16-02-2025

1001CJA101004240018 JA

PART-1 : PHYSICS

SECTION-I (i)

1) In the given figure a steel wire is just held taut between fixed wall and a 3 kg block. If the wire is
cooled by a temperature ΔT, the 3 kg block is on the verge of moving. What is ΔT ?

(A) 1.25°C
(B) 8.5°C
(C) 3.75°C
(D) 11.5°C

2) Two motorcycles V and W starts from rest and move together for the same time interval. Their
acceleration–time graphs are as follows. Which of the following statement is incorrect?

(A) Both the motorcycle attain the same velocity after 10 second
(B) Both the motorcycle travel the same distance in 10 seconds
(C) The distance travelled by the motorcycle W is more than that of motorcycle V in first 5 seconds
(D) The velocity of motorcycle W is more than that of V just after 5 second

3) A block of mass m is pressed against a vertical surface by a spring of unstretched length ℓ. If the
coefficient of friction between the block and the surface is μ, choose the correct statement.
(A)
if spring constant is k = , block will not be in equilibrium.

(B)
if spring constant is k = , the normal reaction is .
(C) in the part (B) force of friction is 2mg.

(D)
minimum spring constant kmin to keep the block of mass M in equilibrium is .

4) A ball of mass m collides elastically with a plank moving with speed of 10 m/s on a rough
horizontal surface. The upper surface of the plank is smooth but the lower surface is rough with
coefficient of friction, µ = 0.1. The mass of the plank is also m. What is the speed of the plank just

after the collision? The speed of ball is 5 m/s.

(A) 9 m/s
(B) 8 m/s
(C) 9.5 m/s
(D) 10 m/s

SECTION-I (ii)

1) A cart of mass M, length L stands just at the end of a slope as shown in figure. A small block of
mass m is released from rest at height h and block slides on cart and comes to rest with respect to
cart at the edge of cart. Friction exists between cart and block and all the surfaces are smooth.

Coefficient of friction is µ :-

(A)
Time for which block moves on cart is .
(B) Net work done by kinetic friction is –µmgL.

(C)
Final velocity of centre of mass of block and cart is .
(D)
Net impulse on cart is .

2) A cyclic process ABCD is shown in the P–V diagram. (BC and DA are isothermal)

Which of the following curves represent(s) the same process?

(A)

(B)

(C)

(D)

3) A disc of mass m and radius R is rolling on a rough surface encounters a movable wedge of
sufficient height as shown in figure. There is no friction between wedge and ground and also

between disc and wedge then :-

(A)
Maximum height attained by the disc centre is
(B) Velocity of wedge when disc reaches maximum height is (v/2)
(C) Angular velocity of disc at maximum height will be zero
(D) Velocity of disc at maximum height will be zero

SECTION-I (iii)
1) The initial condition of a circular body is given in List-I and final condition is given is List-
II. Match the List.

List-I List-II
(Initially) (When pure rolling begins)

(P) (1) vcm is towards left in case of ring.

(Q) (2) vcm is towards left in case of solid sphere.

(R) (3) vcm is towards right in case of ring.

(S) (4) vcm is towards right in case of solid sphere.

(5) None of these

(A) P → 1;Q → 2;R → 2;S → 3
(B) P → 1;Q → 3;R → 1;S → 2
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 1;Q → 4;R → 2;S → 3

2) Match the List where symbols have their usual meaning :—

List-I (Quantity) List-II (Unit)

(P) Energy density (Energy per unit volume) (1) Dyne/cm2

Force constant k of a spring

(Q) (2) kg m–1s–1
(F = kx ; F is force and x is extension)

(R) Power (3) Erg/cm2

(S) Coefficient of viscosity η (F = 6πηrv) (4) kg m2s–3

(5) kg m–2s–1
(A) P → 1;Q → 3;R → 4;S → 2
(B) P → 1;Q → 4;R → 3;S → 2
(C) P → 1;Q → 4;R → 1;S → 3
(D) P → 1;Q → 5 ;R → 2;S → 3

3) Acceleration versus x and potential energy versus x graph of a particle of mass 1 kg moving along
x-axis are shown in figure. Assume that at x = 0, the velocity of the particle is 4 ms–1, match the

following at x = 8 m.

List-I List-II

(P) Kinetic energy (1) 120 J

(Q) Work done by conservative force (2) 240 J

(R) Total work done (3) 128 J

(S) Work done by external forces (4) 112 J

(5) None
(A) P → 5;Q → 2;R → 5;S → 5
(B) P → 2;Q → 5;R → 1;S → 3
(C) P → 3;Q → 1;R → 4;S → 5
(D) P → 2;Q → 3;R → 5;S → 4

4) Four rods of material X and three rods of material Y are connected as shown in figure. All the rods
are of identical lengths and cross–sectional area. Given thermal resistance of rod of material X is, Rx
= R and thermal conductivities of materials are related by relation KY = 2KX.

List–I List–II

Thermal resistance between B

(P) (1)
and E

Thermal resistance between A

(Q) (2)
and F

(R) Temperature of junction B (in °C) (3)

(S) Temperature of junction D (in °C) (4)

(5)

(A) P → 3;Q → 4;R → 1;S → 2

(B) P → 4;Q → 1;R → 2;S → 3
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 4;Q → 1;R → 3;S → 2

SECTION-II

1) A small ball of mass m = 10 gm hangs from a light rod of length 10 cm. An identical ball projected
from ground strikes the hanging ball and sticks to it. Collision takes place at height of 5m while
projected ball is tavelling horizontally. After collision the combined mass just rotates to vertical
position. Assume that plane of projectile motion and circular motion is same. If velocity of ball is

expressed as , give the value of .

2) A semi-circular disc is at rest as shown in the figure. There is no friction between disc and wall.
Coefficient of friction between disc and floor is µ. Minimum value of µ so that disc remains at rest is

0 0

µ . Value of 3πµ is

3) A metal is heated in a furnace where a sensor is kept above the metal surface to read the power
radiated (P) by the metal. The sensor has a scale that displays log2(P/P0), where P0 is a constant.
When the metal surface is at a temperature of 487°C, the sensor shows a value 1. Assume that the
emissivity of the metallic surface remains constant. What is the value displayed by the sensor when
the temperature of the metal surface is raised to 2767°C?

4) A clock pendulum made of invar has a period of 0.5 sec at 20°C. If the clock is used in a climate
where average temperature is 30°C, approximately, how much fast or slow will the clock run in 106
sec ? (αinvar=1×10–6/°C)

5) Two soap bubbles A and B are kept in a closed chamber where the air is maintained at pressure 8
N/m2. The radii of bubbles A and B are 2 cm and 4 cm, respectively. Surface tension of the soap-

water used to make bubbles is 0.04 N/m. Find the ratio , where nA and nB are the number of moles
of air in bubbles A and B, respectively. (Neglect the effect of gravity.)

6) For the arrangement shown in the figure, the time interval in seconds after which the water jet
ceases to cross the wall is found to be (α)3 sec. Area of the cross section of the tank
is and area of the orifice is a = 32 cm2. [Assume that the container remaining fixed]. Find the value

of α. (Take g = 10 m/s2)

PART-2 : CHEMISTRY

SECTION-I (i)

1) Correct order of extent of overlapping is :-

(A) 2s – 2s > 2p – 2p > 2s – 2p

(B) 1s – 1s > 2p – 2p > 2s – 2p
(C) 1s – 1s < 2s – 2s < 3s – 3s
(D) 3s – 3s > 3s – 3p > 3p – 3p

2) The hybridization and geometry of BrF3 molecule is -

(A) sp3d and Bent T-shaped

(B) sp3d2 and tetragonal
(C) sp3d and bent
(D) None of these

3) Difference in wavelength of two extreme spectral lines of H-atom in Balmer region is: (Where RH
is Rydberg constant)

(A) 7.2 / RH
(B) 0.25 / RH
(C) 4 / RH
(D) 3.2 / RH

4) The absolute configuration of the two chiral center in the following molecule are –
(A) 2–R, 3–S
(B) 2–R, 3–R
(C) 2–S, 3–S
(D) 2–S, 3–R

SECTION-I (ii)

1) How many of the following has /have zero dipole moment

(A) C6H6
(B) CCl4
(C) H2
(D) HF

2) Which of the following pair represent correct order of acidic strength :

(A)

(B)

(C)

(D)

3) Select the correct option(s)

(A)

(bond length)

(B)

(% enol content)
(C)

(Rotational energy barrier)

(D)

(Basic strength)

SECTION-I (iii)

1)

Match the list:

List- I (species) List- II (Properties)

Positive electron gain

(P) Be → Be– (1)
enthalpy

Negative electron gain

(Q) O– → O–2 (2)
enthalpy

(R) F → F– (3) Endothermic

(S) Cl → Cl– (4) Exothermic

Most negative electron

(5)
gain enthalpy
The correct option is
(A) P → 1;Q → 4;R → 1;S → 3
(B) P → 1;Q → 2;R → 1;S → 3
(C) P → 1;Q → 3;R → 3;S → 4
(D) P → 1;Q → 3;R → 4;S → 5

2) Match the type of interaction in List I with the distance dependence of their interaction energy in
List II :

List-I List-II

(P) ion - ion (1)

(Q) dipole - dipole (2)

(R) London dispersion (3)

(S) dipole-induced dipole (4)

 (5)

(A) P → 2;Q → 3;R → 1;S → 4

(B) P → 4;Q → 3;R → 1;S → 2
(C) P → 1;Q → 3;R → 4;S → 4
(D) P → 1;Q → 2;R → 4;S → 3

3) Match the List

List-I List-II

(P) 20 V H2O2 (1) 2.5 M

(Q) 24.5 % w/v H2SO4 (2) 1.76 M

(R) Pure water at 4oC (3) 1.5 M

5% w/w NaOH (dsolution= 1.2

(S) (4) 55.5 M
gm/ml)

(5) 1.32 m
The correct option is :-
(A) P → 2;Q → 1;R → 4;S → 3
(B) P → 2;Q → 3;R → 4;S → 5
(C) P → 1;Q → 5;R → 2;S → 3
(D) P → 4;Q → 3;R → 5;S → 2

4) Match the list :-

List-I List-II

(P) (1) Plane of symmetry

(Q) (2) Centre of symmetry

(R) (3) C2-Axis of symmetry

(S) (4) Chiral molecule

(5) Can show geometrical isomerism

(A) P → 1,5;Q → 3,4,5;R → 1,2,3,5;S → 1,3,5
(B) P → 1,5;Q → 3,4,5;R → 1,3,5;S → 3,4
(C) P → 1,5;Q → 1,4,5;R → 1,2;S → 3,5
(D) P → 1,5;Q → 3,4,5;R → 3,5;S → 3,4

SECTION-II

1) How many unpaired electrons are present in Co3+ ion ?

2) For a reaction : . Initially 10 moles of A and 25 moles of B are present. At

equilibrium, 12 moles of C is present. Find the value of at equilibrium, if the volume of

container = 1 litre.

3) In the reaction : xBrO3– + yCr3+ + zH2O → Br2 + HCrO4– + H+, the sum of value of coefficients x, y
and z is :-

4) A gas (X) effuses twice as fast as SO2 gas under similar condition. The molar mass of gas (X) (in
gm mol–1) will be

5) How many of the following can show geometrical isomerism?

(i) (ii) (iii)

(iv) (v) (vi)

(vii) HN = NH (viii) (ix)

6)

How many compounds are optically active.

(i) (ii) (iii) (iv)

(v) (vi) (vii)

PART-3 : MATHEMATICS

SECTION-I (i)

1) The number of ways of selection of 4 letters of the word 'PERFECT " is

(A) 15
(B) 21
(C) 25
(D) 31

2)

If , then is equal to-

(A)

(B)

(C)

(D)

3) The number of ways in which the letters of the word ' LONDON' can be rearranged if the two 'O' s
are together but the two 'N's are seperated is

(A) 72
(B) 71
(C) 36
(D) 35

4)

In the expansion of then coefficient of x–7 and x–8 are equal then n is :

2
(A) One of the root of equation log2(x – 109) = 2log2(54)
(B) A prime number
(C) Greater than 80
(D) An even number

SECTION-I (ii)

1) Let the eccentricity of the hyperbola be reciprocal to that of the ellipse x2 + 4y2 = 4. If
the hyperbola passes through a focus of the ellipse, then -

the equation of the hyperbola is

(A)

(B) a focus of the hyperbola is (2, 0)

(C)
the eccentricity of the hyperbola is
(D) the equation of the hyperbola is x2 – 3y2 = 3

2) The sum of the first two terms of a geometric progression is 15. The first term exceeds the

common ratio of the progression by . The fourth term of the progression is :

(A)

(B)

(C)

(D)

3)

Let α and β be the roots of x2 – x – 1 = 0, with α > β. For all positive integers n, define

b1 = 1 and bn = an–1 + an+1,

Then which of the following options is/are correct ?
(A) a1 + a2 + a3 + ..... + an = an+2 – 1 for all n 1

(B)

(C)

n n
(D) bn = α + β for all n 1

SECTION-I (iii)

1)

List-I List-II

(P) Value of (1 + tan18°) (1 + tan27°) is (1) 0

Total number of solution(s) of sinx = log35

(Q) (2) 1
if x ∈ [0, 2π] is/are

(R) (3) 2
The value of is

(S) If y = x2 – 4x + 8, then minimum value of y is (4) 4

(5) 5
(A) P → 3;Q → 3;R → 4;S → 5
(B) P → 3;Q → 1;R → 2;S → 4
(C) P → 5;Q → 4;R → 1;S → 2
(D) P → 1;Q → 2;R → 3;S → 4

2) Consider the word "BREAKAGE". The number of ways in which the letters of this word can be
arranged such that

List-I List-II

(P) The two A's are not together is (1) 720

(Q) The two E's are together but no two A's are together is (2) 1800

(R) Neither two A's nor two E's are together is (3) 5760

(S) No two vowels are together is (4) 7560

(5) 5050
(A) P → 4;Q → 2;R → 3;S → 1
(B) P → 2;Q → 4;R → 1;S → 3
(C) P → 3;Q → 2;R → 3;S → 4
(D) P → 4;Q → 3;R → 2;S → 1

3) Consider an ellipse with major & minor axis having length 4 & respectively. Let P be any
variable point on it. S & S' be the foci and C be the centre of ellipse Match List-I with List-II and
select the correct answer using the code given below the list.

List-I List-II
(P) Maximum value of [Link]' is (1) 8
2 2
(Q) Minimum value of (PS) + (PS') is (2)
Minimum length of portion of tangent at P
(R) (3) 4
intercepted between principal axes is
If foot of normal from P on major axis is P'
(S) (4)
and normal at P cuts transverse axis at N, then
is
(5) 5
(A) P → 3;Q → 1;R → 2;S → 4
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 3;Q → 2;R → 4;S → 1

4) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

Let and Ai, Bi, Ci are co-factor of ai, bi, ci

(P) (1) 1

respectively and then is

If x > 0 such that

(Q) (2) 2
then x is

Number of solution(s) of the equation

(R) (3) 3
sinx + cosx – 1 = sin2x – 2 is [0, 3π] is

(S) (4) 4
Minimum value of is

(5) 7
(A) P → 1;Q → 3;R → 2;S → 5
(B) P → 2;Q → 5;R → 4;S → 1
(C) P → 1;Q → 5;R → 3;S → 1
(D) P → 2;Q → 4;R → 3;S → 1

SECTION-II
1) A light ray emits from the origin making an angle 45° with the positive x-axis in anticlockwise
direction. After getting reflected by the line y = 5, if this ray intersected x-axis at Q, then the
abscissa of Q is

2) If the circles x2 + y2 + 10x + 8y + 8 = 0 and x2 + y2 + 14x + 16y + c = 0 are orthogonal to each

other then value of c will be.

3) If then the value of is :

4) The coefficient of x40 in the product (1 + x)(1 – x)10 (1 + x + x2 + x3 + x4)9 is :

5) If the normal at P(18, 12) to the parabola y2 = 8x cuts it again at Q. Find

6) If real numbers a, b, c, d, e satisfy a + 2 = b + 5 = c + 6 = d + 7 = e + 1 = a + b+ c + d + e + 5

then find sum of digits of (a2 + b2 + c2 + d2 + e2).
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. C B D A

SECTION-I (ii)

Q. 5 6 7
A. A,C,D A,B A,B

SECTION-I (iii)

Q. 8 9 10 11
A. A A A C

SECTION-II

Q. 12 13 14 15 16 17
A. 2 2 9 5 6 5

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. B A D B

SECTION-I (ii)

Q. 22 23 24
A. A,B,C A,B,D A,C,D

SECTION-I (iii)

Q. 25 26 27 28
A. D C A A

SECTION-II

Q. 29 30 31 32 33 34
A. 4 10 38 16 5 4

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. C C C A

SECTION-I (ii)

Q. 39 40 41
A. B,D A,B A,B,D

SECTION-I (iii)

Q. 42 43 44 45
A. B A A C

SECTION-II

Q. 46 47 48 49 50 51
A. 10 126 1 9 80 9
 SOLUTIONS

PART-1 : PHYSICS

1) µmg = YAαΔT

4) JNormal = m(5 + 5) = 10m

For plank, Jfriction = ΔP
–µJNormal = mv – m × 10
–0.1 × 10m = mv – 10m
v = 9 m/s

5)

0=

t=

Impulse = Mvf – M × 0 = Mm

6)

A → B constant pressure B→C T = constant

C → D constant Volume D→A T = constant
∴ clearly, option A and B are constant

7) mv = 2mvx

= vx

2m(vx)2 + mgh = mv2

mgh = mv2 – 2m ×

8) (A) VCM is towards left for any rolling body.

(B)

K2 = R2 for ring ⇒ VCM = +ve towards right

for sphere VCM = –ve towards left

(C) For any rolling body VCM is towards left.

(D) for both VCM = –ve

9) (A) Energy density = Energy/volume

= Dyne × cm/cm3 = Dyne/cm2
Energy density = Joule/m3 = N × m/m3
= N/m2 = Pascal
(B) K = F/Δl = Dyne/cm = Dyne × cm/(cm × cm)
= Erg/cm2

(D) F = 6πηrv ⇒

11)

For (A)

No heat current flows through rod CD so

For (B)

For (C) Total heat current form A to F, I =

let temperature of B be TB then ⇒ °C

For (D) As heat current is inversely proportional to heat resistance
so heat current in BD = I= I

°C

12)

Velocity after collision to complete circular motion

= 2m/s
Velocity before collision = 2 × 2 = 4m/s
Initial velocity along y direction = = 10 m/s
Hence

So require value =

13)
N1R = mg(BC)sinθ

f2 = N1 ≤ µN2

3πµ0 = 2

14)

P = eAσT4 where T is in kelvin

...(i)

...(ii)
(ii) – (i)

∴x=9
 15) 5 sec. slow

T=

16)

Pressure in bubble – A

also

17)
For minimum velocity at orifice

⇒ ⇒
This will give us minimum height for this velocity

⇒ ⇒
ν1 = and v2 = – dh/dt
By equation of continuity av1=Av2
⇒ t = 125 sec = (5)3 = (α)3 ⇒ α = 5

PART-2 : CHEMISTRY

20)
λ – λ' =

25)

(P) Be → Be–
EC = ns2 (fully filled)
ΔH = +ve (Endothermic)
(P) → 1, 3
(Q) O– → O–2
Here, second Electron gain enthalpy is always positive or endothermic.
(Q) → 1, 3
(R) F → F–
Electron gain enthalpy = –ve (exothermic)
R → 2, 4
(S) Cl → Cl–
Electron gain enthalpy = –ve (Exothermic)
It has the highest electron gain enthalpy in periodic table.
S → 2, 4, 5

30) A + 5B 6C [A] = 8
10 25 0 [B] = 15
10-x 25-5x 6x [C] = 12

31)

BrO3– → Br2 , n-factor = 5

Cr+3 → HCrO4–, n-factor = 3
∴ Molar ratio

BrO3– : Cr+3 = 3 : 5 (n-factor µ )

OR
6 : 10
Charge balancing
6BrO3– + 10Cr+3 + 22H2O → 3Br2 + 10HCrO4– + 34H+
∴ x = 6, y = 10, z = 22
x + y + z ⇒ 6 + 10 + 22 = 38

33) (ii), (iv), (vi), (vii), (ix)

34)
 i, v, vi, vii

PART-3 : MATHEMATICS

35)

2 Alike + 2 different =
All 4 different =

∴ Total = 25

36)

Tn = Sn – Sn–1 = (5n–1) – (5n–1 –1)

= 5n–1.(5–1)=4.5n–1

37)
Number of ways =

38)

n n–r
Tr+1 = Cr (2)
x–r = x–7 ⇒ r = 7 or x–r = x–8 ⇒ r = 8

n
C7(2)n–7 = nC8 (2)n–8
⇒ n = 55

39)

Given hyperbola is

ellipse is

eccentricity of ellipse =

eccentricity of hyperbola =
⇒ ⇒ 3b2 = a2 ...(1)
also hyperbola passes through foci of ellipse

⇒ a2 = 3 ...(2)
from (1) & (2)
b2 = 1

equation of hyperbola is
⇒ x2 – 3y2 = 3

eccentricity of hyperbola

focus of hyperbola =

40) a + ar = 15 ....(1)

a–r= ....(2)

a = 9,

41)

α, β are roots of x2 – x –1

ar+2 – ar

= ar+1
⇒ ar+2 – ar+1 = ar

Now
Further, bn = an–1 + an+1

(as αβ = –1 ⇒ αn–1 = –αnβ & βn–1 = –αβn)

= αn + βn

42)

(P) 18º + 27º = 45º ⇒ (1 + tan18º) (1 + tan27º) = 2

(Q) sinx < 1 and log35 > 1 ⇒ No solution

(R)
(S) y = x2 – 4x + 8 = (x – 2)2 + 4
ymin = 4

43) (P) Arrange A's in gaps ∴

(Q) Arrange and then two A's in gaps.
∴
(R) Ans.(P) – Ans.(Q) = 7560 – 1800 = 5760
(S) Arrange B, R, K, G and vowels in gaps

44) PS + PS' = 4 (P)

(Q)
PS2 + PS'2 ≥ 8
(R) Minimum length of tangent = a + b

(S)

y=0⇒
45) (P) Δ` = Δ2 ⇒ (Q)

⇒x=7
(R) (sinx + cosx) – 1 = (sinx + cosx)2 – 1 – 2
sinx + cosx = t ⇒ t2 – t – 2 = 0
t = 2 or t = –1
sinx + cosx = 2 is rejected &
sinx + cosx = –1
⇒ sinx = –1 or cosx = –1

, x = π, 3π
total solutions are 3

(S) (A.M. ≥ G.M.)

multiply all of them

46) Equation OP y = x
Point P y=5
x=5
P(5,5)
Equation PQ m = tan135° = –1
y – 5 = –1(x – 5)
y + x = 10
y=0 x = 10

47) 2 (g1g2 + f1f2) = c1 + c2

⇒ 2 (5 × 7 + 4 × 8) = 8 + c ⇒ 2 (35 + 32) = 8 + c
⇒ 134 = 8 + c ⇒ c = 126

48)
⇒

49) (1 + x)(1 – x)(1 – x)9 (1 + x + x2 + x3 + x4)9

= (1 – x2)(1 – x5)9
coff. of x40 = coeff. of x40 in (1 – x5)9
= 9C8

50) ∵ at12 = 8 & 2at1 = 12

t12 = 9 t1 = 3

∵ t2 = –t1 –

⇒ t2 = –3 – ⇒ t2 =

∴ Q(at22, 2at2) ≡

⇒ ⇒

51) a + 2 = k
a=k–2
b=k–5
c=k–6
d=k–7
e=k–1
a + b + c + d + e + 5 = 5k – 16 = a + 2
5k – 16 = k
4k = 16
k=4
a = 2 c = –2
d=3
b = – 1 d = –3
a2 + b2 + c2 + d2 + e2 = 27
sum of digits = 9