02-05-2025

5001CJA101022240022 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Two aeroplanes fly from their respective position 'A' and 'B' starting at the same time and reach of
point 'C' (along straight line) simultaneously when wind was not blowing. On a windy day they head
towards 'C' but both reach the point 'D' simultaneously in the same time which they took to reach

'C'. Then the wind is blowing in :

(A) North-East direction

(B) North-West direction.
(C) Direction making an angle 0 < θ < 30 with North towards West.
(D) North direction

2) Two long, thin, parallel conducting wires are kept very close to each other, without touching. One
carries a current i, and the other has charge λ per unit length. An electron is moving parallel to the
conductors with speed v in their plane is undeflected. Then choose the correct option (Let c =

velocity of light, use ) :-

(A)

v=
(B)

(C)

(D)

3) When He+ ions dexcite to ground state from 2nd excitation state, emitted photons incident on a
metal having work function ϕ = 8.35eV, then minimum debroglie wavelength of photoelectron will
be :-

(A) 310Å
(B) 1.94 Å
(C) 382Å
(D) 2.15 Å

4) A broad source of light of wavelength 680nm illuminates normally two glass plates 120mm long
that meet at one end and are separated by a wire 0.034 mm in diameter at the other end. The total

number of bright fringes that appear over the 120 mm distance is :

(A) 50
(B) 100
(C) 200
(D) 400

SECTION-I (ii)

1) A rod AC of length ℓ, mass 25m is kept on a horizontal smooth plane. It is free to rotate and move.
A particle of mass m moving on the plane with velocity v strikes rod at point B, making angle
37°with NORMAL and rebound at angle 53° with NORMAL. All surfaces are smooth.

(A)
Speed of particle after rebounding is
Speed of rod just after collision is
(B)

(C)
Angular velocity of rod just after collision is
(D) 32.81% of kinetic energy is lost due to collision.

2) For a certain stretched string, three consecutive resonance frequencies are observed as 105, 175,
245 Hz respectively. Then select the correct alternative (s) :-

(A) The string is fixed at both ends

(B) The string is fixed at one end only
(C) The fundamental frequency is 35 Hz
(D) The fundamental frequency is 52.5 Hz

3) The galvanometer shown in the figure has resistance 10Ω. It is shunted by a series combination of
a resistance S = 1Ω and an ideal cell of emf 2V. A current 2A passes as shown.
(A) The reading of the galvanometer is 1A
(B) The reading of the galvanometer is zero.
(C) The potential difference across the resistance S is 1.5V
(D) The potential difference across the resistance S is 2V.

4) An object is placed in front of a converging lens at a distance equal to twice the focal length f1 of
the lens. On the other side of the lens is a concave mirror of focal length f2 separated from the lens
by a distance 2(f1 + f2). Light from the object passes rightward through the lens, reflects from the
mirror, passes leftward through the lens and forms a final image of the object.

(A) The distance between the lens and the final image is equal to 2f1.
(B) The distance between the lens and the final image is equal to 2(f1 + f2)
(C) The final image is real, inverted and of same size as that of the object
(D) The final image is real, erect and of same size as that of the object

5) In given circuit, capacitor was initially neutral. At t = 0 key K is closed and at t = 30 μs key K is

opened then.
(A)

Q : Charge on capacitor

(B)

i : Current through Battery

(C)

(D)

6) An ideal gas can be expanded from an initial state to a certain volume through two different
processes (i) PV2 = constant and (ii) P = KV2 where K is a positive constant. Then :-

(A) Final temperature in (i) will be greater then in (ii).

(B) Final temperature in (ii) will be greater then in (i).
(C) Total heat given to the gas in (i) case is greater than in (ii).
(D) Total heat given to the gas in (ii) case is greater than in (i).

7) A semicircular glass tube filled with water containing an air bubble is sealed at its ends. If the
tube is held with its plane vertical and made to move in its plane with constant acceleration, the
bubble stays aside of the highest point as shown in figure then acceleration of tube is:

(A) towards the left

(B) towards the right
(C)
(D)

8) Suppose the potential energy between electron and proton at a distance r is given by – .
Application of Bohr's theory to hydrogen atom in this case shows that

(A) energy in the nth orbit is proportional to n6

(B) energy is proportional to m–3 (m : mass of electron)
(C) energy of the nth orbit is proportional to n–2
(D) energy is proportional to m3 (m = mass of electron)

SECTION-II

1) In the figure shown blocks 'A' and 'B' are kept on a wedge 'C'. A, B and C each have mass m. All

surface are smooth. Find the acceleration of C.

2) A thin uniform metallic rod of length 0.5 m rotates with an angular velocity 400 rad/s in a
horizontal plane about a vertical axis passing through one of its ends. The elongation of the rod will
be x × 10–4 m. The density of the material of the rod is 104 kg/m3 and the Young's modulus is 2 × 1011
N/m2. The value of 3x is:

3) A satellite of mass m is moving in a circular orbit of radius 4R, around a planet of radius R and

mass M, with speed v0. Now a body of mass is projected from satellite in opposite direction with

speed with respect to ground from satellite then satellite starts moving in an elliptical path
having semi major axis 'a' then find .

4) In figure shown a conducting rod of length ℓ, zero resistance, mass m can move freely along
inclined conducting wires MN and PQ. These wires are inclined at angle θ from horizontal. The
capacitance of capacitor is C and uniform magnetic field B is in vertically upward direction. The rod
is released from rest. Find acceleration (in m/s2) of rod. Take m = 1 kg, ℓ = 1m, , C = 10–2 F

and B = .

5) An Indian submarine is moving in "Arab Sagar" with a constant velocity. To detect enemy it sends
out sonar waves which travel with velocity 1050 m/s in water. Initially the waves are getting
reflected from a fixed island and the reflected waves are coming back to submarine. The frequency
of reflected waves are detected by the submarine and found to be 10 % greater than the sent waves.

Now an enemy ship comes in front due to which

at the frequency of reflected waves detected by submarine becomes 21% greater than the sent
waves. The velocity of enemy ship with respect to indian subamrine is X m/s then find X/10.

6) An LCR series circuit with 120Ω resistance is connected to an AC source of peak voltage 193 volt
and angular frequency 300 rad/s. When only capacitor is removed, the current lags behind voltage
by phase 37°. When only inductors is removed, the current leads voltage by 53°. The average power
dissipated in LCR circuit is P watts. Then value of P/10 is

PART-2 : CHEMISTRY

SECTION-I (i)
1) Consider the following statements.
(I) Hybridisation state of Boron is change when B3N3H6 react with solution of hydrochloric acid
(II) In C3N3Cl3 , all the carbon and nitrogen atoms are sp2 hybridised
(III) In , iodine is sp3d2 hybridised
(IV) In H3BO3, oxygen is sp3 hybridised
Select the correct set of codes, using initials 'T' for True and F for False statements.

(A) T T F T
(B) F T F T
(C) T T T F
(D) T T F F

2) Partial roasting of copper pyrites ore by heating in Reverberatory furnace. The method is based
on the principle that :-

(A) Sulphur and iron has less affinity for oxygen than copper at high temperature
(B) Copper has more affinity for oxygen than sulphur at high temperature
(C) Iron has less affinity for oxygen than copper and sulphur at high temperature
(D) Copper has less affinity for oxygen than iron and sulphur at high temperature

3) Which of the following resonating structures contributes the most in resonance hybrid ?

(A) I
(B) II
(C) III
(D) None of these

4) Determine the amount of AgI which may be dissolved in 1.0 litre of 1.0 M CN– solution. Ksp[AgI]
and formation constant for [Ag(CN)2]– complex are 1.19 × 10–17 M2 and 7.11 × 110+19 M–2
respectively.

(A) 1.0 mole

(B) 0.5 mole
(C) 4.0 mole
(D) 2.5 mole

SECTION-I (ii)

1) A bromide does not interfere with the chromyl chloride test because when a bromide is present :

(A) The CrO2Br2 formed does not volatiles as CrO2Cl2 does

(B) CrO2Br2 does not react with NaOH
(C) Br2 is liberated, which gives colorless solution with NaOH
(D) No volatile substance containing bromine is produced

2) Which of the following statement(s) is/are correct for below reaction(s).

(A) Redox reaction take place

(B) 'z' is Na4 [Cu6(S2O3)5]
(C) 'y' is CuS2O3
(D) Formation of Na2S4O6 involve in above reaction(s)

3) Which of the following reaction will produce benzaldehyde as major product ?

(A)

(B)

(C)

(D)

4)
'X' can be :

(A)

(B) Red P / HI
(C)

(D) Zn – Hg / Conc. HCl

5) —→ A (Major)
major product of this reaction is.

(A)

(B)

(C)

(D)

6) Mark out the correct one(s) about P–V plot system.

(A) The entropy change for the overall process is 0

(B) ΔH > ΔE for overall process
(C) For overall cycle : qnet = wnet
(D) Total work for overall process = –620.77 J

7) Two identical containers, each of volume V are joined by a small pipe of negligible volume. The
containers contain identical gases at temperature, T and pressure, P. One container is heated upto
temperature 2T while maintaining the other at same temperature T, then which of the following
is/are correct : –

(A) Final pressure of the gas in each container is 2P.

(B) Final pressure of the gas in each container is 4P/3.

(C)
Final number of moles of gas in container at temperature 2T is .
Final number of moles of gas in container at temperature T is
(D)

8) Identify correct option(s) for colloidal sols given :

Sol-I : Adding AgNO3(aq.) solution to excess KI(aq.) solution
Sol-II : Peptization of Fe(OH)3 precipitate using FeCl3(aq.) solution
Sol-III : Gold sol prepared by Bredig's arc method.

(A) Mixing sol I and sol III can lead to their mutual coagulation
(B) Sol (I) will show electrophoretic movement towards anode
(C) Sol (III) is an irreversible sol.
(D) Sol. (II) shows electro osmotic movement towards anode.

SECTION-II

1) Consider the following complexes

0
[Co(NH3)2(en)2]+3 , , [Zn(NO2)4]–2 , [Co(NH3)(Br)(en)2]+2 , [Zn(gly)2]
0
[Fe(EDTA)]⊕ , [Ni(PPh3)2Cl2] , [Co(gly)3]
⇒ If total number of complexes which show geometrical isomerism ⇒ 'x'
⇒ If total number of complexes which can show optical isomerism = 'y'

then find the value of ?

2) Consider the following compounds

PbO, PbO2 , Pb2O3 , Pb3O4
⇒ Total number of mixed oxide = A
⇒ Total number of dark brown colour compound = B
⇒ Total number of compound which does not affected by HNO3 = C
⇒ Total number of compound in which peroxide ion is present = D

Find the value of

3) How many N-atom are present in final product of following sequence :

4) Monobromo derivatives
the number of possible monobromo products is (excluding stereo isomers)

5) At 20°C, the vapour pressure of benzene is 70 torr and that of methyl benzene is 20 torr. The
mole fraction of benzene in the vapour phase at 20°C above an equimolar mixture of benzene and
methyl benzene is.

6) A proton accelerated from rest through a potential difference of 16 volts has a wavelength λ
associated with it. An alpha particle in order to have the same wavelength must be accelerated from
rest through a potential difference (in volt) of – [Give your answer as nearest integer]

PART-3 : MATHEMATICS

SECTION-I (i)

1) Smallest integer greater than the real number is

(A) 850
(B) 4100

(C)

(D)

2) ABC be a triangle with AB = 13; BC = 14 and CA = 15. AD and BE are the altitudes from A and B
to BC and AC respectively. H is the point of intersection of AD and BE. Then the ratio HD/HB is

(A)

(B)

(C)

(D)

3) If , then amp(z) is (–π < amp(z) ≤ π)

(A)

(B)

(C)
(D)

4) If the trigonometric equation 1 + sin2xθ = cosθ has a non-zero solution in θ, then x must be

(A) an integer
(B) a rational number
(C) an irrational number
(D) strictly between 0 and 1

SECTION-I (ii)

1) The two sequences of numbers {3,9,27,81,...} and {1,4,7,10,13,...} are mixed as follows
{3,1,9,4,27,7,81,10,...}. If one of number in mixed sequence is k = 6561, then

(A) number immediately preceding k is 22

(B) number immediately preceding k is 19
(C) number immediately succeding k is 22
(D) number immediately succeding k is 729

2) If equation 8x3 – 6x + 1 = 0 has roots α, β, γ where α < β < γ, then {where [ ] denotes greatest
integer function}

(A) [|α| + |β| + |γ|] = 1

(B) [α] + [β] + [γ] = –1
(C) 18β < π

(D)
sin–1γ =

3) Consider the quadratic equation (a + c – b)x2 + 2cx + (b + c – a) = 0, where a, b, c are distinct

real numbers. Suppose one root of equation is double of other, then

(A)
is rational
(B) a, b, c are rational
(C) |c| > |a – b|
(D) (a – b) & c both are rational

4) Lines and are tangents to the circle S = 0 at points A & B respectively. If centre
of circle is C(h, k) where h, k > 0 & radius = , then

(A) h + k = 4
(B) h > k
(C) circumcircle of ΔOAB is x2 + y2 – 2x – 2y = 0 (O is origin)
(D)
5) If point P lies outside of circle x2 + y2 – 2x = 0 & moves such that its distance from nearest point
on the circle is half of its distance from line x = 5, then locus of point P can be

(A) an ellipse
(B) a hyperbola
(C) a parabola
(D) a line

6) Consider function f : [0, 1] → [0, π] defined by f(x) = then

(A) f(x) is injective

(B) f(x) is surjective
(C) f(x) is non-differentiable at two points

(D)
f ′ (x) = 0 where x ∈

7) Let f(x) be continuous & strictly increasing function of x and suppose F(x) = 1 + f(x) + (f(x))2 +
(f(x))3. If F(x) has a positive root then

(A) F(x) is a decreasing function of x

(B) |f(0)| < 1
(C) F(0) < 0
(D) f(0) < –1

8) Consider a function y = f(x) satisfies differential equation y ′′ x2 + x(y′)2 = 2xy′ where f(0) = 0 & f ′′

(1) = 1. Let A be area bounded by y = f(x), y-axis & line y = , then

(A) f(x) is strictly decreasing function

(B) f(x) is strictly increasing function
(C) A = 1 – ℓn 2
(D) A = 4 – π

SECTION-II

1) If two distinct chords of a parabola y2 = 4ax passing through (a, 2a) are bisected by the line x + y
= 1 and 4a is a natural number, then the maximum length of the latus-rectum is

2) In a village of 1000 inhabitants, there are three newspapers P, Q and R in circulation. Each of
these papers is read by 500 persons. Papers P and Q are read by 250 persons, papers Q and R are
read by 250 persons, papers R and P are read by 250 persons. All the three papers are read by 250
persons. Then the number of persons who read no newspaper at all, is

3) A rectangular box of volume 48 cu ft is to be constructed, so that its length is twice of its width.
The material to be used for the top and the four sides is three times costlier per sq ft than that used
for the bottom. If the box that minimizes the cost has height equal to h (in ft), then value of h, is

4) Let f(x, y) = x2 + y2 – 2xy and a matrix A = where x1, x2, x3 are

different natural numbers & y1, y2, y3 ∈ R. If trace of A = 0, then least value of determinant of A, is

5) Number of integral points (points whose abscissa & ordinate both are integer) in the common

region bounded by and , is

6) A diagnostic test has a probability 0.9 of giving a positive result when applied to a person
suffering from a certain disease and probability 0.1 of giving a (false) positive when applied to a non
sufferer. It is estimated that 1% of the population are sufferers. Suppose a person selected randomly

administered positive test and probability that he is a sufferer is (p & q are coprime) then (q – 5p),
is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B A B B

SECTION-I (ii)

Q. 5 6 7 8 9 10 11 12
A. A,B,C,D B,C B,D A,C A,D B,D B,C A,B

SECTION-II

Q. 13 14 15 16 17 18
A. 0.00 10.00 64.00 2.50 10.00 11.58

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22
A. C D C B

SECTION-I (ii)

Q. 23 24 25 26 27 28 29 30
A. C A,B,D A,B,C A,B,C,D A,C A B,C,D B,C,D

SECTION-II

Q. 31 32 33 34 35 36
A. 1.66 or 1.67 0.00 3.00 5.00 0.77 or 0.78 2.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40
A. C A D B

SECTION-I (ii)

Q. 41 42 43 44 45 46 47 48
A. B,C A,B,C A,C A,C A B,C,D C,D B,C
 SECTION-II

Q. 49 50 51 52 53 54
A. 3.00 0.00 2.66 or 2.67 8.00 3.00 7.00
 SOLUTIONS

PART-1 : PHYSICS

1) (B) Without wind A reaches to C and with wind it reaches to D in same time so wind must
deflect from C to D so wind blow in the direction of CD.

2)

At P, electric field = E = (to the right),

and magnetic field = B = (into the paper).

for no deflection, E = vB or v =

or v = .

3)
[Link] = hν – ϕ
= [48.35 – 8.35]eV = 40 eV

= Å= Å
= 1.94 Å

4) Constructive interference happens when 2t = (m – 1/2)l. The minimum value for m is m = 1;

the maximum value is the integer portion of

mmax = 100.

5)

...(i)

...(2)

...(3)

...(3)

Heat produced

% of K.E. converted into Heat

= 32.81%

6) As F1 : F2 : F3 = 3 : 5 : 7, string is fixed at one end, its fundamental frequency is

7) Let the currents be as shown in the figure.

KVL along ABCDA

–10i – 2 + (2 – i)1 = 0
i=0
Potential difference across s = (2 – i)1 = 2 × 1 = 2V.

10) From equation PV = nRT

PC < PB, VC = VB and TB > TC
WAB > WAC (TB – TA) > TC – TA
So By 1st law

Q = ΔU + W
Q = nRΔT + W
QAB > QAC

11)
mass of air bubble is neglected

as bubble is towards right, acc. of should also towards right.

12) |F| = = ...(1)

= ...(2)

and mvr = ...(3)

By (2) and (3)

x= = ...(4)

Total energy = (potential energy)

= = =
Total energy ∝ n6
Total energy ∝ n–3
∴ (A) and (B) are correct.

13)
Let c be acceleration of wedge C.
a be acceleration of block A w.r.t. wedge C.
b be acceleration of block B w.r.t. wedge C.
Applying Newtons law in horizontal direction of system of A + B + C.
mc + m(c – a cos 37°) + m(c + b cos 53°) = 0 ....(1)
Applying Newton's law to block A and B along the incline gives.
In case of A : mg sin 37° = m(a – c cos 37°) ........(2)
In case of B : mg sin 53° = m(b + c cos 53°) ......(3)
solving (1), (2) & (3) we get c = 0
Ans. ac = 0

15)
mv0 = 0.8mv – 0.1mv0

...(1)

16)
 ...(i)

...(ii)

m/s2

17)

v1 = 50 m/sec.

[21% greater then sent waves]

get v2 = 50 m/sec toward indian submarine.

18)
PART-2 : CHEMISTRY

19) (I) B3N3H6 + 3HCl → B3N3H9Cl3

B→ sp2 B→sp3

(II)

(III)

(IV)

20) The reaction at high temperature in the blast furnace is :

2CuFeS2 + O2 → Cu2S + 2FeS + SO2

22)

Now let a moles of AgI dissolved in CN– solution.

1 mole 0 0
(1 – 2x) mole x mole x mole
As [CN–] = MV = 1×1 = 1 mole

also Kc = Kf Ksp

x = 0.5

23) Bromides and iodides do not interfere with the chromyl chloride test, because they are
oxidised to Br2 (red vapour) and I2 (violet vapours) which dissolve in the NaOH solution to form
colourless products (halide + hypohalite/halate)
24)

25) ∴ (A) Etard reaction

(B) Mild oxidising agent
(C) Rosenmund reduction
(D) Haloform reaction

26) ∴ All reagents will convert it into alkane.

28) Over all process is cyclic

Thus, ΔE = 0, ΔH = 0, ΔS = 0, ΔE = q + W
0 = q + W ⇒ q = –W

= –5 atm L
= –5 × 101.3 J
= –506.5 J

31) x = [Co(NH3)2(en)2]+3 , [Co(NH3)(Br)(en)2]+2 , [Co(gly)3]0

0
y = [Co(NH3)2(en)2]+3 , [Co(NH3)(Br)(en)2]+2 , [Zn(gly)2]0 , [Fe(EDTA)]⊕ , [Co(gly)3]

32) A ⇒ Pb2O3 ⇒ PbO . PbO2 Reddish - yellow

Pb3O4 ⇒ 2PbO . PbO2 Red
 B ⇒ PbO2 dark brown
PbO ⇒ yellow - massicot
red or reddish-yellow - litharge
C ⇒ PbO2
PbO + 2HNO3 → Pb(NO3)2 + H2O
Pb2O3 + 2HNO3 → Pb(NO3)2 + PbO2 ↓ + H2O
Brown ppt.

A⇒2
B⇒1
C⇒1
D⇒0
Ans. 0.00

35) KB = 0.5 = KT

Now

= 0.777

36) Mα = 4MP

qα = 2e

if λ2 = λ then 8V2 = 16

V2 = 2 volt

PART-3 : MATHEMATICS

37)
38)

39)

40) 1 + sin2xθ = cosθ ⇒ (1 – cosθ) + sin2xθ = 0

⇒ 2sin2(θ/2) + sin2xθ = 0
⇒ sin(θ/2) = 0 and sinxθ = 0
⇒ θ = 2nπ and θ = mπ/x
⇒ mπ/x = 2nπ
⇒ x = m/2n
Option (B) is correct

41)

6561 = 38 and Tn of A.P = 1 + (n – 1) 3 = 3n – 2

number immediately preceding = T7 = 19
number immediately succeding = T8 = 22

42) f(x) = 8x3 – 6x + 1 f'(x) = 6(4x2 – 1)

Also
put x = sinθ

⇒ , , or

43) roots are –1 and

OR

44)
centre lies on line y = x

circumcircle of ΔOAB is x (x – 2) + y(y – 2) = 0

45)

where PM > 2

46)
Put
⇒ f(x) = 2sin–1sinθ + sin–1sin2θ

47)

F'(x) = f'(x) (1 + 2f(x) + 3f2(x))

f(x) is continuous & strictly increasing so f ' (x) > 0
and (1 + 2f(x) + 3f2(x)) > 0 (∵ D < 0)
So F'(x) > 0 ⇒ F(x) is increasing function.
if F(x) has positive root then F(0) < 0

F(0) = (1 + f(0))
1 + f(0) < 0

48)

or
given f"(1) = 1 ⇒ k = 1

f(x) is strictly increasing

49)

Any point on the line x + y = 1 can be taken (t,1 – t)

Equation of the chord, with this as mid point is y(1 – t) – 2a(x + t) = (1 – t)2 – 4at
It passes through (a,2a)
So, t2 – 2t + 2a2 – 2a + 1 = 0, this should have 2 distinct real roots
so a2 – a < 0, 0 < a < 1
⇒ length of latus rectum < 4

50) Let 'a' number of people read no newspaper at all.

Now, x1 + x4 + x5 + x7 = 500
x2 + x5 + x6 + x7 = 500
x3 + x4 + x6 + x7 = 500
x5 + x7 = 250
x4 + x7 = 250
x6 + x7 = 250
x7 = 250
And, x1 + x2 + x3 + x4 + x5 + x6 + x7 + a = 1000
⇒ x4 = x5 = x6 = 0
⇒ x1 = 250, x2 = 250, x3 = 250
⇒ a = 1000 – 250 – 250 – 0 – 0 – 0 – 250 = 0

51)

Let the height is h and width is x

Therefore, length = 2x
Volume = x⋅2x⋅h = 2x2h = 48
⇒ x2 = 24/h
Cost = c⋅x⋅2x+3c(x⋅2x+2⋅x⋅h + 2⋅2x⋅h) where c is cost per sq ft
Cost = C = c(48/h) + 3c(48/h + 6h ) = 4⋅48c/h + 36c
dC/dh = –4⋅48c/h2 + 36c√(6/2√h = 0
⇒ h3/2 = 4⋅48⋅2/36√6 = 16⋅√2/33/2
⇒ h3/2 = (8/3)3/2
⇒ h = 8/3

52)

tr(A) = (x1 – y1)2 + (x2 – y2)2 + (x3 – y3)2 = 0

 when x1 = 1, x2 = 2 and x3 = 3

53)

∵ z ≠ 0,1
∴ 3 integral points.

54)

Let T ≡ Test positive , S ≡ sufferer