18-10-2025

2721CJA101031250012 JM

PHYSICS

SECTION-A

1) Two springs of force constant K and 2K are connected to a mass M as shown. The frequency of

oscillation of the mass is :-

(A)

(B)

(C)

(D)

2) A particle executes S.H.M., starting from mean position with amplitude 8 cm and time period

sec then velocity of particle at t = sec is:-

(A) 32π cm/sec

(B) 16π cm/sec
(C) 16 π cm/sec
(D) 8π cm/sec

3) Which of the following quantities is always non-zero in a simple harmonic motion ?

(A)
(B)
(C)
(D)

4) The potential energy of a particle executing SHM changes from maximum to minimum in 5 s.
Then the time period of SHM is :-

(A) 5 s
(B) 10 s
(C) 15 s
(D) 20 s
5) A particle executes SHM along a straight line with mean position at x = 0, period 20 sec and
amplitude 5 cm. Find the shortest time taken by the particle to go from x = 4 cm to x = – 3 cm in
seconds.

(A) 8 s
(B) 7s
(C) 3s
(D) 5s

6) The potential energy of a particle of mass 'm' situated in a unidimensional potential field varies as
U(x) = U0 [1–cosax], where U0 and a are constants. The time period of small oscillations of the
particle about the mean position is :-

(A)

(B)

(C)

(D)

7) Which of the following relationships between the acceleration a and displacement x of the particle
involve simple harmonic motion :-

(A) a = 0.7 x
(B) a = –200 x2
(C) a = –10 x
(D) a = 100 x2

8) A particle moves on x-axis according to the equation x = x0 sin2ωt, the motion is simple harmonic
:-

(A) with amplitude x0

(B) with amplitude 2x0
(C) with time period (2π/ω)
(D) with time period (π/ω)

9) The variation of acceleration (a) and displacement (x) of the particle executing SHM is indicated
by the following curve :–

(A)
(B)

(C)

(D)

10) A cage of mass M hangs from a light spring of force constant k. A body of mass m falls from
height h inside the cage and sticks to its floor. The amplitude of oscillations of the cage will be (M =

m)

(A)

(B)

(C)

(D)

11) A particle is performing S.H.M. with acceleration a = 8 π2 - 4 π2 x where x is coordinate of the

particle w.r.t. the [Link] parameters are in S.I. units. The particle is at rest at x= -2 at t=0.

(A) coordinate of the particle w.r.t. origin at any time t is 2 - 4 cos2π t

(B) coordinate of the particle w.r.t. origin at any time t is -2 + 4 sin2πt
(C) coordinate of the particle w.r.t. origin at any time t is - 4 + 2 cos2πt
(D) the coordinate cannot be found because mass of the particle is not given.
12) A block of mass 0.9 kg attached to a spring of force constant K is compressed by cm and the

block is at a distance cm from the wall. When the block is released, it makes elastic collision with
the wall and its period of motion is 0.2 s. The value of K is (take π2=10)

(A) 100 Nm–1

(B) 10 Nm–1
(C) 0.1 Nm–1
(D) 1 Nm–1

13) Two particles A and B perform SHM along the same straight line with the same amplitude 'a',
same frequency 'f' and same equilibrium position 'O'. The greatest distance between them is found
to be 3a/2. At some instant of time they have the same displacement from mean position. What is
this displacement?

(A) a/2
(B) a /4
(C) /a2
(D) 3a/4

14) The motion of a mass on a spring, with spring constant K is as shown in figure.

The equation of motion is given by x(t) = Asinωt + Bcosωt with

Suppose that at time t = 0, the position of mass is x(0) and velocity v (0), then its displacement can
also be represented as x(t) = Ccos(ωt – ϕ), where C and ϕ are :

(A)

(B)

(C)
(D)

15) In a simple harmonic oscillation, what fraction of total mechanical energy is in the form of
kinetic energy, when the particle is midway between mean and extreme position.

(A)

(B)

(C)

(D)

16) A uniform cylinder of length L and mass M having cross-sectional area A is suspended, with its
length vertical, from a fixed point by a massless spring, such that it is half submerged in a liquid of
density s at equilibrium position. When the cylinder is given a downward push and released, it starts
oscillating vertically with a small amplitude. The time period T of the oscillations of the cylinder will
be:

(A)
Larger than

(B)
smaller than

(C)

(D)

17) A simple pendulum of length has a time period T for small oscillations. A fixed obstacle is
placed directly below the point of suspension, so that only the lower quarter of the string continues
oscillations (see figure). The pendulum is released from rest at a certain point O. The period of

oscillation, assuming small angles, will be:

(A) 3T/4
(B) T/4
(C) T/2 (1 + √3)
(D) T

18) A light spring of stiffness k is hanging from the ceiling. It is stretched by a distance d, then a
mass m attached to the end A which is then released. The amplitude of the oscillations will be

(A) mg/k
(B) 2mg/k
(C) d
(D) |(mg/k) - d|

19) Spring System in SHM

A toy car of mass m is having two similar rubber ribbons attached to it as shown in the figure. The
force constant of rubber ribbons is k. The car is displaced from mean position by x cm and released.

At the mean position the ribbons are undeformed. Vibration period is

(A)

(B)
(C)

(D)

20)

A mass M is suspended from a spring of negligible mass. The spring is pulled a little and then
released so that the mass executes SHM of time period T. If the mass is increased by M, the time

period becomes . Then the ratio of is

(A)

(B)

(C)

(D)

SECTION-B

1) A block P of mass m is placed on a frictionless horizontal surface. Another block Q of same mass is
kept on P and connected to the wall with the help of a spring of spring constant k as shown in the
figure, μs is the coefficient of friction between P and Q. The blocks move together performing SHM of

amplitude A. The maximum value of the friction force between P and Q is . Find the value of x.

2) In the arrangement as shown in fig., pulleys are small and springs are ideal. k1, k2, k3 and k4 are
force constants of the springs. If the period of small vertical oscillations of block of mass m is

. Find the value of n.

3) Consider two identical springs each of spring constant k and negligible mass compared to the
mass M as shown. Fig.1 shows one of them and Fig.2 shows their series combination. The ratios of

time period of oscillation of the two SHM is , where value of x is ______. (Round off to the

Nearest Integer)

4) A particle performs simple harmonic motion with a period of 2 second. The time taken by the

particle to cover a displacement equal to half of its amplitude from the mean position is . The
value of 'a' to the nearest integer is _______ .

5) In the given spring block system if k = 25π2N/m, find time period of oscillation is ____. (in sec)

CHEMISTRY

SECTION-A

1) The major product the following reaction is :

(A)

(B)
(C)

(D)

2)
Product of above reaction is :

(A)

(B)

(C)

(D)

3) Major product in the reaction

(A)
(B)

(C)

(D)

4) If X and Y are functional group isomers, then what is the structure of reactant (Alkyne)?

(A) CH3–C≡C–CH3
(B) CH3–CH2–C≡C–H
(C) CH2 = CH – CH = CH2
(D) CH3–CH=C=CH2

5) Rate of reaction of following alkenes with H3O⊕ :

(I) (II) (III) (IV)

(A) IV > I > II > III

(B) IV > II > I > III
(C) II > IV > I > III
(D) III > II > I > IV

6) The major product of the following reaction is:

(A) CH3CH2C≡CH

(B)

(C) CH3CH=C=CH2
(D) CH3CH=CHCH2NH2

7) The major product of the following reaction is:

(A)

(B)

(C)

(D)

8) "X"
Considering the above chemical reaction, identify the product "X" :
(A)

(B)

(C)

(D)

9) Give correct order of reactivity towards electrophilic aromatic substitution.

(A) 4 > 3 > 2 > 1

(B) 1 > 2 > 3 > 4
(C) 2 > 3 > 1 > 4
(D) 1 > 4 > 3 > 2
10) (A) (B)
product B is :

(A) Antibiotic
(B) Analgesic
(C) Antacid
(D) Insecticide

11) The product formed in the reaction of cumene with O2 followed by treatment with dil. HCl are :

(A)

and

(B)

and CH3 – OH

(C)

and

(D)
and

12) Consider the following reactions :

Which of these reactions are possible ?

(A) (a) and (d)

(B) (b) and (d)
(C) (a) and (b)
(D) (b) , (c) and (d)

13) Which of these will produce the highest yield in Friedel Crafts reaction ?

(A)

(B)

(C)

(D)

14) The compounds P, Q and S

were separately subjected to nitration using HNO3 / H2SO4 mixture. The major product formed in
each case respectively, is :
(A)

(B)

(C)

(D)

15) Which of the following statements/relationships is not correct in thermodynamic changes ?

(A)
q= –nRT ln (isothermal reversible expansion of an ideal gas)
(B) For a system at constant volume, heat involved merelv changes to internal energy.

(C)
w = –nRT ln (isothermal reversible expansion of an ideal gas)
(D) ΔU = 0 (isothermal reversible expansion of a gas)

16) The entropy values (in JK–1 mol–1) of H2(g) = 130.6, Cl2(g) = 223.0 and HCl(g) = 186.7 at 298 K
and 1 atm pressure. Then entropy change for the reaction H2(g) + Cl2(g) → 2HCl(g) is :-

(A) +540.3
(B) +727.3
(C) –166.9
(D) +19.8

17) of water is –285.8 kJ mol–1. If enthalpy of neutralisation of monoacid strong base is –57.3 kJ
mol–1, of OH– ion will be ?

(A) –228.5 kJ mol–1

(B) 228.5 kJ mol–1
(C) 114.25 kJ mol–1
(D) –114.25 kJ mol–1
18) The volume strength of 1.5 N H2O2 solution is :

(A) 4.8 V
(B) 8.4 V
(C) 3 V
(D) 8 V

19) Given the correct order of initials 'T' or 'F' for the following statements. Use 'T' if statement is
true and 'F' if it is false
(I) In NH3, the orbital in which lone pair is present is pure orbital
(II) In F2O2, polar as well as non polar both bonds are present
(III) In , one of the π-bond can be formed by orbital of central atom
(IV) In , all C–O bonds are not same

(A) T T T T
(B) F T F T
(C) F T T T
(D) T F T F

20) Statement–1 : H3BO3 in water behaves as monobasic acid.

Statement–2 : The ionisation reaction is :
H3BO3 + H2O B(OH)4– + H+.

(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1.
Statement-1 is true, Statement-2 is true and Statement-2 is NOT the correct explanation for
(B)
Statement-1.
(C) Statement-1 is true, Statement-2 is false.
(D) Statement-1 is false, Statement-2 is true.

SECTION-B

1) Number of 90° b.p – l.p interactions in I3– ion is

2) Size of BrΘ is greater than how many among these ions :

IΘ, ClΘ, S2–, FΘ, NΘ, Li⊕, Se2+, Ga2+, Al3+.

3) ΔH = 201 kJ/mol
ΔH = 440 kJ/mol

ΔH = 700 kJ/mol

If the difference between IE3 – IE2 is X, then the value of is :-

4) The entropies of H2(g) and H(g) are 60 & 50 J mol–1 k–1 respectively at 300 K. Using the data given
below, calculate the bond energy of H2(g) in Kcal mol–1
H2(g) → 2H(g), ΔG° = 21.6 kJ mol–1

5) Identify number of substrate those can give SN and SN reaction both-

1 2

, , ,

, , ,

, CH3–Cl . ,

MATHEMATICS

SECTION-A

1) If (k + 1)x + (2k + 1)y + k = 0 cuts equal non-zero intercepts on the coordinate axes on xy-plane
then k ∈ -

(A)

(B)

(C)

(D) ϕ

2) If lines L1 = 0 and L2 = 0 passes through (1,1) and makes an equilateral triangle with line
, then perimeter of the equilateral triangle is-

(A) 1
(B) 2
(C) 3
(D) 4

3) Find the sum of slopes of all possible lines passing through origin and intersecting the lines
x + y = 1, x + 2y = 1 at A, B respectively such that 3(OA)(OB) = 1, where O is origin.

(A)

(B) 3
(C)

(D) None of these

4) The equation represents

(A) Three real straight lines

(B) One point
(C) One real and two imaginary lines
(D) None of the above

5) Let r be radius of the smallest circle which cuts the two circles x2 + y2 = 1 and x2 + y2 + 8x + 8y –
33 = 0 orthogonally then the value of r2 is

(A) 7
(B) 5
(C) 2
(D) 10

6) If a = max{(x + 2)2 + (y – 3)2} and b = min{(x + 2)2 + (y – 3)2}

where x and y satisfying
x2 + y2 + 8x – 10y – 40 = 0, then

(A) a + b = 20
(B) a + b = 172
(C) a – b =
(D) a – b =

7) The line 2x – y + 1 = 0 is tangent to the circle at the point (2, 5) and the centre of the circles lies
on x – 2y = 4. The radius of the circle is :

(A)
(B)
(C)
(D)

8) Let the circle be such that it neither intersects nor tocuhes

the co-ordinates axes. If the point of intersection of the lines, and lies inside the
circle S, then:

(A)
(B)
(C)

(D)
9) A variable chord PQ of parabola y2 = 4x is drawn parallel to a line y = x. Then which of the
following point lies on the locus of point of intersection of the normals at P and Q.

(A) (7, 2)
(B) (7, 1)
(C) (3, 6)
(D) (10, 2)

10) If the line cuts the parabola at P and Q and if A be the

point then is

(A)

(B)

(C)

(D)

11) Let A and B be the two points of intersection of the line y + 5 = 0 and the mirror image of the
parabola y2 = 4x with respect to the line x + y + 4 = 0. If d denotes the distance between A and B,
and a denotes the area of ΔSAB, where S is the focus of the parabola y2 = 4x, then the value of (a +
d) is ____.

(A) 3
(B) 4
(C) 14
(D) 10

12) If two distinct chord drawn from the point (2, 2) on the parabola y2 = 16x are bisected on the line
y = mx then set of all values of m is given by :

(A)

(B)

(C) (–3, 3)

(D)

13) If P is a point on the ellipse whose focii are S and S'. Let ∠PSS' = α and ∠PS'S = β
then which one is incorrect

(A) PS + PS' = 2a if a > b

(B) PS + PS' = 2b if a < b

(C)
(D) None of these

14) If will represent ellipse then complete set of values of λ is

(A)
(B)
(C)
(D) (5,∞)

15) Let L is distance between two parallel normals of , a > b, then maximum value of L is
-

(A) 2a
(B) 2b
(C) a + b
(D) 2(a – b)

16) If the angle between the straight lines joining foci and the ends of minor axis of the ellipse

is 90°, then eccentricity of ellipse is-

(A)

(B)

(C)

(D)

17) The locus of P(x,y) such that is

(A) Hyperbola
(B) Circle
(C) Pair of lines
(D) A Ray

18) The angle between the pair of tangents drawn to the curve 7x2 – 12y2 = 84 from the point (1,2)
is

(A)

(B) 2tan–12
(C)

(D) 2tan–13

19) Tangents are drawn from any point on hyperbola to the circle . If

locus of midpoint of chord of contact is ,then λ is:

(A) 4
(B) 1
(C) 2
(D) 3

20) If the circle x2 + y2 = a2 intersect xy = c2 at four points P(x1,y1), Q(x2,y2), R(x3,y3) and S(x4,y4), then

(A) x1 + x2 + x3 + x4 = 0
(B) y1 + y2 + y3 + y4 = 2
4
(C) x1x2x3x4 = 2c
4
(D) y1y2y3y4 = 2c

SECTION-B

1) Let the foci and length of the latus rectum of an ellipse a>b

be and , respectively. Then, the square of the eccentricity of the hyperbola equals

2) Let tanα, tanβ and tanγ; α, β, γ ≠

n ∈ N be the slopes of three line segments OA, OB and OC, respectively, where O is [Link]
circumcentre of ΔABC coincides with origin and its orthocentre lies on y-axis, then the value of

is equal to :

3) The chord of the hyperbola x2 – y2 = 25, touches the parabola y2 = 20x. If the locus of middle point
of the chords can be expressed as x3 = y2 (x – a), then a2 is

4) A variable chord of the hyperbola , subtends a right angle at the centre of the
hyperbola. If this chord touches a fixed circle which is concentric with the hyperbola and r is radius
of the circle, then r2 is

5) If the area of the quadrilateral formed by the common tangents of the circle x2 + y2 = 25 and the
ellipse is A. Then the value of is
 ANSWER KEYS

PHYSICS

SECTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C C D D D C C D A C A A B D B C A D C B

SECTION-B

Q. 21 22 23 24 25
A. 2 4 2 6 1

CHEMISTRY

SECTION-A

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D C C B C A C C B B C B C C A D A B B A

SECTION-B

Q. 46 47 48 49 50
A. 6 8 3 8 5

MATHEMATICS

SECTION-A

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D B B C A D A C A B C B D A D C D C B A

SECTION-B

Q. 71 72 73 74 75
A. 51 144 25 8 999
 SOLUTIONS

PHYSICS

1)

Springs are in parallel combination

2)

cm/sec

3) For and θ is 180°

∴

4)

P.E. is maximum at extreme position and minimum at mean position.

Time to go from extreme position to mean position is, t = ; where T is time period of SHM

5s=
⇒ T = 20 s.

5)

By phasor diagram
Angle traced = 53° + 37° = 90°

∴ Time taken = = =5s

6)
 0 0
F= = –U [0 + asin ax] = –U a sin ax
for small oscillation; sinax ≈ ax
⇒ F = –(U0a2x)

⇒T=

7)

a = –ω2x
a = –( )2x
(3) is S.H.M.

8) x = x0sin2 ωt

Frequency ω' = 2ω
⇒ 2π/T' = 2ω
⇒ T' = (π/ω)
Amplitude = x0/2

9) a = –ω2x
Straight line

10)

11) a=8π2–4π2x = –4π2(x–2) ⇒ ω=2π

Here a=0 so mean position at x =2
Let x = Asin(ωt + ϕ)
As particle is at rest at x=–2 (extreme position)
and Ampliutde = 4 as particle start from extreme position. Therefore
x –2 = –4cos2πt ⇒ x = 2–4 cos2πt

12) Time period of motion 0.2 =

k = 100 N/m

13) x1 = a sin ωt, x2 = a sin(ωt + ϕ)

Greatest distance

=|x2–x1|max=2a sin
Now according to question x1 =x2
⇒ a sin ωt = a sin (ωt + ϕ)

⇒ π –ωt = ωt + ϕ ⇒ ωt =

⇒ x1 = a sin = a cos

14) Question Explanation: Finding the amplitude and phase of an SHM from its initial
position and velocity.

Concept: General equation of SHM.

Solution:
x = A sin ωt + Bcos ωt

v= = Aω cosωt – Bw sinωt
At t = 0, x (0) = B
v (0) = Aω

x = A sin ωt + B sin (ωt + 90°) Anet =

⇒
⇒ x=
⇒
x = C cos(ωt – ϕ)
​⇒

​⇒

15)
16) Question Explanation: Finding the time period of a uniform cylinder oscillating vertically
in a liquid.
Concept: SHM with buoyancy.
Calculation:
If it is displaced by x amount downward, than
fR = extra force
= kx + σ A x . g
= (k + σ A g)x

17) Question Explanation: Identifying the motion of a torsional pendulum.

Concept: Torsional pendulum.
Solution: A torsional pendulum is a device that oscillates in a horizontal plane about a vertical
axis. It's a type of pendulum, and its motion is a simple harmonic motion.
Calculation: A torsional pendulum performs angular simple harmonic motion. The motion is
periodic, oscillatory, and simple harmonic.
Final Answer: The correct options are (1), (2), (3), and (4).

18) Question Explanation: Finding the maximum downward displacement of a block from an
extended spring.
Concept: Vertical SHM and energy conservation.
Solution: The block is released from rest when the spring has an initial extension. The motion
is SHM about the equilibrium position. The maximum downward displacement is the sum of
the equilibrium extension and the amplitude.
Calculation: The block has mass m and the spring has stiffness k.
The equilibrium position is where kxeq ​= mg ⟹ xeq​ = mg/k.
The block is released from rest when the extension is x0​. Let's assume the spring is stretched.
This point is one of the extremes of the oscillation.
The amplitude of the oscillation is A = ∣xeq ​− x0​∣ = ∣mg/k − x0​∣.
The maximum downward displacement is the distance from the release point to the lowest
point of the oscillation.
The displacement from the unstretched position is x0​. The amplitude is ∣x0​ − mg/k∣.
The maximum downward displacement is xmax​ = x0​ + ∣x0 ​− mg/k∣.
This is a complex problem. Let's re-read the question.
The block is released from rest when the spring is stretched by x0​. This is the upper extreme.
The equilibrium is at xeq​ = mg/k from the unstretched position.
The amplitude is A = xeq​ − x0​.
The maximum downward displacement is from the release point to the lower extreme.
This is 2A = 2(xeq​ − x0​) = 2(mg/k − x0​).
The question asks for the maximum downward displacement of the block.
This is the displacement from the unstretched length to the lowest point.
xbottom​ = xeq​ + A = mg/k + (mg/k − x0​) = 2mg/k − x0​.
Final Answer: |(mg/k) - d|

19) Question Explanation: Finding the vibration period of a toy car with two springs.
Concept: Time period of a spring-mass system.
Solution: The two springs are attached to the car. When the car is displaced, both springs
exert a restoring force. This is a parallel combination of springs.
Calculation: The mass of the car is m. The spring constant of each spring is k.
The springs are in parallel, so the effective spring constant is keff​ = k + k = 2k.

The time period of oscillation is

Final Answer: The correct option is (4).

20)

21) Question Explanation: Finding the maximum frictional force between two blocks in
SHM.

Concept: Frictional force in SHM.

Solution:
At maximum elongation in spring, acceleration of (P + Q) system will be maximum. Hence
friction force on P will be maximum at that instant.

Acceleration ‘a(P+Q)’ =
 Hence friction force on P ‘f’ = ma(P+Q) =

22) Question Explanation: Finding the time period of small vertical oscillations for a block in
a spring-pulley system.

Concept: Equivalent spring constant.

Solution:
Let block be displaced by x then displacement in springs be x1,x2,x3 and x4
Such that x = 2x1 + 2x2 + 2x3 + 2x4
Now let restoring force on m be F = kx then
2f = k1x1 = k2x2 = k3x3 = k4x4

23)

Ta = 2π

Tb = 2π

=
⇒x=2

24) t=
∴ Correct answer = 6.00

25)

CHEMISTRY
26)
I) Br2 addition occurs to the double bond which is anti addtion.

+ Br - Br
II) EtOH alkeks on allylic position through SN mechanism

27) Aromatization reaction.

28)

29)
Butan-2-one (X) and Butanal(Y) are functional group isomers.

30)
I)

(II)

(III)

(IV)

Correct order is - II > IV > I > III

31)
32)

33)

34)

Reactivity of electrophilic aromatic substitution α +H effect.

1>2>3>4

35) Question Explanation:

Question is asking about B product formed by reaction of phenol with (i) CO2/ (ii) H⊕
followed by reaction with acetic anhydride.

Concept:
This question is based on Kolbe schmitt reaction and acetylation of phenolic –OH group.

Solution:

⇒ Aspirin is an analgesic drug.

Final Answer:
The correct option is (2).
36)

Sol./Explanation : We have to find product formed an reaction of cumene with O2 followed by

treatment with dil. HCl.

Concept :

37) (a)

(b)
(electrophilic substitution)

(c)

(d)

38) ∴ (Deactivated ring due to –R effect of amide)

(l.p.e. of –NH2 and group do acid-base reaction with lewis acid AlCl3,
so ring is deactivated)

(Highest yield produced)

39) Better e– releasing group will decide position of EAS.

40) For an reversible isothermal process

ΔU = w + q
ΔU = 0

So, w = –q = –nRT ln

41)
= 2 × 186.7 – (130.6 + 223.0) = 19.8 JK–1 mol–1

42)
–57.3 = –285.5 –

43)

Volume strengh of H2O2 solution.

given Normality = 1.5N
we know,

Normality (N) =
Volume strength = N × 5.6
= 1.5 × 5.6
= 8.4 V

44) (I) NH3 sp3-ideally it should be 25% S for lone pair and 75% P.
But according to bent rule %S character increases for lone pair.
* due to more near the nucleus nature of s-orbital leading to more stability.

(II) F2O2 Open book like structure.

Non-planar molecule.
(III) IO2F2– will not form p-bond.

sp3d orbital is used in hybridisation

s + px + py + pz +

(IV) HCO3–
Only two resonating (identical), relatively stable resonating structure.
 Option (B) is correct.

45) Boric acid gives one H+ in water hence, monobasic acid.

46)

47) H– and I– have bigger size than Br–

48) I.E1 = 201 kJ/ mol

I.E2 = 440 – 201 = 239 kJ/ mol
I.E3 = 700 – I.E1 – I.E2
= 700 – 201 – 239
= 260 kJ/ mol
IE3 – IE2 (X) = 260 – 239 = 21 kJ/mol

= =3

49) Apply : ΔG° = ΔH° – TΔS°

50) , ,

, ,

MATHEMATICS

51) For equal intercepts

m = –1

⇒ ⇒ k + 1 = 2k + 1 ⇒ k = 0
⇒ line is x + y = 0 which has zero intercepts.

52)

Perimeter = 3a =2

53)

=1
±3(1 + tan θ) = (tan θ + 1) (2tan θ + 1)
2

or 5tan2 θ + 3 tan θ + 4 = 0
⇒ imaginary roots

54)

55) Let circle be x2 + y2 + 2gx + 2fy + c = 0

for orthogonality
2(g.0 + f.0) = c – 1
2(g.4 + f.4) = c – 33
⇒ c = 1 and g + f = –4
56)
C : centre

57)

and θ is angle between the tangent and the diameter

58) Answer

59)
Let P(t12,2t1) and Q(t22, 2t2)

slope of chord
∴ t1 + t2 = 2 ...(1)
Equation of normal at P
y = –t1x + 2t1 + t13
equation of normal at Q
y = –t2x + 2t2 + t23
point of intersection of normals at P &Q
x = t12 + t22 + t1t2 + 2 ...(3)
y = –t1t2 (t1 + t2) ...(4)
using (1) y = –2t1t2 ...(2)
x = (t1 + t2)2 –2t1t2 + t1t2 + 2

x = (2)2 – t1t2+ 2 = 6 – t1t2 = 6

2x = 12 + y
2x – y – 12 = 0
it is satisfied by point (7,2)

60) The point lies on the given line whose slope is

Equation of line through A is

where r is the distance of any point from A in the direction of 60o.

It intersects the parabola

61)

Area =
6=4
So a + d = 14
62) Let a point on line y = mx is (α, mα) then equation of chord with given mid point (α, mα) is
T = S1
⇒ y(mα) – 8(x + α) = m2α2 – 16α
Passing through (2, 2)
2mα – 16 – 8α = m2α2 – 16α
⇒ m2α2 – (8 + 2m)α + 16 = 0,
For two chord D > 0
(8 + 2m)2 – 64m2 > 0
⇒ (8 + 2m + 8m) (8 + 2m – 8m) > 0
(10m + 8) (6m – 8) < 0

63)

Use

64) λ2 – λ – 6 > 0 ...(1)

λ – 6λ + 5 > 0 ...(2)
2

λ – λ – 6 ≠ λ – 6λ + 5 ...(3)
2 2

Intersection of (1), (2) & (3)

λ ∈ (–∞, –2) ∪ (5, ∞)

65) axsecθ – bycosecθ = a2 – b2

axsecθ – bycosecθ = –(a2 – b2)

∵ a2sec2θ + b2cosec2θ > (a + b)2

66) ∠ SBS'= 90°

⇒ m1m2 = –1
b2 = a2e2
67) A(0, –4), B(3, 0)
AB = 5, P(x, y)
PA – PB = 5

PA – PB = AB
⇒ A ray

68)
passes through (1, 2)
2 2
(2 – m) = 12m – 7
⇒ 11m2 + 4m – 11 = 0

m1m2 = –1 ⇒

69) ;
equation of chord of contact AB wrt P is T = 0
i.e ....(1)
Also, chord with given midpoint (h, k) is
T = S1
....(2)
comparing (1) and (2)

; as

locus is

70) and x2 + y2 = a2
⇒ x4 – a2x2 + c4 = 0
this equation has 4 roots x1,x2,x3 and x4
x1+ x2 + x3 + x4 = 0

71) ;

ae = 5
 ;

b=5

72) Since orthocentre and circumcentre both lies on y-axis

⇒ Centroid also lies on y-axis
⇒ Σcos α = 0
cos α + cos β + cos γ = 0
⇒ cos3α + cos3β + cos3γ = 3cosα cosβ cosγ

= 12

73) Assume (h, k) be the middle point of chord

∴ Its equation is

hx – ky = h2 – k2 ⇒

Now using , we get

⇒ x3 = y2(x – 5)
∴ a2 = 25

74) Question Explanation: Find the square of the radius of a fixed circle tangent to a
variable chord.
Concept: Homogenization of conic sections and properties of a hyperbola.
Solution: The equation of the lines joining the origin to the intersection points of a line and a
conic can be found by homogenization. For these lines to be perpendicular, the sum of the
coefficients of x2 and y2 must be zero. This gives a condition on the parameter of the line.
Let the variable chord be x cos α + y sin α = p which intersect the hyperbola in A and B
the joint equation of OA and OB is

Final Answer: 8.
 ⇒ p2 = 8
The variable line touches the fixed circle,
thus perpendicular distance of (0, 0) = Radius

∴ equation of the circle is x2 + y2 = 8.

75)

Required Area =