Class- XII
Test- Ch- Solutions, Electrochemistry, Biomolecules MM:30
1. Increasing the temperature of an aqueous solution will cause
(a) Increase in Molarity 1
(b) Increase in Molality
(c) Decrease in Molarity
(d) Decrease in Molality
2. The value of KH (Henry’s law constants) for the given gases in water at 293 K are
I. He – 144.97 k bar
II. H2 – 69.16 k bar
III. N2 – 76.45 k bar
IV. O2 – 34.86 k bar
Which gas has the lowest solubility in water? 1
(a) He
(b) H2
(c) N2
(d) O2
3. A 5% (by mass) solution of glucose (molar mass = 180 g mol–1) is isotonic with 1% solution
(by mass) of a substance ‘X’. The molar mass of ‘X’ is
(a) 36 g mol–1 1
(b) 18 g mol–1
(c) 72 g mol–1
(d) 900 g mol–1
4. An electrochemical cell can behave like an electrolytic cell when ____________.
(a) Ecell = 0
(b) Ecell > Eext 1
(c) Eext > Ecell
(d) Ecell = Eext
5. The specific conductance of a saturated solution of AgCl at 298 K is 1.8 × 10 –5 S cm–1. What
is solubility product of AgCl if Λ°m = 120.0 S cm2 mol–1?
(a) 2.25 × 10–8
1
(b) 1.25 × 10–8
(c) 1.5 × 10–4
(d) 2.25 × 10–10
6. Which of the following has highest molar conductivity?
(a) 0.01 M KCl
(b) 1 M KCl 1
(c) 0.5 M KCl
(d) 0.1 M KCl
7. Which of the following is non-reducing sugar?
(a) Glucose (b) Sucrose 1
(c) Maltose (d) Lactose
8. Dinucleotide is obtained by joining two nucleotides together by phosphodiester linkage.
Between which carbon atoms of pentose sugars of nucleotides are these linkages present?
1
(a) 5′ and 3′ (b) 1′ and 5′
(c) 5′ and 5′ (d) 3′ and 3′
9. Mention the reactions occurring at (i) anode, (ii) cathode, during working of a mercury cell. 2
Why does the voltage of a mercury cell remain constant during its operation?
10. Calculate the time to deposit 1.27 g of copper at cathode when a current of 2 A was
passed through the solution of CuSO4. 2
(Molar mass of Cu = 63.5 g mol–1, 1 F = 96500 C mol–1)
11. Which sugar is called invert sugar? Why is it called so? 2
12. Name two fat soluble vitamins, their sources and the diseases caused due to their 2
deficiency in diet.
13. What is van’t Hoff factor? What types of values can it have if in forming the solution the 2
solute molecules undergo (i) Dissociation (ii) Association?
14. For a 5% solution of urea (Molar mass = 60 g/ mol), calculate the osmotic pressure at
2
300 K. [R = 0.0821 L atm K–1 mol–1]
15. (a) State Kohlrausch law of independent migration of ions. Write an expression for the
molar conductivity of acetic acid at infinite dilution according to Kohlrausch law.
(b) Calculate for acetic acid. 5
Given that (HCl) = 426 S cm2 mol–1
(NaCl) = 126 S cm2 mol–1
(CH3COONa) = 91 S cm2 mol–1
16. (a) Explain why a solution of chloroform and acetone shows negative deviation from
Raoult’s law.
(b) Phenol associates in benzene to certain extent to form a dimer. A solution containing 5
20 g of phenol in 1.0 kg of benzene has its freezing point lowered by 0.69 K. Calculate the
fraction of phenol that has dimerised. [Given Kf for benzene = 5.1 Km–1]