11-12-2025

1803CJA101029250116 JM

PART-1 : PHYSICS

SECTION-I

1) A nucleus at rest disintegrates into two smaller nuclei with their masses in the ratio of 2:1. After
disintegration they will move :-

(A) In opposite directions with speed in the ratio of 1:2 respectively

(B) In opposite directions with speed in the ratio of 2:1 respectively
(C) In the same direction with same speed.
(D) In opposite directions with the same speed.

2) The following figure represents two biconvex lenses L1 and L2 having focal length 10 cm and 15

cm respectively. The distance between L1 & L2 is :

(A) 10 cm
(B) 15 cm
(C) 25 cm
(D) 35 cm

3) The temperature of a gas is –78°C and the average translational kinetic energy of its molecules is
K. The temperature at which the average translational kinetic energy of the molecules of the same
gas becomes 2K is :

(A) –39°C
(B) 117°C
(C) 127°C
(D) –78°C

4) A hydrogen atom in ground state is given an energy of 10.2 eV. How many spectral lines will be
emitted due to transition of electrons ?

(A) 6
(B) 3
(C) 10
(D) 1
5) The magnetic field in a plane electromagnetic wave is By = (3.5 × 10–7) sin (1.5 × 103x + 0.5
×1011t)T. The corresponding electric field will be

3 11 –1
(A) Ey = 1.17 sin (1.5 × 10 x + 0.5 × 10 t)Vm
3 11 –1
(B) Ez = 105 sin (1.5 × 10 x + 0.5 × 10 t)Vm
3 11 –1
(C) Ez = 1.17 sin (1.5 × 10 x + 0.5 × 10 t)Vm
3 11 –1
(D) Ey = 10.5 sin (1.5 × 10 x + 0.5 × 10 t)Vm

6) A square loop of side 15 cm being moved towards right at a constant speed of 2 cm/s as shown in
figure. The front edge enters the 50 cm wide magnetic field at t = 0. The value of induced emf in the

loop at t = 10 s will be :

(A) 0.3 mV
(B) 4.5 mV
(C) Zero
(D) 3 mV

7) Two cars are travelling towards each other at speed of 20 ms–1 each. When the cars are 300 m
apart, both the drivers apply brakes and the cars retard at the rate of 2 ms–2. The distance between
them when they come to rest is :

(A) 200 m
(B) 50 m
(C) 100 m
(D) 25 m

8) If a p-n junction is forward biased, then which of the following figures gives the correct direction
of current inside the semiconductor?

(A)

(B)
(C)

(D)

9) The excess pressure inside a soap bubble is thrice the excess pressure inside a second soap
bubble. The ratio between the volume of the first and the second bubble is :

(A) 1 : 9
(B) 1 : 3
(C) 1 : 81
(D) 1 : 27

10) The de-Broglie wavelength associated with a particle of mass m and energy E is . The
dimensional formula for Planck's constant is :

(A) [ML–1T–2]
(B) [ML2T–1]
(C) [MLT–2]
(D) [M2L2T–2]

11) A satellite of 103 kg mass is revolving in circular orbit of radius 2R. If energy is supplied
to the satellite, it would revolve in a new circular orbit of radius : (use g = 10m/s2, R = radius of
earth)

(A) 2.5 R
(B) 3 R
(C) 4 R
(D) 6 R

12) The effective resistance between A and B, if resistance of each resistor is R, will be

(A)
(B)

(C)

(D)

13) Five charges +q, +5q, –2q, +3q and –4q are situated as shown in the figure. The electric flux

due to this configuration through the surface S is :

(A)

(B)

(C)

(D)

14) A proton and a deutron (q= +e, m = 2.0u) having same kinetic energies enter a region of
uniform magnetic field , moving perpendicular to . The ratio of the radius rd of deutron path to the
radius rp of the proton path is :

(A) 1 : 1
(B)
(C)
(D)

15) UV light of 4.13 eV is incident on a photosensitive metal surface having work function 3.13 eV.
The maximum kinetic energy of ejected photoelectrons will be :

(A) 4.13 eV
(B) 1 eV
(C) 3.13 eV
(D) 7.26 eV

16) The diagram below shows a radioactive sample contained in a lead housing. Which diagram best
represents the trajectory of the emitted particles; alpha α (positively charged), beta β (negatively
charged) and gamma γ (neutral) through the electric filed? (the options below are in the order A, B,
C)

(A) α, β, γ
(B) β, γ, α
(C) γ, β, α
(D) γ, α, β

17) A spherical ball of radius 1×10–4 m and density 105 kg/m3 falls freely under gravity through a
distance h before entering a tank of water, If after entering in water the velocity of the ball does not
change, then the value of h is approximately : (The coefficient of viscosity of water is 9.8 × 10–6 N
s/m2)

(A) 2296 m
(B) 2249 m
(C) 2518 m
(D) 2396 m

18) A 1 kg mass is suspended from the ceiling by a rope of length 4m. A horizontal force 'F' is
applied at the mid point of the rope so that the rope makes an angle of 45° with respect to the

vertical axis as shown in figure. The magnitude of F is :

(A)

(B) 1 N

(C)

(D) 10 N
19) A real gas within a closed chamber at 27°C undergoes the cyclic process as shown in figure. The
gas obeys PV3 = RT equation for the path A to B. The net work done in the complete cycle is

(assuming R = 8 J/molK) :

(A) 225 J
(B) 205 J
(C) 20 J
(D) –20 J

20)
In the truth table of the above circuit the value of X and Y are :

(A) 1, 1
(B) 1, 0
(C) 0, 1
(D) 0, 0

SECTION-II

1) A straight magnetic strip has a magnetic moment of 44 Am2. If the strip is bent in a semicircular

shape, its magnetic moment will be ………. Am2. (Given π = )

2) A particle of mass 0.50 kg executes simple harmonic motion under force F = –50(Nm–1)x. The time

period of oscillation is . The value of x is …………… (Given π = )

3) An electric field exists in space. A cube of side 2 m is placed in the space as per
figure given below. The electric flux through the cube is ……………… Nm2/C.
4) To determine the resistance (R) of a wire, a circuit is designed below, The V-I characteristic curve
for this circuit is plotted for the voltmeter and the ammeter readings as shown in figure. The value of

R is ………… Ω.

5) Monochromatic light of wavelength 500 nm is used in Young's double slit experiment. An

interference pattern is obtained on a screen When one of the slits is covered with a very thin glass
plate (refractive index = 1.5), the central maximum is shifted to a position previously occupied by
the 4th bright fringe. The thickness of the glass-plate is ……………….μm.

PART-2 : CHEMISTRY

SECTION-I

1) The candela is the luminous intensity, in a given direction, of a source that emits monochromatic

radiation of frequency 'A' × 1012 hertz and that has a radiant intensity in that direction of watt
per steradian. 'A' and 'B' are respectively

540 and
(A)

(B) 540 and 683

450 and
(C)

(D) 450 and 683

2) The correct stability order of the following resonance structures of CH3 –CH = CH–CHO is
(A) II > III > I
(B) III > II > I
(C) I > II > III
(D) II > I > III

3) Total number of stereo isomers possible for the given structure:

(A) 8
(B) 2
(C) 4
(D) 3

4) The correct increasing order for bond angles among BF3, PF3 and CℓF3 is :

(A) PF3 < BF3 < CℓF3

(B) BF3 < PF3 < CℓF3
(C) CℓF3 < PF3 < BF3
(D) BF3 = PF3 < CℓF3

5) Match List-I with List-II.

List-I List-II
(Test) (Observation)

Yellow orange or orange red

(A) Br2 water test (I)
precipitate formed

Ceric ammonium
(B) (II) Reddish orange colour disappears
nitrate test

(C) Ferric chloride test (III) Red colour appears

Blue, Green, Violet or Red colour

(D) 2, 4-DNP test (IV)
appear

Choose the correct answer from the options given below:

(A) A-I, B-II, C-III, D-IV
(B) A-II, B-III, C-IV, D-I
(C) A-III, B-IV, C-I, D-II
(D) A-IV, B-I, C-II, D-III

6) Match List-I with List-II.

List-I List-II
(Cell) (Use/Property/Reaction)

A. Leclanche cell I. Converts energy of combustion into electrical energy

B. Ni-Cd cell II. Does not involve any ion in solution and is used in hearing aids

C. Fuel cell III. Rechargeable

D. Mercury cell IV. Reaction at anode Zn → Zn2+ + 2e–

Choose the correct answer from the options given below:

(A) A-I, B-II, C-III, D-IV
(B) A-III, B-I, C-IV, D-II
(C) A-IV, B-III, C-I, D-II
(D) A-II, B-III, C-IV, D-I

7) Match List-I with List-II.

List-I List-II

A. K2[Ni(CN)4] I. sp3

B. [Ni(CO)4] II. sp3d2

C. [Co(NH3)6]Cl3 III. dsp2

D. Na3[CoF6] IV. d2sp3

Choose the correct answer from the options given below:
(A) A-III, B-I, C-II, D-IV
(B) A-III, B-II, C-IV, D-I
(C) A-I, B-III, C-II, D-IV
(D) A-III, B-I, C-IV, D-II

8) The coordination environment of Ca2+ ion in its complex with EDTA4– is :

(A) tetrahedral
(B) octahedral
(C) square planar
(D) trigonal prismatic

9) The incorrect statement about Glucose is :

(A) Glucose is soluble in water because of having aldehyde functional group

(B) Glucose remains in multiple isomeric form in its aqueous solution
(C) Glucose is an aldohexose
(D) Glucose is one of the monomer unit in sucrose

10)
In the above reaction product 'P' is

(A)

(B)

(C)

(D)

11) Which of the following compound can give positive iodoform test when treated with aqueous
KOH solution followed by potassium hypoiodite.

(A)

(B)

(C) CH3CH2CH2CHO

(D)

12) For a sparingly soluble salt AB2, the equilibrium concentrations of A2+ ions and B– ions are 1.2 ×
10–4 M and 0.24 × 10–3 M, respectively. The solubility product of AB2 is :

(A) 0.069 × 10–12

(B) 6.91 × 10–12
(C) 0.276 × 10–12
(D) 27.65 × 10–12

13) Major product of the following reaction is

(A)

(B)

(C)
(D)

14) Given below are two statements :

Statement-I : The higher oxidation states are more stable down the group among transition
elements unlike p-block elements.
Statement-II : Copper can not liberate hydrogen from weak acids.
In the light of the above statements, choose the correct answer from the options given below :

(A) Both Statement I and Statement II are false

(B) Statement I is false but Statement II is true
(C) Both Statement I and Statement II are true
(D) Statement I is true but Statement II is false

15) The incorrect statement regarding ethyne is

(A) The C–C bonds in ethyne is shorter than that in ethene

(B) Both carbons are sp hybridised
(C) Ethyne is linear
(D) The carbon-carbon bonds in ethyne is weaker than that in ethene

16) Match List-I with List-II.

List-I
List-II
(Eleme
(Electronic Configuration)
nt)

A. N I. [Ar] 3d104s2 4p5

B. S II. [Ne] 3s2 3p4

C. Br III. [He] 2s2 2p3

D Kr IV. [Ar] 3d10 4s2 4p6

Choose the correct answer from the options given below :
(A) A-IV, B-III, C-II, D-I
(B) A-III, B-II, C-I, D-IV
(C) A-I, B-IV, C-III, D-II
(D) A-II, B-I, C-IV, D-III

17) Match List-I with List-II.

 List-I List-II

A. Meltingpoint [K] I. Tl > In > Ga > Al > B

B. Ionic Radius [M+3/pm] II. B > Tl > Al ≈ Ga > In

–1
C. ΔiH1[kJ mol ] III. Tl > In > Al > Ga > B

D AtomicRadius [pm] IV. B > Al > Tl > In > Ga

Choose the correct answer from the options given below :
(A) A-III, B-IV, C-I, D-II
(B) A-II, B-III, C-IV, D-I
(C) A-IV, B-I, C-II, D-III
(D) A-I, B-II, C-III, D-IV

18) Which of the following compounds will give silver mirror with ammoniacal silver nitrate?
(A) Formic acid
(B) Formaldehyde
(C) Benzaldehyde
(D) Acetone
Choose the correct answer from the options given below :

(A) C and D only

(B) A, B and C only
(C) A only
(D) B and C only

19) Conductivity of an aqueous solution of 0.1 M HX (a weak mono-protic acid) is 5 × 10–4 Sm–1.
Given :

Find pKa of HX.

(A) 6
(B) 7
(C) 8
(D) 9

20) The electronic configuration of Einsteinium is : (Given atomic number of Einsteinium = 99)

0
(A) [Rn] 5f12 6d 7s2
0
(B) [Rn] 5f11 6d 7s2
0
(C) [Rn] 5f13 6d 7s2
0
(D) [Rn] 5f10 6d 7s2

SECTION-II

1) The vapour pressure of pure benzene and methyl benzene at 27°C is given as 80 Torr and 24 Torr,
respectively. The mole fraction of methyl benzene in vapour phase, in equilibrium with an equimolar
mixture of those two liquids (ideal solution) at the same temperature is____× 10–2 (nearest integer)

2) The blue pigment prussian blue is an iron complex with formula . Value of x + y is
_______

3) Consider the following first order gas phase reaction at constant temperature
A(g) → 2B(g) + C(g)
If the total pressure of the gases is found to be 200 torr after 23 sec. and 300 torr upon the complete
decomposition of A after a very long time, then the rate constant of the given reaction is____× 10–2
s–1 (nearest integer) [Given : log10(2) = 0.301]

4) In the given TLC, the distance of spot A & B are 5 cm & 7 cm, from
the bottom of TLC plate, respectively.
Rf value of B is x × 10–1 times more than A. The value of x is_____.

5) When ΔHvap = 30 kJ/mol and ΔSvap = 75J mol–1 K–1, then the temperature of vapour, at one
atmosphere is ______K.

PART-3 : MATHEMATICS

SECTION-I

1) The straight lines L1 and L2 pass through the origin and trisect the line segment of the line L: 9x +
5y = 45 between the axes. If m1 and m2 are the slopes of the lines L1 and L2, then the point of
intersection of the line y = (m1 + m2)x with L lies on

(A) 6x + y = 10
(B) 6x– y = 15
(C) y –x = 5
(D) y –2x = 5

2) The surface area of a balloon of spherical shape being inflated, increases at a constant rate. If
initially, the radius of balloon is 3 units and after 5 seconds,, it becomes 7 units, then its radius after
9 seconds is :
(A) 9
(B) 10
(C) 11
(D) 12

3) The sum of absolute maximum and absolute minimum values of the function f(x) = |2x2 + 3x – 2| +
sin x cos x in the interval [0, 1] is :

(A)

(B)

(C)

(D)

4) The integral is equal to (where c is a constant of integration)

(A)

(B)

(C)

(D)

5)

The sum of all the 4-digit distinct numbers that can be formed with the digits 1, 2, 2 and 3 is:

(A) 26664
(B) 122664
(C) 122234
(D) 22264

6) If g(x) = x2 + x – 1 and (gof)(x) = 4x2 – 10x + 5, then f is equal to

(A)

(B)

(C)
(D)

7) Five numbers are in A.P., whose sum is 25 and product is 2520. If one of these five numbers is
, then the greatest number amongst them is :

(A)

(B) 27
(C) 16
(D) 7

8) Let α be a root of the equation x2 + x + 1 = 0 and the matrix , then the

matrix A31 is equal to:

(A) A3
(B) A
(C) A2
(D) I3

9) If the distance between the foci of an ellipse is 6 and the distance between its directrices is 12,
then the length of its latus rectum is :

(A)
(B) 2
(C)

(D)

10) The area of the region, enclosed by the circle x2 + y2 = 2 which is not common to the region
bounded by the parabola y2 = x and the straight line y = x, is :

(A)

(B)

(C)

(D)

11) If the system of linear equations

2x + 2ay + az = 0
2x + 3by + bz = 0
2x + 4cy + cz = 0,
where a, b, c ∈ R are non-zero and distinct; has a non-zero solution, then :

(A) a, b, c are in A.P.

(B) a + b + c = 0
(C) a, b, c are in G.P.

(D)
are in A.P.

12) is equal to :

(A) e

(B)

(C) 0
(D) e–e2

13) Let z be a complex number such that the real part of is zero. Then, the maximum value of
|z –(6+8i)| is equal to :

(A) 12
(B) ∞
(C) 10
(D) 8

14) If the variance of the frequency distribution is 160, then the value of c ∈ N is

x c 2c 3c 4c 5c 6c

f 2 1 1 1 1 1
(A) 5
(B) 8
(C) 7
(D) 6

15) Let the range of the function

f (x) = , x ∈ R be [a, b].

If α and β are respectively the A.M. and the G.M. of a and b, then is equal to:

(A)
(B) 2
(C)
(D) π
16) If loge y = 3 sin–1x, then (1 – x)2 y" –xy' at x = is equal to :

(A) 9eπ/6
(B) 3eπ/6
(C) 3eπ/2
(D) 9eπ/2

17) If an unbiased dice is rolled thrice, then the probability of getting a greater number in the ith roll
than the number obtained in the (i–1)th roll, i = 2, 3, is equal to :

(A) 3/54
(B) 2/54
(C) 5/54
(D) 1/54

18) Let , , , where α and β are integers and αβ = –6. Let the
values of the ordered pair (α, β) for which the area of the parallelogram of diagonals and

is , be (α1, β1) and (α2, β2).

Then – α2β2 is equal to

(A) 17
(B) 24
(C) 21
(D) 19

19) The set of all values of k for which is the interval

(A)

(B)

(C)

(D)

20) The sum of the coefficient of x2/3 and x–2/5 in the binomial expansion of is :

(A) 21/4
(B) 69/16
(C) 63/16
(D) 19/4
 SECTION-II

1) Let and [t] be the greatest integer < t. Then the number of points, where the function f(x)
= [a + 13 sin x], x ∈ (0, π) is not differentiable, is ____

2) A circle passing through the point P(α, β) in the first quadrant touches the two coordinate axes at
the points A and B. The point P is above the line AB. The point Q on the line segment AB is the foot
of perpendicular from P on AB. If PQ is equal to 11 units, then the value of αβ is______

3) Let the plane ax + by + cz + d = 0 bisect the line joining the points (4,–3,1) and (2, 3, –5) at the
right angles. If a, b, c, d are integers, then the minimum value of (a2 + b2 + c2 + d2) is

4) Let ƒ(x) and g(x) be two functions satisfying ƒ(x2) + g(4 – x) = 4x3 and g(4 – x) + g(x) = 0, then the

value of is

5) The number of points where the function [t] denotes the

greatest integer ≤ t, is discontinuous is ______ .
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C B D B C C B D B D B B C B B C D B A

SECTION-II

Q. 21 22 23 24 25
A. 28 22 16 2500 4

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B C C B C D B A A B B B C D B C B D B

SECTION-II

Q. 46 47 48 49 50
A. 23 7 3 15 400

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A B A A B C A C B D A A C A D C D A A

SECTION-II

Q. 71 72 73 74 75
A. 25 121 28 512 7
 SOLUTIONS

PART-1 : PHYSICS

1) By conservation of momentum
pi = pf
0 = m1 u1 + m2 u2

as
move in opposite direction with speed ratio 1 : 2

2)
D = f1 + f2 = 25 cm
Paraxial parallel rays pass through focus and ray from focus of convex lens will become
parallel

3) K.E =
Ti = –78°C → 273 + [–78°C] = 195K
K.E α T
To double the K.E energy temp also become double
Tf = 390 K
Tf = 117°C

4) Hydrogen will be in first excited state therefore it will emit one spectral line corresponding
to transition b/w energy level 2 to 1

5) E0 = B0C
E0 = 3 × 108 × (3.5 × 10–7) sin (1.5 × 103x + 0.5 ×1011t)
E0 = 105 sin (1.5 × 103x + 0.5 × 1011t)Vm–1
Data inconsistent while calculating speed of wave. You can challenge for data.

6) At t = 10 sec complete loop is in magnetic field therefore no change in flux

e = 0 for complete loop

7)

Apply (v2 = u2 + 2as)relative

O = (40)2 + 2(–4)(S)
S = 200 m
Remaining distance = 300 – 200 = 100 m

8) In a forward biased p-n junction diode, p junction is connected to +ve terminal of battery &
n-junction is connected to –ve terminal.
So holes are attracted to negative terminal and electrons are attracted to positive terminal,
both constituting the current direction from p to n side.

Direction of movement of holes"

p to n
current due to holes : p to n
direction of electrons : n to p
current due to electrons : p to n.
Thus, direction of current is from p side to n-side.

9)

r2 = 3r1

10) or E = hν
11) Total energy =

if energy = is added then

where r is new radius of revolving and

(m = 103 kg)

r = 6R

12) From symmetry we can remove two middle resistance.

New circuit is

13) As per gauss theorem,

14) In uniform magnetic field,

Since same K.E

∴ γd : γp =

15) Ephoton = (work function) + [Link]

∴ 4.13 = 3.13 + [Link]
∴ [Link] = 1 eV

16) +ve charge experience a force in the direction of electric field while –ve charge in the
direction opposite to electric field.

17)

⇒ VT = 224.5
when ball fall from height (h)

18) T1sin45° = F
T1 cos45° = T2 = 1×g

∴ tan45° =
∴ F = 10N

19) WAB = (Assuming T to be constant)

= 225 J
WBC =
WCA = 0
∴ Wcycle = 205 J
Note : Data is inconsistent in process AB.
So needs to be challenged.

20) For x

For y

21) Magnetic moment of straight wire = mxl = 44

Magnetic moment of arc

=m×2r

=m×

22) m = 0.5 kg
F = – 50 (x)
ma = (–50x)
0.5 a = – 50x
a = (–100x)
 W2 = 100 ⇒ (w = 10)

23)

dnet = ϕin + ϕout = –16 + 32 = 16 Nm2/c

24)
E = 4V, I = 2mA

⇒ 20R = 40000 + 4R
16R = 40000
R = 2500 Ω

25) (μ – 1) t = nλ
(1.5 – 1) t = 4 × 500 × 10–9 m
t = 4000 × 10–9 m
t = 4μm

PART-2 : CHEMISTRY

26)

The candela is the luminous intensity of a source that emits monochromatic radiation of
frequency radiation of frequency 540 × 1012 Hz and has a radiant intensity in that direction of

w/sr. It is unit of Candela.

27)
Stability order III > II > I

28) Question is Asking About :

No. of stereoisomers

Concept :
Compound showing both Geometrical isomerism and optical isomerism.

Solution / Explanation :

One chiral centre and one double bond showing Geometrical isomerism, thus for 2n n = 2 here
​Total Stereoisomers 4.

29)

Order of bond angle is

CℓF3 < PF3 < BF3

30)
(A) Br2 water test is test of unsaturation in which reddish orange colour of bromine water
disappears.
(B) Alcohols given Red colour with ceric ammonium nitrate.
(C) Phenol gives Violet colour with natural ferric chloride.
(D) Aldehyde & Ketone give Yellow/Orange/Red Colour compounds with 2, 4-DNP i.e., 2, 4-
Dinitrophenyl hydrazine.

31) A-IV, B-III, C-I, D-II

32) (A)
Ni2+ : [Ar]3d8 4s° , (CN– is S.F.L)
Pre hybridization state of Ni+2

(B) [Ni(CO)4]
Ni : [Ar] 3d8 4s2
CO is S.F.L , so pairing occur
Pre hybridization state of Ni

(C)

With Co3+, NH3 act as S.F.L

(D) Na3 [CoF6]

Co3+ : [Ar] 3d6 ( : W.F.L)

33) EDTA4– → Hexadentate ligand

[Ca(EDTA)]2–
So Coordination environment is octahedral

34) Glucose is soluble in water due to presence of alcohol functional group and extensive
hydrogen bonding.
Glucose exist is open chain as well as cyclic forms in its aqueous solution.
Glucose having 6C atoms so it is hexose and having aldehyde functional group so it is aldose.
Thus, aldohexose.
Glucose is monomer unit in sucrose with fructose.
35)
Due to NGP effect of phenyl ring Nucleophilic substitution of Br will occurs.

36)

37)

38)
39) On moving down the group in transition elements, stability of higher oxidation state
increases, due to increase in effective nuclear charge.
⇒
⇒
SRP : Cu2+ > H+
Cu can't liberate hydrogen gas from weak acid.

40) The carbon-carbon bonds in ethyne is stronger than that in ethene.

(H–C ≡ C–H) Ethyne is linear and carbon atoms are SP hybridised.

41) (A)
(B)
(C)
(D)

42) Melting point : B > Aℓ > Tℓ > In > Ga

Ionic radius (M+3/pm) : Tℓ > In > Ga > Aℓ > B

: B > Tℓ > Aℓ Ga > In

Atomic radius (in pm) : Tℓ > In > Aℓ > Ga > B

43) Apart from aldehyde, Formic acid also gives silver mirror test with
ammonical silver nitrate.

44) α =

=
Ka = α2C = 10–9
pKa = 9

0
45) Einsteinium (atomic No = 99) : [Rn] 5f11 6d 7s2

46) Xmethylbenzene = 0.5

47)

(NH4)2CO3 NH3 + CO2 + H2O

(NH4)2Cr2O7 N2 + Cr2O3 + 4H2O
NH4NO2 N2 + 2H2O
2NH4ClO4 N2 + Cl2 + 2O2 + 4H2O
NH4Cl NH3 + HCl
(NH4)2S NH3 + H2S
(NH4)2HPO4 NH3 +H2O + HPO3
(NH4)2SO4 NH3 + H2SO4
NH4NO3 N2O + 2H2O

48) A(g) → 2B(g) + C(g)

P0 = 100

49)

(Rf)B = 1.5 (Rf)A

x = 15

50) At equilibrium ΔGPT = 0

PART-3 : MATHEMATICS

51)

=
y =(m1 + m2)x

y=

Point of intersection with L is

52) Let r be the radius of spherical balloon

S = Surface area
S = 4πr2

(constant)
2
4πr = kt + C (C is constant of integration)
For t = 0,r = 3 ⇒ 36π = C
For t = 5, r = 7 ⇒ K = 32π
4πr2 = 32πt + 36π
r2 = 8t + 9
for t = 9
r2 = 81
r=9

53) f(x) = |2x2 + 3x – 2| + sin x cos x f(x) = |(2x – 1)(x + 2)| + sin x cos x

For

For

f (x) local minima at x = and

local maxima at x = 1

54)
(2x – 1)2 + 5 = t2
2(2x – 1) 2dx = 2t dt

So =

55)

Digits are 1, 2, 2, 3

total distinct numbers .

total numbers when
1 at unit place is 3.
2 at unit place is 6
3 at unit place is 3.
So, sum = (3 + 12 + 9) (103 + 102 + 10 + 1)
= (1111) × 24 = 26664

56) g(x) = x2 + x–1

g (f(x)) = 4 x2 – 10x + 5
= (2x –2)2 + (2 – 2x) –1
= (2 – 2x)2 + (2 – 2x) –1
⇒ f(x) = 2 – 2x

57) Let the A.P is

a – 2d, a – d, a, a + d, a + 2d
∵ sum = 25 ⇒ a = 5
Product = 2520
(25 – 4d2) (25 –d2) = 504
4d4 – 125d2 + 121 = 0

⇒ d2 = 1,

d= 1 is rejected because none of the term can be .

⇒d=

⇒ AP will be –6, , 5,
Largest term is 16.

58) x2 + x + 1 = 0
α=ω
α2 = ω2

⇒ A4 = A2 . A2 = I3
A31 = A28. A3 = A3.

59) Given 2ae = 6 ⇒ ......(1)

and .......(2)
from (1) and (2)

6e2 = 3 ⇒

⇒
Now, b2 = a2 (1 – e2)

⇒ b2 = 18

Length of L.R =

60)
 Required Area :

61) For non-zero solution

=0
⇒ (3b – 2a) (c –a) – (b – a) (4c – 2a) = 0
⇒ 2ac = bc + ab

⇒ Hence are in A.P.

62)

= (–e) × (–1) =e

63)

⇒ 2|z|2 = 8 ⇒ |z| = 2

64)

x C 2C 3C 4C 5C 6C

f 2 1 1 1 1 1

Var (x) =
–

65)

f(x) =

= =

66)

,
67)

Favourable cases =
Total out comes = 63

Probability of getting greater number than previous one =

68)

Area of parallelogram =

A=
so,

and αβ = –6
and given α, β are integers
so,
α = –3, β = 2
or
α = 3, β = –2

69) Let S =

⇒
=

70)

Tr + 1 =

for coefficient of x2/3, put

⇒r=5

∴ Coefficient of x2/3 is =

For coefficient of x–2/5, put

⇒r=6

Coefficient of x–2/5 is 9C6

Sum = 9C5 + 9C6 =

71)

f(x) = [a + 13 sin x], x ∈ (0, π)

For [n sin x]; Total number of non differentiable points are = 2n –1 for
So number of non differentiable points for [13 sin x] ⇒ 25 Points

72)
Let equation of circle is
which is passing through P (α,β)
then

Here equation of AB is x + y = a
Let Q (α', β') be foot of perpendicular of P on AB
PQ2 =

242 = 2αβ
⇒ αβ = 121

73)
Plane is 1(x – 3) – 3(y – 0) + 3(z + 2) = 0
x – 3y + 3z + 3 = 0
(a2 + b2 + c2 + d2)min = 28

74) {Even function}

= 2(256 – 0) = 512

75)