_Hatoalkanco
J = RH all eile -
CHgth = chioride- ce
__cHactaBr exh Qouomide :
13 nalagan _davivaive—cb: aliphatic oF Asura
4 __ Coben one. called clans OF
Gn the. booin_____00- of,
— nekwst oh
halogen Casthenakion
Monchalaalkane 1 ——— — == SS
City Ct =
CHyCHaCh
—_____dihaloalkang.+
ate fensthuytent | dichloromethane
Chiosido.
feta palonkon:
Cig Cast on tebe __
Chiovidea Jon the basin_of Canton ee
| heloalkang a? = netsh ate ie
CHa aha ab 208
[ge paloalieine...
a
1 Chg — CH — Co
Ft ons st
haloolkene (3,
_ Chg 6 — Cd.
“Le ! chs
joo tes basta —hypetidizating <¢______
2 Alky{ halide
Cha —CHa —CH
spa sea
— 0) Ally tie haut
CH = CH-CHa—Cd
se? sp3. r6e3
a) wiani halide
CHS
“= 1. C= sp 3. wa Le :
T 7 yu at
sisi frnase, _ds
1 ,
Vinge ‘ I - Gar
CHa = CH-Cu
NY fRogl halla on ~
or
oe oe——__Metnad of Asuperation of halo alkanc
— 1). Fotom —_aleahe! — aychiybucnn suptier ind
oH son a el — Pty: Cate cel 4 Hod =
CoWcoH + Plus —
Ca tlt Potlg ie HCL
18a Wea + Peg >) aC attgtd 4 3003
Apel oF oa r
_CoHsoH. 460d,
. ——=§
Toauer of —oveactinity o- ‘Kalogen oxid Hl >HiSo.2 Hoy
[ 3), be preectithala' nation. oh alkoxy
Stet gM GHC
~ Ct Cty
lg coy
| ahed
Cn clMch
‘
3)_finkeahin ——sstonchion= '
Or2tene
_ CBr + Na t——> AICS Tye
—— Atattiviky — 0} _Haloalkone.- “jhe haloaltcona one
—- highly _“Amoortive due
~tp__ante___ of splat C-A_ @ond + orden
— j—th—omactivity, —
ont DCH aBr CHatd ad Usieiak wt
- bon = oN)Cement petofesrdicn “b Haloalkene-
fota 4 oe 4. aol
_ Tgpcnd ‘veachion. of -[Link] may he . dewidod
| tints ee aie sist!
Baviins 4
——e cfaippdéa 22
> Holoatkont _
Petes =
tar,
ares sath sel —
Flkecton ae eae — —slreies —————
W) Roortion —aisith No Cususike ascdorbion} = ie _
——— Adeyl halide ce. suarttert be «just bh sans ag
~ otha to give “hydsingecansbana +e =
AX + DN, ———— R-AK asec
(bap en
———itHab— 4.2No tong cg +t onaBys
Ethons) fle 9p a
a2) igenetion— “sit mapa! Calon of.
_palpalkanen therm —grignased_ ouapat Cag fagnas
— ep eel iat th cheered act iustth 1 ekhgne
CHg.CHg8y_ +. at
if a
mpei God gnostdic T Ahould/ tae: pouasal_onde
Onhydno wd concibinn___ bararhe Giugno. Hongint.
Ss ane __hig _pomcive.. Tk wiogrte —wibh___
—moiatue. dooids “the app ayiotixn —____
A -Mg -X +H-0H 7B -HE My Con) x.
aa nowd _
At he“[Link] H don =%
~ When at wate with 6- hydicogen atom
“Up | hosted with -oleoholic solution of KOM.
— hie do eliminalion ff, ypluagen -O%0™
~~ throm 6 Carbon and. a. halogen ober “hy om
thee cahen atom Ao a. sionult a
—elkant de permed + 9 us g oFter called
— 8 ‘Aimination +
+A 0_ellminaban otasttion involves “the 48m Oval _
———— fone. _motenle of Hx Yrom -the-motatula
ae O_halodlkant the oliminghipn vores 2
“Ath osabere yore! called areas ify
—__ + etaackions toy Henke
- = 1. oytaath ule oth? fap
~————4n_on_alkyt “natide — Corlain more -than_ one
“yh ob
eke + ot corepet with — haloalkane. o Auh —
_eatitubion tortion take shines en -halegen tem
—Louing Grip.) dapat os. hatide don ines —
the 9 gutbpluhution—suaction__ip__dini Hated by
_nusleophile ib tin «1 Colird pnicleophilée-: tibatida Bion
___ oteaction: _ a
= pec —x Seu sx é
Anema __of,- —enompla. oh —oucleopiilic — sarhion.
WG He Breet KOH ————> Ca Hs - 0H 4_KBr
Cy Hy Ch Ab KCN rt Co Hg CN EL
Cg Hs Ca. .AgCN a Co sNC TAG
—CHgCH2 Br + CottgNa ——>_ CHgCH—0 -Ca ts + NaBr
f= _Nesharam ot, “amélaahhidie Aubatitaion >"Roortien =:
Fla Fens 2 _S4hn—of
Jacsearkion~ :
SN Cunimalaculaw. —Nuchaphiie ante.)
—.SN2_T himoleentan —_Nusleahbibie __suoactie.
nuda asiana : stearHen 2 — — $= +
Te unl _Anio sguartien thea tate of staat
| depend only an the — concentration “hr
—— -alfey lL __halide—-—thasinbor & -thin —vieaction —army >
Cnlled di tumolaeiitay “nusleshhilic —bubsbfubion
ow ae
srtearkfon 1
a
—~
Pt nino} — stig — oa 985. wt
ppt Veins eof2) sna_Ceimoletolast: Inueltophitit Substitution. ecartion-
an tha —tyhe of —otpstion. vty —otane_
_-ien __do____“dapend-_on_ —fancentration alkyl alida
op tell a seo phil,
= sua guattion. ——0. coun dina thatoughy ——
! 4ronnifien” stata -
eh gar —ton7 ——> _Con7-=-- cg = 647) __—
CH,0H4 Br
b | a ”
Et ot
_uw) oOo a- © CHa FHBF Pononide.
| CZ 4
[NF = CH, ~CH, CH = Br
t 7 z 2,
| ——_ |
} y
E
-ow ; : :
z —chy ee CHa
Hl . 2 5
v) crattiate Nat —— CH .
vy) CugChaty 4 Nab CHyL
ons JHyt
. 4 Bagh —
© UV light —
eeLi Aye a
elt While fhe-sbrycone of a He ap sip pane pat
Cue CHUL a Nad ere Craetkce 1 phaet |
le nic ef_dffoenl—didaleyn Cen ClO, a aol
waive St faapre 3 =
amen SAE ohh CH
BN Caen; Ba bert ES cry cron RB
ed “GON -GHs| ——o-Gt Ig =0=Gis-i fat |
— og a ai 7 ens CyORUC ser
eye
Ti) ba bot chlonde te tragfed with abkitit
fy "Cis cH. CH Cel take. Foy seers
= CH ch Ch = che KO Ho)Naot ates ate and erate —
ite belles as
Orthe =—emed _mede= iiamess.
1o-Beephin-tohe © 3
Tele reco af ihe Ha
of aplhengl
GEN
CET Ail cheat Teeth ia
ci CT 9g Kol = CH CHM= (68) Whit ene cable huckophile? =
TT Keplatn ei examples
E Aly ambi pr aa ki
1 as
Syjart lites mt spe
nel anid cule lets
at Sanne he Cada
a ies chess
2 ~ “r= 2 SN== : —Hauanen es. /4
_.Combourd_obbeined a ——_aubstitutien of
— al dace gen = ree 6h ee hydouecastbon
tos helen gt ce wu, i. +L) axe called ~ halide —
| _Chinsiohenzene - Chiosisbinzene —_Chinowbenvent
89 gg tg gy
= (6) —\.— ee og)
Oy re
___.Buinmobrnzene 1,a-- LiGooma___4,9,.3 ti. Qstome -___
_ + + Bonzene Gonzeno
a —METHO0 oF fReenennoN_of
~— Fett ——+
es poe 7
| + ba Ses
2) Fotom tire: ray) Roachion) —4
—When_.___p.$timnasiy seit ineot MOip solved oe
0 eetd ucoun acid | os treated
with —NaNoa a. ae: —_dalt— dn_formeds
—!
Shin ——stanetign a Known an ~ diazatisation—
- { NeN0y + HOt Co -
—[0) aS ttt
=F
TER _Gazene dizonium
7 Chinsude- |
When dizenium chalk | to treoted unitth eal
———0f —Cutla + HO 6+ _CuBra + HBr _,-the chipodine
Tee ee —rthin_suockion aa
Koown woortion
irae 20 ——bondmargas = =
7 Nyc Sed: + Fi
“2) _Fowom —diovect _halogenatlen.-!.
co Os. ae OL
* 0 -Ftolo:
*skotuana
“Cerren ‘Aractiow oF,
— ~ Jratoreies—
y Nusleopintic Substitution _yiancklon
TAY Reaction Suith mbdl « — -
‘3)- Cisetvephilics _. durcbhtitubion : _owockions
1 ‘Nustsiphlit ~ Sutottubion
‘ 4H
y- hlacemant Peon aia (Dour poroceda- “tor tho
fe She 4 : __monupackune of phenat)
_ (ChJowiebincens.__Con. be cenventad __dinke _phonel_by
—__—, hantling- dn __.09 utoun —fNooit holuHen of 4 —__
fembiotune — oh © 625k ——e— 20 [Link]
tt ;
Hh 63,
— as S00 ale
“ed ‘ite 03 ak
a - =a “et Wp
Bcdiun
- { ~Phanoxide7 React bap amine, -qoouh— (ania :
ae ; wit —aguasun — ammonia Un Anta
=e of Cu 20 Geupont onde) ° ok Gis K —Ond q
Ports
ak + ——— —
—— Nr =
oy Yo -
4—INH3 ithe eae? eee ( +eubi| _
aL Anttne HO [- =
ena ovr Grau, ee, o to
oe ee £5 el
___|_on_—_hasling aie cubious—cynit
ah pga on mt ‘te =
packed 6 a olBur : -—_____—_
T © + INo + CHa Br whe = (0) 4 2NaBy
= Fak legeeabion rif esGivea.. analaque
: tng 2+ st Su -auhan +: streaked —“uith
v4 Shae inst ethan an! + thith tw
tle grep ane jalnad veeogpbhan 9k Gn
n cals” = filing cHoactton.
halsastonen tone cuith dedium in
- : = “poms of at ethou = idaho
—— _ Oiphenyt
__ 2) Reartion with my x
a -Sigmlan to “alkyl halide ool —binmide ond —
—Andine _olnn _ stonek sith 2" tia, dou ethp—-— —= —= ye
Boy - _ -
| aby
hee 4
a, he i Author :
pt wtrartian of, th. __henzens___ ong —- =
pleas halegiedtion sy ‘nitration — Aulbhonalion- ~ ond}
LtaeCoubtr: sypteartion 3+ Dug ta __osehpnante—. en.
“uancstengs sscimores.—ok—0° ond j
te. Js Popthion +o thon ob mz, 2+ poniinn ++ ;
BE! _ seine cuits felis a4
FE) intoge Aalion a ciwer pear eie fed —
BS gg + eth eeleg j cy peg fe — _
{ 4
Bobi Foc th
ere ae
a
—. ‘ya Madoran
=e ees hs! dichlone bonzene——t mt mar
(major)
NO,
4. mitrochloet-
Aanzene
aa3) ulphanation + - ce of
j t SOqh
ce}
- 2 o) + 2s50,—~—>
Achlosio benzene SO3H
Sulbhonk acid qe ~ thlosben-
v2ene balh horue
+ Pouedal coin Reaction ——
». Aiken -t -
——— ca
CA |
: — Rahal Cg
= | (0) + Cgc —Aitls, +
— oe ph 2 na !
. = Genzene Cha
a). Alkylation 7
—+— Gt
; oct tu -
ANTS? ? FY
___I-CH o10™1-arete SN
> Phenone
eh 5 oF psecha
, — / ~aretophinone