5 - DAY C H A L L E N G E
U N I T- 2 I M P O R TA N T QU E S T I O N S
AKTU
DAY-2
ENGINEERING CHEMISTRY (BAS-102)
CHEMISTRY BY DR. ANJALI SSAXENA
UNIT-2 IMPORTANT QUESTIONS
1. Briefly Explain Absorption laws.
2. Calculate the absorbance value if 80% light is transmitted through the
solution.
3. At definite wavelength, an absorber when placed in a cell f 1 cm
pathlength absorbs 20 % of the incident light. If the absorptivity of the
absorber at this wavelength is 2.0. Find out its concentration.
4. A compound having concentration 10-3 g/l resulted absorbance value
0.20 at wave length 510 nm using 1.0 cm cell. Calculate its absorptivity
and molar absorptivity values. Molecular weight of compound is 400.
UNIT-2 IMPORTANT QUESTIONS
1. Which of the following will be UV active and Why ?
CH3Br, C6H5OH and HCHO
2. Differentiate following on the basis of UV/IR spectra
Ethyl benzene and Styrene
CH2=CH-CH2-CH=CH2 and CH2=CH-CH=CH-CH3
3. Explain Chromophores and Auxochromes. Also explain various
absorption and intensity shift.
UNIT-2 IMPORTANT QUESTIONS
1. What is finger print and functional group region in IR spectroscopy.
Explain various molecular vibrations for AB2 molecule.
2. The following characteristic peaks were observed in the infrared
spectrum of an organic compound having Molecular formula-C2H6O.
Strong band at 3300 Cm-1 (ii) Band at 2965 Cm-1
(iii) Band at 2920 Cm-1 (iv) Band at 1050 Cm-1
Predict the compound.
UNIT-2 IMPORTANT QUESTIONS
1. Write the basic principle of NMR spectroscopy and briefly explain
Chemical shift.
2. Why TMS is used as internal standard in NMR spectroscopy.
3. Predict NMR spectrum of following compounds-
4. An organic compound C3H6O contains a carbonyl group C=O. How
will its NMR spectrum decide whether it is an aldehyde or ketone.
5. An organic compound C10H14 . it gives the following NMR data-
(a)0.88 δ (9H S) (b) 7.28 δ (5H S aromatic proton)
Assign the structure to the compound.