19-12-2025

6001CJA10102225005ADV JA

PHYSICS

SECTION-I(i)

1) The energy of a system is given as E(t) = a3e–bt, where t is the time and b = 0.3 s–1. The errors in
the measurement of a and t are 1.2% and 1.6%, respectively. At t = 5 s, maximum percentage error
in the energy is :

(A) 4%
(B) 11.6%
(C) 6%
(D) 8.4%

2) Air flows with a velocity v. There is loosely fitted sheet on roof of total mass m and area A of each

sheet as shown in figure. (Assume ρ = density of air)

the minimum value of the speed v of the air flow so that sheet can be lifted off is
(A)

the minimum value of the speed v of the air flow so that sheet can be lifted off is
(B)

the minimum value of the speed v of the air flow so that sheet can be lifted off is
(C)

(D) None of these

3) A simple pendulum of mass 'm', length 'ℓ' and charge '+q' suspended in the electric field
produced by two conducting parallel plates as shown. The value of deflection of pendulum in
equilibrium position will be

(A)

(B)

(C)

(D)

4) A battery of emf E and internal resistance r is connected to a resistor of resistance r1 and Q joules
of heat is produced in r1 in a certain time t. When the same battery is connected to another resistor
of resistance r2, the same quantity of heat is produced in r2 in the same time t, the value of r is :

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) A liquid of density is filled in a cuboidal container of dimension as shown in the

figure. A semicircular gate is made at the bottom of container of radius . Let F is the force
acting on the gate due to the liquid and τ is the torque acting on the gate due to the liquid about a
line PQ. Then choose the correct option(s).

(A)

(B)

(C)

(D)

2) The capacitance of a parallel plate capacitor is C when the region between the plate has air. This
region is now filled with a dielectric slab of dielectric constant k. The capacitor is connected to a cell
of emf E, and the slab is taken out

(A) charge CE(k – 1) flows through the cell

(B) energy E2C(k – 1) is absorbed by the cell.
(C) the energy stored in the capacitor is reduced by E2C(k – 1)

(D)
the external agent has to do E2C(k – 1) amount of work to take the slab out.

3) Two identical moving coil galvanometer have 10 Ω resistance and full scale deflection at 2 µA
current. One of them is converted into a voltmeter of 100 mV full scale reading and the other into an
Ammeter of 1 mA full scale current using appropriate resistors. These are then used to measure the
voltage and current in the Ohm's law experiment with R = 1000 Ω resistor by using an ideal cell.
Which of the following statement(s) is/are correct?

(A) The measured value of R will be 978Ω < R < 982Ω.

(B) The resistance of the Voltmeter will be 100 kΩ.
(C) The resistance of the Ammeter will be 0.02Ω ( round off to 2nd decimal place)
If the ideal cell is replaced by a cell having internal resistance of 5Ω then the measured value
(D)
of R will be more than 1000 Ω.

SECTION-I(iii)

1) During space exploration, ISRO found a new planet similar to Earth. Experiments are conducted
by four astronauts using simple pendulum to measure the value of g on this new planet. The
observations are shown in table below.
 Length of number of
Astronaut Total Time (sec)
pendulum (cm) oscillations (n)

(1) 10 12 40

(2) 20 5 60

(3) 5 10 30

(4) 10 8 20

Least count of length is 0.1 cm and least count of time is also 0.1 sec. List-I given about
four astronauts and List-II gives fractional error in the measurement of g.

List-I List-II

(P) Astronaut-1 (1)

(Q) Astronaut-2 (2)

(R) Astronaut-3 (3)

(S) Astronaut-4 (4)

(A) P → 1;Q → 3;R → 2;S → 4

(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 1;Q → 2;R → 3;S → 4

2) List-I contains some systems having a solid body and fluid. List-II contains some physical
quantities for the systems in List-I. Match List-II with List-I.

List-I List-II
Atmospheric pressure = P0
A solid sphere of radius R is tied
inside a non-viscous liquid and Fx (on surface x applied
the system is in equilibrium
by liquid)
(I) (sphere just touching the top (P)
surface of the liquid). Here x-
= P πR2 + πR3ρg
0
Density of
upper half spherical surface and
liquid = ρ
y-lower half spherical surface.
Density of solid = σ(σ ≠ ρ)
Atmospheric pressure = P0 A solid disc of radius R,
thickness R/3 is tied inside a
non-viscous liquid and the Fy (Force on surface y
system is in equilibrium. Here x applied by liquid)
(II) (Q)
is rim of the disc and y is one of
Density of the flat faces of disc. The upper = P πR2 + πR3ρg
0

liquid = ρ point of disc is 2R/3 below liquid

Density of solid = σ(σ ≠ ρ) surface.
 Atmospheric pressure = P0
A solid sphere of radius R is
moving upward with a terminal
velocity vt inside a viscous liquid
Force of buoyancy on
and the beaker is at rest. Here x
sphere or disc (FB) –
(III) is surface of the beaker base (R)
weight of sphere or disc
just below the sphere shadow
(W) ; is certainly positive
and y is remaining surface of the
beaker base. Total height of
Density of liquid = ρ liquid is 5R/3.
Density of solid = σ(σ ≠ ρ)
Atmospheric pressure = P0
A solid disc of radius 2R and
height 4R/3 is placed inside a
liquid, whose lower part is
partially open to atmosphere
and the disc is in equilibrium.
(IV) (S) σ < ρ (necessarily)
Here x is top surface of the disc
and y is bottom surface of the
disc which is in contact with
liquid. Height of liquid surface
Density of liquid = ρ from the bottom of disc is 5R/3.
Density of solid = σ(σ ≠ ρ)
(T) σ > ρ (necessarily)

(A) I → Q;II → R,S;III → Q,T;IV → P,Q,R,S

(B) I → R,S;II → Q;III → P,Q,R,S;IV → Q,T
(C) I → Q,T;II → P,Q,R,S;III → Q;IV → R,S
(D) I → P,Q,R,S;II → Q,T;III → R,S;IV → Q,T

3) Consider the situation shown in diagram. Both capacitors are having same capacitance C.
Capacitors are initially uncharged. Switch K is closed at time = 0 & after a long time capacitors are
fully charged. Column-I represents value of r and Column-II represents charge passing through r

during complete charging process. Now match the followings :

(A) A → S;B → R;C → Q;D → P
(B) A → P;B → Q;C → R;D → S
(C) A → R;B → S;C → P;D → Q
(D) A → Q;B → P;C → R;D → S

4) Three metallic bars 1, 2, 3 are arranged as shown in figure, with total number of free charge
carriers in ratio N1 : N2 : N3 = 1 : 3 : 2; resistivity ratio ρ1: ρ2 : ρ3 = 2 : 1 : 3; lengths in ratio ℓ1 : ℓ2 : ℓ3
≡ 2 : 2 : 3 for 1, 2, and 3 bars respectively (radius of cross-section shown in figure), carry current i
as shown, then match the columns.

Column-I Column-II

If P1, P2 and P3 are power dissipiated across AB, BC, and CD respectively
(A) (P)
then

If E1, E2 and E3 are magnitude of Electric-fields across AB, BC and

(B) (Q)
CD respectively then

If are drift speeds in bar AB, BC and CD respectively then

(C) (R)

If V1,V2, V3 are potential differences across AB, BC and CD respectively

(D) (S) < 1
then

(T)

(A) A → Q,S;B → P;C → R,S;D → Q,S

(B) A → Q,S;B → R;C → P;D → Q
(C) A → P,Q;B → R,S;C → Q,S;D → R,S
(D) A → S;B → Q,S;C → P,Q;D → R

SECTION-II

1)

Intensity observed in an interference pattern is I = I0 sin2θ. At θ = 30°, intensity I = 5 ± 0.0020

W/m2. If I0 = 20 W/m2 and percentage error in angle θ is , then the value of n is.

2)

The main scale of a vernier callipers reads in millimeter and its vernier is divided into 10 divisions
which coincides with 9 divisions of the main scale. The reading for shown situation is found to be

mm. Find the value of x.

3) A bubble is placed at the fluid with a coefficient of surface tension σ = 5.0 × 10–2 N/m. A cross-
section of the bubble through its vertical axis is shown at the picture below. What is depth h (in
multiple of 10–4 m) of the lowest point B of the gas inside the bubble relatively to free water level, if
radii of curvatures at the top and bottom points are RT = 2.0 cm and RB = 5.0 cm respectively? For
calculations use density of water as ρ = 1000 kg/m3 and acceleration due to gravity as g = 10 m/s2

4) A capacitor of 10 μF capacitance whose plates are separated by 10 mm through air and each plate
has area 4 cm2 is now filled equally with two dielectric media of K1 = 2, K2 = 3 respectively as shown
in figure. If new force between the plates is 8 N. The supply voltage is _____ V.

5) In the show circuit, all cells are ideal. If current in branch BE is x ampere and current in branch
AE is y ampere then value of x + y (in ampere) is

6) A conducting sphere with inner radius R and outer radius 3R has some alloys mixed in it due to
which its resistivity changes with radial distance r according to the function ρr = Kr, where K is a
+ve constant. Inner surface of the sphere is grounded while outer surface of sphere in maintained at
potential V0 with the help of a battery of emf V0. Battery is ideal. The potential of the sphere at radial

distance of 2R is . Find (a + b).

CHEMISTRY

SECTION-I(i)

1) The valence shell of the element X contains 2 electrons in a 5s subshell. Below that shell element
X has a partially filled 4d subshell. What type of element X is ?

(A) Alkali metal

(B) Alkaline earth metal
(C) Chalcogen
(D) d-Block element

2) The product formed when I– reacts with alkaline KMnO4 is :

(A) I2
–
(B) IO3
(C) IO–
–
(D) IO4

3) what is X and Y?
(A) Methanol, Methanal
(B) Ethanol, Ethanal
(C) Acetyl chloride, Acetone
(D) Ethane, Chloro ethane

4) Product P3 in following reaction sequence :

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Identify correct statements

(A)
(Exothermic)

(B)
(Endothermic)

(C)
(Endothermic)

(D)
(Exothermic)

2) Which can not be cleaved by HIO4?

(A)

(B)
(C)

(D)

3) Which of the following reactions proceeds with inversion of configuration ?

(A)

(B)

(C)

(D)

SECTION-I(iii)

1) LIST-I contains compounds and LIST-II contains reaction

LIST-I LIST-II

(I) H2O2 (P) Mg(HCO3)2 + Ca(OH)2 →

(II) Mg(OH)2 (Q) BaO2 + H2SO4 →

(III) BaCl2 (R) Ca(OH)2 + MgCl2 →

(IV) CaCO3 (S) BaO2 + HCl →

(T) Ca(HCO3)2 + Ca(OH)2 →

Match each compound in LIST-I with its formation reaction(s) in LIST-II, and choose the
correct option
(A) I → Q;II → R;III → S;IV → T
(B) I → T;II → P;III → Q;IV → R
(C) I → T;II → R;III → Q;IV → P
(D) I → S;II → Q;III → R;IV → P

2) Answer the following by appropriately matching the lists based on the information given
in the paragraph
List-I includes starting materials and reagents of selected chemical reactions. List-II gives structures
of compounds that may be formed as intermediate products and/or final products from the reactions
of List-I

List-I List-II

(P) (1)

(Q) (2)

(R) (3)

(S) (4)

(5)

(6)

Which of the following options has correct combination considering List-I and List-II?
(A) R → 4;S → 3
(B) S → 2;T → 3
(C) R → 5;S → 6
(D) S → 2;T → 6

3) The major products obtained from the reactions in List-II are the reactants for the named
reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in List-II and
choose the correct options.

List-I List-II

(P) Stephen reaction (1)

(Q) Sandmeyer reaction (2)

(R) Hoffmann bromamide degradation reaction (3)

(S) Cannizzaro reaction (4)

(5)

(A) P → 2;Q → 4;R → 1;S → 3

(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 5;Q → 3;R → 4;S → 2
(D) P → 5;Q → 4;R → 2;S → 1

4) Answer the following by appropriately matching the lists based on the information given
in the paragraph.
1° alcohol on oxidation by mild oxidising agent produces aldehyde while with strong oxidising agent
carboxylic acid is obtained. On the other hand 2° alcohol with mild oxidising agent gives ketone. 3°
alcohol is reluctant to oxidation by mild oxidising agents.

List-I (Reaction) List-II (Reagents)

(I) (P) PCC, CH2Cl2

+
(II) (Q) KMnO4 / H

(III) (R) Collin's Reagent

(IV) (S) Cu/300°C

 (T) TsCl + DMSO + NaHCO3

(U) MnO2, Δ
Correctly matched away the following is :
(A) II → P
(B) II → Q
(C) II → S
(D) II → U

SECTION-II

1) Consider the following order :-

(1) C2H6 < C2H4 < C2H2 : E.N. of central atom C
(2) Mg2⊕ < K⊕ < S2⊝ < Se2⊝ : Ionic radius

(3) : Ionic mobility

(4) Be2⊕ > Li⊕ > Al3⊕ : Hydrated size
(5) Be > Li > Cs : Reducing power
(6) : Electrical conductance in infinite dilute solution
Then calculate value of |x – y|2, where x and y are correct and incorrect orders respectively :-

2) Out of the following compounds given below, the number of compounds which given positive
iodoform test are :
I. CH3CHO II. CH3COCH3 III. C2H5COC2H5 IV. PhCOC2H5

V. VI. PhCOCH2COPh VII. VIII. PhCOCH3

IX. CH3COC2H5 X.

3) . The number of chiral carbons in A is x, in B is y and in

C is z the x + y + z is _____

4) Find out number of reactions those proceed with retention of configuration

(A) (B)

(C) (D)

(E)

(F) (G)

(H)

5) How many reaction are correct with major product?

(1)

(2) CH3CH2O⊖ + CH3–CH2–Br

(3)

(4)

(5)

(6)

6)
For alkali metal M :
M2O + H2O → x
M2O2 + H2O → x + y
MO2 + H2O → x + y + z
Sum of the number of atoms present in one molecule each of x, y, z.

MATHEMATICS

SECTION-I(i)

1) Let ƒ(x) = min(2x, sgn(|x|), |x – 3|), then identify the INCORRECT statement (sgn(.) denotes
signum function) -

(A) ƒ(x) is non derivable at exactly four points in its domain.

(B) ƒ(x) is discontinuous at exactly one point in its domain.
(C) ƒ(x) is increasing for all x ∈ (1, ∞)
(D) ƒ(x) is increasing for all x ∈ (–∞, 0).

2) The shortest distance between the point and the curve is :

(A)

(B)

(C)

(D)

3) Let f (x) = . Then

(A) 2
(B) –2
(C) –1
(D) 1

4) Let a = min {x2 + 2x + 3, x∈R} and b = then value of is

equal to:

(A) 200
(B)

(C) 100
(D) 2100 –1

SECTION-I(ii)

1) On which of the following intervals, the function f(x)= x100 + sin x – 1 is strictly increasing.

(A) (–1, 1)
(B) (0, 1)

(C)

(D)

2) If g is inverse of ƒ and ƒ (x) = x2 + 3x – 3 (x > 0) then g'(1) equals-

(A)

(B) –1

(C)

(D)

3) Identify the true statement(s) -

(A)
= 1, where [.] denotes the greatest integer function.
(B) If f(x) = (x – 1) {x}, then limit of f(x) does not exist at all integers.

(C)
= 1, where [.] denotes the greatest integer function.

(D)
= 1, where [.] denotes the greatest integer function.

SECTION-I(iii)

1)

List-I List-II

(P) Number of points of local maxima of the function ƒ (x) = x2 + 4cosx + 5 is (1) 4

Integral value of 'k' for which ƒ '(x) = 0 where

(Q) 2 (2) 2
ƒ(x) = (k – 5k + 6) tanx + (3k –6)x
 Length of subtangent drawn to function
(R) (3) 3
ƒ(x) = 7sinx + tan at point is

If ƒ (x) = 2|x|3 + 3x2 – 12|x| + 3, where

(S) (4) 1
x ∈ [–1, 1], then greatest value of ƒ (x) is

(5) 0
(A) P → 4;Q → 2,3;R → 1,2,3;S → 3,5
(B) P → 2;Q → 2,4,5;R → 1,3;S → 3,4
(C) P → 4,5;Q → 1,2,3;R → 1,2;S → 2,3
(D) P → 4;Q → 2,4,5;R → 1;S → 3

2) Let , if M, m, q denotes number of local maximum points, number

of local minimum points and number of non differential points of ƒ(x) respectively. P denotes number
of solutions of equation πƒ(x) = 1.
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) Value of M is (1) 0

(Q) Value of m is (2) 1

(R) Value of P is (3) 2

(S) Value of q is (4) 3

(A) P → 4;Q → 1;R → 3;S → 3
(B) P → 3;Q → 2;R → 3;S → 2
(C) P → 2;Q → 1;R → 4;S → 2
(D) P → 3;Q → 2;R → 4;S → 3

3) Answer the following by appropriately matching the lists based on the information given in the
list.

List-I List-II

If f(x) = sgn (sin2x – sin x – 1) has exactly 4 points

(P) (1) 0
of discontinuity for x ∈ (0, nπ) n ∈ N then n can be

Let f(x) = x2 – x + k – 2 and g(x) = x2 – x + 1. If the

complete set of values of k for which y = (where [.]

(Q) (2) 4
denotes greatest integer function) is continuous ∀ x ∈ R is

[a, b) then equals

 (R) Let . Then the number (3) 5
of real points in the domain of f(x) where it is non-
differentiable is

Number of points where

(S) (4) 3
is non-
differentiable is

(5) 2
Correctly match among the following is :
(A) P → 2,3;Q → 1;R → 4;S → 1
(B) P → 2,3;Q → 1;R → 3;S → 4
(C) P → 3;Q → 2;R → 3;S → 4
(D) P → 3;Q → 2;R → 4;S → 1

4)

Column-I Column-II

Let ƒ(x) = ex + x. Let (c, ƒ(c)) is a point where the tangent is parallel to line
(P) joining the points (0,ƒ(0)) and (2,ƒ(2)). Then [ec] is less than (where [.] (1) 0
represents greatest integer function)

Let a sphere is kept inside a cube in such a way that it always touches all
the faces of cube. When the rate of change of side of cube is 2 cm/sec and
(Q) (2) 1
the side of cube is 2 cm then the rate of change of sum of their volumes
is greater than

–1 3
(R) Let ƒ(x) = tan x + x where , then number of integers lying in (3) 2
the range of ƒ(x) is/are

Let ƒ'(x) = (x + 1)(x – 1)(x – 2)(x – 3)2(x – 4) (x – 5), then number of points of
(S) (4) 3
local maxima is greater than

(5) 5
(A) P → 4;Q → 1,2,3,4,5;R → 1,2;S → 5
(B) P → 5;Q → 1,2,3,4,5;R → 5;S → 1,2
(C) P → 3;Q → 1,2,3,4;R → 5;S → 1
(D) P → 2;Q → 1,3,4,5;R → 1;S → 3

SECTION-II

1) A bus contractor agrees to run special buses for the employees of ABC Co. Ltd. He agrees to run
the buses if atleast 200 persons travel by his buses. The fare per person is to be Rs. 10 per day if 200
travel and will be decreased for everybody by 2 paise per person over 200 that travels. How many
passengers will give the contractor maximum daily revenue?
2) Let f be a twice differentiable function with f(–1) = 1 = f(1) and f(0) = 0. then the minimum
number of roots of equation f(x)(f′(x))3 + (f(x))2 f′(x) f′′(x) – f(x) f′(x) = x(f′(x))2 + x f(x) f′′(x)– x is

3) Given and , then the digit at the unit's place of

is

4) Let for all real x and y. If f'(0) exists and equals – 1 and f(0) = 1, find |f(2)|

5) Let ƒ be a derivable function and ƒ'(x) is continuous with ƒ'(2) = 14, then value of is L, where

absolute value of difference of digits of L is

6) Number of points where the function is non-

differentiable, is
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. C A C D

SECTION-I(ii)

Q. 5 6 7
A. B,C A,B,D A,C

SECTION-I(iii)

Q. 8 9 10 11
A. D D A A

SECTION-II

Q. 12 13 14 15 16 17
A. 4 3 8 80 1 5

CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21
A. D B B B

SECTION-I(ii)

Q. 22 23 24
A. A,B,D A,D B,C,D

SECTION-I(iii)

Q. 25 26 27 28
A. A B B D

SECTION-II

Q. 29 30 31 32 33 34
A. 4 7 4 3 5 9

MATHEMATICS
 SECTION-I(i)

Q. 35 36 37 38
A. C A B C

SECTION-I(ii)

Q. 39 40 41
A. B,C,D A,C C,D

SECTION-I(iii)

Q. 42 43 44 45
A. D D B B

SECTION-II

Q. 46 47 48 49 50 51
A. 350 5 7 1 6 3
 SOLUTIONS

PHYSICS

1) α3e–βt
ln E = 3 ln α – βt

=
= 3 × 1.2% + (0.3 × 1.6 × 5)%
= 6%

2) , where F = (ΔP)A;

by Bernoulli’s equation.

3) Explain the Question : We have given R-C circuit and we have to choose correct option(s)
if switch is closed at t = 0.
Concept : This question is based on RC circuit.
Solution :

Let E be electric field in air

T sinθ = qE
T cosθ = mg

tanθ =
Now,

Final Answer : 3

4)

5)

dF = pdA =

F=

6)

Explanation the question :

We have to determine the charge flown and energy absorbed by the cell, and work done by
external agent to take the slab out of the capacitor, connected to a cell of EMF E.

Concept: This question is based on Dielectric slab with capacitor

Solution:
Capacitance : C' = KC
Charge on capacitor : Q' = C'E = KCE
Capacitance : C
Charge on capacitor : Q = CE
Q < Q'
(a) charge flown through cell = Q' – Q = (K – 1)CE
(b) work done on cell = ΔQE = (Q' – Q) E = (K – 1)CE2
(c) change in stored energy

Final Answer: The correct option is (1), (2) and (4).

7)
0.1 = 2 × 10–6 (10 + RV)
∴ RV = 49990 Ω

2 × 10–6 × 10 = 10–3 RA
y 50000 = (x – y) 1000
∴ 51y = x

Reading = ≈980

8)

Question Explanation: Calculate the fractional error in 'g' for four different experiments
using a simple pendulum.
Concept: Error propagation in simple pendulum

Solution: The time period of a simple pendulum is given by Rearranging this

gives .
The fractional error in g is the sum of the fractional error in length and twice the fractional
error in the time period. The fractional error in time period is the fractional error in total time,
which is the least count of the stopwatch divided by the total time measured.

Calculation:

T= ⇒g=
 Final Answer: (P) Astronaut-1 matches (1) 3/200​. (Q) Astronaut-2 matches (2) 1/120​. (R)
Astronaut-3 matches (3) 2/75​. (S) Astronaut-4 matches (4) 1/50​.

9)

(I) From free body diagram of the liquid above the sphere, Fx = P πR2 + πR2ρg
0

Force of buoyancy on the sphere = πR3ρg

So, Fy = P πR2 + πR3ρg

0

(II)
Force of buoyancy on the disc Fx = πR2ρg

Fy = P πR2 + πR2ρg
0

(III) From the free body diagram of the liquid in the container Fx and Fy are different with option
(p) and (q)
(IV)

Force on the part open to atmosphere = P03πR2

So, (N = normal reaction)

10)

= 2 CV Now Let = q and

Now applying loop rule 2I1 R = rx + R ( I–I1)

3I1 = x+I
3 q1 = q + 2CV (i)

Also (I1+x) dt = CV
∴ q1 + q = CV (ii)
After solving

(A)

(B)

(C)

(D)

11) R1 = 2ρ ⋅

R2 = ρ ⋅

R3 = 3ρ ⋅

E = ρJ

J = nevd =

E=

E1 =

E2 =

E3 =

Similarly value of

12)
 Question Explanation: Determine the value of n from a given percentage error in angle θ for
an interference pattern. Concept: Error propagation

Solution: The intensity is given by I=I0​sin2(2θ). The fractional error in angle θ is related to the
fractional error in intensity. We need to find the derivative of I with respect to θ and then
relate the fractional errors.

Final Answer: N/A.

13)

Least count = mm; Zero error

= –(10–6) × 0.1 = – 0.4 mm;
Reading = 6 + 5 × (0.1) – (–0.4) = 6.9 mm

14)

⇒h=

= 10–5 [80] = 8 × 10–4 m

15) NTA Ans. (80)

Allen Ans. (Bonus)

Ceq = C1 + C2

Ceq = 25 μF
Now the charge on C1 = 10V μc
C2 = 1.5 V μC.

Now force between the plates

325 V2 = 8 × 4 × 10–4 × 8.85

V2 =

∴
 16) Since A and B are same potential we can redraw the circuit as

Hence current through 8Ω is 1A and

17) V0 = I Req

CHEMISTRY

18) Explain question : To identify the element on the basis of given electronic configuration.
Concept : Classification of element on the basis of their block

Solution :
Final answer : The correct option is (4)

19) + I– + H2O → 2MnO2 + + 2OH–

20) Question Explanation: To identify product X and Y.

 Concept: Reduction by LiAlH4 and oxidation of alcohols.

Solution: CH3 – COOH CH3 – CH2 – OH CH3 – CH = O

Ethanol Ethanal

Final answer: The correct option is (2).

21)

Explanation Question: Question is asking about product of given sequence of reaction.

Concept: This question is based on multiple concept like allylic substitution, preparation of
Grignard reagent, Nucleophilic addition reaction and dehydration of alcohol.
Solution:

The correct option is (2)

22) (1)
(2)
Formation of poly valent anion endothermic.

(3)
(4) |EA of F| > |IP of I|

23) Question Explanation:

To find out the compound cannot be cleaved by periodic acid (HIO4), an oxidizing agent that
cleaves vicinal (1,2-) diols and similar linkages.

Concept:
This question is based on Periodic acid oxidation, glycol cleavage, vicinal diols requirement.

Solution:
Periodic acid (HIO4) cleaves compounds having –CHOH–CHOH–, –CHOH–CO–, or –CO–CO–
linkages — i.e., adjacent carbons each bearing oxygen-containing groups.
If the oxygen atoms are not on adjacent carbons (e.g., separated by a –CH₂– group), no
cleavage occurs.
So, Vicinal diol, α – hydroxy carbohyl, α, β– dicarbonyl are cleaved by HIO4.

Final Answer: The correct options are (1) & (4).

24)

25) Explain Question: Match list I with list II

Concept: Acid -base reaction of inorganic compounds
Solution:
(P) Mg(HCO3)2 + 2Ca(OH)2 → Mg(OH)2 + 2CaCO3 + 2H2O
(Q) BaO2 + H2SO4 → H2O2 + BaSO4
(R) Ca(OH)2 + MgCl2 → Mg(OH)2 + CaCl2
(S) BaO2 + 2HCl → BaCl2 + H2O2
(T) Ca(HCO3)2 + Ca(OH)2 → 2CaCO3 + 2H2O
Final Answer: option (1)
26)

R, 5, 2, 3

S, 2, 3

27)

28) MnO2 oxidises only allylic or benzylic –OH 1° on oxidises to Aldehyde.

29) Question Explanation: Select the correct & incorrect statement and get value of |x – y|2.

Concept: General trends in s-block.

Solution: Correct statement = 1 and 2

Incorrect statement = 3, 4, 5 and 6.
[|2 – 4|]2 = 22 = 4

Final Answer: 4

30)

Seven compounds (I, II, VI, VII, VIII, IX and X)

Methyl ketone or aldehyde (I, II, VIII and IX) and 1, 3-dikentone or cyclic 1, 3-didetone (VI and
VII) gives iodoform test.

31)

32) (A) Same retention

(B) SN2 Inversion

(C) Darzen reaction retension of configurations

(D)

(E) Inversion will takes place

 (F) Inversion will takes place

(G) Retension

(H)
In ACD (3) retension takes place

33)

1,2,4,5,6

34)

(x = 3, y = 4, z = 2)
x = MOH; y = H2O2 ; z = O2

MATHEMATICS

35) Graph of ƒ(x)

36) Let points , (t2, t), t > 0

Distance =

= =

So minimum distance is
37) f(x)
= cos x(x2 – 2x2) – x(2sinx – 2x tan x) + 2x sin x – x2 tan x
= –x2 cos x – 2x sin x + 2x2 tan x + 2x sin x – x2 tan x
f(x) = –x2 cosx + x2 tan x = x2 (tan x – cos x)
f′(x) = x2 (sec2 x + sin x) + (tan x – cos x)2x
Required value

x(sec2 x + sin x) + 2(tan x – cos x)

=–2

38) a = 2

ab = 1

39) f'(x) = 100 x99 + cosx

for x ∈(0, 1) and , cosx and x are both +ve ⇒↑

for , x > 1 hence 100 x99 obviously > cosx ⇒↑

40) f(g(x)) = x
f′(g(x)) . g′(x) = 1
f(x) = x2 + 3x – 3
f′(x) = 2x + 3
f′(g(x)) = 2g(x) + 3
f′(g(1)) = 2g(1) + 3

g′(1)
g(1) = f–1(1) = 1

g′(1)

Final Answer: option (1) & (3)

41) (A) So,

(B) f(x) = (x – 1) {x} check → Limit exists for all integers except x = 1

(C) for So,

(D)

42) (P) ƒ '(x) = 2x – 4sinx = 2(x – 2 sinx) =0

⇒ 2sinx = x

⇒ x = x1, x2 are points of minimas

and x = 0 is point of maxima
(Q) ƒ '(x) = (k – 2) (k – 3) sec2x + 3 (k – 2)
for critical point ƒ '(x) = 0
⇒ (k – 3) sec2x + 3 = 0

for real point

⇒
⇒ 0<k<3

(R) ƒ '(x) = y' = 7cosx +

Length of sub-tangent = unit

3 2
(S) ƒ (t) = 2t + 3t – 12t + 3 (t = |x| ∈ [0, 1])
ƒ '(t) = 6t2 + 6t – 12 = 6(t + 2)
(t – 1) ≤ 0 ∀ t ∈ [0, 1]
ƒ (t) is decreasing function so maximum value is ƒ (0) = 3

43)
M = 2, m = 1, p = 3, q = 2
(x = 1,3) (x = 2) (x = 1,2)
44) (P) f(x) = sgn (sin2x–sin x–1) sin2x–sin x–1 = 0

⇒ sin x =

⇒ sin x =
f(x) will be discontinuous when

sin x =

⇒ x ∈ (0, 4π] or x ∈ (0, 5π]

(Q) y =

y=

y=

y=1+
for y to be continuous in R

0≤k–3< ⇒ k∈

⇒ a = 3, b =

(R) f(x) =

f(x) =
cos–1 x is non differentiable at x = –1, 1.

f(x) is non-differentiable at x = –1, , 0, , 1.

(S) max [|x2 – x – 2|, x2 – 3x]

max (ln(–x), ex)

y = f(x)

From the above graph of y = f(x) we can see that f(x) is non differentiable at 3 points.

45) (A)

(B) a = 2r

(C) ƒ′
is an increasing function

(D)
number of point of local maxima are two.

46) Let the number of passengers be x ( x ≥ 200)

Fair changed per person = 10 – (x – 200)

Total revenue

= x.

f (x) = 14x –

f ′(x) = 14 – =0
⇒ x = 350
f ′′(x) < 0 ⇒ x = 350 gives maxima

47) Given expression is

(f(x) f′(x) – x) ((f′(x))2 + f(x) f′′(x) – 1) = 0
consider g(x) = f2(x) – x2
since g(x) = 0 has 3 real roots
⇒ g′(x) = 0 must have minimum 2 real roots
and g′′(x) = 0 must have minimum 1 real root

48)

Given ƒ(x) =

∴ ƒ(x) =

⇒ ƒ'(x) =

⇒
⇒
∴ (1 + |α - β|)2015 = (1 + 2)2015 = 32015
⇒ unit digit = 7

49) putting y = 0

2f = f(x) + 1
⇒ 2f(x) = f(2x) + 1

f'(x) = =

= =

= =
= f′(0)
f(x) = f′(0) × x + c
f(0) = 1
1=c
⇒ f(x) = f′(0) × x + 1
f(2) = 2f′(0) + 1
f(2) = –2 + 1
f(2) = –1
|f(2)| = 1

Final Answer: 1

50)
51)
∴ max (|x2 – x – 2|, x2 – 3x) = |x2 – x – 2|

∴ Graph of f(x)

Clearly 3 non-differentiable points