20-12-2024

4001CJA101021240110 JA

PART-1 : PHYSICS

SECTION-I

1) I1 and I2 are diametric axis and I3 is axis perpendicular to plane of disc and passing through centre

of disc having mass m and radius R, I1 + I2 + I3 will be :

(A) mR2

(B)

(C)

(D) 2mR2

2) The moment of inertia of a uniform rod of mass M and length L about an axis passing through its
centre and inclined to it at an angle θ = 60° is

(A)

(B)

(C)

(D)

3) A uniform straight wire is bended into arc as shown in figure. Radius of Arc is 1 meter as shown
in figure. Length and mass of wire are 60cm and 2kg respectively. Find moment of inertia of bended
wire about an axis passing through O and perpendicular to plane of arc.

(A) 2 kg-m2
(B) 1 kg-m2

(C)
kg-m2
(D) Can't determine

4) For the wheel-and-axle system shown, which of the following expresses the condition required for

the system to be in static equilibrium?

(A) m1 = m2
(B) am1 = bm2
(C) am2 = bm1
2 2
(D) a m1 = b m2

5) A rigid body can be hinged about any point on the x-axis. When it is hinged such that the hinge is
at x, the moment of inertia is given by I = 2x2 - 12x + 27. The x-coordinate of centre of mass is :-

(A) x = 2
(B) x = 0
(C) x = 1
(D) x = 3

6) Let be the force acting on a particle having position vector . Let be the torque of this force
about the origin, then

(A) and
(B) and
(C) and
(D) and

7) A ray of light passes through four transparent media with refractive indices μ1, μ2, μ3 and μ4 as
shown in the figure. The surface of all media are parallel. If the emergent ray CD is parallel to the

incident ray AB, we must have

(A) μ1 = μ2
(B) μ2 = μ3
(C) μ3 = μ4
(D) μ4 = μ1

8) A uniform disc of mass m0 rotates freely about a fixed horizontal axis passing through its centre.
A thin cotton pad is fixed to its rim, which can absorb water. The mass of water dripping onto the
pad per unit time is μ. After what time will the angular velocity of the disc get reduced to half of its

initial value ?

(A)

(B)

(C)

(D)

9) If for a rigid body, where = resultant torque & = angular momentum about a point
and both are non-zero. Then :

(A) = constant
(B) | | = constant
(C) | | will increase
(D) | | may increase

10)

A uniform rod of length ℓ is placed on a frictionless horizontal surface and a horizontal force F is
applied on it at a distance x from its centre. The acceleration of centre

(A) is maximum for x = 0

(B) is maximum of x = ℓ/2
(C) is maximum for x =ℓ/4
(D) is independent of x

11) A disc of the radius R is confined to roll without slipping at A and B. If the plates have the

velocities v and 2v as shown, the angular velocity of the disc is

(A)
Anticlockwise

(B)
Clockwise

(C)
Anticlockwise

(D)
Clockwise

12) A wheel of radius R with an axle of radius is shown in the figure and is free to rotate about a
frictionless axis through its centre and perpendicular to the page. Three forces (F, F, 2F) are exerted
tangentially to the respective rims as shown in the figure. The magnitude of the net torque acting on

the system is nearly :-

(A) 3.5 FR
(B) 3.2 FR
(C) 2.5 FR
(D) 1.5 FR

13) A rod of mass m = 5kg and length L = 1.5m is held vertical on a table as shown. A gentle push is
given to it and it starts falling. Friction is large enough to prevent end A from slipping on the table.
When it rotates through an angle θ = 37°, the angular velocity of the rod will be :
(A)
rad/sec
(B) 2 rad/sec

(C)
rad/sec
(D) 3 rad/sec

14) A uniform cube of side a and mass m rests on a rough horizontal table. A horizontal force F is
applied normal to one of the faces at a point directly above the centre of the face, at a
height above the base. What is the minimum value of F for which the cube begins to tip about an

edge?

(A)

(B)

(C)

(D)

15) White light is incident on the interface of glass and air as shown in the figure. If green light is

just totally internally reflected then the emerging ray in air contains

(A) Yellow, orange, red

(B) Violet, indigo, blue
(C) All colours
(D) All colours except green

16) A disc moves as shown in the figure, with a velocity of translation of 6v0 of its centre of mass and
an angular velocity of . The distance of instantaneous axis of rotation from its centre of mass is

(A) R
(B) 2R
(C) 3R
(D) 4R

17) The plot of deviation (δ) v/s angle of incidence (i) for a prism is as shown in figure. Find the

angle of the prism (A).

(A) 64°
(B) 32°
(C) 16°
(D) 18°

18) An object placed 10 cm in front of a lens has an image 20 cm behind the lens. What is the power
of the lens(in dioptres):-

(A) 1.5
(B) 3.0
(C) –15.0
(D) +15.0

19) A thin uniform straight rod of mass 2 kg and length 1m is free to rotate about its upper end.
When at rest, it receives an impulsive blow of 10 Ns at its lowest point, normal to its length as shown

in figure. The kinetic energy of rod just after impact is

(A) 75 J
(B) 100 J
(C) 200 J
(D) none of these

20) A luminous point object is moving along the principal axis of a concave mirror of focal length 12
cm towards it. When its distance from the mirror is 20 cm its velocity is 4 cm/s. The velocity of the
image in cm/s at that instant is

(A) 6, towards the mirror

(B) 6, away from the mirror
(C) 9, away from the mirror
(D) 9, towards the mirror

SECTION-II

1) Time taken by the sunlight to pass through a slab of 4 cm and refractive index 1.5 is x × 10–10. The
value of x is :

2) A concave mirror of focal length 15 cm forms an image having twice the linear dimensions of the

object. The position of the object when the image is virtual will be cm. Find x.

3) A and B are thin lenses. 1, 2 and 3 are representative wave fronts of incident and refracted
monochromatic light with distances from the lenses as shown. The radii of curvature of wave fronts
2 and 3 are 4m and 7m respectively. Find the focal length (modulus value) of lens B in meter.

4) A prism of refractive index n1 and another prism of refractive index n2 are stuck together (as
shown in the figure). n1 and n2 depend on λ, the wavelength of light, according to the relation

The wavelength for which rays incident at any

angle on the interface BC pass through without bending at that interface will be _______ nm
5) Cross-section view of a prism is the equilateral triangle ABC shown in the figure. The minimum
deviation is observed using this prism when the angle of incidence is equal to the prism angle. The
time taken by light to travel from P (mid point of BC) to A is _______ × 10–10 s. (Given, speed of light in

vacuum = 3 × 108 m/s and cos 30° = .

PART-2 : CHEMISTRY

SECTION-I

1) (NH4)2CO3(s) 2NH3(g) + CO2(g) + H2O(g)

The value of Kp for above equilibrium is 64 atm4. The equilibrium pressure of the system is (consider
initially only (NH4)2CO3 is present in container)

(A) 4 atm
(B) 8 atm
(C) 2 atm
(D) 6 atm

2)

In a reaction
A2(g) + 4B2(g) 2AB4(g) ; ΔH < 0

the formation of AB4(g) will be favoured by :-

(A) Low temperature and high pressure
(B) High temperature and low pressure
(C) Low temperature and low pressure
(D) High temperature and high pressure

3) The vapour density of undecomposed N2O4 is 46. On heating N2O4(g) in a closed container, vapour
density decreases to 24.5 due to dissociation. The % dissociation of N2O4 at the equilibrium is :-

(A) 87.7
(B) 60.5
(C) 40.8
(D) 70.6

4) For the following reactions, equilibrium constants are given :

S(s) + O2(g) SO2(g); K1 = 1052
2S(s) + 3O2(g) 2SO3(g); K2 = 10129
The equilibrium constant for the reaction,
2SO2(g) + O2(g) 2SO3(g) is :

(A) 10181
(B) 10154
(C) 1025
(D) 1077

5) In which one of the following equilibria, ?

(A) NO2(g) + SO2(g) NO(g) + SO3(g)

(B) 2HI(g) H2(g) + I2(g)
(C) 2NO(g) N2(g) + O2(g)
(D) 2C(s) + O2(g) 2CO(g)

6) 1 g of non-volatile non-electrolyte solute is dissolved in 100g of two different solvents A and B

whose ebullioscopic constants are in the ratio of 1 : 5. The ratio of the elevation in their boiling

points, , is :

(A) 5 : 1
(B) 10 : 1
(C) 1 : 5
(D) 1 : 0.2

7) On increasing temperature, vapour pressure of a pure liquid

(A) Remains unchanged

(B) Increases
(C) Decreases
(D) None of these

8) K2HgI4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is :-

(A) 1.8
(B) 2.2
(C) 2.0
(D) 1.6

9) In a mixture of A and B, components show negative deviation when -

(A) A – B interaction is stronger than A – A and B – B interaction

(B) A – B interaction is weaker than A – A and B – B interaction
(C) ΔVmix > 0, ΔSmix > 0
(D) ΔVmix = 0, ΔSmix > 0

10) Which of the following liquid pairs shows a positive deviation from Raoult's law ?

(A) Water-hydrochloric acid

(B) Benzene-methanol
(C) Water-nitric acid
(D) Acetone-chloroform

11) Which compound is formed when excess KCN is added to aqueous solution of copper sulphate ?

(A) Cu(CN)2
(B) K2[Cu(CN)4]
(C) K[Cu(CN)2]
(D) K3[Cu(CN)4]

12) Which of the following cation gives red colour in flame -

(A) Cs+
(B) Ba2+
(C) Sr2+
(D) K+

13) Which of the following ion gives brown ring test with dil. H2SO4.

–
(A) NO2
(B) NO3–
(C) Both (A) and (B)
(D) None
14) Which of the following anion does not convert yellow solution of FeCl3 to green solution of FeCl2
as a final product?

2–
(A) S2O3
(B) S2–
–
(C) NO2
–
(D) CH3COO

15) Which of the following salt is not soluble in HNO3 (1 : 1) but soluble in aquaregia?

(A) PbS
(B) Ag2S
(C) HgS
(D) Ag2CO3

16) The compound whose 0.1 M solution is basic is

(A) Ammonium acetate

(B) Ammonium chloride
(C) Ammonium sulphate
(D) Sodium acetate

17) The highest pH value is of :-

(A) 0.1 M KNO3

(B) 0.1 M NH4Cl
(C) 0.1 M CH3COONa
(D) 0.01 M CH3COONa

18) The rapid change of pH near the stoichiometric point of an acid–base titration is the basis of
indicator detection. pH of the solution is related to ratio of the concentrations of the conjugate acid
(HIn) and base (In–) forms of the indicator by the expression :-

(A)
log = pKIn – pH

(B)
log = pH – pKIn

(C)
log = pH + pKIn

(D)
log = pKIn – pH

19) In 1 L saturated solution of AgCl [Ksp(AgCl) = 1.6 × 10–10], 0.1 mol of CuCl [Ksp(CuCl) = 1.0 ×
10–6] is added. The resultant concentration of Ag+ in the solution is 1.6 × 10–x. The value of ‘x’ is.
(A) 5
(B) 6
(C) 7
(D) 4

20) Which of the following is most soluble in water?

–37
(A) MnS (Ksp= 8 × 10 )
–16
(B) ZnS (Ksp= 7 × 10 )
–72
(C) Bi2S3 (Ksp = 1 × 10 )
–18
(D) Ag3(PO4) (Ksp = 1.8 × 10 )

SECTION-II

1) Benzene and toluene form nearly ideal solutions. At 20°C, the vapour pressure of benzene is 75
torr and that of toluene is 22 torr. The partial vapour pressure of benzene at 20°C for a solution
containing 78 g of benzene and 46 g of toluene in torr is -

2) A buffer solution contains 0.2 M NH4OH and 0.02M NH4Cl. If value of pKa of NH4+ is 9, then find
the pH of the buffer solution.

3) A(g) + 2B(s) 2C(g).

Initially 2 mol A(g), 4 mole of B(s) and 1 mole of a inert gas are present in a closed container. After
equilibrium has established total pressure of container becomes 9 atm. If A(g) is consumed 50% at
equilibrium then calculate Kp for above reaction -

4) How many of the given sulphides are soluble in (YAS) solution ?

PbS, SnS2, As2S3, SnS, As2S5, ZnS, Sb2S5, HgS

5) Total number of ions which are identified by dil. HCl from the following.

(i) SO42– (ii) CO32–

(iii) SO32– (iv) HCO3–

(v) NO2– (vi) NO3–

(vii) CH3COO– (viii) PO43–

PART-3 : MATHEMATICS

SECTION-I
1) Vectors make an angle θ = . If then =

(A) 225
(B) 250
(C) 275
(D) 300

2) If are unit vectors satisfying then value of

is

(A) 9
(B) 10
(C) 11
(D) 12

3) Let A (2, 3, 5) and C(–3, 4, –2) be opposite vertices of a parallelogram ABCD if the diagonal
then the area of the parallelogram is equal to

(A)

(B)

(C)

(D)

4) Let be the foot of perpendicular from the point (1, 2, 3) on the line .
then is equal to :

(A) 102
(B) 101
(C) 99
(D) 100

5) Let and be three non-zero vectors such that and are non-collinear. If is collinear
with , is collinear with and , then is equal to

(A) 35
(B) 30
(C) –30
(D) –25
6) Let P be the point of intersection of the line and the plane x + y + z = 2. If
the distance of the point P from the plane
3x – 4y + 12z = 32 is q, then q and 2q are the roots of the equation

(A) x2 – 18x – 72 = 0
(B) x2 + 18x + 72 = 0
(C) x2 – 18x + 72 = 0
(D) x2 + 18x – 72 = 0

7) Let two vertices of triangle ABC be (2, 4, 6) and (0, –2, –5), and its centroid be (2, 1, –1). If the
image of third vertex in the plane x + 2y + 4z = 11 is (α, β, γ), then αβ + βγ + γα is equal to

(A) 72
(B) 74
(C) 76
(D) 70

8) Let P, Q and R are subsets of a set A, then R × (P' ∪ Q')' equals

(A) (R × P) ∩ (R × Q)
(B) R × (P ∪ Q)
(C) (R' × P) ∪ (R' × Q)
(D) R × P

9) If A = {1, 3, 5, 7, 9, 11},
B = {2, 4, 6, 8, 10, 12},
U is universal set, then A' ∪ ((A ∪ B) ∩ B') is-

(A) U
(B) A'
(C) A ∩ B
(D) A

10) Let A = {2, 3, 4} and B = {8, 9, 12}. Then the number of elements in the relation R = {((a1, b1),
(a2, b2)) ∈ (A × B, A × B) : a1 divides b2 and a2 divides b1} is :

(A) 36
(B) 12
(C) 18
(D) 24

11) Let ƒ : → and ƒ(x) = x3 + ax2 + bx – 8. If ƒ(x) = 0 has three real roots & ƒ(x) is a bijective
function, then (a + b) is equal to

(A) 0
(B) 6
(C) –6
(D) 12

12) For x ∈ , two real valued functions f(x) and g(x) are such that, and
Then f(1) is equal to

(A) 1
(B) 3
(C) 5
(D) 0

13) Let f(x) = x2 – 2x – 1 ∀ x ∈ R and f:(–∞, a] → [b, ∞), where a is the largest real number for which
f(x) can be made bijective, then value of (a + b) is :

(A) –2
(B) –1
(C) 0
(D) 1

14) Let P(x) = kx3 + 2k2 x2 + k3. The sum of all real numbers k for which (x – 2) is a factor of P(x), is

(A) 4
(B) 8
(C) –4
(D) –8

15) Consider ƒ(x) = x2 – 5x + 4, then number of solutions of |ƒ(|x|)| = 2 is equal to -

(A) 2
(B) 4
(C) 6
(D) 8

16) If ƒ(x,y) = max(x,y) + min(x,y) and g(x,y) = max(x,y) – min(x,y), then the value of ƒ

is greater than -

(A) 1
(B) 2
(C) 3
(D) 4

17) If y = ƒ(x) and then domain of ƒ(x) is :-

(A)

(B)

(C)

(D)

18) The value of

is equal to

(A)

(B)

(C)

(D)

19) The range of function is

(A)

(B) [0, 1]

(C)

(D) [e–π, eπ]

20) If the equation sin–1(4x – x2 – 5) + cos–1(4x – x2 – 5) + λx =0 has a real solution. Then the value of
[λ] is (where [.] denotes greatest integer function).

(A) –2
(B) –1
(C) 0
(D) Infinitely many

SECTION-II

1) Let & . If projection of on is , then the value of (k – 2) is

2) If the distance of a point lying on the plane 2x +3y + 6z = p from the point (3, 0, 1) is unity then
the total number of possible values of p, where p is a prime number, is
3) Let Q be the foot of the perpendicular from the point P(7,–2,13) on the plane containing the line

and , is equal to

4) Sum of all integer values in the range of f(x) = 5 + (cos–1x) is-

5) Number of integral value(s) of x for which π – 3sec–1x ≥ 0 is :

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A D A B D A D D D D A A B A A C B D A C

SECTION-II

Q. 21 22 23 24 25
A. 2 2 2 600 5

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A A C D C B A A B D C A D C D C A C D

SECTION-II

Q. 46 47 48 49 50
A. 50 10 9 5 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C B B A C B A A A B B B D D A D B A B

SECTION-II

Q. 71 72 73 74 75
A. 9 6 96 26 2
 SOLUTIONS

PART-1 : PHYSICS

1)

I3 = mR2

2)

3)

I = MR2

4)
m2b = m1a

5) The moment of inertia should be minimum

x=3

6)
and

8)

9) ⇒ or is antiparallel to Thus may increase.

10) Acceleration of center of mass is independent of point of application of force.

11)
Let angular velocity and linear velocity of centre of mass of disc

be ω and vcm then vcm + ωR = 2v and ωR–vcm = v 2ωR = 3v ω=

12) ∴ Tnet = 3.5 FR

13) When rod becomes 37° from the vertical the change in PE ; increases the KE of the
rotational kinetic energy.

ω = 2 rad/sec

15) sinθc =

16)

Instantaneous axis of rotation lies above the centre of mass where v – ωr = 0

17)
δ=i+e–A
28 = 18 + 42 – A
28 = 60 – A ⇒ A = 32°

18) u = –10 cm
v = + 20 cm
P = 15

19) Apply C.O.A.M., 10 = ; w = 15 rad.

K.E. =

20)

,
away from the mirror

22)

f = – 15 cm
m=2

–30 – 2u = –15
u = – 7.5 cm

23) For lens B according to the figure

u=+3
v=–6

24) For without deviation passing at interface, we must have same refractive index on the two
sides of the interface, so we use
n1 = n2
 25) Minimum deviation of light through the prism is given as
δmin = 2i – A
Refractive index of prism in terms of minimum deviation angle is given as

Velocity of light in prism is given as

Time taken by light to cover the distance AP is given as

PART-2 : CHEMISTRY

26) (NH4)2CO3(s) 2NH3(g) + CO2(g) + H2O(g)

2p p p
Kp = (2p)2 p.p = 64 atm
p = 2 atm
ptotal = 2p + p + p = 8 atm

29) S(s) + O2(g) SO2(g) K1 = 1052 ...(1)

2S(s) + 3O2(g) 2SO3(g) K2 = 10129 ...(2)
2SO2(g) + O2(g) 2SO3(g) K3 = x
multiplying equation (1) by 2;
2SO(s) + 2O2(g) 2SO2(g) ...(3)
⇒ Substracting (3) from (2); we get
;
(129 – 104) 25
Keq = 10 = 10

30) if Δng ≠ 0
Kp ≠ Kc
31) Given : weight of solute dissolved = 1 gm,

If the molar mass of solute = M & mass of solvent taken = W

⇒ Applying the formula of elevation in boiling point ;

32)

On increasing temperature, vapour pressure of a pure liquid increases because more vapour of
liquid form.

33) Van't Hoff factor (i) = 1 + (m - 1)α; where

m = total moles of product per mole of reactant
α = degree of dissociation
⇒ given: α = 0.4

⇒ i = 1 + (3 – 1) (0.4) = 1.8

36) Cu2+ + KCN (excess) → K3[Cu(CN)4]

41) NH4CH3COO pH = 7 + (pKa – pKb), salt of weak acid + weak base

NH4Cl Salt of strong acid + weak base ⇒ pH < 7
(NH4)2SO4 Salt of strong acid + weak base ⇒ pH < 7
CH3COONa Salt of weak acid + strong base ⇒ pH < 7

43) pH = + log

or, log

44)

45) (A) Ksp = S2 ⇒ S =

(B) Ksp = S2 ⇒ S =
 (C) Ksp =108 S5 ⇒ S =

(D) Ksp = 27 S5 ⇒ ⇒ Maximum

47) pH = pKa + log

= 9 + log
=9+1
= 10

48)

A(g) + 2B(s) ⇌ 2C(g)

Eq. 1 – 2 mole

49) PbS, ZnS, HgS are not soluble in yellow ammonium sulphides.

50) (ii, iii, iv, v, vii)

PART-3 : MATHEMATICS

51)
⇒ .....(1)

Now

52) On simplyfication

53) Area =
54)
Let foot P (5k – 3, 2k + 1, 3k – 4)

Condition of perpendicular lines

(25k–20) + (4k–2) + (9k – 21) = 0

Then
Then = 101

55)

Eliminating

56) P = (3λ – 3, λ – 2, 1 – 2 λ)
P lies on the plane, x + y + z = 2

P = (6, 1, –5)

q = 6, 2q = 12
Equation, x2 – 18x + 72 = 0

57) Given, A(2, 4, 6), B(0, -2, -5)

G(2, 1, –1)
Let vertex C(x, y, z)
Third vertex, C(4, 1, -4)
Then image of vertex in the plane let image (α, β, γ)

i.e,.
α = 6, β = 5, γ = 4
αβ + βγ + γα = 30 + 20 + 24 = 74

58) R × (P' ∪ Q')' = R × (P ∩ Q) = (R × P) ∩ (R × Q)

59) (A ∪ B) ∩ B' = A
⇒ A' ∪ ((A ∪ B) ∩ B') = A' ∪ A = U

60)
a1 divides b2
Each element has 2 choices
⇒3×2=6
a2 divides b1
Each element has 2 choices
⇒3×2=6
Total = 6 × 6 = 36

61)

ƒ(x) must be a perfect cube

ƒ(x) = (x – 2)3 = x3 – 6x2 + 12x – 8
⇒ a = –6, b = 12

62)

63) f(x) = x2 – 2x – 1
for injective f '(x) = 2x – 2
f '(x) ≥ 0 f '(x) ≤ 0 ∀ x ∈ (–∞, a]
= 2x – 2 ≤ 0 = x ≤ 1
so largest value of a is 1
for surjective → f(x) = (x – 1)2 – 2
at x = 1 f(x) = –2
so f is surjective if f(x) ∈ [–2, ∞)
a = 1, b = –2
a + b = 1 – 2 = –1

64) ⇒ P(x) = kx3 + 2k2 x2 + k3

⇒ (x – 2) is a factor of P(x)
i.e. P(2) = 0
⇒ k(2)3 + 2(k)2(2)2 + k3 = 0
⇒ 8k + 8k2 + k3 = 0
⇒ k(k2 + 8k + 8) = 0

⇒ k1 + k2 = –8
Sum of all real numbers k will be –8

65) Let us plot ƒ(x) = x2 – 5x + 4

Now x → |x|
⇒ y = ƒ(|x|) will be

Now ƒ(|x|) → |ƒ|x||

From the above graph it is clear that number of points of intersection of y = |ƒ(|x|)| & y = 2 is

66)

g(–3, –4) = max(–3, –4) – min(–3, –4)

= –3 + 4 = 1

∴
67) , x > 0, |y| ≠ 0

68)

69)

Maximum when sin–1x =

Minimum when

70) –1 < 4x – x2 – 5 < 1 ⇒ (x – 2)2< 0

So Df = {2}

71) Projection of on =

72)
|12 – p| 7 –7 p – 12 7
5 p 19 5, 7, 11, 13, 17, 19
i.e. six possible values of p.

73) Containing the line

9(x + 1) – 18 (y – 1) + 9(z– 3) = 0
x – 2y + z = 0
PQ =
PQ2 = 96

74) Range ⇒ [5, 5 + π]

Sum = 5 + 6 + 7 + 8 = 26

75)