CALCULATION [10 Marks]
1. Spirits of salts is used in the building industry to clean excess mortar from
new brickwork. The active ingredient is hydrochloric acid with a
concentration of around 13 mol L-1. In order to precisely determine the
concentration of hydrochloric acid in some spirits of salts, a chemist takes
a 20.00 mL aliquot and makes this up to 500.0 mL in a volumetric flask.
The diluted spirits of salts is analysed by taking 20.00 mL samples of the
diluted solution and titrating this with 0.4590 mol L -1 sodium hydroxide
solution. An average titre of 21.25 mL of base was obtained for the end
point. Use this information to determine the following:
a) The moles of sodium hydroxide used in the titration.
[2 marks]
b) The concentration of hydrochloric acid in the diluted solution.
[3 marks]
c) The concentration of the hydrochloric acid in the original spirits of
salts.
[2 marks]
d) The percentage of hydrochloric acid by mass in the original undiluted
spirits of salts. Assume the original solution has a density of 1.18 g
mL-1.
[3 marks]