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Physics and Chemistry Problem Set

The document contains a series of physics, chemistry, and mathematics problems and questions, primarily focused on concepts such as forces, pressure, fluid dynamics, and chemical reactions. Each section presents multiple-choice questions that require application of scientific principles and mathematical reasoning. The problems are structured for an academic examination setting, likely aimed at students preparing for competitive exams.
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0% found this document useful (0 votes)
13 views27 pages

Physics and Chemistry Problem Set

The document contains a series of physics, chemistry, and mathematics problems and questions, primarily focused on concepts such as forces, pressure, fluid dynamics, and chemical reactions. Each section presents multiple-choice questions that require application of scientific principles and mathematical reasoning. The problems are structured for an academic examination setting, likely aimed at students preparing for competitive exams.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

17-11-2024

9610WJA8011642400A5 JA

PHYSICS

SECTION-I (i)

1) A rod of mass ‘M’ is subjected to force ‘f’ and ‘2f’ at both the ends as shown in the figure. If young
modulus of its material is ‘y’ and its length is L find total elongation of rod.

(A)

(B)

(C)

(D)

2) A liquid is filled in a spherical container of radius R till a height h. At this position the liquid

surface at the edges is also horizontal. The contact angle is :-

(A) 0
cos–1
(B)

(C)
cos–1

(D)
sin–1

3) Water rises in a capillary as shown. The correct graph of pressure (p) vs height (y) above point O
along the axis of capillary is :-

(A)

(B)

(C)

(D)

4) A vertical U-tube of uniform inner cross section contains mercury in both sides of its arms. A
glycerin (density =1.3 g/cm3) column of length 10 cm is introduced into one of its arms. Oil of
density 0.8 gm/cm3 is poured into the other arm until the upper surfaces of the oil and glycerin are
in the same horizontal level. Find the length of the oil column, Density of mercury = 13.6 g/cm3

(A) 10.4 cm
(B) 8.2 cm
(C) 7.2 cm
(D) 9.6 cm

5) A large open tank has two small holes in its vertical wall as shown in figure. One is a square hole
of side 'L' at a depth '4y' from the top and the other is a circular hole of radius 'R' at a depth 'y' from
the top. When the tank is completely filled with water, the quantities of water flowing out per second

from both holes are the same. Then, 'R' is equal to :-

(A)

(B)

(C)

(D)

SECTION-I (ii)

1)

Water is coming out from a small hole of cross section area S at the bottom of large tank as shown.
Choose the correct statements :

(A) Speed of water coming out is .


(B) Speed of water coming out is .
(C) Thrust force on tank is 2ρSgh.
(D) Thrust force on tank is ρSgh.

2) A small hole of area a is at the bottom of a container of area A. The liquid is filled up to height h
from base. As liquid comes out then

(A)
level of liquid in container falls at rate of
magnitude of acceleration of top surface of liquid is
(B)

acceleration of top surface of liquid is


(C)

(D) None of these

3) A cylindrical tube, with its base as shown in the figure, is filled with water. It is moving down with
a constant acceleration a along a fixed inclined plane with angle θ = 45°. P1 and P2 are pressures at
points 1 and 2, respectively, located at the base of the tube. Let β = (P1 –P2)/(ρgd), where r is density
of water, d is the inner diameter of the tube and g is the acceleration due to gravity. Which of the

following statement(s) is(are) INCORRECT?

β = 0 when a = g/
(A)

β > 0 when a = g/
(B)

(C)
β= when a = g/2

(D)
β= when a = g/2

4) A uniform capillary tube of inner radius r is dipped vertically into a beaker filled with water. The
water rises to a height h in the capillary tube above the water surface in the beaker. The surface
tension of water is σ. The angle of contact between water and the wall of the capillary tube is θ.
Ignore the mass of water in the meniscus. Which of the following statements is (are) true?

(A) For a given material of the capillary tube, h decreases with increase in r
(B) For a given material of the capillary tube, h is independent of s
(C) If this experiment is performed in a lift going up with a constant acceleration, then h decreases
(D) h is proportional to contact angle θ.

5) The figure shows the stress-strain graphs for materials A and B. From the graph it follows that

(A) Material A has a higher Young’s modulus


(B) Material B is more ductile
(C) Material B can withstand greater stress
(D) Material A can withstand greater stress

6) A uniform rod of mass m, length ℓ, area of cross-section A and Youngs modulus Y is pulled by a
force F = Mg on a rough table (µ = 0.5). Choose the INCORRECT option(s).

(A)
Strain at mid point of rod is .

(B)
Elastic potential energy density at mid point is .
(C) Acceleration of rod is g/2.

(D)
Stress at distance l/4 from end, where force is applied, is .

7) Consider a thin square plate floating on a viscous liquid in a large tank. The height h of the liquid
in the tank is much less than the width of the tank. The floating plate is pulled horizontally with a
constant velocity u0. Which of the following statements is (are) true?

(A) The resistive force of liquid on the plate is inversely proportional to h


(B) The resistive force of liquid on the plate is independent of the area of the plate
(C) The tangential (shear) stress on the floor of the tank increases with u0
(D) The tangential (shear) stress on the plate varies linearly with the viscosity η of the liquid

8) An open-ended U-tube of uniform cross-sectional area contains water (density 103kg m–3). Initially
the water level stands at 0.29 m from the bottom in each arm. Kerosene oil (a water-immiscible
liquid) of density 800 kg m–3 is added to the left arm until its length is 0.1 m, as shown in the

schematic figure below. The ratio of the heights of the liquid in the two arms is-
(A)

(B)

(C)

(D)

SECTION-II

1) Two vessels A and B have the same base area and contain water to the same height, but the mass
of water in A is four times that in B. The ratio of the liquid thrust at the base of A to that at the base

of B is n.

2) A contain filled with water is allowed to fall freely. The pressure difference between points ‘A’ and

‘B’ separated by distance 10 cm is :

3) A solid floats with 1/3 of its volume immersed in liquid-A and with 3/5 of its volume immersed in
liquid-B. A homogenous mixture is created by mixing equal volumes of both liquid-A and B, then

fraction of solid immersed in mixture is a/b, fill the value of in OMR.

4) A wire of uniform cross section is hanging vertically and due to its own weight its length changes.
There is a point 'C' on the wire such that change in length AC is equal to the change in length BC.

Points A,B & C are shown in figure. If (where 'n' is an integer). Find the value of 2n.
5) A soap bubble of radius 3 cm is formed inside the another soap bubble of radius 6 cm. The radius
of an equivalent soap bubble which has the same excess pressure as inside the smaller bubble with
respect to the atmospheric pressure is ........ cm. [JEE-Main 2021]

CHEMISTRY

SECTION-I (i)

1)

How many minimum moles of MgCl2 should be added to just precipitate Mg(OH)2 in
100 ml buffer solution containing 0.2M NH4OH and 0.1 M(NH4)2SO4 ?

Kb(NH4OH) = 10–5 ; Ksp[Mg(OH)2] = 10–11


(A) 0.1
(B) 0.01
(C) 2.0
(D) 5

2) If K1 & K2 be first and second ionisation constant of H3PO4 and K1 >> K2 which is incorrect.

(A)
(B)

(C)

(D)

3) pH of solution at first 1/4th equivalence point of Na2CO3 when titrated with HCl will be
(for H2CO3 = 10–7 ; = 10–11)

(A) 7 + log 3
(B) 7 – log3
(C) 11 + log3
(D) 11 – log3
4) The IUPAC name of

(A) 3-Carboxy-3-hydroxypentanedicarboxylic acid


(B) 2-Hydroxypropane-1, 2, 3-tricarboxylic acid
(C) 2-Hydroxypropane-1, 2, 3-trioic acid
(D) 3-Hydroxypropane-1, 2, 3-tricarboxylic acid

5) Which one of the following structures has the IUPAC name


3-ethynyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid ?

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) 100 ml of 0.5 M hydrazoic acid (HN3, Ka = 3.6 × 10–4) and 400 ml of 0.1 M cyanic acid (HOCN,
Ka = 8 × 10–4) are mixed. Which of the following is (are) true for the final solution?

(A) [H+] = 10–2


(B)
(C) [OCN–] = 4.571 × 10–3
(D) [H+] = 1.4 × 10–2

2) At 90oC pure water has [H+] = 10−6 M. Based on this correct statement is (are) :

(A) Increasing the temperature, increases degree of ionization of water


(B) At 60oC, pH of pure water will be less than 6
(C) At 90oC, pH of a 10−6 M HCl solution will be less than 6
o −12
(D) Ionization constant (Ka) of H2O at 90 C is 10

3) Which of the following mixtures will act as buffer ?

(A) H2CO3 + NaOH (1.5 : 1 molar ratio)


(B) H2CO3 + NaOH (1.5 : 2 molar ratio)
(C) NH4OH + HCl (5 : 4 molar ratio)
(D) NH4OH + HCl (4 : 5 molar ratio)

4) Which is/are correct statement(s) about the solubility of AgCI(s)?

(A) Solubility of AgCI in 2M NH3 is 0.166 M


–11
(B) Solubility of AgCI in 2M AgNO3 is 5 × 10 M
–5
(C) Solubility of AgCI in 2M KNO3 is 10 mol/L
(D) Solubility of AgCI in pure water is 10–5 g/L

5) In an acidic indicator HIn has ionization constant is 10–8. The acid form of indicator is yellow and
alkaline form is red. Which is/are correct statements ?
(Given : log2 = 0.3, log3 = 0.48)

(A) The pH range of indicator is 7 to 9


(B) Change in pH is 0.96 when 75 % yellow colour change to 75 % red colour
(C) This indicator is suitable for the titration of strong acid vs. strong base
(D) pH of indicator is 8.3 when ratio of acid form to alkaline form is 2.

6) The IUPAC name(s) of the following compound is(are) :

(A) 4-Methylchlorobenzene
(B) 4-Chlorotoluene
(C) 1-Chloro-4-methylbenzene
(D) 1-Methyl-4-chlorobenzene

7) Which of the following IUPAC names are correct.


(A)

(B)

(C)

(D)

8) Which of the following is not triad of homologous series ?

(A) CH3NH2, (CH3)2NH, (CH3)3N


(B) Ph–OH, Ph–CH2–OH, Ph–CH2–CH2–OH
(C) HCOOH, CH3COOH, CH3COOCH3
(D) CH3NH2 , CH3CH2NH2 , CH3CH2CH2NH2

SECTION-II

1) Write the IUPAC locant position of multiple bond in the given structure.

2) Number of different types of functional groups in the following compound is/are:

3) of SrF2 is 1 × 10−10. The solubility of SrF2 in 0.1 NaF is 1 × 10− . The value of is…

4) In the neutralization process of and NaOH, the number of buffers formed will be:
5) Amongst the following, the total number of compounds whose aqueous solution turns red litmus
paper blue is :
[given , for is 6.37, 10.33]
NaCN KCl Na2SO4 (NH4)2SO4
ZnCl2 Na3PO4 Fe(NO3)3 Na2CO3
NH4Cl NaHCO3 Na2C2O4

MATHS

SECTION-I (i)

1) The equation of the parabola whose focus is at (–1,2) and the directrix is the straight line x – 2y +
3 = 0, is

(A) 4x2 –y2 + 4xy – 4x + 32y + 16 = 0


(B) 4x2 +y2 – 4xy – 4x + 32y – 16 = 0
(C) 4x2 +y2 + 4xy + 4x – 8y – 16 = 0
(D) 4x2 +y2 + 4xy + 4x – 8y + 16 = 0

2) A ray of light bisect the chord y = 2x – 3 and is parallel to axis of the parabolic mirror y2 = 4x and
strikes the interior of this parabola. The co-ordinates of the point where the ray meets the parabola
for the second time is

(A)

(B) (4, – 4)
(C) (1, 0)
(D) The ray never meets second time.

3) If two distinct chords of the parabola y2 = 4ax are bisected by the line x + y = 1 and pass through
the point (a, 2a), then length of latus rectum can be

(A) 8
(B) 4
(C) 6
(D) 2

4) The common tangents to the circle x2 + y2 = 2 and the parabola y2 = 8x touch the circle at the
points P, Q and the parabola at the points R, S. Then the area of the quadrilateral PQRS in sq. units
is

(A) 3
(B) 6
(C) 9
(D) 15
5) If a normal chord of y2 = 4 ax subtends a right angle at the vertex, then its slope can be

(A)

(B)

(C)

(D) 2

SECTION-I (ii)

1) The tangent PT and the normal PN to the parabola y2 = 4ax at a point P on it meet its axis at T
and N respectively the locus of the centroid of the triangle PTN is a parabola whose

(A)
vertex is
(B) directrix is x = 0

(C)
latus rectum is
(D) focus is (a, 0)

2) TP and TQ are tangents to parabola y2 = 4x and normals at P and Q intersect at a point R


on the curve. The locus of the centre of the circle circumscribing ΔTPQ is a parabola whose

(A) vertex is (1, 0).

(B)
foot of directrix is

(C)
length of latus-rectum is

(D)
focus is

3) If the focus of the parabola (y – λ)2 = 4(x – λ) always lies between the lines 2x + y = 1 and 2x + y
= 3 then the possible values of λ is -

(A) –1/6
(B) 1/6
(C) 0
(D) 2

4)

Let P and Q be distinct points on the parabola y2 = 2x such that a circle with PQ as diameter passes
through the vertex O of the parabola. If P lies in the first quadrant and the area of the triangle ΔOPQ
is , then which of the following is (are) the coordinates of P?
(A)

(B)

(C)

(D)

5) Let P be the point on the parabola y2 = 4x which is at the shortest distance from the center S of
the circle x2 + y2 – 4x – 16y + 64 = 0. Let Q be the point on the circle dividing the line segment SP
internally. Then-

(A)

(B)

(C) the x-intercept of the normal to the parabola at P is 6

(D)
the slope of the tangent to the circle at Q is

6) For the parabola , which touches x-axis at (2,0) and y-axis at (0,3), which of the
following is/are true?

(A) Equation of axis is

(B)
Focus is
(C) Directrix is

(D)
Length of Latusrectum is

7) Consider a circle with its centre lying on the focus of the parabola, y2 = 2px such that it touches
the directrix of the parabola. Then a point of intersection of the circle & the parabola is :

(A)

(B)

(C)

(D)

8) Let P, Q and R are three co-normal points on the parabola y2 = 4ax. Then the correct statement(s)
is/are

(A) algebraic sum of the slopes of the normals at P, Q and R vanishes


(B) algebraic sum of the ordinates of the points P, Q and R vanishes
(C) centroid of the triangle PQR lies on the axis of the parabola
(D) circle circumscribing the triangle PQR passes through the vertex of the parabola

SECTION-II

1) Radius of largest circle that can be inscribed in the parabola x2 = 4y and passing through its focus
is

2) If equation of directries of the parabola y2 – kx + 8 = 0 is x = 1 then, the positive value of k is:

3) Consider the parabola y2 = 8x. Let Δ1 be the area of the triangle formed by the end points of

its latus rectum and the point on the parabola, and Δ2 be the area of the triangle

formed by drawing tangents at P and at the end points of the latus rectum. Then is :

4) If y = mx + 4 is a tangent to both the parabolas, y2 = 4x and x2 = 2by, then is equal to

5) If the normals at two points P and Q of a parabola y2 = 4ax intersect at a third point R on the
curve, then the product of abscissa of P and Q is Ka2 then value of K is
ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5
A. C B A D C

SECTION-I (ii)

Q. 6 7 8 9 10 11 12 13
A. A,C A,B B,D A,C A,D A,B A,B,D B

SECTION-II

Q. 14 15 16 17 18
A. 1 0 5 4 2

CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23
A. B D C B D

SECTION-I (ii)

Q. 24 25 26 27 28 29 30 31
A. A,B A,C A,B,C A,B,C A,B,C B,C A,C,D A,B,C

SECTION-II

Q. 32 33 34 35 36
A. 4 7 8 3 5

MATHS

SECTION-I (i)

Q. 37 38 39 40 41
A. D B D D A

SECTION-I (ii)

Q. 42 43 44 45 46 47 48 49
A. A,D A,B,D A,B,C A,D A,C,D A,B,C,D A,B A,B,C,D
SECTION-II

Q. 50 51 52 53 54
A. 4 4 2 2 4
SOLUTIONS

PHYSICS

2)

3) Pressure inside liquid and outside liquid layer its P0 [where P0 is atmospheric
pressure]

4) At the condition of equilibrium


Pressure at point A = Pressure at point B
PA = PB

By solving we get h = 9.7 cm

5)

6)

v=
Fthrust = ρsv2
= ρs(2gh)

7) Applying Bernoulli’s equation between P and Q

.....(i)
From equation of continuity,
Acceleration of top layer

8)

∴ ....(A)

....(B)

9)
[R → Radius of meniscus]

[r → radius of capillary; θ → contact angle]

(A) For given material, θ → constant

(B) h depend on σ
(C) If lift is going up with constant acceleration,
geff = (g + a)
It means h decreases
(D) h is proportional to cosθ

10)

The slope of the linear portion of the curve gives the Young’s modulus of the material. The
slope of the linear portion OP for material A is greater than that of the linear portion
of material B. Hence, statement (a) is correct. The plastic region for material A (from P to Q) is
greater than that (from R to S) for material B, which indicates that material A is more ductile.
Hence, statement (b) is correct. The breaking stress for material for material B (i.e. stress
corresponding to point S) is less than that for material A (i.e. stress corresponding to point Q),
which implies that material B can break more easily than material A. Hence, choice (c) is also
incorrect. Material A is stronger than material B because it can withstand a greater stress
before it breaks. The breaking stress is the stress corresponding to point Q for material A and
to point S for material B. Hence, the correct choices are (a) and (d).

11)
F – f = ma

At mid point

Stress Strain =

Energy density = Stress × strain

At

Stress =

12)

f=τ.A
t = shear stress =

13) h1 + h2 = 0.29 × 2 + 0.1


h1 + h2 = 0.68 ……(1)
⇒ [ρk = density of kerosene & ρw = density of water]


=
⇒ 800 × 10 × 0.1 + 1000 × 10 × h1
– 1000 × 10 × 0.1 = 1000 × 10 × h2
⇒ 10000 (h1 – h2) = 200
⇒ h1 – h2 = 0.02 ……(2)

So,

16)

ρ → density of solid
ρA = 3r

ρB =

ρmixture = ⇒ ⇒
Fraction of solid submerged in mixture

=
Answer a = 3, b = 7

17)
Tension in elementary section of width dx is
( = mass / length)
Extension of length x (= BC) of wire is

g ...(1)
Extension in total length of wire is

...(2)

From equation (1) and (2)

n = 2, 2n = 4

18)

Excess pressure inside the smaller soap bubble

...(i)
The excess pressure inside the equivalent soap bubble

...(ii)
From (i) and (ii)

Req = 2 cm

CHEMISTRY

19)
pOH = 5

Mg(OH)2 Mg2+ + 2OH–


KSP = [Mg2+] [OH–]2
10-11 = [Mg2+] [10-5]2
[Mg2+] = 0.1

mole =

20)
Solving above this we obtain :-

C = Initial concentration of H3PO4


Ka1 = K1

Acid - dissociation constant

21) Na2CO3 + HCl → NaHCO3 + NaCl

a – –

Buffer solution

pH = pKa + log
pH = 11 + log 3

22)
(2-Hydroxypropane-1, 2, 3-tricarboxylic acid)

23)
3-ethynyl-2-hydroxy-4-methyl-hex-3-en-5-ynoic acid.

24)

25)

Increasing the temperature, increases degree of ionization of water.


At 90oC, pH of a 10−6 M HCl solution will be less than 6.

26)

(A) H2CO3 + OH– HCO3– + H2O


moles 1.5 1
0.5 – 1
so it is a buffer solution.
(B) H2CO3 + OH– HCO3– + H2O
moles 1.5 2
– 0.5 1.5
HCO3– + OH– CO32– + H2O
moles 1.5 0.5
– – 0.5
so it is a buffer solution.
(C) NH4OH + H+ NH4+ + H2O
moles 5 4
1 –
so it is a buffer solution.
27)

28)

Change in

29)

30)

When carbon containing chain terminating F.G is attached to ring special suffix is used

31) (A) 1º, 2º and 3º amines are functional group isomers.


(B) Phenol and alcohol are functional group isomers of each other.
(C) Acid and esters are functional group isomers.

32)
33)

34)
- s1 2s1+0.1
ksp = s1 x (2s1 +0.1)2

35)

36) NaCN Na2CO3 Na2C2O4


Na3PO4 NaHCO3 Na2HPO4

MATHS

37)

SP = PM
⇒ SP2 = PM2


On simplifying further, we get
4x2 +y2 + 4xy + 4x – 8y + 16 = 0

42) Equation of tangent : ty = x + at2


⇒ T ≡ (–at2,0)
equation of normal : y = –tx + 2at + at3

If centroid of ΔPTN is (h,k) then


3h = at2 – at2 + 2a + at2, 3k = 2at

44)

Clearly focus is (1 + λ, λ)
Focus lies between 2x + y – 1 = 0 and 2x + y – 3 = 0

A, B, C are correct

47) For the parabola

Focus is ,

Axis is
Directrix is ax + by = 0

50)
Equation of circle : x2 + (y – r – 1)2 = r2
solve with x2 = 4y : 4y + (y – r – 1)2 = r2
D=0⇒r=4

53)

Any tangent to parabola y2 = 4x is y = mx + a/m


On comparing with y = mx + 4, we have
1/m = 4 = > m = 1/4
Now, equation of tangent y = (x/4) + 4 to x2 = 2by
x2 = 2b(x/4+4)
or 2x2 - bx - 16b = 0
Find the value of b:
Discriminant, D = 0
so, b2 + 128 b = 0
b(b +128) = 0
b = 0 or b = -128

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