30-11-2025

1001CJA106216250216 JA

PART-1 : PHYSICS

SECTION-I

1) Water flows steadily through a horizontal pipe of variable cross-section. If the pressure of water is
P at a point where flow speed is v, the pressure at another point where the flow speed is 2v, is :-
(Take density of water as ρ)

P–
(A)

P–
(B)

P–
(C)

(D) P – ρv2

2) If a capillary of radius r is dipped in water, the height of water that rises in it is h and its mass is
M. If the radius of the capillary is doubled the mass of water that rises in the capillary will be:–

(A) 4 M
(B) 2 M
(C) M
(D) M/2

3) Assertion (A) : For higher temperature, the peak emission wavelength of a black body shifts to
lower wavelengths.
Reason (R) : Peak emission wavelength of a black body is proportional to the fourth power of
temperature.
In the light of the above statements, choose the most appropriate answer from the options given
below:

(A) Both assertion and reason are true and reason is the correct explanation of assertion.
(B) Both assertion and reason are true and reason is NOT the correct explanation of assertion.
(C) Assertion is true but reason is false.
(D) Assertion is false but reason is true.

4) Find the velocity v, if liquid flowing in streamline manner

(A) 4 m/s
(B) 8 m/s
(C) 12 m/s
(D) 16 m/s

5) A 5 metre long wire is fixed to the ceiling. A weight of 10 kg is hung at the lower end and is 1
metre above the floor. The wire was elongated by 1 mm. The energy stored in the wire due to
stretching is

(A) Zero
(B) 0.05 joule
(C) 100 joule
(D) 500 joule

6) A viscous fluid is flowing through a cylindrical tube. The velocity distribution of the fluid is best
represented by the diagram.

(A)

(B)
(C)

(D)

7) With an increase in temperature, the viscosity of:

(a) Gases decreases
(b) Liquids increases
(c) Gases increases
(d) Liquids decreases
Which of the following options is/are correct?

(A) (b) and (c)

(B) (a) and (d)
(C) (c) and (d)
(D) (a) and (b)

8) A uniformly tapering vessel is filled with a liquid of density 900 kg/m3. The force that acts on the
base of the vessel due to the liquid is. (g = 10 ms–2 and neglect atmospheric pressure)

(A) 3.6 N
(B) 7.2 N
(C) 9.0 N
(D) 14.4 N

9) Find the increase in pressure required to decrease the volume of a water sample by 0.01%. Bulk
modulus of water = 2.1 × 109 N/m2.

(A) 2.1 × 106 N/m2

(B) 2.1 × 104 N/m2
(C) 2.1 × 105 N/m2
(D) 2.1 × 103 N/m2

10) Along a streamline :-

(A) the velocity of a fluid particle remains constant

(B) the velocity of all fluid particles crossing a given position is constant
(C) the velocity of all fluid particles at a given instant is constant
(D) the speed of a fluid particle remains constant

11) In a physics demonstration at the fair, a correct Fahrenheit thermometer is placed next to a
Celsius thermometer to measure the temperature of a water bath. The Fahrenheit thermometer
shows a reading of 86°F. If the Celsius thermometer reads 32°C, what correction needs to be made
to the Celsius reading to match the correct temperature?

(A) 2.5ºC
(B) 2ºC
(C) 1.5ºC
(D) 3ºC

12) A cylinder of radius R is surrounded by a cylindrical shell of inner radius R and outer radius 2R.
The thermal conductivity of material of inner cylinder is k1 and that of outer cylinder is k2. Assuming
no loss of heat, the effective conductivity of system for heat flowing along the length of cylinder is -

(A)

(B)

(C)

(D) k1 + k2

13) 5n, n and 5n moles of a monoatomic, diatomic and non-linear polyatomic gases (which do not
react chemically with each other) are mixed at room temperature. The equivalent degree of freedom
for the mixture is-

(A)

(B)

(C)

(D)

14) In the renowned Allen Physics lab, a Carnot engine is operating between two heat reservoirs
at temperatures of 300 K and 600 K. The engine produces a work output of 800 J per cycle. The
amount of heat energy the engine must absorb from the hot source to perform this work.
(A) 1400 J
(B) 1500 J
(C) 1600 J
(D) 1700 J

15) The mean free path of nitrogen molecules at a pressure of 1.0 atm and temperature 0 °C is
. If the number density of molecules is , then the molecular diameter is

(A) 3.2 nm
(B) 3.2 Å
(C)
(D) 2.3 mm

16) Adiabatic modulus of elasticity of a gas is . What will be its isothermal modulus

of elasticity ?

(A)
(B)
(C)
(D)

17) If the door of a refrigerator is kept open, then which of the following is true ?

(A) Room is cooled.

(B) Room is heated.
(C) Room is either cooled or heated.
(D) Room is neither cooled nor heated.

18) An ideal refrigerator has a freezer at a temperature of −13°C. The coefficient of performance of
the engine is 5. The temperature of the air (to which heat is rejected) is :

(A) 325°C
(B) 325 K
(C) 39°C
(D) 312°C

19) The temperature and the surface area of the body are 227°C and 0.15 m2 respectively. If its
transmitting power is negligible and reflecting power is 0.5, then the power radiated by the body is
(σ = 5.67 × 10–8 J/m2-s-K) :-

(A) 500 W
(B) 265.78 W
(C) 132.89 W
(D) 420.52 W
20) To get the maximum flight a ball must be thrown as :-

(A)

(B)

(C)

(D) Any of (A), (B) and (C)

SECTION-II

1) A student is calibrating an unmarked glass thermometer. They find that the length of the liquid
column is 10 cm when it's placed in melting ice (0°C) and 60 cm when it's placed in boiling water
(100°C). If they use this thermometer to measure the temperature of an unknown liquid, and the
liquid column is 50 cm long, what is the temperature of the liquid in Celsius?

2) In a calorimetry experiment, a teacher has two spheres, A and B. They tell the students that the
spheres have diameters in a ratio of 1:2, densities in a ratio of 2:1, and specific heats in a ratio of
1:3. What is the ratio of thermal heat capacity of B to A?

3) Imagine you're examining a crystal in a lab. You measure its linear expansion and find it's
anisotropic, meaning it expands differently in different directions. Along one axis, its coefficient of
expansion is 13 × 10−7. In every direction perpendicular to that axis, the coefficient is 231 × 10−7.
Based on this observation, what is the total cubical coefficient of expansion for this crystal? If your
answer is α × 10–7, the value of α is :

4) A body cools from 50°C to 48°C in 5 s. How long (in sec) will it take to cool from 40°C to 38°C ?
Assume temperature of surrounding to be 29°C and Newton's law of cooling is valid :-

5) Two Carnot engines A and B are operated in succession. The first one, A receives heat from a
source at T1​ = 800 K and rejects to sink at T2K. The second engine B receives heat rejected by the
first engine and rejects to another sink at T3​ = 300 K. If the work outputs of two engines are equal,
then the value of T2​ (in K) is

PART-2 : CHEMISTRY

SECTION-I

1) At 25°C and 1 atm, enthalpy of atomisation of H2(g) and graphite is 'X' kJ/mol and 'Y' kJ/mol
respectively. Determine bond dissociation enthalpy of C–H bond by using enthalpy of formation of
CH4(g) at 25°C and 1 atm, which is 'Z' kJ/mol.
(A)

(B)

(C)

(D)

2) If enthalpy of hydrogenation of C6H6(l) into C6H12(l) is – 205kJ and resonance energy of C6H6(l) is

–152 kJ/mol then enthalpy of hydrogenation of is.

(Assume that ∆Hvap of C6H6(l) and C6H10(l),C6H12(l) are equal)

(A) – 535.5 kJ/mol

(B) – 238 kJ/ mol
(C) – 357 kJ/mol
(D) – 119 kJ / mol

3) Statement-1 : The enthalpy of neutralization of the reaction between HCl and NaOH is –13.7
kcal/mol. If the enthalpy of neutralization of oxalic acid (H2C2O4) by a strong base is –25.4 kcal/mol,
then the magnitude of enthalpy change (|ΔrH|) of the process : H2C2O4 → 2H+ + C2O42– is 11.7 kcal
/mol.
Statement-2 : H2C2O4 is a weak acid.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1
(C) Statement-1 is true, statement-2 is false
(D) Statement-1 is false, statement-2 is true.

4) Consider a reversible isoentropic expansion of 1 mole of an ideal monoatomic gas from 27ºC to
927ºC. If the initial pressure of gas was 1 bar, the final pressure of gas become -

(A) 8 bar
(B) 32 bar

(C)
bar

(D)
bar

5)

Which of the following is INCORRECT statement ?

(A) In adiabatic expansion of an ideal gas, temperature of gas always decreases

In isothermal reversible expansion of an ideal gas, temperature of a gas always remains
(B)
constant
(C) In a reversible adiabatic compression of an ideal gas, change in entropy of system is zero
(D) In an irreversible adiabatic compression of an ideal gas, change in entropy of system is positive

6) If four identical samples of an ideal gas initially at same state (P0, V0, T0) are allowed to expand to
double their volumes by the following processes:
Process I: Isothermal reversible process
Process II: Reversible process P2V = constant
Process III: Reversible adiabatic process
Process IV: Irreversible adiabatic expansion against constant external pressure.
If the final states of gases are shown by different points in the graph represented, then match each

point with the correct process:

(A) I - 1, II - 2, III - 3, IV - 4
(B) I - 2, II - 1, III - 4, IV - 3
(C) I - 4, II - 3, III - 2, IV - 1
(D) I - 2, II - 1, III - 3, IV - 4

7) If all degree of freedom of a three dimensional N-atomic gaseous molecules is active, then
of gas should be :

(A)

(B)

(C)

(D) 3N – 3

8) Vapour pressure of water is 0.01 atm at 27ºC. Calculate ΔG for following change :
H2O (l, 0.01 atm, 27ºC) → H2O(g, 0.01atm, 27ºC)

(A) zero
(B) 300 R ln (0.01)
(C) 300 R
(D) –300 R

9) One mole of ice is converted into water at 1atm, 300K. During conversion in the given conditions,
entropies of H2O(s) and H2O(l) are 38 and 60 J mol–1K–1 respectively. The enthalpy change for the
conversion is -

(A) 6.6 kJ mol–1

(B) < 6.6 kJ mol–1
(C) > 6.6 kJ mol–1
(D) > 6.6 J mol–1

10) For the reaction takes place at certain temperature

NH2COONH4(s) ⇌ 2NH3(g) + CO2(g).
If equilibrium pressure is 3X bar, then ΔrG° would be :-

(A) – RT ln 4 – 3RT ln X
(B) RT ln 4–3RT ln X
(C) –3RT ln X
(D) – RT (ln 4 – 3 ln X)

11) Two nuclear processes are given :

Process 1 → Decay Products
Process 2 + → Products
Based on the properties of the gaseous product select the correct statement.

(A) One of the gas produced in process-1 show highest electron gain enthalpy among noble gases.
(B) Difluoride of a gas (obtained in process-1) is reported.
(C) All products of process-1 can form difluorides
(D) In Both process-1 and process-2 products formed in the same molar ratio.

12) ____________shows more____________than____________.

Choose the option that correctly completes the comparative statement.
The statements provided are :

(A) NI3, thermal stability, NF3

(B) H2O2, O-O bond length, O2F2
(C) H2S, dipole moment, NH3
(D) O2 molecule, ionization energy, N atom,

13) Consider a fullerene (Cn), which is isostructural with truncated B12 unit of boron. Select correct
statement regarding structure of that Cn.

(A) The total number of edges in the structure is 60

(B) None of the hexagonal faces are adjacent
(C) The Sum of the number of vertices and edges is 90
(D) The number of pentagonal rings present is 12

14) Which of the following set of species contains CORRECT set as per mentioned properties
(A) , , , (All planar species)
(B) KO3, Na2O2, NaNO3, C6H6 (All Diamagnetic species)
(C) , , , (All non planar species)
(D) , , , , (All 'S' atoms are sp3 hybridized)

15) Which of the following order is INCORRECT as per mentioned property ?

(A) B2Cl4 < B2F4 (Relative stability order)

(B) BF3 < BCl3 < BBr3 < BI3 (Lewis acidic strength)
(C) AℓF3(s) > AℓI3(s) > AℓBr3(s) > AℓCl3(s) (Melting point order)
(D) SiF4 > SiCl4 > SiBr4 > SiI4 (Lewis acidic strength)

16) Assertion : All Group 14 elements are not affected by water/steam.

Reason : All Group 14 elements forms a protective oxide film.

(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a incorrect explanation of assertion.
(C) If assertion is true but the reason is false.
(D) assertion and reason both are false

17) Select the correct density order.

(A) CDiamond < CGraphite

(B) CDiamond < Si(s)
(C) CGraphite < Si(s)
(D) Si(s) > Ge(s)

18) Which of the following order is in correct ?

List-II (Order of mentioned

List-I Specie (i), Specie(ii), Specie(iii) property with group
of compounds given )

(P) Br2, Cl2, F2 (Bond energy) (1) I > II > III

HF, NH3, H2O

(Q) (2) II > I > III
(Dipole moment)

(R) B, Aℓ, Ga (Melting point order) (3) I > III > II

(S) H2O, NH3, HF (Boiling point) (4) III > I > II

Select correct code :-

(A) P→2,Q→4,R→3,S→1
(B) P→1,Q→2,R→3,S→4
(C) P→2,Q→4,R→1,S→3
(D) P→1,Q→2,R→4,S→3

19) Select INCORRECT option about hydrogen bonding.

It is attractive force which binds partially positive (δ+) hydrogen atom with more
(A)
electronegative atom.
(B) Intermolecular hydrogen bond in ethanol is weaker than the covalent bond present in ethanol.
(C) Magnitude of hydrogen bond is maximum in solid state and minimum in gaseous state.
Hydrogen bond is formed when hydrogen fix itself between electronegative atom and
(D)
electropositive atom.

20) Which of the following option does NOT represent anomalous behaviour of fluorine.

(A)

is existing but is not

(B) HCl , HBr , HI are gases but HF is liquid.
(C) Cl, Br, I can show (–1) to (+7) oxidation states but F show –1 and zero oxidation state
(D) Electron affinity and bond dissociation energy are quite high.

SECTION-II

1) ;
At equilibrium, partial pressure of N2 = 50 Bar, H2 = 2 Bar, NH3 = 200 Bar. Find |ΔS°| of reaction (in
JK–1).

(ℓn10 = 2.3, JK–1 mol–1, all data for T = 300 K)

(Answer to the nearest integer).

2) 7.8 kg of liquid benzene in vaporised at 1 atm and 78°C to obtain benzene vapour at 78°C and 5
atm pressure. Calculate change in Gibbs energy (in kcal) for the process, if normal boiling point of
benzene is 78°C ?
[Given ln 2 = 0.7, ln 5 = 1.6]
[Give your answer as nearest integer]

3) One mole of a monoatomic ideal gas initially at a pressure of 2.00 bar and a temperature of 273 K
is taken to a final pressure of 4.00 bar by a reversible path defined by P/V = constant, the value of

for this process is?

4) Calculate % by mass of F¯ in fluorapatite.

[Atomic mass H = 1, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, P = 31, S = 32, Cl = 35.5,
K = 39, Ca = 40]
5) Among the following acids, if number of acids which have pπ-dπ bond is 'x' and number of
monobasic acids is 'y', then (x + y) would be?
H2CO3 , H3PO3 , CH3CO2H , H2SO4 , H3PO2 , HClO4 , H3BO3 , HNO3 , HSbF6

PART-3 : MATHEMATICS

SECTION-I

1) The value of is

(A)

(B)

(C)

(D)

2) If x,y,z are three positive numbers such that x + y + z = 1, then the least value of the expression
(x–1 – 1)(y–1 – 1) (z–1 – 1) is

(A) 6
(B) 8
(C) 10
(D) 11

3) Assertion A : The greatest and least values of the function , does not
exist.
Reason R : The range of f(x) is unbounded.

(A) A is True, R is True; R is a correct explanation for A.

(B) A is True, R is True; R is not a correct explanation for A.
(C) A is True, R is False
(D) A is False, R is True.

4) Total number of values of a so that x2 – x – a = 0 has integral roots, where a ∈ N and 6 < a < 100
is equal to

(A) 2
(B) 4
(C) 6
(D) 8

5) Let x,y,z, t be real numbers such that x2 + y2 = 9, z2 + t2 = 4 and xt – yz = 6. Then the sum of
absolute values of least and greatest values of xz

(A) 0
(B) 2
(C) 4
(D) 6

6) Suppose a cubic polynomial f(x) = x3 + px2 + qx + 72 is divisible by both x2 + ax + b and x2 + bx +

a (where a,b,p,q are real constants and a ≠ b), then the value of p is

(A) 0
(B) 2
(C) 4
(D) 6

7)

P(x) = x5 + x2 + 1 has roots x1,x2,x3,x4,x5 and g(x) = x2 – 2 then (g(x1) g(x2) g(x3) g(x4) g(x5) –
30g(x1 x2 x3 x4 x5)) is

(A) 7
(B) 9
(C) 23
(D) 30

8) If a,b,c,d ∈ R satisfies a2 + b2 + c2 + d2 – ab – bc – cd – d + = 0, then the value of is

equal to

(A) 5
(B) 4
(C) 3
(D) 2

9)

List-I List-II

The infinite geometric series with common ratio

(A) (I) 6
has a finite sum, then x cannot take
value equal to

If x, 5x – 1, 4x are first three terms of G.P. and S is

(B) the sum of infinite geometric series whose common (II) 7
ratio is x and 1st term is 1, then 6S is/are equal to
 The number of ordered pairs (x,y) which satisfy
(C) the equation 2(cos2x + sin2y) + 1 = 2(cosx – siny) (if x,y (III) 10
∈ [0,3π]) is

If a > 1 and b > 1, then the minimum integral value of

(D) (IV) 9
is
(A) (A) – II, (B) – II,IV, (C) – I, (D) – III
(B) (A) – I, (B) – II,IV, (C) – I, (D) – III
(C) (A) – III, (B) – II,IV, (C) – I, (D) – II
(D) (A) – II, (B) – I, (C) – II,IV, (D) – III

10) Let 'β' be the product of the real solutions of the equation (log52x)(log53x) = 12, then 36β is
equal to

(A) 3
(B) 4
(C) 6
(D) 9

11) The one of the solution of the equation 9cos12x + cos22x + 1 = 6 cos6x cos2x + 6cos6x – 2 cos2x is

x = α, (where α acute is angle and cosx ≠ 0) such that , then 'a' is

(A) Prime
(B) Composite
(C) Even
(D) Even prime

12) If upto infinite terms = k, then the value of

( upto infinite terms) will be-

(A)

(B)

(C)

(D)

13) The sum equals-

(A)
(B)

(C) 1
(D) –1

14) If 1 + 22 + 333 + .....+... upto n terms = , (1 < n < 9) ; then is :-

(A)

(B)

(C)

(D)

15) Statement-I : Minimum value of , (where x > 0) is 27.

Statement-II : If a, b, c are three positive numbers then AM > GM

(A) Statement-I is true but Statement-II is false

(B) Both Statement-I and Statement-II are false
(C) Both Statement-I and Statement-II are true
(D) Statement-I is false but Statement-II is true

16) In ΔABC, if A + B = 120º, then is equal to -

(A)

(B)

(C)

(D)

17) Let a,L,e,n be real number with (a + L) (L + e) (e + a) ≠ 0 that satisfy

and . Then the value of sum of digits of n

(A) 6
(B) 8
(C) 10
(D) 12

18) If such that a2 – b2 = c2 + 2, then the number of possible triplets (a, b, c) is equal to -

(A) 0
(B) 1
(C) 2
(D) infinite

19) If the sum of the series can be expressed as , where p and q are
coprime numbers, then (q – 3p) is equal to

(A) 6
(B) 5
(C) 7
(D) 8

20) If the complete set of values of 'x' satisfying the inequality is

(where a,b,c ∈ N), then value of a + b + c is

(A) 0
(B) 140
(C) 136
(D) 272

SECTION-II

1) Let a,b,c be real numbers with

1 < a < b < c that satisfy the equation
logab + logbc + logca = 6.5
logba + logcb + logac = 5.
Then max {logab, logbc, logca} can be written in the form , where x and y are positive
integer, then the value of (x + y) is equal to

2) Let A and B be sets with the property that there are exactly 144 sets which are subsets of at least
one of A or B. How many elements does the union of A and B have ?

3) If P is a point on the altitude AD of triangle ABC such that ∠CBP = and if AP = λ

(where symbols have their usual meanings), then λ is -
4) In a right angled triangle ΔABC with C as a right angle, a perpendicular CD is drawn to AB. The
radius of the circles inscribed into the triangles ACD and BCD are equal to 9 and 40 respectively.
Then the radius of the circle inscribed into ΔABC is

5) If m,n are relatively prime positive integers such that , then the value of
(100m+n) is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B C B B C C B C B B A B C B B B C B B

SECTION-II

Q. 21 22 23 24 25
A. 80 12 475 10 550

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D D B A B C A B A B B D D C D C C D D

SECTION-II

Q. 46 47 48 49 50
A. 268 112 3 4 10

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B A D D A A C A C A B D C D A A A B B

SECTION-II

Q. 71 72 73 74 75
A. 16 8 2 41 504
 SOLUTIONS

PART-1 : PHYSICS

1)

Correct Answer is (A)

2)

Correct Answer is (B)

3)
(As temperature increases λm decreases)

4)

Correct Answer is (B)

5)

× 10 × 10 × 1 × 10–1 = 0.05J

6)

Correct Answer is (C)

7)

Correct Answer is (C)

8)

Correct Answer is (B)

9)

Correct Answer is (C)

10)

Correct Answer is (B)

11)

Correct Answer is (B)

12)

13)

14)

Correct Answer is (C)

15) We have the mean free path as λ = 0.8 × 10–7 m and the number of molecules per unit
volume (or number density) as n = 2.7 × 1025 per m3.

Substituting these values in the expression of mean free path , we get the
molecular diameter as follows:

= 3.2 × 10–10 m = 3.2A

16)

= 1.5 × 105 Nm–2

17) In a refrigerator, the heat dissipated in the atmosphere is more than that taken from the
cooling chamber; therefore, the room is heated if the door of a refrigerator is kept open.

18) Coefficient of performance of an engine is given by:

Substituting the values in this relation, we get the temperature of the air (to which heat is
rejected) as follows:

⇒ 5T1 – 1300 = 260

⇒ 5T1 = 1560
⇒ T1 = 312 K = 39°C

19) Transmitting power + Absorbtion power + Reflection power = 1

Absorptive power = 0.5 ⇒

Q = 0.5 × QTotal = 0.5 [σAT4]
= 0.5 × 5.67 × 10–8 × 0.15 × 5004
Q = 265.78 W.

20)

Correct Answer is (B)

21)

Correct Answer is 80

22)

Correct Answer is 12

23)

Correct Answer is 475

24)

Correct Answer is 10

25) We have the following two efficiencies:

Therefore,
Since WA = WB, we get

= 550K
PART-2 : CHEMISTRY

26) Cgraphite + 2H2(g) → CH4(g)

ΔH°f[CH4(g)] = 2X + Y – 4 × BEC–H

BEC–H =

27)

Correct answer is option (4)

28) H2CrO4(aq) + 2OH–(aq) → C2 (aq) + 2H2O ΔH1 = –25.4 kcal/mol.

H+(aq) + OH–(aq) → H2O ΔH2 = –13.7 kcal/mol.
H2C2O4(aq) → 2H+(aq) + C2 (aq) ΔH3 = ΔH1 – 2ΔH2 = 2 kcal/mol.

29)

P2 = 32 bar

30)

In adiabatic free expansion temperature does not change.

31)

Correct answer is option (2)

32)
= (3N – 3)R

33)

Above reaction / phase change would be at equilibrium at 0.01 atm and 27°C,
∴ ΔG = 0

34) Reaction will be spontaneous at 400 K and 1atm

H2O(s) → H2O(l)
 ΔS = 60 –38 = 22 Jmol–1K–1
ΔG < 0
ΔH – TΔS < 0
ΔH < TΔS
ΔH < (400) (22)
ΔH < 8800

35) ΔG° = –RT ln Kp ; Kp = (2x)2X = 4X3

ΔG° = –RT ln(4X3)
ΔG° = –RT ln 4–3RT ln X

36)

37) The correct answer is option (B)

38) The correct answer is option (D)

39) The correct answer is option (D)

40) The correct answer is option (C)

41) The correct answer is option (D)

42) The correct answer is option (C)

43) The correct answer is option (C)

44) The correct answer is option (D)

45) The correct answer is option (D)

46) ΔrG° = – RT ln K°P

=– × 300 × ln J
= – 11500 J
Now, ΔrG° = ΔrH° – T, ΔrS°
or, – 11500 = – 46000 × 2 – 300 × ΔrS°
∴ ΔrS° = – 268.33 J/K.
 47)

Benzene (ℓ) Benzene (g) Benzene (g)

(1 atm, 78°C) (1 atm, 78°C) (5 atm, 78°C)

ΔG = ΔG1 + ΔG2 = 0 + nRT ln

= × 351 × ln = 112.320 kcal.

48) P1 = 2 bar, T = 273 K, P2 = 4 bar

= constant PV–1 = constant x = –1

49) 3 Ca3(PO4)2.CaF2
⇒ 3 [40 × 3 + (31 + 16 × 4) × 2] + [40 + 19 × 2] = 1008

% F (by mass) = × 100 = 3.76 % 4

50) x = 4 ;
y=6

PART-3 : MATHEMATICS

51)

sin15º = sin(45º – 30º) = sin 45º cos30º – cos45º sin30º

52)

Similarly, y–1 – 1 and and hence

53)

Let g(x) = 6 sin x – 8 cosx + 5.

The maximum and minimum values of g(x) are 15 and –5 i.e., –5 < g(x) < 15

and
Thus, the range of f(x) =
i.e., the range of f(x) is unbounded.
∴ the maximum and minimum values of f(x) does not exist.

54)

x–2 – x – a = 0, D = 1 + 4a = odd
Let D = (2λ + 1)2 ⇒ 1 + 4a = 1 + 4λ2 + 4λ ⇒ a = λ(λ + 1)
Since a ∈ [6,100], therefore a = 6,12,20,30,42,56,72,90
Thus 'a' can attain 8 different values.

55)

Let x = 3 cosθ, y = 3 sinθ

z = 2 cos ϕ and t = 2 sinϕ
⇒ 6 cos θ sin ϕ – 6 sinθ cos ϕ = 6
⇒ sin(ϕ – θ) = 1
⇒ ϕ – θ = 90º ⇒ ϕ = 90 + θ
Therefore, x = 3 cosθ, y = 3 sin θ and z = –2 sinθ, t = 2 cosθ
let P = xz = –6 sinθ cosθ = – 3 sin2θ
Hence, Pmax = 3 , Pmin = –3

56)

Since cubic is divisible by both x2 + ax + b and x2 + bx + a. Therefore, x2 + ax + b and x2 + bx

+a
must have a common roots
x2 + ax + b = 0
x2 + bx + a = 0
subtract
⇒ x(a – b) = (a – b)
⇒x=1
Therefore, common roots
for x2 + ax + b are 1 and α ⇒ 1. α = b ⇒ α = b
for x2 + bx + a = 0 are 1 and β ⇒ 1.β = a ⇒ β = a
⇒ roots of cubic be 1,a,b
⇒ 1 × a × b = –72 ...(1)
and a + b +1 = 0 ....(2) (from x2 + ax + b = 0 put x = 1)

∴
⇒ a2 + a – 72 = 0
(a + 9) (a – 8) = 0
a = –9,8
Therefore roots are 1, –9,8

57)

Let y = x2 – 2 = g(x) ⇒ x =

P(x) = 0 ⇒

(y + 2)4 (y + 2) = (y + 3)2
⇒ y5 + 10y4 + 40y3 + 79y2 + 74y + 23 = 0
Root are g(x1), g(x2), g(x4), g(x5)
Product of roots
= g(x1) g(x2) g(x3) g(x4) g(x5) = –23
x1x2x3x4x5 = –1
g(x1x2x3x4x5) = g(–1) = 1 – 2 = –1
g(x1) g(x2) g(x3) g(x4) g(x5) – 30g(x1x2x3x4x5)
= –23 – 30(–1) = 7

58)

a2 + b2 + c2 + d2 – ab – bc – cd – d + =0

Now,

59) (I) < 1 ⇒ x2 – 14x + 50 > 1

⇒ (x – 7)2 > 0 ⇒ x ≠ 7.
(II) (5x – 1)2 = 4x2 ⇒ 21x2 – 10x + 1 = 0

⇒ or
(III) 4cos2x – 4sin2y + 2 – 4cosx + 4siny = 0
⇒ (2cosx – 1)2 + (2siny + 1)2 = 0

⇒ and

(IV)

⇒ 1 + logba + (∴ 1 + logba ≠ 1)
60)

Let y = log5x. Then

(log52x) (log53x) = (log5x + log52) (log5x + log53)
= (y + log52) (y + log53)
= y2 + (log52 + log53)y + log5 2log53
So the given equation becomes
y2 + (log52 + log53)y + log52log53 – 12 = 0
The discriminant of this quadratic is
(log52 + log53)2 – 4(log52log53 – 12) = (log52 – log53)2 + 48 > 0.
so, it has two real distinct roots. Let them be y1 and y2. Then by Vieta's formulas,
y1 + y2 = –(log52 + log53) = –log56.
Then the corresponding solutions in x are x1 = and x2 = , so

61)

Given equation (3 cos6x – 1 – cos2x)2 = 0

3 cos6x – 2 cos2x = 0

cos2x ≠ 0

62)

63)

64) 1 + 22 + 333 + ........ n terms

∴

65) Statement-I :

∴ Minimum value is 55

66) Put ∠C = 60º

67) ...(1)

....(2)

....(3)
Add (1), (2) and (3)

a – L + L – e + e – a = n – 123
∴ n = 123

68) a2 – b2 = c2 + 2
where c is a even natural number
⇒ (a + b) (a – b) = c2 + 2
(i) if a,b ∈ odd ⇒ (a + b) (a – b) is divisible by 4, but c2 + 2 is not divisible by 4 so case(i)
rejected
(ii) if a,b ∈ even ⇒ case is same as (i)
so case (ii) is rejected
(ii) if a,b are even and odd respectively
⇒ (a + b) (a – b) is an odd number
but c2 + 2 is even
so case (iii) rejected.

69) Let S =
then

Now by the differentiation of the power series expansion (1 – z)–1

we get (1 – z)–2

multiply by z and put , we get

⇒ q – 3p = 5.

70) put |log2x| = t

⇒ t2 – 5t – 14 ≤ 0
⇒ (t – 7)(t + 2) ≤ 0
–2 ≤ t ≤ 7
and t2 – 5t + 6 ≥ 0
⇒ (t – 2)(t – 3) ≥ 0 ⇒ t ∈ (–∞, 2] ∪ [3, ∞)
Hence t ∈ [–2, 2] ∪ [3, 7]
0 ≤ |log2x| ≤ 2 and 3 ≤ |log2x| ≤ 7

a + b + c = 128 + 8 + 4 = 140

71)

Let logab = α, logbc = β, logca = γ

Given
αβγ = 1 (by observation)
αβ + βγ + γα = 5αβγ = 5
Now, form a cubic polynomial with
α,β,γ as its roots

2t3 – 13t2 + 10t – 2 = 0

check if satisfies,

∴ is a root and (2t – 1) is a factor (2t3 – 13t2 + 10t – 2) = (2t – 1) (t2 – 6t + 2)

max {α,β,γ} = 3 + =

72)

2p+r + 2q+r – 2r = 144

⇒ 2r(2p + 2q – 1) = 16.9
⇒ r = 4 and 2p + 2q = 10 ⇒ p = 1 and q = 3
⇒p+q+r=8

73)

∠ABP = & ∠APB = 90° +

Use sine law in ΔAPB

AP = 2Csin
⇒ λ=2
74)
ΔACD ΔCBD ABC

AC2 + BC2 = AB2

81 + 1600 = r2
r = 41

75)

(if i = even then j = odd and if i = odd then j = even)

∴ 100 m + n = 504.