21-12-2025

1001CJA106216250222 JA

PART-1 : PHYSICS

SECTION-I

1) A hydrogen atom (at ground state) of kinetic energy k, head on collides with stationary helium
atom (at ground state). Find minimum value of k for which after collision, photons corresponding to
Balmer series of hydrogen and Lyman series of helium are emitted :

(A) 66.2 eV
(B) 80 eV
(C) 51 eV
(D) 53.36 eV

2) In a sample of hydrogen like atoms all of which are in ground state, a photon beam containing
photons of various energies is passed. In absorption spectrum, five dark lines are observed. The
number of bright lines in the emission spectrum will be (assume that all transitions take place)

(A) 21
(B) 10
(C) 15
(D) None of these

3) Statement–1 : Pendulum clocks go slow in summer and fast in winter.

and
Statement–2 : The length of the pendulum used in clock increases in summer.

Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for

(A)
Statement–1
Statement–1 is True, Statement–2 is True ; Statement–2 is NOT a correct explanation for
(B)
Statement–1
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

4) The graph representing correct relation of frequency of characteristic X-ray with the atomic
number Z of material is :

(A)
(B)

(C)

(D)

5) A rod of length ‘5m’ and mass ‘12 kg’ leans against the wall as shown. If end ‘A’ of rod is moving
with a velocity of 3 m/s and rod makes an angle of 37° with horizontal find kinetic energy of rod at

that instant :

(A) 50 Joule
(B) 100 Joule
(C) 150 Joule
(D) 200 Joule

6) In a system of four thin uniform rods each of mass m as shown. If AE = EB, AH = HD and BC = 2

AB then choose the CORRECT statement :-

(A) Moment of inertia of the system is minimum about EG
(B) Moment of inertia of the system is maximum about HF
(C) Moment of inertia of the system is minimum about HF
(D) Moment of inertia of the system is maximum about EG

7) A hollow sphere of mass M and radius r slips on a rough horizontal plane. At some instant it has
translational velocity v0 and angular velocity about the centre v0/2r as shown in the figure. The

translational velocity after the sphere starts pure rolling

(A) 4v0/5 in forward direction

(B) 6v0/7 in backward direction
(C) 6v0/7 in forward direction
(D) 5v0/4 in backward direction

8) A sphere has to purely roll upwards. At an instant when the velocity of sphere is v, frictional force

acting on it is

(A) Downwards and μmg cosθ

(B)
Downwards and
(C) Upwards and μmg cosθ

(D)
Upwards and

9) A block A of mass m is moving on a frictionless horizontal plane towards a smooth wedge (B) of
mass 2m, which is kept at rest on smooth horizontal plane at t = 0, At t = t1, it is found that both
block & wedge is moving with same velocity and at t = t2 it is found that block & wedge are again
moving on the horizontal frictionless plane. In list-I work done by different forces are given and in

list-II value of work done by those forces are given.

List-I List-II

(P) Work done by gravity on block A from t = 0 to t = t1 (1)

(Q) Work done by normal force exerted by wedge on the block A from t = 0 to t = t1 (2)
 Work done by the normal force exerted by block A on the wedge for t = t1 to t =
(R) (3) Zero
t2.

(S) Work done by the gravity on block A from t = 0 to t = t2. (4)

(A) (P) - (2) ; (Q) - (1) ; (R) - (4) ; (S) - (3)

(B) (P) - (1) ; (Q) - (3) ; (R) - (1) ; (S) - (2)
(C) (P) - (3) ; (Q) - (1) ; (R) - (4) ; (S) - (2)
(D) (P) - (4) ; (Q) - (1) ; (R) - (2) ; (S) - (3)

10) Which of the following is most correct ?

If net force on a system is zero then the momentum and kinetic energy of the system remains
(A)
conserved.
Internal forces can change the mechanical energy of the system [Assume only conservative
(B)
forces are present in system]
In elastic collision (e = 1), the momentum and the kinetic energy of system will be conserved
(C)
throughout the collision.
If net external force on system is non-zero then it might be possible to conserve the mechanical
(D)
energy.

11) Two identical balls are interconnected with a light and inextensible thread having length ℓ. The
system is on a smooth horizontal table with the thread just taut . Initial velocities of both as shown.

The kinetic energy of the system after the string gets taut.

0
(A) mv
(B) 2mv2
(C) 3/4 mv2
(D) 3/2 mv2

12)

Two identical balls are moving as shown. The final speed of ball A & total number of collisions is :-
(All collisions are elastic)

(A) u, 3
(B) u, 4
(C) 2u, 2
(D) 2u, 3

13) A small sphere of radius r and mass m is placed on a big hemisphere of mass 2m and radius R
which is kept on a smooth horizontal surface as shown in the figure. Find the displacement of
hemisphere when line joining between centre of small sphere and centre of big hemisphere makes
30° with the vertical (initially this line was vertical, and assume small sphere is not losing the
contact with hemisphere)

(A)

(B)

(C)

(D) None of these

14) Two identical small elastic balls have been suspended using two strings of different length (see
figure (a)). Pendulum A is puled to left by a small angle θ0 and released. It hits ball B head on which
swings to angle 2θ0 from the vertical. Calculate the time period of oscillation of A if its length is

known to be ℓ.

(A)

(B)

(C)

(D)

15) Statement-1 : To calculate KE of a body we can assume the whole mass is supposed to be
concentrated over centre of mass

Statement-2 : VCM = , where symbols have their usual meanings.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

16) Circuit given below is that of

(A) AND gate

(B) OR gate
(C) NAND gate
(D) NOR gate

17) For D1 forward bias resistance is 20 Ohm and reverse bias resistance is 600 Ohm. For D2 forward
bias resistance is 30 Ohm and reverse bias resistance is 200 Ohm. Find the equivalent resistance
between A and B if (i)A is at a higher potential (ii) B is at a higher potential

(A)

(B)

(C)
(D)

18) In the figure D is an ideal diode and an alternating voltage of peak value 10 volts is connected as
input v1, Which of the following figures represents the correct waveform of output voltage v0?

(A)

(B)
(C)

(D)

19) Which one of the following statement is not correct in the case of light emitting diodes?
A. It is a heavily doped p-n junction.
B. It emits light only when it is forward biased.
C. It emits light only when it is reverse biased.
D. The energy of the light emitted is equal to or slightly less than the energy gap of the
semiconductor used.
Choose the correct answer from the options give below:

(A) C and D
(B) A
(C) C
(D) B

20) Drawing power from a 12V car battery, a 9V stabilized DC voltage is required to power a car
stereo system, attached to the terminals A and B, as shown in the figure. If a Zener diode with
ratings, Vz = 9V and Pmax = 0.27 W, is connected as shown in the figure, for the above purpose, the

minimum series resistance RS must be :-

(A) 111Ω
(B) 103Ω
(C) 100Ω
(D) 97 Ω

SECTION-II

1) A small piece of cesium metal (work function'ϕ' = 1.9 eV) is kept at a distance of 20 cm from a
large metal plate having a charge density of 1.0 × 10–9 C/m2 on surface facing the cesium piece. A
monochromatic light of wavelength 400 nm is incident on the cesium piece. Ratio of maximum to
minimum kinetic energy of the photoelectron reaching the large metal plate is given by k. Then find
the nearest integral value of 'k'.

2) If 20 gm of a radioactive substance due to radioactive decay reduces to 10gm in 4 minutes, then

in what time (in minutes) 80gm of the same substance will reduce to 20 gm -
3) A ball hits the rough horizontal surface at an angle 45° from vertical and reflected at an angle 45°
from the vertical, then find 6μ where μ is coefficient of friction between the ball and the surface.

4) A metre stick swinging in vertical plane about an fixed horizontal axis passing through its one end
undergoes small oscillation of frequency is . If the bottom half of the stick were cut off, then

its new frequency (in Hz) of small oscillation would become:

5) If this body rolls purely then time period of its small oscillations is T. It's moment of inertia about

CM is 9 kg.m2. Fill value of ?

PART-2 : CHEMISTRY

SECTION-I

1)

List-I List-II
(Pair of compounds) (Differentiated by)

(P) (1) Fehling solution

and
 (Q) (2) Tollen's reagent
and

(R) (3) NaHSO3

and

(S) (4) NaHCO3

and
(A) P → 2; Q → 3; R → 1; S → 4
(B) P → 1; Q → 4; R → 1,2; S → 3
(C) P → 1,2; Q → 3; R → 2,3; S → 4
(D) P → 1,2; Q → 4; R → 2; S → 3

2)
Which of the following statement(s) is not correct about reaction sequence and products.

(A) Polymerisation of product V gives poly methyl acrylate.

(B) 3 moles of product W gives benzene as product when it is passed through red hot Cu tube.
(C) Dipole moment of product R is zero.
(D) Product P, R and W gives positive bromine water test.

3) A (B)
Major product (B) is :

(A)

(B)
(C)

(D)

4) Consider the following amines :

(a) CH3CH2 – NH2
(b) CH3 – NH – CH3
(c) (C2H5)3N
(d) PhNH2

(e)

(f)

(g)
Find (X + Y + Z) where
X = No. of amines give foul smelling poisonous gas when treated with CHCl3/KOH.
Y = No. of amines produce oily yellow coloured nitroso compound when treated with aq. HNO2
Z = No. of amines after reacting with Ph–SO2Cl, the product will be soluble in aq. KOH.

(A) 3
(B) 6
(C) 9
(D) 12

5) Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason
R.

Assertion (A) : can be subjected to Wolff-Kishner reduction to give .

Reason (R) : Wolff-Kishner reduction is used to convert into .

In the light of the above statements, choose the correct answer from the options given below :

(A) Both A and R are true but R is NOT the correct explanation of A.
(B) A is true but R is false.
(C) A is false but R is true.
(D) Both A and R are true and R is the correct explanation of A.
6)
Q is :

(A)

(B)

(C)

(D)

7) In which of the following reaction, 2º alcohol is obtained as major product.

(A)

(B)

(C)

(D) None of these

8)
Which of the following tests is not given by compound (Z)

(A) Fehling test

(B) Tollen's test
(C) Iodoform test
(D) Lucas test

9)

(A)

(B)

(C)

(D)

10) Consider 100 ml 1M NaCl aq. solution having freezing point t°C. 50 ml 3M AgNO3 is added in
this solution, then (Consider molarity = molality)

(A) freezing point of resulting solution will become 2 t°C.

(B) freezing point of resulting solution will remain same t°C.
(C) freezing point of resulting solution will become 0.5 t°C.
(D) freezing point of resulting solution will become 1.5 t°C.

11) The thermal decomposition of acetaldehyde : CH3CHO(g) → CH4(g) + CO(g), has rate constant of

1.8 × 10–3 mol–1/2 L1/2 min–1 at a given temperature. How would – will change if
concentration of acetaldehyde is doubled keeping the temperature constant?

(A) will increase by 2.828 times

(B) will increase by 11.313 times
(C) will not change
(D) will increase by 4 times

12) The kinetic energy of the photoelectron ejected from metal surface increased from 0.6 eV to 0.9
eV, when the energy of incident photon was increased by 20%. The work function of the metal is

(A) 0.66 eV
(B) 0.72 eV
(C) 0.90 eV
(D) 0.30 eV

13) Hydrogen atoms in a particular excited state of orbit number 'n'. When all returned to ground
state, photons of 6 different energies are emitted. The total number of radial nodes in all the orbitals
of nth shell are

(A) 6
(B) 8
(C) 12
(D) 14

14) The mass of glucose that should be dissolved in 100 g of water in order of produce the same
lowering of vapour pressure as produced by dissolving 1 g of urea (molecular mass = 60) in 50 g of
water is :

(A) 6 g
(B) 1 g
(C) 2 g
(D) 12 g

15) The following figure gives the plot of boiling point (Tb) of a mixture of two volatile liquids A and B

vs mole fraction of A, ZA Mixture is composed of

(A) HNO3 and H2O

(B) C2H5OH and H2O
(C) C2H5Cl and C2H5Br
(D) CCl4 and CHCl3

16) Select the correct statement when positive catalyst is added in a chemical reaction

(A) It decreases enthalpy of chemical reaction.

(B) It does not alter the gibbs free energy change of a reaction.
(C) It increases the potential energy barrier.
(D) It catalyse all chemical reaction.

17) On mixing 2.5 g of non-volatile, non-electrolyte solute in 200 mL of water, its boiling point
becomes 100.13°C at 1 atm pressure. If kb for water is 0.52 [Link]/mole, then molecular weight of
solute is :

(A) 50 g/mol
(B) 60 g/mol
(C) 30 g/mol
(D) 15 g/mol

18) Select the number of correct statements from the given.

S1 : Potential energy of the two opposite charge system (point charges) increases with the decrease
in distance.
S2 : When an electron make transition from higher orbit to lower orbit, it's kinetic energy increases.
S3 : When an electron make transition from lower energy to higher energy state, it's potential energy
increases.
S4 : 11 eV photon can free an electron from the 1st excited state of He+ ion.

(A) 0
(B) 1
(C) 2
(D) 3

19) Statement-1 : Rate of irreversible elementary reaction increases with increase in temperature,
always.
Statement-2 : Increasing the temperature of the substance increase the fraction of molecules,
which collide with energies greater than activation energy.

(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
Statement-1 is true, Statement-2 is true and Statement-2 is NOT the correct explanation for
(B)
Statement-1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

20) Which of the following reactions represent correct major product formation.

(A)

(B)
(C)

(D)

SECTION-II

1) Major product
The ratio of number of carbons in the product to the number of keto groups in the product is

2) In a sample of hydrogen atom an electron is in the 5th excited state. Find the total number of
possible electronic transitions in Balmer series.

3) Arsine decomposes on heating according to the first order equation

AsH3(g) → As(s) + H2(g)
The decomposition was studied at constant temperature and constant volume by measuring total
pressure at various time intervals.

Time (in min) 0 20

Total pressure (mmHg) 300 375

Calculate total pressure (mmHg) at time 80 minutes.
(Answer to the nearest integer)

4) Mole fraction of component B in the vapour phase is 0.6 and that of component A in liquid mixture
is 0.8. The observed vapour pressure of ideal liquid mixture is 0.60 atm. Calculate vapour pressure
(in mmHg) of pure liquid B.

5) The compound among following which can give both 2,4-DNP test (2,4-dinitrophenylhydrazine
test) & Iodoform test with (NaOH I2).

(i) (ii) (iii) (iv)

(v) (vi) (vii) (viii)

(ix) (x)

PART-3 : MATHEMATICS

SECTION-I

1) If the equation x3 – 9x2 + 24x + k = 0 has three distinct and real roots then number of integral
values of k is

(A) 2
(B) 3
(C) 4
(D) 5

2) Let f be a continuous function such that . The value of is

(A)

(B)

(C) 1
(D) 2

3) Assertion A : The function f(x) = x3 + bx2 + cx + d where 0 < b2 < c is strictly increasing in (–∞,
∞).
Reason R : If f is continuous on (a, b), differentiable in (a, b) and f'(x) > 0 ∀ x ∈ (a, b), then f is
strictly increasing in (a, b).

(A) A is correct but R is not correct.

(B) A is not correct but R is correct.
(C) Both A and R are correct but R is NOT the correct explanation of A.
(D) Both A and R are correct and R is the correct explanation of A.

4) If where 'C' is constant of integration and f(1) = 2

then the value of (f′(1) + f′′(1)) is

(A) 2
(B) 4
(C) 8
(D) 12

5) The value of is

(A)

(B)

(C)

(D)

6) Let S = {z|z – 6 – 8i| = 5, z ∈ C}. If z1,z2 ∈ S such that |z1| is maximum and

then |z2| is

(A)
(B)
(C)
(D)

7) The median of a set of 9 observations is 20.5. If each of the largest five observations are increased
by 2 and each three smallest observation are decreased by 2 then the median of the new set

(A) remains the same as that of the original set

(B) is increased by 2
(C) is decreased by 2
(D) is two times the original median

8) The least value of where α,k ∈ R, is

(A) 12
(B)
(C) 16
(D)

9) Let , n ∈ N ∪ {0}

List-I List-II

(A) 9u3 = (I) 7

(B) 4(4u4 – 3u2) = (II) 3

(C) 30(10u10 – 9u8) = (III) 1

[16u2 – 4] =
(D) (IV) 9
{[.] → GIF}
(A) (A) – I, (B) – II, (C) – III, (D) – IV
(B) (A) – II, (B) – I, (C) – III, (D) – IV
(C) (A) – I, (B) – III, (C) – II, (D) – IV
(D) (A) – I, (B) – II, (C) – IV, (D) – III

10) Let a real valued function f satisfies the inequality |f(x) + x2 + 1| > |f(x)| + |x2 + 1| and f(x) < 0.

The value of is

(A) 3 + 2ℓn2
(B) 3 + 4ℓn2
(C) 4 + 4ℓn2
(D) 4 + 2ℓn2

11) Let z2 = a + ib, a,b ∈ R be a complex number such that |z| = 5. If |z2 – 1 – 2i| is maximum then

is equal to

(A) 25
(B) 30
(C) 35
(D) 45

12) Let f : R → R be a function for which f′, f′′, f′′′ and f′′′′ exists and f(0) = 0, f(1) = 1, f(2) = –1, f(3) =
2 and f(4) = –2. Then minimum numbers of zeros (4f'f"' + 3(f")2 + f f"")(x) is

(A) 3
(B) 4
(C) 5
(D) 6

13) The mean and standard deviation of 15 observations are found to be 7 and respectively. On
rechecking it was found that, in the observation 5 was misread as 20. The correct variance is

(A) 5
(B) 4
(C) 4.5
(D) 6

14) Let f be a differentiable function and |f ′(x)| ≤ 5 for all x ∈ R. If f(1) = 9, f(5) = 29 then the value
of f(4) – f(3) is

(A) 5
(B) 4
(C) 3
(D) 2

15) Let A = {z|(z + 1)4 = 16z4 , z ∈ C} and

Statement-I : n(A ∩ B) = 2
Statement-II : A ray emanating from any point inside a circle meets the circle at exactly one point

(A) Statement-I is true but Statement-II is false

(B) Both Statement-I and Statement-II are false
(C) Both Statement-I and Statement-II are true
(D) Statement-I is false but Statement-II is true

16) is equal to -
(Where 'C' is the constant of integration)

(A)

(B)

(C)

(D)

17) The number of point(s) of inflection on the curve in [–π, π]

is(are) -
(A) 2
(B) 0
(C) 4
(D) 3

18) If arguments of all the roots of the equation satisfying the equation 1 + z5 + z10 + z15 + . . . + z125

= 0 lie in (0, 2π) and largest value of the argument of one of the roots is where p & q are
coprime, then (p + q) is -

(A) 388
(B) 363
(C) 259
(D) 194

19) If the curves 4x2 + 3y2 = 1 and 6x2 + αy2 = 1 intersect each other at right angle they 'α' is -

(A) 4
(B) 5
(C) 3
(D) 6

20) Consider the statistics of two sets of observations as follows :

Size Mean Variance
observation -I n1 2 2
observation -II n2 3 1

If the variance of combined set of those two observation is then is

(A) 15
(B) 60
(C) 20
(D) 30

SECTION-II

1) The number of solutions of the equation is

2) If and then is equal to

3) Consider, . If is has the least value then (a +
b) is

4) If tangent drawn to the curve g(x) = e–x(x2 – 8x + 17) – 4x at P(t,g(t)) meets the curve again at two
distinct points then sum of all possible integral values of 't' is

5) Let x1,x2,x3,........ be n numbers as , i = 1,2,3,....n. A new data is constructed by

replacing each xi by (xi – 3i) and if arithmetic mean of new data is then the value of n is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C A C A A A D D D C D C B D C B D C C

SECTION-II

Q. 21 22 23 24 25
A. 1 8 2 4 4

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A B C C B C D C B A C D A A B A C A D

SECTION-II

Q. 46 47 48 49 50
A. 3 4 431 1368 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D D C A C B C C B C B A A D C B D A A

SECTION-II

Q. 71 72 73 74 75
A. 3 3 4 6 20
 SOLUTIONS

PART-1 : PHYSICS

1) Maximum possible loss

=
Minimum energy required
= 12.1 + 40.8 = 52.9

2)

Correct answer is (C)

3)

Explanation Question:
Pendulum lock moves and we have to choose the correct statement.

Concept:
This question is based on motion due to energy

Solution:
In summer temperature is more than the temperature in winter which increases the length
due to which pendulum performs slow oscillation.

Final Answer : The correct option is (1)

4)
ν = a2 (z – b)2
ν vs z graph will parabola.
(Increasing slope)

5)

KE =
 IIOR = ICOM + Md2 = = 100
v = ωR
∴ 50 Joule

6) Moment of inertia is maximum if masses are farther from the axis and vice-versa

7)
Angular momentum can be conserved about lowest point

0
mv r + = mv'r +

v' =

8)

Correct answer is (D)

9) Wgravity = 0

10) Explanation Question:

We have to select the appropriate option.

Concept:
Conservation of momentum and mechanical energy of system.

Solution:
The net force on a system is the vector sum of all the forces acting on it. If the net force is
zero, it indicates that the forces are balanced. According to Newton's first law of motion, if the
net force acting on an object remains constant. So the momentum of system is conserved. So
then internal forces acts on a system then mechanical energy does not change. If work done by
net internal force is zero then it is possible to conserve the mechanical energy.

Final Answer
The correct option is (4)

11)
12)
Collision - 1 : Firstly ball (B) collide with wall comes back and collide with back (A)
Now, collision between A & B.
Collision - 2 :

Same man → velocity exchange

After collision between two masses

Collision - 3 : After collision with wall

No more collision [2u and 3 collision]

13)

0 = 3x – (R + r) sin 30°

14) ;
mgl(1 – cos θ) = mgl'(1 – cos2θ)
l(1 – cos θ) = l' (1 – cos2θ)
l(2 sin2(θ/2)) = l' (2 sin2θ)
⇒ l sin2(θ/2) = l' sin2θ

= 2 ⇒ l = 4l'

15) Statement–1 is true only for rigid body translational motion.

16) Truth table for NAND gate

17)

18)

Correct answer is (D)

19) Conceptual

20)

21) Energy incident on cesium metal

=
Kmx = 3.1 – 1.9 = 1.2 eV
(kmx = maximum kinetic energy of photoelectron from the metal cesium)
So kinetic energy of photoelectron
0 ≤ k ≤ kmx.

So
[k] = [1.053] = 1

22) 20 gmn subotonic reduces to 10 gm in 4 min i.e. T1/2 = 4 min

 t = 8 min

23)

Correct answer is (2)

24)

0
f =
where, l is distance between point of suspension and centre of mass of the body. Thus, for the
stick of length L and mass m :

f =
when bottom half of the stick is cut off

0 0

f'= = f

25)
Taking torque about lower point
Iα = k(2aθ)2a + k(a + b)θ(a +b)
(9 + ma2)α = 800 θ + 3200 θ
α = 400 θ ⇒ ω = 20

PART-2 : CHEMISTRY

26) Benzaldehyde do not give test with Fehling solution

* NaHSO3 gives positive test with methyl ketone (not with Di ethyl ketone)
NaHCO3 give effervesce of CO2 with carboxylic acid

27)

P = CH3–C≡CH
Q=
R = CH3 – C ≡ C – CH3

S=

T=
U = CHI3

V=
W = CH ≡ CH

28)

The correct answer is option (B)

29) X = 3 (a, d, f are 1o amines give positive carbyl amine test)

Y = 3 (b, e, g are 2o amines give oily yellow coloured nitroso compounds on reaction with
aq.HNO2)
Z = 3 (a, d, f are 1o amines react with Hinsberg reagent (PhSO2Cl) and the product is soluble in
aq. KOH
X+Y+Z=9

30) Wolff-Kishner reduction is not suitable for base sensitive group.

31)

The correct answer is option (B)

32)

The correct answer is option (C)

33)
Lucas test is used to detect alcoholic functional group

34)

35) For NaCl 0 – t°C = 2 × Kf × 1

For mixture
NaCl(aq) + AgNO3(aq) → AgCl(s) + NaNO3(aq)
100 mmol 150 mmol
50 mmol 100 mmol

0 – x°C = Kf ×
– x°C = Kf × 2 = – t°C
x = t°C

36) Rate constant = mol–1/2 L1/2 min–1 ; Order = 3/2

37) E = w + 0.6
1.2 E = w + 0.9
w = 0.9 eV

38) Value of n is 4
4s : 3 radial node × 1 orbital = 3
4p : 2 radial node × 3 orbital = 6
4d : 1 radial node × 5 orbital = 5

39)

or wB = 6g.

40) Maximum boiling azeotrope can be obtained by -ve deviated solution.

41) Theoretical.

42) ΔTb = iKb × m

0.13 = 1 × 0.52 ×
Msolute = 50 g/mol

43) S2 and S3 are correct.

44) Theoretical.

45) The correct answer is option (D)

46)
Number of keto groups in product = 3
The number of carbon atoms in product = 9

47) 5th exited state ; n2 = 6 Balmer series n1 = 2

6 → 2, 5 → 2, 4 → 2, 3 → 2

48) AsH3(g) → As(s) + H2(g)

300 0
300–x 3x/2
Ptotal = 375 = 300 – x + 3x/2
x = 150
thus, t1/2 = 20 min
at t = 80 min
= 300/23 = 37.5
x = 300 – 37.5 = 262.5
Ptotal = 300 + 262.5/2 = 431.25 mmHg

0
49) PB = XB P B= YB × Ptotal
0
0.2 × P B= 0.6 × 0.6
0
P B= 1.8 atm = 1368 mmHg

50)

Question Asking About:

 compounds which give 2, 4 DNP test.

Key Concept: Ammonia derivative reaction with carbonyl compound.

Solution/Explanation/Calculation:
Aldehydes & ketones give red -orange ppt with 2, 4- DNP. 2, 4 DNP is known as bradys'
reegent.
It is used for reparation & identification of aldehydes & kitones from a mixture of unknown
organic compounds.
Methyl ketone can show Iodoform test.

PART-3 : MATHEMATICS

51)

f(x) = x3 – 9x2 + 24x

f '(x) = 3x2 – 18x + 24
= 3(x2 – 6x + 8)
= 3(x – 2)(x – 4)
f(2) = 20, f(4) = 16
for three distinct and real roots of the equation f(x) =
–k,
–k ∈ (16, 20) ⇒ K ∈ (–20, –16)
∴ no. of integral values of k is 3.

52) ⇒ f(t) =

53)

Statement-II is a consequence of Lagrange's mean value theorem. Now

f(x) = x3 + bx2 + cx + d
Differentiating this, we get
f '(x) = 3x2 + 2bx + c
 (∵ 0 < b2 < c)
Hence f is strictly increasing for all real x.

54)

∴ f(x) = 2x2

55)

n = kπ + a , k ∈ I , a ∈ R

56)

57)

x1 , x2 , x3 , x4 , x5 , x6 , x7 , x8 , x9 (let xi < xi + 1)
 median = 20.5
Now median will be 20.5 + 2 = 22.5

58)

2x = t ⇒ dx =

∴ Least value is = 16 (k = 0)

59)

n=3
∴ 9u3 = 7

n=4

n = 10

0
n=2 (u = π2)8

⇒ [16u2 – u] = 9

60)

= 1 + 4ℓn2 + 2 = 3 + 4ℓn2

61)

|z2 – 1 – 2i| ≤ |z|2 + | –1 – 2i|

for |z2 – 1 – 2i| to be maximum z2 and –1 – 2i must be collinear and lie on same of origin.
∴

62)

h(x) = f(x) f '(x)

h' = ff '' + (f ')2
h'' = ff ''' + f '' f ' + 2f ' f ''
h''' = ff '''' + f ''' f ' + f '' f '' + f ' f ''' + 2(f '
f ''' + (f '')2)
= 4f ' f ''' + 3(f '')2 + f f ''''
∴ min no. of roots of h(x) = 7
min no. of roots of h'(x) = 6
min no. of roots of h''(x) = 5
min no. of roots of h'''(x) = 4

63) , σ2 = 17

New

New

New

New variance =

64)

f(x) = 5x + 4
f(4) – f(3) = 5

65)

|z + 1| = 2|z|

⇒ circle with centre and radius ,

⇒ 'z' lies on a ray emanating from and making an angle from positive real axis, which
meets the at exactly one point.
∴ statement-I is false and statement-II is obviously true.
66)

x = tan4θ ⇒ dx = 4tan3θ sec2θdθ

67)

∀ x ∈ R ⇒ No point of inflection

68)

(Z5)26 – 1 = 0 ⇒ Z5 = (1)1/26 , Z5 = 1 (rejected)

Z5 = , m = 1, 2, .........25

for the largest root, Z5 = ,n=4

Z=
Z=e

∴
∴ p + q = 194

69)

α=4

70)

17(n1 + n2)2 = 9(n1 + n2) (2n1 + n2) + 9n1n2

 ⇒ (n1 + 4n2)(n1 – 2n2) = 0
∴ n1 = 2n2

71)

clearly no. of solutions are 3

72)

(2x – 2)2 = –3 ⇒ 4x2 – 8x + 7 = 0 = 4y2 – 8y + 7

Now,

73)

Clearly for to be minimum a + b = 4

74)
g(x) = e–x((x – 4)2 + 1) – 4x
g'(x) = e–x(2(x – 4) + ((x – 4)2 + 1) (–e–x) – 4
= e–x(–(x – 4)2 – 1 + 2(x – 4)) – 4
= –e–x(x – 5)2 – 4
g''(x) = –(e–x 2(x – 5) + (x – 5)2 (–e–x))
= + e–x((x – 5)2 – 2(x – 5))
= e–x(x – 5)(x – 7)
∴ t ∈ (5, 7)
⇒ Required sum = 6

75)

x1 + x2 + ..... + xn =

Mean of new data =

⇒ + 42 – 63(n + 1)2 = –1321(n + 1)

⇒ 63(n + 1)2 – 1321(n + 1) – 42 = 0
⇒ 63(n + 1)2 – 1323(n + 1) + 2(n + 1 – 4) = 0
⇒ 63(n + 1) (n + 1 – 21) – 2(n + 1 – 21) = 0
⇒ (63(n + 1) – 2) (n – 20) = 0
⇒ n = 20