(0999DJA161101240017) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Main)

TEST # 14
(Academic Session : 2024 - 2025)
16-02-2025

JEE(Main+Advanced) : NURTURE TEST SERIES / JOINT PACKAGE COURSE

Test Type : Review (Unit Test # 06, 07, 08, 09 & 10)
ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. B D C C B B B B B C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D A A A B A D C B D
Q. 1 2 3 4 5
SECTION-II
A. 2 8 2 2 6

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. B B C A C B D A A C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A C A C D A A D C A
Q. 1 2 3 4 5
SECTION-II
A. 64 10 8 3 7

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C B A B B C A B D C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A B D A B B C C A A
Q. 1 2 3 4 5
SECTION-II
A. 0 1 6 1 40

HINT – SHEET

PART-1 : PHYSICS P is same in both the frames.

SECTION-I Also KEi = 0
1. Ans ( B ) KEy = 1 1
mV12 + 2mV22
2 2
Before collision After collision
KE increase (B)
2. Ans ( D )
Vcm = 0 as fent = 0 M(0) − M
16
(0) − M
16
(3R) −3R
xCM = =
mV1 = 2mV2 M− M
− M 14
16 16

V1 = 2V2 M(0) − M
(3R) − M
(0)
16 16 −3R
yCM = =
M− M
− M 14
16 16

0999DJA161101240017 HS-1/8
 Target : JEE(Main + Advanced) 2026/16-02-2025
3. Ans ( C ) 7. Ans ( B )
′
L = mr2 ω ; Only ω is decreasing, thus only L→ s
direction is constant.
mu = 2mV + mV 8. Ans ( B )
V = u/3 2R
mg × = N × 2R
1 π
k (02 − x2 ) mg
2 ⇒N=
1 2 1 2 1 π
= m(u/3) + 2m(u/3) − mu2
2 2 2 9. Ans ( B )
4. Ans ( C ) 1
m. x
+ m
.x
+ m x
. +. . . . . . . ∞ stress × strain
2 4 4 16 8 2
xcm = L ⇒ m m
=L
(stress)
2
S2
m+ + +. . . . . ∞
4 16 = =
5. Ans ( B ) 2Y
10. Ans ( C )
2Y

YA tan θA tan 30∘ 1/√3 1

= = ∘
= =
YB tan θB tan 60 √3 3
⇒ YB = 3YA
11. Ans ( D )
Speed just before collision = √ 2gh = vi ΔT
=
1
∝ ΔQ = ∝ t
1
h T0 2 2
Speed just after collision = √
2g = vf
4 In 1 day, it will lose 1 α t × 86400 sec
vf = evi 2
√
2gh 1
12. Ans ( A )
= e√2gh ⇒ e = For large ' α ' bend is more
2 2
6. Ans ( B ) 13. Ans ( A )
Heat required by ice

Q1 = MS Δ T = 25 cal
mg sin θ – fs = macm ...(1) Q2 = MLf = 800 cal
fs·R = Icm α ——————————
Icm acm
⇒ ...(2) Qr = 825 cal
R2
Adding (1) + (2) ——————————
mg sin θ Heat available with water
acm =
Icm
m+
R2
From (2)
Qa = MS Δ T = 600 cal
⎛
mg sin θ ⎞
Icm
μmg cos θ = ⎜ ⎟ As Qa < Qr
Icm R2
⎝ m+ ⎠
R2
2 ∴ All ice will not melt hence final temperature
tan θ ⋅ 3 2
⇒μ= = tan θ will be 0°C
1+ 2 5
3

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14. Ans ( A ) 19. Ans ( B )
80 × 1 × (30 – 0) = m × 80
15. Ans ( B )
dT
H = KA is same in steady state condition
dx
dT
∴A = constant
dx
∴ Hyperbolic graph

16. Ans ( A ) heat supplied = nCv (2T0 − T0 ) + nCp (4T0 − 2T0 )

Stefan's law n3RT0 n5R 13 13

= + (2T0 ) = nRT0 = P 0 V0
2 2 2 2
Q
t
= σAT 4
20. Ans ( D )
λm T = const. g g
geff = g – =
2 2
λred Tred = λgreen Tgreen
So PA + ρ (geff)h = PB
Tred λgreen
= ρgh
Tgreen λred PB – PA = ρ (geff)h =
2
λred > λgreen (VIBGYOR)
PART-1 : PHYSICS
Tgreen > λred
SECTION-II
1
A∝
T4 1. Ans ( 2 )
Ared > Agreen Ma = Fnet = Mg – B – 6 π η rv
17. Ans ( D ) at v = vT , a = 0
E2 σA2 T24 R22 T24
= =
E1 σA1 T14 R21 T14
⇒ Mg – B = 6 π η rvT
R2 = 2R, R1 = R
4 3 ρ
3
πr [ρ − 2
]g

T2 = 2T, T1 = T ⇒ vT = = 2m/ sec

6πrη

⇒ E2
=
(2R)2 (2T )4
= 64 2. Ans ( 8 )
E1 (R)2 (T )4 ρgH
F = Pavg A = (HL)
18. Ans ( C ) 2
ρgH 2 L
F=
2

F ∝ H 2L

0999DJA161101240017 HS-3/8
 Target : JEE(Main + Advanced) 2026/16-02-2025
3. Ans ( 2 ) PART-2 : CHEMISTRY
PE
KE = PE + SECTION-I
4
KE = 5
PE 1. Ans ( B )
1
4
5 1
Question is asking about :
m ω 2 (A2 – x2) = × m ω 2x2 Acidic Strength
2
[ v = ω √ A2 − x 2 ]
4 2
Solution/Explanation/Calculation :
Option 2 will form aromatic stabilised conjugate
5 2 anion thus it is most acidic.
A2 – x2 = x
4
9x2
= A2
4
2
x= A
3
2 2. Ans ( B )
∴ x = × 3cm Generally Basic strength ∝ electron density at
3
x = 2cm donor site
So, (I) >(II) <(II) < (IV)
4. Ans ( 2 ) 3. Ans ( C )
+ + +

P = e σ AT4 ( C
) − N F3 > − N R3 > − N H3

4. Ans ( A )
λ T = constant

PA eσAA TA4 A T
4
r2A λ4B
= = A A = .
PB eσAB TB4 AB TB4 r2B λ4A
4
In this lone pair is localised because formation of
104 = 4002. ( λB ) π -bond at bridgehead carbon is highly unstable
λA
4
(Bredt's rule).
104 λB whereas, in (II) lone pair is delocalised. So, less (II)
=( )

16 × 104 λA
1
is basic.
λA
λB
16 4
=( ) =2
1
5. Ans ( C )
5. Ans ( 6 ) (A) (B)
By applying conseruation of angular momentum

(C) (D)

6. Ans ( B )
2 v′
mv0 R + mR2 v0 = mv'R + 2 mR2 (I), (IV) have centre of symmetry and (iii) no chiral
5 2R 5 R centre
6 7 6 II) have no plane of symmetry , no centre of
⇒ mv0R= mv'R ⇒ v' = v0
5 5 7
symmetry and no alternate axis of symmetry.

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7. Ans ( D ) 13. Ans ( A )
In Kjedahl's method Nitrogen in the organic hc hc
N1 × × 0.5 = N2 ×
compound convert into NH3. Those which are net 4000 5000
N 5
able to convert in NH3 are nor suitable by Kjedahl's ⇒ 2 =
N1 8
method like → 14. Ans ( C )
⇒ Pyridin (N Present in Ring System) (n2 − n1 )(n2 − n1 + 1)
⇒ Nitro – Compound Spectral lines = = 10
2
⇒ Azo – Compound 15. Ans ( D )
8. Ans ( A ) 1
= RH (
1
−
1
) = RH (
1 1
− ) = RH ×
5
At normal pressure B.P. of glycerol is 563 k, it will λ 2 2
3 2 4 9 36
decomposes at this temperature therefore most 1 1 1 RH
= RH ( − ) =
suitable method for distillation of glycerol from λ′ 22 ∞2 4
spent-lye is distillation under reduced pressure. 36 4 1 36
λ – λ' = − = − 4] = 3.2/RH
9. Ans ( A )
[
5RH RH RH 5
α – C – H bond e – move to empty orbitals available. 16. Ans ( A )
10. Ans ( C )

17. Ans ( A )
12. Ans ( C ) 2AB2 2AB + B2
⇌

G.I. Initial 2 0 0
Final 2 – 2x 2x x
(1) × total no. of moles = 2 – 2x + 2x + x = 2 + x
2 − 2x 2x
PAB2 = × P, PAB = × P,
2+x 2+x
x
P B2 = ×P
(2) × 2+x
2
2x x
(PAB )2 (PB2 ) ( ) P 2 × ( 2+x )P
2+x x3 × P
KP = 2
=
2
=
(PAB2 ) (
2−2x
) ×P2 (2 + x)(1 − x)2
2+x

(3) 18. Ans ( D )

On decreasing volume the conc. of each specie will
increase.
19. Ans ( C )
(4) × As concentration of reactant increases, So reaction
goes forward, red colour of the solution deepens.

0999DJA161101240017 HS-5/8
 Target : JEE(Main + Advanced) 2026/16-02-2025
20. Ans ( A ) 2. Ans ( 10 )
The correct option is D 2.55 We have to considers all paschal transitions from
PCl5 ⇌ PCl3 + Cl2 n = 7 (6th excited state) to n =1
t=0 5 0 0 Infrared lines = Total lines – visible lines – UV lines
7 (7 − 1)
t=t 5–n n n { } – 5 – 6 = 21 – 11 = 10
2
Total moles = 5 – n + n + n = 5 + n
For Argon
3. Ans ( 8 )
C6H12
nAr = 4
DU = 1 × (2 × 6 + 2 – 12) = 1
Total moles = nAr + nP Cl5 + nP Cl3 + nCl2 2
=4+5+n
=9+n
PV = nRT
6 × 100 = (9 + n) × 0.82 × 610
n=3
PP Cl3 . PCl2
KP =
PP Cl5
3 3
(
12
× 6) × ( 12 × 6)
2
×6 12
27 9
= = = 2.25 atm
12 4

PART-2 : CHEMISTRY 2+ 2+4 = 8 optically active isomers

SECTION-II 4. Ans ( 3 )
1. Ans ( 64 )
PCl5(g) ⇌ PCl3(g) + Cl2(g)
t=0 2 0 0
2–x
t = teq. x x
5. Ans ( 7 )
x 80
=
2 100
x = 1.6
0.4
[PCl5] =
5
1.6
[PCl3] = PART-3 : MATHEMATICS
5
1.6 SECTION-I
[Cl2] =
5
1.6
× 1.6 6.4 1. Ans ( C )
KC = 0.4 5 =
5
64
5
5 y = mx + , y = mx – 8m2
m
KC × 50 = 64 64
⇒ = −8m2 ⇒ m = – 2
m
⇒ y int. = – 32

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2. Ans ( B ) 8. Ans ( B )
E → 2, A → 2, R → 1 1
2
x+y+1
2
2 2
T → 1, H → 1, Q → 1, U → 1, K → 1 (x − 2) + y = ( ) ( )
√ 2 √ 2
1
⇒e=
7! √ 2
2!
3. Ans ( A ) 9. Ans ( D )
A vector along the normal to the required plane is
A line will be tangent to a circle, if length of ^ ^ ^
( i + ^j + k) × (^i + 2j^ + k) = −i^ + k
^
perpendicular drawn from centre (a, 0) upon the
line ℓ x + my + n = 90 is equal to radius = a 10. Ans ( C )
x2 y 2
− =1
12 7
y = mx ± √12m2 − 7 passes through (1, 2)
⇒ (aℓ + n)2 = a2 (ℓ2 + m2 )
⇒ n2 + 2aℓn = a2 m2 (2 – m)2 = 12m2 – 7
⇒ n2 + 2aℓn − a2 m2 = 0
⇒ 11m2 + 4m – 11 = 0
5. Ans ( B ) π
1 1 1 1 1 m1m2 = – 1 ⇒ θ=
+ + + = ...(i) 2
a+ω b+ω c+ω d+ω
Taking conjugate we get,
ω
11. Ans ( A )
1 1 1 1 1 f(x) (1 − cos x) 3 f (x) 6
2
+
2
+
2
+
2
= ...(ii) lim = ⇒ lim =
a+ω b+ω c+ω d+ω ω2 x→0 g (x) tan2 x 7 x→0 g (x) 7
Taking difference, f(x)
6

1 1 1 1 e g(x) = e 7
− ) = −
12. Ans ( B )
∑(
a+ω a + ω2 ω ω2
2 1
⇒ (ω − ω) ∑ = ω2 − ω 3! × 4! = 144
(a + ω)(a + ω2 )
⇒ ∑
1
=1 13. Ans ( D )
a2 −a+1 Equation of chord of the circle x2 + y2 = 25, whose
6. Ans ( C ) midpoint is P(h, k)
ƒ(1) + ƒ(2) + ƒ(3) + ƒ(4) = an odd number
Case-I : one odd and 3 even T = S1
4
C3 × 2C1 × 23 = 64 xh + yk – 25 = h2 + k2 – 25 ...(1)
Case-II : 3 odd and one even ⇒ this chord is tangent to the circle
4C × 23 × 21 = 64
3
Total = 128 x2 + y2 – 20x – 20y + 175 = 0
7. Ans ( A ) Length of perpendicular from centre
1000C + 1000C x + ..... + 1000C x1000 = (1 + x)1000
0 1 1000
= Radius
⇒ 1000C1 + 2 C2x + ..... + 10001000C1000x999
1000 = ∣
10h + 10k − h2 − k2 ∣
∣ ∣ =5
1000(1 + x)999 ∣ √ h2 + k2 ∣

put x = 1 ⇒ (10h + 10k – h2 – k2)2 = 25(h2 + k2)

⇒ 1000C1 + 2.1000C2 + ..... + 10001000C1000 (10x + 10y – x2 – y2)2 = 25(x2 + y2)
= 1000 × 2999

0999DJA161101240017 HS-7/8
 Target : JEE(Main + Advanced) 2026/16-02-2025
14. Ans ( A ) 19. Ans ( A )
f(x + 6) 2 The total number of reflexive relations on a finite
f(x) = =
3 f(x + 7) set having n elements is_________ .
√3m 2
lim f(x) = √m = + Consider a set A with n elements.
x→∞ 3 √3 Say A ={1, 2,...... n – 1, n}
m
m= +2 out of n² elements n elements are compulsory for
3
So, m = 3 relation to be reflexive.
15. Ans ( B ) i.e (1, 1) (2, 2) (3, 3) .... (n, n)
and for remaining n² – n elements, we have choice
Let total number of families be x.
of filling i.e either they are present or absent.
2
Then according to question, Hence, Total number of reflexive relation are 2n −n
x=
65x
+ 15000 −
15x 20. Ans ( A )
100 100 X Y Z
x
⇒ = 15000 ⇒ x = 30, 000. 5 one & 4 five 4 one & 5 five 3 one & 6 five
2
4/9 4 1
Thus, there are 30,000 families in the town. P = = =
5/9 + 4/9 + 3/9 12 3
16. Ans ( B ) PART-3 : MATHEMATICS
r
10 10−r k
Cr . ( √x ) . ( − ) SECTION-II
x2
r 10−r
(−1) . 10 Cr . x 2 −2r kr 2. Ans ( 1 )
10 − r ƒ(x) = |(2x – 1).(3x – 3)x.(x – 1).(x – 2)|
− 2r = 0
2 ƒ(x) is not differentiable at x = 2
r=2 3. Ans ( 6 )
17. Ans ( C ) p=
n!
n n
=
5
324
(n C0 )2 + (n C1 )2 +. . . . +(n Cn )2 By hit and trial we get n = 6
A. M. =
(n + 1)
4. Ans ( 1 )
3 1
= P (A) + P (B) −
5 5
4
18. Ans ( C ) ⇒ P (A) + P (B) =
5
Let variance of first n positive integer be ¯ ¯ = 4
⇒ 1 − P (A) + 1 − P (B)
5
V ar (n) = σ 2 ¯ ¯ 6
⇒ P (A) + P (B) =
5
i.e. Variance of first n positive multiple of 5 will be
2
5. Ans ( 40 )
Var (5n) = 25 σ n
1
a n

Variance of first n positive multiple of 10 will be (b + c) (( ) + 1) + (c + a)

(b + c)
1
n
Var (10n) = 100 σ 2 ((
b
) + 1)
n
+ (a + b)
V ar (5n) 25 σ 2 1 c+a
⇒ = = n
1

V ar (10n) 100σ 2 4 c n
(( ) + 1)
(a + b)
= 2(a + b + c) = 40
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