02-08-2025
7001CJA101021250017 JA
PART-1 : PHYSICS
Seaction-I(i)
1) A conducting wire fixed at both end is vibrating in it's fundamental mode in the plane of paper. A
constant magnetic field (B) is switched on as shown. Find the emf induced in wire at an instant it is
passing through mean position. Here a is maximum amplitude, ω is angular frequency of wave of
which standing wave is formed and length of wire is l .
(A)
(B)
(C)
(D)
2) The arm PQ of a rectangular conductor is moving from x = 0 to x = 2b outwards and then inwards
from x = 2b to x = 0 as shown in the figure. A uniform magnetic field perpendicular to the plane is
acting from x = 0 to x = b. Identify the graph showing the variation of different quantities with
distance:
(A) A-Flux, B-Power dissipated, C-EMF
(B) A-Power dissipated, B-Flux, C-EMF
(C) A-Flux, B-EMF, C-Power dissipated
(D) A-EMF, B-Power dissipated, C-Flux
3) A ring of circular cross section is made of material of resistivity ‘ρ’. The inner and outer radii of
ring are a and 2a respectively and its thickness is ‘h’. The ring is placed in a time varying magnetic
field B = kt (where k is a constant) which is parallel to the axis of the ring as shown in the figure.
The induced current in the ring is.
(A)
(B)
(C)
(D)
4) Two conducting rings of radii r and 2r move in opposite direction with velocity as shown on a
conducting surface. There is a uniform magnetic field of magnitude B, perpendicular to plane of
ring. The potential difference between the highest point of two rings is :-
(A) zero
(B) 2rvB
(C) 4rvB
(D) 8rvB
Seaction-I(ii)
1) In a region there exists a magnetic field B0 along positive x-axis. A metallic wire of length 2a and
one side along x-axis and one side parallel to y-axis is rotating about y-axis with an angular velocity
ω. Then at the instant shown.
(A) Potential difference across PQ is zero.
(B)
Potential difference across PQ is
(C)
Potential difference across QR is
(D) Potential difference across QR is
2) You are given a bar magnet and a coil of wire. Which of the following would induce an emf in the
coil ?
(A) Moving the magnet toward the coil.
(B) Moving the coil away from the magnet.
(C) Turning the coil about a vertical axis.
(D) none of these
3) A circular conducting loop of radius R and resistance per unit length λ is pulled out from the
region of uniform magnetic field with constant velocity v. The situation shown in the figure
corresponds to time t = 0. Mark out the correct statement(s)
Just after t = 0 i.e., the motion starts, the induced current in the loop is
(A)
(B)
Current will be induced in the loop for
(C) At any time t, the current induced in the loop is given by and is in
clockwise direction.
(D) Induced current is in clockwise direction for t = 0 to and thereafter it becomes in
anticlockwise direction.
Section-II(i)
Common Content for Question No. 1 to 2
Figure shows a conducting rod of negligible resistance that can slide on smooth U-shaped rails made
of wire of resistance 1Ω/m. Position of the conducting rod at t = 0 is shown. A time t dependent
magnetic field B = 2t Tesla is switched on at t = 0.
1) At t = 0, when the magnetic field is switched on, the conducting rod is moved to the left at
constant speed 5 cm/s by some external means. The rod moves perpendicular to the rails. At t = 2s,
induced emf has magnitude in Volts :
2) Following situation of the previous question, the magnitude of the force required to move the
conducting rod at constant speed 5 cm/s at t = 5s, is equal to(in Newton)
Common Content for Question No. 3 to 4
Two infinitely long solenoids (seen in cross section) pass through a circuit as shown in Figure. The
magnitude of inside each is the same and is increasing at the rate of 100 T/s.
3) What is the current (in A) in the middle 3Ω resistor ?
4) What is the magnitude of induced emf in the left loop (in V) ?
Section-II(ii)
1) A uniform disc of radius r and mass m is charged uniformly with the charge q. This disc is placed
flat on a rough horizontal surface having coefficient of friction µ. A uniform magnetic field is present
in a circular region (a > r) but varying as kt3 as shown in figure. Find the time in second after which
the disc begins to rotate.
(Given r = 1 m, m = 18 kg, q = 1C, µ = 0.1m, K = 4, g = 10 m/s2)
2) A uniform magnetic field of intensity B = sin 2t directed into the plane of the paper exists in the
cylindrical region of radius 1 m. A loop of resistance 10Ω folded in the form of equilateral triangle of
side length 2m is placed as shown in figure. Find the maximum potential drop in wire AB.
3) A resistance R = 1kΩ is connected to a conducting rod PQ that can slide on conducting circular
ring of radius 2m with center at P. The rod is hinged at the center of circular loop so that it can
freely rotate about an axis perpendicular to plane of ring. A constant uniform magnetic field 10 Tesla
exist as shown in figure. At t = 0, switch 'S' is closed and simultaneously an external toque is applied
on the rod so that it rotates with constant angular velocity 20 rad/sec. The magnitude of power (in
watt) delivered by external agent is N. Find N (Neglect the gravity, friction and self inductance of
circular loop)
4) A uniform magnetic filed T exists in a circular region of radius R = 5 m. A loop of radius
R = 5 m encloses the magnetic filed at t = 0 and then pulled at uniform speed v = 2 m/s in the plane
of the paper. Find the induced emf (in V) in the loop at time t = 3s
5) A small conducting square loop of side length d = 10 cm, is at height h above the boundary of a
region of uniform magnetic field B0 = 1T (into the plane of the paper as shown in figure). The mass
of the square loop is m = 100 gram and resistance R = 0.1 Ω. The loop is dropped from such position
and after some time it enters the magnetic field region. Find the height 'h' in metre so that velocity
of the loop will remain constant during the time interval the loop will be entering into the magnetic
field region (g = 10 m/s2)
6)
PART-2 : CHEMISTRY
Seaction-I(i)
1) Which of the following obey Sidgwick EAN rule ?
(A) Wilkinson catalyst
(B) cis-platin
(C) Brown ring complex
(D) Prussian blue
2) Identify the homoleptic complex(es) that is/are low spin.
(A) [Fe(CN)5NO]2– (B) [CoF6] 3–
(C) [Fe(CN)6] 4– (D) [Co(NH3)6] 3+
(E) [Cr(H2O)6] 2+
Choose the correct answer from the options given below :
(A) (B) and (E) only
(B) (A) and (C) only
(C) (C) and (D) only
(D) (C) only
3) The ether on heating with concentrated HI produces-
(A)
(B)
(C)
(D)
4) C, C is
(A)
(B)
(C)
(D)
Seaction-I(ii)
1) Which of the following statement(s) is/are correct for Na3[Co(ONO)6]?
(A) It’s aqueous solution is slightly basic in nature.
(B) It’s IUPAC name is sodium hexanitrito cobaltate(III)
(C) It is called sodium cobaltinitrite
(D) One molecule of it forms three ions in water.
2) Which combination of reagents will not bring about the following conversion ?
⊕
(A) MeMgBr/H , H2SO4/Δ, HBr/H2O2, hv
⊕
(B) MeMgBr/H , H2SO4/Δ, HBr
⊕
(C) MeMgBr/H , HBr/CCl4
(D) MeMgBr, NH4Br
3) Select reaction(s) with incorrect major product
(A)
(B)
(C)
(D)
Section-II(i)
Common Content for Question No. 1 to 2
Two complexes of Cobalt have same molecular formula Co(NH3)3(H2O)2ClBr2. 34.15 gm of (A) loses
1.8 gm of weight when heated to 200°C whereas no weight loss was observed on similar treatment
with (B).
An aqueous solution of (A) has conductivity equivalent to that of a compound with two ions per
formula unit while conductivity of (B) in aqueous solution is equivalent to a compound with (X)
number ions per unit. Also a 100 ml 0.1 M aq. solution of (A), on treatment with excess of AgNO3.
Solution produce (Y) gm of only yellow ppt while a 100 ml 0.1 M aqueous solution of (B) on
treatment with excess of AgNO3 solution product 3.315 gm precipitate.
(Atomic mass : Ag = 107.8 , Br = 80 , Cl = 35.5)
1) the value of (X) is :
2) The value of Y is :
Common Content for Question No. 3 to 4
Lucas reagent is used to differentiate different type of alcohols.
(a) (b) (c) CH2=CH-CH2OH
(d) Me3C–OH (e) (f) CH3OH
(g) (h) CH3CH2OH (i)
3) How many compound when react with Lucas reagent it gives instant turbidity?
4) How many compound when undergo dehydration with conc. H2SO4, it gives more than one alkene?
Section-II(ii)
1) How many unpaired electrons are present in [Fe(H2O)5NO]SO4 complex ?
2) Estimate the numbers for the central metal ion:
(A) Oxidation state in [Mn(H2O)6]SO4 = x
(B) d-orbital occupation in cis-[Cr(en)2 Cl2]Cl = y (If d8 then y = 8]
(C) Co-ordination number in K3[FeCl6] = z
(D) Spin multiplicity in Cs[FeCl4] = t
Hence, find the value of z – (x + y) + t
3) Find the number of moles of anions present in resultant solution, when 1mole of
Diamminediaquadipyridineiron(III) sulphate is added in 0.5 M , 4litre of BaCl2 (aq) solution.
4)
What is the value of (X + Y)?
5) Reaction - I :
Reaction - II :
Reaction - III :
Value of x + y + z is :
6) The number of hydroxyl group(s) in Q is
PART-3 : MATHEMATICS
Seaction-I(i)
1) If a,b,c are any real numbers, then which of the following is always correct ?
(A) max(a,b) < max (a,b,c)
min(a,b)
(B)
(C) max (a,b) < min (a,b,c)
min(a,b)
(D)
2) Points L and M are on the curve 14x2 – 7xy + y2 = 2, each have x co-ordinate '1', point of
intersection of tangent at L and M is (h,k), then k equals to -
(A) 1
(B) 0
(C) 4
(D) don't intersect
3) If ƒ"(x) > 0; ∀ x ∈ [–3, 4] then which of following is false
(A) ƒ(x) must have a minimum in (–3, 4)
(B) ƒ(x) has a minimum in [–3, 4]
(C) ƒ(x) has a maximum in [–3, 4]
(D) ƒ(x) is concave upwards
4) The maximum value of is equal to
(A) 2
(B) –1
(C) 0
(D) 1
Seaction-I(ii)
1) Let , then identify the correct statement(s)-
(A) x = 0 is point of local maxima of ƒ(x) for α < 1
(B) x = 2 is point of local minima of ƒ(x) for α > 1
(C) ƒ(x) is increasing at x = 0 for α > 1
(D) ƒ(x) is increasing at x = 2 for α < 1
2) Let f be a function such that for all x ≥ 1, f "(x) + f '(x) ≥ 2 and f '(1) = 2, f(1) = 3 then
(A) f '(x) ≥ 2 ∀ x ≥ 1
(B) f(2) ≥ 5
(C) f(2) ≥ 6
(D) f(3) ≥ 8
3) If
(A) f (x) is decreasing in the given interval
(B) f (x) is increasing in the given interval
(C) Number of local extremum for f (x) in the given interval is 1
(D) If g is inverse of f, then g"(0) is 0
Section-II(i)
Common Content for Question No. 1 to 2
Let f (x) be a monic cubic polynomial such that and . Suppose
for which conclusion of Rolle’s theorem in [a,b] holds at x
= 2, where
1) The value of is
2) The value of definite integral is (where λ & µ are relatively prime numbers), then λ –
5μ is equal to:
Common Content for Question No. 3 to 4
A function f(x) having the following properties:
(i) f(x) is continuous except at x = 3
(ii) f(x) is differentiable except at x = –2 and x = 3
(iii)
(iv) and
(v) and
3) The maximum possible number of solutions of f(x) = |x|, is(are)
4) If , the graph of function is non-differentiable at
Section-II(ii)
1) Let f(x) = . If least value of k for which is defined for all
is λ, then [λ] (where [.] is G.I.F).
2) Let ƒ(x) be a non-constant twice derivable function on R such that ƒ(2 + x) = ƒ(2 – x) and
, then the minimum number of roots of the equation ƒ"(x) = 0 ; is(are)
3) Let function ƒ : R → R defined by . If ƒ(x) is
strictly increasing function for ∀ x ∈ R, then sum of integral value(s) of b is :-
4) Let x intercept of tangent to curve y = ex, which is parallel to x – 4y = 1 is k, then value of [–k] is :-
(Where [.] is G.I.F.)
5) The sum of all the integral value(s) of 'k' so that curve x4 + 3kx3 + 6x2 + 5 is not situated below
any of its tangent lines is -
6) If m is the slope of a line which is tangent to y3 = x4 & a normal to x2 – 2x + y2 = 0, then is
equal to (m ≠ 0)
ANSWER KEYS
PART-1 : PHYSICS
Seaction-I(i)
Q. 1 2 3 4
A. D C A D
Seaction-I(ii)
Q. 5 6 7
A. A,D A,B,C A,B
Section-II(i)
Q. 8 9 10 11
A. 0.08 0.16 1.22 3.14
Section-II(ii)
Q. 12 13 14 15 16 17
A. 2.00 2.00 160 8.00 5.00 1.73
PART-2 : CHEMISTRY
Seaction-I(i)
Q. 18 19 20 21
A. D C C B
Seaction-I(ii)
Q. 22 23 24
A. A,B,C B,C,D A,B,C,D
Section-II(i)
Q. 25 26 27 28
A. 3.00 1.88 5.00 1.00
Section-II(ii)
Q. 29 30 31 32 33 34
A. 3.00 7.00 5.00 3.00 8.00 4.00
PART-3 : MATHEMATICS
Seaction-I(i)
Q. 35 36 37 38
A. B C A D
Seaction-I(ii)
Q. 39 40 41
A. A,B,C,D A,B A,D
Section-II(i)
Q. 42 43 44 45
A. 6.00 1.00 3.00 2.00
Section-II(ii)
Q. 46 47 48 49 50 51
A. 5.00 4.00 0.00 2.00 0.00 4.00
SOLUTIONS
PART-1 : PHYSICS
1) Consider a small element of length dx at a distance x from left end.
Motional emf across this = vBdx
= aBw sin kx dx
Total emf across wire =
2)
A-Flux, B-EMF, C-Power dissipated
3) The emf induced in a thin circular ring of radius ‘r’ is
4)
Replace the induced emf's in the ring by cells,
e1 = B(2r)2V = 4BrV
e2 = B(4r)V = 4BrV
∴ V2 – V1 = e2 + e1 = 8BrV
5)
Potential difference across PQ is zero.
Potential difference across QR is
6)
Moving the magnet toward the coil.
Moving the coil away from the magnet.
Turning the coil about a vertical axis.
7) differentiable w.r.t. x,
we get
m = 4ℓ
Put m = 4ℓ to get
By parts
m=1
8) ϕ = (0.4 – 0.05t) × 0.2 × 2t
E = (0.16 – 0.04t)
9) E = (0.16 – 0.04 × 5)
= – 0.04 V
F = Bil = 0.16 N
10)
Answer 1.22
11) = π × 0.12 × 100 = 3.14 V
12)
..........(i)
torque due to friction force
dτ = μdmgx
......(ii)
13)
Answer 2.00
14)
Induced emf current
Torque about
So, power
Alternate solution
Power = Heat loss in ressistance
15)
So
given R = 5m, v = 2 m/s, t = 3s
16) v2 = 2hg
mgv =
17)
Answer 1.73
PART-2 : CHEMISTRY
18) Wilkinson catalyst – [RhCl(PPh3)3] = 16e–
cis-platin – [PtCl2(NH3)2] = 16e–
Brown ring complex – [Fe(H2O)5NO]SO4
= 19e–
Prussian blue – Fe4[Fe(CN)6]3 = 18e¯
19)
20)
21)
22)
Na3 [Co(ONO)6] 3Na+ + [Co(ONO)6]3–
[Co(ONO)6]3– + H2O H[Co(ONO)6]2– + OH–
The IUPAC name of the ligand is nitrito.
23)
24)
Answer (A,B,C,D)
25)
Co(NH3)3 (H2O)2 Cl Br2 = M = 341.5 cm/mol
(A) [Co(NH3)3 (H2O) Cl Br] Br. H2O (2 ions in solution)
(100 ml, 0.1 M = 10 mmol)
AgBr (yellow ppt.)
0.01 mol
= 188×0.01 = 1.88 gm
(y)
(B) = [Co(NH3)3 (H2O)2 Br] Cl Br (3 ions in solution)
(0.01 mol) (x)
AgCl + AgBr
(0.01 mol) (0.01 mol)
= 1.435 + 1.88 = 3.315 gm
26)
Concept : Given molecular formula is Co(NH3)3 (H2O)2 ClBr2.
Two isomer (A) and (B) exist with same formula but different properties.
(A) loses weight upon heating at 200oC, meaning it contains co-ordinated water (H2O ligands).
(B) does not lose weight, meaning it does not have co-ordinated water.
(A) gives conductivity equivalent to 2 ions, meaning it dissociates into two species in solution.
(B) gives conductivity equivalent to X ions, which we need to determine.
Possible structures
For A
∵ A loses water upon heating, the H2O molecules are co-ordinated to Co. This means chloride
(Cl−) and bromide (Br−) are in the ionization sphere.
[Co(NH3)3(H2O) ClBr] Br or [Co(NH3)2(H2O)Br2]Cl
For B
∵ (B) doesnot lose weight upon heating, water is not co-ordinated
This means water is outside the co-ordination sphere and both Cl− and Br− are co-oridnated to
Co.
Possible formula:
[Co(NH3)3 Br2Cl]
∴ Total number of ions = 2
∴ X=2
Precipitation with AgNO3
(A) Contains Br− and Cl− as free ions.
Both Br− and Cl− react with AgNO3 to form AgBr (yellow ppt) and AgCl (white ppt)
However, the problem states that only yellow ppt is formed, meaning only AgBr is precipitated
This suggests that Cl− is in the co-ordination sphere, and Br− is free.
So the correct formula for A should be [Co (NH3)3 (H2O) ClBr] Br
It dissociates as
[Co(NH3)3 (H2O) ClBr] Br → [Co(NH3)3 (H2O) ClBr]+ + Br−
→ ∵ there is 1Br− per molecule the amount of AgBr precipitated is calculated as :
Moles of complex in 100 mL of 0.1 M solution = 0.01 moles
∵ each molecule gives 1 Br− ion, moles of Br− = 0.01
Mass of AgBr precipitates
→ Molar mass of AgBr = 107.8 + 80 = 187.8 g mol
→ Mass of precipitate (Y)
= 0.01 x 187.8 = 1.878 g
∵ y = 1.88 g (round off to 3 significant figures)
27)
b, c, d, e, i
28)
Answer 1.00
29) The oxidation state of Fe in the complex is +1. Thus, Fe+ has configuration 3d7. Thus, there
are three unpaired electron.
30) x = +2, y = 3, z = 6, t = 6
31) Formula of compound is [Fe(H2O)2(en)2(py)2]2 (SO4)3
moles of SO42– ions per mole of complex compound = 3
Moles of Ba+2 ions in 0.5 M , 4litre of BaCl2 (aq) solution = (0.5 ´ 4) = 2
SO42– + Ba+2 → BaSO4↓
3moles 2 moles 0
1 mole 0 mole 2 mole ; finally
moles of anions (SO42– and Cl– ) present in resultanant solution = 1 + 2 ´ 2 = 5
32)
Answer 3.00
33)
Answer 8.00
34)
Answer 4.00
PART-3 : MATHEMATICS
35)
36) x = 1
14 – 7y + y2 = 2
y2 – 7y + 12 = 0
y=4 y=3
28x – 7y – 7xy' + 7yy' = 0)(1,4)
Tangent y = 4
M2 = y')(1,3)
y – 3 = 7(x – 1)
37) Do yourself
38)
39)
40) is an increasing function of x.
So for x ≥ 1;
g(x) ≥ g(0)
ex(f '(x)–2) ≥ 0.
⇒ (f(x) – 2x) is increasing
⇒ f(x) – 2x ≥ f(1) – 2 = 1
⇒ f(x) ≥ 2x + 1, ∀ x ≥ 1.
41)
f'(x)
f'(x)
We having
⇒ g"(0) = 0 as f'(π/4) = 0
42)
Answer 6.00
43) we have, ______________(i)
Since, Rolle’s theorem is applicable to g (x) at x = 2.
So,
and
_______(ii)
from (i),
also, from (i) and (ii)
44)
Maximum possible number of solutions = 3
45) y = f(–|x|)
Clearly non-differentiable at 2 points.
46)
(a + b) = 7
47) ƒ(2 + x) = ƒ(2 – x)
ƒ'(2 + x) = –ƒ'(2 – x) .......(1)
put x = 0 in (1)
ƒ'(2) = –ƒ'(2) ⇒ ƒ'(2) = 0
put x = –1 in (1)
ƒ'(1) = –ƒ'(3) = 0
⇒ ƒ'(1) = ƒ'(3) = 0
put in (1)
⇒ ⇒
Now
⇒ = ƒ'(1) = ƒ '(2) = ƒ '(3) = =0
Hence, from Rolle's theorem, minimum 4 roots of ƒ "(x) = 0
48) ƒ'(x) = 6x2 + 2bx + 4 + cos2x
ƒ'(x) > 0 ∀ x ∈ R
Given :
⇒ 6x2 + 2bx + 4 + cos2x > 0
⇒ 6x2 + 2bx + 4 > 0
⇒ 3x2 + bx + 2 > 0, ∀ x ∈ R
put
D < 0, b2 – 24 < 0
b = 0, ±1, ±2, ±3, ±4
49)
Do yourself.
50) curve must be concave upwards so
Hence, 2x2 + 3kx + 2 > 0
D < 0 ⇒ 9k2 – 16 < 0
51) Let a point on y3 = x4 be (t3, t4)
3y2y' = 4x3
⇒ ⇒
Equation of tangent is
∵ it is a normal to x2 + y2 – 2x = 0
∴ it must pass through (1, 0)
⇒ ⇒
⇒ t3 = 4
Now m =
⇒