28-11-2025

1001CJA101021250034 JA

PART-1 : PHYSICS

SECTION-I

1) A charge particle (m,q) is moving along positive 'x'-direction without deviation in a region where
both magnetic & electric field are present. If electric field is uniform, then possible magnetic
field for such a motion of particle is :-

(A)
(B)
(C)
(D)

2) A thin, 50 cm long metal bar with mass 750 g rests on, but is not attached to, two metallic
supports in a uniform 0.450 T magnetic field as shown in figure. A battery and a 25 Ω resistor in
series are connected to the supports. What is the largest voltage the battery can have without

breaking the circuit at the supports? (Take : g = 9.8 m/s2)

(A) 817 V
(B) 325 V
(C) 412 V
(D) 160 V

3) Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R),
Assertion (A) : A coil is suspended in a uniform magnetic field. With the plane of the coil parallel to
the magnetic field, it starts oscillating and oscillate for long time, but if an aluminium plate is placed
near to the coil it stops sooner.
Reason (R) : Electromagnetic induction in the aluminium plate giving rise to electromagnetic
damping.

(A) Both (A) and (R) are true and (R) is the correct explanation of (A)
(B) Both (A) and (R) are true and (R) is not the correct explanation of (A)
(C) (A) is true but (R) is false
(D) (A) is false but (R) is true
4) An series LCR circuit is resonating with a source whose emf varies with time as described in
diagram-1. If we replace source by another source whose emf varies with time according to

diagram-2, then :-

(A) for getting resonance again, decrease R

(B) current will remain in phase with source voltage
(C) current will lag from source voltage after replacing the source
(D) current will lead from source voltage after replacing the source

5) Two AC sources ε1 = 10 sinωt and are fed to an LR circuit. The resistance is

10 Ω and inductance reactance is , then choose the correct option.

(A) The equivalent emf of AC source has a peak value of .

(B)
The peak value of current is .

(C)
Phase angle between current and voltage is radian.

(D)
Power factor of the circuit is .

6) The current through the coil in figure (a) varies as shown in figure (b). Which graph does best
show the ammeter A reading as a function of time?
(A)

(B)

(C)

(D)

7) The following figure shows the displacement versus time graph for two particles A and B
executing simple harmonic motions. The ratio of their maximum velocities is :-
(A) 3 : 1
(B) 1 : 3
(C) 1 : 9
(D) 9 : 1

8) A square loop of side length 6 cm, carries I = 30 Amp. Find the magnitude of at a point lying on

the axis of loop at a distance cm.

(A) 3 × 10–4 T
(B) 2.7 × 10–4 T
(C) 2.7 × 10–3 T
(D) 3 × 10–3 T

9) In a series AC circuit if we change either resistance or reactance not only current amplitude
changes, but phase angle between current and voltage also changes. If we take voltage as a
reference and draw voltage phasor then head of this phasor moves on a perticular trajectory. In List-
I, variation of resistance and reactance is specified and in List-II is given path followed by head of
current phasor.

List-I List-II

(1)
(P)
 (2)
(Q)

(3)
(R)

(4)

(S)

Choose the correct answer from the option given below :

(A) P→1, Q→2, R→3, S→4
(B) P→4, Q→1, R→2, S→3
(C) P→2, Q→1, R→3, S→4
(D) P→1, Q→4, R→2, S→3

10) Current sensitivity of a moving coil galvanometer is increased by 50% and its resistance is
increased so that new resistance is twice of the initial resistance. So its voltage sensitivity is :-

(A) increased by a factor 2

(B)
decreased by a factor of
(C) increased by a factor 4

(D)
decreased by a factor of

11) A triangular shaped wire of side length, total resistance R = 2 Ω is rotated in a

magnetic field B = 5 T through 180° in Δt = 0.02 second. The amount of charge flown through the

loop will be :-

(A)
(B)

(C)

(D) Zero

12) Find current through the inductor after long time after making the circuit.

(A) 1A from A to B
(B) 1A from B to A
(C) 0.5 A from A to B
(D) 0.5 A from B to A

13) Current I flows through an inductor L given by I = e–t – e–2t, then induced emf in this coil is zero
at time :-

(A) t = 0
(B) t = 1

(C)

(D) t = ℓn2

14) Figure shows a cross-section of a large-section of an infinite metal sheet carrying an electric
current along its surface. The current per unit length is J. A current carrying square loop is placed
nearby the metal sheet such that the plane of square is perpendicular to the plane of sheet then :-

(A) Square loop will be attracted towards the sheet.

(B) Square loop will be repelled away from the sheet.
(C) Square loop will remain in translational equilibrium.
(D) Square loop will remain in rotational equilibrium.

15) Find the total time during which a non-zero current is flowing in the loop (given : b > a)
(A)

(B)

(C)

(D)

16) A small magnet of dipole moment M is placed at origin as shown in figure. Then select correct

alternative about magnetic field produced by it at (a, 0) :-

(A)
, at angle ϕ = 30° with x-axis.

(B)
, at angle ϕ = 60° with x-axis.

(C)
, at angle ϕ = tan–1 with x-axis.

(D)
, at angle ϕ = tan–1 with x-axis.

17) The B–H curve for a ferromagnet is shown in the figure. The ferromagnet is placed inside a long
solenoid with 1000 turns/cm. The current that should be passed in the solenoid to demagnetise the
ferromagnet completely is :-

(A) 1 mA
(B) 20 µA
(C) 2 mA
(D) 40 µA

18) The region between x = 0 and x = d contains a magnetic field . A particle of mass m and

charge q enters the region with a velocity . If d = , the acceleration of the charged
particle at the point of its emergence at the other side is :-

(A)

(B)

(C)

(D)

19) Consider two identical circular loops of same radius, with the second (right side) coil rotated
slightly clockwise relative to the first when looked from above as shown in figure. A large current is

suddenly injected into the left side loop. What happen to the right side loop?

(A) Force to the left, torque rotates clockwise (in top view).
(B) Force to the right, torque rotates clockwise (in top view).
(C) Force to the right, torque rotates counterclockwise (in top view).
(D) Can't tell without knowing which direction current injected into left loop.

20) The switch 1 is closed for a long time. Then switch 2 is closed at point A and switch 1 is open
simultaneously at t = 0. Inductors are ideal and battery has no internal resistance. There is no loss

of heat during switching. Choose incorrect statement.

(A) Before t = 0, current in 3H inductor is 2A.

(B) Before t = 0, current in 1 Ω resister is zero.
(C) The total heat dissipated in 1 Ω resistor after t = 0 is 18 J.
(D) The total heat dissipated in 1 Ω resistor after t = 0 is 12 J.

SECTION-II

1) A conducting bar of thickness d is made to move with uniform velocity μ perpendicular to a

uniform magnetic field of induction B. Top and bottom faces of the bar are parallel to the lines of
magnetic field as shown in the figure. If the surface charge density on the upper and bottom faces of

the bar is σ = nε0 C/m2 when & , find value of n :-

2) For a series LCR circuit half power frequencies are 950 Hz & 1050 Hz. Find value of quality factor
in nearest integer.

3) Two uniform magnetic fields B1 = 10 T and B2 = 20 T exist above and below the current carrying

sheet as shown in figure. Here K is current per unit length in the sheet. If , find the
value of η.

4) A coil of inductance L = 5H and resistance is connected in series to the mains

alternating voltage of frequency f = 50 HZ in series. What can be the non-zero capacitance of the
capacitor (μF) connected in series with the coil if the power dissipated has to remain unchanged?
(take π2 = 10)

5) Two particle of m each are are fixed to a massless rod of length . The rod is smoothly hinged at
one end to ceiling. It performs oscillation of small angle in vertical plane. If the length of the

equivalent simple pendulum is , then find the value of x.

PART-2 : CHEMISTRY

SECTION-I

1) The kinetic energy of an electron in second Bohr's orbit of a hydrogen atom is : (a0 is Bohr's
radius):-

(A)

(B)

(C)

(D)

2) Assertion :- In H-atom, the energy of 3d-level is smaller than 4s-level.

Reason :- In multi-electron species, an orbital with lower value of (n + ℓ) has energy smaller than
the orbital with larger value of (n + ℓ).
(A) Both Assertion & Reason are True & Reason is a correct explanation of the Assertion.
(B) Both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.
(C) Assertion is True but the Reason is False.
(D) Both Assertion & Reason are False.

3) Give the correct order of initials T (true) or F (false) for following statements :-
(I) If an ion has 2 electrons in K shell, 8 electrons in L shell and 6 electrons in M shell, then number
of S electrons present in that element is 6.
(II) The maximum number of electrons in a subshell is given by 2n2
(III) If electron has magnetic quantam number –1, then it cannot be present in s-orbital.
(IV) One nodal plane is present in 3p orbital.

(A) TTFF
(B) FTTF
(C) TFTT
(D) FFTF

4) The mechanism of the reaction

A + 2B → D is as under :
[slow]
B2 + A → D [fast]
What is the rate, order with respect to A, B and the total order respectively?

(A) k[B]2, 0, 2, 2
(B) k[A] [B]2, 1, 2, 3
(C) k[A]2, 0, 2, 2
(D) k[A]2 [B], 1, 2, 3

5)

For 1st order reaction :

A(g) → B(g) + 3C(g)
following graph are constructed -

calculate
time in which total pressure of container is increased to 2.9 atm. (ln2 = 0.7)
(A) 3hr
(B) 2hr
(C) 30 min
(D) 20 min

6) For the reaction 2A —→ B + 3C ;

if ;

the correct reaction between k1, k2 and k3 is :-

(A) k1 = k2 = k3
(B) 2k1 = k2 = 3k2
(C) 4k1 = k2 = 3k2

(D)

7) For the following reactions

it was found that Ea is decreased by 30 kJ/mol in the presence of catalyst.

If the rate remains unchanged, the activation energy for catalysed reaction is (Assume pre
exponential factor is same):

(A) 135 kJ/mol

(B) 105 kJ/mol
(C) 198 kJ/mol
(D) 75 kJ/mol

8) Which reagent would best accomplish the following transformation?

(A) 1. LiAlH4; 2. Jone's reagent

(B) 1. LiAlH4; 2. PCC in CH2Cl2
(C) 1. NaBH4; 2. Jone's reagent
(D) 1. NaBH4; 2. PCC in CH2Cl2

9) Column I & Column II contain data on Schrondinger Wave-Mechanical model, where symbols
have their usual meanings.
 Column-II
Column-I
(Type of orbital)

(A) (P) 4s

(B) (Q) 5px

(C) ψ(θ, ) = K (independent of θ & ) (R) 3s

(D) atleast one angular node is present (S) 6dxy

Select the correct match

(A) A R, B P, Q, S, C P, R; D Q, S
(B) A P, B P, R; C P, Q, S; D Q, S
(C) A P, B P, Q, S; C P, R; D Q, S
(D) A R, B P, R; C P, Q, S; D Q, S

10) What reagent is the source of nitrogen in the Gabriel synthesis of amines?

(A) sodium azide, NaN3

(B) sodium nitrite, NaNO2
(C) potassium cyanide, KCN
(D) potassium phthalimide, C6H4(CO)2NK

11) A nitrogen containing compound dissolves in 10% aq. sulfuric acid.

The Hinsberg test (C6H5SO2Cl in base) gives a solid product that is not soluble in 10% aq. NaOH.
Which of the following would best fit these facts?

(A) N,N-dimethylaniline, C6H5N(CH3)2.

(B) N-methylbenzamide, C6H5CONHCH3.
(C) N-methylaniline, C6H5NHCH3.
(D) benzylamine, C6H5CH2NH2

12)

Which of the following is the weakest Brønsted base?

(A)

(B)

(C)

(D)

13) A C7H12O2 compound gives a positive Tollens' silver mirror test and a positive iodoform
test. Which of the following would satisfy these facts?

(A) 2-hydroxy-3,3-dimethylcyclopentanone
(B) 2,5-heptanedione
(C) 2,2-dimethyl-3-oxopentanal
(D) 2,2-dimethyl-4-oxopentanal

14) Which of the following common names does not represent a dicarboxylic acid?

(A) lactic acid

(B) succinic acid
(C) phthalic acid
(D) glutaric acid

15) Read the given statements and choose the correct option
Statement-I : Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols
of comparable molecular masses.
Statement-II : More extensive association of carboxylic acid molecules through intramolecular
hydrogen bonding.

(A) Both Statement-I and Statement-II are incorrect

(B) Statement-I is correct and Statement-II is incorrect
(C) Statement-I is incorrect and Statement-II is correct
(D) Both Statement-I and Statement-II are correct

16) The product of the reaction between diethyl cadmium and acetylchloride is -
(A) CH3CH2COCH2CH3
(B) C2H5COC2H5
(C) CH3CH2OH
(D) CH3COC2H5

17)

Find the major product of given reaction :

(A) 4-Phenylbut-2-enal
(B) 2-Methylpent-2-enal
(C) 3-Phenylprop-2-enal
(D) Hex-3-enal

18) Predict the products in the given reaction.

(A)

(B)

(C)

(D)
19)
Product [P] in above reaction is

(A)

(B)

(C)

(D)

20) An aromatic compound 'P' with molecular formula C9H10O gives the following chemical tests :
(i) undergoes Cannizzaro reaction
(ii) on vigorous oxidation, 1,2-benzenedicarboxylic acid is obtained
(iii) forms 2, 4-DNP derivative
(iv) reduces Tollens' reagent P is

(A)

(B)

(C)
(D)

SECTION-II

1) 99% of a first order reaction was completed in 32 minutes, what will be time (in minutes) of
completion of 99.9% of the reaction :

2) In thermal decomposition of a gaseous substance, following half life periods were obtained at
different pressures :

P (mm) 900 400

t1/2 (min) 300 200

Determine order of reaction.

Fill your answer by multiplying with 2.

3) An orbital of Li2+ ion does not have any nodal surface (radial node). If the Bohr radius of the orbit,
of which the given orbital belongs, is 1.587 Å, the value of azimuthal quantum number of that orbital
is:

4) Total number of sp2 atoms present in the expected product from the reaction sequence drawn
below?

5) Find total number of 1° amides (benzenoid) having molecular formula (C8H9NO) on reaction with
Br2/NaOH. Gives 1° amines as major products

PART-3 : MATHEMATICS

SECTION-I

1) A biased coin is tossed repeatedly until a tail appears for the 1st time. The head is 2 times likely to
appear as tail. The probability that the number of tosses required will be more than 6 given that in
1st three toss no tail has occured is/are

(A)

(B)

(C)

(D)

2) The product of all the even divisors of N = 9000 is

(A) 272 . 336 . 536

(B) 254 . 336 . 554
(C) 254 . 354 . 536
(D) 272 . 336 . 554

3)

Assertion : If f : {a, b, c, d, e} → {a, b, c, d, e}, f is onto and f(x) ≠ x for each x ∈ {a, b, c, d, e}.
Then number of such functions are 44.

Reason : The number of derangement for n objects is n!

(A) Assertion is True, Reason is True, Reason is correct explanation for Assertion
(B) Assertion is True, Reason is True, Reason is NOT a correct explanation for Assertion
(C) Assertion is True, Reason is False
(D) Assertion is False, Reason is True

4) Let Bn denotes the event that n fair dice are rolled once with , e.g.

. Here B1, B2, B3,.......Bn are pairwise mutually

exclusive and exhaustive events as n → ∞. The event A occurs with atleast one of the event B1,
B2,....,Bn and denotes that the sum of the numbers appearing on the dice is S.
If even number of dice has been rolled, the probability that S = 4, is

(A)
Very close to

(B)
Very close to

(C)
Very close to

(D)
Very close to
5) The value of is equal to

(A) 4
(B) 3
(C) 1
(D) 5

6) Let S = set of triplets (A, B, C) where A, B and C are subsets of {1, 2, 3,....n}. E1 = event that a
selected triplet at random from set S will satisfy , then P(E1) is
equal to

(A)

(B)

(C)

(D)

7) If three one by one squares are selected at random from the chessboard, then the probability that
they form the letter 'L' is (In any orientation)

(A)

(B)

(C)

(D)

8) The number of ways of choosing triplet (x, y, z) such that z ≥ max{x, y} and x, y, z ∈ {1, 2, ..., n, n
+ 1} is

n+1
(A) C3 + n+2C3

(B)

(C) 12 + 22 + ... + n2

(D)

9) A square of 5 x 5 unit2 area is shown is the diagram, contain 25 square of 1 × 1 unit2 area. A
person can move on this grid (on the sides of small squares) either right or up, then
 List-I List-II

Number of such paths from point P to point Q which do

(A) not touch the boundary of squares (1 × 1 unit2 area) (I) 73
contain alphabets A, I, T and S

Number of such paths from point P to point Q which do

(B) (II) 84
not crosses the diagonal PQ at any moment

How many rectangles can be formed by joining small (1

(C) × 1 unit2 area) so that none of rectangles contain (III) 218
alphabets A, I, T and S

Number of such paths from P to Q, which always pass

(D) through the boundaries of the square which contain (IV) 4
either (A and I) or (T and S)

The correct option is

(A) (A) → III, (B) → IV, (C) → I, (D) → II
(B) (A) → II, (B) → I, (C) → III, (D) → IV
(C) (A) → IV, (B) → II, (C) → I, (D) → III
(D) (A) → I, (B) → III, (C) → IV, (D) → II

10) Consider the following frequency distribution

Class 0-10 10-20 20-30 30-40 40-50 50-60

Frequency 3 a b 11 8 4

If the mean is and median is , then the value of 4a + b is

(A) 40
(B) 38
(C) 50
(D) 48

11) The remainder on dividing 1234567 + 891011 by 12 is

(A) 1
(B) 5
(C) 9
(D) 8
12) A person buys eight packets of TIDE detergent. Each packet contains one coupon, which bears
one of the letters of the word TIDE. If he shows all the letters of the word TIDE, he gets one free
packet. Suppose he gets exactly one free packet, then the number of different possible combinations
of the coupons is

7
(A) C3 – 1
8
(B) C4 – 1
8
(C) C3
(D) 44

13) Consider a 9 sided regular polygon then the probability that if 3 vertices are selected at random
the triangle so formed will contain the centre of the polygon is

(A)

(B)

(C)

(D)

14) In a group of 3 girls and 4 boys, there are two boys B1 and B2. The number of ways, in which
these girls and boys can stand in a queue such that all the girls stand together, all the boys stand
together, but B1 and B2 are not adjacent to each other, is :

(A) 144
(B) 72
(C) 96
(D) 120

15) Statement 1 :

Statement 2 :

(A) Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for statement-1
Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for
(B)
statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

16) If log2 for positive x, y and z,

then which of the following is true ?

(A) z < x < y

(B) x < y < z
(C) y < z < x
(D) z < y < x

17) Let m, n be real numbers satisfying the relation :

= log2n + log2 (2m + 2 – n)

Identify which of the following statement(s) is/are correct ?

(A) m + n = 3
(B) ||m| – |n|| = 4
(C) Area of the figure enclosed by |x| + |y| = |m| + |n| is 8 square units.
(D) Area of the figure enclosed by |x| + |y| = |m| + |n| is 16 square units.

18) Let X = {11, 12, 13, ......... 40, 41} and Y = {61, 62, 63, ........ 90, 91} be the two sets of
observations. If and are their respective means and is the variance of all the observations in
, then is equal to

(A) 600
(B) 601
(C) 603
(D) 602

19) equals

(A) 1
(B) –1
(C) n
(D) 0

20) When is divided by 7, then the remiander

(A) 2
(B) 3
(C) 4
(D) 5

SECTION-II

1)
and xy = 4a then total number of ordered pair solution (x, y) where x, y ∈ I+ is

2) Let n be the number of triangles that can be formed by using three different line segments a, b, c
where a, b, c ∈ {2, 3, 4, 5, 6, 7}. If x and y are two positive integers whose LCM is (n + 2) then total
no of ordered pair solution (x, y) will be

3) Betty has a 3 × 4 grid of dots. She colors each dot either red or maroon. Compute the number of
ways Betty can color the grid such that there is no rectangle whose sides are parallel to the grid
lines and whose vertices all have the same color.

4) The number of terms with integral coefficient in the expansion of is :

5) All five letter words that are made using all the letters A, B, C, D, E and arranged as in an English
dictionary with serial numbers. Let the word at serial number 'n' be denoted by Wn. Let the
probability P(Wn) of choosing the word Wn satisfy P(Wn) = 2P(Wn – 1), n > 1. If P(CDBEA) =

, then α + β is equal to :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B A A D A A A B B D A A D C B D A D B C

SECTION-II

Q. 21 22 23 24 25
A. 2 10 20 1 5

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B C A A D D B C D C D D A B D C A D A

SECTION-II

Q. 46 47 48 49 50
A. 48 1 2 8 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D D C D C D A D C A C A A A D A C C D C

SECTION-II

Q. 71 72 73 74 75
A. 8 9 408 101 183
 SOLUTIONS

PART-1 : PHYSICS

1) (for no deviation)
∴

2) Bil sinθ = mg ⇒ B(V/R)I sinθ = mg

⇒ 0.450(V/25) (0.5) sin90º = 0.750 × 9.8
⇒ V = 817 V

3) (A)-C, R-C, Reason is correct explanation.

4)

ω2 < ωR from diagram

Circuit will behave as capacitance circuit
∴ current leads voltage

5)
εeq = ε1 + ε2 [just like a superposition of SHM]

=
∴ Peak value of equivalent emf =
cosϕ = power factor = 1/2

6)

Hence, (direction already indicated)

7) TA = 16 s,

TB = 24s, rad/s

=3

8)

Perpendicular distance of P from each side of loop is

= 9 × 10–5 T
Bnet = 4B0 cos θ = 2.7 × 10–4 T

9) as we know that X = Net reactance

&
x , ϕ i, i0 , when R = constant
X = constant R , ϕ , i0 2

10) We knew that :

Sv = Voltage sensitivity
Sv = Voltage sensitivity
G = Resistance of Galvanometer

∴ It decreased by a factor of

11) =

12)

Correct answer is (A).

13)

Correct answer is D.

14)

square loop experiences an attractive force.

15)

correct answer is B.

16)

tanα = tanθ = tan60 =

α = tan–1 from x-axis

17)

n = 1000 turns/cm, H = 100 A/m

H = ni
100 = 1000 × 102 i
i = 1 mA

18)

19)
When suddenly current injected into the left loop flux through the IInd loop increase w.r.t.
time. So, according to Lenz law a induced current develop in the IInd loop.
τ= [clock wise]

20) Before switching

When switch at position 1 for a long time all inductors are short circuited

Energy in 3H inductor = × 3 × 2 = 6J

Energy in 6H inductor × 6 × 2
Total 0 initial energy = 18 J
after switch on

For a closed loop

i = 2e–t/6 A

∴ Heat loss = =
= 4 × 3 = 12 J

21)
free e– of this conductor will experiences an upward force due to magnetic field. This will lead
accumulation of negative charges on top surface and the charge on bottom surface.
∴ An electric field induced from bottom to upper surface. Now if σ be the charge density of two
surfaces then in equilibrium

0 0 0
⇒ σ = ε VB = ε × 20 × 10–2 × 10 = 2 ε

22) f1 = 950 , f2 = 1050

23)
By Ampere law

=
k

∴ 10 =
η = 20

24) XL = wL = 100 π × 5 = 500 p, R = 55

P = I2 R

∴ XC = 2XL

= 1 μF

2
25) I = m +m
TC = T
 ∴

PART-2 : CHEMISTRY

26) Nuclear attraction = Centrifugal force

v2 = ....(i)

Angular momentum, (mvr) =

v2 = ....(ii)
Comparing eqns. (i), (ii)

r=

∴ vn = ; K.E. =

K.E. for (n = 2, Z = 1) =

27)

3d 4s

n 3 4

ℓ 2 0

n+ℓ 5 4
Energy is higher for the subshell having higher value of n + ℓ.

28)

Each shell has one & subshell.

Maixmum no. of electrons in a subshell are 4 + 2.
 Magnetic quantum number is s–orbital is 0.
No. of radial node = (n – – 1)

29)

Concept :- rate law with the help of reaction mechanism.

Solution :- From slow step (R.d.s) r = K [B]2
order w.r.t A = 0
order w.r.t B = 2
Total order = 0 + 2 = 2
Answer :- 1
k[B]2, 0, 2, 2

30)

By observing the graph at t = 0, PA = 0.8

at t = 0

⇒ 0.56 = K(0.8) K = 0.7

A → B + 3C
0.8 – –
at t 0.8–x x 3x
2.9 = 0.8 – x + x + 3x
x = 0.7
As we know for 1st order

31)

Rate of reaction =

or

32)

For same rate

K1 = K2

5Ea = 7Ea – 210

210 = 2Ea
Ea = 105 kJ/mole
Ea – 30 = 75

33)

in

Correct Answer is (B)

34) It is for 4s.

It is for 4s, 5p, 6d.

Ψ (θ, ϕ) = K (independent of θ & ϕ) ⇒ valid for s orbital which have spherical symmetry.
No. of angular node =

35)

Informative
36)

insoluble
Correct Answer is (C)

37)

Basicity order

> > >

38) Positive Tollen's silver mirrore test

39) is Lactic acid.

40) More extensive association of carboxylic acid molecules through intermolecular

hydrogen bonding not by intramolecular hydrogen bonding.

41)

Preparation of carbonyl compounds.

42)

Aldol condensation reaction.

Answer: Option (C)

43) It is self cannizaro reaction

It is a Redox reaction

44)

Oxidation, NAR, Reduction.

45)

46)

= 48 min.

47)

⇒ n = 1/2

48) r =

from equation, = 1.587 ⇒ n = 3

Now, as (n – ℓ – 1) = 0 ⇒ ℓ = 2

49) +
 50)

PART-3 : MATHEMATICS

51) Let X denotes the number of toss required

Required Probability

52) N = 23 32 53

53) Dearrangement Theorem

54) , where A = sum is 4.

And

Hence

55)
56) n(E1) = 7n - 2.6n + 5n

57)

n(S) = 64C3
Let 'E' be the even of selecting 3 squares which from the letter 'L'

No ways of selecting squares consisting of 4 unit squares = 7C1 x 7C1 = 49

Each square with 4 unit squares forms 4L-shapes consisting of 3 unit squares
∴ n (E) = 7 x 7 x 4 = 196

58) z ≥ max(x, y)
(1) z > x > y , (2) z = x > y
(3) z > y > x , (4) z = y > x
(5) z > x = y , (6) z = x = y
(1) n+1C3 × 2 + n+1C2 × 3 + n+1C1
= 2 × n+2C3 + n+1C2 + n+1C1
2 × n+2C3 + n+2C2
or if z = n + 1
x, y can be chosen in (x + 1)2 ways
if z = x, x, y can be chosen in x2 ways
∴ Req.
12 + 22 + ... + (n + 1)2

59) (A) Count only for first up & then right movement.
Only 2 cases are possible
VVVVVHHHHH
and
VVVVHVHHHH
same for first right & then upward movement.
∴ Total 4 cases
(B) For n horizontal & n vertical
paths , Req. no. of such

paths =
(C)
No. of rectangles in case-I = 3C2 × 3C2
same for four corners
∴ total = 3C2 × 3C2 × 4 = 36
Case-II : Rectangles = 5
Remaining rectangles in (column 1) only

=
same for all corners
= 8 × 4 = 32 cases
∴ total = 36 + 5 + 32
= 73 cases

(D)
Total P ot Q = 10C5 = 252
4n favourable cases [Horizontal counting]
Case-I : No touching ot boundary
=5

Case-II : [touching boundary of s only]

∴
∴ Total = 34 cases (Including vertical)
∴ Req. cases = 252 – 34 = 218

60) ........ (1)

Also
a + b = 19 ......... (2)
From (1) and (2) a = 7, b = 12

61) 1234 = (1236 – 2)

∴ 1234567 = (1236 – 2)567
∴ Reminder when divided by 12 = (–2)567
similarly 891011 = (84 + 5)1011
Reminder = 51011
∴ By combining = (–2)567 + 51011
= –(2)567 + (52)505 . 51
Now because 2odd has reminder = 8 when divided by 12.
Reminder = –8 + (24 + 1)505 . 5
= –8 + 5 = –3 + 12 – 12
= –12 + 9
∴ Reminder = 9 when divided by 12

62) x1 + x2 + x3 + x4
xi ≥ 1
7
C3 – 1

63)

64) Total – when B1 and B2 are together

= 2!(3! 4!) – 2! (3!(3! 2!)) = 144

65)

General term =

Sum

66) Solving we get x = 21/2, y = 31/3, z = 51/5

Using graph of x1/x

⇒ 31/3 > 51/5
Also 21/2 < 31/3 21/2 > 51/5
as 23 < 32 25 > 52
⇒y>x>z
Hence (B), (C) & (D) are NOT true

67)
So m2 + n2 + 1 = n (2m + 2-n)
(m-n)2 + (n - 1)2 = 0 m = n = 1

68) (31 elements)

(31 elements)

Combined mean

Since, are in A.P. with 31 elements & common difference 1, same is , when
written in increasing order.

= 102 + 112 + ....... + 402

69)

=
=

70) where
3m+1
= 32 (2 ) = 32 (23)5m
5 3m
Now = 32
= 32 (1 + 7)5m
= 32 (7k + 1) where k
= 7q + 4 = clearly remainder is 4.

71) + ... +
=

So, = coeff of x22 in

a = 10 xy = 40 has total order pair (x, y) solution = 4 × 2 = 8

72) We must choose 3 distinct lengths from

{2, 3, 4, 5, 6, 7} and check the triangle
inequality (for ordered triple we
need a + b > c). The valid triples are :
(2, 3, 4), (2, 4, 5), (2,5,6), (2, 6, 7)
(3, 4, 5), (3, 4, 6), (3, 5, 6), (3, 5, 7), (3, 6, 7)
(4, 5, 6), (4, 5, 7), (4, 6, 7), (5, 6, 7)
there are n = 13 such triangles.
step-2 - Number of ordered pairs (x, y) with
lcm (x, y) = n + 2 .
n + 2 = 13 + 2 = 15 = 31. 51
let a is greatest & c is least side length b + c > a

73) 3 × 4 Grid :

Case-I : each row is coloured by (2R, 1M)

or by (1R, 2M)
∴ No row have same order of colour as other
∴ 3 dots of first row can be coloured in 6 ways

or
∴ total ways to colour 4 rows
= 6 × 5 × 4 × 3 = 360 ways
Case-II : one row having (3R) [4C1 ways]
other rows must have (1R, 2M)
∴ total cases = 4C1 × (3 × 2 × 1)
= 24 cases
Case-III : one row having (3M) [4C1 ways]
other rows must have (1M, 2R)
∴ total cases = 4C1 × 3 × 2 × 1
= 24 cases
Req. cases = case-I + case-II + case-III
= 408

74)

r = 0, r = 6, r = 12,....... r = 600
Total rational terms = 101

75) Let P(W1) = x

x + 2x + 22x + 23x + ... + 2119x = 1

....(1)
Rank of CDBEA
A____= = 24
B____= = 24
CA____= =6
CB____= =6
CDA___= =2
CDBAE=1
CDBEA=1
______________________
64
______________________
So, P(W64) = 2P(W63) = ... = 263 P(W1)

α + β = 63 + 120 = 183