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The document discusses various chemical reactions involving haloalkanes, including substitution and elimination reactions. It covers the mechanisms of nucleophilic substitution and the properties of different halogenated compounds. Additionally, it briefly touches on methods for synthesizing and transforming these compounds in organic chemistry.

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0% found this document useful (0 votes)
10 views20 pages

Solution Notes

The document discusses various chemical reactions involving haloalkanes, including substitution and elimination reactions. It covers the mechanisms of nucleophilic substitution and the properties of different halogenated compounds. Additionally, it briefly touches on methods for synthesizing and transforming these compounds in organic chemistry.

Uploaded by

neetusonin42
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
_Hatoalkanco J = RH all eile - CHgth = chioride- ce __cHactaBr exh Qouomide : 13 nalagan _davivaive—cb: aliphatic oF Asura 4 __ Coben one. called clans OF Gn the. booin_____00- of, — nekwst oh halogen Casthenakion Monchalaalkane 1 ——— — == SS City Ct = CHyCHaCh —_____dihaloalkang.+ ate fensthuytent | dichloromethane Chiosido. feta palonkon: Cig Cast on tebe __ Chiovide a Jon the basin_of Canton ee | heloalkang a? = netsh ate ie CHa aha ab 208 [ge paloalieine... a 1 Chg — CH — Co Ft ons st haloolkene (3, _ Chg 6 — Cd. “Le ! chs joo tes basta —hypetidizating <¢______ 2 Alky{ halide Cha —CHa —CH spa sea — 0) Ally tie haut CH = CH-CHa—Cd se? sp3. r6e3 a) wiani halide CHS “= 1. C= sp 3. wa Le : T 7 yu at sisi frnase, _ds 1 , Vinge ‘ I - Gar CHa = CH-Cu NY fRogl halla on ~ or oe oe ——__Metnad of Asuperation of halo alkanc — 1). Fotom —_aleahe! — aychiybucnn suptier ind oH son a el — Pty: Cate cel 4 Hod = CoWcoH + Plus — Ca tlt Potlg ie HCL 18a Wea + Peg >) aC attgtd 4 3003 Apel oF oa r _CoHsoH. 460d, . ——=§ Toauer of —oveactinity o- ‘Kalogen oxid Hl >HiSo.2 Hoy [ 3), be preectithala' nation. oh alkoxy Stet gM GHC ~ Ct Cty lg coy | ahed Cn clMch ‘ 3)_finkeahin ——sstonchion= ' Or2tene _ CBr + Na t——> AICS Tye —— Atattiviky — 0} _Haloalkone.- “jhe haloaltcona one —- highly _“Amoortive due ~tp__ante___ of splat C-A_ @ond + orden — j—th—omactivity, — ont DCH aBr CHatd ad Usieiak wt - bon = oN) Cement petofesrdicn “b Haloalkene- fota 4 oe 4. aol _ Tgpcnd ‘veachion. of -[Link] may he . dewidod | tints ee aie sist! Baviins 4 ——e cfaippdéa 22 > Holoatkont _ Petes = tar, ares sath sel — Flkecton ae eae — —slreies ————— W) Roortion —aisith No Cususike ascdorbion} = ie _ ——— Adeyl halide ce. suarttert be «just bh sans ag ~ otha to give “hydsingecansbana +e = AX + DN, ———— R-AK asec (bap en ———itHab— 4.2No tong cg +t onaBys Ethons) fle 9p a a2) igenetion— “sit mapa! Calon of. _palpalkanen therm —grignased_ ouapat Cag fagnas — ep eel iat th cheered act iustth 1 ekhgne CHg.CHg8y_ +. at if a mpei God gnostdic T Ahould/ tae: pouasal_onde Onhydno wd concibinn___ bararhe Giugno. Hongint. Ss ane __hig _pomcive.. Tk wiogrte —wibh___ —moiatue. dooids “the app ayiotixn —____ A -Mg -X +H-0H 7B -HE My Con) x. aa nowd _ At he “[Link] H don =% ~ When at wate with 6- hydicogen atom “Up | hosted with -oleoholic solution of KOM. — hie do eliminalion ff, ypluagen -O%0™ ~~ throm 6 Carbon and. a. halogen ober “hy om thee cahen atom Ao a. sionult a —elkant de permed + 9 us g oFter called — 8 ‘Aimination + +A 0_ellminaban otasttion involves “the 48m Oval _ ———— fone. _motenle of Hx Yrom -the-motatula ae O_halodlkant the oliminghipn vores 2 “Ath osabere yore! called areas ify —__ + etaackions toy Henke - = 1. oytaath ule oth? fap ~————4n_on_alkyt “natide — Corlain more -than_ one “yh ob

eke + ot corepet with — haloalkane. o Auh — _eatitubion tortion take shines en -halegen tem —Louing Grip.) dapat os. hatide don ines — the 9 gutbpluhution—suaction__ip__dini Hated by _nusleophile ib tin «1 Colird pnicleophilée-: tibatida Bion ___ oteaction: _ a = pec —x Seu sx é Anema __of,- —enompla. oh —oucleopiilic — sarhion. WG He Breet KOH ————> Ca Hs - 0H 4_KBr Cy Hy Ch Ab KCN rt Co Hg CN EL Cg Hs Ca. .AgCN a Co sNC TAG —CHgCH2 Br + CottgNa ——>_ CHgCH—0 -Ca ts + NaBr f= _Nesharam ot, “amélaahhidie Aubatitaion >"Roortien =: Fla Fens 2 _S4hn—of Jacsearkion~ : SN Cunimalaculaw. —Nuchaphiie ante.) —.SN2_T himoleentan —_Nusleahbibie __suoactie. nuda asian a : stearHen 2 — — $= + Te unl _Anio sguartien thea tate of staat | depend only an the — concentration “hr —— -alfey lL __halide—-—thasinbor & -thin —vieaction —army > Cnlled di tumolaeiitay “nusleshhilic —bubsbfubion ow ae srtearkfon 1 a —~ Pt nino} — stig — oa 985. wt ppt Veins eof 2) sna_Ceimoletolast: Inueltophitit Substitution. ecartion- an tha —tyhe of —otpstion. vty —otane_ _-ien __do____“dapend-_on_ —fancentration alkyl alida op tell a seo phil, = sua guattion. ——0. coun dina thatoughy —— ! 4ronnifien” stata - eh gar —ton7 ——> _Con7-=-- cg = 647) __— CH,0H4 Br b | a ” Et ot _ uw) oOo a- © CHa FHBF Pononide. | CZ 4 [NF = CH, ~CH, CH = Br t 7 z 2, | ——_ | } y E - ow ; : : z —chy ee CHa Hl . 2 5 v) crattiate Nat —— CH . vy) CugChaty 4 Nab CHyL ons JHyt . 4 Bagh — © UV light — ee Li Aye a elt While fhe-sbrycone of a He ap sip pane pat Cue CHUL a Nad ere Craetkce 1 phaet | le nic ef_dffoenl—didaleyn Cen ClO, a aol waive St faapre 3 = amen SAE ohh CH BN Caen; Ba bert ES cry cron RB ed “GON -GHs| ——o-Gt Ig =0=Gis-i fat | — og a ai 7 ens CyORUC ser eye Ti) ba bot chlonde te tragfed with abkitit fy "Cis cH. CH Cel take. Foy seers = CH ch Ch = che KO Ho) Naot ates ate and erate — ite belles as Orthe =—emed _mede= iiamess. 1o-Beephin-tohe © 3 Tele reco af ihe Ha of aplhengl GEN CET Ail cheat Teeth ia ci CT 9g Kol = CH CHM = (68) Whit ene cable huckophile? = TT Keplatn ei examples E Aly ambi pr aa ki 1 as Syjart lites mt spe nel anid cule lets at Sanne he Cada a ies chess 2 ~ “r= 2 SN == : —Hauanen es. /4 _.Combourd_obbeined a ——_aubstitutien of — al dace gen = ree 6h ee hydouecastbon tos helen gt ce wu, i. +L) axe called ~ halide — | _Chinsiohenzene - Chiosisbinzene —_Chinowbenvent 89 gg tg gy = (6) —\.— ee og) Oy re ___.Buinmobrnzene 1,a-- LiGooma___4,9,.3 ti. Qstome -___ _ + + Bonzene Gonzeno a —METHO0 oF fReenennoN_of ~— Fett ——+ es poe 7 | + ba Ses 2) Fotom tire: ray) Roachion) —4 —When_.___p.$timnasiy seit ineot MOip solved oe 0 eetd ucoun acid | os treated with —NaNoa a. ae: —_dalt— dn_formeds —! Shin ——stanetign a Known an ~ diazatisation— - { NeN0y + HOt Co - —[0) aS ttt =F TER _Gazene dizonium 7 Chinsude- | When dizenium chalk | to treoted unitth eal ———0f —Cutla + HO 6+ _CuBra + HBr _,-the chipodine Tee ee —rthin_suockion aa Koown woortion irae 20 ——bondmargas = = 7 Nyc Sed: + Fi “ 2) _Fowom —diovect _halogenatlen.-!. co Os. ae OL * 0 -Ftolo: *skotuana “Cerren ‘Aractiow oF, — ~ Jratoreies— y Nusleopintic Substitution _yiancklon TAY Reaction Suith mbdl « — - ‘3)- Cisetvephilics _. durcbhtitubion : _owockions 1 ‘Nustsiphlit ~ Sutottubion ‘ 4H y- hlacemant Peon aia (Dour poroceda- “tor tho fe She 4 : __monupackune of phenat) _ (ChJowiebincens.__Con. be cenventad __dinke _phonel_by —__—, hantling- dn __.09 utoun —fNooit holuHen of 4 —__ fembiotune — oh © 625k ——e— 20 [Link] tt ; Hh 63, — as S00 ale “ed ‘ite 03 ak a - =a “et Wp Bcdiun - { ~Phanoxide 7 React bap amine, -qoouh— (ania : ae ; wit —aguasun — ammonia Un Anta =e of Cu 20 Geupont onde) ° ok Gis K —Ond q Ports ak + ——— — —— Nr = oy Yo - 4—INH3 ithe eae? eee ( +eubi| _ aL Anttne HO [- = ena ovr Grau, ee, o to oe ee £5 el ___|_on_—_hasling aie cubious—cynit ah pga on mt ‘te = packed 6 a ol Bur : -—_____—_ T © + INo + CHa Br whe = (0) 4 2NaBy = Fak legeeabion rif esGivea.. analaque : tng 2+ st Su -auhan +: streaked —“uith v4 Shae inst ethan an! + thith tw tle grep ane jalnad veeogpbhan 9k Gn n cals” = filing cHoactton. halsastonen tone cuith dedium in - : = “poms of at ethou = idaho —— _ Oiphenyt __ 2) Reartion with my x a -Sigmlan to “alkyl halide ool —binmide ond — —Andine _olnn _ stonek sith 2" tia, dou ethp —-— —= —= ye Boy - _ - | aby hee 4 a, he i Author : pt wtrartian of, th. __henzens___ ong —- = pleas halegiedtion sy ‘nitration — Aulbhonalion- ~ ond} LtaeCoubtr: sypteartion 3+ Dug ta __osehpnante—. en. “uancstengs sscimores.—ok—0° ond j te. Js Popthion +o thon ob mz, 2+ poniinn ++ ; BE! _ seine cuits felis a4 FE) intoge Aalion a ciwer pear eie fed — BS gg + eth eeleg j cy peg fe — _ { 4 Bobi Foc th ere ae a —. ‘ya Madoran =e ees hs! dichlone bonzene——t mt mar (major) NO, 4. mitrochloet- Aanzene aa 3) ulphanation + - ce of j t SOqh ce} - 2 o) + 2s50,—~—> Achlosio benzene SO3H Sulbhonk acid qe ~ thlosben- v2ene balh horue + Pouedal coin Reaction —— ». Aiken -t - ——— ca CA | : — Rahal Cg = | (0) + Cgc —Aitls, + — oe ph 2 na ! . = Genzene Cha a). Alkylation 7 —+— Gt ; oct tu - ANTS? ? FY ___I-CH o10™1-arete SN > Phenone eh 5 oF psecha , — / ~aretophinone

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