Solutions JEE Main 2026 Crash Course

Daily Practice Problems MARKS

Q1.
The elevation in boiling point for 1 molal solution of glucose is 2 K. The depression in freezing point for 2 molal
solution of glucose in the same solvent is 2 K. The relation between K and K is: b f

(1) K b = 2 Kf (2) K b = 1 .5 Kf (3) K b = Kf (4) K b = 0 .5 Kf

Q2.
Consider the given plots of vapour pressure (VP) vs temperature(T/K). Which amongst the following options is
correct graphical representation showing ΔT , depression in the freezing point of a solvent in a solution?
f

(1) (2)

(3) (4)

Q3.
If a substance ′A′ dissolves in solution of a mixture of ' B' and ' C ' with their respective number of moles as n A, nB

and n , mole fraction of C in the solution is:

C

(1) nC

nA×nB×nC
(2) nA+nB+nC
nC
(3) nC

nA−nB−nC
(4) nB

nA+nB

Q4.
Mass of ethylene glycol (antifreeze) to be added to 18. 6 kg of water to protect the freezing point at −24°C is kg
(Molar mass in gmol −1
for ethylene glycol 62, Kf of water = 1. 86 K kg
−1
mol )

Q5.
Sea water contains 29. 25% NaCl and 19% MgCl by weight of solution. The normal boiling point of the sea water
2

is ∘
C (Nearest integer) Assume 100% ionization for both NaCl and MgCl Given: K 2 b(H2O = 0. 52 K kg
−1
mol )

Molar mass of NaCl and MgCl is 58. 5 and 95 g mol

2
−1
respectively.
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

Q6.
Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y. respectively in 1 kg of
water. The ratio of depression in freezing points for A and B is found to be 1 : 4. The ratio of molar masses of X and
Y is
(1) 1 : 4 (2) 1 : 0. 25 (3) 1 : 0. 20 (4) 1 : 5

Q7.
The number of pairs of the solution having the same value of the osmotic pressure from the following is
(Assume 100% ionization)
A. 0. 500 M C 2H5 OH(aq) and 0. 25 M KBr(aq)

B. 0. 100 M K 4[Fe(CN)6](aq) and 0. 100 M FeSO 4 (NH4)

2
SO4(aq)

C. 0. 05 M K 4[Fe(CN)6] (aq) and 0. 25 M NaCl (aq)

D. 0. 15 M NaCl(aq) and 0. 1 M BaCl2(aq)

E. 0. 02 M KCl. MgCl . 6H2O(aq)

2
and 0. 05 M KCl(aq)

Q8.
Some amount of dichloromethane (CH2 Cl2) is added to 671. 141 mL of chloroform (CHCl3) to prepare
2. 6 × 10
−3
M solution of CH 2 Cl2(DCM) . The concentration of DCM is _____ ppm (by mass).
Given: Atomic mass : C = 12; H : 1; Cl = 35. 5 density of CHCl 3 = 1. 49g cm
−3

Q9.
XY is the membrane / partition between two chambers 1 and 2 containing sugar solutions of concentration c and 1

c2 (c1 > c2)molL

−1
. For the reverse osmosis to take place identify the correct condition
(Here p and p are pressures applied on chamber 1 and 2)
1 2

(A) Membrane/Partition; Cellophane, p 1 > π

(B) Membrane/Partition ; Porous. p 2 > π

(C) Membrane/Partition ; Parchment paper, p 1 > π

(D) Membrane/Partition : Cellophane, p 2 > π

Choose the correct answer from the option given below :

(1) B and D only (2) A and D only (3) A and C only (4) C only

Q10.
If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0. 3, then the observed
freezing point will be _____ % higher than the expected/theoretical freezing point. (Nearest integer).
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

Q11.
If the concentration of glucose (C 6H12O6) in blood is 0. 72 gL −1
, the molarity of glucose in blood is − × 10 −3
M

(Nearest integer):
Given : Atomic mass of C = 12, H = 1,
[ O = 16 u]

Q12.
If A 2B is 30% ionised in an aqueous solution, then the value of van't Hoff factor (i) is ______ ×10 . −1

Q13.
CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K . If CO2 exerts a partial
pressure of 0. 835 bar then x m mol of CO would dissolve in 0. 9 L of water. The value of x is _______. (Nearest
2

integer)
(Henry's law constant for CO at 298 K is 1. 67 × 10
2
3
)
bar

Q14.
The vapour pressures of pure liquids A and Bare 400 and 600 mm Hg respectively at 298 K. On mixing the two
liquids, the sum of their volumes is equal to the volume of the final mixture. The mole fraction of liquid B is 0.5 in
the mixture. The vapour pressure of the final solution, the mole fractions of components A and B in the vapour
phase, respectively are
(1) 500 mm Hg, 0.5, 0.5 (2) 450 mm Hg, 0.4, 0.6

(3) 450 mm Hg, 0.5, 0.5 (4) 500 mm Hg, 0.4, 0.6

Q15.
A set of solutions is prepared using 180 g of water as a solvent and 10 g of different non-volatile solutes A, B and C
. The relative lowering of vapour pressure in the presence of these solutes are in the order [Given, molar mass of
A = 100 g mol
−1
; B = 200 g mol
−1
; C = 10, 000 g mol
−1
]
(1) B > C > A (2) C > B > A (3) A > B > C (4) A > C > B

Q16.
An artificial cell is made by encapsulating 0.2M glucose solution within a semipermeable membrane. The osmotic
pressure developed when the artificial cell is placed within a 0.05M solution of NaCl at 300 K is _______ ×10 −1

bar. (nearest integer).

[Given : R = 0.083 Lbarmol −1 −1
K ] Assume complete dissociation of NaCl

Q17.
A solution is made by mixing one mole of volatile liquid A with 3 moles of volatile liquid B. The vapour pressure
of pure A is 200 mm Hg and that of the solution is 500 mm Hg. The vapour pressure of pure B and the least volatile
component of the solution, respectively, are :
(1) 1400 mmHg, A (2) 1400 mmHg, B (3) 600 mmHg, B (4) 600 mmHg, A

Q18.
When 1 g each of compounds AB and AB are dissolved in 15 g of water separately, they increased the boiling point
2

of water by 2.7 K and 1.5 K respectively. The atomic mass of A (in amu) is ____ ×10 −1
(Nearest integer)
(Given : Molal boiling point elevation constant is 0.5 K kg mol −1
)
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

Q19.
Elevation in boiling point for 1. 5 molal solution of glucose in water is 4 K. The depression in freezing point for 4. 5
molal solution of glucose in water is 4 K. The ratio of molal elevation constant to molal depression constant
(Kb/Kf ) is

Q20.
The mole fraction of a solvent in aqueous solution of a solute is 0.8. The molality (in mol kg −1
) of the aqueous
solution is:
(1) 13.88 × 10 −3
(2) 13.88 × 10 −1
(3) 13.88 (4) 13.88 × 10 −2

Q21.
The vapour pressure of 30% (w/v), aqueous solution of glucose is ________ mm Hg at 25∘
C.
[Given: The density of 30% (w/v) , aqueous solution of glucose is 1. 2 g cm
–3
and vapour pressure of pure water is
24 mm Hg .]
(Molar mass of glucose is 180 g mol
–1
)

Q22.
The mass of sodium acetate (CH 3 COONa) required to prepare 250 mL of 0. 35M aqueous solution is _____ g.(
Molar mass of CH 3 COONa is 82. 02 g mol
−1
) Round off to the nearest integer.

Q23.
Considering acetic acid dissociates in water, its dissociation constant is 6.25 × 10 . If 5 mL of acetic acid is −5

dissolved in 1 litre water, the solution will freeze at −x × 10 −2∘

C , provided pure water freezes at 0 ∘
C .
x = ______ . (Nearest integer) Given :
−1
(Kf ) = 1.86 K kg mol .
water

−1
density of acetic acid is 1.2 g mol .

−1
molar mass of water = 18 g mol .

−1
molar mass of acetic acid=60 gmol .

−3
density of water = 1 g cm

Acetic acid dissociates as CH 3COOH ⇌ CH3COO

⊖
+ H
⊕

Q24.
The osmotic pressure of blood is 7. 47 bar at 300 K. To inject glucose to a patient intravenously, it has to be isotonic
with blood. The concentration of glucose solution in gL −1
is (Molar mass of glucose = 180 g mol
−1
,
R = 0. 083 Lbar
−1
mol
−1
) (Nearest integer)

Q25.
At 35 o
C, the vapour pressure of CS , is 512mm Hg and that of acetone is 144 mmHg. A solution of CS in acetone
2 2

has a total vapour pressure of 600 mmHg . The false statement amongst the following is:
(1) Raoult's law is not obeyed by this system
(2) a mixture of 100mLCS and 100mL acetone has a volume < 200mL
2

(3) CS and acetone are less attracted to each other than to themselves
2

(4) heat must be absorbed in order to produce the solution at 35 o

C
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

Q26.
80 mole percent of MgCl is dissociated in aqueous solution. The vapour pressure of 1. 0 molal aqueous solution of
2

MgCl
2
at 38 o
C is _____ mm Hg . (Nearest integer)
Given: Vapour pressure of water at 38 o
C is 50 mm Hg

Q27.
A solution containing 2 g of a non-volatile solute in 20 g of water boils at 373. 52 K. The molecular mass of the
solute is _____ gmol . (Nearest integer)
−1

Given, water boils at 373 K, K for water = 0. 52K

b kg mol
−1

Q28.
Which of the following graph correctly represents the plots of K at 1 bar gases in water versus temperature?
H

(1) (2)

(3) (4)

Q29.
K2HgI
4
is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is:
(1) 1.6 (2) 1.8 (3) 20 (4) 22

Q30.
Molal depression constant for a solvent is 4.0 K kg mol −1
. The depression in the freezing point of the solvent for
0.03 mol kg
−1
solution of K 2SO4 is:
(Assume complete dissociation of the electrolyte)
(1) 0.36 K (2) 0.24 K (3) 0.18 K (4) 0.12 K

Q31.
Liquids A and B form an ideal solution in the entire composition range. At 350K, the vapour pressure of pure A and
pure B are 7 × 10 3
Pa and 12 × 10 3
Pa , respectively. The composition of the vapour in equilibrium with a solution
containing 40 mole percent of A at this temperature is:
(1) x A
= 0.4; xB = 0.6 (2) x A
= 0.76; xB = 0.24

(3) x A
= 0.28; xB = 0.72 (4) x A
= 0.37; xB = 0.63
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

Q32.
An aqueous solution of volume 300 cm
3
contains 0. 63 g of protein. The osmotic pressure of the solution at 300 K

is 1. 29 mbar . The molar mass of the protein is gmol . −1

Given : R = 0. 083 L barK

−1
mol
−1

Q33.
The osmotic pressure of a dilute solution is 7 × 10 5
Pa at 273 K. Osmotic pressure of the same solution at 283 K is
_______ × 10
4
Nm
−2
.(Nearest integer)

Q34.
Which one of the following statements regarding Henry's law is not correct?
(1) Different gases have different K (Henry's law constant) values at the same temperature
H

(2) The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the solution
(3) Higher the value of K at a given pressure, higher is the solubility of the gas in the liquids
H

(4) The value of K increases with increase of temperature and K is function of the nature of the gas
H H

Q35.
224 mL of SO 2(g)
at 298 K and 1 atm is passed through 100 mL of 0. 1 M NaOH solution. The non-volatile
solute produced is dissolved in 36 g of water. The lowering of vapour pressure of solution (assuming the solution is
dilute) (P° (H2O)
= 24 mm of Hg) is x × 10 −2
mm of Hg the value of x is (Integer answer)

Q36.
Ferrous sulphate heptahydrate is used to fortify foods with iron. The amount (in grams) of the salt required to
achieve 10ppm of iron in 100kg of wheat is ____________.
Atomic weight: Fe = 55.85; S = 32.00; O = 16.00

Q37.
A solution containing 10 g of an electrolyte AB in 100 g of water boils at 100.52
2
∘
C . The degree of ionization of the
electrolyte (α) is _______ ×10 . (nearest integer)
−1

[Given : Molar mass of AB 2 = 200 g mol

−1
, Kb (molal boiling point elevation const. of water) = 0.52 K kg mol , −1

boiling point of water = 100 ∘

C; AB2 ionises as AB 2 → A
2+
+ 2 B
−
]

Q38.
A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100. 52 ∘
C . The percentage association
of A is ___ .
(Round off to the Nearest integer)
Use : K for water = 0. 52 K
b kg mol
−1

Boiling point of water = 100°C

Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

Q39.
Liquid A and B form an ideal solution. The vapour pressure of pure liquids A and B are 350 and 750 mm Hg
respectively at the same temperature. If x and x are the mole fraction of A and B in solution while y and y are
A B A B

the mole fraction of A and B in vapour phase then :

(1) xA

xB
<
yA

yB
(2) xA

xB
=
yA

yB

(3) xA

xB
>
yA

yB
(4) (x A − yA) < (xB − yB)

Q40.
A solution of H 2 SO4 is 31. 4% H 2 SO4 by mass and has a density of 1. 25 g/ mL. The molarity of the H 2 SO4

solution is M (nearest integer) [Given molar mass of H 2 SO4 = 98 g mol ]

−1
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

ANSWER KEYS
1. (1) 2. (1) 3. (2) 4. (15) 5. (116) 6. (2) 7. (4) 8. (148)
9. (3) 10. (30) 11. (4) 12. (16) 13. (25) 14. (4) 15. (3) 16. (25)
17. (4) 18. (25) 19. (3) 20. (3) 21. (23) 22. (7) 23. (19) 24. (54)
25. (2) 26. (48) 27. (100) 28. (4) 29. (2) 30. (1) 31. (3) 32. (40535)
33. (73) 34. (3) 35. (18) 36. (4.95) 37. (5) 38. (100) 39. (3) 40. (4)

1. (1)
Freezing point depression refers to the lowering of the freezing point of solvent upon the addition of
solute. Boiling point elevation refers to the increase in the boiling point of a solvent upon the addition of a solute.
ΔTb = iKb m ⇒ 2 = iKb × 1. . . . . . . . . . . .(i)

ΔTf = iKf m ⇒ 2 = iKf × 2. . . . . . . . . . . . . . .(ii)

Dividing ( i

ii
) ,
Kb
1 =
2Kf

Kb = 2 Kf

2. (1) On adding non-volatile solute in a solvent, the freezing point of solution decreases.
0
Tf < T
f

F.P. of solution < F.P. of pure solvent

Also V.P. of solution decreases on adding nonvolatile solute in a solvent.

3. (2)
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

Mole fraction is defined as the amount (number of moles or molecules) of a constituent or component divided by
the total amount of all the constituent or component present.
Number of moles of compnent
Mole fraction= Total number of moles of all the components

Suppose we have a mixture with 3 components A, B and C.

nC
Mole fraction of C= n +nB +nC
A

Hence, the answer is option B.

4. (15)
Given, ΔT f
= − 24 C
0

Molar mass of Ethylene glycol= 62

ΔTf = i Kf × molality
W
24 = (1) × 1. 86 ×
62×18.6

W = 14880 gm

= 14. 880 kg

5. (116)
Molality of solution= moles

mass
of

of
solute

solvent
× 1000

Number of moles NaCl =

29.25

58.5
= 0. 5

Number of moles of MgCl 2

=
19

95
= 0. 2

0.5
NaCl = × 1000
51.75
0.2
MgCl = × 1000
2
51.75

(ΔTb )={(i1 m1 )+(i2 m2 )}kb

ΔTb = Elevation in boiling point

i = Van't Hoff factor
m = molality
kb = molal elevation constant
2×0.5×1000 3×0.2×1000
ΔTb= ( × )×0. 52
51.75 51.75

= 16. 077

Boiling point of sea water

= 116. 077°C

≈ 116°C (Nearest integer)

6. (2)
We know that for an non-electrolyte
ΔTf = Kf m where m = molality
1

ΔTfx kf ⋅mx Mx

= =
ΔT kf ⋅my 1
fy
My

My
1
⇒ =
4 Mx

⇒ Mx : My = 1 : 0. 25

7. (4)
Solutions JEE Main 2026 Crash Course
Daily Practice Problems MARKS

We know,
π = iCRT

π ∝ iC

A. 0. 500 M C 2
H5 OH(aq)(iC = 1 × 0. 5 = 0. 5) and 0. 25 M KBr(aq)(iC = 2 × 0. 25 = 0. 5)

B. 0. 100 M K 4
[Fe(CN)6 ](aq)(iC = 5 × 0. 1 = 0. 5) and 0. 100 M
FeSO4 (NH4 ) SO4 (aq)(iC = 5 × 0. 1 = 0. 5)
2

C. 0. 05 M K 4
[Fe(CN)6 ](iC = 5 × 0. 05 = 0. 25) (aq) and 0. 25 M NaCl(iC = 2 × 0. 25 = 0. 5) (aq)

D. 0. 15 M NaCl(aq)(iC = 2 × 0. 15 = 0. 3) and 0. 1 M BaCl2 (aq)(iC = 3 × 0. 1 = 0. 3)

E. 0. 02 M KCl. MgCl . 6H2 O(aq)(iC = 5 × 0. 02 = 0. 1)

2
and 0. 05 M KCl(aq)(iC = 2 × 0. 05 = 0. 1)
8. (148)
mole mass / Molar mass
Molarity = =
Volume in L Volume in L

x/85
−3
2. 6 × 10 =
0.67141

x = 0. 148 g

The number of ppm = mass

mass of

of
solute

solution
× 10
6

Mass of solution = density of solution×Volume of solution

DCM in ppm = 0.148

1.49×671.141
× 10
6

= 148 ppm .
9. (3)

Normal osmosis occurs from (2) to (1)

For reverse osmosis from (1) to (2)
Pressure : P 1 > π

∴ Answer [A & C] only

10. (30)
+ −
HA ⇋ H + A
1−α α α

Van't Hoff factor, i = 1 + α(n − 1)

= 1 + 0. 3(2 − 1)
Solutions JEE Main 2026 Crash Course
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= 1 + 0. 3

= 1. 3

ΔTf without considering dissociation = k f× molality

ΔTf without considering dissociation = ik f
× molality
′
= ΔT
f

ΔT
′

f
− ΔTf = 0. 3 (k f
× molality)
1
ΔT −ΔTf 0.3 ( k ×molality )
f f
= = 0. 3
ΔTf k ×molality
f

% value = 30
11. (4) [Glucose]= C(gm /ℓ)
=
0.72
= 4 × 10
−3
M
M(gm / mol) 180

12.

(16)
i = 1 + 2α

= 1 + 2 × (0.3)

= 1.6
−1
= 16 × 10

13. (25)
From Henry's law
Pgas = KH⋅ Xgas

n ( CO2 )
3
0. 835 = 1. 67 × 10 ×
0.9×1000

18

n(CO2 )= 0. 025

Millimoles of CO 2 = 0. 025 × 1000 = 25

14. (4)
Raoult’s law for ideal solution,
PTotal = PA + PB

∘ ∘
PTotal = xA × P + xB × P
A B

1 1
PTotal = × 400 + × 600 = 500 mm of Hg
2 2

Dalton’s law,
yA × PTotal = PA
0
xA ×P
A 1 400
yA = = × = 0.4
PTotal 2 500

yB = 1 − 0.4 = 0.6

15. (3)
wt ( gm )
Number of moles = MW
=
10

MW

Relative lowering in vapour pressure depends on no. of mole of solute greater the no. of moleof solute greater in
RLVP and smaller will be vapour pressure.
So order of vapour pressure is A > B > C.
Solutions JEE Main 2026 Crash Course
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16. (25)

+ −
NaCl ⟶ Na + Cl

0.05M 0.05M 0.05M

Total C1 = 0.05 + 0.05 = 0.1M(NaCl)

C2 = 0.2M( glucose )

π = (C2 − C1 ) RT

= (0.2 − 0.1) × 0.083 × 300

= 2.49bar

−1
= 24.9 × 10 bar

o o
17. PS = P
A
⋅ XA + P
B
⋅ XB

1 3
(4) 500 = 200 × + P
o
B
⋅
4 4
o
P = 600 mmHg
B

As P o

A
< P
o
B
⇒ A is least volatile.
18. (25) For AB
ΔTb = 2.7 K

2.7 = 1 × 0.5 × m

27
m =
5

Let molar mass of AB = x.

1/x 27
So × 1000 =
15 5

x = 12.34

For AB 2

ΔTb = 1.5 K

1.5 = 1 × 0.5 × m

m = 3

Let molar mass of AB 2

= y

1/y
So 15
× 1000 = 3

1000
y =
45

y = 22.22

Now let a and b be atomic masses of A and B respectively, then

A + b = 12.34 . . . (i)

A + 2 b = 22.22 . . . (ii)

B = 22.22 − 12.34 = 9.88

Now a = 12.34 − 9.88 = 2.46

−1 −1
= 24.6 × 10 = 25 × 10

19. (3)
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Elevation in boiling point ΔT b = ikb m1

Depression in freezing point ΔT f

= ikf m2

4 = ikb (1. 5)

4 = ikf (4. 5)

Dividing both:
kb 3
=
kf 1

Hence, The ratio of molal elevation constant to molal depression constant is 3:1
20. (3)
Since mole fraction of solvent is 0.8, it implies that 10 moles of aqueous solution will have 8 moles of water and 2
moles of solute.
∴ 2 moles of solute is present in → 8 moles of water
Or, 2moles of solute is present in →(8 × 18)gm of water
144 gm of water has 2 moles of solute
1 gm of water will have 2

144
moles of solute
1 kg of water will have 2

144
× 1000 = 13.88 moles

∴ Molality = 13.88 m
21. (23)
To calculate the vapour pressure of the 30% (w/v) aqueous solution of glucose, we can use Raoult's law, which
states that the vapour pressure of a component in an ideal solution is directly proportional to its mole fraction in
the solution.
Weight of solution = 100 × 1. 2 = 120 gm

Weight of water = 120 − 30 = 90 gm

Now using formula

P0 −P moles of glucose
=
P moles of water
30

24−P 180 3
= =
P 90 90
18

24 × 90 − P × 90 = 3 P

⇒ P = 23. 22

22. (7)
Given, Molarity= 0. 35 M
Moles = Molarity × Volume in litres
= 0. 35 × 0. 25

No. of moles = Mass/ Molar mass

Mass = moles ×molar mass
= 0. 35 × 0. 25 × 82. 02 = 7. 18 g

Ans. 7
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23. (19)
Mass of CH3 COOH = V × d

= 5ml × 1.2 g/ml

= 6gm

6
nCH = = 0.1 mol
3 COOH
60

0.1
mCH ≈ MCH = = 0.1M
3 COOH 3 COOH
1
− +
CH3 COOH ⇌ CH3 COO + H

C
C − Cα Cα Cα
2
Cα
Ka =
1 − α
2
1 − α ≈ 1 ⇒ Ka = Cα

−5
Ka 6.25 × 10
−3
α = √ = √ = 25 × 10
C 0.1

V.f. (i) = 1 + α(n − 1) = 1 + α(2 − 1) = 1 + α

−3
= 1 + 25 × 10 = 1.025

ΔTf = iKf m

= (1.025)(1.86)(0.1)

= 0.19
−2
= 19 × 10

24. (54)
Osmotic pressure, π = iCRT
i = van't hoff factor
C = concentration in molarity
R = universal gas constant
T = temperature
C = Molarity
moles
=
Litre

ω
= / Litre
GMω

π = iCRT

i = 1 for glucose as it neither associates nor dissociates in solution.

7. 47 = 1 × C × 0. 083 × 300

ω
7. 47 = 1 × × 0. 083 × 300
180
7.47×180
ω = = 54 g/ Lit
0.083×300

25. (2) P observed

= 600

0 0
PCal = P xA +P xB
A B

= 512x + 344 − 344x

= 168x + 344
Solutions JEE Main 2026 Crash Course
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= 512 (If x = 1 for maximum value)

Thus, Pcal < Pobserved

Thus' the process is deviated from Raoult's law, showing positive deviation from Raoult's law.
ΔH > 0 , i.e., is absorbed
26. (48)
One molal solution means one of solute present in one kg of solvent.
2+ −
MgCl ⇌ Mg + 2 Cl
2

1 0 0

1 − 0. 8 0. 8 1. 6

Hence, overall moles after dissociation = 2. 6

The relative lowering of vapour pressure
o
p −ps moles of solute
o =
p moles of solute+moles of solvent
p°−ps
2.6
=
p° 1000
+2.6
18

For dilute solution

p°−ps 2.6
=
p° 1000

18

p = 47. 66 ≃ 48 mm Hg

27. (100)
Elevation in boiling point:
⇒ ΔTb = 373. 52 − 373 = 0. 52

ΔTb = Kb ⋅ m

2 1
⇒ 0. 52 = 0. 52 × ×
Molar Mass of Solute −3
20×10

Molar Mass of solute= 100 g/ mol

28. (4) As temperature increases solubility first decrease then increase hence K first increase than decrease also at H

moderate temperature K value He > N H 2

> CH4 .
29. (2) K + 2−
2 Hgl4 ⇌ 2 K + [Hgl ]
4
;n = 3

i − 1 i − 1
∵α = ; 0.4 =
n − 1 3 − 1

i = 1.8

30. (1)
Depression in Freezing Point = ΔT f

ΔTf = i × kf × m

Molality = 0.03 mol/kg

i = 3; kf = 4 K kg/mol

ΔTf = 3 × 4 × 0.03 = 0.36 K

31. (3) Since, P 0

A
= 7 × 10 P a; P
3

B
0
= 12 × 10 P a
3
and X A = 0.4 ,X B = 1 − 0.4 = 0.6

According to Raoult's Law: P T

= P
A
0
XA + P
0

B
XB

3 3
PT =(7 × 10 )(0.4)+(12 × 10 )(0.6)
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3
PT = 10 × 10 P a

Now, P A
0
XA = P T x A
0
P XA 3
A 7×10 ×0.4
xA = = ⇒ 0.28
PT 4
10

xB = 1 − xA ⇒ 1 − 0.28 ⇒ 0.72

32. (40535)
The osmotic pressure of a non-electrolytic solution can be calculated as follows,
π = CRT

π = osmotic pressure
= molarity=
Number of moles
C
Volume of solution in L

−3 0.63
(1. 29 × 10 )= × (0. 083) × 300
(MW)(0.3)

0.63×0.083×300
MW =
−3
(0.3)× ( 1.29×10 )

= 40534. 88

≈ 40535 (Nearest integer)

33. (73)
Osmotic pressure can be calculated as,
π = CRT

π is the osmotic pressure

C is the molar concentration of the solute in the solution
R is the universal gas constant
Here given,

T1 = 273K

T2 = 283K

π1 = CRT1

By putting the values in this equation, we get,

5
7 × 10 = C × R × 273
5
7×10
CR =
273

π2 = CRT2
5
7×10
= × 283
273

4 −2
= 72. 56 × 10 Nm

34. (3)
p = KH . x

Where K H = Henry law constant

p = partial pressure
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x = amount soluble
Henry's constant increases with increase in temperature while it decreases with increase in solubility.
Hence value of K increases as solubility of gas increases is a wrong statement.
H

35. (18)
Sol (1)
SO2 + 2 NaOH → Na2 SO3 + H2 O

224
= 9. 2 m mol 10 mmol 5 mmol
0.0821×298

(L. R. ) (i = 3)

0 s 0
P − P = iXsolute P
−3
3 ×5×10
= 24 ×
2

= 0. 18 = 18 × 10
−3
mm of Hg
36. (4.95)
Formula of ppm is as follow-
weight of solute
6
ppm = × 10
weight of solution

M ass of F e(ing)
6
10 = × 10
100×1000

Or mass fe = 1g
F eSO4 . 7H2 O(M = 278)

56g in 1 mole
1
1g − mole
56

1
× 278g = 4.96g
56

PPM is a concentration term and its full form is "parts per million" and it also can be expressed as milligrams per
liter (mg/L). This measurement is the mass of a chemical or contaminate per unit volume of water.
37. (5)
+2 ⊖
AB2 → A + 2 B

i = 1 + (3 − 1)α

i = 1 + 2α

ΔTb = kb im

10

200
0.52 = 0.52(1 + 2α)
100

1000

10
1 = (1 + 2α)
20

2 = 1 + 2α

α = 0.5

Ans. α = 5 × 10 −1

38. (100)
0
ΔTb = Tb − T
b

100. 52 − 100

= 0. 52°C

α
i =(1 − )
2
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∵ ΔTb = iKb × m

α
0. 52 =(1 − )×0. 52 × 2
2

α = 1

So, percentage association = 100%.

39. (3)
o o
P < P
A B
o
P
A
< 1
o
P
B
o
y P xA
A A
=
o
y P xB
B B

y
A

y
B

xA

xB

40. (4)
Given, Density= 1. 25 g/ mL,
Molar mass of H 2 SO4 = 98 g mol
−1

Molarity is defined as no. of moles of solute present in one litre of solution. Thus,
Molarity= No. of

Volume
moles

of
of

solution
solute

in L

No. of moles= mass/ molar mass

n
solute
M = × 1000
V
31.4
( )
98

= × 1000
100
( )
1.25

= 4. 005 ≈ 4