence, is

5) If M and m are the respective maximum and minimum values of |z| satisfying |z – 4| ≤ 2 but not |z|
< 4, where 'z' is complex number, then the value of M – m is-
6) In a tournament four players are participating. Each player play with every other player. Each
player has 50% chance of winning any game and there are no ties. If the probability that at the end

of tournament there is neither a winless nor an undefeated player is there is , where a and b are
relatively prime integers then |2a – b| is equal to :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8
A. A A A B C B B C

SECTION-I (ii)

Q. 9 10 11 12 13 14
A. A,C,D A,C,D A,C A A,C,D A,C

SECTION-III

Q. 15 16 17 18 19 20
A. 2 2 2 3 3 2

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 21 22 23 24 25 26 27 28
A. C A B C C C B C

SECTION-I (ii)

Q. 29 30 31 32 33 34
A. A,C,D A,C,D A,B,D A,B A,C,D B,C

SECTION-III

Q. 35 36 37 38 39 40
A. 9 6 8 6 4 7

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 41 42 43 44 45 46 47 48
A. C C A B C C B D

SECTION-I (ii)

Q. 49 50 51 52 53 54
A. A,B,C A,C B,C A,B,C B,C,D A,B,D
 SECTION-III

Q. 55 56 57 58 59 60
A. 6 7 1 7 2 2
 SOLUTIONS

PART-1 : PHYSICS

1) When the system is heated, the rods expand and the triangle does not remain equilateral.
Let lengths of rods A, B and C be ℓ1, ℓ2 and ℓ3 respectively then

or ...(i)
Differentiating Eq.(i), we get

...(ii)
Let the temperature of the system be increased by ΔT. Then

and ...(iii)
In case of equilateral triangle ℓ1 = ℓ2 = ℓ3 and θ = 60° (say)
From Eqs. (ii) and (iii), we get :

2) use brewster's law

tan i = µ ⇒i = 53°

3) Pressure inside smallest bubble

0
P=P +
for n > 1 value of P increases with increase in n
so for n = 2 P is minimum.

4)
 KEmax = = (eE)d

0
⇒ λ =

5)
At t = t1, 'N' is minimum.

At t = t2, is minimum,

= 3αt2 – λ (αt3 – λN) = 0

6) ,

7)

= – 8 (±0.1) + 8 (±0.1) = ±1.6

y= = =4–8=–4
∴ y = – 4 ± 1.6

8) Question Explanation: Calculate the correct diameter of a sphere using a vernier caliper
with zero error.
Concept: Vernier calipers with zero error
Given 10 VSD = 9 MSD Here MSD → Main Scale division

1 VSD = MSD VSD → Vernier Scale division

Least count = 1 MSD – 1 VSD

= MSD
= 0.1MSD
= 0.1 × 0.1 cm
= 0.01 cm
As '0' of V.S. lie before '0' of M.S.
Zero error = –[10 – 6]L.C.
= – 4 × 0.01 cm
= –0.04 cm
Reading = 3.1 cm + 1 × LC
= 3.4 cm + 1 × 0.01 cm
= 3.11 cm
True diameter = Reading – Zero error
= 3.11 – (–0.04) cm = 3.15 cm
Final Answer: The correct diameter of the sphere is 3.15 cm.

9) • For isothermal process : Q = W

• For adiabatic process : Q = 0

• For isobatic process : and

where
[where f is degree of freedom]

10) = 0.1 ⇒ λ = 0.4 m

from graph ⇒ T = 0.2 sec. and amplitude of standing wave is 2A = 4 cm.
Equation of the standing wave

y(x, t) = – 2A cos cm
y (x = 0.05, t = 0.05) = – 2 cm

speed = = 2 m/sec.

Vy = = – 2A ×

Vy = (x = m, t = 0.1) = 20 π cm/sec

11)
V1 = 300 m/s
V2 = 100 m/s
f1 = f2
λ1 : λ2 = V1 : V2 = 3 : 1
ω = 75 π rad/sec
V = 300 m/s
λ = 8m
A = Ax sin kx

= 1 sin = 0.5 mm

12)

When 'H' is max friction will be maximum.

Use condition of equilibrium.

13) h =

14) Area of sheet used = curved area + cross section of bottom

= 2πrℓ + πr2 (rounded off to 4 significant figures)

Volume of calorimeter = πr2ℓ

percentage error

= 0.16% + 0.04% = 0.2%

So volume of cylinder = 25.781cc ± 0.2%
15)
T1 = 0°C = 273 K
T2 = 17°C = 290 K
TS = 27°C = 300 K

= 1.8 W/m-K

16) Question Explanation:

The problem describes a cylindrical vessel divided into two compartments by a heat-
conducting partition. The left side contains a gas with a specific heat capacity and the right
side contains a mixture of gases with a different heat capacity. The right side is compressed by
a piston, and the total change in internal energy of the gases is to be determined.
Concept:
This question is based on Internal energy.
Solution:

+ + 4RT

T = 600 K

ΔU = × 2R × (600 – 300) + 4 ×
(600 – 300)
= 8R × 300

=8× = 2 × 104J
Final Answer:
The value of n is 2.

17)

Concept : In YDSE we know

from graph Imax = 1

Imin =
3A1 – 3A2 = A1 + A2
2A1 = 4A2

18) Path difference between two sound waves reaching at A is

Δx = S1A – S2A = (9 – 1) = 8m

Since, Δx =
the minimum intensity is observed at A.
S1 = (–5, 0)
S2 = (5, 0)
For intensity to be minimum,

S1P – S2P = (2n – 1) n = 1, 2, 3, .....

or n = 1, 2, 3,....
This is the desired relation between x and y when intensity is minimum.

19)
(Pi = Pf)Y
V1 = V2 = V
(Pi = Pf)X
mu = mv1 cos 30° + mv2 cos 30°
u = 2v cos 30°

....(1)
Ei = Ef
Ki = Kf + IExcitation energy

Here

20) Question Explanation: Calculate the diameter of a wire using a screw gauge with given
pitch and scale readings.
Concept: Screw gauge reading
 Solution: The least count is the pitch divided by the number of divisions on the circular scale.
The diameter is the sum of the main scale reading (MSR) and the circular scale reading (CSR),
where CSR is the product of the coinciding division and the least count. The result should be
expressed with the correct number of significant figures.

Diameter of wire (3 × ) + (20) = 1.5 + 0.20 = 1.70 mm (The answer should be

upto two decimal places because this screwgauges can measure upto 0.01 mm accuracy).
Final Answer: The diameter (in mm) of wire in correct significant figure is 1.70.

PART-2 : CHEMISTRY

21)

Correct answer is option (C)

22) 6NaOH + 3Cl2 —→ NaClO3 + 5NaCl + 3H2O

(hot and conc.) (A) side product
2Ca(OH)2 + 2Cl2 —→ Ca(OCl)2 + CaCl2 + 2H2O
dry (B) side product

23)

Question Explanation: Matching various transition metal catalysts with their corresponding
industrial processes. Concept: Industrial Catalysis. Solution:

A. (1) TiCl3​ (or TiCl4​): Component of Ziegler-Natta catalyst used for polymerization of
alkenes. → Zigler - Nata polymerization.

B. (2) PdCl2​: Catalyst for the Wacker process (oxidation of ethene to ethanal). → Wacker
process

C. (3) CuCl2​: Catalyst for the Deacon's process (oxidation of HCl to Cl2​). → Deacon's
process

D. (4) V2​O5​: Catalyst for the Contact process (oxidation of SO2​ to SO3​). → Contact process

24)

Correct answer is option (C)

25)

Correct answer is option (C)

26)
Hence CH3–CH=O do not give acetanilide with aniline

27)

28) Question Explanation: Calculating the percentage of bromine using the Carius method.
Concept: Carius method.
Solution:
Molecular mass of AgBr = 188 gm/mol
188g AgBr 80 gm Br

= 0.08 gm

29) Acid base reaction proceeds from stronger acid base to weaker acid base.

30)

Correct answer is option (A,C,D)

31)

Correct answer is option (A,B,D)

32) Rate of esterification Rate of decarboxylation

µ stability of carbanion.
 33) can not show tautomerism.

34) Tautomers are not resonating structures.

35) Correct answer is (9)

36) ∵ Δng = 0 ∴ Kp = KC =
[CO2] = 6M

37)

Correct answer is (8)

38)

The correct answer is (6) : (a),(b),(d),(f),(g),(h)

39)

The correct answer is (4)

40)

The correct answer is (7) : Fe2O3, MnO, NO, PmO, Eu2O3, U2O3, MnO2

PART-3 : MATHEMATICS

41) amp (iω) + amp (iω2) = amp (i2ω3)

= amp (–1) = π
Hence (C) is the correct answer

42)
43) Equation of BC

⇒
Let co-ordinate of M is
= (–8 + 20λ, 5 – 4λ, 6 – 6λ)
Now use , we get
20(–9 + 20λ) – 4(4 – 4λ) – 6(5 – 6λ) = 0

∴ co-ordinates of M = (2,3,3), Now check options.

44)
Direction vector of line L (intersection of plane)

= =
one of fixed point (–2, 2, 0)

equation of line L:
Let point Q:

is parallel to .

λ=1
required distance

45)

46) P(X = 1) = 5C1 p.q4 = 0.4

P(X = 2) = 5C2 p2.q3 = 0.6

...(1)
p+q=1 ...(2)
47)

48) The given relation may be written in set builder form as

R = {(a, b) : a – b divided by n and a, b ∈ Z}
As a – a = 0 and 0 divided by n
∴ (a, a) ∈ R
∴ R is reflexive
Let a, b ∈ Z such that (a, b) ∈ R
Then (a, b) ∈ R ⇒ a – b divided by n.
a – b = nk for some integer k
⇒ b – a = n(– k)
∴ (a, b) ∈ R ⇒ (b, a) ∈ R
∴ R is symmetric
Now, (a, b), (b, c) ∈ R
Now, a – b = nc1 and b – c = nc2 for some integers c1 and c2.
∴ (a – b) + (b – c) = n(c1 + c2)
⇒ a – c = nk, where k = c1 + c2, an integer.
⇒ (a, c) ∈ R.
∴ (a, b), (b, c) ∈ R ⇒ (a, c) ∈ R
∴ R is transitive and hence R is an equivalence relation.

49)

S.D. =

S.D. =
point (–1, 1, 1) satisfy equation of line L1
So, Line of shortest distance of L1 and L2 is parallel to

Equation of line of shortest distance of L1 and L2 is

50)

D ≡ (2,3,4)
median through B :

B ≡ (3,4,6) and

51)

(A)

(B)

(C)

(D)
52)
So, are coplanar

So, Equation of plane =

⇒ a = 8, b = and c =

53) |z1 + z2|2 = |z1|2 + |z2|2

is purely imaginary

so amp is may be or

54) ∵

55) ,

3i(–2i) = 6

56) Distance between planes

57)

58) {(1, 2), (2, 3)}

(2, 1), (3, 2), (1, 3), (3, 1)
(1, 1), (2, 2), (3, 3)

59)
M–m=6–4=2

60) A : There is at least one player with all wins

B: There is at least one player with all defeats
E : Neither a winless nor undefeated player.
P(E) = 1 – P(A ∪ B)