07-12-2025

9610WJA801928250021 JA

PART 1 : PHYSICS

SECTION-I (i)

1) Find acceleration of the lower block w.r.t. upper block if both blocks were at rest initially and
then a force F acts on upper block as shown in figure. Friction coefficients between different

surfaces are as shown in figure.

(A) 1 m/s2
(B) Zero
(C) 2 m/s2
(D) 5 m/s2

2) From a circular disk of radius R, a triangular portion is cut (see figure). The distance of the centre

of mass of the remainder from the centre of the disk is-

(A)

(B)

(C)

(D)

3) A block ‘A’ of mass 10 kg having dimension “4 × 4 × 10” is placed on smooth plane. It is

connected to a body of unknown mass through a string passing through ideal pulley. If block ‘A’
slides on horizontal table without toppling than the maximum mass of the block is : :
(A)
kg

(B)
kg
(C) 10kg

(D)
kg

4) A 2m long light metal rod AB is suspended from the ceiling horizontally by means of two vertical
wires of equal length, tied to its ends. One wire is of brass and has cross-section of 0.3 × 10–4 m2 and
the other is of steel with 0.1 × 10–4 m2 cross section. In order to have equal stresses in the two wires,
a weight is hung from the rod. The position of the weight along the rod from end A should be :

(A) 66.6 cm
(B) 133 cm
(C) 50 cm
(D) 155.6 cm

SECTION-II (i)

Common Content for Question No. 1 to 2

In a certain system of absolute units, the acceleration produced by gravity in a body falling freely is
denoted by 20 unit, the kinetic energy of a 50 kg ball moving with a velocity of 10 m/s is denoted by
1000 unit and its momentum by 100. (In SI units g = 10 m/s2)

1) The unit of force in this new system is equal to ____ SI unit.

2) The unit of velocity in this new system is equal to _____ SI unit.

Common Content for Question No. 3 to 4

A particle of mass 10 kg is projected from a horizontal surface with a velocity of 20 m/s at an angle
of 60° with the horizontal. When it hits the horizontal surface, its velocity makes an angle of 30° with
the horizontal. Apart from gravity, a horizontal force acts on the particle during the motion (g = 10
m/s2)

3) The speed of the particle when it hits the ground is m/s. Find the value of x :-

4) The work done by the horizontal force (in kJ) during the complete motion is :-

Common Content for Question No. 5 to 6

Two objects are attached to ropes that are attached to wheels on a common axle so that they rotate
together as shown in figure. The total moment of inertia of the two wheels is 0.25 kg-m2. The radii of

the wheels are R1 = 3 R, R2 = R and R = .

5) If m1= 24 kg, find m2 (in kg) such that there is no angular acceleration of the wheels.

6) If 12 kg is gently added to the top of m1, find the angular acceleration (in rad/sec2) of the wheels.
(Consider values of m1 & m2 used/calculated in previous question.)

SECTION-I (ii)

1) Figure shows a wedge on which a small block is released from rest. All the surfaces are smooth
and system comprises of wedge and block. Mark the correct statement(s) regarding motion of block

on wedge till block attains maximum height on wedge.

(A) Acceleration of centre of mass of system is initially vertically down then vertically up.
(B) Initially centre of mass moves down and then up.
(C) At the maximum height, block and wedge have same velocity.
(D) Centre of mass of wedge moves towards left and then right

2) Potential energy function along x-axis in a certain free field is given as

For the given free field,

(A) the points of equilibrium are x = 1, x = 2 and x = 3

(B) the point x = 2 is a point of unstable equilibrium
(C) the points x = 1 and x = 3 are points of stable equilibrium
(D) there exists no point of neutral equilibrium

3) A small body of mass m is allowed to slide on an inclined frictionless track from rest position as
shown in the figure. If block successfully complete the loop of radius 1m :-

(A) Minimum height h, so that body may successfully complete the loop is 2.5 m
(B) Minimum height h, so that body may successfully complete the loop is 5m
(C) Minimum height h, so that body may successfully complete the loop is 6.5 m

(D) If velocity of the body is at the lowest point, normal force become zero when body
reaches at the highest point

4) The figure shows the stress-strain graphs for materials A and B. From the graph it follows that

(A) Material A has a higher Young’s modulus

(B) Material B is more ductile
(C) Material B can withstand greater stress
(D) Material A can withstand greater stress

5) The displacement-time graph of a particle executing SHM is shown. Which of the following
statements is/are true?

(A) The velocity is maximum at t = T/2

(B) The acceleration is maximum at t = T
(C) The force is zero at t = 3T/4
The potential energy equals the oscillation energy at t = T/2. Assuming minimum potential
(D)
energy in zero at means position

6) Figure shows a block of mass m projected with velocity v0 towards a wedge. Consider all the
surfaces to be smooth. Block does not have sufficient energy to negotiate (over come) wedge. Mark

the correct option(s).

When block is at the maximum height on wedge, block and wedge have velocity equal to
(A)
velocity of centre of mass of block wedge system
Wedge acquires maximum speed with respect to ground when block returns to lowest point on
(B)
wedge.
(C) Momentum of wedge and block is conserved at all times
(D) Centre of mass of wedge and block remains stationary

SECTION-II (ii)

1) A particle of mass 2 kg moving with constant speed 4 m/sec. Now a force which varies as shown
in the graph below acted on the particle along initial velocity. The final velocity acquired by the

particle is α times 13 m/sec. Find α.

2) Ball A of mass 1 kg moving right with speed 2 m/s bounces off ball B of mass 1.5 kg, and then
moves left with speed 4 m/s.

Calculate magnitude of impulse (SI Units) received

by ball B.

3) A uniform rod of mass 3kg and 1 m length is hinged at an end as shown. If a bullet of mass 1kg
moving horizontally with velocity 10 m/s hits at the other end of rod and gets embedded as shown,
then find angular velocity (in rad/s) attained by rod just after collision.

PART 2 : CHEMISTRY

SECTION-I (i)

1) Choose the aromatic nitrogen heterocycles.

(A) (i)
(B) (ii)
(C) (iii)
(D) (i) and (ii)

2) Benzene is a resonance hybrid mainly of two Kekule’s structures. Hence :

(A) Half of the molecules correspond to one structure, and half of the second structure
(B) At low temperatures benzene can be separated into two structures
(C) Two structures make equal contribution to resonance hybrid
(D) An individual benzene molecule changes back and forth between two structures

3) Considering C2–C3 bond rotation, the most stable conformation for the compound

among following :

(A)

(B)

(C)

(D)

4) Identify pair in which Ist structure is more stable than IInd ?

(A)

(B)

(C)
(D)

SECTION-II (i)

Common Content for Question No. 1 to 2

A container is divided into two compartment. One compartment contains 2 mole of N2 gas at 1 atm
and 300 K & other compartment contains H2 gas at the same temperature and pressure. Volume of
H2 compartment is four times the volume of N2 compartment.
[Assuming no reaction under these condition]

1) If the container containing N2 & H2 are further heated to 1000 K, forming NH3 with 100% yield.
Calculate the final total pressure.

2) Calculate the final total pressure if partition between two compartments is removed. (No reaction
is taking place)

Common Content for Question No. 3 to 4

In a balance redox reaction, net gain of electron(s) is equal to net loss of electrons(s). nfactor is a
reaction specific parameter and for inter molecular redox reaction nfactor of oxidising or reducing
agent is the no. of moles of electron gained / loss by one mole of compound, respectively.

3) 50 ml 0.1M CuSO4 is mixed with 50 ml of 0.1M KI. Then number of moles of K2SO4 produced (as
per above reaction) is x × 10–3. The value of x is.

4)

Consider the following reaction :

CrO5 + H2SO4 → Cr2(SO4)3 + H2O + O2
One mole of CrO5 will librate how many moles of O2

Common Content for Question No. 5 to 6

Entropy is a state function and its value depends on two or three variables temperature (T), Pressure
(P) and volume (V). Entropy change for an ideal gas having number of moles (n) can be determined
by the following equation.

ΔS = 2.303 nCV log + 2.303 nR log

ΔS = 2.303 nCp log + 2.303 nR log

Since free energy change for a process or a chemical equation is a deciding factor of spontaneity,
which can be obtained by using entropy change (ΔS) according to the expression, ΔG = ΔH – TΔS at
a temperature T.

5) An isobaric process having one mole of ideal gas has entropy change 23.03 J/K for the
temperature range 27°C to 327°C. What would be the molar specific heat capacity (CV) ?

6) What would be the entropy change involved in thermodynamic expansion of 2 moles of a gas from
a volume of 5 L to a volume of 50 L at 25°C [Given R = 8.3 J/mole – K]

SECTION-I (ii)

1) 100 mL of 0.06 M Ca(NO3)2 is added to 50 mL of 0.06 M Na2C2O4. After the reaction is complete

(A) 0.003 moles of calcium oxalate will get precipitated.

(B) 0.003 M of excess of Ca2+ will remain in excess.
(C) Na2C2O4 is limiting reagent.
(D) Ca(NO3)2 is excess reagent.

2)

Select the correct statement -

(A) C–O bond length of CO molecule is higher than the C–O bond length of CO2
(B) C–O bond length of CO molecule is lower than the C–O bond length of CO2

(C)
N–O bond length of ion is higher than the N–O bond length of

(D)
N–O bond length of ion is lower than the N–O bond length of

3) Choose the correct options for NO2 :

(A) It is odd electron specie

(B) N–O bond order = 1.5
(C) Paramagnetic specie
(D) Isoelectronic with CO2

4) Which of the following orders of atomic / Ionic radius is correct?

(A) B < Ga ≲ Aℓ
(B) Cu < Zn
(C) C < O < N
(D) Al3+ < Al2+ < Al+

5) In which of the following pairs of compounds, will second structure have more contribution to
resonance hybrid than first ?
(A)

(B)

(C)

(D)

6) Choose the reaction(s) from the following options, for which the standard enthalpy of reaction is
equal to the standard enthalpy of formation?

(A)

(B)
S8(s,rhombic) + O2(g) → SO2(g)
(C) 2H2(g) + O2(g) → 2H2O(l)
(D) 2C(g) + 3H2(g) → C2H6(g)

SECTION-II (ii)

1) Enthalpy for the reaction, A+(aq.) + B–(aq) → AB(s) is –20 kcal. Magnitude of enthalpy of
+ – +
formation of A (aq) and B (aq) are in the ratio 4 : 5. Formation of A (aq) is an endothermic process
whereas formation of B–(aq) is an exothermic process enthalpy of formation of AB(s) is –21.5 kcal
mol–1. Calculate the enthalpy of formation of A+(aq) in Kcal mol–1.

2) From the given list, the number of compounds with + 4 oxidation state of Sulphur ________.
SO3, H2SO3, SOCl2, SF4, BaSO4, H2S2O7

3)

How many carbons are present in parent carbon chain of following compound :
 PART 3 : MATHEMATICS

SECTION-I (i)

1) Find the total number of 4 letter words formed using four letters from the word
'PARALLELOPIPED'.

(A) 2780
(B) 2480
(C) 2680
(D) 3000

2) The sum of series equals

(A) 5050
(B) 5051
(C) 4950
(D) 5151

3) y2 – 2x – 2y + 5 = 0 is :

(A) a circle with centre (1, 1)

(B) a parabola with vertex (1, 2)
(C) a parabola with directrix x = 3/2
(D) a parabola with directrix x = –1/2

4)

A variable circle S passes through points (–2, –a), (–a, –2) and (–a, –a), where a is a parameter and a
≠ 2, then circle S will always pass through the point/points -

(A) (0, 0)
(B) (–1, –1)
(C) (–2, –2)
(D) no such fixed point

SECTION-II (i)

Common Content for Question No. 1 to 2

Given pair of lines 2x2 + 5xy + 2y2 + 4x + 5y + a = 0 and the line L as bx + y + 5 = 0.

1) If pair of lines 2x2 + 5xy + 2y2 + 4x + 5y + a = 0 and L : bx + y + 5 = 0 are concurrent then 'b' is

2) If there exactly 2 circles which touch pair of lines and line L simultaneously, then sum of possible
values of b is

Common Content for Question No. 3 to 4

We know that 1 + 2 + 3 + ...n = = f(n),

12 + 22 + 32 + ... + n2 = = g(n),

13 + 23 + 33 + ... + n3 = = h(n).

3) Find

4) must be equal to

Common Content for Question No. 5 to 6

A circle touches both the circle x2 + y2 = 25 and (x – 2)2 + y2 = 1. Then locus of its centre is

5) An ellipse, whose length of major axis is

6) An ellipse with auxiliary circle x2 + y2 – 2g x – 2fy – c = 0 then g + f + c is equal to

SECTION-I (ii)

1) If circle S : x2 + y2 + 2gx + 2ƒy + c = 0 is orthogonal to x2 + y2 + 4x + 2y + 3 = 0 and passes

through point of intersection of circles S1 : x2 + y2 = 1 and S2 : x2 + y2 + 2x + 2y + 1 = 0, then

(A) intercept on x-axis by S = 0, is 1 unit

(B) intercept on y-axis by S = 0, is 1 unit
(C) g + ƒ + c = 1
(D) g + ƒ + c = 2

2) N = number of ways of distributing 12 identical balls among 3 persons so that each can recieve
none, one or more balls then select correct options

14
(A) N= C2
(B) N = coefficient of x12 in (1+x+x2+…….∞)3
 14
(C) N= C3
(D) N = coefficient of x12 in (x + x2 + x3+…….∞)3

3) The coefficient of x4 in , | x |<1, is

(A) 4
(B) -4
(C)
(D) 16

4) For non-negative integers s and r, let

For positive integers m and n, let g (m, n) =

Where p is any non-negative integer, f(m, n, p) =

Then which of the following statements is/are TRUE?

(A) g(m, n) = g(n, m) for all positive integers m, n

(B) g(m, n +1) = g(m + 1, n) for all positive integers m, n
(C) g(2m, 2n) = 2g(m, n) for all positive integers m, n
(D) g(2m, 2n) = (g(m, n))2 for all positive integers m, n

5) The equations of perpendicular of the sides AB & AC of ΔABC are x – y – 4 = 0 and 2x – y – 5 = 0

respectively. If the vertex A is (–2, 3) and circumcenter is then which of the following is
true.

(A) Equation of median of side AB is x – y + 1 = 0

(B) Centroid of triangle ABC is (3, 1)
(C) Vertex C is (4, 0)
(D) Area of triangle ABC is 12.

6) Equations of circles which pass through the points (1,–2) and (3,–4) and touch the x-axis is

(A) x2 + y2 + 6x + 2y + 9 = 0
(B) x2 + y2 + 10x + 20y + 25 = 0
(C) x2 + y2 – 6x + 4y + 9 = 0
(D) x2 + y2 + 10x + 20y –25 = 0

SECTION-II (ii)
1) If y = mx + 4 is a tangent to both the parabolas, y2 = 4x and x2 = 2by, then is equal to

2) The tangent at any point P of a circle x2 + y2 = a2 meets the tangent at a fixed point A (a, 0) in T
and T is joined to B, the other end of the diameter through A. If 'e' is the eccentricity of a conic
which is the locus of the point of intersection of AP and BT, then find then value of .

3) Let 5 boys & 4 girls sit in a straight line. If the number of ways in which they can be seated if 2
girls are together & the other 2 are also together but separated from the first 2 are N, then sum of
digits of N is
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B D B C

SECTION-II (i)

Q. 5 6 7 8 9 10
A. 5.00 0.50 12.00 4.00 72.00 10.00

SECTION-I (ii)

Q. 11 12 13 14 15 16
A. B,C A,B,C,D A,D A,D B,C,D A,B

SECTION-II (ii)

Q. 17 18 19
A. 3 6 5

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 20 21 22 23
A. D C C A

SECTION-II (i)

Q. 24 25 26 27 28 29
A. 2.00 1.00 2.50 1.75 24.00 to 25.00 38.00 to 39.00

SECTION-I (ii)

Q. 30 31 32 33 34 35
A. A,C,D B,C A,B,C A,B,D A,B,C A,B

SECTION-II (ii)

Q. 36 37 38
A. 6 3 5

PART 3 : MATHEMATICS
 SECTION-I (i)

Q. 39 40 41 42
A. A D C C

SECTION-II (i)

Q. 43 44 45 46 47 48
A. 5.00 2.50 70.00 1.00 6.00 9.00

SECTION-I (ii)

Q. 49 50 51 52 53 54
A. A,B,C A,B C,D A,B,D C B,C

SECTION-II (ii)

Q. 55 56 57
A. 2 3 9
 SOLUTIONS

PART 1 : PHYSICS

1) Question Explanation:
The problem asks to calculate the relative acceleration of two blocks as shown in figure, when
a horizontal force is applied to the upper block.

Concept:
This question is based Friction, block over block system.

Solution:
(1) Limiting friction between for blocks = 0.3 × 20 = 6N

(2) Let the acceleration of system (common acceleration)

= 1 m/s2

(3) Check for ac

FBD of 3 kg block
∴ fs = 3 × 1 = 3N (< 6N)

So, both the blocks have same acceleration i.e., their relative acceleration will be zero.

Final answer: The correct option is (2).

2)

Explain Question : The problem asks for the distance of the center of mass of the remaining
portion of a circular disc after a triangular section is removed
Concept : This question is based on center of mass.
Solution :

Let mass per unit area be σ

Final answer : 4

3)

Explain Question: Determine the maximum hanging mass that will cause the block to slide
instead of toppling by checking torque balance.
Concept: Rotational equilibrium & toppling
Solution:
Taking torque about centre of mass

(T) (5) = (N) (2)

T(5) = 100 (2)
T = 40
Acceleration of 10 kg block is 4 m/s2
∴ acceleration of M will also 4
10 m – 40 = 4 m
Final Answer: Option (B) is Correct.

4)

Explain Question: Find the position x from end A so that stresses in brass and steel wires
become equal.

Concept: Stress = ; equilibrium of forces and moments.

Solution:

Force balance:

Torque about A:

Final Answer: Option (C) is Correct.

5)

Explain Question: Convert the force unit of the newly defined system into SI units using
dimensional relations provided.
Concept: Dimensional analysis
Solution:
New units

m* = pm
kg* = q kg
S* = rs

g = 10 = 20
 ....(1)
momentum

....(2)
Kinetic energy

....(3)
from (1), (2) & (3)

, q = 10, r = 1

Velocity

∴ 1 m*/s* = 0.5 m/s

Final Answer: 5

6)

Explain Question: Convert the force unit of the newly defined system into SI units using
dimensional relations provided.
Concept: Dimensional analysis
Solution:
New units

m* = pm
kg* = q kg
S* = rs

g = 10 = 20

....(1)
momentum

....(2)
Kinetic energy

....(3)
from (1), (2) & (3)
 , q = 10, r = 1

Velocity

∴ 1 m*/s* = 0.5 m/s

Final Answer: 0.50

7)

Explain Question: Calculate the horizontal distance traveled by a projectile when a

horizontal force modifies its final velocity angle.
Concept: Projectile with altered horizontal component
Solution:
vy = same ⇒ 20 sin 60 = v sin 30°

Final Answer: 12

8)

Explain Question: Compute work done by the horizontal force during the projectile’s motion
using energy change.
Concept: Work–energy theorem
Solution:

Final Answer: 4

9)

Explain Question: Find the mass m such that the two-wheel rotational system has zero
angular acceleration.
Concept: Torque balance
Solution:
m1gR1 = m2gR2
⇒ 24 × 3R = m2 × R ⇒ m2 = 72 kg
Final Answer: 72

10)

Explain Question: Determine the angular acceleration after adding extra mass to the
rotational setup.
Concept: Rotational Dynamics
Solution:
 ......(1)
36g – T1 = 3Rα × 36
⇒ T1= 36g – 9α ......(2)
T2 – 72g = Rα × 72
T2 = 6α + 72 g ......(3)
From (1), (2) & (3)
α=g
Final Answer: 10

11)

Explain Question: Analyse motion of block on a smooth wedge and choose statements that
stay valid through entire motion.
Concept: Momentum Conservation
Solution:

acom =
and momentum is conserved of the system.
Final Answer: Option (B,C) is Correct.

12) Explanation Question: We are given a potential energy as a function of position we have
to comment the type of equilibrium.
Concept: Conmment the type of equilibrium
Solution:
For equilibrium points,
∴ Final answer = option 1,2,3 and 4

13) Explanation of Question:

It is asking the value of height 'h' for successful completion of the loop and normal at the top
in the given diagram.
Concept:
This question is based on vertical circular motion.
Solution:
For the completing vertical circular track , the minimum velocity at the lowest position should
be
Now
wg = Δk
mgh = kf – ki

mgh =
2gh =
2gh = 5gr
2gh = 5g × 1
h = 2.5 m
At the............. lowest point if and when it reaches at heighest point normal force will
be zero.

Final Answer:
options are (1) and (4).

14)

Explain Question: From the stress - strain graph, compare Young's Modulus, ductility, and
maximum stress of materials A and B.
Concept: Slope → Young's modulus; Fracture strain → Ductility; Peak Stress → strength.
Solution:
The slope of the linear portion of the curve gives the Young’s modulus of the material. The
slope of the linear portion OP for material A is greater than that of the linear portion
of material B. Hence, statement (a) is correct.
The plastic region for material A (from P to Q) is greater than that (from R to S) for material B,
which indicates that material A is more ductile. Hence, statement (b) is correct.
The breaking stress for material for material B (i.e. stress corresponding to point S) is less
than that for material A (i.e. stress corresponding to point Q), which implies that material
B can break more easily than material A. Hence, choice (c) is also incorrect.
Material A is stronger than material B because it can withstand a greater stress before it
breaks. The breaking stress is the stress corresponding to point Q for material A and to point
S for material B. Hence,
Final Answer: Option (A, D) is Correct.

15) Question Explanation:

Identifying true statements about a particle's SHM from its displacement-time graph.

Concept:
This question is based on relationship between displacement, velocity, acceleration, force, and
energy in SHM.

Solution:
Velocity is maximum at mean position & acceleration is maximum at extereme position. At
mean position acceleration is zero.
The force is zero at t = 3T/4, This statement is correct because 3T/4 is the mean position.
The potential energy equals the oscillation energy at t = T/2. This statement is correct because
T/2 is extreme position so velocity is zero.

Final Answer :
The correct option is (2), (3) and (4).

16)

Explain Question: Block of mass m (speed v0) moves on smooth wedge M; choose true
statements about velocities/ momentum/COM.
Concept: Horizontal momentum conserved; when block momentarily stops on the wedge its
velocity equals wedge's velocity; energy exchange between block and wedge during climb/fall.
Solution:
(i) in horizontal direction momentum is conserved. when block is at maximum height it would
be stationary w.r.t. plank.
So vblock = vplank = vcm
(ii) PE + KE = constant
(iii) momentum is not conserved at all time.
(iv) vcm ≠ 0
Final Answer: Option (A, B) is Correct.

17)

Explain Question: Find α by calculating total impulse from the given force–time graph and
determining final velocity.
Concept: Impulse–momentum
Solution:

vf – 4 = 35
vf = 39 m/sec.
Final Answer: 3

18)

Explain Question: Calculate impulse transferred to ball B by analysing momentum change of

ball A.
Concept: Collision
Solution:
Impulse on ball B = change in momentum of
 = impulse on A
⇒ 1× 2 - 1(-4)
= 6 kgm/sec.
Final Answer: 6

19)

Explain Question: Compute angular speed of rod–bullet system using angular momentum
conservation about the hinge.
Concept: Angular momentum conservation
Solution:

Final Answer: 5

PART 2 : CHEMISTRY

20) Explain Question: To find the aromatic nitrogen heterocycles

Concept: Aromaticity
Solution:

Final Answer: (D)

21) Question Explanation: The question asks which statement correctly explains benzene’s
resonance nature.
Concept: This question is based on resonance and aromaticity.
Solution:
Benzene is not oscillating between two Kekulé structures nor separable into them. Instead, it
exists as a resonance hybrid in which π electrons are delocalized over the entire ring. Both
Kekulé structures are equivalent and contribute equally to the resonance hybrid.
Final Answer:(C)

22)

Explaining the Question : Question is asking about the most stable conformation.
Concept: This question is based on strains, repulsions and intramolecular H-bond present in
different conformers.
Solution :-

In this molecule intramolecular H-bond is possible in gauche conformer, therefore gauche

conformer is the most stable.

Final Answer : (C)

23)

Explanation of Question : To identify the pair in which Ist structure is more stable than IInd.
Concept : Resonance and hyperconjugation effect.
Solution :

Structure I has 5 resonating structure but

structure II has 4 resonating structure (R.S.).

→ Due to hyperconjugation effect, negative charge acquire on

nd
primary carbon in II structure. Primary carbanion is more stable than secondary carbanion.

→ In Cis-1, 2-dichloroethene dipole-dipole attraction increases its

stability.
 → Ist and IInd are R.S. of each other, IInd has maximum benzenoid
structure so more stable resonating structure.
Final answer : (A)

24) Explain Question: To find the final total pressure

Concept: PV = n RT
Solution:
At 1000 K
N2 + 3H2 → 2NH3
2 8
- 2 4
nT = 6 mole

PT =
Final Answer: (2.00)

25) Explain Question: To find the final total pressure if partition between two compartments
is removed
Concept: Conservation of moles.
Solution:
nT = 2 + 8 = 10 moles
As volume of H2 compartment is four times that of N2 compartment
Final Answer: (1.00)

26) Explain Question: To find number of moles of K2SO4 produced

Concept: equivalent KI = equivalent of electron
Solution:
milli equation of CuSO4 = 0.1 × 50 × 1 milli equivalent of KI = 0.1 × 50 × 1/2
hence KI is limiting reactant
equivalent KI = equivalent of electron

=n×1
–3
n = 2.5 × 10 moles.
Final Answer: (2.50)

27) Explain Question: To find One mole of CrO5 will librate how many moles of O2
Concept: Balancing of redox reaction.
Solution:

2CrO5 + 3H2SO4 → Cr2(SO4)3 + 3H2O + O2

One mole of CrO5 will produce 7/4 moles of O2
Final Answer: (1.75)

28) Explain Question: To find What would be the molar specific heat capacity (CV)
Concept: ΔS = 2.303 nCp log + 2.303 nR log (As ΔP = 0)
Solution:

ΔS = 2.303 × 1 × CP log = 23.03 ⇒ CP =

CV = CP – R =
Final Answer: (24.00-25.00)

29) Explain Question: To find the entropy change involved in thermodynamic expansion of 2
moles of a gas from a volume of 5 L to a volume of 50 L at 25°C

Concept: ΔS = 2.303 nCp log + 2.303 nR log

Solution:

ΔS = 2.303 x 2 x 8.3 log = 38.23 J/K

Final Answer: (38.00-39.00)

30)

Explain Question: To find the correct statement

Concept: Redox reaction
Solution:

100 ml of 0.06 M Ca(NO3)2 contains 100 × 0.06 = 6 millimole

50 ml of 0.06 M Na2C2O4 contains 50 × 0.06 = 3 millimole
3 millimoles of will react with 3 millimoles of Ca2+ for 3 millimoles of

moles
(a) is correct

Excess of Ca2+ left = 6 – 3 = 3 millimoles = moles

(c) is correct because sodium oxalate is present in smaller amount than required
(d) is correct because Ca (NO3)2 is present in large amount
Final Answer: (ACD)

31) Question Explanation: Compare the bond length of C–O in CO vs CO2 and N–O in NO–2 vs
NO3 . –

Concept:This question is based on Bond length and bond order relationship.

Solution:
Final Answer: (BC)

32) Explain Question: To find the correct options for NO2

Concept: odd electron molecule
Solution:

BO = =1.5
So, correct options is A,B,C.
Final Answer: (ABC)

33)

Explain Question: To find which of the following orders of atomic / Ionic radius is correct
Concept: Periodic properties.
Solution:
(A) B < Al ≅ Ga⇒ B < Al : n ,size
⇒ Al ≅ Ga : d-contraction/scandide contraction
(B) Cu < Zn ⇒ 3d- series size order
(C) C < O < N ⇒ incorrect order as left to right in period, size decreases
Correct order: C > N > O
(D) Al3⊕ < Al2⊕ < Al⊕ ⇒ As cationic charge increases on atom, zeff increases & hence size of
cation decreases.
Final Answer: (ABD)

34) Explanation - Asking about the pair of structures in which II contribute more than I in
resonance hybrid.
Concept - This question is based on resonance effect and stability of resonating structure.
Solution -
More stable resonance structure contributes more to the resonance hybrid.
Resonance structure having more number of bonds is the more stable.
In resonance structures of options 1, 2 & 3, Structure II have complete octet at all atoms
(except-H) and more number of π-bonds. Therefore in options 1,2 and 3 Stability &
 contribution in resonance hybrid: II >I
In resonance structures of option-4, structure I have complete octet and more stable than
II.

Final Answer: (ABC)

35) Question Explanation: Identify a reaction in which the standard enthalpy of reaction is
equal to the standard enthalpy of formation.
Concept: This question is based on standard enthalpy of formation.
Solution:
Heat released or absorbed when one mole of compound is formed from its constituent
elements in their standard state is called standard enthalpy of formation. In option (3) two
moles of H2O are being formed and in option (4) carbon is not its standard state.
Final Answer: (AB)

36) Question Explanation: Find ΔHf of A+(aq) using given ratio data.
Concept: This question is based on Hess’s law.
Solution:
A+(aq) + B– (aq) → AB(s)
0
ΔfH (kcal/mole) 4x –5x –21.5
0
ΔrH = – 20 = (–21.5) – (4x – 5x)
x = 1.5
0
(ΔfH )A+ = 4x = 6
Final Answer: (6)

37) Explain Question: To find From the given list, the number of compounds with + 4
oxidation state of Sulphur
Concept: Calculation of oxidation state.
Solution:

Compounds SO3 H2SO3 SOCl2 SF4 BaSO4 H2S2O7

[Link] Sulphur: +6 +4 +4 +4 +6 +6

Final Answer: (3)

38)

Explanation Question: Question is asking number of carbon atom in parent chain.

Concept: This question is based on IUPAC nomenclature.
Solution:
⇒ For selection of main chain or parent chain in compound according to IUPAC nomenclature.
Senior most functional group > Maximum number of multiple bond > Maximum number of
carbon atom > Maximum number of side chain.

Given compound has main functional group.

 So, it has five carbon atoms in main chain or parent chain.

Final answer: (5)

PART 3 : MATHEMATICS

39) Explain Question: We have to find total number of 4 letter word formed from given word.
Concept: Selection of letters.
Solution:
Given letters are PPP, LLL, AA, EE, R, O, I, D..

Final Answer: (A)

40) Question Explain: We have to find value of expression

Concept:

Solution:
= (102)(101) –
= (101)(102 – 51) = 5151

Final Answer: Option (4)

41) Explain Question: We have to check given equation represent which conic.
Concept: Make perfeet square.
Solution:
y2 – 2x – 2y + 5 = 0
y2 – 2y + 1 – 2x + 4 = 0
(y – 1)2 = 2x – 4
(y – 1)2 = 2(x – 2)
Y2 = 4AX
Y=y–1 X=x–2
4A = 2

Vertex (2, 1) A =
Directrix → X = –A

x–2=–

x=
Final Answer: (C)

42) Explain Question: A circle passes through given point. We have to check from which
point it always pass.
Concept: Cyclic quadrilateral.
Solution:

Points (–2,–a), (–a,–a), (–a,–2) and (–2,–2) form a cyclic quadrilateral

Final Answer: (C)

43) Explain Question : We have to find the value of b when line are concurrent
Concept : Concurrent lines
Solution : For pair of straight lines,
abc + 2fgh – af2 – bg2 – ch2 = 0

⇒a=2
2x + 5xy + 2y2 4x + 5y + 2 = 0
2

2x + y + 2 = 0 or x + 2y + 1 = 0
Line bx + y + 5 = 0

If lines are concurrent then

2(9) – (5 – b) + 2(1 – 2b) = 0
15 = 3b ⇒ b = 5
Final Answer : (5.00)

44) Explain Question : We have to find the sum of value of b

Concept : Parallel lines
Solution : For pair of straight lines,
abc + 2fgh – af2 – bg2 – ch2 = 0

⇒a=2
2x + 5xy + 2y2 4x + 5y + 2 = 0
2

2x + y + 2 = 0 or x + 2y + 1 = 0
Line bx + y + 5 = 0
It is only possible when the lines L is parallel to L1 or L2

–2 = –b or –b =

b = 2 or b =
Final Answer : (2.50)

45) Explain Question: We have to find value of given expression.

Concept: f(n) – g(n).
Solution:
g(n) – f(n)

[2n + 1 – 3]
 =
Final Answer: (70.00)

46) Explain Question: We have to find value of given expression.

Concept: Put n → n – 1 to get g(n–1).
Solution:

Final Answer: (1.00)

47) Explain Question: We have to find locus of center of circle which touch given circles.
Concept: c1 c2 = r1 + r2.
Solution:
Let center of variable circle be (h, k), Then

(h – 2)2 + k2 = (1 + r)2
h2 + k2 = (5 – r)2
(h – 2)2 – h2 = (1 + r)2 – (5 – r)2

locus is
length of major axis = 6
Final Answer: (6.00)

48) Explain Question: We have to find auxiliary circle of ellipse.

Concept: auxiliary circle x2 + y2 = a2.

Solution:
Let center of variable circle be (h, k), Then
 (h – 2)2 + k2 = (1 + R)2
h2 + k2 = (5 – r)2
(h – 2)2 – h2 = (1 + r)2 – (5 – r)2

locus is
Auxiliary circle in (x – 1)2 + y2 = 32
x2 - 2x + y2 + 1 = 9
Final Answer: (9.00)

49)

Explain Question: We have to find circle which passes through intersection of S1 & S2 and
orthogonal to given circle.
Concept : Family of circle and orthogonal circle
Solution:
S : S1 + λS2 = 0
x2(1 + λ) + y2 (1 + λ) + 2λx + 2λy + λ – 1 = 0
S is orthogonal to x2 + y2 + 4x + 2y + 3 = 0
∴ 2g.2 + 2ƒ.1 = 3 + l – 1
∴λ=1
∴ S : x2 + y2 + x + y = 0
Final Answer: (A,B,C)

50) Explain Question: Number of ways to distribute 12 identical balls among 3 persons.
Concept: Multinomial theorem.
Solution:
x + y + z = 12
x ≥ 0; y ≥ 0, z ≥ 0; x,y,z ∈
Number of ways = 14C2
Coeff of x12 in (1+x+x2+…….∞)3 = Coefficient of x12 in (1 – x)–3
= 3+12–1C12 = 14C12
Final Answer: (A,B)

51) Explain Question: We have to find coefficient of x4 in given expression.

Concept: Binomial expression.
Solution:
 Given , | x |<1

=
= (1 + 2x + x2) (1 + 2x + 3x2+ 4x3 + 5x4 + .........)
So, Coefficient of X4 = (1) (5) + (2) (4) + (1) (3) = 5 + 8 + 3 = 16
Final Answer: (C,D)

52)

Explain question : We have to evaluate sum of scries given by g(m,m) =

Concept : This question is based on sum of series using binomial coefficients

Solution :-
Solving

m
Ci . n+iCp . p+nCp–i

m
Ci . n+pCp . nCp–i {mCi . nCp–i = m+nCp}
f(m, n, p) = n+pCp . m+nCp

Now

g(m, n) = 2m+n
(A) g(m, n) = g(n, m)
(B) g(m, n + 1) = 2m+n+1 g(m + 1, n) = 2m+1+n
(D) g(2m, 2n) = 22m+2n
= (2m+n)2
= (g(m, n))2
Final answer :- (1),(2)&(4)

53)

Explain Question : Two side, one vertex and circumcenter of triangle is given. We have to
check which option is correct.
Concept : Equation of line, image of a point.
Solution :

Equation of line L1 is y – = 2 . (x – )

Or 2x – y – = 0
Or 4x – 2y – 1 = 0
equation of line L2 is L2

y – = 1 (x – ) or x – y + 1 = 0
Point C is mirror image of point A w.r.t line L1

= = ∴ C(4, 0)
similarly B is mirror image of A in line L2 = 0

= 4 ∴ B(2, – 1) ⇒ D(1, ) ; E (0, 1)

median through B is (y + 1) = (x – 2) ⇒ 5x + 2y = 8

median through C is (y – 1) = ⇒ x + 4y = 4.

Area = Centroid ≡
Final Answer: (C)

54)

Explain Question: We have to find equation of circle passing through two given points and
touch x-axis.
Concept: Circle touch x-axis then g2 = c.
Solution:
Let equation of required circle is
x2 + y2 + 2gx + 2fy + c = 0
it passes through (1,–2) & (3,–4)
2g – 4f + c = – 5 … (i)
6g – 8f + c = – 25 … (ii)
Equation (ii) – 2(equation (i)
2g – c + 15 = 0
circle touches x – axis g2 = c
g2 – 2g – 15 = 0
g = 5, -3
 g = 5 , c = 25, f = 10 ⇒ x2 + y2 + 10x + 20y + 25 = 0
g = –3 , c = 9, f = 2 ⇒ x2 + y2 – 6x + 4y + 9 = 0
Final Answer: (B,C)

55)

Explain the question : In this question, we have to given a line which is tangent to two

parabolas then ask the value of

Concept : This question is based on tangent and normal of the parabola
Solution :-
Any tangent to parabola y2 = 4x is y = mx + a/m

On comparing with y = mx + 4, we have

1/m = 4 ⇒ m=1/4
Now, equation of tangent y = (x/4) + 4 to x2 = 2by
x2 = 2b(x/4+4)
or 2x2 - bx - 16b = 0
Find the value of b:
Discriminant, D = 0
so, b2 + 128 b = 0
b(b +128) = 0
b = 0 and b = –128

so,
Final answer :- (2)

56) Explain Question: We have to find locus of point of intersection of given lines from given
data.
Concept: Equation of tangent.
Solution:

equation of PT
x cosθ + y sinθ = a and equation of TA ⇒ x = a

solving above equation x = a and y = a tan

Now equation of BT ⇒ ...(1)

equation of PA ⇒ ...(2)
multiply (1) and (2) ⇒

Final Answer: (3)

57)

Explain Question: We have to find number of ways to arrange 5 boys, 2 girls according to
given information
Concept: Arrangement
Solution:
Step 1st : Arrange 5 boys in 5! ways
Step 2nd : Select 2 gaps from 6 gaps for 4 girls (2girls for each gap) in 6C2 ways.
Step 3rd : Select 2 girls to sit in one of the gaps and other 2 in remaining selected gaps
= 4C2 ways
Step 4 : Arrange 1st, 2 girls in 2! and other 2 in 2! Ways
Hence, total ways (N) = 5! × 6C2 × 4C2 × 2 × 2 = 43200
Sum of digits of N = 4 + 3 + 2 + 0 + 0 = 9
Final Answer: (9)