29-11-2025

1001CJM202023250009 JM

PART-1 : PHYSICS

SECTION-I

1) Two charges q1 and q2 are placed 30 cm apart, as shown in the figure. A third charge q3 is moved
along the arc of a circle of radius 40 cm from C to D. The change in the potential energy of the

system is k, where k is :-

(A) 8q2
(B) 6q2
(C) 8q1
(D) 6q1

2) Two positively charged infinitely long wires

(λ1 > λ2) are placed parallel to each other at
x = –a and x = +a as in figure. find the x – coordinate of a point at which electric field is zero.

(A)

(B)

(C)

(D)

3) A copper ball of density ρc and diameter d is immersed in oil of density ρ0. What charge should be
present on the ball, so that it could be suspended in the oil, if a homogeneous electric field E is
applied vertically upward ?
(A)

(B)

(C)

(D)

4) Figure shows, in cross section, two solid spheres with uniformly distributed charge throughout
their volumes. Each has radius R. Point P lies on a line connecting the centres of the spheres, at
radial distance R/2 from the center of sphere 1. If the net electric field at point P is zero and Q1 is 64

μC, what is Q2(in μC) :

(A) 64
(B) 36
(C) 32
(D) 72

5) Refer to the arrangement of charges in figure and a Gaussian surface of radius R with Q at the

centre. Then :-

(A)
Total flux through the surface of the sphere is
Field on the surface of the sphere is
(B)

(C) Flux through the surface of sphere due to 5Q is zero

(D) Field on the surface of sphere due to –2Q is same everywhere

6) In figure, two positive charges q2 and q3 fixed along the y-axis, exert a net electric force in the +x
direction on a charge q1 fixed on the x-axis. If a positive charge Q is added at (x, 0), the force on q1
(A) Shall increase along the positive x-axis
(B) Shall decrease along the positive x-axis
(C) Shall point along the negative x-axis
(D) None of these

7) Charges are placed on the vertices of a square as shown. Let be the electric field and V the
potential at the centre. If the charges on A and B are interchanged with those on D and C

respectively, then

(A) remains unchanged, V changes

(B) Both and V change
(C) and V remain unchanged
(D) changes, V remains unchanged

8)

Two free point charges +q and +4q are a distance R apart. A third charge is so placed that the
entire system is in equilibrium. Then the third charge is :-

(A) zero

(B)

(C)

(D)

9) Two charges 9e and 3e are placed at a separation r. The distance of the point where the electric
field intensity will be zero, is :–

(A)
from 9e charge

(B)
from 9e charge
(C)
from 9e charge

(D)
from 3e charge

10) As shown in fig. if a charge +q is carried from a point A (r, 135°) to point B (r, 45°). If dipole

moment is p then the work done by the external agent is :-

(A) 0

(B)

(C)

(D)

11) Three charges Q, + q and + q are placed at the verticles of a right – angled isosceles triangle as
shown. The net electrostatic energy of the configuration is zero if Q is equal to :-

(A)

(B)

(C) –2q
(D) +q

12) A circle of radius R is drawn in a uniform electric field E as shown in the fig. VA, VB, VC and VD are
respectively the potentials of points A, B, C and D on the circle then :-

(A) VA > VC, VB = VD

(B) VA < VC, VB = VD
(C) VA = VC, VB < VD
(D) VA = VC, VB > VD

13) In the circuit shown in the figure, the current through :

(A) the 3Ω resistor is 0.50 A

(B) the 3Ω resistor is 0.25 A
(C) the 4Ω resistor is 0.50 A
(D) the 4Ω resistor is 0.25 A

14) In the circuit shown, the current in the 1Ω resistor is :-

(A) 0.13 A, from Q to P

(B) 0.13 A, from P to Q
(C) 1.3 A, from P to Q
(D) 0A

15) In the circuit shown in figure reading of voltmeter is V1 when only K1 is closed, reading of
voltmeter is V2 when only K2 is closed and reading of voltmeter is V3 when both K1 and K2 are closed.

Then :-
(A) V3 > V2 > V1
(B) V2 > V1 > V3
(C) V3 > V1 > V2
(D) V1 > V2 > V3

16) For what value of R in the circuit as shown, current passing through 4Ω resistance will be zero:-

(A) 1Ω
(B) 2Ω
(C) 3Ω
(D) 4Ω

17) The current in a conductor varies with time t as

I = 2t + 3t2 amp. where I is ampere and t in second. Electric charge flowing through a section of the
conductor during t = 2 sec to t = 3 sec is :–

(A) 10 C
(B) 24 C
(C) 33 C
(D) 44 C

18) A steady current is passing through a linear conductor of non-uniform cross-section. The current
density in the conductor is :-

(A) independent of area of cross-section

(B) directly proportional to area of cross-section
(C) inversely proportional to area of cross-section
(D) Inversely proportional to the square root of area of cross-section

19) A battery of emf E and internal resistance r is connected across a resistance R. Resistance R can
be adjusted to any value greater than or equal to zero. A graph is plotted between the current (i)
passing through the resistance and potential difference (V) across it. Select the correct alternative.
(A) internal resistance of battery is 5Ω
(B) emf of the battery is 20V
(C) maximum current which can be taken from the battery is 4A
(D) V- i graph can never be a straight line as shown in figure.

20) The resistance in the two arms of a meter bridge are 5 Ω and R Ω, respectively and galvanometer
shows zero deflection. When the resistance R is shunted with an equal resistance, the new balance

point is at 1.6 ℓ1. The resistance ‘R’ is :-

(A) 10 Ω
(B) 15 Ω
(C) 20 Ω
(D) 25 Ω

SECTION-II

1) A solid metallic sphere has a charge + 3Q. Concentric with this sphere is a conducting spherical
shell having charge –Q. The radius of the sphere is a, and that of the spherical shell is b (b > a). If

the electric field at a distance R (a < R < b) from the centre is , then x will be

2) The electric field in a region of space is given by E = (5 + 2 ) N/C. The electric flux through an
area of 2m2 lying in the YZ plane, in S.I. units is

3) In a certain region of space, the potential is given by : V = k[2x2 – y2 + z2]. The electric field at the
point (1, 1, 1) has magnitude xk , then x = ?

4) A galvanometer gives full scale deflection with 0.006 A current. By connecting it to a 4990 Ω

resistance, it can be converted into a voltmeter of range 0–30 V. If connected to a resistance,

it becomes an ammeter of range 0 - 1.5 A. The value of n is :-

5) 12 cells each having same emf are connected in series with some cells wrongly connected in a
battery. The arrangement is connected in series with an ammeter and two more such cells which are
in series. Current is 3 A when cells and battery aid each other and is 2 A when cells and battery
oppose each other. The number of cells wrongly connected is :-
 PART-2 : CHEMISTRY

SECTION-I

1) A2 + B2 → 2AB; Rate of reaction = k[A2]a[B2]b

Rate of reaction (r)

Initial [A2] Initial [B2]
M sec–1

0.2 0.2 0.4

0.1 0.4 0.4

0.2 0.4 0.8

order of reaction with respect to A2 and B2 are respectively :-
(A) a = 1, b = 1
(B) a = 2, b = 0
(C) a = 2, b = 1
(D) None

2) For a complex reaction A products

=180 kJ/mol; = 80 kJ/mol;
= 50 kJ/mol Overall rate constant k is related to individual rate constant by the equation

k= . Activation energy (kJ/mol) for the overall reaction is :-

(A) 100
(B) 43.44
(C) 150
(D) 140

3)

Consider the following statements :-

(i) Increase in concentration of reactant increases the rate of a zero order reaction
(ii) Rate constant k is equal to 'A' if Ea = 0
(iii) Rate constant k is equal to 'A' if Ea = ∞
(iv) loge k vs T is a straight line

(v) logek vs 1/T is straight line Correct statement are :-

(A) (i) and (iv)
(B) (ii) and (v)
(C) (iii) and (iv)
(D) (ii) and (iii)

4) Two first order reactions have half-lives in the ratio 3 : 2. Calculate the ratio of time intervals t1 :
t2 if t1 is the time period for 25% completion of the first reaction and t2 for 75% completion of the
second reaction :-

(A) 0.3 : 1
(B) 0.5 : 1
(C) 0.2 : 1
(D) 0.1 : 1

5) For a 1st order reaction, if the time taken for completion of 50% of the reaction is t second, then
the time required for completion of 99.9% of the reaction is :-

(A) 10 t
(B) 5 t
(C) 100 t
(D) 2 t

6) A graph between log t1/2 and log a, 'a' being the initial concentration of reactant A is given, for

reaction : A → product. If 75% of A is decomposed in 100 min. How

long will it take for 90% of the compound to decompose.
[Given : log 2 = 0.3]

(A) 176.66 min.

(B) 156.66 min.
(C) 166.66 min.
(D) 150 min.

7) On introducing a catalyst at 500 K the rate of a first order reaction increases by 1.718 times. The

activation energy in presence of catalyst is 4.15 kJ mol–1. The slope of the plot of ln k (in sec–1) vs (T
in Kelvin) in absence of catalyst is (R = 8.3 J mol–1 K–1)
(Given : ln 1.718 = 0.54)

(A) –230
(B) –770
(C) +1000
(D) –1000

8) For the reaction: NO2(g) + CO(g) → NO(g) + CO2(g), the rate law is, r = k [NO2]2. Which of the
following can be the correct mechanism of the reaction according to the observed rate law?

NO2 + NO2 → NO3 + NO (fast)

(A)
NO3 + CO → NO2 + CO2 (slow)
 2NO2 → N2 + 2O2 (slow)
(B) 2CO + O2 → 2CO2 (fast)
N2 + O2 → 2NO (fast)
2NO2 + O2 → 2NO3 (slow)
(C) 2NO3 → 2NO + 2O2 (fast)
2CO + O2 → 2CO2 (fast)

(D) 2NO2 + → N2O5 (slow)

N2O5 + CO → 2NO + CO2 + O2 (fast)

9) For the reaction of type A(g) → 2B(g)

List-I contains four entries and List-II contains four entries. Entry of List-I are to be matched with
only one entry of List-II.

List-I List-II

(P) (1)
vs for first order

(Q) [A] vs t for first order (2)

(R) [B] vs t for first order (3)

(S) [A] vs t for zero order (4)

(A) P-4, Q-3, R-1, S-2

(B) P-1, Q-2, R-3, S-4
(C) P-4, Q-3, R-2, S-1
(D) P-2, Q-4, R-1, S-2

10) The mechanism of the reaction

2NO + O2 → 2NO2 is :

NO + NO N2O2 (fast) ;
N2O2 + O2 2NO2 (slow)
The rate constant of the reaction is

(A) k2
(B) k2k1 (k–1)
(C) k2k1

(D)

11) The correct reaction is.

(A)

(B)

(C)

(D) All of these

12) An unknown alcohol is treated with the "Lucas reagent" to determine whether the alcohol is
primary, secondary or tertiary. Which alcohol reacts fastest and mechanism used is :

(A)

(B)

(C)

(D)

13) Correct order of reactivity towards SN2 reaction is :

(A)

(B)
(C)

(D)

14) When conc. HI is added in excess to the unsymmetrical ether : it

results in

(A) Ph CH2OH
(B) PhI
(C) HOCH2CH2Ph – NO2
(D) I CH2CH2 Ph – NO2

15)

List-I List-II

(P) R–OH + SOCl2 (1) Swarts reaction

(Q) R–X+NaI in acetone (X=Cl, Br) (2) Darzen process

(R) R–Br + AgF (3) Wurtz fittig reaction

(S) (4) Finkelstein reaction

+ Na

Correctly matched option is :

(A) (P) → (4)
(B) (Q) → (2)
(C) (S) → (3)
(D) (R) → (1)

16)

Which one of the following compounds will be most reactive for SN1 reaction:

(A)
(B)

(C)

(D)

17) Match the reactions in column-I and name of their mechanism in column-II and select the
correct answer :

Column-II
Name of
Column-I
mechanism
Reactions
of the
reaction

(a) (p) E1

(b) (q) SN1

(c) (r) SN2

(d) (s) E2

(A) (a-s) , (b-r) , (c-p) , (d-q)

(B) (a-r) , (b-s) , (c-q) , (d-p)
(C) (a-r); (b-p); (c-s); (d-q)
(D) (a-q) , (b-p), (c-r) , (d-s)

18)
What is A, B & C respectively ?
(A)

(B)

(C)

(D)

19) Which of the following reaction is incorrect :-

(A)

(B)

(C)

(D)

20) In the following sequence of reaction, the major products B and C respectively are :

(A)
and

(B)
and

(C)
and

(D)
and

SECTION-II
1) The reaction 2A + B + C → D + E is found to be first order in A, second order in B and zero order
in C. How many times rate of reaction increase if concentrations of A, B, and C becomes double?

2) A molecule undergoes two independent first order reactions whose respective half lives are 12
min and 3 min. If both the reactions are occurring then the time taken for the 50% consumption of
the reactant is _______ min. (Nearest integer)

3) For the adsorption of hydrogen on platinum, the activation energy is 30 kJ mol–1 and for the
adsorption of hydrogen on nickel, the activation energy is 41.4 kJ mol–1. The logarithm of the ratio of
the rates of chemisorption on equal areas of the metals at 300 K is ……… (Nearest integer)
Given: ln 10 = 2. 3 R = 8.3 JK–1 mol–1

4) How many of the following compounds would give positive iodoform test ?

, , , ,

CH3CH2OH, , CH3 – CONH2

5)

How many chlorides can react with AgNO3 will give white preciptate of AgCl ?

, , , , ,

PART-3 : MATHEMATICS

SECTION-I

1) Using the elements –3, –2, –1, 0, 1, 2, 3, then which statement is not true.

(A) The number of 3 × 3 matrices having trace 0 is are 35 × 77

(B) The number of 3 × 3 matrices having trace 0 are 37 × 76
(C) The number of 3 × 3 skew symmetric matrices are 73
(D) The number of 3 × 3 symmetric matrices are 76

2) Consider the system of linear equation x + y + z = 4μ,

x + 2y + 2λz = 10μ, x + 3y + 4λ2z = μ2 + 15 where λ, μ ∈ R. Which one of the following statements
is NOT correct ?
(A)
The system has unique solution if and μ ≠ 1,15

(B)
The system is inconsistent if and μ ≠ 1

(C)
The system has infinite number of solution if and μ = 15

(D)
The system is consistent if

3) Consider a system of linear equation

2x + y - z = 7
x - 3y + 2z = 1 where a, b ∈ I, and a, b ∈ [-10, 10]
x + 4y + az = b
Identify correct statements

List - I List - II

No. of ordered pair (a, b) for which system of

(P) (1) 1
equations has atleast one solution

No. of ordered pair (a, b) for which system of

(Q) (2) 20
equations has unique solution

No. of ordered pair (a, b) for which system of

(R) (3) 420
equations has no solution

No. of ordered pair (a, b) for which system of

(S) (4) 431
equations has infinite number solution

(5) 421
(A) P → 5;Q → 3;R → 4;S → 1
(B) P → 5;Q → 3;R → 1;S → 4
(C) P → 5;Q → 3;R → 2;S → 1
(D) P → 5;Q → 4;R → 1;S → 4

4) If x, y & z are different even integers and minimum value of

is N, then is

(A) 4
(B) 8
(C) 1
(D) 16

5) In a class of 55 students, the number of students studying different subjects are 23 in

mathematics, 24 in physics, 19 in chemistry, 12 in mathematics and physics, 9 in mathematics and
chemistry, 7 in physics and chemistry and 4 in all the three subjects. The number of students who
have taken exactly mathematics is

(A) 6
(B) 2
(C) 4
(D) None of these

6) A student appears for a quiz consisting of only true-false type questions and answers all the
questions. The student knows the answers of some questions and guesses the answers for the
remaining questions. Whenever the student knows the answer of a question, he gives the correct
answer. Assume that the probability of the student giving the correct answer for a question, given

that he has guessed it, is . Also assume that the probability of the answer for a question being

guessed, given that the student's answer is correct, is . Then the probability that the student
knows the answer of a randomly chosen question is :

(A)

(B)

(C)

(D)

7) The coefficients a, b, c in the quadratic equation ax2 + bx + c = 0 are chosen from the set {1, 2, 3,
4, 5, 6, 7, 8}. The probability of this equation having repeated roots is :

(A)

(B)

(C)

(D)

8) There are three bags X, Y and Z. Bag X contains 5 one-rupee coins and 4 five-rupee coins; Bag Y
contains 4 one-rupee coins and 5 five-rupee coins and Bag Z contains 3 one-rupee coins and 6 five-
rupee coins. A bag is selected at random and a coin drawn from it at random is found to be a one-
rupee coin. Then the probability, that it came from bag Y, is :

(A)

(B)

(C)
(D)

9) An unbiased coin is tossed n times. Let X denote the number of times head occurs. If P(X = 4), P(X
= 5) and P(X = 6) are in AP, then the value of n can be

(A) 7
(B) 10
(C) 12
(D) 13

10) Let A and B be two square matrices of order 3 such that and .

Then is equal to:

(A) 81
(B) 64
(C) 32
(D) 108

11) Let and and Q = PAPT, then PTQ2013P

(A)

(B)

(C)

(D)

12) Let M = and N = .

If (а – b) + (d – e) = 36,
2 2

(b – c)2 + (e – f)2 = 64, (a – c)2 + (d – f)2 = 100,

then value of |N| is equal to :

(A) 1152
(B) 48
(C) 144
(D) 288
13) The value of K for which the function,

is continuous at x = –2 is

(A) 0
(B) 1
(C) 2
(D) 3

14) Let f : R → R be a function such that

, f(0) = 3
and f '(0) = 3, then :-

(A)
is differentiable in R
(B) f(x) is continuous but not differentiable in R
(C) f(x) is continuous in R
(D) None

15) Let f : R → R be a function defined as :

f(x) =
Then, f is :

(A) continuous if a = 5 and b = 5

(B) continuous if a = –5 and b = 10
(C) continuous if a = 0 and b = 5
(D) not continuous for any values of a and b

16) Let ƒ(x) = min when x > 0 then number of points where ƒ(x) is non-differentiable is :-

(A) 0
(B) 1
(C) 2
(D) 3

17) Let K be the set of all real values of x where the function f(x) = sin |x| – |x| + 2(x – p) cos |x| is
not differentiable. Then the set K is equal to:-

(A) {π}
(B) {0}
(C) ϕ (an empty set)
(D) {0, π}

18) If ƒ(x) =
is continuous at x = 0, then the ordered pair (p, q) is equal to :

(A)

(B)

(C)

(D)

19) The sum to infinite terms of the series

is-

(A)

(B)

(C) cot–1 2
(D) –cot–1 2

20)

(A) 0
(B) π – 2
(C) 2 – π
(D) 2

SECTION-II

1) Let such that AB = B and tr.(A) = 50 and ad – bc is k then is

2) Let , then det(A10 + A–10) is equal to:

3) Area of triangle whose vertices are (a, a2), (b, b2), (c, c2) is , and area of another triangle whose

vertices are (p, p2), (q, q2) and (r, r2) is 4, then the value of is

4) Let f(x) be twice differentiable function and f''(0) = 5,

then is equal to

5) The number of ordered triplets (x,y,z) satisfy equation

is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C B D C A D D B C B C D A B A B C A B

SECTION-II

Q. 21 22 23 24 25
A. 6 10 2 5 1

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A D B A A C B B A D D D C D D A B B B A

SECTION-II

Q. 46 47 48 49 50
A. 8 2 2 6 3

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B C B A C C A A B A D A C D B C D C B

SECTION-II

Q. 71 72 73 74 75
A. 7 8 4 120 2
 SOLUTIONS

PART-1 : PHYSICS

1)

ΔU = Uf – Ui

2) Let coordinates of P are (x, 0) the distance of P from wire 1 = (a + x)

and from wire 2 = (a – x)
∵ E1 = E2

∴
⇒ λ1(a – x) = λ2(a + x)
⇒ λ1a – λ1x = λ2a + λ2x
⇒ (λ1 – λ2)a = (λ1 + λ2)x

⇒x=

3) Let Fe = electrostatic force

FB = buoyancy force
∴ mg = FE + FB

mg =

∴
⇒

4) ∵ EP = 0
∴ E1 = E2

Q2 =

=
= 72 µc

5) Due to external charge ϕin = ϕout

∴ No contribution in flux

6) q1 → –ve
∴ Q → exert force on q1
along + x–axis
∴ net force → increase

7)

EF → Vector quantity so when direction is reversed then -charged.

8)

Let third charge Q is located at a distance x from +q charge. For equilibrium force on it due to
+ q charge and +4q charge should be equal in magnitude and directed oppositely.

or or x =
for the entire system of free charges to be in equilibrium, the force on the + q as well as + 4q
should also be zero. Consider force

or or Q = – 4q/9
The answer is (D)
 9)

10) WA→B = q(VB – VA)

11)

12)

Perpendicular to EF, V → same

Along EF, V ↓

13) The Correct Answer is (D)

14)

The Correct Answer is (A)

15)

The Correct Answer is (B)

16)

When current through resistance is zero then

VA – VB = 6V

so potential difference across 2Ω resistance would be 10 – 6 = 4V

∴ Current through 2Ω resistance is 2A
Now =
R = 1Ω

17) I =

q=
= (9 + 27) – (4 + 8)
= 36 – 12 = 24C

18)

The Correct Answer is (C)

19)
V = ε – ir
ε = 10V

r = 5Ω

imix =

20)

ℓ1 = 25 cm

R = 15 Ω
21)

22) ϕ =

23)

The Correct Answer is (2)

24)
V = Ig(R + g)
30 = 0.006 (R + g)

R + G = 5000
⇒ G = 10Ω
IgG = (I – Ig)g
(.006)(10) = (1.494)(S)

S= ⇒∴n=5

25) Let n be the number of wrongly connected cells.

Number of cells helping one another = (12 – n)
Total e.m.f. of such cells = (12 – n)E
Total e.m.f. of cells opposing = nE
Resultant e.m.f. of battery = (12 – n) E – nE = (12 –2n)E
Total resistance of cells = 12r
(resistance remains same irrespective of connections of cells)
With additional cells
(a) Total e.m.f. of cells when additional cells help battery
= (12 - 2n) E + 2E
Total resistance = 12r + 2r = 14r
 ......(i)
(b) Similarly when additional cells oppose the battery

......(ii)
Solving (i) and (ii), n = 1

PART-2 : CHEMISTRY

26) r = K[A2]a[B2]b
Put the given values of conc. and rate in equation.

27) k =

= = (A')2/3 .
On comparison with Arhenius Eq :

Ea = [Ea1+ Ea2–Ea3]
⇒ Ea = [180 + 80 – 50] = 140 kJ

28)

k=A×
k = A (if Ea = 0)

ℓnk = lnA – ; ℓnk Vs = linear

(ii) and (v) ⇒ correct

29) k1 =

t1 = (log 4 – log 3)
similarly,

k2 =

t2 = (log 4)

∴
 = = 0.3 : 1

30) K =

K= ⇒K= log2 ..... (1)

K= log ⇒
⇒ K= ×3 ..... (2)
From equation (1) and equation (2)

= ⇒ t99.9% =
t99.9 % = 10t

31)

......(1)

......(2)
From eq. (1) and (2)

32) ∵ ex/RT = 1.718

∴ = ℓn (1.718) = 0.54
x = 2241 Joule
∴ Ea in the absence of catalyst
= 4150 + 2241 = 6391 Joule/mole

∴ |Slope| = = 770

33) Concept:

rate
For reaction slow
fast
fast
rate …… at it is slow step

Final Answer:
The correct option is (B).
34)

P-4, Q-3, R-1, S-2

The Correct Answer is (A)

35)

rate = K2 [N2O2] [O2] … for RDS.

36)

Explaining the Question :- Question is asking about the correct reaction.

Concept :- This question is based on Based on electrophilic substitution reaction (ESR).
Solution :- Chlorine is ortho para directing and deactivating group.
Generally % para product is more than % ortho product in halobenzene.

All are correct.

Final Answer :- (D)

37) Explain Question :

Lucas test of alcohols → Asking the most reactive alcohol and mechanism.
Concept :
Mechanism is SN1 reaction.
Rate of SN1 ∝ stability of intermediate carbocation.
Solution :
Hint : → 3° Alcohols reacts immediate with Lucas reagent.
→ 2° Alcohols reacts in 5 minute with Lucas reagent.
→ 1° Alcohols do not react appreciably with Lucas reagent.

Final Answer : (D)

38)

Explaining the Question :-

Question is asking about the Reactivity order of alkyl halides towards SN2 reaction
Concept:-
Rate of SN2 ∝ stability of transition state
∝ – I, –M effect

∝
∝ Leaving group ability if alkyl part is same.
Solution :-
For the given compounds relative rate of SN2 reaction will be :

(1)

(2)

(3)

(4)
Correct order is given in option (C) only
Final Answer :- (C)

39) Fact

40)

Explaining the Question :-

Question is asking about the Match the reaction with name
Concept:-
This question is based on facts
Solution :-
Correct match are :
(P) R – OH + SOCl2 → R – Cl + SO2 + HCl [Darzen process]
(Q)
(R) R – Br + AgF → R – F + AgBr ↓ [Swarts reaction]

(S)
Final Answer :- (D)

41) SN1 reaction rate ∝ stability of carbocation ∝ leaving ability of group

42) (a)

(b)

(c)

(d)

43) NCERT Page No. # 369, (Aldehyde, Ketones & Carboxylic acid)

44)
45)

46)

2A + B + C → D + E

rate = –
0
r = k[A]1 [B]2 [C]
0
on increasing concentrations twice new rate will become (21 × 22 × 2 ) times, ie, 8 times.

47)

48)

Ans: 2

49) , , CH3CH(OH)CH3 , ,
CH3CH2OH , CH3COCH3
give iodoform test.
 50)
they have stable carbocation

PART-3 : MATHEMATICS

51)

The Correct Answer is (A)

52) x + y + z = 4μ, x + 2y + 2λz = 10μ, x + 3y + 4λ2z = μ2 +15,

For unique solution

Let

For infinite solution

53)

2x + y – z = 7 .......(i)
x – 3y + 2z = 1 ......(ii)
x + 4y + az = b ......(iii)
(ii) + (iii)
2x + y + (2 + a)z = 1 + b .....(iv)
(iv) – (i)
(3 + a)z = (b – 6)
For unique solution
∴ No. of order pair for unique solution
20 × 21 = 420
For infinitely number solution
a = –3, b = 6
∴ Only one pair
For no solution
a = –3, b ≠ 6
No. of order pair = 1 × 20 = 20
For atleast one solution = unique + infinite
= 420 + 1 = 421

54) Given determinant is

= (x – y)2 (y – z)2 (z – x)2
minimum value is 256
(take x = 2, y = 0, z = –2)

55)
n(M) = 23, n(P) = 24, n(C) = 19
n(m ⋂ P) = 12, n(M ⋂ C) = 9, n(P ⋂ C) = 7,
n(M ⋂ P ⋂ C) = 4
We have to find n(M ⋂ P' ⋂ C')

56) C → Correct
G → Guess
K → Knows

Let required probability = x

 ⇒ Option (C) is correct.

57) ax + bx + c = 0
2

a, b, c ∈ {1, 2, 3, 4, 5, 6,7, 8}
Repeated roots D = 0
⇒ b2 – 4ac = 0 ⇒ b2 = 4ac

Prob =
⇒ (a, b, c)
(1, 2, 1) ; (2, 4, 2) ; (1, 4, 4) ; (4, 4, 1) ; (3, 6, 3) ; (2, 8, 8) ; (8, 8, 2) ; (4, 8, 4)
8 case

58)

X Y Z

5 one & 4 4 one & 5 3 one & 6

five five five

59) ⇒ 2 nc5 = nc4 + nc6 ⇒ 4 nc5 = n + 1c5 + n + 1c6 ⇒ 4 nc5 = n + 2c6

⇒ 24 (n – 4) = (n + 2) (b + 1) ⇒ n = 7, 14.

60)

The Correct Answer is (B)

61)

The Correct Answer is (A)

62)
The Correct Answer is (D)

63)
= 2(–2) + 5 (–2) + 2 = 8 – 10 + 2 = 0
2

64) Given
Replacing x by 3x and y by zero,

then f(x) =
⇒ f(3x) – 3f(x) = –f(0)

and f '(x) =

= [from Eq. (i)]

= f '(0)
=3
∴ f(x) = 3x + c
⇒ f(0) = 0 + c = 3
∴c=3
Then, f(x) = 3x + 3
Hence, f(x) is continuous and differentiable everywhere.

65)
f(1) = 5, f(1–) = 5, f(1+) = a + b
f(3–) = a + 3b, f(3) = b + 15, f(3+) = b + 15
f(5–) = b + 25 ; f(5) = 30 f(5+) = 30
from above we concluded that f is not continuous for any values of a and b.
66)
Only one point of intersetion

Sharp corner at one point

67) ƒ(x) = sin|x|–|x| + 2(x – π) cosx

∵ sin|x| – |x| is differentiable function at x=0
∴k=ϕ

68) RHL= =

LHL =
for continuity LHL = RHL = f(0)

⇒ (p, q) =

69)

tan–1 (2r+1) – tan–1(2r)

= (tan–1 2n+1 – tan–1 2)

= – tan–1 2 = cot–1 2

70) = sin–1(sin(2))
=π–2

71)
Using tr. A = 50 we get det A = 49 ⇒

72) A = ⇒A =
n

and A–n = (An)–1 = (adj An) (∵ |A| = 1)

⇒ |A10 + A–10| = = 8.00

73) Δ = = 2 · 2Δ1 · 2Δ2

= 8Δ1Δ2 = 8 ·

74)

= 24f"(0) = 24(5) = 120

75) x = ±1, y = 0, z = 0
∴ Number of triples = 2